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A simple method to valorize silica sludges into sustainable coatings for indoor humidity buffering 一种将二氧化硅污泥估价为室内湿度缓冲用可持续涂料的简单方法
IF 4.9 3区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2021-09-15 DOI: 10.21203/rs.3.rs-871601/v1
C. Kuok, Wahid Dianbudiyanto, Shou‐Heng Liu
In this study, the production of indoor humidity-buffering coatings (IHC-s) from recycling waste silica sludges by using a room-temperature sol-gel method which is a simple and energy-efficient route is reported. The properties of these IHC-s are identified by scanning electron microscope, X-ray diffraction, X-ray fluorescence spectrometer, laser particle size analyzer, N 2 adsorption-desorption isotherms and toxicity characteristic leaching procedure (TCLP). The moisture adsorption-desorption tests show that the IHC-s have moisture buffering values of ca. 270–316 g m − 2 and moisture contents of 23.6–26.7% in the range of 50–90% relative humidity (RH). Furthermore, the humidity buffering capacities, moisture adsorption-desorption rate and stability are significantly superior to commercially available coatings in the range of 50–75% RH. The enhancement may be due to the formation of porous structure in the coatings via the dispersed waste silica sludges and gypsum which transformed from bassanite by self-assembly process. Most importantly, the prepared IHC-s show surpassing antimicrobial efficacy (> 99.99%) and no detectable leaching heavy metals based on TCLP tests, which provides an economic and environmental-friendly route for recovering and valorizing industrial wastes.
本研究报道了利用回收的废弃二氧化硅污泥,采用室温溶胶-凝胶法生产室内湿度缓冲涂料(IHC-s),这是一种简单高效的方法。通过扫描电子显微镜、X射线衍射、X射线荧光光谱仪、激光粒度分析仪、N2吸附-解吸等温线和毒性特征浸出程序(TCLP)对这些IHC的性质进行了鉴定。水分吸附-解吸试验表明,IHC-s的水分缓冲值约为270–316 g m− 在50–90%的相对湿度(RH)范围内,水分含量为23.6–26.7%。此外,在50–75%RH范围内,湿度缓冲能力、水分吸附-解吸速率和稳定性显著优于商用涂料。这种增强可能是由于分散的废二氧化硅污泥和石膏通过自组装过程从蓝晶石转化而来,在涂层中形成多孔结构。最重要的是,制备的IHC-s显示出超越的抗菌功效(> 99.99%),并且基于TCLP测试没有可检测的浸出重金属,这为回收和估价工业废物提供了一条经济和环境友好的途径。
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引用次数: 0
Assessment of surface water quality and monitoring in southern Vietnam using multicriteria statistical approaches 使用多标准统计方法评估越南南部地表水质量和监测
IF 4.9 3区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2021-09-15 DOI: 10.1186/s42834-022-00133-y
Thanh Giao Nguyen, Thi Hong Ngu Huynh
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引用次数: 10
Efficient isolation of keratin from protein-rich waste biomass: a practical approach to minimize environmental impact and valorize waste biomass 从富含蛋白质的废弃生物质中有效分离角蛋白:一种减少环境影响并使废弃生物质增值的实用方法
IF 4.9 3区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2021-09-10 DOI: 10.1186/s42834-022-00152-9
K. Prasad, T. Maity, Nripat Singh, P. Vaghela, A. Ghosh, S. Singh, P. Shinde, Rosy Alphons Sequeira
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引用次数: 2
Specifically designed amine functional group doped sludge biochar for inorganic and organic arsenic removal 专门设计胺官能团掺杂污泥生物炭去除无机和有机砷
IF 4.9 3区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2021-09-07 DOI: 10.1186/s42834-021-00103-w
Chih-Kuei Chen, Nhat-Thien Nguyen, Thuy-Trang Le, Cong-Chinh Duong, T. Duong
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引用次数: 2
Enhanced photocatalytic removal of nitric oxide over Ag-decorated ZnSn(OH)6 microcubes ag修饰ZnSn(OH)6微立方体增强光催化去除一氧化氮
IF 4.9 3区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2021-09-02 DOI: 10.21203/rs.3.rs-829556/v1
Minh-Thuan Pham, N. Van, T. T. Nguyen, H. Tran, Hieu Trung Nguyen, Jheng-Jie Jiang, S. You, Ya-Fen Wang
Presently, most of the population has been facing a string of severe air pollution problems that include the intensive emission of nitric oxide (NO), which requires a practical approach to sustain our living conditions. Herein, Ag nanoparticles (Ag NPs)-decorated ZnSn(OH) 6 microcubes (Ag:cZHS) photocatalysts are synthesized and used for photocatalytic NO removal under solar light activation. The properties of the newly obtained photocatalysts are comprehensively characterized by a series of typical methods. The NO removal performance over the c:ZHS photocatalysts was increased markedly upon being combined with Ag NPs because of the surface plasmon resonance effect. The contribution of electron (e − ), hole (h + ), hydroxyl radical (•OH), and oxygen radicals (•O 2 ) was investigated through trapping tests and electron spin resonance analysis. Also, the by-products and apparent quantum efficiency of the photocatalysts were thoroughly studied.
目前,大多数人都面临着一系列严重的空气污染问题,包括一氧化氮(NO)的大量排放,这需要一种切实可行的方法来维持我们的生活条件。本文合成了Ag纳米粒子(Ag-NPs)修饰的ZnSn(OH)6微管(Ag:cZHS)光催化剂,并将其用于太阳能活化下的光催化NO去除。通过一系列典型的方法对新获得的光催化剂的性能进行了综合表征。由于表面等离子体共振效应,与Ag NPs结合后,c:ZHS光催化剂的NO去除性能显著提高。通过俘获实验和电子自旋共振分析研究了电子(e−)、空穴(h+)、羟基自由基(•OH)和氧自由基(·O2)的贡献。此外,还对光催化剂的副产物和表观量子效率进行了深入的研究。
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引用次数: 3
Photocatalytic removal of toluene with CdIn2S4/CNFs catalyst: effect of ozone addition CdIn2S4/CNFs催化剂光催化去除甲苯:臭氧添加的影响
IF 4.9 3区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2021-08-17 DOI: 10.21203/rs.3.rs-688592/v1
R. Liu, Minh Man Trinh, M. Chang
CdIn 2 S 4 (CIS) has attracted widespread attention due to its structural stability and photoelectric properties, however, it is difficult to recycle when after usage. Carbon nanofibers (CNFs) as a suitable electron acceptor due to its stable physicochemical properties enhanced the mechanical properties and easily to recycle. There are also few reports on applying CIS/CNFs composite as photocatalyst in removing volatile organic compounds (VOCs). In this study, a novel CIS/CNFs composite was synthesized via a simple hydrothermal method. Various characterizations, such as X-ray diffraction, Scanning Electron Microscope, X-ray Photoelectron Spectroscopy and Transmission Electron Microscopy proved the successful synthesis of CIS/CNFs composite and revealed that CNFs grow on the surfaces of CIS connected with three-dimensional (3D) conductive network. Under visible light irradiation, degradation of toluene reached the optimal level of 86% as the CIS doped with 3% CNFs. Furthermore, 95% removal efficiency was achieved as 200 ppm ozone was added into the system and mineralization rate is also improved. The 3D network of CNFs can facilitate the effective separation and transfer of the photogenerated electron-hole pairs, protect CIS core from photo-corrosion and easily be recycled. Ultimately, plausible of ozone-enhanced photocatalytic mechanisms were proposed. Hence, this study presents a new photocatalyst with visible-light driven ozone-enhanced photocatalysis process toward VOCs.
CdIn2S4(CIS)由于其结构稳定性和光电性能而受到广泛关注,但使用后难以回收。碳纳米纤维(CNFs)作为一种合适的电子受体,由于其稳定的物理化学性质,增强了其机械性能,易于回收。关于应用CIS/CNFs复合材料作为光催化剂去除挥发性有机化合物(VOCs)的报道也很少。本研究采用简单的水热法合成了一种新型的CIS/CNFs复合材料。X射线衍射、扫描电子显微镜、X射线光电子能谱和透射电子显微镜等多种表征证明了CIS/CNFs复合材料的成功合成,并揭示了CNFs生长在与三维导电网络连接的CIS表面。在可见光照射下,掺杂3%CNFs的CIS对甲苯的降解率达到86%的最佳水平。此外,当200 在系统中加入ppm臭氧,矿化率也得到提高。CNFs的3D网络可以促进光生电子-空穴对的有效分离和转移,保护CIS核免受光腐蚀,并易于回收。最后,提出了臭氧增强光催化机制的合理性。因此,本研究提出了一种新的光催化剂,它具有可见光驱动的臭氧增强VOCs光催化过程。
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引用次数: 2
Low-temperature conversion of Fe-rich sludge to KFeS2 whisker: a new flocculant synthesis from laboratory scale to pilot scale 富铁污泥低温转化为KFeS2晶须:一种新型絮凝剂的合成
IF 4.9 3区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2021-07-27 DOI: 10.1186/s42834-021-00098-4
Dongxu Liang, Yu Chen, Suiyi Zhu, Y. Gao, Tong Sun, Kyonghun Ri, Xinfeng Xie
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引用次数: 4
Quantitative determination of energy potential of refuse derived fuel from the waste recovered from Indian landfill 从印度垃圾填埋场回收的垃圾中定量测定垃圾燃料的能源潜力
IF 4.9 3区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2021-07-20 DOI: 10.1186/s42834-021-00097-5
V. R. S. Cheela, Michele John, B. Dubey
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引用次数: 6
Analyzing the relationship between water pollution and economic activity for a more effective pollution control policy in Bali Province, Indonesia 分析印尼巴厘省水污染与经济活动的关系,以制定更有效的污染控制政策
IF 4.9 3区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2021-07-12 DOI: 10.21203/rs.3.rs-604424/v1
S. Chapagain, G. Mohan, A. B. Rimba, C. Payus, I. Sudarma, K. Fukushi
An adequate water supply is essential for the continued and sustainable growth of the Balinese economy. In addition to mounting water demand, Bali’s water supply has been constrained by high levels of water pollution. Despite being paid great attention, Bali’s earlier efforts to control water pollution yet to prove effective, mainly owing to their reliance on traditional methods and regulations that focus on water pollution being linked to discrete sets of economic activity (e.g., processing industries, livestock farming, and hotels). However, an economy of a region/country comprises a set of sectoral activities, which are interconnected through supply chains; thus, water pollution could be well explained by examining the entire sectoral economic activities and their environmental performance. Therefore, determining the structural relationships between water pollution and economic activity serves as an important basis for more effective forms of pollution control for the Balinese economy. In this study, accordingly, we employed an environmentally extended input–output model to establish the links between water pollution and the production processes of the entire economy. Using biochemical oxygen demand (BOD) as a proxy for water quality in our analysis, we estimated that 246.9 kt of BOD were produced from Bali’s economic activity in 2007. Further, we identified the chief BOD-emitting sectors and found that intermediate demand and household demand were the major causes of BOD discharge in the economy. We also accounted for the indirect role of each sector in total BOD emissions. Moreover, we categorized the sectors into four groups based on their direct and indirect BOD emission characteristics and offered appropriate policy measures for each group. Managing demand (i.e., lowering household consumption and exports) and shifting input suppliers (i.e., from polluters to non-polluters) are effective measures to control pollution for Categories I and II, respectively; clean production and abatement is advised for Category III; and a hybrid approach (i.e., demand management and abatement technology) is recommended for Category IV.
充足的水供应对巴厘岛经济的持续和可持续增长至关重要。除了不断增长的水需求外,巴厘岛的水供应还受到严重水污染的制约。尽管受到了极大的关注,但巴厘岛早期控制水污染的努力尚未证明是有效的,主要原因是他们依赖于传统的方法和法规,将水污染与离散的经济活动(例如,加工业、畜牧业和酒店)联系起来。然而,一个地区/国家的经济由一系列部门活动组成,这些活动通过供应链相互联系;因此,水污染可以通过审查整个部门经济活动及其环境绩效得到很好的解释。因此,确定水污染与经济活动之间的结构性关系是为巴厘岛经济提供更有效的污染控制形式的重要基础。因此,在本研究中,我们采用环境扩展的投入产出模型来建立水污染与整个经济生产过程之间的联系。在我们的分析中,使用生化需氧量(BOD)作为水质的代表,我们估计2007年巴厘岛的经济活动产生了246.9 kt的BOD。进一步,我们确定了主要的BOD排放部门,发现中间需求和家庭需求是经济中BOD排放的主要原因。我们还考虑了每个部门在总生物需氧量排放中的间接作用。并根据行业直接和间接BOD排放特征将其划分为4类,提出了相应的政策措施。管理需求(即降低家庭消费和出口)和转移投入供应商(即从污染者转向非污染者)分别是控制第一类和第二类污染的有效措施;第三类建议清洁生产和减排;第IV类建议采用混合方法(即需求管理和减排技术)。
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引用次数: 2
Towards biowastes valorization: Peanut shell as resource for quality chemicals and activated biochar production 走向生物废物的价值化:花生壳作为优质化学品和活性生物炭生产的资源
IF 4.9 3区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2021-06-29 DOI: 10.21203/rs.3.rs-632811/v1
C. Fermanelli, Adrián Chiappori, L. Pierella, C. Saux
The purpose of this work was to transform a regional biowaste into value-added chemicals and products through a modest thermo-catalytic pyrolysis process. ZSM-11 (Zeolite Socony Mobile-11) zeolites modified by nickel (Ni) incorporation (1–8 wt%) were synthesized and characterized by means of X-Ray Diffraction, Inductively Coupled Plasma Atomic Emission Spectroscopy, Infrared Fourier Transform Spectroscopy, UV–Vis Diffuse Reflectance Spectra and Temperature Programmed Reduction. Results demonstrated that Ni was mainly incorporated as oxide. These porous materials were evaluated as heterogeneous catalysts to improve biooil composition. In this sense, higher hydrocarbon yields, and quality chemicals were obtained and oxygenates were diminished. The deactivation of the most active material was studied over six cycles of reaction. In order to achieve the circular bioeconomy postulates, the obtained biochar (usually considered a residue) was further transformed through a physicochemical activation. The obtained activated biochars were extensively characterized.
这项工作的目的是通过适度的热催化热解过程将区域生物废物转化为增值化学品和产品。合成了1 ~ 8 wt%镍掺杂改性ZSM-11 (Socony mobile11)分子筛,并用x射线衍射、电感耦合等离子体原子发射光谱、红外傅立叶变换光谱、紫外-可见漫反射光谱和程序升温还原等手段对其进行了表征。结果表明,Ni主要以氧化物形式掺入。这些多孔材料被评价为改善生物油组成的多相催化剂。在这种意义上,获得了更高的烃收率和高质量的化学品,并减少了含氧物。在六个反应循环中研究了最活性物质的失活。为了实现循环生物经济的假设,获得的生物炭(通常被认为是残留物)通过物理化学活化进一步转化。得到的活性炭进行了广泛的表征。
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引用次数: 4
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Sustainable Environment Research
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