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Sensitivity Analysis and Comparative Study for Different Detection Modes of Logging-While-Drilling Ultradeep Azimuthal Electromagnetic Tools 边钻井边测井超深层方位电磁仪器不同探测模式的灵敏度分析与比较研究
IF 3.6 3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2024-03-05 DOI: 10.2118/219479-pa
Yubo Hu, Guozhong Gao

The logging-while-drilling (LWD) ultradeep azimuthal electromagnetic tool plays a pivotal role in real-time drilling optimization operations. Established tool designs include arrays of coaxial and tilted coils that, during drilling operations, can be processed to a multicomponent magnetic induction data. These data can then be combined into different detection modes, which accentuate sensitivity to particular geological features. Leveraging the established coil design and definitions of various detection modes for an electromagnetic look-ahead (EMLA) tool, this study undertakes a comprehensive exploration of the disparities in detection performance and characterization of subsurface parameters. Through sensitivity analysis, the varying degrees of sensitivity exhibited by these detection modes concerning parameters such as subsurface formation resistivity, formation inclination, and electrical anisotropy have been investigated. The ensuing conclusions derived from an in-depth analysis are as follows: Detection Mode I exhibits remarkable prowess in delineating subsurface boundaries. Optimal exploration distances can be achieved through the judicious selection of source-receiver distances and frequencies. Detection Mode II displays heightened sensitivity to wellbore inclination and anisotropy, effectively elucidating subsurface resistivity anisotropy. This sensitivity is particularly pronounced at wellbore inclinations approaching 60°. Detection Mode III, while lacking directional capability, nonetheless furnishes fundamental insights into subsurface resistivity. Detection Mode IV demonstrates exceptional sensitivity to electrical anisotropy, particularly at higher wellbore inclinations, manifesting a conspicuous response to subsurface resistivity anisotropy. In summary, the diverse detection modes within the realm of ultradeep azimuthal electromagnetic technology each offer distinctive attributes, facilitating optimal mode selection to attain superior outcomes as per specific requisites. This research contributes significantly to an enhanced comprehension of the performance and applicability of the ultradeep azimuthal electromagnetic tool in the field of optimal drilling.

边钻井边测井(LWD)超深方位电磁工具在实时钻井优化作业中发挥着举足轻重的作用。成熟的工具设计包括同轴和倾斜线圈阵列,在钻井作业期间,可将这些线圈处理为多分量磁感应数据。这些数据可以组合成不同的探测模式,从而提高对特定地质特征的灵敏度。本研究利用电磁前视(EMLA)工具的既定线圈设计和各种探测模式的定义,对探测性能和地下参数特征的差异进行了全面探索。通过灵敏度分析,研究了这些探测模式对地下地层电阻率、地层倾角和电各向异性等参数的不同灵敏度。深入分析得出的结论如下:探测模式 I 在划定地下边界方面表现突出。通过明智地选择信号源-接收器的距离和频率,可以达到最佳探测距离。探测模式 II 对井筒倾角和各向异性表现出更高的灵敏度,可有效阐明地下电阻率各向异性。这种灵敏度在井筒倾角接近 60° 时尤为明显。探测模式 III 虽然缺乏定向能力,但仍能提供有关地下电阻率的基本信息。探测模式 IV 对电各向异性特别敏感,尤其是在井筒倾角较大的情况下,对地下电阻率各向异性有明显的反应。总之,超深层方位电磁技术领域的各种探测模式各具特色,有利于根据具体要求选择最佳模式,以取得优异的成果。这项研究对提高对超深方位电磁工具在优化钻井领域的性能和适用性的理解大有裨益。
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引用次数: 0
A Grain Size Profile Prediction Method Based on Combined Model of Extreme Gradient Boosting and Artificial Neural Network and Its Application in Sand Control Design 基于极梯度提升和人工神经网络组合模型的粒度轮廓预测方法及其在防沙设计中的应用
IF 3.6 3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2024-03-04 DOI: 10.2118/219484-pa
Shanshan Liu

The grain size distribution along the well depth is of great significance for the prediction of the physical properties and the staged sand control design of the unconsolidated or weakly consolidated sandstone reservoir. In this paper, a new method for predicting the formation median grain size profile based on the combination model of extreme gradient boosting (XGBoost) and artificial neural network (ANN) is proposed. The machine learning algorithm and weighted combination model are applied to the prediction and analysis of reservoir grain size. The prediction model is improved from two aspects: First, the feature engineering of the XGBoost-ANN model is constructed by using the data of multiple sampling points on the logging curve. Second, the prediction accuracy is improved by increasing the dimension of the prediction model, that is, the XGBoost and ANN single-prediction models are weighted by the error reciprocal method and a combined prediction model containing multidimensional information is established. The research results show that compared with the single-point mapping model, the prediction accuracy of the multipoint mapping model considering the vertical geological continuity of the reservoir is higher than that of the single-point prediction and the coefficient of determination in the testing set can be improved up to 14.5%. The influence of different weighting methods on prediction performance is studied, and the prediction performance of original XGBoost, ANN, and XGBoost-ANN combined models is compared. The combined prediction model has a higher prediction accuracy than the single XGBoost and ANN models with the same number of sampling points and the coefficient of determination can be improved by up to 16.5%. The prediction accuracy and generalization ability of the XGBoost-ANN combined model are evaluated comprehensively. The combined model is used to design layered sand control of a well in an adjacent block, and good results have been achieved in production practice. This study provides a new method with high accuracy and efficiency for the prediction of unconsolidated sand median grain size profile.

沿井深的粒度分布对于预测未固结或弱固结砂岩储层的物性和进行阶段性防砂设计具有重要意义。本文提出了一种基于极梯度提升(XGBoost)和人工神经网络(ANN)组合模型的预测地层中值粒度剖面的新方法。将机器学习算法和加权组合模型应用于储层粒度的预测和分析。该预测模型从两个方面进行了改进:首先,利用测井曲线上多个采样点的数据构建了 XGBoost-ANN 模型的特征工程。其次,通过增加预测模型的维度来提高预测精度,即通过误差倒数法对 XGBoost 和 ANN 单一预测模型进行加权,建立包含多维信息的组合预测模型。研究结果表明,与单点测绘模型相比,考虑储层垂直地质连续性的多点测绘模型的预测精度高于单点预测,测试集中的判定系数最高可提高 14.5%。研究了不同加权方法对预测性能的影响,并比较了原始 XGBoost、ANN 和 XGBoost-ANN 组合模型的预测性能。在采样点数相同的情况下,组合预测模型的预测精度高于单一的 XGBoost 模型和 ANN 模型,其判定系数最高可提高 16.5%。综合评价了 XGBoost-ANN 组合模型的预测精度和泛化能力。将该组合模型用于相邻区块的油井分层防砂设计,在生产实践中取得了良好的效果。该研究为预测未固结砂中值粒度剖面提供了一种高精度、高效率的新方法。
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引用次数: 0
Dynamic Scaling Prediction Model and Application in Near-Wellbore Formation of Ultradeep Natural Gas Reservoirs 动态缩放预测模型及在超深层天然气储层近井筒形成中的应用
IF 3.6 3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2024-02-28 DOI: 10.2118/219471-pa
Lihu Cao, Hua Yuan, Zhaocai Pan, Zhibin Liu, Bao Zhang, Tao Sun, Jianyi Liu, Hongjun Wu

To address the significant scaling challenges within the near-wellbore formation of ultradeep natural gas reservoirs characterized by high temperature and high salinity, we developed a dynamic scaling prediction model. This model is specifically designed for the prediction of scaling in gas-water two-phase seepage within fractured-matrix dual-porosity reservoirs. It accounts for the concentration effects resulting from the evaporation of water on formation water ions. Our scaling model is discretely solved using the finite volume method. We also conducted on-site dynamic scaling simulations for gas wells, allowing us to precisely predict the distribution of ion concentrations in the reservoir, as well as changes in porosity and permeability properties, and the scaling law dynamics. The simulation results reveal a significant drop in formation pressure, decreasing from 105 MPa to 76.7 MPa after 7.5 years of production. The near-wellbore formation is particularly affected by severe scaling, mainly attributed to the radial pressure drop funneling effect, leading to a reduction in scaling ion concentrations in the vicinity of the wellbore. Calcium carbonate is identified as the predominant scaling component within the reservoir, while calcium sulfate serves as a secondary contributor, together accounting for roughly 85.2% of the total scaling deposits. In contrast, the scaling impact on the matrix system within the reservoir remains minimal. However, the central fracture system exhibits notable damage, with reductions of 71.2% in porosity and 59.8% in permeability. The fracture system within a 5-m radius around the wellbore is recognized as the primary area of scaling damage in the reservoir. The use of the simulation approach proposed in this study can offer valuable support for analyzing the dynamic scaling patterns in gasfield reservoirs and optimizing scaling mitigation processes.

超深层天然气储层具有高温和高盐度的特点,为解决其近井筒地层内的重大缩放难题,我们开发了一种动态缩放预测模型。该模型专门用于预测裂缝基质双孔隙储层中气水两相渗流的缩放情况。它考虑了水蒸发对地层水离子产生的浓度效应。我们的缩放模型采用有限体积法进行离散求解。我们还对气井进行了现场动态缩放模拟,从而可以精确预测储层中离子浓度的分布、孔隙度和渗透率特性的变化以及缩放规律的动态变化。模拟结果显示,地层压力显著下降,在生产 7.5 年后从 105 兆帕下降到 76.7 兆帕。井筒附近地层尤其受到严重缩放的影响,这主要归因于径向压降漏斗效应,导致井筒附近缩放离子浓度降低。碳酸钙被确定为储层中最主要的结垢成分,而硫酸钙则是次要的结垢成分,二者合计约占结垢沉积总量的 85.2%。相比之下,结垢对储层内基质系统的影响仍然很小。然而,中央裂缝系统受到了明显的破坏,孔隙度降低了 71.2%,渗透率降低了 59.8%。井筒周围 5 米半径范围内的裂缝系统被认为是储层中主要的缩放破坏区域。使用本研究提出的模拟方法,可以为分析气田储层的动态缩放模式和优化缩放减缓过程提供有价值的支持。
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引用次数: 0
Virtual Meter with Flow Pattern Recognition Using Deep Learning Neural Networks: Experiments and Analyses 利用深度学习神经网络进行流量模式识别的虚拟仪表:实验与分析
IF 3.6 3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2024-02-15 DOI: 10.2118/219465-pa
Renata Mercante, Theodoro Antoun Netto

Operators often require real-time measurement of fluid flow rates in each well of their fields, which allows better control of production. However, petroleum is a complex multiphase mixture composed of water, gas, oil, and other sediments, which makes its flow challenging to measure and monitor. A critical issue is how the liquid component interacts with the gaseous phase, also known as the flow pattern. For example, sometimes liquids can accumulate in the lower part of the pipeline and block the flow completely, causing a gas pressure buildup that can lead to unstable flow regimes or even accidents (blowouts). On the other hand, some flow patterns can also facilitate sediment deposition, leading to obstructions and reduced production. Thus, this work aims to show that deep neural networks can act as a virtual flowmeter (VFM) using only a history of production, pressure, and temperature telemetry, accurately estimating the flow of all fluids in real time. In addition, these networks can also use the same input data to detect and recognize flow patterns that can harm the regular operation of the wells, allowing greater control without requiring additional costs or the installation of any new equipment. To demonstrate the feasibility of this approach and provide data to train the neural networks, a water-air loop was constructed to resemble an oil well. This setup featured inclined and vertical transparent pipes to generate and observe different flow patterns and sensors to record temperature, pressure, and volumetric flow rates. The results show that deep neural networks achieved up to 98% accuracy in flow pattern prediction and 1% mean absolute prediction error (MAPE) in flow rates, highlighting the capability of this technique to provide crucial insights into the behavior of multiphase flow in risers and pipelines.

运营商通常需要实时测量油田每个油井的流体流速,以便更好地控制生产。然而,石油是一种复杂的多相混合物,由水、气体、石油和其他沉积物组成,因此测量和监控其流动具有挑战性。一个关键问题是液相成分如何与气相相互作用,也就是所谓的流动模式。例如,有时液体会积聚在管道下部,完全阻塞流动,造成气体压力积聚,从而导致不稳定的流动状态,甚至发生事故(井喷)。另一方面,某些流动模式也会促进沉积物沉积,导致阻塞和减产。因此,这项工作旨在证明,深度神经网络可以充当虚拟流量计(VFM),只需使用历史产量、压力和温度遥测数据,就能实时准确地估计所有流体的流量。此外,这些网络还可以使用相同的输入数据来检测和识别可能损害油井正常运行的流量模式,从而在不增加成本或安装任何新设备的情况下加强控制。为了证明这种方法的可行性,并提供训练神经网络的数据,我们建造了一个类似油井的水气环路。该装置包括倾斜和垂直的透明管道,用于产生和观察不同的流动模式,以及用于记录温度、压力和容积流量的传感器。结果表明,深度神经网络在流动模式预测方面的准确率高达 98%,在流速方面的平均绝对预测误差 (MAPE) 仅为 1%,这凸显了该技术为立管和管道中的多相流行为提供重要见解的能力。
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引用次数: 0
Injection Temperature Impacts on Reservoir Response during CO2 Storage 二氧化碳封存过程中注入温度对储层响应的影响
IF 3.6 3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2024-02-15 DOI: 10.2118/219461-pa
Mahendra Samaroo, Mark McClure, Garrett Fowler, Rick Chalaturnyk, Maurice B. Dusseault, Christopher Hawkes

Sustained injection of industrial-scale volumes of cold CO2 into warmer subsurface rock will result in extensive cooling which can alter rock mass mechanical behavior and fluid migration characteristics. Advanced simulation tools are available to assess and characterize such phenomena; however, the effective use of these tools requires appropriate injection temperatures and rock thermophysical parameters (in addition to geomechanical and hydraulic properties). The primary objective of this study was to demonstrate the sensitivity of injection-induced tensile fracturing and fault reactivation to injection temperature and reservoir thermophysical properties during CO2 injection operations. This was achieved by (1) compiling and reviewing thermophysical parameter data available for formations in the province of Alberta, Canada, and CO2 injection temperature records for CO2 injection projects in western Canada and (2) using a 3D, physics-based, fully integrated hydraulic fracturing and reservoir simulation numerical model to examine the geomechanical response of several potential CO2 reservoirs in the Alberta Basin as a function of injection temperature, thermal conductivity (TC), and coefficient of linear thermal expansion (CLTE) values. The simulation results indicate that reducing the fluid injection temperature from 15°C (assumed in previous work) to 2°C (conservative value selected based on temperature data reviewed in this work) could trigger extensive vertical (20–130 m high, 100–600 m long) tensile fractures with rapid fracture initiation and full vertical growth within short periods (weeks to months) and continued horizontal length increase. When low values for thermophysical properties are used, the results show that thermally-induced tensile fracturing is unlikely, whereas the use of high values results in extensive tensile fracturing in all simulations. A similar conclusion was reached for the thermally-induced reactivation (unclamping) of proximal, critically-stressed faults. Notably, slip is predicted for all simulations where high thermophysical property values are used. This confirms that accurate determination of minimum fluid injection temperature and thermophysical parameters is important for containment risk assessment for commercial-scale CO2 storage projects. Another significant outcome of this work is the observation that most thermophysical parameters in the available data were measured using experimental conditions and/or temperature paths that are not representative of CO2 injection projects. As such, the development and validation of best practice approaches for accurate assessment of these parameters seem necessary.

将工业规模的低温二氧化碳持续注入温度较高的地下岩石会导致大面积冷却,从而改变岩体的机械行为和流体迁移特性。先进的模拟工具可用于评估和描述此类现象;然而,要有效使用这些工具,需要适当的注入温度和岩石热物理参数(以及地质力学和水力特性)。本研究的主要目的是证明在二氧化碳注入过程中,注入诱导的拉伸压裂和断层再活化对注入温度和储层热物理特性的敏感性。具体方法是:(1) 汇编和审查加拿大阿尔伯塔省地层的热物理参数数据,以及加拿大西部二氧化碳注入项目的二氧化碳注入温度记录;(2) 使用基于物理的三维全集成水力压裂和储层模拟数值模型,研究阿尔伯塔盆地几个潜在二氧化碳储层的地质力学响应与注入温度、热导率 (TC) 和线性热膨胀系数 (CLTE) 值的函数关系。模拟结果表明,将流体注入温度从 15°C(以前工作中的假设)降低到 2°C(根据本工作中审查的温度数据选择的保守值)可引发大范围垂直(20-130 米高,100-600 米长)拉伸裂缝,裂缝在短期内(几周到几个月)迅速形成并完全垂直生长,水平长度持续增加。热物理性质数值较低时,结果表明热引起的拉伸断裂不太可能发生,而数值较高时,在所有模拟中都会出现大面积拉伸断裂。对于近端严重受压断层的热诱导重新激活(解闭)也得出了类似的结论。值得注意的是,在使用高热物理特性值的所有模拟中都预测到了滑移。这证明,准确确定最低流体注入温度和热物理参数对于商业规模二氧化碳封存项目的封存风险评估非常重要。这项工作的另一个重要成果是发现,现有数据中的大多数热物理参数都是在不代表二氧化碳注入项目的实验条件和/或温度路径下测量的。因此,似乎有必要开发和验证准确评估这些参数的最佳实践方法。
{"title":"Injection Temperature Impacts on Reservoir Response during CO2 Storage","authors":"Mahendra Samaroo, Mark McClure, Garrett Fowler, Rick Chalaturnyk, Maurice B. Dusseault, Christopher Hawkes","doi":"10.2118/219461-pa","DOIUrl":"https://doi.org/10.2118/219461-pa","url":null,"abstract":"<p>Sustained injection of industrial-scale volumes of cold CO<sub>2</sub> into warmer subsurface rock will result in extensive cooling which can alter rock mass mechanical behavior and fluid migration characteristics. Advanced simulation tools are available to assess and characterize such phenomena; however, the effective use of these tools requires appropriate injection temperatures and rock thermophysical parameters (in addition to geomechanical and hydraulic properties). The primary objective of this study was to demonstrate the sensitivity of injection-induced tensile fracturing and fault reactivation to injection temperature and reservoir thermophysical properties during CO<sub>2</sub> injection operations. This was achieved by (1) compiling and reviewing thermophysical parameter data available for formations in the province of Alberta, Canada, and CO<sub>2</sub> injection temperature records for CO<sub>2</sub> injection projects in western Canada and (2) using a 3D, physics-based, fully integrated hydraulic fracturing and reservoir simulation numerical model to examine the geomechanical response of several potential CO<sub>2</sub> reservoirs in the Alberta Basin as a function of injection temperature, thermal conductivity (TC), and coefficient of linear thermal expansion (CLTE) values. The simulation results indicate that reducing the fluid injection temperature from 15°C (assumed in previous work) to 2°C (conservative value selected based on temperature data reviewed in this work) could trigger extensive vertical (20–130 m high, 100–600 m long) tensile fractures with rapid fracture initiation and full vertical growth within short periods (weeks to months) and continued horizontal length increase. When low values for thermophysical properties are used, the results show that thermally-induced tensile fracturing is unlikely, whereas the use of high values results in extensive tensile fracturing in all simulations. A similar conclusion was reached for the thermally-induced reactivation (unclamping) of proximal, critically-stressed faults. Notably, slip is predicted for all simulations where high thermophysical property values are used. This confirms that accurate determination of minimum fluid injection temperature and thermophysical parameters is important for containment risk assessment for commercial-scale CO<sub>2</sub> storage projects. Another significant outcome of this work is the observation that most thermophysical parameters in the available data were measured using experimental conditions and/or temperature paths that are not representative of CO<sub>2</sub> injection projects. As such, the development and validation of best practice approaches for accurate assessment of these parameters seem necessary.</p>","PeriodicalId":22252,"journal":{"name":"SPE Journal","volume":"55 1","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141062705","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adsorption Characteristics of CO2/CH4/H2S Mixtures in Calcite Nanopores with the Implications for CO2 Sequestration 方解石纳米孔中 CO2/CH4/H2S 混合物的吸附特性及其对二氧化碳封存的影响
IF 3.6 3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2024-02-15 DOI: 10.2118/219463-pa
Zhenhua Rui, Cheng Qian, Yueliang Liu, Yang Zhao, Huazhou Andy Li, Andrey Afanasyev, Farshid Torabi
<p>Injecting CO<sub>2</sub> into reservoirs for storage and enhanced oil recovery (EOR) is a practical and cost-effective strategy for reducing carbon emissions. Commonly, CO<sub>2</sub>-rich industrial waste gas is used as the CO<sub>2</sub> source, whereas contaminants such as H<sub>2</sub>S may severely impact carbon storage and EOR via competitive adsorption. Hence, the adsorption behavior of CH<sub>4</sub>, CO<sub>2</sub>, and H<sub>2</sub>S in calcite (CaCO<sub>3</sub>) micropores and the impact of H<sub>2</sub>S on CO<sub>2</sub> sequestration and methane recovery are specifically investigated. The Grand Canonical Monte Carlo (GCMC) simulations were applied to study the adsorption characteristics of pure CO<sub>2</sub>, CH<sub>4</sub>, and H<sub>2</sub>S, and their multicomponent mixtures were also investigated in CaCO<sub>3</sub> nanopores to reveal the impact of H<sub>2</sub>S on CO<sub>2</sub> storage. The effects of pressure (0–20 MPa), temperature (293.15–383.15 K), pore width, buried depth, and gas mole fraction on the adsorption behaviors are simulated. Molecular dynamics (MD) simulations were performed to explore the diffusion characteristics of the three gases and their mixes. The amount of adsorbed CH<sub>4</sub>, CO<sub>2</sub>, and H<sub>2</sub>S enhances with rising pressure and declines with rising temperature. The order of adsorption quantity in CaCO<sub>3</sub> nanopores is H<sub>2</sub>S > CO<sub>2</sub> > CH<sub>4</sub> based on the adsorption isotherm. At 10 MPa and 323.15 K, the interaction energies of CaCO<sub>3</sub> with CO<sub>2</sub>, H<sub>2</sub>S, and CH<sub>4</sub> are −2166.40 kcal/mol, −2076.93 kcal/mol, and −174.57 kcal/mol, respectively, which implies that the order of adsorption strength between the three gases and CaCO<sub>3</sub> is CO<sub>2</sub> > H<sub>2</sub>S > CH<sub>4</sub>. The CH<sub>4</sub>-CaCO<sub>3</sub> and H<sub>2</sub>S-CaCO<sub>3</sub> interaction energies are determined by van der Waals energy, whereas electrostatic energy predominates in the CO<sub>2</sub>-CaCO<sub>3</sub> system. The adsorption loading of CH<sub>4</sub> and CO<sub>2</sub> are lowered by approximately 59.47% and 24.82% when the mole fraction of H<sub>2</sub>S is 20% at 323.15 K, reflecting the weakening of CH<sub>4</sub> and CO<sub>2</sub> adsorption by H<sub>2</sub>S due to competitive adsorption. The diffusivities of three pure gases in CaCO<sub>3</sub> nanopore are listed in the following order: CH<sub>4</sub> > H<sub>2</sub>S ≈ CO<sub>2</sub>. The presence of H<sub>2</sub>S in the ternary mixtures will limit diffusion and outflow of the system and each single gas, with CH<sub>4</sub> being the gas most affected by H<sub>2</sub>S. Concerning carbon storage in CaCO<sub>3</sub> nanopores, the CO<sub>2</sub>/CH<sub>4</sub> binary mixture is suitable for burial in shallower formations (around 1000 m) to maximize the storage amount, while the CO<sub>2</sub>/CH<sub>4</sub>/H<sub>2</sub>S ternary mixture sho
向储油层注入二氧化碳进行封存和提高石油采收率(EOR)是一种实用且具有成本效益的减少碳排放的策略。通常,富含二氧化碳的工业废气被用作二氧化碳源,而 H2S 等污染物可能会通过竞争性吸附严重影响碳储存和 EOR。因此,本文专门研究了 CH4、CO2 和 H2S 在方解石(CaCO3)微孔中的吸附行为以及 H2S 对 CO2 封存和甲烷回收的影响。应用大卡农蒙特卡罗(GCMC)模拟研究了纯 CO2、CH4 和 H2S 的吸附特性,还研究了它们的多组分混合物在 CaCO3 纳米孔中的吸附特性,以揭示 H2S 对 CO2 封存的影响。模拟了压力(0-20 兆帕)、温度(293.15-383.15 K)、孔隙宽度、埋藏深度和气体摩尔分数对吸附行为的影响。分子动力学(MD)模拟探讨了三种气体及其混合气体的扩散特性。CH4、CO2 和 H2S 的吸附量随压力升高而增加,随温度升高而减少。根据吸附等温线,CaCO3 纳米孔中的吸附量顺序为 H2S > CO2 > CH4。在 10 MPa 和 323.15 K 条件下,CaCO3 与 CO2、H2S 和 CH4 的相互作用能分别为 -2166.40 kcal/mol、-2076.93 kcal/mol 和 -174.57 kcal/mol,这意味着三种气体与 CaCO3 的吸附强度顺序为 CO2 > H2S > CH4。CH4-CaCO3 和 H2S-CaCO3 的相互作用能由范德华能决定,而 CO2-CaCO3 系统中则以静电能为主。在 323.15 K 下,当 H2S 的摩尔分数为 20% 时,CH4 和 CO2 的吸附负荷分别降低了约 59.47% 和 24.82%,这反映了 H2S 由于竞争吸附而削弱了对 CH4 和 CO2 的吸附。三种纯气体在 CaCO3 纳米孔中的扩散率按以下顺序排列:CH4 > H2S ≈ CO2。三元混合物中 H2S 的存在将限制系统和每种单一气体的扩散和流出,而 CH4 是受 H2S 影响最大的气体。关于 CaCO3 纳米孔中的碳封存,CO2/CH4 二元混合物适合埋藏在较浅的地层中(1000 米左右),以获得最大的封存量,而 CO2/CH4/H2S 三元混合物则应尽可能深埋,以减少 H2S 的不利影响。该研究阐明了 H2S 对 CaCO3 纳米孔隙中 CO2 封存和 CH4 回收的影响,为碳酸盐岩层中的 CO2 封存和 EOR 项目提供了理论帮助。
{"title":"Adsorption Characteristics of CO2/CH4/H2S Mixtures in Calcite Nanopores with the Implications for CO2 Sequestration","authors":"Zhenhua Rui, Cheng Qian, Yueliang Liu, Yang Zhao, Huazhou Andy Li, Andrey Afanasyev, Farshid Torabi","doi":"10.2118/219463-pa","DOIUrl":"https://doi.org/10.2118/219463-pa","url":null,"abstract":"&lt;p&gt;Injecting CO&lt;sub&gt;2&lt;/sub&gt; into reservoirs for storage and enhanced oil recovery (EOR) is a practical and cost-effective strategy for reducing carbon emissions. Commonly, CO&lt;sub&gt;2&lt;/sub&gt;-rich industrial waste gas is used as the CO&lt;sub&gt;2&lt;/sub&gt; source, whereas contaminants such as H&lt;sub&gt;2&lt;/sub&gt;S may severely impact carbon storage and EOR via competitive adsorption. Hence, the adsorption behavior of CH&lt;sub&gt;4&lt;/sub&gt;, CO&lt;sub&gt;2&lt;/sub&gt;, and H&lt;sub&gt;2&lt;/sub&gt;S in calcite (CaCO&lt;sub&gt;3&lt;/sub&gt;) micropores and the impact of H&lt;sub&gt;2&lt;/sub&gt;S on CO&lt;sub&gt;2&lt;/sub&gt; sequestration and methane recovery are specifically investigated. The Grand Canonical Monte Carlo (GCMC) simulations were applied to study the adsorption characteristics of pure CO&lt;sub&gt;2&lt;/sub&gt;, CH&lt;sub&gt;4&lt;/sub&gt;, and H&lt;sub&gt;2&lt;/sub&gt;S, and their multicomponent mixtures were also investigated in CaCO&lt;sub&gt;3&lt;/sub&gt; nanopores to reveal the impact of H&lt;sub&gt;2&lt;/sub&gt;S on CO&lt;sub&gt;2&lt;/sub&gt; storage. The effects of pressure (0–20 MPa), temperature (293.15–383.15 K), pore width, buried depth, and gas mole fraction on the adsorption behaviors are simulated. Molecular dynamics (MD) simulations were performed to explore the diffusion characteristics of the three gases and their mixes. The amount of adsorbed CH&lt;sub&gt;4&lt;/sub&gt;, CO&lt;sub&gt;2&lt;/sub&gt;, and H&lt;sub&gt;2&lt;/sub&gt;S enhances with rising pressure and declines with rising temperature. The order of adsorption quantity in CaCO&lt;sub&gt;3&lt;/sub&gt; nanopores is H&lt;sub&gt;2&lt;/sub&gt;S &gt; CO&lt;sub&gt;2&lt;/sub&gt; &gt; CH&lt;sub&gt;4&lt;/sub&gt; based on the adsorption isotherm. At 10 MPa and 323.15 K, the interaction energies of CaCO&lt;sub&gt;3&lt;/sub&gt; with CO&lt;sub&gt;2&lt;/sub&gt;, H&lt;sub&gt;2&lt;/sub&gt;S, and CH&lt;sub&gt;4&lt;/sub&gt; are −2166.40 kcal/mol, −2076.93 kcal/mol, and −174.57 kcal/mol, respectively, which implies that the order of adsorption strength between the three gases and CaCO&lt;sub&gt;3&lt;/sub&gt; is CO&lt;sub&gt;2&lt;/sub&gt; &gt; H&lt;sub&gt;2&lt;/sub&gt;S &gt; CH&lt;sub&gt;4&lt;/sub&gt;. The CH&lt;sub&gt;4&lt;/sub&gt;-CaCO&lt;sub&gt;3&lt;/sub&gt; and H&lt;sub&gt;2&lt;/sub&gt;S-CaCO&lt;sub&gt;3&lt;/sub&gt; interaction energies are determined by van der Waals energy, whereas electrostatic energy predominates in the CO&lt;sub&gt;2&lt;/sub&gt;-CaCO&lt;sub&gt;3&lt;/sub&gt; system. The adsorption loading of CH&lt;sub&gt;4&lt;/sub&gt; and CO&lt;sub&gt;2&lt;/sub&gt; are lowered by approximately 59.47% and 24.82% when the mole fraction of H&lt;sub&gt;2&lt;/sub&gt;S is 20% at 323.15 K, reflecting the weakening of CH&lt;sub&gt;4&lt;/sub&gt; and CO&lt;sub&gt;2&lt;/sub&gt; adsorption by H&lt;sub&gt;2&lt;/sub&gt;S due to competitive adsorption. The diffusivities of three pure gases in CaCO&lt;sub&gt;3&lt;/sub&gt; nanopore are listed in the following order: CH&lt;sub&gt;4&lt;/sub&gt; &gt; H&lt;sub&gt;2&lt;/sub&gt;S ≈ CO&lt;sub&gt;2&lt;/sub&gt;. The presence of H&lt;sub&gt;2&lt;/sub&gt;S in the ternary mixtures will limit diffusion and outflow of the system and each single gas, with CH&lt;sub&gt;4&lt;/sub&gt; being the gas most affected by H&lt;sub&gt;2&lt;/sub&gt;S. Concerning carbon storage in CaCO&lt;sub&gt;3&lt;/sub&gt; nanopores, the CO&lt;sub&gt;2&lt;/sub&gt;/CH&lt;sub&gt;4&lt;/sub&gt; binary mixture is suitable for burial in shallower formations (around 1000 m) to maximize the storage amount, while the CO&lt;sub&gt;2&lt;/sub&gt;/CH&lt;sub&gt;4&lt;/sub&gt;/H&lt;sub&gt;2&lt;/sub&gt;S ternary mixture sho","PeriodicalId":22252,"journal":{"name":"SPE Journal","volume":"68 1","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141062739","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A New Mechanistic Model for Wettability-Altering Surfactant Floods in Carbonates 碳酸盐中润湿性改变表面活性剂泛滥的新机制模型
IF 3.6 3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2024-02-14 DOI: 10.2118/219468-pa
Yue Shi, Kishore K. Mohanty, Juliana Y. Leung, Qing You

Surfactants and low-salinity brines have been shown to be effective for enhanced oil recovery in carbonate rocks through wettability alteration (WA). Oil wettability of carbonates is ascribed to the adsorbed organic acid components in oil. The removal of the adsorbed acids leads to WA. Previous experiments with wettability-altering surfactants have shown the following: WA is a slow process; acid removal is irreversible in most cases; surfactants can access the rock surface in water-wet regions and at three-phase contact lines rather than the entire rock surface; surfactant molecules become inactive after interactions with acids. Existing models/simulators do not incorporate the aforementioned observations. In this work, a multiphase, multicomponent, finite-difference reservoir simulator incorporating a new mechanistic model for WA was developed. The model captures the key physicochemical reactions between adsorbed acids and surfactant molecules and honors the four experimental evidences. The model was first tested at the core scale. The simulation results demonstrated that the model can accurately predict waterflood performance in rocks with various wettability. It can also effectively account for the influence of injection rates in surfactant flood experiments. The effectiveness of the surfactant, controlled by an interaction constant in the model, was found to be a dominant factor. The model was also tested for field-scale pilot tests. The results revealed that total quantity of chemicals injected and the injection rate have a more pronounced effect on oil recovery compared to the timing of surfactant treatment and the concentration of surfactant slug.

事实证明,表面活性剂和低盐度盐水可通过润湿性改变(WA)有效提高碳酸盐岩的石油采收率。碳酸盐岩的石油润湿性归因于石油中吸附的有机酸成分。吸附酸的去除会导致润湿性改变。之前使用润湿性改变表面活性剂进行的实验表明了以下几点:WA 是一个缓慢的过程;酸的去除在大多数情况下是不可逆的;表面活性剂可以进入水湿区域和三相接触线处的岩石表面,而不是整个岩石表面;表面活性剂分子在与酸相互作用后会失去活性。现有的模型/模拟器没有将上述观察结果纳入其中。在这项工作中,开发了一种多相、多组分、有限差分储层模拟器,其中包含一个新的 WA 机理模型。该模型捕捉到了吸附酸和表面活性剂分子之间的关键物理化学反应,并尊重了四个实验证据。该模型首先在核心尺度上进行了测试。模拟结果表明,该模型可以准确预测不同润湿性岩石的注水性能。该模型还能有效地解释表面活性剂注水实验中注入率的影响。研究发现,表面活性剂的效果是一个主导因素,由模型中的相互作用常数控制。还对该模型进行了实地规模的试验测试。结果显示,与表面活性剂处理时间和表面活性剂蛞蝓浓度相比,化学品注入总量和注入率对采油率的影响更为明显。
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引用次数: 0
Performance Analysis of the Vortex Cuttings Cleaner: Turbine Hydraulic Drive and Cuttings Transport in Wellbore Annulus 涡流式岩屑清理机的性能分析:涡轮水力驱动与井筒环形空间的岩屑输送
IF 3.6 3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2024-02-13 DOI: 10.2118/219462-pa
Yiqun Zhang, Zhaowen Hu, Qi Wang, Haochen Huang, Ya Liu, Wei Wang

In the process of directional and horizontal well drilling, cuttings tend to settle and form a bed at the low side of the annulus due to gravity, which decreases the drilling rate and even causes accidents in severe cases. This paper analyzes the performance of a new tool, the vortex cuttings cleaner, which can be effective without rotation of the drillpipe. Based on the computational fluid dynamics (CFD) approach, together with the discrete phase, Euler, and dynamic mesh models, the vortex cuttings cleaner is investigated with respect to the turbine torque, turbine velocity, pressure drop, and cuttings transport in the annulus. The working mechanism of the vortex cuttings cleaner is clarified. Finally, field tests are conducted on the tool to evaluate its application in terms of service life, wellbore friction, and rate of penetration (ROP). The results show that the turbine can rotate continuously under hydraulic drive. The turbine torque/velocity and the tool’s pressure drop increase with increasing displacement. The cuttings transport in the annulus is jointly affected by factors such as turbine velocity, fluid velocity, and particle size. A too low or high turbine velocity is unfavorable for cuttings transport. Through the analysis of the number of particles and particle concentration, the optimal velocity is determined to be 125 rev/min. The swirling flow intensity in the annulus flow field increases with the increase in turbine velocity. Field applications suggest a service life longer than 200 hours, a notable decrease in wellbore friction, and an average increase in ROP by more than 20%. This study provides a theoretical basis for the research on wellbore cleaning tools.

在定向井和水平井钻井过程中,由于重力作用,切屑容易沉淀并在环空低侧形成床层,从而降低钻井速度,严重时甚至会造成事故。本文分析了一种新工具--涡流式钻屑清理器的性能,该工具无需旋转钻杆即可有效清理钻屑。基于计算流体动力学(CFD)方法,结合离散相位模型、欧拉模型和动态网格模型,研究了涡流式掘进机的涡轮扭矩、涡轮速度、压降和掘进物在环形空间中的输送情况。阐明了涡流式掘进机的工作机理。最后,对该工具进行了现场测试,以评估其在使用寿命、井筒摩擦和穿透率(ROP)方面的应用。结果表明,涡轮可在液压驱动下连续旋转。涡轮扭矩/速度和工具压降随着排量的增加而增加。环空中的切屑输送受到涡轮速度、流体速度和颗粒大小等因素的共同影响。涡轮速度过低或过高都不利于切屑的输送。通过对颗粒数量和颗粒浓度的分析,确定最佳速度为 125 转/分钟。环形流场中的漩涡流强度随着涡轮速度的增加而增加。现场应用表明,涡轮的使用寿命超过 200 小时,井筒摩擦显著降低,ROP 平均提高 20% 以上。这项研究为井筒清洁工具的研究提供了理论依据。
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引用次数: 0
Plugging Mechanism of Rigid and Flexible Composite Plugging Materials for Millimeter-Scale Fractures 毫米级裂缝刚性和柔性复合堵漏材料的堵漏机理
IF 3.6 3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2024-01-03 DOI: 10.2118/218401-pa
Yingrui Bai, Yuan Liu, Jinsheng Sun, Kaihe Lv

Drilling-fluid loss caused by millimeter-scale fractures is a notoriously difficult problem in drilling engineering, and both rigid and flexible plugging materials are commonly used to address this issue. This investigation aims to comprehensively explore the plugging efficacy and underlying mechanisms of rigid, flexible, and fiber materials when used individually and in combination. The findings of our investigations into macroscopic high-temperature and high-pressure plugging experiments divulge a revelation: Under conditions of enhanced concentration, rigid particles evince the remarkable ability to engender a pressure-enduring plugging stratum; in contrast, independent attempts by flexible and fiber materials to yield a stable plugging layer are challenging. In this context, the optimal ratio of rigid, flexible, and fiber materials has been determined through composite plugging experiments. Calcite particles with a concentration of 5–8%, rubber particles with a concentration of 2–3%, and polypropylene fibers with a concentration of 1–2% were compounded for fracture plugging with widths of 1 mm, 3 mm, and 5 mm, respectively. The resulting plugging strengths were 10 MPa, 9 MPa, and 7 MPa. The microscopic visualized plugging experiments showed that the rigid particles form an I-shaped plugging layer with high strength but are difficult to transport to the deep part of the fracture. Flexible particles can be transported into the deep part of the fracture to form a plugging layer, but the “V”-shaped formation is unstable and has low strength. Based on the experimental results of “rigid-flexible synergistic” composite bridging-plugging formulations for different scales of fractured strata, the preferred template for bridging-plugging material formulations in the field is investigated to provide a reference for the bridging-plugging material formulations in the field.

毫米级裂缝造成的钻井液流失是钻井工程中一个众所周知的难题,通常使用刚性和柔性堵漏材料来解决这一问题。本研究旨在全面探索刚性材料、柔性材料和纤维材料单独使用或组合使用时的堵漏效果和内在机理。我们在宏观高温高压堵塞实验中的研究结果给我们带来了启示:在浓度较高的条件下,刚性颗粒具有形成耐压堵塞层的卓越能力;与此相反,柔性材料和纤维材料独立尝试形成稳定的堵塞层却面临挑战。在这种情况下,通过复合堵塞实验确定了刚性、柔性和纤维材料的最佳比例。将浓度为 5%-8%的方解石颗粒、浓度为 2%-3%的橡胶颗粒和浓度为 1%-2%的聚丙烯纤维进行复合,用于断裂堵塞,宽度分别为 1 毫米、3 毫米和 5 毫米。结果堵塞强度分别为 10 兆帕、9 兆帕和 7 兆帕。显微可视化堵塞实验表明,刚性颗粒形成的 I 形堵塞层强度高,但难以输送到断裂深部。柔性颗粒可以输送到断裂深部形成堵塞层,但形成的 "V "形堵塞层不稳定,强度低。根据 "刚柔协同 "复合桥塞配方对不同尺度断裂地层的实验结果,研究了现场桥塞材料配方的优选模板,为现场桥塞材料配方提供参考。
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引用次数: 0
An Optimization Analysis of the Melt-Cutting Diversion Jetting Mechanism for Downhole Drilling Columns 井下钻柱熔融切割分流喷射机制优化分析
IF 3.6 3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2024-01-02 DOI: 10.2118/218400-pa
Jun Jing, Xirui Luo, Xiaohua Zhu, Yang Peng, Hongbin Shan

Molten metal jet cutting, based on the transient superexothermic characteristics of aluminum thermal reaction, presents a novel technology for swiftly cutting and disposing of stuck drilling columns in downhole oil and gas wells. The key to achieving efficient cutting in drilling columns lies in the jetting mechanism, which guides the high-speed radial ejection of aluminum thermal reaction products that act upon the metal pipe wall. This study uses computational fluid dynamics (CFD) simulation to establish a fluid domain model for the process of cutting molten drilling columns. The optimization of the jetting mechanism is conducted to improve the circumferential coverage by the molten metal by analyzing the impact of molten metal yield and jetting mechanism parameters (cone angle of the conical conductor, diameter, number and length of nozzles, and shape of the diverter). Finally, an ejection test is carried out to verify the optimized jetting mechanism. Research results show that increasing the cone angle of the conical conductor can increase the flow rate of the molten metal at the upper end of the axial nozzle assembly to smoothly discharge the molten metal. Increasing the number of nozzles with equal diameters can increase the circumferential distribution range of molten metal ejected into the cutting area. However, the molten metal circumferential coverage will be impacted by increasing cutting distance. Increasing the nozzle size can reduce the divergence of the molten metal, thereby improving the coverage of the molten metal in the cutting area. When the nozzle arc length L = 8 mm, the molten metal can cover almost the entire cutting area. Adding a 2-mm horizontal draining table at the end of the diverter can assist the molten metal in changing its flow direction, allowing the molten metal to be ejected in a radial direction. The research results provide a theoretical basis for optimizing fusion cutting tools and formulating cutting processes.

熔融金属喷射切割基于铝热反应的瞬时过热特性,是一种快速切割和处理井下油气井中卡住钻柱的新技术。实现钻柱高效切割的关键在于喷射机制,该机制引导铝热反应产物高速径向喷射,作用于金属管壁。本研究利用计算流体动力学(CFD)模拟,建立了熔融钻柱切割过程的流体域模型。通过分析熔融金属产量和喷射机制参数(锥形导体的锥角、喷嘴的直径、数量和长度以及分流器的形状)的影响,对喷射机制进行了优化,以提高熔融金属的圆周覆盖率。最后,还进行了喷射试验,以验证优化后的喷射机制。研究结果表明,增大锥形导体的锥角可以提高轴向喷嘴组件上端的熔融金属流速,使熔融金属顺利排出。增加直径相等的喷嘴数量可以增大喷射到切割区域的熔融金属的圆周分布范围。但是,熔融金属的圆周覆盖范围会因切割距离的增加而受到影响。增大喷嘴尺寸可以减少熔融金属的发散,从而提高熔融金属在切割区域的覆盖率。当喷嘴弧长 L = 8 毫米时,熔融金属几乎可以覆盖整个切割区域。在分流器末端增加一个 2 毫米的水平排水台可以帮助熔融金属改变流向,使熔融金属沿径向喷出。研究成果为优化熔融切削工具和制定切削工艺提供了理论依据。
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引用次数: 0
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