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An Investigation on the Impact of Submicron-Sized Bubbles on the Fragmentation of Methane Clathrates Using Molecular Dynamics Simulation 利用分子动力学模拟研究亚微米级气泡对甲烷凝块破碎的影响
IF 3.6 3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2023-12-01 DOI: 10.2118/218399-pa
John Michael Tesha, Derrick S. Dlamini, Edgar Christian Mapunda, Ashura Katunzi Kilewela
The formation of submicron-sized bubbles is frequently associated with the fragmentation of methane clathrate. A bubble refers to a pocket or a round particle of one substance trapped inside another. In most cases, these spherical pockets are made of gas trapped inside of a liquid. Usually, bubbles can lie underneath the surface of the liquid until the surface tension breaks and the gas escapes back into the atmosphere. Therefore, understanding the fluid dynamics behavior of the clathrate phase shift and enhancing the production efficiency of natural gas requires knowledge of the impact of submicron-sized bubbles on the clathrate fragmentation. In this scenario, molecular dynamics simulation (MDS) models were carried out to investigate the methane clathrate fragmentation rate with and without preexisting submicron-sized bubbles. The findings demonstrate layer-by-layer fragmentation of the methane clathrate cluster in the liquid phase. Furthermore, this mechanism shows temperature and submicron-sized bubble existence independent of simulation settings or conditions. However, because of the stability of the supersaturated methane solution for a long period, methane clathrate fragmentation does not always result in the formation of submicron-sized bubbles. It was observed that between the bubble (submicron-size) of methane and the cluster surface of methane clathrate, there is a steep slope of methane concentration. This results in the liquid phase efficiently decreasing the methane concentration and improving the migration of natural gas in different directions, hence the driving force increases for methane clathrate fragmentation. Our discoveries in this research show that the existence of submicron-sized bubbles near the surface of the methane clathrate can speed up the rate of intrinsic decomposition while decreasing the activation energy of methane clathrate fragmentation. The mass flow rate toward submicron-sized bubbles linearly correlates with the methane clathrate fragmentation rate. The mass flow rate is governed by the size of the submicron-sized bubbles and the spacing between the methane clathrate submicron-sized bubbles. Our results contribute to the in-depth knowledge of the fragmentation technique in the liquid phase for methane clathrates, which is critical in optimizing and designing effective gas clathrate development methods.
亚微米级气泡的形成经常与甲烷凝块的破碎有关。气泡指的是一种物质被困在另一种物质内部的口袋或圆形颗粒。在大多数情况下,这些球形口袋是由被困在液体中的气体构成的。通常情况下,气泡可以隐藏在液体表面之下,直到表面张力被打破,气体逃逸回大气中。因此,要了解凝块相变的流体动力学行为并提高天然气的生产效率,就必须了解亚微米级气泡对凝块破碎的影响。在这种情况下,采用分子动力学模拟(MDS)模型研究了存在和不存在亚微米级气泡时的甲烷凝块破碎率。研究结果表明,液相中的甲烷凝块逐层破碎。此外,这种机制显示温度和亚微米级气泡的存在与模拟设置或条件无关。然而,由于过饱和甲烷溶液具有长期稳定性,甲烷凝块的破碎并不总是导致亚微米级气泡的形成。据观察,在甲烷气泡(亚微米级)和甲烷凝块簇表面之间,甲烷浓度有一个陡峭的斜坡。这导致液相有效地降低了甲烷浓度,改善了天然气向不同方向的迁移,从而增加了甲烷凝块破碎的驱动力。我们在这项研究中的发现表明,甲烷凝块表面附近亚微米级气泡的存在可加快本征分解速度,同时降低甲烷凝块破碎的活化能。流向亚微米级气泡的质量流量与甲烷凝块的破碎率成线性关系。质量流量受亚微米级气泡大小和甲烷凝块亚微米级气泡间距的影响。我们的研究结果有助于深入了解甲烷凝块在液相中的破碎技术,这对于优化和设计有效的气体凝块开发方法至关重要。
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引用次数: 0
Development of Novel Delayed Swelling Polymer Gel Particles with Salt Resistance for Enhanced In-Depth Permeability Control 开发具有耐盐性的新型延迟膨胀聚合物凝胶颗粒,以增强深层渗透性控制能力
IF 3.6 3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2023-12-01 DOI: 10.2118/218394-pa
Yining Wu, Haiqing Zhang, Liyuan Zhang, Yongping Huang, Mingwei Zhao, Caili Dai
Prolonged waterflooding or polymer flooding in oil fields often exacerbates reservoir heterogeneity, leading to premature water breakthrough and high water cut, which significantly hinders efficient oilfield development. To address this issue, polymer gel particles have been prescribed to enhance sweep efficiency and augment waterflooding recovery by plugging preferential pathways within the reservoir. However, inherent weaknesses of polymer gel particles, such as fast water absorption and expansion rates in the initial stage and low post-expansion rates, make it difficult to balance in-depth transportation and plugging performance. Additionally, these gel particles are sensitive to ions in the formation water, resulting in reduced expansion rates under high-salinity conditions. Therefore, there are still challenges in the application of polymer gel particles for in-depth permeability control. In this study, a new type of delayed swelling and salt-resistant polymer gel particle was synthesized through inverse emulsion copolymerization. To achieve delayed swelling, we use a degradable crosslinker and hydrophobic monomer to enhance the crosslinked network density and hydrophobicity of gel particles. Our double crosslinked gel particles keep their original size until Day 2, then gradually swell up to 20 days in NaCl solution with a concentration of 15×104 mg·L−1 at 90°C. In comparison, the traditional single crosslinked gel particles show significant disparities in swelling behaviors and quickly swell when just dispersed in a 15×104 mg·L−1 NaCl solution at 90°C, maintaining roughly the same size over the testing period. Coreflooding experiments demonstrate that the residual resistance before and after aging increases from 2.37 to 6.82. The newly synthesized delayed swelling and salt-resistant polymer gel particles exhibit promising potential for overcoming the challenges associated with reservoir heterogeneity and high salinity.
油田中长时间的注水或聚合物注水往往会加剧储层的异质性,导致过早的水突破和高断水,从而严重阻碍油田的高效开发。为解决这一问题,人们采用聚合物凝胶颗粒堵塞储层中的优先通道,从而提高扫油效率,提高注水采收率。然而,聚合物凝胶颗粒固有的弱点,如初期吸水和膨胀速度快,后期膨胀速度低,使其难以兼顾深度输送和堵塞性能。此外,这些凝胶颗粒对地层水中的离子很敏感,导致在高盐度条件下膨胀率降低。因此,聚合物凝胶颗粒在深度渗透控制方面的应用仍面临挑战。本研究通过反向乳液共聚合成了一种新型延迟膨胀耐盐聚合物凝胶粒子。为了实现延迟溶胀,我们使用了可降解交联剂和疏水单体来增强凝胶粒子的交联网络密度和疏水性。我们的双交联凝胶粒子在第 2 天前保持原有尺寸,然后在 90°C 下浓度为 15×104 mg-L-1 的氯化钠溶液中逐渐膨胀,最长可达 20 天。相比之下,传统的单交联凝胶颗粒在膨胀行为上表现出明显的差异,在 90°C 温度下,刚分散到 15×104 mg-L-1 的 NaCl 溶液中就会迅速膨胀,在测试期间大小基本保持不变。充芯实验表明,老化前后的残余电阻从 2.37 增加到 6.82。新合成的延迟膨胀和耐盐聚合物凝胶粒子在克服储层异质性和高盐度带来的挑战方面具有广阔的前景。
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引用次数: 0
New Approach to Encapsulation for Controlled Release of Chemical Additives 封装控制释放化学添加剂的新方法
IF 3.6 3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2023-12-01 DOI: 10.2118/213736-pa
Elizabeth Q. Contreras
A new approach for the synthesis of bio-inspired polymer microcapsules used to encapsulate chemical additives and designed for small molecule release and delivery is shown here. The flexibility to design different microcapsules using an emulsion template results in various encapsulated additives for a new polymer technology platform. The base materials for encapsulation are polyaramids that are highly crosslinked membrane shells around an empty core. These empty capsules provide a carefully designed space to site-isolate chemical additives, various encapsulants for encapsulation, and delivery where needed. These microcapsules have demonstrated that after being formed from a simple one-pot synthesis between two immiscible solutions, a new method for encapsulation for applications in ordinary Portland cement is possible. The final product is a free-flowing solid that can be easily added to any fluid application. Experimental results show that when added to a basic cement slurry design, cement responds to the release of a salt accelerant as measured using standard oilfield equipment, like the pressurized consistometer, which measures changes in viscosity and thickening times. In one of many applications, the consistency of cement remains favorable at 20 Bc after adding encapsulated calcium chloride for up to 5 hours, for example. Over time, various capsules caused cement slurries to set at right angles at various thickening times with the controlled release of encapsulated calcium chloride. This new approach for encapsulation is promising for the chemical and energy field.
本文展示了一种合成生物启发聚合物微胶囊的新方法,这种微胶囊用于封装化学添加剂,专为小分子释放和递送而设计。利用乳液模板设计不同微胶囊的灵活性,为新的聚合物技术平台提供了各种封装添加剂。封装的基础材料是聚芳酰胺,它是围绕空芯的高度交联膜壳。这些空心胶囊提供了一个精心设计的空间,可用于隔离化学添加剂、各种用于封装的封装剂,并在需要时进行输送。这些微胶囊已经证明,通过两种不相溶溶液之间简单的一锅合成法形成后,一种应用于普通硅酸盐水泥的封装新方法是可行的。最终产品是一种自由流动的固体,可以很容易地添加到任何流体应用中。实验结果表明,当添加到基本的水泥浆设计中时,水泥会对盐促进剂的释放做出反应,这可以用标准的油田设备来测量,如加压稠度仪,它可以测量粘度和稠化时间的变化。在许多应用中,例如在添加氯化钙胶囊长达 5 小时后,水泥的稠度仍保持在 20 Bc。随着时间的推移,各种胶囊使水泥浆在不同的稠化时间以直角凝结,封装氯化钙的释放受到控制。这种新的封装方法在化学和能源领域大有可为。
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引用次数: 0
A Novel Evaluation Technique for Mudcake of Drilling Fluid Based on the Nuclear Magnetic Resonance Method 基于核磁共振法的新型钻井液泥饼评价技术
IF 3.6 3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2023-12-01 DOI: 10.2118/217995-pa
Yunxing Duan, Xianshu Dong, Yang Hao, Yuping Fan, Xiaomin Ma, Lu Zhou
In drilling engineering, mudcake is formed when the drilling fluid invades the near-wellbore zone, which can reduce drilling fluid leakage and reservoir pollution and maintain wellbore stability. Exploring the method that can best represent the field working conditions to evaluate the mudcake is an urgent problem. At present, the macro-evaluation method cannot describe the characteristics of heterogeneity, particle accumulation, and porous media of mudcake. The micro-evaluation method needs local sampling, drying, curing, slicing, and other tedious disturbance treatments, which cannot reflect the overall characteristics of mudcake. To solve these problems, a novel technique for evaluating the pore structure of mudcake was established by taking nuclear magnetic resonance (NMR) T2 tests as the key mean and integrating high-pressure mercury injection tests, fluid isotope tracing, dynamic/static filtration experiment of drilling fluid, pore permeability parameter tests of core, and particle-size distribution tests of drilling fluid. The evaluation results of mudcake formed by drilling fluid static and dynamic filtration show that this technology can study the pore structure characteristics of the outer mudcake and intruded core and the distribution characteristics of the inner mudcake and filtrate in the intruded core. The novel evaluation technique has strong operability and less demand for experimental samples, which can study the micron-scale pore structure of mudcake and provide practical methods for drilling fluid system optimization and application effect evaluation, reservoir damage evaluation, and development or verification of the filtration model.
在钻井工程中,钻井液侵入近井筒区会形成泥饼,泥饼可以减少钻井液渗漏和储层污染,保持井筒稳定。探索最能代表现场工况的泥饼评价方法是一个亟待解决的问题。目前,宏观评价方法无法描述泥饼的异质性、颗粒堆积和多孔介质等特征。微观评价方法需要进行局部取样、干燥、固化、切片等繁琐的扰动处理,无法反映泥饼的整体特征。为解决这些问题,以核磁共振(NMR)T2 试验为手段,结合高压注汞试验、流体同位素示踪、钻井液动静滤实验、岩心孔隙渗透参数试验、钻井液粒度分布试验等,建立了一种新型的泥饼孔隙结构评价技术。钻井液静态和动态过滤形成的泥饼评价结果表明,该技术可以研究外层泥饼和侵入岩心的孔隙结构特征,以及内层泥饼和滤液在侵入岩心中的分布特征。该新型评价技术可操作性强,对实验样品要求不高,可研究泥饼的微米尺度孔隙结构,为钻井液体系优化和应用效果评价、储层损害评价、过滤模型开发或验证提供实用方法。
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引用次数: 0
A New Approach to Apply Decline-Curve Analysis for Tight-Oil Reservoirs Producing Under Variable Pressure Conditions 针对在变压条件下生产的致密油藏应用递减曲线分析的新方法
IF 3.6 3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2023-11-17 DOI: 10.2118/218016-pa
Leopoldo Matias Ruiz Maraggi, Mark P. Walsh, Larry W. Lake
<p>Decline-curve models inherently assume that the bottomhole flowing pressure (BHP) is constant. This is a poor assumption for many unconventional wells. For this reason, the application of decline-curve models might lead to incorrect flow regime identification and estimated ultimate recovery (EUR). This work presents a novel technique that combines variable BHP conditions with decline-curve models and compares its results with traditional decline-curve analysis (DCA) for both synthetic and tight-oil wells.</p><p>Using superposition, we generate a synthetic rate example using the constant-pressure solution of the diffusivity equation for a slightly compressible fluid (decline-curve model) along with a BHP history. However, we validate the technique using bottomhole and initial reservoir pressures that contain errors. The algorithm consists of three sequential optimizations. In each optimization, the algorithm estimates (1) the decline-curve model parameters, (2) the BHP, and (3) the initial reservoir pressure. The result of the synthetic example leads to an accurate production history match and corrected estimates of the initial reservoir pressure and the BHP history. Finally, we compare the results of the technique with traditional DCA in terms of (a) the model parameters, (b) flow regime identification, (c) production history matches, and (d) EUR for tight-oil wells using three decline-curve models: 1D single-phase constant-pressure solution of the diffusivity equation for a slightly compressible fluid, logistic growth model, and Arps hyperbolic relation.</p><p>For the synthetic case, the algorithm estimates the model parameters and the true initial reservoir pressure within a 2% error. In addition, the method regenerates the true BHP history and provides an excellent production history match. The analysis of the tight-oil wells shows that the new approach clearly identifies the flow regimes present in the well, which can be difficult to detect using traditional DCA when the BHP varies. In contrast, the application of traditional DCA shows considerable errors in the estimation of the model’s parameters and a poor history match of the production data. Finally, this work shows that incorporating variable BHP into the decline-curve models leads to more accurate production history matches and EUR values compared to using only rate-time data.</p><p>This paper illustrates a workflow that incorporates variable BHP conditions for any decline-curve model. Moreover, the approach can handle errors in both the BHP and the initial reservoir pressure and provides corrected estimates of these variables. The technique is computationally fast and history matches and forecasts the production of unconventional wells more accurately than traditional DCA. The major contribution of this work is the remarkable simplicity yet robustness of our solution to variable-pressure DCA. Finally, we developed a web-based application to provide the readers with a hands-on exper
递减曲线模型本质上假定井底流动压力(BHP)是恒定的。对于许多非常规油井来说,这一假设并不可靠。因此,应用递减曲线模型可能会导致不正确的流态识别和最终采收率(EUR)估算。本研究提出了一种将可变 BHP 条件与递减曲线模型相结合的新技术,并将其结果与传统的递减曲线分析(DCA)进行了比较。不过,我们使用含有误差的井底压力和初始储层压力对该技术进行了验证。该算法包括三次连续优化。在每次优化中,该算法都会估算 (1) 井下曲线模型参数、(2) BHP 和 (3) 初始储层压力。合成示例的结果导致了精确的生产历史匹配以及对初始储层压力和 BHP 历史的修正估计。最后,我们比较了该技术与传统 DCA 在以下方面的结果:(a) 模型参数;(b) 流态识别;(c) 生产历史匹配;(d) 使用三种递减曲线模型的致密油井欧元:对于合成情况,该算法对模型参数和真实初始储层压力的估计误差不超过 2%。此外,该方法还能重新生成真实的必发888官网登录入口历史,并提供出色的生产历史匹配。对致密油井的分析表明,新方法可以清楚地识别出油井中存在的流态,而当 BHP 发生变化时,使用传统 DCA 很难检测到这些流态。相比之下,应用传统的 DCA 方法在估计模型参数时会出现相当大的误差,而且生产数据的历史匹配性很差。最后,这项工作表明,与仅使用速率时间数据相比,将可变 BHP 纳入衰退曲线模型可获得更准确的生产历史匹配和 EUR 值。此外,该方法还能处理 BHP 和初始储层压力的误差,并提供这些变量的修正估计值。该技术计算速度快,与传统 DCA 相比,能更准确地匹配和预测非常规井的产量。这项工作的主要贡献在于,我们的变压 DCA 解决方案具有显著的简便性和稳健性。最后,我们开发了一个基于网络的应用程序,让读者亲身体验这项新技术。
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引用次数: 0
Hybrid Approach Using Physical Insights and Data Science for Stuck-Pipe Prediction 使用物理洞察和数据科学进行卡钻预测的混合方法
3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2023-11-01 DOI: 10.2118/218013-pa
Tatsuya Kaneko, Tomoya Inoue, Yujin Nakagawa, Ryota Wada, Shungo Abe, Gota Yasutake, Kazuhiro Fujita
Summary Early detection of stuck-pipe incidents is crucial because of the enormous costs of recovering from such incidents. Previous studies have leaned significantly toward a physics-based or data science approach. However, both approaches have challenges, such as the uncertainty of the physics-based model and the lack of data in the data science approach. In this study. we propose a hybrid approach using physical insights and data science and discuss the possibility of stuck-pipe prediction. The proposed method comprises two steps. In the first step, a data-driven model with physical insights is trained using the historical data of the in-situ well to estimate some of the drilling variables. In the second step, the risk of stuck-pipe occurrence (hereafter referred to as sticking risk) is calculated based on the historical and current measured data and the estimation of the trained model. This approach is expected to overcome the limitations of the previous methods as it allows the construction of a detection model tuned to the in-situ well. In the case studies, models for estimating the topdrive torque and standpipe pressure were constructed. The performance of the models is discussed using actual drilling data from drilling fields, including 21 stuck-pipe incidents during drilling operations. The proposed method was first examined using short-term output. The output confirmed that the sticking risk increased shortly (up to 20 hours) before the stuck-pipe incident occurred in 15 cases. This increase in sticking risk was consistent with physical considerations. Subsequently, this study examined the long-term output over several months; this was rarely done in previous studies. Even within this long-term output, some cases had good performance with only a few false alarms, while others had problems with many false alarms. For cases of low performance, several model improvements, such as adding mud information or making the learning and threshold-setting methods more robust to outliers, were found to have the potential to improve performance. The novelty of our research lies in creating a broad framework for the stuck-pipe prediction by using both physical insights and data science methods. The proposed hybrid approach demonstrated the potential to reduce false alarms and improve interpretability compared with previous methods. The framework is highly extensible, and further performance improvements can be expected in the future.
由于从此类事故中恢复的成本巨大,因此早期发现卡钻事故至关重要。以前的研究明显倾向于基于物理或数据科学的方法。然而,这两种方法都存在挑战,例如基于物理的模型的不确定性以及数据科学方法中数据的缺乏。在这项研究中。我们提出了一种使用物理洞察力和数据科学的混合方法,并讨论了卡钻预测的可能性。该方法包括两个步骤。第一步,使用现场井的历史数据来训练具有物理洞察力的数据驱动模型,以估计一些钻井变量。第二步,根据历史和当前的测量数据以及训练好的模型的估计,计算卡管发生的风险(以下简称卡管风险)。该方法有望克服以前方法的局限性,因为它允许构建适合于原位井的检测模型。在实例研究中,建立了估算顶驱扭矩和立管压力的模型。利用钻井现场的实际钻井数据,包括钻井作业中的21起卡钻事故,对模型的性能进行了讨论。首先用短期产出检验了所提出的方法。输出结果证实,在15例卡钻事故发生之前,卡钻风险增加了不久(长达20小时)。粘连风险的增加与身体因素是一致的。随后,本研究考察了几个月的长期产出;在以前的研究中很少这样做。即使在这个长期输出中,有些情况下只有少数假警报,而其他情况下有许多假警报的问题。对于性能较低的情况,一些模型改进,如添加泥浆信息或使学习和阈值设置方法对异常值更具鲁棒性,被发现有可能提高性能。我们研究的新颖之处在于,通过使用物理洞察力和数据科学方法,为卡钻预测创建了一个广泛的框架。与以前的方法相比,所提出的混合方法具有减少误报和提高可解释性的潜力。该框架是高度可扩展的,未来还会有进一步的性能改进。
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引用次数: 0
Drill-In Fluid Optimization for Formation Damage Control Considering Salt Dissolution in Saline-Lacustrine Reservoirs 考虑盐湖储层盐溶的入井钻井液防损优化研究
3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2023-11-01 DOI: 10.2118/218018-pa
Qigui Tan, Bin Yang, Lijun You, Yili Kang, Haoping Peng, Fuquan Song, Chong Lin
Summary Salt dissolution induced by drill-in fluid loss is a frequent occurrence in saline-lacustrine reservoirs, which can potentially result in serious formation damage. In light of this, an experimental study was conducted to investigate the salt mineral dissolution and dynamic damage in the rock samples collected from a saline-lacustrine carbonate reservoir and the response of pore-fracture structures using the in-situ drill-in fluids. The study further involved analyzing the formation-damage-control (FDC) ability of the in-situ drill-in fluids. The results indicated that although salt dissolution significantly increased the pore size of the tight matrix and the width of natural fractures, improving the conductivity of seepage channels, the increase in pore-fracture size may have greatly aggravated the drill-in fluid loss during the process. The continuous serious filtrate loss, lower pressure-bearing capacity of the plugging zone, and lower permeability recovery rate (PRR) of rock indicated poor FDC performance of in-situ brine drilling fluids for the salt-dissolved core samples. The FDC performance of drill-in fluids for saline-lacustrine carbonate reservoirs was optimized based on the response of reservoir pore-fracture structure to salt dissolution and the theory of slightly underbalanced activity. The experimental results showed that the optimized drill-in fluids had better FDC ability, with an average PRR increase of 14.04%. Field application indicated that the optimized drill-in fluids reduced the drill-in fluid loss by 76.48%, shortened the drilling cycle by 45.20%, and increased the initial production capacity per well by 7.70%. This study can provide insightful guidance to optimize the FDC performance of drill-in fluids for saline-lacustrine hydrocarbon reservoirs during drilling.
在盐湖储层中,钻入液漏失引起的盐溶是常见的现象,可能会导致严重的地层损害。在此基础上,利用原位钻进流体,对某盐湖相碳酸盐岩储层岩样中的盐矿物溶蚀、动态损伤及孔隙-裂缝结构响应进行了实验研究。研究进一步分析了原位钻井液的地层损害控制(FDC)能力。结果表明,盐溶作用虽然显著增大了致密基质的孔隙尺寸和天然裂缝宽度,提高了渗流通道的导流能力,但孔隙-裂缝尺寸的增大可能极大地加剧了钻井过程中的钻井液漏失。滤失持续严重,封堵区承压能力较低,岩石渗透率采收率(PRR)较低,表明原位盐水钻井液对盐溶岩心样品的FDC性能较差。基于储层孔隙-裂缝结构对盐溶蚀的响应和微欠平衡活性理论,对盐湖相碳酸盐岩储层钻进液的FDC性能进行了优化。实验结果表明,优化后的入井液具有较好的FDC能力,平均PRR提高14.04%。现场应用表明,优化后的入井液使入井损失量降低了76.48%,钻井周期缩短了45.20%,单井初始产能提高了7.70%。该研究对盐碱湖相油气藏钻井过程中钻井液FDC性能的优化具有指导意义。
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引用次数: 0
Visual Laboratory Tests: Effect of Operational Parameters on Proppant Transport in a 3D Printed Vertical Hydraulic Fracture with Two-Sided Rough Surfaces 视觉实验室测试:操作参数对具有双面粗糙表面的3D打印垂直水力裂缝中支撑剂输送的影响
3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2023-11-01 DOI: 10.2118/218007-pa
Jun Li, Xu Han, Siyuan He, Mingyi Wu, Xinqian Lu
Summary Hydraulic fracturing technology is an effective measure that can improve oil and gas production and achieve enormous economic benefits owing to it phenomenally increasing the oil recovery from the low intrinsic permeability of the compact rock. Good placement and distribution of the proppant in the hydraulic fractures can provide successful stimulation for a well, which is essential for applying the hydraulic fracturing process. Previous studies extensively explored proppant placement, distribution, and operational factors in simplified smooth surface fracture models. However, the operational factors such as pump rate, proppant concentration, proppant size, fluid viscosity, and inlet condition (pulse time) involved in proppant placement and distribution in realistic rough surfaces of fractures are not clearly understood. In particular, the law of proppant transport in a two-sided rough surface of fracture with changes in the aforementioned operational factors was unclear. Hence, in this study, we investigated the effect of these operational factors on proppant placement and transport in both the smooth surface fracture model and the two-sided rough surface fracture model. The results suggested that the traditional law of proppant transport drawn on the smooth surface fracture model did not apply to the two-sided rough surface model. It is suggested that selecting corresponding variables was needed to reduce the risk of proppant bridging and offer a better channel ratio.
水力压裂技术能显著提高致密岩石低本征渗透率油藏的采收率,是提高油气产量并取得巨大经济效益的有效措施。支撑剂在水力裂缝中的良好放置和分布可以为井提供成功的增产,这对于水力压裂工艺的应用至关重要。之前的研究广泛探讨了简化光滑面裂缝模型中支撑剂的放置、分布和操作因素。然而,诸如泵速、支撑剂浓度、支撑剂尺寸、流体粘度和入口条件(脉冲时间)等操作因素对支撑剂在实际粗糙裂缝表面的放置和分布的影响尚不清楚。特别是,随着上述操作因素的变化,支撑剂在双面粗糙裂缝表面的运移规律尚不清楚。因此,在本研究中,我们研究了在光滑面裂缝模型和双面粗糙面裂缝模型中,这些操作因素对支撑剂放置和输送的影响。结果表明,光滑面裂缝模型中传统的支撑剂输运规律不适用于双面粗糙面裂缝模型。建议选择相应的变量,以降低支撑剂桥接的风险,并提供更好的通道比。
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引用次数: 0
Investigation of Carbonate Matrix Damage and Remediation Methods for Preformed Particle Gel Conformance Control Treatments 碳酸盐基质损伤调查和预制颗粒凝胶一致性控制处理的修复方法
IF 3.6 3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2023-11-01 DOI: 10.2118/210311-pa
Abdulaziz A. Almakimi, Junchen Liu, Baojun Bai, I. Hussein
Preformed particle gels (PPGs) have been widely applied to control excessive water production in mature oil fields with fractures or fracture-like features, especially in sandstones, but with limited attention to carbonates. However, a vital concern arises regarding the potential damage of PPGs on the adjacent matrix that might promote negative results. This paper comprehensively evaluates PPGs’ potential damage to the carbonate matrix and seeks design optimization solutions. Filtration tests were applied to compare PPGs’ penetration into the matrix under different sets of conditions. The filtration regimes were defined by filtration curves, and the gel damage on the matrix was determined by permeability measurement results. Experiments were conducted to investigate the efficiency of an oxidizer as a remediation method to remove the damage. The qualitative description of gel particles’ invasion and plugging behavior in the carbonate matrix was presented based on the analysis of filtration test results and permeability measurements. The results show that the swollen gel filtration curves can be divided into three regions: prior-filter-cake, filter-cake-building, and stable stages according to the gel particles’ response to the injection pressure and effluent flow rates. PPGs can form cakes on the rock surface to prevent particles’ further penetration into the carbonate matrix, and the penetration was only limited to less than a few millimeters. The smallest gel particles (50–70 US mesh size) were more likely to form external and internal filter cakes at higher pressure values (700 psi) and result in more damage to the matrix. To restore the matrix permeability after filtration tests, oxidizer soaking proved to be a reliable solution. In all, the results indicated that unintentional matrix permeability damage induced by gel injection is generally unavoidable but conditionally treatable.
预制颗粒凝胶(PPG)已被广泛应用于控制成熟油田中具有裂缝或类似裂缝特征的过量产水,尤其是在砂岩中,但对碳酸盐岩的应用却很有限。然而,PPG 对邻近基质的潜在破坏可能会带来负面影响,这也是一个重要的问题。本文全面评估了 PPG 对碳酸盐基质的潜在破坏,并寻求设计优化方案。通过过滤试验来比较 PPG 在不同条件下对基体的渗透情况。根据过滤曲线确定过滤条件,并根据渗透性测量结果确定凝胶对基质的破坏程度。实验还研究了氧化剂作为修复方法消除损伤的效率。根据对过滤测试结果和渗透性测量结果的分析,对凝胶颗粒在碳酸盐基质中的侵入和堵塞行为进行了定性描述。结果表明,根据凝胶颗粒对注入压力和流出流速的反应,膨胀凝胶过滤曲线可分为三个区域:过滤前结饼阶段、过滤结饼阶段和稳定阶段。PPG 可以在岩石表面形成滤饼,阻止颗粒进一步渗透到碳酸盐基质中,而且渗透范围只限于几毫米以内。在较高压力值(700 psi)下,最小的凝胶颗粒(50-70 US 目)更容易形成外部和内部滤饼,从而对基质造成更大的破坏。为了在过滤测试后恢复基质的渗透性,氧化剂浸泡被证明是一种可靠的解决方案。总之,研究结果表明,凝胶注入引起的无意基质渗透性破坏一般是不可避免的,但可以有条件地加以处理。
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引用次数: 0
Nonionic Surfactant Blends for Enhanced Oil Recovery in High-Temperature Eagle Ford Reservoir 非离子表面活性剂混合物在高温伊格尔福特油藏中的强化采油技术
IF 3.6 3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2023-11-01 DOI: 10.2118/218382-pa
Elsie B. Ladan, David S. Schechter
Nonionic surfactants have proven successful and cost-effective in enhancing production from conventional and unconventional reservoirs. However, studies into the mechanism and performance of nonionic surfactants have been limited to reservoirs with temperatures below 200°F due to the temperature-dependent physiochemical properties, especially cloudpoint (CP). In this study, nonionic-ionic surfactant blends were designed to create nonionic systems with cloudpoint temperatures (CPTs) above 300°F for wettability alteration in high-temperature reservoirs like the Eagle Ford Shale in Texas, USA. Through CP, wettability, interfacial tension (IFT), and spontaneous imbibition experiments, 22 commercial surfactant samples (individual and blends) were investigated. Results showed that the amount of ionic cosurfactant affected thermal stability, with increasing concentration leading to increasing CPT. Wettability alteration was dependent not only on temperature but also on the class of ionic cosurfactant. Cationic cosurfactants were superior at improving nonionic surfactants’ thermal stability. However, they resulted in oil-wet contact angles (CAs) with increasing temperature. On the other hand, anionic cosurfactants displayed better synergy in terms of wettability alteration, creating strongly water-wet and intermediate-wet CAs at high temperatures. Therefore, the focus was placed on nonionic-anionic surfactant blends for the reservoir samples used in this study. Stable surfactant blends with CPTs from 316°F to 348°F were successfully created for enhanced oil recovery (EOR) applications at high-temperature conditions. Spontaneous imbibition studies using these blends indicated improved recovery by up to 173%. This work validates and builds upon previous studies of surfactant performance, wettability alteration, and IFT while providing new insight into nonionic surfactant blends at temperature conditions not currently available in the literature. It also serves as a template for the surfactant screening and selection process when considering nonionic surfactants.
事实证明,非离子表面活性剂在提高常规和非常规储层的产量方面非常成功,而且具有成本效益。然而,由于非离子表面活性剂的理化性质(尤其是浊点 (CP))与温度有关,因此对其机理和性能的研究仅限于温度低于 200°F 的油藏。本研究设计了非离子-离子表面活性剂混合物,以创建浊点温度(CPT)高于 300 华氏度的非离子体系,用于改变美国得克萨斯州伊格尔福特页岩等高温储层的润湿性。 通过氯化石蜡、润湿性、界面张力(IFT)和自发浸润实验,对 22 种商用表面活性剂样品(单独样品和混合样品)进行了研究。结果表明,离子共表面活性剂的含量会影响热稳定性,浓度越高,CPT 越高。润湿性的改变不仅取决于温度,还取决于离子共表面活性剂的种类。阳离子共表面活性剂在改善非离子表面活性剂的热稳定性方面更胜一筹。不过,随着温度的升高,它们会导致油湿接触角(CAs)增大。另一方面,阴离子共表面活性剂在改变润湿性方面表现出更好的协同作用,在高温下可产生强水湿和中湿接触角。因此,本研究中使用的储层样品的重点是非离子-阴离子表面活性剂混合物。我们成功研制出 CPT 值为 316°F 至 348°F 的稳定表面活性剂混合物,用于高温条件下的提高石油采收率 (EOR)。使用这些混合物进行的自发浸泡研究表明,采收率提高了 173%。这项工作验证并借鉴了之前对表面活性剂性能、润湿性改变和 IFT 的研究,同时为非离子表面活性剂混合物在温度条件下的应用提供了新的见解,而这些研究目前在文献中还没有。在考虑使用非离子表面活性剂时,它还可作为表面活性剂筛选和选择过程的模板。
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引用次数: 0
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