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Simulation of Hydrate Particles Aggregation and Deposition in Gas-Dominated Flow 模拟气体主导流中水合物颗粒的聚集和沉积
IF 3.6 3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2023-11-01 DOI: 10.2118/218384-pa
Zhiyuan Wang, Zeqin Li, Jihao Pei, Nan Ma, Jianbo Zhang, Baojiang Sun
Owing to low-temperature and high-pressure production environments, hydrate generation, accumulation, and deposition are prone to occur in deepwater oil and gas production wells and transportation pipelines, leading to pipeline blockage and threatening the safety of oil and gas production. To explore the aggregation mechanism and deposition law of hydrate particles in the main gas diversion pipeline, this study considered the adhesion effect of hydrate particles and established a hydrate particle aggregation and deposition model based on theory and experiments. The coupled computational fluid dynamics-discrete element method (CFD-DEM) is used in the simulation calculation. The simulation results were compared with the relevant experimental results, and maximum and average errors of 9.48% and 4.56% were observed, respectively. It was found that the main factor affecting the aggregation of hydrates is the adhesion between particles. As the subcooling temperature increased, the aggregation and adhesion of the hydrate particles increased to varying degrees. The tangential adhesion force between the hydrate aggregate particles was significantly greater than the normal adhesion force, and the adhesion force between the particles gradually increased from the surface to the interior of the aggregates. The coordination number of the hydrate particles can quantitatively characterize the degree of aggregation and is affected by many factors, such as adhesion. By studying the particle coordination number, the evolution of hydrate accumulation and deposition under different conditions can be summarized. Based on the simulation results, the mathematical relationship between different dimensionless numbers and hydrate deposition ratio (HDR) was calculated, and an expression that can predict the HDR was obtained, with an average relative error of 10.155%. This study provides a theoretical basis for predicting the aggregation and deposition of hydrate particles in gas-dominated systems and a reference for the development of hydrate prevention and control plans.
由于低温高压的生产环境,深水油气生产井和运输管道中容易发生水合物生成、聚集和沉积,导致管道堵塞,威胁油气生产安全。为探索水合物颗粒在主输气管道中的聚集机理和沉积规律,本研究考虑了水合物颗粒的粘附效应,在理论和实验的基础上建立了水合物颗粒聚集沉积模型。模拟计算采用了计算流体力学-离散元耦合方法(CFD-DEM)。模拟结果与相关实验结果进行了比较,观察到最大和平均误差分别为 9.48% 和 4.56%。研究发现,影响水合物聚集的主要因素是颗粒之间的粘附力。随着过冷温度的升高,水合物颗粒的聚集和粘附都有不同程度的增加。水合物聚集颗粒之间的切向粘附力明显大于法向粘附力,颗粒之间的粘附力从聚集体表面向内部逐渐增大。水合物颗粒的配位数可以定量表征聚集程度,并受到粘附力等多种因素的影响。通过研究颗粒配位数,可以总结出不同条件下水合物聚集和沉积的演变过程。根据模拟结果,计算了不同无量纲数与水合物沉积率(HDR)之间的数学关系,得到了可以预测 HDR 的表达式,平均相对误差为 10.155%。这项研究为预测气体主导系统中水合物颗粒的聚集和沉积提供了理论依据,也为制定水合物防治计划提供了参考。
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引用次数: 0
Reservoir Drilling and Openhole Gravel Packing with High-Density Cesium Formate Fluids in a High-Pressure, Marginal Mud Window Environment at Martin Linge 在马丁林格的高压边缘泥浆窗环境中使用高密度甲酸铯流体进行储层钻探和裸眼砾石封隔
IF 3.6 3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2023-11-01 DOI: 10.2118/212487-pa
Simen Jøsang Nilsen, Hanne Undheim Obrestad, H. Kaarigstad, Nadia Mansurova, Tom Are Solvoll, Johan Løchen, Siv Howard, Ben Abrahams, Christian Busengdal
High-density cesium/potassium (Cs/K) formate fluids were successfully utilized from reservoir drilling to upper completion installation in five productive Martin Linge high-rate gas wells. Four wells were completed with openhole gravel pack (OHGP) and one with standalone sand screens. The gravel packing operation marks what is considered to be the highest density carrier fluid OHGP successfully completed worldwide, with a specific gravity (SG) of 2.06. A complex operation under pressure and temperature conditions (745–780 bar and 135–140°C) that almost qualify as high pressure/high temperature (HP/HT), including managed pressure drilling (MPD), overbalanced screen running, and openhole gravel packing, was simplified by using the same base brine throughout the operation. Cs/K formate reservoir drilling fluid (RDF) and screen-running fluid were designed with biopolymeric additives and minimal calcium carbonate bridging particles. Clear Cs/K formate brine was chosen as gravel pack (GP) carrier fluid. The use of Cs/K formate fluids for all stages of the operation reduced the complexity of transitioning between the operational stages. In addition, the reservoir was only exposed to one filtrate without application of damaging weighting solids. The drilling fluid contributed to successful MPD and delivered wells with very good hole quality in the reservoir, which consisted of interbedded sandstone, coal stringers, and shale. The shale-stabilizing properties of concentrated formate brine–based fluids provided acceptable conditions for extended openhole time and allowed additional logging runs, including pore pressure measurements, under near-HP/HT conditions, before running the screens. One bottom-up cleanout was conducted before the screen-running fluid was circulated in and the screens installed. The spurt and seepage losses were low throughout the drilling and screen-running phases. No breaker treatment was required in any of the wells. All wells have proved to have good initial productivity and high well productivity index. The successful OHGP operations performed with the high fluid densities required in Equinor’s Martin Linge field have set a new standard for well completions in challenging high-pressure environments.
高密度铯/钾(Cs/K)甲酸盐流体在五口高产的马丁林格高速气井中,从储层钻探到上部完井安装都得到了成功应用。四口井采用裸眼砾石填料(OHGP)完井,一口井采用独立砂筛完井。 砾石填料作业被认为是全球成功完成的密度最高的载液 OHGP,其比重 (SG) 为 2.06。在压力和温度条件(745-780 巴,135-140°C)下进行的复杂作业几乎可被称为高压/高温(HP/HT)作业,包括有管理压力钻井(MPD)、超平衡筛运行和裸眼砾石包装,通过在整个作业过程中使用相同的基础盐水,简化了这一作业。 Cs/K 甲酸盐储层钻井液 (RDF) 和筛分运行液在设计时使用了生物聚合物添加剂,并尽量减少碳酸钙架桥颗粒。清澈的甲酸钙/甲酸钾盐水被选为砾石包(GP)载液。所有作业阶段都使用甲酸钙/甲酸钾流体,降低了作业阶段之间过渡的复杂性。此外,储层只需接触一种滤液,无需使用破坏性加重固体。 钻井液有助于成功进行 MPD,并在由砂岩、煤系层和页岩组成的储层中钻出了孔质量非常好的井。浓甲酸盐基流体的页岩稳定特性为延长井眼开放时间提供了可接受的条件,并允许在运行滤网之前进行更多的测井工作,包括在接近高压/超高压条件下进行孔隙压力测量。在循环滤网运行流体和安装滤网之前,进行了一次自下而上的清理。在整个钻井和滤网运行阶段,喷涌和渗流损失都很低。所有油井都无需进行破碎处理。事实证明,所有油井都具有良好的初始生产力和较高的油井生产力指数。 在 Equinor 的 Martin Linge 油田,在所需的高流体密度条件下成功完成 OHGP 作业,为在极具挑战性的高压环境下完井树立了新标准。
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引用次数: 0
Real-Time Gamma Ray Log Generation from Drilling Parameters of Offset Wells Using Physics-Informed Machine Learning 利用物理信息机器学习从偏置井钻井参数生成实时伽马射线测井曲线
IF 3.6 3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2023-11-01 DOI: 10.2118/212445-pa
Prasham Sheth, Sailaja Sistla, Indranil Roychoudhury, Mengdi Gao, Crispin Chatar, Jose Celaya, Priya Mishra
By 2026, USD 5.05 billion will be spent per year on logging while drilling (LWD) according to the market report from Fortune Business Insights (2020). Logging tools and wireline tools are costly services for operators to pay for, and the companies providing the services also have a high cost of service delivery. They are, however, an essential service for drilling wells efficiently. The ability to computationally generate logs in real time using known relationships between the rock formations and drilling parameters, namely, rate of penetration (ROP), rotations per minute (RPM), surface weight on bit (SWOB), surface torque (TQX), standpipe pressure (SPPA), and hookload (HKLD), provides an alternative method to generate formation evaluation information (analysis of the subsurface formation characteristics such as lithology, porosity, permeability, and saturation). This paper describes an approach to creating a digital formation evaluation log generator using a novel physics-informed machine learning (PIML) approach that combines physics-based approaches with machine learning (ML) algorithms. The designed approach consists of blocks that calculate mechanical specific energy (MSE), physical estimates of gamma ray (GR) using physical and empirical models, and formation information. All this information and the drilling parameters are used to build a classification model to predict the formations, followed by formation-based regression models to get the final estimate of GR log. The designed PIML approach learns the relationships between drilling parameters and the GR logs using the data from the offset wells. The decomposition of the model into multiple stages enables the model to learn the relationship between drilling parameters data and formation evaluation data. It makes it easier for the model to generate GR measurements consistent with the rock formations of the subject well being drilled. Because the computationally generated GR by the model is not just dependent on the relationships between drilling parameters and GR logs, this model is also generalizable and capable of being deployed into the application with only retraining on the offset wells and no change in the model structure or complexity. For this paper, the drilling of the horizontal section will not be discussed, as this was done as a separate body of work. Historically collected data from the US Land Permian Basin wells are used as the primary data set for this work. Results from the experiments based on the data collected from five different wells have been presented. Leave-one-out validation for each of the wells was performed. In the leave-one-out validation process, four of the wells represent the set of offset wells and the remaining one becomes the subject well. The same process is repeated for each of the wells as they are in turn defined as a subject well. Results show that the framework can infer and generate logs such as GR logs in real time. The average root-mean-squar
根据《财富商业洞察》(2020 年)的市场报告,到 2026 年,每年用于钻井测井(LWD)的费用将达到 50.5 亿美元。对于运营商来说,测井工具和有线工具是成本高昂的服务,而提供这些服务的公司的服务成本也很高。然而,它们却是高效钻井的基本服务。利用岩层与钻井参数(即穿透率 (ROP)、每分钟转数 (RPM)、钻头表面重量 (SWOB)、表面扭矩 (TQX)、立管压力 (SPPA) 和钩载 (HKLD))之间的已知关系实时计算生成测井曲线的能力,为生成岩层评价信息(分析岩性、孔隙度、渗透率和饱和度等地下岩层特征)提供了另一种方法。本文介绍了一种使用新颖的物理信息机器学习(PIML)方法创建数字地层评价测井仪的方法,该方法结合了基于物理的方法和机器学习(ML)算法。所设计的方法由计算机械比能(MSE)、使用物理和经验模型对伽马射线(GR)进行物理估算以及地层信息的模块组成。所有这些信息和钻井参数都用于建立预测地层的分类模型,然后通过基于地层的回归模型来获得伽马测井曲线的最终估算值。 所设计的 PIML 方法利用偏移井的数据学习钻井参数与 GR 测井曲线之间的关系。将模型分解为多个阶段使模型能够学习钻井参数数据与地层评价数据之间的关系。这使得模型更容易生成与钻探对象井岩层一致的 GR 测量结果。由于该模型通过计算生成的 GR 不仅取决于钻井参数和 GR 测井曲线之间的关系,因此该模型还具有通用性,只需在偏移井上重新训练,模型结构或复杂性不变,即可部署到应用中。本文将不讨论水平段的钻井情况,因为这是一项单独的工作。 从美国陆地二叠纪盆地油井中收集的历史数据被用作这项工作的主要数据集。实验结果基于从五个不同油井收集的数据。对每口油井都进行了剔除验证。在剔除验证过程中,其中四口井代表一组偏移井,剩下一口井成为主体井。当每口井依次被定义为主体井时,重复同样的过程。结果表明,该框架可以实时推断和生成测井曲线,如 GR 测井曲线。实验观察到的平均均方根误差(RMSE)为 27.25 api,误差约为 10%。这个误差值是根据平均估计值计算的,没有考虑预测的置信区间。考虑置信区间有助于进一步缩小误差范围。
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引用次数: 0
Effect of Molecular Structure of Thio-Chemicals on Corrosion Inhibition in CO2 Corrosive Environments 硫代化学品分子结构对二氧化碳腐蚀环境中缓蚀作用的影响
IF 3.6 3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2023-11-01 DOI: 10.2118/213848-pa
Jiang Yang, Xintong Wang, Yefei Wang, Zhen Yang
Carbon dioxide (CO2) is frequently present in oil and gas fields, and its use in CO2 flooding for enhanced oil recovery is growing. However, CO2 is highly corrosive to steel in oilfield fluid. The effective and economical method for controlling corrosion is the addition of corrosion inhibitors for carbon steel materials. Thio-compounds of small size have shown potential as corrosion inhibitors to enhance the performance of imidazoline inhibitors. In this study, several small thio-derivatives inhibitors including mercaptoethanol (ME), thiourea (TU), mercaptoacetic acid (TGA), and 2-mercaptobenzimidazole (MBI) were compared to inhibit the CO2 corrosion. They were used as synergists to enhance corrosion inhibition of oleic imidazoline (OIM) on carbon steel in CO2-saturated brine at 60°C. The corrosion inhibition was evaluated using weight loss and electrochemical techniques, while the surface was characterized using atomic force microscopy (AFM). Additionally, quantum chemical calculations were conducted to investigate the mechanism of corrosion inhibition. The results demonstrate that the MBI, with its aromatic group, exhibited superior corrosion inhibition performance compared with ME, TGA, and TU. The surface characterization revealed no pitting and localized corrosion at 10 ppm of inhibitor. A proposed interaction model suggests that OIM becomes protonated and forms a coadsorption layer with MBI on the carbon steel surface through electrostatic attraction. MBI adsorbs onto iron through a bidentate binding-N-S-bridge connection, effectively preventing carbon steel corrosion in the CO2 environments. This research contributes to establishing a structure-properties relationship for thio-chemicals, aiding in the development of more efficient corrosion inhibitors.
二氧化碳(CO2)经常出现在油田和气田中,其在二氧化碳充注提高石油采收率中的应用也在不断增加。然而,二氧化碳对油田流体中的钢材具有很强的腐蚀性。控制腐蚀的有效而经济的方法是在碳钢材料中添加缓蚀剂。小尺寸的硫代化合物作为缓蚀剂具有提高咪唑啉缓蚀剂性能的潜力。本研究比较了几种小型硫代衍生物抑制剂(包括巯基乙醇 (ME)、硫脲 (TU)、巯基乙酸 (TGA) 和 2-巯基苯并咪唑 (MBI))对二氧化碳腐蚀的抑制作用。它们被用作增效剂,以增强油酸咪唑啉(OIM)在 60°C CO2 饱和盐水中对碳钢的缓蚀作用。采用失重和电化学技术对缓蚀效果进行了评估,同时使用原子力显微镜(AFM)对表面进行了表征。此外,还进行了量子化学计算以研究缓蚀机理。结果表明,与 ME、TGA 和 TU 相比,带有芳香基团的 MBI 表现出更优越的缓蚀性能。表面表征显示,在抑制剂含量为 10 ppm 时,没有点蚀和局部腐蚀现象。根据提出的相互作用模型,OIM 会质子化,并通过静电吸引与 MBI 在碳钢表面形成共吸附层。MBI 通过双齿结合-N-S 桥连接吸附在铁上,从而有效防止碳钢在二氧化碳环境中腐蚀。这项研究有助于建立硫代化学品的结构-性能关系,从而帮助开发更有效的缓蚀剂。
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引用次数: 0
Corrosion Inhibition of Benzyl Quinoline Chloride Derivative-Based Formulation for Acidizing Process 基于苄基氯化喹啉衍生物的酸化工艺配方的缓蚀作用
IF 3.6 3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2023-11-01 DOI: 10.2118/218374-pa
Zhen Yang, Yefei Wang, Jiang Yang, Jing Wang, M. Finšgar
Due to the severe and rapid corrosion of metallic equipment by strong acids at high temperatures, a high concentration of acidizing corrosion inhibitors (ACIs) is required during acidizing processes. There is always a need to develop more effective and environmentally friendly ACIs than current products. In this work, a highly effective ACI obtained from a novel main component and its synergistic effect with paraformaldehyde (PFA) and potassium iodide (KI) is presented. The ACI was prepared from the crude product of benzyl quinolinium chloride derivative (BQD) synthesized from benzyl chloride and quinoline in a simple way. The new ACI formulation, named “synergistic indolizine derivative mixture” (SIDM), which consists of BQD, PFA, and KI, showed superior corrosion inhibition effectiveness (IE) and temperature stability compared with commercially available ACI. More importantly, the SIDM formulation eliminates the need for commonly used highly toxic synergists (e.g., propargyl alcohol and As2O3). In a 20 wt% hydrochloric acid (HCl) solution, the addition of 0.5 wt% SIDM mitigates the corrosion rate of N80 steel down to less than 0.00564 lbm·ft−2 at 194°F, while the corrosion rate at 320 °F is 0.0546 lbm·ft−2·when 4.0 wt% SIDM is added.
由于金属设备在高温下会被强酸迅速腐蚀,因此在酸化过程中需要使用高浓度的酸化缓蚀剂(ACIs)。与现有产品相比,我们一直需要开发更有效、更环保的酸化缓蚀剂。在这项工作中,介绍了一种由新型主要成分制成的高效 ACI 及其与多聚甲醛(PFA)和碘化钾(KI)的协同作用。ACI 是由苄基氯化喹啉衍生物(BQD)的粗产品制备而成,该衍生物由苄基氯和喹啉以简单的方法合成。这种由 BQD、PFA 和 KI 组成的新型 ACI 配方被命名为 "增效吲哚利嗪衍生物混合物"(SIDM),与市售 ACI 相比,具有更高的缓蚀效果(IE)和温度稳定性。更重要的是,SIDM 配方无需使用常用的剧毒增效剂(如丙炔醇和 As2O3)。在 20 wt% 的盐酸 (HCl) 溶液中,添加 0.5 wt% 的 SIDM 可使 N80 钢在 194 °F 时的腐蚀率降低到 0.00564 lbm-ft-2 以下,而在 320 °F 时的腐蚀率为 0.0546 lbm-ft-2(当添加 4.0 wt% SIDM 时)。
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引用次数: 0
Experimental and Simulation Investigation on Ball-Sealer Transport and Diversion Performance Aided by Machine Learning Method 基于机器学习方法的球封机输导性能实验与仿真研究
3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2023-11-01 DOI: 10.2118/218010-pa
Hai Qu, Ying Liu, Chengying Li, Zhijun Zeng, Xu Liu, Zhelun Li
Summary Ball-sealer diversion has been proven to be an effective and economical way to increase fractures and fracturing volume in multistage hydraulic fracturing and matrix acidizing treatments. However, designing and implementing a successful ball-sealer diversion treatment is still challenging. Typically, operators rely on empirical data to determine diversion parameters and need an understanding of accurate ball transport and diversion behaviors. A model for optimizing operating parameters, including fluid and ball properties, and predicting the diversion performance of ball sealers before treatment is needed for designing the fracturing process. In this work, we systematically investigated ball-sealer diversion using experimental and numerical methods. The resolved model of computational fluid dynamics (CFD) and discrete element method (DEM) is first developed to simulate the transport of a large ball in a horizontal wellbore with side holes. The experimental results validated the numerical model. The effects of the ball position in the pipe, flow ratio of the hole to pipe, injection flow rate, and ball density on the diversion performance were studied under field parameters. The results show that the ball sealer easily misses the heel-side perforation due to the inertial effect and travels to the toe side due to the large inertia and turbulent flow. The ball position and flow rate ratio are crucial for the diversion performance. There is a threshold value of the ball position under the specific condition, and the ball successfully turns to the perforation only when the threshold distance is met. A ball sealer closer to the perforation will have a larger probability of blocking the hole than the ball at the other side of the wellbore. The larger the flow rate ratio, the more the drag force on the ball, and the ball can successfully divert to the perforation despite the ball being far from the hole. The injection flow rate and ball density negatively correlate with the diversion performance due to the large inertia and gravity. The best classification result with the F1 score of 87.0% in the prediction set was achieved using the random forest (RF) algorithm. It provides new insight into developing ball sealers and adjusting fracturing parameters based on machine learning (ML) methods.
在多级水力压裂和基质酸化处理中,球密封导流是一种经济有效的增产方法。然而,设计和实施一种成功的密封球转移处理仍然具有挑战性。通常情况下,作业者依靠经验数据来确定导流参数,需要了解准确的球运移和导流行为。在设计压裂工艺时,需要一个优化操作参数的模型,包括流体和球的特性,以及在处理前预测球密封剂的导流性能。在这项工作中,我们采用实验和数值方法系统地研究了球密封转移。首次建立了计算流体力学(CFD)和离散元法(DEM)的解析模型,用于模拟带侧孔的水平井筒中大球的运移。实验结果验证了数值模型的正确性。在现场参数下,研究了球在管内位置、孔管流量比、注入流量和球密度对导流性能的影响。结果表明:由于惯性效应,密封球容易漏过足跟侧的射孔,而由于较大的惯性和紊流,密封球容易向足跟侧移动;球的位置和流量比对导流效果至关重要。在特定条件下,球的位置存在一个阈值,只有满足阈值距离,球才能成功转向射孔。靠近射孔的密封球比位于井筒另一侧的密封球堵塞井眼的可能性更大。流量比越大,对球的阻力越大,即使球离井眼较远,也能成功转向射孔。由于惯性和重力较大,注入流量和球密度与导流性能呈负相关。采用随机森林(RF)算法,预测集F1得分为87.0%,分类效果最好。它为开发球密封器和基于机器学习(ML)方法调整压裂参数提供了新的见解。
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引用次数: 0
Fabrication and Release Mechanism Study of a Nanocapsule Breaker for Controlling Degradation Rate of Insoluble Residue in Slickwater at Moderate-Temperature Reservoirs 控制中温油层滑溜水中不溶性残留物降解速率的纳米破囊剂制备及释放机理研究
3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2023-10-01 DOI: 10.2118/217981-pa
Jingyang Pu, Ming-liang Luo, Kai Wang, Xu Li, Jin-bo Wu, Na Zhang, Yang Zhao, Mingjing Lu
Summary In an ideal hydraulic fracturing project, the viscosity of hydraulic fracturing fluid (HFF) should drop to facilitate an efficient and quick fracture cleanup once proppants have been placed. Ammonium persulfate (APS) is widely used as an oxidizer breaker to degrade the insoluble residue of the HFF. However, a complex network of artificial fractures with sizes ranging from millimeters to micrometers restricts the transportation application and reaction time of standard breakers and current millimeter-sized capsule breakers. In this study, we introduce an APS nanocapsule (APS-NC) breaker, fabricated via a simple miniemulsion technique, that is capable of addressing the degradation of insoluble residue of the HFF in deep fractures. The nanocapsules are produced through precise control of the nanoprecipitation of poly(methyl methacrylate) (PMMA) onto aqueous APS nanodroplets. Stable aqueous nanodroplets are generated by means of an inverse miniemulsion using Pluronic P-123 as a specific surfactant to form a large and stable water-oil internal surface referring to the long chain and amphipathic property of Pluronic P-123 molecule. Pluronic P-123 is included in the process not only to stabilize the miniemulsion and increase the precipitation efficiency of PMMA but also to function as a thermo-responsive switch for the delayed burst release of APS. The size of the resulting nanocapsules can be controlled within the 207 and 821 nm range, yielding APS up to 92%. The release rate of APS can be controlled by the initial amount of PMMA (150–300 mg), environmental temperature (40–80°C), and environmental pH (3.4–7). When the temperature was 80℃, the initial amount of Pluronic P-123 dominated the release dynamic of APS. Compared with the APS breaker in a dynamic degradation experiment, the APS-NC had a more controllable degradation profile that could cause hydrolyzed polyacrylamide (HPAM) to burst degrade after 6 hours of heating at 80°C.
在理想的水力压裂项目中,在注入支撑剂后,水力压裂液(HFF)的粘度应该降低,以促进高效、快速的裂缝清理。过硫酸铵(APS)作为一种氧化剂破断剂被广泛用于降解HFF的不溶性残留物。然而,从毫米到微米大小的复杂人工裂缝网络限制了标准破碎机和目前毫米大小的胶囊破碎机的运输应用和反应时间。在这项研究中,我们介绍了一种APS纳米胶囊(APS- nc)破碎剂,通过简单的微乳液技术制备,能够解决深层裂缝中HFF不溶性残留物的降解问题。这种纳米胶囊是通过精确控制聚甲基丙烯酸甲酯(PMMA)在APS纳米液滴上的纳米沉淀而制成的。利用Pluronic P-123分子的长链和两亲性,以Pluronic P-123为特异性表面活性剂,通过反相微乳液形成稳定的水-油内表面,形成稳定的水-油内表面。Pluronic P-123不仅可以稳定微乳液,提高PMMA的沉淀效率,还可以作为APS延迟爆发释放的热响应开关。所得纳米胶囊的尺寸可以控制在207和821 nm范围内,APS率高达92%。APS的释放速率可由PMMA初始用量(150 ~ 300 mg)、环境温度(40 ~ 80℃)和环境pH(3.4 ~ 7)控制。当温度为80℃时,Pluronic P-123的初始用量主导了APS的释放动态。与动态降解实验中的APS破胶剂相比,APS- nc具有更可控的降解特性,在80℃下加热6小时后,可使水解的聚丙烯酰胺(HPAM)发生爆裂降解。
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引用次数: 0
Development and Optimization of a High-Frequency Axial-Torsional Composite Percussion Drilling Tool for Enhanced Impact Technology 高频轴扭复合冲击钻井工具的研制与优化
3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2023-10-01 DOI: 10.2118/218006-pa
Haili Yang, Yinglin Yang, YueXiang Huang, Hengjing Zhang, Liangliang Xie
Summary A high-frequency axial-torsional composite percussion drilling tool is designed to enhance the drilling efficiency by delivering high-frequency axial and torsional impact loads directly to the drill bit. The impact performance and influencing factors of the tool are analyzed via the large eddy simulation method, and a scaled-down experiment on the pulse nozzle structure is conducted. The analysis reveals that after design optimization, the tool achieves high-frequency axial and torsional impacts of 421 and 284 Hz, respectively, at an inlet flow rate of 30 kg/s. Additionally, the unilateral amplitudes of the axial and torsional impact loads reach 1511 N and 19.3 N·m, respectively, with a pressure drop of 2.998 MPa. Furthermore, the similarity degree between the parameters derived from the experiment and numerical analysis is close to or exceeds 70%, demonstrating the reliability and precision of the numerical analysis results. Overall, this study sets a baseline for high-frequency impact technology, paving the way for further advancements in drilling efficiency.
为了提高钻井效率,设计了一种高频轴向和扭转复合冲击钻井工具,将高频轴向和扭转冲击载荷直接传递到钻头上。通过大涡模拟方法分析了刀具的冲击性能及其影响因素,并对脉冲喷管结构进行了缩小实验。分析表明,优化设计后,在进口流量为30 kg/s的情况下,该工具分别实现了421 Hz和284 Hz的高频轴向和扭转冲击。轴向和扭转冲击载荷的单侧幅值分别达到1511 N和19.3 N·m,压降为2.998 MPa。实验参数与数值分析参数的相似度接近或超过70%,表明了数值分析结果的可靠性和精度。总的来说,该研究为高频冲击技术奠定了基础,为进一步提高钻井效率铺平了道路。
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引用次数: 0
Solution Gas/Oil Ratio Prediction from Pressure/Volume/Temperature Data Using Machine Learning Algorithms 利用机器学习算法从压力/体积/温度数据预测溶液气/油比
3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2023-10-01 DOI: 10.2118/217979-pa
Asia Majid, Grant Charles Mwakipunda, Chaohua Guo
Summary Many methods have been developed to determine the solution gas/oil ratio (Rs), starting with experiments, followed by empirical correlations establishments, and recently with machine learning applications receiving much interest due to their ability to produce precise results compared with empirical correlations. In this paper, the group method of data handling (GMDH) and the enhanced GMDH based on discrete differential evolution (GMDH-DDE) are used for the first time to estimate the Rs and to provide a correlation to the laboratory measured Rs from bubblepoint pressure (Pb), oil API gravity (API), gas-specific gravity (γg), and reservoir temperature (T) without crude oil properties. These two methods are compared with backpropagation neural networks (BPNN). The reason for using the hybrid GMDH (GMDH-DDE) is to overcome the drawbacks of the GMDH, such as the method used to calculate neuron weights (i.e., quadratic polynomial transfer function), which seems to have inaccuracies. Also, in selecting model inputs, the GMDH tends to choose the most appropriate inputs for the model; however, the selection criteria are not straightforward and may affect the final results. Furthermore, the GMDH has a multicollinearity problem, affecting model coefficient stability and overfitting problems, etc. A total of 420 data sets from the Mpyo oil field were used, with 70% used for training and 30% used for testing. According to the findings, the GMDH-DDE outperformed both the GMDH and BPNN. In comparison with the GMDH and BPNN, the GMDH-DDE has a higher correlation coefficient (R), lower root-mean-square error (RMSE), and lower mean absolute error (MAE). During training, R, RMSE, and MAE were 0.9849, 0.090, and 0.010, respectively, and during testing, R = 0.9603, RMSE = 0.290, and MAE = 0.017. The second-best technique (GMDH) produces R, RMSE, and MAE values of 0.9611, 0.122, and 0.032 in training, and R = 0.9438, RMSE = 0.349, and MAE = 0.055 in testing. Furthermore, the GMDH-DDE used less computational time (1.32 seconds) compared with the GMDH (2.01 seconds) and BPNN (4.96 seconds), proving that the GMDH-DDE has accurate and fast convergence compared with the GMDH and BPNN. These findings show that the GMDH-DDE and GMDH can be adopted as alternative methods for predicting the Rs.
已经开发了许多方法来确定溶液气/油比(Rs),从实验开始,然后是经验相关性的建立,最近机器学习应用因其与经验相关性相比能够产生精确的结果而受到广泛关注。本文首次采用分组数据处理方法(GMDH)和基于离散差分演化的改进GMDH (GMDH- dde)来估计Rs,并在不考虑原油物性的情况下,通过气泡点压力(Pb)、原油API比重(API)、气体比重(γg)和储层温度(T)与实验室测量的Rs进行了相关性分析。将这两种方法与反向传播神经网络(BPNN)进行了比较。使用混合GMDH (GMDH- dde)的原因是为了克服GMDH的缺点,例如用于计算神经元权重的方法(即二次多项式传递函数)似乎存在不准确性。此外,在选择模型输入时,GMDH倾向于为模型选择最合适的输入;然而,选择标准并不简单,可能会影响最终结果。此外,GMDH存在多重共线性问题,影响模型系数稳定性和过拟合问题等。总共使用了来自Mpyo油田的420个数据集,其中70%用于训练,30%用于测试。根据研究结果,GMDH- dde优于GMDH和BPNN。与GMDH和BPNN相比,GMDH- dde具有更高的相关系数(R)、更低的均方根误差(RMSE)和更低的平均绝对误差(MAE)。训练时R、RMSE和MAE分别为0.9849、0.090和0.010,检验时R = 0.9603、RMSE = 0.290、MAE = 0.017。次优技术(GMDH)在训练中的R、RMSE和MAE值分别为0.9611、0.122和0.032,在测试中的R = 0.9438、RMSE = 0.349和MAE = 0.055。与GMDH (2.01 s)和BPNN (4.96 s)相比,GMDH- dde的计算时间(1.32 s)更短,证明了GMDH- dde与GMDH和BPNN相比具有准确和快速的收敛性。这些结果表明GMDH- dde和GMDH可以作为预测Rs的替代方法。
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引用次数: 1
Effect of Polishing on Cutting Efficiency and Mechanical Properties of PDC Cutters 抛光对PDC刀具切削效率和机械性能的影响
3区 工程技术 Q1 ENGINEERING, PETROLEUM Pub Date : 2023-10-01 DOI: 10.2118/217997-pa
Jiusen Wei, Wei Liu, Deli Gao, Dameng Guo
Summary Polycrystalline diamond compact (PDC) bits equipped with polished cutters have shown improvements in drilling performance compared to the bits using nonpolished cutters. Despite the positive feedback from numerous global field runs, the merits of polished cutters are still not fully studied and not taken seriously, for example, by the bit manufacturers and drilling engineers in China. In this work, the effect of polishing on the rock-cutting efficiency and mechanical properties of PDC cutters was comprehensively analyzed through laboratory tests and field trials. The underlying mechanism was also investigated through theoretical modeling and experimental results. A rock-cutting force model of a single PDC cutter was developed to elucidate the effect of polishing on the rock-cutter interaction considering the friction between the cutter surface and rock cuttings. The results revealed that the polished cutter has better rock-cutting efficiency because the polishing reduces the friction on the cutter surface. This reduction in friction facilitates the evacuation of rock cuttings from the crushing zone and plastic flow zone, leading to lower mechanical specific energy (MSE) compared to the nonpolished diamond surface. Moreover, the polished cutters exhibit improved thermal stability and better impact fatigue resistance while maintaining comparable wear and impact resistance to nonpolished cutters. To further validate the findings, two field trials were conducted in Sinopec Shengli Oilfield. The first field trial using four PDC bits with polished cutters and one bit with nonpolished cutters found that the bits with polished cutters obtained a higher rate of penetration (ROP) in drilling hard and plastic mudstone, which agreed well with the theoretical and experimental results. In the second field trial, it was noted that the polished cutters presented comparable mechanical properties to nonpolished cutters, which was also consistent with experimental results. However, the advantages of polished cutters in thermal stability and impact fatigue resistance were not distinguished in the field trials. This work elucidated the beneficial effect of polishing in enhancing the drilling efficiency of PDC cutters and, more meaningfully, without sacrificing the mechanical properties of PDC cutters, which provided solid evidence to convince bit manufacturers and drilling engineers for the broader adoption of polished cutters.
与使用未抛光切削齿的钻头相比,配备抛光切削齿的PDC钻头的钻井性能得到了改善。尽管在全球范围内进行了大量的现场测试,得到了积极的反馈,但抛光切削齿的优点仍然没有得到充分的研究和重视,例如,中国的钻头制造商和钻井工程师。通过室内试验和现场试验,综合分析了抛光对PDC切削齿岩石切削效率和力学性能的影响。通过理论建模和实验结果对其机理进行了探讨。建立了单个PDC切削齿的岩石切削力模型,考虑了切削齿表面与岩屑之间的摩擦,阐明了抛光对岩屑相互作用的影响。结果表明,抛光后的刀具由于减少了刀具表面的摩擦,具有更好的岩石切削效率。摩擦的减少有助于岩屑从破碎区和塑性流动区排出,与未抛光的金刚石表面相比,机械比能(MSE)更低。此外,抛光后的切削齿表现出更好的热稳定性和更好的抗冲击疲劳能力,同时保持与未抛光切削齿相当的磨损和抗冲击性。为了进一步验证这些发现,在中石化胜利油田进行了两次现场试验。第一次现场试验使用了4台PDC钻头和1台非抛光钻头,结果发现,在钻硬质和塑性泥岩时,使用抛光钻头的钻头获得了更高的钻速(ROP),这与理论和实验结果吻合得很好。在第二次现场试验中,经过抛光的切削齿与未经抛光的切削齿具有相当的机械性能,这也与实验结果一致。然而,在现场试验中,抛光切削齿在热稳定性和抗冲击疲劳方面的优势并没有得到明显的体现。这项工作阐明了抛光在提高PDC切削齿的钻井效率方面的有益作用,更重要的是,在不牺牲PDC切削齿机械性能的情况下,这为说服钻头制造商和钻井工程师更广泛地采用抛光切削齿提供了坚实的证据。
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引用次数: 0
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