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Carbon Monoxide Concentrations in Kitchens of Gas-fired Burners, Karachi, Pakistan 煤气燃烧器厨房的一氧化碳浓度,卡拉奇,巴基斯坦
Pub Date : 2022-02-22 DOI: 10.52763/pjsir.phys.sci.65.1.2022.25.32
Z. Shams, T. Javed, A. Zubair, M. Waqas, S. Ali, Anusha Ahmed
In this study, gas-fired kitchens of 54 bungalows and 25 apartments were studied using stationary indoor carbon monoxide (CO) monitoring. The levels of CO were measured in each kitchen for a period of 24 h with a 1 min resolution using data logger EL-USB-CO300. Hourly, 8 h and 24 h, CO means for all the kitchens were calculated. Hourly and 24 h CO means of kitchens for bungalows were 3.72±6.26 ppm and 3.72±3.16 ppm, respectively, while those apartments have 3.74±6.96 ppm and 3.74±2.17 ppm, respectively. 8 h CO means of night, day and evening in the kitchens of bungalows were 2.62±3.22 ppm, 4.85±4.66 ppm and 3.53±3.30 ppm, respectively, while in apartments 2.13±2.02 ppm, 3.79±3.86 ppm and 5.29±4.17 ppm. The mean difference between the 8 h CO concentrations during the evening in bungalows and apartments was 1.76±0.87 ppm (P<0.01). 20% of kitchens apartment and 16.67% of bungalows which exceeded the WHO guidelines for daily exposure limit.
在这项研究中,使用固定式室内一氧化碳(CO)监测仪对54间平房和25间公寓的燃气厨房进行了研究。使用EL-USB-CO300数据记录仪以1分钟分辨率测量每个厨房内24小时的CO水平。每小时,8小时和24小时,计算所有厨房的CO平均值。平房厨房每小时和24小时的CO平均值分别为3.72±6.26 ppm和3.72±3.16 ppm,而公寓厨房的CO平均值分别为3.74±6.96 ppm和3.74±2.17 ppm。平房厨房8 h CO均值夜间、白天和晚上分别为2.62±3.22 ppm、4.85±4.66 ppm和3.53±3.30 ppm,公寓厨房8 h CO均值分别为2.13±2.02 ppm、3.79±3.86 ppm和5.29±4.17 ppm。平房与公寓夜间8 h CO浓度的平均差异为1.76±0.87 ppm (P<0.01)。20%的厨房公寓和16.67%的平房超过了世界卫生组织的每日接触限值。
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引用次数: 2
Cadmium Investigations in Lahore Soil and Other Regions of Pakistan 巴基斯坦拉合尔及其他地区土壤镉调查
Pub Date : 2022-02-22 DOI: 10.52763/pjsir.phys.sci.65.1.2022.64.73
Sheikh Asrar Ahmad, S. Hussain, Hina Aziz, Muhammad Riaz
Cadmium (Cd) is toxic even in the very trace amounts and shows adverse effects on the human being and his environment. Current studies were performed to evaluate the Cd concentration in soil of Lahore (Pakistan) and the results were compared with those reported from other cities of Pakistan. The metal concentration evaluated by graphite furnace atomic absorption spectrometer (GFAAS). Cd concen- tration was found to be 1.39-20.82 µg/L, 1.38-93.60 µg/L, 2.42-94.60 µg/L, 2.25-93.98 µg/L and  1.15-8.14 µg/L in GT road, Misri shah, river Ravi, fertilized land of Raiwind side and unfertilized land of Raiwind side, respectively. The higher Cd concentration (2.42-94.60 µg/L) at "River Ravi" as compared to the other investigated areas (1.15-93.98 µg/L) is owed to the dumping of untreated waste from all  industrial, sewage, domestic and agricultural zones in "River Ravi". The fertilized land was found to possess higher amount of Cd as compared to the unfertilized land. The awareness in farmers and the  periodic monitoring of soil are important to eradicate the sources of Cd poisoning.    
即使是极微量的镉(Cd)也是有毒的,并对人类及其环境产生不利影响。目前对巴基斯坦拉合尔土壤镉浓度进行了评价,并与巴基斯坦其他城市报告的结果进行了比较。用石墨炉原子吸收光谱仪(GFAAS)测定了金属的浓度。GT公路、Misri shah、Ravi河、雨风侧施肥地和雨风侧未施肥地的Cd浓度分别为1.39 ~ 20.82µg/L、1.38 ~ 93.60µg/L、2.42 ~ 94.60µg/L、2.25 ~ 93.98µg/L和1.15 ~ 8.14µg/L。“拉维河”的Cd浓度(2.42-94.60µg/L)高于其他调查地区(1.15-93.98µg/L),这是由于在“拉维河”倾倒了来自所有工业、污水、家庭和农业区的未经处理的废物。研究发现,与未施肥土地相比,施肥土地具有更高的Cd含量。提高农民的认识和定期监测土壤对消除镉中毒的来源是很重要的。
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引用次数: 0
Treatment of Sugarcane Industry Waste Water by Combination of Chemical Coagulation and Activated Carbon 化学混凝-活性炭联合处理甘蔗工业废水
Pub Date : 2022-02-22 DOI: 10.52763/pjsir.phys.sci.65.1.2022.59.63
A. Panhwar, Khalida Faryal, A. Kandhro, N. Brohi, Kamran Ahmed, Mansoor Iqbal
The study was designed to treat the effluent from sugarcane sector. The use of fresh water in sugarcane industry and result huge amount of waste water is not a secret to anyone. The use of chemicals in large quantities has caused a great risk and damage to the groundwater, soil, and aquaculture and ultimately leads to the destruction of our environment. Treatment of industrial sugarcane wastewater is not an easy task it has becomes a challenging task for environmental scientist. The purpose of our study is treatment, time saving and reuse for irrigation purpose. Coagulation with alum, ferric chloride, ferrous sulphate with combination of activated charcoal technique was used. The results of the study disclosed that COD and BOD were in huge amount and were successfully treated. Results of COD and BOD removal efficiencies were 51 and 28 mg/L, 76 and 42 mg/L, 90 and 52 mg/L by using alum, ferric chloride and ferrous sulphate respectively with combination of activated charcoal. After treatment, the effluent was very clear and met the requirements of National Environmental Quality Standards. Subsequently, using coagulation with combination of adsorption technique proved very effective, time saving, harmless technique for  industrial sugarcane wastewater treatment.  
本研究旨在处理甘蔗生产废水。甘蔗工业使用淡水,产生大量的废水,这已经不是什么秘密了。化学品的大量使用对地下水、土壤和水产养殖造成了巨大的风险和破坏,最终导致了我们环境的破坏。工业甘蔗废水的处理不是一件容易的事情,它已经成为环境科学家面临的一项具有挑战性的任务。我们研究的目的是处理,节省时间和再利用灌溉目的。采用明矾、氯化铁、硫酸亚铁混凝,结合活性炭技术进行混凝。研究结果表明,COD和BOD量大,处理成功。明矾、氯化铁和硫酸亚铁复合活性炭对COD和BOD的去除率分别为51和28 mg/L、76和42 mg/L、90和52 mg/L。经处理后,出水水质清澈,达到国家环境质量标准要求。经实践证明,混凝与吸附相结合处理工业甘蔗废水是一种高效、省时、无害化的工艺。
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引用次数: 0
Manufacturing of Electrochemical Cell and Enhanced its Efficiency by Adding Additive in Electrolyte 电解液中添加添加剂制备电化学电池及提高电池效率
Pub Date : 2022-02-22 DOI: 10.52763/pjsir.phys.sci.65.1.2022.9.24
Rizwan Qamar, A. Mushtaq, A. Ullah, Zaeem Uddin Ali
The importance of a lead-acid battery in our daily life needs no explanation. Automotive batteries in their dominant part were made with hard rubber holders and heavy plates and the service life was two years. On the other hand, in stationary batteries, open Planet style cells were still being used and got an additional arrangement of positive plates once the primary set was exhausted. The world has improved significantly from that point forward, both in structure and innovation. Still, the lead-corrosive battery for rechargeable frameworks has not changed, despite there is no indication that it tends to be supplanted close to term by secondary battery framework. So, it is advantageous to take a gander at enhancements in the innovation of battery creation that have occurred essentially in the course of the most recent ten years. Thyristor innovation and micro-processor control take into account strategies that one could dream about in previous times. From a car battery to a UPS inverter, we daily need the services of a lead-acid battery. Considering these aspects, the current research is an effort to provide such solutions so, that the working life of the lead-acid battery increases by not increasing its manufacturing cost. It was found that the two added substances methane sulfonic acid (MSA) and aminomethyl sulfonic acid (AMSA) to lead-acid batteries can enhance the electro-chemical performance and thermal stability of which MSA shows the best impact.  
铅酸电池在我们日常生活中的重要性无需解释。汽车电池的主体部分采用硬质橡胶支架和厚板,使用寿命为两年。另一方面,在固定电池中,开放式行星式电池仍然被使用,一旦主组耗尽,就会有额外的正极板排列。从那时起,世界在结构和创新方面都有了显著改善。尽管如此,用于可充电框架的铅腐蚀电池并没有改变,尽管没有迹象表明它倾向于被二次电池框架取代。因此,我们有必要研究一下近十年来在电池制造方面取得的进步。晶闸管创新和微处理器控制考虑到以前人们可以梦想的策略。从汽车蓄电池到UPS逆变器,我们每天都需要铅酸蓄电池的服务。考虑到这些方面,目前的研究就是在不增加铅酸电池制造成本的情况下,提供这样的解决方案,从而提高铅酸电池的使用寿命。结果表明,在铅酸电池中添加甲烷磺酸(MSA)和氨基甲基磺酸(AMSA)两种物质均能提高铅酸电池的电化学性能和热稳定性,其中MSA的影响最大。
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引用次数: 0
Vortex-Assisted and Cloud Point Extraction of Cadmium, Lead, Copper and Zinc in Different Personal Care Product Samples 漩涡辅助和云点萃取不同个人护理产品样品中的镉、铅、铜和锌
Pub Date : 2022-02-22 DOI: 10.52763/pjsir.phys.sci.65.1.2022.33.40
K. M. Malik, Mahboob Ali Rind, N. Jalbani, A. Panhwar, Shahid Bhutto, Iftikhar Ahmed, Amber . Rasheed, D. R. Hashmi, Humaira Khan
A rapid vortex assisted-cloud point extraction (VA-CPE) method was developed to separate cadmium (Cd), copper (Cu), zinc (Zn) and lead (Pb) in accordance with important parameters. Cd and Pb was determined in personnel care products (PCPs) by Electrothermal Atomic Absorption Spectrometry (ETAAS), however Cu and Zn was determined by Flame Atomic Absorption Spectrometry (FAAS). Triton X-100 and xylenol orange were used as a chelating agent. The important factors including pH, Ligand Volume (LV), Vortex Time (Vt), Centrifuge Time (Ct), Centrifuge (rpm) and volume of Triton X-100 as well as volume of chloroform and concentration of surfactant were optimized. The Certified Reference Material (CRM) (wheat flour-1567 a) and standard addition recovery test was used to analyze the accuracy of proposed method. Detection limits (LODs) of metals like, Cd, Pb, Cu and Zn were 0.001 mg/L, 0.01 mg/L, 0.05 mg/L and 0.1 mg/L respectively. The method has been successfully applied to real samples.
建立了一种快速涡辅助云点萃取(VA-CPE)方法,根据重要参数分离镉(Cd)、铜(Cu)、锌(Zn)和铅(Pb)。采用电热原子吸收光谱法(ETAAS)测定个人护理用品(pps)中的Cd和Pb,采用火焰原子吸收光谱法(FAAS)测定Cu和Zn。采用Triton X-100和二甲酚橙作为螯合剂。对pH、配体体积(LV)、涡流时间(Vt)、离心时间(Ct)、离心机转速(rpm)、Triton X-100体积以及氯仿体积和表面活性剂浓度等重要因素进行了优化。采用标准物质(CRM)(小麦粉- 1567a)和标准添加回收率试验对该方法的准确度进行了分析。镉、铅、铜、锌的检出限分别为0.001 mg/L、0.01 mg/L、0.05 mg/L和0.1 mg/L。该方法已成功地应用于实际样品。
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引用次数: 2
Significance and Role of Industrial Inputs in Productivity of Large-scale Manufacturing in Karachi: A Correlation Analysis 工业投入对卡拉奇大规模制造业生产率的意义与作用:一个相关分析
Pub Date : 2022-02-22 DOI: 10.52763/pjsir.phys.sci.65.1.2022.80.86
M. Iqbal, G. Mahar
In an industrial process, productivity is a basic concern. A combination of production input, namely employment, labour cost, energy and raw material cost, result in value addition expressed as value- added. The effective role of each input in the manufacturing process can be assessed through the influence of variables involved. Pearson's correlation coefficients show various degrees of effects through interrelationships of variables and bring out the outstanding or relatively more important role of one or more variables (inputs) in specific combinations in the manufacturing process. The paper in hand analyses the interrelationship of structuring variables in the major groups of manufacturing in Karachi using Pearson's correlation measurement techniques. The role of the variables has been assessed through sets of ten correlations in each of the six major industrial categories. The results of the analyses show the leading or the dominant contribution of the variables towards value addition and productivity. In the case of the textile industry, strong correlations are indicated between Value Added (VA) and 'Other Cost' (OC) and Average Daily Employment (ADE) and Employment Cost (EC) and also VA and ADE. For chemical and chemical products strong correlation exist between VA and OC, OC and IC (industrial cost) and ADE and EC. In respect of the wearing apparel category, a strong correlation occur between OC and IC, VA and OC, ADE and EC. Basic metal industry shows strong correlation in all ten sets of relationships, thus every variable exercising an equal influence. The food and beverage group has only two strong correlations that are VA and OC, IC, and OC. In the case of motor vehicles and trailers, strong relationships are indicated by all sets of correlation ship.  
在工业生产过程中,生产率是一个基本问题。生产投入,即劳动力成本、劳动力成本、能源成本和原材料成本的组合,产生增加值,表示为增加值。每个输入在制造过程中的有效作用可以通过所涉及的变量的影响来评估。皮尔逊相关系数通过变量之间的相互关系表现出不同程度的影响,并揭示出一个或多个变量(输入)在制造过程中特定组合中的突出或相对更重要的作用。本文利用Pearson的相关测量技术分析了卡拉奇主要制造业群体中结构变量的相互关系。通过六个主要工业类别中每一个的十组相关性来评估变量的作用。分析结果显示了变量对附加值和生产率的主导或主导贡献。就纺织行业而言,增加值(VA)和“其他成本”(OC)、平均每日就业(ADE)和就业成本(EC)以及VA和ADE之间存在很强的相关性。对于化工产品而言,VA与OC、OC与IC(工业成本)、ADE与EC之间存在很强的相关性。就穿着服装类别而言,OC与IC、VA与OC、ADE与EC之间存在很强的相关性。基础金属工业在所有十组关系中都表现出很强的相关性,因此每个变量的影响都是相等的。食品和饮料组只有两个强相关性,即VA和OC, IC和OC。在机动车和挂车的情况下,强关系由所有相关船的集合表示。
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引用次数: 0
Solar De-salination of Water 太阳能脱盐水
Pub Date : 2022-02-22 DOI: 10.52763/pjsir.phys.sci.65.1.2022.41.46
Rizwan Qamar, A. Mushtaq, A. Ullah, Zaeem Uddin Ali
Water is one of the most vital substances on Earth. Sustainment of life on this planet depends greatly on the availability of water. Water consumption is used not only for drinking but for purposes like agricultural irrigation, industrial raw material and domestic household purposes. Hence, the quality of water is an important matter. Solar de-salination is a technique that uses the Sun's radiant energy to de- salinate water. Due to its energy requirement, de-salinating seawater is generally more costly than freshwater, water obtained through bore wells also called Brackish water from rivers or groundwater. However, these sources may not be available in most of the places, like barren lands or may not be easily extractable, maybe even not a sustainable long term solution. The technique selected based on the evapouration and condensation rates to increase the efficiency, one must implement measures to enhance the evapouration and condensation rates of the capability. De-salination is a costly process majorly depending on its high energy requirements when as input power the whole system of de-salination either as fuel and electricity, following the century old traditions, modern day engineers have come up with a solution of harvesting the Sun's energy, hence the advent of solar de-salination of water.    
水是地球上最重要的物质之一。这个星球上生命的维持在很大程度上取决于水的可用性。水的消耗不仅用于饮用,还用于农业灌溉、工业原料和家庭用途。因此,水的质量是一个重要的问题。太阳能脱盐是一种利用太阳辐射能使水脱盐的技术。由于其能源需求,脱盐海水通常比淡水更昂贵,淡水是通过钻孔获得的水,也称为从河流或地下水中获得的微咸水。然而,这些资源在大多数地方可能无法获得,比如贫瘠的土地,或者可能不容易提取,甚至可能不是一个可持续的长期解决方案。在选择基于蒸发和冷凝速率的技术来提高效率的同时,必须实施提高蒸发和冷凝速率能力的措施。脱盐是一个昂贵的过程,主要取决于它的高能量需求,当整个脱盐系统作为燃料和电力的输入动力时,遵循一个世纪以来的传统,现代工程师已经提出了一种收集太阳能的解决方案,因此出现了太阳能脱盐水。
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引用次数: 0
Enhancement of Physico-chemical and Biological Activities of Antibiotic Cephradine by Gamma Irradiation 伽马辐射增强抗生素头孢定的理化和生物活性
Pub Date : 2022-02-22 DOI: 10.52763/pjsir.phys.sci.65.1.2022.1.8
S. Raza, Sikandar Khan, Ata-ur- Rahman, M. Raza, F. Wahid
Radiation based sterilization is a common tool for microbial inactivation in different products on a commercial scale. The objective of the current study was to determine the effect of gamma radiation on cephradine antibiotic in the solid-state to enhance its biological response. Cephradine drug in powder form was treated with different doses (25, 50, 75, 100 and 125 kGy) of the cobalt-60 source in a Gamma cell-220 at a current rate of 8.5 gray/h. The effect of radiation doses on antibiotic was assessed with the help of different analytical techniques such as FT-IR, UV, XRD, SEM and HPLC. The UV spectra of radiated cephradine show some changes in the absorption peak by increasing the intensity of radiations while only slight changes were observed in the other peaks. The crystallinity of antibiotics was tested by the XRD and SEM, it shows a little morphological change. The FT-IR data disclosed significant changes in the absorption bands. The HPLC analysis showed reports an insignificant change which revealed that the radiolytic products are not formed. The radiated cephradine exposes a remarkable antibacterial activity against bacteria; indicating the enhancement of a biological response. In summary, a slight change was observed in cephradine drug with the radiation but the drug was chemically stable.    
辐射灭菌是商业规模上不同产品中微生物灭活的常用工具。本研究的目的是确定伽马辐射对固态头孢定抗生素的影响,以增强其生物反应。用不同剂量(25、50、75、100和125 kGy)的钴-60源在Gamma cell-220中以8.5 gray/h的电流速率处理粉末形式的头孢定药物。采用FT-IR、UV、XRD、SEM、HPLC等分析技术评价了不同剂量的辐射对抗生素的影响。辐射后的头孢定紫外光谱显示,随着辐射强度的增加,吸收峰发生了一些变化,而其他峰变化不大。通过x射线衍射(XRD)和扫描电镜(SEM)对抗生素的结晶度进行了测试,发现抗生素的结晶度发生了微小的形态变化。FT-IR数据揭示了吸收带的显著变化。HPLC分析显示无明显变化,表明未形成放射性溶解产物。经辐射的头孢定对细菌具有显著的抗菌活性;表明生物反应增强的。综上所述,头孢定药物随辐射有轻微变化,但化学性质稳定。
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引用次数: 0
Effects of Nodes Mobility on the Energy Consumption of Routing Protocols (AODV, DSDV) in Adhoc Networks Adhoc网络中节点移动性对路由协议(AODV, DSDV)能耗的影响
Pub Date : 2022-02-22 DOI: 10.52763/pjsir.phys.sci.65.1.2022.74.79
Muhammad Sadiq, Abdul Majid, A. Naveed, Muhammad Arif, M. Asif, A. Khattak
 Provision of routing mechanism is the elemental concern in adhoc networks. Various routing protocols have been devised and are in use. Quest for the best is in progress and have highlighted certain limitations associated to every protocol. Assessments of routing protocols by their performance in the usage of bandwidth, route selection, delay, packet delivery ratio and throughput have been the main concerns for researchers. Mobility of nodes is a very charming characteristic of adhoc networks, however, it has an allied issue that its nodes are mostly limited battery powered. Routing protocols have a definite influence on the overall energy consumption of the nodes. Energy consumption is an equally important concern to be addressed in evaluating the existing or developing new routing protocols. This research will evaluate two well-known routing protocols AOVD and DSDV on basis of energy consumption. The affects of nodes mobility on the energy consumption levels of these routing protocols will remain the main focus. All the simulations will be made in NS 2.35, and will have these two different scenarios i.e. adhoc network with static nodes and adhoc network with mobile nodes.  
路由机制的提供是自组网中最基本的问题。各种路由协议已经被设计出来并正在使用。对最佳的追求正在进行中,并强调了与每种协议相关的某些限制。路由协议在带宽使用、路由选择、延迟、分组传送率和吞吐量方面的性能评估一直是研究人员关注的主要问题。节点的移动性是自组织网络的一个非常迷人的特征,然而,它有一个相关的问题,即它的节点大多是有限的电池供电。路由协议对节点的总能耗有一定的影响。在评估现有路由协议或开发新的路由协议时,能源消耗是一个同样重要的问题。本研究将基于能量消耗来评估两种知名的路由协议AOVD和DSDV。节点移动性对这些路由协议能耗水平的影响仍将是研究的重点。所有的模拟都将在NS 2.35中进行,并且会有两种不同的场景,即带有静态节点的自组网和带有移动节点的自组网。
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引用次数: 0
Manufacturing of Small Scale Water Treatment Plant for Household 小型家用水处理厂的制造
Pub Date : 2022-02-22 DOI: 10.52763/pjsir.phys.sci.65.1.2022.47.58
Rizwan Qamar, A. Mushtaq, A. Ullah, Zaeem Uddin Ali
Water is one of the essential resources in the world. Without water, the world cannot survive. Earth is covered by 71% water and 2.5 % coverd by freshwater. Out of 7 billion peoples, only 1.2 billion peoples are getting fresh water for drinking. The scarcity of water exerts strong effects around the world. The world is working to develop appropriate, cost-effective methods to provide high purified water for drinking purposes. Water contains suspended particles, micro-organisms, bacteria, organic and inorganic compounds as impurities. For purification, lots of methods are available which are widely used all around the world. This research is based on the research and development of water treatment plants which is cost- effective and provides safe drinking water for household purposes. Solar de-salination is one of the best energy efficient methods used for water treatment. In this process, solar energy is utilized to purify saline water. Minerals and salts were quickly removed as a brine solution and vapors condensed and collected to get the product. The energy requirement is low as compare to other methods. The construction of the plant was simple and cheap. This process removes 99.5 % of salts from the water. This research is successful in achieving the objectives and goals of getting potable water that meets the standards of WHO. This research also focuses on a large scale for water treatment as it is cost-effective and can reduce the shortage of freshwater around the world.
水是世界上必不可少的资源之一。没有水,世界就无法生存。地球上71%是水,2.5%是淡水。在70亿人口中,只有12亿人有淡水饮用。水的短缺在世界各地产生了强烈的影响。世界正在努力发展适当的、具有成本效益的方法,以提供高纯净水供饮用。水中含有悬浮颗粒、微生物、细菌、有机和无机化合物等杂质。对于净化,有许多方法可供选择,这些方法在世界各地广泛使用。本研究的基础是研究和开发具有成本效益的水处理厂,为家庭提供安全的饮用水。太阳能脱盐是水处理中最节能的方法之一。在这个过程中,利用太阳能净化咸水。矿物质和盐作为卤水溶液被迅速除去,蒸汽被冷凝和收集以得到产品。与其他方法相比,能量需求低。工厂的建设简单而廉价。这个过程从水中去除99.5%的盐。这项研究成功地实现了获得符合世卫组织标准的饮用水的目标。这项研究还侧重于大规模的水处理,因为它具有成本效益,可以减少世界各地的淡水短缺。
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引用次数: 0
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