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Influence of the M and M’ Metals on the Carbides Population in As-Cast M’-based Alloys Designed to be MC-Strengthened M和M′金属对铸态mc强化M′基合金中碳化物数量的影响
Pub Date : 2019-04-19 DOI: 10.30564/JMMR.V2I1.604
P. Berthod
High temperature applications such as turbine blades for aeronautics or molten glass-shaping tools require the use of refractory metallic materials. Among the later ones, cast superalloys based on some transition metals and reinforced by MC carbides stay in good place and their metallurgy merits to be well known. This work consists in a general exploration of the as-cast microstructures which can be obtained after solidification and solid state cooling down to ambient temperature for a wide series of alloys for which the base element and the MC-former element both vary. For fixed contents in chromium and carbon contents, the compositions of a total of nineteen alloys were considered. These alloys are based on Ni, Co, Fe or Nb and the M content was each time chosen to favor the appearance of TiC, TaC, NbC, HfC or ZrC, as single carbide in a given alloy. After elaboration, metallographic samples were observed by electron microscopy to investigate the obtained microstructures. The obtained results show first that the MC carbides were in many cases successfully obtained at the expense of other possible carbides (for all Co-based alloys for example) but there are also several exceptions (notably for some Ni-based alloys). Second, the obtained monocarbides have a eutectic origin and they are script-liked shaped. However they are here too some exceptions, as the rare HfC obtained in a Nb-base). In general, the results obtained in this work show that the principle of dendritic matrix combined with MC carbides with a script-like morphology is not necessarily obtained: the nature of the {base element, MC-former element} combination governs the microstructure of the alloy in its as-cast state for these particular  compositions in chromium and carbon. In some cases other carbides may appear and the microstructures may be even of another type.
高温应用,如航空涡轮叶片或熔融玻璃成型工具需要使用耐火金属材料。其中以某些过渡金属为基体,以MC碳化物为增强材料的铸造高温合金保存完好,其冶金优点是众所周知的。这项工作包括对多种合金在凝固和固态冷却到环境温度后可以获得的铸态显微组织的一般探索,这些合金的基本元素和MC-former元素都是不同的。对于固定的铬含量和碳含量,共考虑了19种合金的成分。这些合金以Ni, Co, Fe或Nb为基础,每次选择的M含量有利于TiC, TaC, NbC, HfC或ZrC在给定合金中作为单一碳化物出现。精加工后,用电子显微镜观察金相样品,以研究得到的显微组织。获得的结果首先表明,在许多情况下,MC碳化物是在牺牲其他可能的碳化物(例如所有co基合金)的情况下成功获得的,但也有一些例外(特别是某些ni基合金)。其次,所制得的单碳化物具有共晶起源,且呈脚本状。然而,这里也有一些例外,如在nb碱中获得的罕见的HfC)。总的来说,本工作的结果表明,枝晶基体与具有脚本状形貌的MC碳化物结合的原理并不一定得到:对于铬和碳中这些特定成分,{碱元素,MC原元素}组合的性质决定了合金在铸态时的显微组织。在某些情况下,可能出现其他碳化物,甚至可能是另一种类型的微观结构。
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引用次数: 0
Health Risks of Trace Metals in Wastewater-Fed Fishes: A Case Study 废水养殖鱼类中微量金属的健康风险:个案研究
Pub Date : 2019-04-19 DOI: 10.30564/JMMR.V2I1.540
A. Katip
In this study, the usage wastewater from secondary treatment in feeding fishes of Carassius gibelio species and suitability of the fishes for human food were evaluated. The metals (Ag, Al, As and B) in treated effluent and skeleton, skin, eyes and brain tissues of fishes were examined seasonally. It was found that treated effluent was not suitable for irrigation and aquaculture in terms of Al according to the Turkish standard values. According to annual averages the size order of Ag and B concentrations were skeleton> skin> eyes>brain and skeleton> skin>brain>eye respectively. Also, skin>brain>eyes>skeleton was for As and Al.   TF (Transfer Factor) values of all metals examined were determined as >1 in the four tissues and the metals caused bioaccumulation because of treated effluent. Concentrations in muscles were found 7 to 6227 times higher than in water. The size order of TF and BCF (Bio-concentration Factor) values in skin and eye tissue were the same and it was Ag>Al>As>B. It was Ag>Al>As>B in skeleton, Al>As>Ag>B in brain. HQ (Hazard Quotient) of Al in all tissues had carcinogenic risk level.
本研究对异育银鲫(Carassius gibelio)饵料二次处理后的使用废水及其对人类食用的适宜性进行了评价。对处理后的出水及鱼的骨骼、皮肤、眼睛和脑组织中的金属(Ag、Al、As和B)进行了季节性检测。根据土耳其标准值,经处理的流出物不适合用于灌溉和水产养殖。按年平均值计算,银和B的浓度大小依次为骨骼>皮肤>眼睛>脑和骨骼>皮肤>脑>眼。砷和铝的富集顺序为皮肤>大脑>眼睛>骨骼。四种组织中所有金属的TF(传递因子)值均>1,且金属因处理过的废水而引起生物富集。肌肉中的浓度是水中的7到6227倍。皮肤和眼组织中TF和BCF值大小顺序相同,为Ag>Al>As>B。骨骼表现为Ag>Al>As>B,脑组织表现为Al>As>Ag>B。所有组织中Al的危害系数HQ均为致癌危险水平。
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引用次数: 0
Hot Cracking Susceptibility of 800H and 825 Nickel-Base Superalloys during Welding via Spot Varestraint Test 现场变应变试验研究800H和825镍基高温合金焊接时的热裂敏感性
Pub Date : 2019-04-19 DOI: 10.30564/JMMR.V2I1.958
Chih-Chun Hsieh
Hot cracking susceptibility of fillers 52 and 82 in 800H and 825 nickel-base superalloys was discussed using the Spot Varestraint test. The fillers of 52 and 82 were added into nickel-base superalloys via a gas tungsten arc welding (GTAW).Experimental results showed that the hot cracking sensitivity of the nickel-base superalloys with filler at high temperature was lower than that without filler. The hot cracking sensitivity had a slight effect when the filler 82 was added. The total length of crack was increased, the liquid-solid (L-S) two-phase range is higher so that the hot cracking susceptibility will be raised. The morphologies of cracks included the intergranular crack in the molten pool, molten pool of solidification cracking, heat-affected zone of intergranular cracks, and transgranular crack in the heat-affected zone.
采用现场变应变试验研究了填料52和82在800H和825镍基高温合金中的热裂敏感性。采用钨气弧焊将52和82填料加入到镍基高温合金中。实验结果表明,添加填料的镍基高温合金在高温下的热裂敏感性低于未添加填料的镍基高温合金。添加填料82对热裂敏感性影响不大。裂纹总长度增大,液固两相(L-S)范围增大,热裂敏感性提高。裂纹形态包括熔池沿晶裂纹、熔池凝固裂纹、沿晶裂纹的热影响区和热影响区的穿晶裂纹。
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引用次数: 3
Study on the tensile and the fatigue behavior of air plasma sprayed YSZ TBC systems 空气等离子喷涂YSZ TBC系统的拉伸和疲劳性能研究
Pub Date : 2019-01-22 DOI: 10.30564/JMMR.V1I1.452
Dipak Kumar
AbstractThermal barrier coating (TBC) system composing of bond coat, having two different metallic bond coating materials such as NiCoCrAlY and CoNiCrAlY, and top coat, 8YSZ (8 wt%Y2O3-ZrO2) ceramic coating was deposited on aluminum-based alloy by atmoshpheric plasma spray (APS). Fatigue test and tensile test both was performed for TBC sample. The tensile test and fatigue, both results showed that that fracture occurred in 8YSZ coating near the interface of ceramic-bond coating. These lead to the formation of weak inter-bonding strength and the failure of APS 8YSZ TBC. Moreover, in order to better understand the failure process, a deposition mechanism of coating was proposed. Experimental observations of the failed specimens subjected to tensile as well as fatigue loading showed that the coating cracking and spallation processes were different. Tensile results highlighted the different fracture mode and crack propagation up to macroscopic failure. 
摘要采用大气等离子喷涂(APS)技术,在铝基合金表面沉积了由NiCoCrAlY和CoNiCrAlY两种不同金属结合层和面层组成的8YSZ (8wt %Y2O3-ZrO2)陶瓷涂层。对TBC试样进行了疲劳试验和拉伸试验。拉伸试验和疲劳试验结果表明,8YSZ涂层在陶瓷结合层界面附近发生断裂。这些导致APS 8YSZ TBC形成弱的间键强度和破坏。此外,为了更好地了解涂层的失效过程,提出了涂层的沉积机理。破坏试样在拉伸和疲劳载荷作用下的实验观察表明,涂层开裂和剥落过程是不同的。拉伸结果显示了不同的断裂模式和裂纹扩展直至宏观破坏。
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引用次数: 3
Metal Swarf and Cutting Fluid Waste Management in Metal Processing Industry 金属加工行业的金属屑和切削液废弃物管理
Pub Date : 2019-01-22 DOI: 10.30564/JMMR.V1I1.431
N. K. Salihoglu, Z. Amin, Çagla Celikli
Metal swarf is unavoidable material in metal processing industry, also metal swarf treatment lead to cost savings by metal waste reduction and removing the cutting fluid waste, that cause to increasing process stability and metal value. It is interested that in how to recycle metal swarf especially when swarf surrounded by cutting fluid, is considered because these waste are classified as hazardous waste. The aim of the study is to increase the process efficiency and environmental performance by metal waste reduction at source which are the first step of the waste hierarchy. The results of the experiments showed that 3391 tons of metal swarf coated with cutting fluids which contained 2.29% cutting fluid be produced annually. It has been found that if the total amount of cutting fluid on the swarf surface be reduced to less than 1% leads to a significant mass reduction in the amount of hazardous waste. In this research, it was considered, 107,922 USD profit at the end of first year and 205,278 USD at the end of second year would be obtained by reducing the cutting fluid content from 2.29% to 0.8% with using cutting fluid that surrounded metal swarf separation equipment in manufacturing location.
金属屑是金属加工业中不可避免的材料,金属屑处理通过减少金属废料和去除切削液废料来节省成本,从而提高工艺稳定性和金属价值。由于金属屑被归类为危险废物,因此有兴趣考虑如何回收金属屑,特别是被切削液包围的金属屑。该研究的目的是提高工艺效率和环境绩效,从源头上减少金属废物,这是废物层次结构的第一步。试验结果表明,该工艺每年可生产切削液含量为2.29%的金属屑3391吨。研究发现,如果切屑表面的切削液总量减少到1%以下,则会导致危险废物量的显著减少。本研究认为,在制造地点使用金属屑分离设备周围的切削液,将切削液含量从2.29%降低到0.8%,第一年年底利润为107,922美元,第二年年底利润为205,278美元。
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引用次数: 2
Effects of suspension dispersity and concentration on its flocculation efficiency in static and dynamic flocculators 悬浮液的分散性和浓度对静态和动态絮凝器絮凝效果的影响
Pub Date : 2019-01-22 DOI: 10.30564/JMMR.V1I1.411
N. Rulyov, O. Kravtchenko, F. Concha
Flocculation presents one of the most effective methods for enhancing separation of both anthropogenic and natural suspensions by sedimentation, filtration and flotation techniques.The flocculation effectiveness much depends on the medium shear rate in a flocculator. The objective of this research comprises the study how the suspension dispersity and concentration effect the efficiency of its flocculation in a static tubular flocculator and in a dynamic Couette flocculator. The studies used aqueous suspensions of ultra-fine calcium carbonate (<7 μm) and fine silica (<90 μm) as objects. It was established that treatment of ultra-fine calcium carbonate suspension in a static flocculator produced in the range 400-450 s-1 a pronounced primary maximum in the dependence "flocculation efficiency/shear rate". The increase of the suspension concentration to 70 g/l and above resulted in a small secondary maximum of the flocculation efficiency in the region of around 950 s-1. This can be due to a higher dissolution rate of flocculant and a corresponding increase of particles adhesion forces in flocs, which counteract viscous forces destroying them. In silicon dioxide suspension treatment, the primary and secondary peaks occur at both small and high suspension concentrations, but in a latter case, they are by far more pronounced and comparable in magnitude.
絮凝是通过沉降、过滤和浮选技术来提高人为悬浮物和自然悬浮物分离的最有效方法之一。絮凝效果在很大程度上取决于絮凝器中介质的剪切速率。本研究的目的包括研究悬浮液的分散性和浓度如何影响其在静态管状絮凝器和动态库埃特絮凝器中的絮凝效率。研究以超细碳酸钙(<7 μm)和细二氧化硅(<90 μm)的水悬浮液为对象。结果表明,在400 ~ 450 s-1范围内的静态絮凝剂中处理超细碳酸钙悬浮液,絮凝效率/剪切速率的相关性最大。当悬浮液浓度增加到70 g/l及以上时,絮凝效率的二次最大值在950 s-1左右。这可能是由于絮凝剂的溶解速率更高,絮凝体中颗粒的附着力相应增加,从而抵消了破坏它们的粘性力。在二氧化硅悬浮液处理中,初级峰和次级峰在小悬浮液浓度和高悬浮液浓度下都出现,但在后一种情况下,它们的幅度要明显得多。
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引用次数: 0
STUDY OF DEFORMATION OF ALUMINIUM ALLOY IN EQUAL CHANNEL ANGULAR MATRIX WITH QUASI-SMALL CHANNELS INTERSECTION ANGLE 准小通道交会角等通道角矩阵下铝合金的变形研究
Pub Date : 2019-01-22 DOI: 10.30564/jmmr.v1i1.312
S. Lezhnev
This article is described the various possible schemes of severe plastic deformation, by ECAP process that allows receiving metal with ultrafine-grained structure. The results of computer simulation and TEM investigations of aluminium alloy 6060 were presented. It is shown that the equal-channel angular pressing in the proposed matrix with a quasi-starched channel joint angle 45° provides the formation of a homogeneous subgrain structure with a size about 0.5 µm and has a positive effect on the mechanical properties of the aluminium alloy.
本文描述了各种可能的严重塑性变形方案,通过ECAP工艺,允许接收具有超细晶结构的金属。介绍了6060铝合金的计算机模拟和透射电镜研究结果。结果表明,以45°准淀粉通道连接角对基体进行等通道角挤压,可形成尺寸约为0.5 μ m的均匀亚晶组织,对铝合金的力学性能有积极影响。
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引用次数: 2
Combined effect of thermal shock and hot corrosion on the failure of yttria stabilized zirconia thermal barrier coatings 热冲击和热腐蚀对氧化钇稳定氧化锆热障涂层失效的共同影响
Pub Date : 2019-01-22 DOI: 10.30564/JMMR.V1I1.307
Changhai Zhou, X. Li, R. Pan
The thermal barrier coatings (TBCs) of 8wt.% yttria stabilized zirconia (8YSZ) on a GH2132 alloy were deposited by air plasma spraying. The combined effect of thermal shock and hot corrosion on the failure of TBCs was highlighted investigated. The results showed that the combined effect of hot corrosion and thermal shock was prone to induce the failure of TBCs. The main failure of TBCs under the combined effect was in the form of penetrating crack to the bondcoat/substrate interface and oxidation at the penetrating crack front. 
8wt的热障涂层(tbc)。采用空气等离子喷涂技术在GH2132合金表面沉积了钇稳定氧化锆(8YSZ)。重点研究了热冲击和热腐蚀对TBCs失效的共同影响。结果表明,热腐蚀和热冲击的共同作用容易导致tbc失效。复合作用下TBCs的主要失效形式为粘结层/基体界面的穿透裂纹和穿透裂纹前缘的氧化。
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引用次数: 1
Common Problems in Metal Material Testing and Solutions 金属材料测试中的常见问题及解决方法
Pub Date : 2018-10-25 DOI: 10.30564/jmmr.v1i1.192
Xiang-Ran Du
Metal materials are the most important material materials for humandevelopment and progress. In major scientific and technological fields such asindustry, agriculture, and national defense, corresponding metal materials are used according to different functions and uses. This paper analyzes the common problems in the detection of metal materials, in order to provide suggestions for the related application of metal materials.
金属材料是人类发展和进步最重要的材料。在工业、农业、国防等重大科技领域,根据不同的功能和用途,使用相应的金属材料。本文对金属材料检测中常见的问题进行了分析,以期为金属材料的相关应用提供建议。
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引用次数: 0
Influencing Factors and Control Strategies of Heat Treatment Deformation of Metal Materials 金属材料热处理变形的影响因素及控制策略
Pub Date : 2018-10-25 DOI: 10.30564/jmmr.v1i1.190
Qiang Li, Yutao Wang
In the thermal processing of metal materials, the performance of thematerial is more stable, and the heat-treated materials are processed into parts to make the performance more excellent and more in line with the performance requirements of mechanical parts. However, in thermal processing, metal materials are prone to problems, such as deformation, deformation of the appearance of metal materials, and fatal effects on the processing of mechanical parts. Therefore, this paper focuses on solving the causes of deformation in the thermal processing of metal materials, as well as solutions to improve the problems in the processing of metal materials.
在金属材料的热加工中,材料的性能更加稳定,将经过热处理的材料加工成零件,使其性能更加优异,更符合机械零件的性能要求。然而,在热加工中,金属材料容易出现变形、金属材料外观变形等问题,对机械零件的加工产生致命影响。因此,本文着重于解决金属材料热加工中产生变形的原因,以及改进金属材料加工中存在问题的解决方案。
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引用次数: 3
期刊
Journal of Metallic Material Research
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