首页 > 最新文献

Water Environment Research最新文献

英文 中文
Removal of Fe2+ in coastal aquaculture source water by manganese ores: Batch experiments and breakthrough curve modeling. 用锰矿去除沿海水产养殖源水中的 Fe2+:批量实验和突破曲线建模。
IF 2.5 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-01 DOI: 10.1002/wer.11147
Jianhua Wang, Wenchao Feng, Jian Lu, Jun Wu, Wenxin Cao, Jianbai Zhang, Cui Zhang, Bing Hu, Wensheng Li

Excessive Fe2+ in coastal aquaculture source water will seriously affect the aquaculture development. This study used manganese sand to investigate the removal potential and mechanism of Fe2+ in coastal aquaculture source water by column experiments. The pseudo-first-order kinetic model could better describe Fe2+ removal process with R2 in the range of 0.9451-0.9911. More than 99.7% of Fe2+ could be removed within 120 min while the removal rate (k) was positively affected by low initial concentration of Fe2+, high temperature, and low pH. Logistic growth (S-shaped growth) model could better fit the concentration variation of Fe2+ in the effluent of the column (R2>0.99). The Fe2 breakthrough curve could be fitted by Bohart-Adams, Yoon-Nelson, and Thomas models (R2>0.95). Smooth slices with irregular shapes existed on the surface of manganese sand after the reaction while Fe content increased significantly on the surface of manganese sand after the column experiment. Moreover, FeO (OH) was mainly formed on the surface of manganese sand after the reaction. PRACTITIONER POINTS: Fe2+ in coastal aquaculture source water could be removed by manganese ores. The pseudo-first-order kinetic model better described the Fe2+ removal process. FeO (OH) was mainly formed on the surface of manganese sand after the reaction.

沿海养殖源水中过量的 Fe2+ 会严重影响水产养殖的发展。本研究利用锰砂,通过柱实验研究了近海养殖源水中Fe2+的去除潜力和机理。伪一阶动力学模型能较好地描述 Fe2+ 的去除过程,R2 在 0.9451-0.9911 之间。在 120 分钟内,99.7%以上的 Fe2+ 可被去除,而去除率(k)受低初始 Fe2+ 浓度、高温和低 pH 值的正向影响。Logistic 生长(S 型生长)模型能更好地拟合色谱柱出水中 Fe2+ 的浓度变化(R2>0.99)。Bohart-Adams、Yoon-Nelson 和 Thomas 模型可以拟合 Fe2 突破曲线(R2>0.95)。反应后锰砂表面出现了形状不规则的光滑切片,而柱实验后锰砂表面的铁含量显著增加。此外,反应后锰砂表面主要形成了 FeO(OH)。实践点:锰矿可去除沿海养殖源水中的 Fe2+。伪一阶动力学模型较好地描述了 Fe2+ 的去除过程。反应后锰砂表面主要形成 FeO(OH)。
{"title":"Removal of Fe<sup>2+</sup> in coastal aquaculture source water by manganese ores: Batch experiments and breakthrough curve modeling.","authors":"Jianhua Wang, Wenchao Feng, Jian Lu, Jun Wu, Wenxin Cao, Jianbai Zhang, Cui Zhang, Bing Hu, Wensheng Li","doi":"10.1002/wer.11147","DOIUrl":"10.1002/wer.11147","url":null,"abstract":"<p><p>Excessive Fe<sup>2+</sup> in coastal aquaculture source water will seriously affect the aquaculture development. This study used manganese sand to investigate the removal potential and mechanism of Fe<sup>2+</sup> in coastal aquaculture source water by column experiments. The pseudo-first-order kinetic model could better describe Fe<sup>2+</sup> removal process with R<sup>2</sup> in the range of 0.9451-0.9911. More than 99.7% of Fe<sup>2+</sup> could be removed within 120 min while the removal rate (k) was positively affected by low initial concentration of Fe<sup>2+</sup>, high temperature, and low pH. Logistic growth (S-shaped growth) model could better fit the concentration variation of Fe<sup>2+</sup> in the effluent of the column (R<sup>2</sup>>0.99). The Fe<sup>2</sup> breakthrough curve could be fitted by Bohart-Adams, Yoon-Nelson, and Thomas models (R<sup>2</sup>>0.95). Smooth slices with irregular shapes existed on the surface of manganese sand after the reaction while Fe content increased significantly on the surface of manganese sand after the column experiment. Moreover, FeO (OH) was mainly formed on the surface of manganese sand after the reaction. PRACTITIONER POINTS: Fe<sup>2+</sup> in coastal aquaculture source water could be removed by manganese ores. The pseudo-first-order kinetic model better described the Fe<sup>2+</sup> removal process. FeO (OH) was mainly formed on the surface of manganese sand after the reaction.</p>","PeriodicalId":23621,"journal":{"name":"Water Environment Research","volume":"96 11","pages":"e11147"},"PeriodicalIF":2.5,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142547819","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Using off-gas testing to map mixing gradients and audit blower capacity. 利用废气测试来绘制混合梯度图和审核鼓风机容量。
IF 2.5 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-01 DOI: 10.1002/wer.11143
Brock Hodgson, Kenneth Brischke, Branden Cavanaugh, Manel Garrido-Baserba, Elinor S Austin, Diego Rosso

A water resource recovery facility sited in a region at a high elevation has experienced the effects of over-designing its blowers. In this case study, we used off-gas analysis and site-specific power tariffs to quantify actual process loading and air requirements, and we quantitatively evaluated various options for blower replacement or upgrade. Off-gas analysis mapped the oxygen uptake rate at the surface of the tank, suggesting that the tanks were not evenly loaded across their sections. The local cost of energy directly affects the return on the investment calculation and limits the available solutions. The payback of partial or complete blower replacement may not be justified even in the event of excessive aeration, and the sequencing of aeration system improvements including diffuser replacement, process controls, and blower modifications should be evaluated contemporaneously. PRACTITIONER POINTS: Off-gas analysis can be used to evaluate process loading imbalances by mapping the oxygen uptake rate. Alpha factors from off-gas testing are used in process models to evaluate air requirements and blower air demand. Comparative evaluation of blowers must be done considering the net present value of the status quo, upgrades, or replacement.

位于高海拔地区的一家水资源回收设施经历了鼓风机过度设计的影响。在本案例研究中,我们使用废气分析和现场特定功率电价来量化实际工艺负荷和空气需求,并对鼓风机更换或升级的各种方案进行了定量评估。废气分析绘制了储罐表面的氧气吸收率,表明储罐各部分的负载并不均匀。当地的能源成本直接影响到投资回报的计算,并限制了可用的解决方案。即使在曝气量过大的情况下,部分或全部更换鼓风机的投资回收期也可能不合理,因此应同时评估曝气系统改进(包括更换扩散器、工艺控制和鼓风机改造)的先后顺序。实践点:废气分析可通过绘制氧气吸收率图来评估工艺负载失衡。废气测试得出的 Alpha 因子可用于工艺模型,以评估空气需求和鼓风机空气需求。鼓风机的比较评估必须考虑现状、升级或更换的净现值。
{"title":"Using off-gas testing to map mixing gradients and audit blower capacity.","authors":"Brock Hodgson, Kenneth Brischke, Branden Cavanaugh, Manel Garrido-Baserba, Elinor S Austin, Diego Rosso","doi":"10.1002/wer.11143","DOIUrl":"https://doi.org/10.1002/wer.11143","url":null,"abstract":"<p><p>A water resource recovery facility sited in a region at a high elevation has experienced the effects of over-designing its blowers. In this case study, we used off-gas analysis and site-specific power tariffs to quantify actual process loading and air requirements, and we quantitatively evaluated various options for blower replacement or upgrade. Off-gas analysis mapped the oxygen uptake rate at the surface of the tank, suggesting that the tanks were not evenly loaded across their sections. The local cost of energy directly affects the return on the investment calculation and limits the available solutions. The payback of partial or complete blower replacement may not be justified even in the event of excessive aeration, and the sequencing of aeration system improvements including diffuser replacement, process controls, and blower modifications should be evaluated contemporaneously. PRACTITIONER POINTS: Off-gas analysis can be used to evaluate process loading imbalances by mapping the oxygen uptake rate. Alpha factors from off-gas testing are used in process models to evaluate air requirements and blower air demand. Comparative evaluation of blowers must be done considering the net present value of the status quo, upgrades, or replacement.</p>","PeriodicalId":23621,"journal":{"name":"Water Environment Research","volume":"96 11","pages":"e11143"},"PeriodicalIF":2.5,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142629398","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biofilm characterization and dynamic simulation of advanced rope media reactor for the treatment of primary effluent. 用于处理一级污水的先进绳状介质反应器的生物膜特征和动态模拟。
IF 2.5 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-01 DOI: 10.1002/wer.11150
Wudneh A Shewa, Lin Sun, Kevin Bossy, Martha Dagnew

Biofilm modeling is inherently complex, often requiring multiple assumptions and simplifications. In biofilm modeling, default or literature-based values in biofilm systems are usually used to estimate biofilm parameters, including boundary layer, biofilm density, thickness, attachment, and detachment rates. This study aimed to characterize and model the biofilm of a specific rope-type fixed media system, removing carbon and total inorganic nitrogen, coupled with sensitivity analysis. Among the five model parameters, the sensitivity analysis of this study showed that boundary layer thickness is the most influential parameter for predicting effluent ammonia and nitrate concentrations, and biofilm density is most sensitive with respect to effluent chemical oxygen demand (COD). The least sensitive parameter is the detachment rate. Based on the calculated mean absolute error (MAE) and root mean squared error (RMSE), the calibrated BioCord fixed-film reactor (BFFR) model accurately predicted effluent ammonium and dissolved oxygen (DO) in the continuously aerated bench-scale reactor (R1) and failed to predict well in the intermittently aerated bench-scale reactor (R2). RMSE values calculated for NH3-N and DO in R1 are 0.95 and 0.53 mg/L, respectively. In the BioCord pilot plant's case, ammonium-N predicted by the model fit the measured values well, while it overpredicted DO concentrations. PRACTITIONER POINTS: Fixed biofilm BioCord reactors were studied for primary effluent treatment. A methodology was developed to characterize biofilms. Boundary layer thickness is the most influential parameter for predicting effluent ammonia and nitrate concentrations. Biofilm density is the most sensitive parameter with respect to effluent COD. The calibrated BFFR model can predict effluent ammonium, nitrite, and nitrate-nitrogen.

生物膜建模本身就很复杂,往往需要多种假设和简化。在生物膜建模中,通常使用生物膜系统的默认值或基于文献的值来估算生物膜参数,包括边界层、生物膜密度、厚度、附着率和脱离率。本研究旨在对特定绳索型固定介质系统的生物膜进行特征描述和建模,去除碳和无机氮总量,并结合灵敏度分析。本研究的灵敏度分析表明,在五个模型参数中,边界层厚度是对预测出水氨氮和硝氮浓度影响最大的参数,而生物膜密度对出水化学需氧量(COD)最为敏感。最不敏感的参数是脱落率。根据计算得出的平均绝对误差 (MAE) 和均方根误差 (RMSE),校准过的 BioCord 固定膜反应器 (BFFR) 模型在连续通气的台式反应器 (R1) 中准确预测了出水氨氮和溶解氧 (DO),而在间歇通气的台式反应器 (R2) 中未能很好地预测。R1 中计算的 NH3-N 和溶解氧的 RMSE 值分别为 0.95 和 0.53 mg/L。在 BioCord 试验工厂的案例中,模型预测的铵-氮与测量值非常吻合,但对溶解氧浓度的预测过高。实践点:研究了用于一级污水处理的固定生物膜 BioCord 反应器。开发了一种表征生物膜的方法。边界层厚度是预测出水氨氮和硝氮浓度的最有影响力的参数。生物膜密度是对出水化学需氧量最敏感的参数。经过校准的 BFFR 模型可以预测出水氨氮、亚硝酸盐氮和硝酸盐氮。
{"title":"Biofilm characterization and dynamic simulation of advanced rope media reactor for the treatment of primary effluent.","authors":"Wudneh A Shewa, Lin Sun, Kevin Bossy, Martha Dagnew","doi":"10.1002/wer.11150","DOIUrl":"10.1002/wer.11150","url":null,"abstract":"<p><p>Biofilm modeling is inherently complex, often requiring multiple assumptions and simplifications. In biofilm modeling, default or literature-based values in biofilm systems are usually used to estimate biofilm parameters, including boundary layer, biofilm density, thickness, attachment, and detachment rates. This study aimed to characterize and model the biofilm of a specific rope-type fixed media system, removing carbon and total inorganic nitrogen, coupled with sensitivity analysis. Among the five model parameters, the sensitivity analysis of this study showed that boundary layer thickness is the most influential parameter for predicting effluent ammonia and nitrate concentrations, and biofilm density is most sensitive with respect to effluent chemical oxygen demand (COD). The least sensitive parameter is the detachment rate. Based on the calculated mean absolute error (MAE) and root mean squared error (RMSE), the calibrated BioCord fixed-film reactor (BFFR) model accurately predicted effluent ammonium and dissolved oxygen (DO) in the continuously aerated bench-scale reactor (R1) and failed to predict well in the intermittently aerated bench-scale reactor (R2). RMSE values calculated for NH<sub>3</sub>-N and DO in R1 are 0.95 and 0.53 mg/L, respectively. In the BioCord pilot plant's case, ammonium-N predicted by the model fit the measured values well, while it overpredicted DO concentrations. PRACTITIONER POINTS: Fixed biofilm BioCord reactors were studied for primary effluent treatment. A methodology was developed to characterize biofilms. Boundary layer thickness is the most influential parameter for predicting effluent ammonia and nitrate concentrations. Biofilm density is the most sensitive parameter with respect to effluent COD. The calibrated BFFR model can predict effluent ammonium, nitrite, and nitrate-nitrogen.</p>","PeriodicalId":23621,"journal":{"name":"Water Environment Research","volume":"96 11","pages":"e11150"},"PeriodicalIF":2.5,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142629388","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Insights into the efficiencies of different biological treatment systems for pharmaceuticals removal: A review. 对不同生物处理系统去除药物效率的见解:综述。
IF 2.5 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-01 DOI: 10.1002/wer.11153
Armin Dolatimehr, Ali Mahyar, Saeid Panahi Hassan Barough, Mohammadreza Mahmoodi

This review presents a comprehensive analysis of current research on biological treatment processes for removing pharmaceutical compounds (PhCs) from wastewater. Unlike previous studies on this topic, our study specifically delves into the effectiveness and drawbacks of various treatment approaches such as traditional wastewater treatment facilities (WWTP), membrane bioreactors (MBRs), constructed wetlands (CW), and moving bed biofilm reactors (MBBR). Through the examination and synthesis of information gathered from more than 200 research studies, we have created a comprehensive database that delves into the effectiveness of eliminating 19 particular PhCs, including commonly studied compounds such as acetaminophen, ibuprofen, diclofenac, naproxen, ketoprofen, indomethacin, salicylic acid, codeine, and fenoprofen, amoxicillin, azithromycin, ciprofloxacin, ofloxacin, tetracycline, atenolol, propranolol, and metoprolol. This resource provides a depth and scope of information that was previously lacking in this area of study. Notably, among these pharmaceuticals, azithromycin demonstrated the highest removal rates across all examined treatment systems, with the exception of WWTPs, while carbamazepine consistently exhibited the lowest removal efficiencies across various systems. The analysis showcases the diverse results in removal efficiency impacted by factors such as system configuration, operation specifics, and environmental circumstances. The findings emphasize the critical need for continued innovation and research, specifically recommending the integration of advanced oxidation processes (AOPs) with existing biological treatment methods to improve the breakdown of recalcitrant compounds like carbamazepine. PRACTITIONER POINTS: Persistent pharmaceuticals harm aquatic ecosystems and human health. Biological systems show varying pharmaceutical removal efficiencies. Enhancing HRT and SRT improves removal but adds complexity and costs. Tailored treatment approaches needed based on contaminants and conditions.

本综述全面分析了当前有关去除废水中药物化合物 (PhCs) 的生物处理工艺的研究。与以往有关该主题的研究不同,我们的研究专门探讨了各种处理方法的有效性和缺点,如传统废水处理设施 (WWTP)、膜生物反应器 (MBR)、人工湿地 (CW) 和移动床生物膜反应器 (MBBR)。通过检查和综合从 200 多项研究中收集到的信息,我们创建了一个综合数据库,深入研究消除 19 种特定 PhCs 的有效性、包括对乙酰氨基酚、布洛芬、双氯芬酸、萘普生、酮洛芬、吲哚美辛、水杨酸、可待因和非诺洛芬、阿莫西林、阿奇霉素、环丙沙星、氧氟沙星、四环素、阿替洛尔、普萘洛尔和美托洛尔等常用化合物。该资料提供的信息深度和广度是以前在这一研究领域所缺乏的。值得注意的是,在这些药物中,除污水处理厂外,阿奇霉素在所有受检处理系统中的去除率最高,而卡马西平在各种系统中的去除率一直最低。分析结果表明,系统配置、操作细节和环境条件等因素对去除效率的影响各不相同。研究结果强调了持续创新和研究的迫切需要,特别建议将高级氧化工艺 (AOP) 与现有的生物处理方法相结合,以提高对卡马西平等难降解化合物的分解效率。实践者观点:持久性药物会危害水生生态系统和人类健康。生物系统对药物的去除效率各不相同。加强 HRT 和 SRT 可以提高去除率,但会增加复杂性和成本。需要根据污染物和条件采取量身定制的处理方法。
{"title":"Insights into the efficiencies of different biological treatment systems for pharmaceuticals removal: A review.","authors":"Armin Dolatimehr, Ali Mahyar, Saeid Panahi Hassan Barough, Mohammadreza Mahmoodi","doi":"10.1002/wer.11153","DOIUrl":"https://doi.org/10.1002/wer.11153","url":null,"abstract":"<p><p>This review presents a comprehensive analysis of current research on biological treatment processes for removing pharmaceutical compounds (PhCs) from wastewater. Unlike previous studies on this topic, our study specifically delves into the effectiveness and drawbacks of various treatment approaches such as traditional wastewater treatment facilities (WWTP), membrane bioreactors (MBRs), constructed wetlands (CW), and moving bed biofilm reactors (MBBR). Through the examination and synthesis of information gathered from more than 200 research studies, we have created a comprehensive database that delves into the effectiveness of eliminating 19 particular PhCs, including commonly studied compounds such as acetaminophen, ibuprofen, diclofenac, naproxen, ketoprofen, indomethacin, salicylic acid, codeine, and fenoprofen, amoxicillin, azithromycin, ciprofloxacin, ofloxacin, tetracycline, atenolol, propranolol, and metoprolol. This resource provides a depth and scope of information that was previously lacking in this area of study. Notably, among these pharmaceuticals, azithromycin demonstrated the highest removal rates across all examined treatment systems, with the exception of WWTPs, while carbamazepine consistently exhibited the lowest removal efficiencies across various systems. The analysis showcases the diverse results in removal efficiency impacted by factors such as system configuration, operation specifics, and environmental circumstances. The findings emphasize the critical need for continued innovation and research, specifically recommending the integration of advanced oxidation processes (AOPs) with existing biological treatment methods to improve the breakdown of recalcitrant compounds like carbamazepine. PRACTITIONER POINTS: Persistent pharmaceuticals harm aquatic ecosystems and human health. Biological systems show varying pharmaceutical removal efficiencies. Enhancing HRT and SRT improves removal but adds complexity and costs. Tailored treatment approaches needed based on contaminants and conditions.</p>","PeriodicalId":23621,"journal":{"name":"Water Environment Research","volume":"96 11","pages":"e11153"},"PeriodicalIF":2.5,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142629396","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fate of biosolids-bound PFAS through pyrolysis coupled with thermal oxidation for air emissions control. 通过热解和热氧化控制生物固体中的全氟辛烷磺酸。
IF 2.5 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-01 DOI: 10.1002/wer.11149
Lloyd J Winchell, Joshua Cullen, John J Ross, Alex Seidel, Mary Lou Romero, Farokh Kakar, Embrey Bronstad, Martha J M Wells, Naomi B Klinghoffer, Franco Berruti, Alexandre Miot, Katherine Y Bell

Pyrolysis has been identified as a possible thermal treatment process for reducing perfluoroalkyl and polyfluoroalkyl substances (PFAS) from wastewater solids, though off-gas from the pyrolysis unit can still be a source of PFAS emissions. In this work, the fate of PFAS through a laboratory-scale pyrolysis unit coupled with a thermal oxidizer for treatment of off-gasses is documented. Between 91.5% and >99.9% reduction was observed through the entire system for specific compounds based on targeted analyses. Overall, the pyrolysis and thermal oxidizer system removed 99.4% of the PFAS moles introduced. Furthermore, shorter chain variants comprised the majority of reportable PFAS in the thermal oxidizer flue gas, indicating the longer chain compounds present in the dried biosolids fed to pyrolyzer decompose through the system. PRACTITIONER POINTS: Thermal oxidation is a promising treatment technology for exhaust systems associated with thermal biosolids treatments. Thermal oxidation demonstrated significant degradation capabilities, with gas phase emissions comprising only 0.200% of initial PFAS concentrations to the system. Short-chain PFAS made up a higher percent of thermal oxidizer emissions, ranging between 54.4% and 79.5% of PFAS in the exhaust on a molar basis. The possibility of recombinant PFAS formation and partial thermal decomposition of PFAS in thermal oxidation is a needed area of research.

热解被认为是减少废水固体中全氟烷基和多氟烷基物质 (PFAS) 的一种可能的热处理工艺,但热解装置产生的废气仍可能是 PFAS 的排放源。本研究记录了 PFAS 通过实验室规模的热解装置和热氧化器处理废气后的去向。根据有针对性的分析,在整个系统中观察到特定化合物的降解率在 91.5% 到 99.9% 之间。总体而言,热解和热氧化系统去除了 99.4% 的 PFAS 摩尔。此外,在热氧化炉烟气中,应报告的 PFAS 大部分都是短链变体,这表明送入热解器的干燥生物固体中存在的长链化合物会通过该系统进行分解。实践者观点:对于与生物固体热处理相关的废气系统而言,热氧化是一种很有前途的处理技术。热氧化技术具有显著的降解能力,气相排放仅占系统初始 PFAS 浓度的 0.200%。短链 PFAS 在热氧化剂排放物中的比例较高,按摩尔计算占废气中 PFAS 的 54.4% 到 79.5%。在热氧化过程中可能会形成重组 PFAS 和部分 PFAS 热分解,这是一个需要研究的领域。
{"title":"Fate of biosolids-bound PFAS through pyrolysis coupled with thermal oxidation for air emissions control.","authors":"Lloyd J Winchell, Joshua Cullen, John J Ross, Alex Seidel, Mary Lou Romero, Farokh Kakar, Embrey Bronstad, Martha J M Wells, Naomi B Klinghoffer, Franco Berruti, Alexandre Miot, Katherine Y Bell","doi":"10.1002/wer.11149","DOIUrl":"https://doi.org/10.1002/wer.11149","url":null,"abstract":"<p><p>Pyrolysis has been identified as a possible thermal treatment process for reducing perfluoroalkyl and polyfluoroalkyl substances (PFAS) from wastewater solids, though off-gas from the pyrolysis unit can still be a source of PFAS emissions. In this work, the fate of PFAS through a laboratory-scale pyrolysis unit coupled with a thermal oxidizer for treatment of off-gasses is documented. Between 91.5% and >99.9% reduction was observed through the entire system for specific compounds based on targeted analyses. Overall, the pyrolysis and thermal oxidizer system removed 99.4% of the PFAS moles introduced. Furthermore, shorter chain variants comprised the majority of reportable PFAS in the thermal oxidizer flue gas, indicating the longer chain compounds present in the dried biosolids fed to pyrolyzer decompose through the system. PRACTITIONER POINTS: Thermal oxidation is a promising treatment technology for exhaust systems associated with thermal biosolids treatments. Thermal oxidation demonstrated significant degradation capabilities, with gas phase emissions comprising only 0.200% of initial PFAS concentrations to the system. Short-chain PFAS made up a higher percent of thermal oxidizer emissions, ranging between 54.4% and 79.5% of PFAS in the exhaust on a molar basis. The possibility of recombinant PFAS formation and partial thermal decomposition of PFAS in thermal oxidation is a needed area of research.</p>","PeriodicalId":23621,"journal":{"name":"Water Environment Research","volume":"96 11","pages":"e11149"},"PeriodicalIF":2.5,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142629394","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chlormequat inhibits Vallisneria natans growth and shapes the epiphytic biofilm microbial community. 矮壮素能抑制 Vallisneria natans 的生长并形成附生生物膜微生物群落。
IF 2.5 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-10-01 DOI: 10.1002/wer.11148
Zihang Ma, Dan Ai, Zuhan Ge, Tao Wu, Jibiao Zhang

Submerged macrophytes can overgrow and negatively affect freshwater ecosystems. This study aimed to investigate the use of chlormequat (CQ) to regulate submerged Vallisneria natans growth as well as its impact on the microbial community of epiphytic biofilms. V. natans height under CQ dosages of 20, 100, and 200 mg/L decreased within 21 days by 12.57%, 30.07%, and 44.62%, respectively, while chlorophyll content increased by 1.94%, 20.39%, and 38.83%. At 100 mg/L, CQ reduced the diversity of bacteria in the biofilm attached to V. natans leaves but increased the diversity of the eukaryotic microbial community. CQ strongly inhibited Cyanobacteria; compared with the control group, the treatment group experienced a significant reduction from 36.54% to 2.61%. Treatment significantly inhibited Gastrotricha and Rotifera, two dominant phyla of eukaryotes in the leaf biofilm, reducing their relative abundances by 17.41% and 6.48%, respectively. CQ significantly changed the leaf biofilm microbial community correlation network. The treatment group exhibited lower modularity (2.012) compared with the control group (2.249); however, the central network of the treated group contained a higher number of microbial genera (13) than the control group (4), highlighting the significance of eukaryotic genera in the network. The results obtained from this study provide invaluable scientific context and technical understanding pertinent to the restoration of submerged macrophytes within aquatic ecosystems. PRACTITIONER POINTS: Chlormequat reduced the plant height but increased leaf chlorophyll content. Chlormequat reduced biofilm bacterial diversity but increased eukaryotic diversity. Chlormequat affected the bacterial-fungal association networks in biofilms.

沉水大型藻类会过度生长并对淡水生态系统产生负面影响。本研究旨在调查使用矮壮素(CQ)调节沉水大叶女贞(Vallisneria natans)生长及其对附生生物膜微生物群落的影响。在 CQ 剂量为 20、100 和 200 mg/L 的条件下,V. natans 的高度在 21 天内分别下降了 12.57%、30.07% 和 44.62%,而叶绿素含量则分别增加了 1.94%、20.39% 和 38.83%。在 100 毫克/升的浓度下,CQ 会降低附着在 V. natans 叶片上的生物膜中细菌的多样性,但会增加真核微生物群落的多样性。CQ 对蓝藻有很强的抑制作用;与对照组相比,处理组的抑制率从 36.54% 显著下降到 2.61%。处理组明显抑制了叶片生物膜中的两个主要真核微生物门--胃孢子虫和轮虫,它们的相对丰度分别降低了 17.41% 和 6.48%。CQ 明显改变了叶片生物膜微生物群落相关网络。与对照组(2.249)相比,处理组的模块化程度(2.012)较低;然而,处理组的中心网络包含的微生物属数量(13 个)高于对照组(4 个),凸显了真核生物属在网络中的重要性。这项研究的结果为恢复水生生态系统中的沉水大型藻类提供了宝贵的科学背景和技术理解。实践点:矮壮素降低了植物高度,但增加了叶片叶绿素含量。百草枯降低了生物膜细菌的多样性,但增加了真核生物的多样性。毒死蜱会影响生物膜中的细菌-真菌关联网络。
{"title":"Chlormequat inhibits Vallisneria natans growth and shapes the epiphytic biofilm microbial community.","authors":"Zihang Ma, Dan Ai, Zuhan Ge, Tao Wu, Jibiao Zhang","doi":"10.1002/wer.11148","DOIUrl":"https://doi.org/10.1002/wer.11148","url":null,"abstract":"<p><p>Submerged macrophytes can overgrow and negatively affect freshwater ecosystems. This study aimed to investigate the use of chlormequat (CQ) to regulate submerged Vallisneria natans growth as well as its impact on the microbial community of epiphytic biofilms. V. natans height under CQ dosages of 20, 100, and 200 mg/L decreased within 21 days by 12.57%, 30.07%, and 44.62%, respectively, while chlorophyll content increased by 1.94%, 20.39%, and 38.83%. At 100 mg/L, CQ reduced the diversity of bacteria in the biofilm attached to V. natans leaves but increased the diversity of the eukaryotic microbial community. CQ strongly inhibited Cyanobacteria; compared with the control group, the treatment group experienced a significant reduction from 36.54% to 2.61%. Treatment significantly inhibited Gastrotricha and Rotifera, two dominant phyla of eukaryotes in the leaf biofilm, reducing their relative abundances by 17.41% and 6.48%, respectively. CQ significantly changed the leaf biofilm microbial community correlation network. The treatment group exhibited lower modularity (2.012) compared with the control group (2.249); however, the central network of the treated group contained a higher number of microbial genera (13) than the control group (4), highlighting the significance of eukaryotic genera in the network. The results obtained from this study provide invaluable scientific context and technical understanding pertinent to the restoration of submerged macrophytes within aquatic ecosystems. PRACTITIONER POINTS: Chlormequat reduced the plant height but increased leaf chlorophyll content. Chlormequat reduced biofilm bacterial diversity but increased eukaryotic diversity. Chlormequat affected the bacterial-fungal association networks in biofilms.</p>","PeriodicalId":23621,"journal":{"name":"Water Environment Research","volume":"96 10","pages":"e11148"},"PeriodicalIF":2.5,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142509002","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of novel composite material with spent coffee ground biochar and steel slag zeolite for enhanced dye and phosphate removal. 用废咖啡粉生物炭和钢渣沸石合成新型复合材料,以增强染料和磷酸盐的去除效果。
IF 2.5 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-10-01 DOI: 10.1002/wer.11137
Shazia Noorin, Tanushree Paul, Arnab Ghosh, Jurng-Jae Yee, Sung Hyuk Park

Rising concerns over water scarcity, driven by industrialization and urbanization, necessitate the need for innovative solutions for wastewater treatment. This study focuses on developing an eco-friendly and cost-effective biochar-zeolite composite (BZC) adsorbent using waste materials-spent coffee ground biochar (CGB) and steel slag zeolite (SSZ). Initially, the biochar was prepared from spent coffee ground, and zeolite was prepared from steel slag; their co-pyrolysis resulted in novel adsorbent material. Later, the physicochemical characteristics of the BZC were examined, which showed irregular structure and well-defined pores. Dye removal studies were conducted, which indicate that BZC adsorption reach equilibrium in 2 h, exhibiting 95% removal efficiency compared to biochar (43.33%) and zeolite (74.58%). Moreover, the removal efficiencies of the novel BZC composite toward dyes methyl orange (MO) and crystal violet (CV) were found to be 97% and 99.53%, respectively. The kinetic studies performed with the dyes and phosphate with an adsorbent dosage of 0.5 g L-1 suggest a pseudo-second-order model. Additionally, the reusability study of BZC proves to be effective through multiple adsorption and regeneration cycles. Initially, the phosphate removal remains high but eventually decreases from 92% to 70% in the third regeneration cycle, highlighting the robustness of the BZC. In conclusion, this study introduces a promising, cost-effective novel BZC adsorbent derived from waste materials as a sustainable solution for wastewater treatment. Emphasizing efficiency, reusability, and potential contributions to environmentally conscious water treatment, the findings highlight the composite's significance in addressing key challenges for the removal of toxic pollutants from the aqueous solutions. PRACTITIONER POINTS: A novel biochar-zeolite composite (BZC) material has been synthesized. Excellent removal of dyes by BZC (~95%) was achieved as compared to their counterparts The kinetic studies performed suggest a pseudo-second-order model. BZC proves to be highly effective for multiple adsorption studies. Excellent reusability showed potential as a robust adsorbent.

在工业化和城市化的推动下,人们对水资源短缺的担忧与日俱增,因此有必要寻找创新的废水处理解决方案。本研究的重点是利用废弃材料--咖啡渣生物炭(CGB)和钢渣沸石(SSZ),开发一种生态友好且经济高效的生物炭-沸石复合材料(BZC)吸附剂。最初,生物炭是用废咖啡粉制备的,而沸石则是用钢渣制备的。随后,对 BZC 的理化特性进行了研究,结果显示其结构不规则,孔隙清晰。染料去除研究表明,BZC 的吸附在 2 小时内达到平衡,与生物炭(43.33%)和沸石(74.58%)相比,去除率达到 95%。此外,新型 BZC 复合材料对染料甲基橙(MO)和水晶紫(CV)的去除率分别为 97% 和 99.53%。在吸附剂用量为 0.5 g L-1 时,对染料和磷酸盐进行的动力学研究表明,该模型为假二阶模型。此外,BZC 的可重复使用性研究证明,经过多次吸附和再生循环,BZC 是有效的。最初,磷酸盐的去除率仍然很高,但在第三个再生周期中,去除率最终从 92% 降至 70%,这凸显了 BZC 的稳健性。总之,本研究介绍了一种从废料中提取的前景广阔、经济高效的新型 BZC 吸附剂,它是一种可持续的废水处理解决方案。研究结果强调了该复合材料的高效性、可重复利用性以及对环保型水处理的潜在贡献,并强调了其在应对从水溶液中去除有毒污染物的关键挑战方面所具有的重要意义。实践点:合成了一种新型生物炭-沸石复合材料(BZC)。与同类材料相比,BZC 对染料的去除率极高(约 95%)。事实证明,BZC 对多重吸附研究非常有效。出色的可重复使用性显示了其作为一种坚固吸附剂的潜力。
{"title":"Synthesis of novel composite material with spent coffee ground biochar and steel slag zeolite for enhanced dye and phosphate removal.","authors":"Shazia Noorin, Tanushree Paul, Arnab Ghosh, Jurng-Jae Yee, Sung Hyuk Park","doi":"10.1002/wer.11137","DOIUrl":"https://doi.org/10.1002/wer.11137","url":null,"abstract":"<p><p>Rising concerns over water scarcity, driven by industrialization and urbanization, necessitate the need for innovative solutions for wastewater treatment. This study focuses on developing an eco-friendly and cost-effective biochar-zeolite composite (BZC) adsorbent using waste materials-spent coffee ground biochar (CGB) and steel slag zeolite (SSZ). Initially, the biochar was prepared from spent coffee ground, and zeolite was prepared from steel slag; their co-pyrolysis resulted in novel adsorbent material. Later, the physicochemical characteristics of the BZC were examined, which showed irregular structure and well-defined pores. Dye removal studies were conducted, which indicate that BZC adsorption reach equilibrium in 2 h, exhibiting 95% removal efficiency compared to biochar (43.33%) and zeolite (74.58%). Moreover, the removal efficiencies of the novel BZC composite toward dyes methyl orange (MO) and crystal violet (CV) were found to be 97% and 99.53%, respectively. The kinetic studies performed with the dyes and phosphate with an adsorbent dosage of 0.5 g L<sup>-1</sup> suggest a pseudo-second-order model. Additionally, the reusability study of BZC proves to be effective through multiple adsorption and regeneration cycles. Initially, the phosphate removal remains high but eventually decreases from 92% to 70% in the third regeneration cycle, highlighting the robustness of the BZC. In conclusion, this study introduces a promising, cost-effective novel BZC adsorbent derived from waste materials as a sustainable solution for wastewater treatment. Emphasizing efficiency, reusability, and potential contributions to environmentally conscious water treatment, the findings highlight the composite's significance in addressing key challenges for the removal of toxic pollutants from the aqueous solutions. PRACTITIONER POINTS: A novel biochar-zeolite composite (BZC) material has been synthesized. Excellent removal of dyes by BZC (~95%) was achieved as compared to their counterparts The kinetic studies performed suggest a pseudo-second-order model. BZC proves to be highly effective for multiple adsorption studies. Excellent reusability showed potential as a robust adsorbent.</p>","PeriodicalId":23621,"journal":{"name":"Water Environment Research","volume":"96 10","pages":"e11137"},"PeriodicalIF":2.5,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142354838","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Understanding machine learning predictions of wastewater treatment plant sludge with explainable artificial intelligence. 用可解释人工智能理解污水处理厂污泥的机器学习预测。
IF 2.5 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-10-01 DOI: 10.1002/wer.11136
Fuad Bin Nasir, Jin Li

This study investigates the use of machine learning (ML) models for wastewater treatment plant (WWTP) sludge predictions and explainable artificial intelligence (XAI) techniques for understanding the impact of variables behind the prediction. Three ML models, random forest (RF), gradient boosting machine (GBM), and gradient boosting tree (GBT), were evaluated for their performance using statistical indicators. Input variable combinations were selected through different feature selection (FS) methods. XAI techniques were employed to enhance the interpretability and transparency of ML models. The results suggest that prediction accuracy depends on the choice of model and the number of variables. XAI techniques were found to be effective in interpreting the decisions made by each ML model. This study provides an example of using ML models in sludge production prediction and interpreting models applying XAI to understand the factors influencing it. Understandable interpretation of ML model prediction can facilitate targeted interventions for process optimization and improve the efficiency and sustainability of wastewater treatment processes. PRACTITIONER POINTS: Explainable artificial intelligence can play a crucial role in promoting trust between machine learning models and their real-world applications. Widely practiced machine learning models were used to predict sludge production of a United States wastewater treatment plant. Feature selection methods can reduce the required number of input variables without compromising model accuracy. Explainable artificial intelligence techniques can explain driving variables behind machine learning prediction.

本研究调查了机器学习(ML)模型在污水处理厂(WWTP)污泥预测中的应用,以及可解释人工智能(XAI)技术对预测背后变量影响的理解。使用统计指标对随机森林(RF)、梯度提升机(GBM)和梯度提升树(GBT)这三种 ML 模型的性能进行了评估。通过不同的特征选择(FS)方法选择输入变量组合。采用了 XAI 技术来增强 ML 模型的可解释性和透明度。结果表明,预测精度取决于模型的选择和变量的数量。研究发现,XAI 技术可有效解释每个 ML 模型做出的决策。本研究提供了在污泥产量预测中使用 ML 模型的实例,并应用 XAI 对模型进行解释,以了解影响因素。对 ML 模型预测进行可理解的解释可促进对工艺优化进行有针对性的干预,并提高污水处理工艺的效率和可持续性。实践者观点:可解释的人工智能在促进机器学习模型与实际应用之间的信任方面发挥着至关重要的作用。广泛应用的机器学习模型被用于预测美国一家污水处理厂的污泥产量。特征选择方法可以在不影响模型准确性的情况下减少所需的输入变量数量。可解释的人工智能技术可以解释机器学习预测背后的驱动变量。
{"title":"Understanding machine learning predictions of wastewater treatment plant sludge with explainable artificial intelligence.","authors":"Fuad Bin Nasir, Jin Li","doi":"10.1002/wer.11136","DOIUrl":"https://doi.org/10.1002/wer.11136","url":null,"abstract":"<p><p>This study investigates the use of machine learning (ML) models for wastewater treatment plant (WWTP) sludge predictions and explainable artificial intelligence (XAI) techniques for understanding the impact of variables behind the prediction. Three ML models, random forest (RF), gradient boosting machine (GBM), and gradient boosting tree (GBT), were evaluated for their performance using statistical indicators. Input variable combinations were selected through different feature selection (FS) methods. XAI techniques were employed to enhance the interpretability and transparency of ML models. The results suggest that prediction accuracy depends on the choice of model and the number of variables. XAI techniques were found to be effective in interpreting the decisions made by each ML model. This study provides an example of using ML models in sludge production prediction and interpreting models applying XAI to understand the factors influencing it. Understandable interpretation of ML model prediction can facilitate targeted interventions for process optimization and improve the efficiency and sustainability of wastewater treatment processes. PRACTITIONER POINTS: Explainable artificial intelligence can play a crucial role in promoting trust between machine learning models and their real-world applications. Widely practiced machine learning models were used to predict sludge production of a United States wastewater treatment plant. Feature selection methods can reduce the required number of input variables without compromising model accuracy. Explainable artificial intelligence techniques can explain driving variables behind machine learning prediction.</p>","PeriodicalId":23621,"journal":{"name":"Water Environment Research","volume":"96 10","pages":"e11136"},"PeriodicalIF":2.5,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142354839","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impact of organic matter constituents on phosphorus recovery from CPR sludges. 有机物成分对 CPR 污泥中磷回收的影响。
IF 2.5 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-10-01 DOI: 10.1002/wer.11141
Aseel A Alnimer, D Scott Smith, Wayne J Parker

This study evaluated the influence of organic matter (OM) constituents on the potential for recovery of P from wastewaters when FeCl3 treatment is employed for P removal. The presence of OM constituents did not influence P release from Fe-P sludges when alkaline and ascorbic acid treatments were employed. However, the overall recovery of P from wastewater was impacted by the presence of selected OM constituents through the reduction of P uptake during coagulation. The presence of protein and humic matter showed remarkably low P removal values (3.0 ± 0.4% and 23 ± 1% respectively) when compared to an inorganic control recipe (62 ± 2%). Elevated soluble Fe (SFe) residuals in the presence of proteins (87 ± 5%) and humics (51 ± 1%) indicated interactions between Fe(III) cations and negatively charged functional groups like hydroxyl, carboxyl, and phenolic groups available in these organics. Significant negative correlations between P removal and residual SFe were observed suggesting Fe solubilization by OM constituents was the mechanism responsible for reduced P removal. The findings of this study identify, for the first time, the impact of OM constituents on overall P recovery when Fe(III) salts are employed and provide insights into recoveries that can be expected when Fe is added to primary, secondary treated, and industrial wastewaters. PRACTITIONER POINTS: Low P removal values were observed for protein and humic dominated wastewater recipes. Iron(III) solubilization counted for P removal reduction by proteins and humic acids. There is no effect of OM on P release from Fe-P sludge at pH 10 and ascorbic acid treatments. OM and agent employed to release P from sludges affected overall recovery of P.

本研究评估了在采用三氯化铁(FeCl3)处理去除 P 时,有机物(OM)成分对从废水中回收 P 的潜力的影响。在采用碱性和抗坏血酸处理时,有机物成分的存在不会影响铁-磷淤泥中 P 的释放。然而,由于某些 OM 成分的存在会在混凝过程中减少 P 的吸收,因此会影响废水中 P 的总体回收率。与无机对照配方(62 ± 2%)相比,蛋白质和腐殖质的存在显示出极低的磷去除率(分别为 3.0 ± 0.4% 和 23 ± 1%)。蛋白质(87 ± 5%)和腐殖质(51 ± 1%)存在时,可溶性铁(SFe)残留量升高,这表明铁(III)阳离子与这些有机物中的羟基、羧基和酚基等带负电荷的官能团之间存在相互作用。P 清除率与残留 SFe 之间呈显著负相关,表明有机物成分对铁的溶解是导致 P 清除率降低的机制。这项研究的结果首次确定了在使用铁(III)盐时有机物成分对总体磷回收率的影响,并为在一级、二级处理和工业废水中添加铁时可预期的回收率提供了启示。实践点:蛋白质和腐殖质为主的废水配方对 P 的去除率较低。蛋白质和腐殖酸对铁(III)的增溶作用可减少对 P 的去除。在 pH 值为 10 和抗坏血酸处理条件下,OM 对铁-磷污泥中的 P 释放没有影响。从污泥中释放 P 所使用的 OM 和药剂影响了 P 的总体回收率。
{"title":"Impact of organic matter constituents on phosphorus recovery from CPR sludges.","authors":"Aseel A Alnimer, D Scott Smith, Wayne J Parker","doi":"10.1002/wer.11141","DOIUrl":"https://doi.org/10.1002/wer.11141","url":null,"abstract":"<p><p>This study evaluated the influence of organic matter (OM) constituents on the potential for recovery of P from wastewaters when FeCl<sub>3</sub> treatment is employed for P removal. The presence of OM constituents did not influence P release from Fe-P sludges when alkaline and ascorbic acid treatments were employed. However, the overall recovery of P from wastewater was impacted by the presence of selected OM constituents through the reduction of P uptake during coagulation. The presence of protein and humic matter showed remarkably low P removal values (3.0 ± 0.4% and 23 ± 1% respectively) when compared to an inorganic control recipe (62 ± 2%). Elevated soluble Fe (SFe) residuals in the presence of proteins (87 ± 5%) and humics (51 ± 1%) indicated interactions between Fe(III) cations and negatively charged functional groups like hydroxyl, carboxyl, and phenolic groups available in these organics. Significant negative correlations between P removal and residual SFe were observed suggesting Fe solubilization by OM constituents was the mechanism responsible for reduced P removal. The findings of this study identify, for the first time, the impact of OM constituents on overall P recovery when Fe(III) salts are employed and provide insights into recoveries that can be expected when Fe is added to primary, secondary treated, and industrial wastewaters. PRACTITIONER POINTS: Low P removal values were observed for protein and humic dominated wastewater recipes. Iron(III) solubilization counted for P removal reduction by proteins and humic acids. There is no effect of OM on P release from Fe-P sludge at pH 10 and ascorbic acid treatments. OM and agent employed to release P from sludges affected overall recovery of P.</p>","PeriodicalId":23621,"journal":{"name":"Water Environment Research","volume":"96 10","pages":"e11141"},"PeriodicalIF":2.5,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142476026","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Seasonal nitrogen removal in an outdoor microalgal polyculture at Nordic conditions. 北欧条件下室外微藻多元养殖的季节性脱氮。
IF 2.5 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-10-01 DOI: 10.1002/wer.11142
Lina Mattsson, Hanna Farnelid, Maurice Hirwa, Martin Olofsson, Fredrik Svensson, Catherine Legrand, Elin Lindehoff

Microalgal solutions to clean waste streams and produce biomass were evaluated in Nordic conditions during winter, spring, and autumn in Southeast Sweden. The study investigated nitrogen (N) removal, biomass quality, and safety by treating industrial leachate water with a polyculture of local microalgae and bacteria in open raceway ponds, supplied with industrial CO2 effluent. Total N (TN) removal was higher in spring (1.5 g-2d-1), due to beneficial light conditions compared to winter and autumn (0.1 and 0.09 g-2d-1). Light, TN, and N species influenced the microalgal community (dominated by Chlorophyta), while the bacterial community remained stable throughout seasons with a large proportion of cyanobacteria. Winter conditions promoted biomass protein (19.6-26.7%) whereas lipids and carbohydrates were highest during spring (11.4-18.4 and 15.4-19.8%). Biomass toxin and metal content were below safety levels for fodder, but due to the potential presence of toxic strains, biofuels or fertilizer could be suitable applications for the algal biomass. PRACTITIONER POINTS: Microalgal removal of nitrogen from leachate water was evaluated in Nordic conditions during winter, spring, and autumn. Total nitrogen removal was highest in spring (1.5 g-2d-1), due to beneficial light conditions for autotrophic growth. Use of local polyculture made the cultivation more stable on a seasonal (light) and short-term (N-species changes) scale. Toxic elements in produced algal biomass were below legal thresholds for upcycling.

在瑞典东南部的冬季、春季和秋季,在北欧条件下对微藻清洁废物流和生产生物质的解决方案进行了评估。该研究调查了工业渗滤液的脱氮、生物质质量和安全性,方法是在开放式赛道池塘中利用当地微藻和细菌的多重培养来处理工业渗滤液水,并向其供应工业二氧化碳废水。与冬季和秋季(0.1 g-2d-1 和 0.09 g-2d-1)相比,由于光照条件良好,春季的总氮(TN)去除率更高(1.5 g-2d-1)。光照、TN 和氮的种类影响了微藻群落(以叶绿藻为主),而细菌群落在各个季节保持稳定,蓝藻占很大比例。冬季条件促进了生物量蛋白质(19.6-26.7%)的增加,而春季则以脂类和碳水化合物含量最高(分别为 11.4-18.4% 和 15.4-19.8%)。生物质毒素和金属含量低于饲料的安全水平,但由于可能存在有毒菌株,生物燃料或肥料可能是藻类生物质的合适用途。实践点:在北欧的冬季、春季和秋季,对微藻类去除渗滤液中的氮进行了评估。春季的总脱氮量最高(1.5 g-2d-1),这得益于有利于自养生长的光照条件。采用本地多培养方式使培养在季节(光照)和短期(氮种变化)范围内更加稳定。所产藻类生物量中的有毒元素低于可循环利用的法定阈值。
{"title":"Seasonal nitrogen removal in an outdoor microalgal polyculture at Nordic conditions.","authors":"Lina Mattsson, Hanna Farnelid, Maurice Hirwa, Martin Olofsson, Fredrik Svensson, Catherine Legrand, Elin Lindehoff","doi":"10.1002/wer.11142","DOIUrl":"https://doi.org/10.1002/wer.11142","url":null,"abstract":"<p><p>Microalgal solutions to clean waste streams and produce biomass were evaluated in Nordic conditions during winter, spring, and autumn in Southeast Sweden. The study investigated nitrogen (N) removal, biomass quality, and safety by treating industrial leachate water with a polyculture of local microalgae and bacteria in open raceway ponds, supplied with industrial CO<sub>2</sub> effluent. Total N (TN) removal was higher in spring (1.5 g<sup>-2</sup>d<sup>-1</sup>), due to beneficial light conditions compared to winter and autumn (0.1 and 0.09 g<sup>-2</sup>d<sup>-1</sup>). Light, TN, and N species influenced the microalgal community (dominated by Chlorophyta), while the bacterial community remained stable throughout seasons with a large proportion of cyanobacteria. Winter conditions promoted biomass protein (19.6-26.7%) whereas lipids and carbohydrates were highest during spring (11.4-18.4 and 15.4-19.8%). Biomass toxin and metal content were below safety levels for fodder, but due to the potential presence of toxic strains, biofuels or fertilizer could be suitable applications for the algal biomass. PRACTITIONER POINTS: Microalgal removal of nitrogen from leachate water was evaluated in Nordic conditions during winter, spring, and autumn. Total nitrogen removal was highest in spring (1.5 g<sup>-2</sup>d<sup>-1</sup>), due to beneficial light conditions for autotrophic growth. Use of local polyculture made the cultivation more stable on a seasonal (light) and short-term (N-species changes) scale. Toxic elements in produced algal biomass were below legal thresholds for upcycling.</p>","PeriodicalId":23621,"journal":{"name":"Water Environment Research","volume":"96 10","pages":"e11142"},"PeriodicalIF":2.5,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142476028","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Water Environment Research
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1