Water Environment Research最新文献

This work assessed the performance of a pilot-scale cascade anaerobic digestion (AD) system when treating mixed municipal wastewater treatment sludges. The cascade system was compared with a conventional continuous stirred tank reactor (CSTR) digester (control) in terms of process performance, stability, and digestate quality. The results showed that the cascade system achieved higher volatile solids removal (VSR) efficiencies (28-48%) than that of the reference (25-41%) when operated at the same solids residence time (SRT) in the range of 11-15 days. When the SRT of the cascade system was reduced to 8 days the VSR (32-36%) was only slightly less than that of the reference digester that was operated at a 15-day SRT (39-43%). Specific hydrolysis rates in the first stage of the cascade system were 66-152% higher than those of the reference. Additionally, the cascade system exhibited relatively stable effluent concentrations of volatile fatty acids (VFAs: 100-120 mg/l), while the corresponding concentrations in the control effluent demonstrated greater fluctuations (100-160 mg/l). The cascade system's effluent pH and VFA/alkalinity ratios were consistently maintained within the optimal range. During a dynamic test when the feed total solids concentration was doubled, total VFA concentrations (85-120 mg/l) in the cascade system were noticeably less than those (100-170 mg/l) of the control, while the pH and VFA/alkalinity levels remained in a stable range. The cascade system achieved higher total solids (TS) content in the dewatered digestate (19.4-26.8%) than the control (17.4-22.1%), and E. coli log reductions (2.0-4.1 log MPN/g TS) were considerably higher (p < 0.05) than those in the control (1.3-2.9 log MPN/g TS). Overall, operating multiple CSTRs in cascade mode at typical SRTs and mixed sludge ratios enhanced the performance, stability digesters, and digestate quality of AD. PRACTITIONER POINTS: Enhanced digestion of mixed sludge digestion with cascade system. Increased hydrolysis rates in the cascade system compared to a reference CSTR. More stable conditions for methanogen growth at both steady and dynamic states. Improved dewaterability and E. coli reduction of digestate from the cascade system.

Knowledge on natural background levels (NBLs) of aluminum (Al) in groundwater can accurately assess groundwater Al contamination at a regional scale. However, it has received little attention. This study used a combination of preselection and statistic methods consisting of the oxidation capacity and the boxplot iteration methods to evaluate the NBL of shallow groundwater Al in four groundwater units of the Pearl River Delta (PRD) via eliminating anthropogenic-impacted groundwaters and to discuss driving factors controlling high NBLs of Al in groundwater in this area. A total of 280 water samples were collected, and 18 physico-chemical parameters including Redox potential, dissolved oxygen, pH, total dissolved solids, HCO₃ ^-, NH₄ ⁺, NO₃ ^-, SO₄ ^2-, Cl^-, NO₂ ^-, F^-, K⁺, Na⁺, Ca²⁺, Mg²⁺, Fe, Mn, and Al were analyzed. Results showed that groundwater Al NBLs in groundwater units A-D were 0.11, 0.16, 0.15, and 0.08 mg/L, respectively. The used method in this study is acceptable for the assessment of groundwater Al NBLs in the PRD, because groundwater Al concentrations in various groundwater units in residual datasets were independent of land-use types, but they were opposite in the original datasets. The dissolution of Al-rich minerals in sediments/rocks was the major source for groundwater Al NBLs in the PRD, and the interaction with Al-rich river water was secondary one. The high groundwater Al NBL in groundwater unit B was mainly attributed to the acid precipitation and the organic matter mineralization inducing the release of Al in Quaternary sediments. By contrast, the high groundwater Al NBL in groundwater unit C mainly was ascribed to the release of Al complexes such as fluoroaluminate from rocks/soils into groundwater induced by acid precipitation, but it was limited by the dissolution of Mg minerals (e.g., dolomite) in aquifers. This study provides not only useful groundwater Al NBLs for the evaluation of groundwater Al contamination but also a reference for understanding the natural geochemical factors controlling groundwater Al in urbanized deltas such as the PRD. PRACTITIONER POINTS: The natural background level (NBL) of groundwater aluminum in the Pearl River Delta (PRD) was evaluated. The dissolution of aluminum-rich minerals in sediments/rocks was the major source for groundwater aluminum NBLs in the PRD. The acid precipitation and organic matter mineralization contribute to high groundwater Al NBL in the groundwater unit B. The acid precipitation contributes to high groundwater Al NBL in the groundwater unit C, while dissolution of magnesium minerals limits it.

Digital twins have been gaining an immense interest in various fields over the last decade. Bringing conventional process simulation models into (near) real time are thought to provide valuable insights for operators, decision makers, and stakeholders in many industries. The objective of this paper is to describe two methods for implementing digital twins at water resource recovery facilities and highlight and discuss their differences and preferable use situations, with focus on the automated data transfer from the real process. Case 1 uses a tailor-made infrastructure for automated data transfer between the facility and the digital twin. Case 2 uses edge computing for rapid automated data transfer. The data transfer lag from process to digital twin is low compared to the simulation frequency in both systems. The presented digital twin objectives can be achieved using either of the presented methods. The method of Case 1 is better suited for automatic recalibration of model parameters, although workarounds exist for the method in Case 2. The method of Case 2 is well suited for objectives such as soft sensors due to its integration with the SCADA system and low latency. The objective of the digital twin, and the required latency of the system, should guide the choice of method. PRACTITIONER POINTS: Various methods can be used for automated data transfer between the physical system and a digital twin. Delays in the data transfer differ depending on implementation method. The digital twin objective determines the required simulation frequency. Implementation method should be chosen based on the required simulation frequency.

The principled utilization of treated wastewater can reduce the pollution load on the environment. Because on the one hand, treated wastewater can be a suitable fertilizer substitute, and on the other hand, using treated wastewater in irrigation prevents the discharge of polluted surface water into water sources. In the south of Tehran province, polluted surface water is used for irrigation in the agricultural sector, and this has led to environmental problems. To solve this problem, it has been decided to implement a plan to build surface water treatment plants and an irrigation and drainage network to transfer treated wastewater to farms. Therefore, the present study aimed to investigate the economic and environmental effects of this project in the region. A hydro-economic model has been used to achieve this goal. According to the results, in the case of the application of environmental constraints in the optimization model, the cultivation area and the farmers' profit will be reduced by about 5% and 36%, respectively, compared with the noncompliance of environmental constraints. However, this decline in profit can be compensated by adopting solutions such as improving the irrigation system, the application of treated wastewater, or using the fertilizer potential of water sources in the agricultural sector. PRACTITIONER POINTS: In the optimal economic-environmental situation, farmers' profit is reduced compared with the optimal economic situation. In the case of implementing the treated wastewater application, the farmers' profit will increase despite environmental constraints. In the optimal economic-environmental situation, fewer lands are cultivated with diverse crops than in optimal economic conditions.

Subsurface wastewater infiltration systems (SWISs) are suggested to be a cost-effective and environmentally friendly method for sewage treatment. However, a comprehensive summary of the relevant mechanisms and optimization methods for nitrogen (N) removal in SWIS is currently lacking. In this review, we first summarize the N transformation mechanisms in SWIS. The impact of operational parameters on the N removal efficiency is then delineated. To enhance pollutant removal and minimize resource wastage, it is advisable to maintain a wet-dry ratio of 1:1 and a hydraulic loading rate of 8-10 cm/day. The organic load should be determined based on influent characteristics to optimize the balance between sewage treatment and nitrous oxide (N₂O) emission. Finally, various strategies and modifications have been suggested to enhance pollutant removal efficiency and reduce N₂O emissions in SWIS, such as artificial aeration, supply electron donors, and well-designed structures. Overall, greater emphasis should be placed on the design and management of SWIS to optimize their co-benefits while effectively controlling N pollution. PRACTITIONER POINTS: SWISs are often considered black boxes with their efficiency depending on hydraulic characteristics, biological characteristics, and substrate properties. Biological nitrification coupled with denitrification is considered to be the major N removal process. Increasing the reduction of N₂O to the inert N₂ form is a potential mechanism to mitigate global warming. Strategies such as artificial aeration, supply electron donors, and well-designed structures are suggested to improve N removal performance.

The Anthropocene has driven a transformative era where human activities exert unprecedented influence on Earth's biosphere. Consequently, synanthropic organisms, adept at thriving in human-modified environments, have emerged. While well studied in terrestrial ecosystems, the presence and ecological importance of synanthropic species in aquatic ecosystems, specifically among cyanobacteria, are less understood. Cyanobacteria blooms, notorious for their detrimental effects on ecosystems and human health, are increasing in frequency and intensity globally. In this perspective, we explore the evidence supporting this rise of cyanobacteria blooms, emphasizing the roles of human-induced eutrophication and climate change on select cyanobacteria genera. Cyanobacteria are not a monolith, with certain genera showing an observable increase within anthropogenically modified environments. We propose the establishment of a new sub-branch of phycology that explicitly investigates the ecology and physiology of synanthropic cyanobacteria. Understanding the intricate interactions between synanthropic species and human populations is imperative for managing human-altered ecosystems and conserving freshwater resources, particularly in the face of increasing global water insecurity. PRACTITIONER POINTS: The rise in cyanobacteria blooms is driven by a small subset of human-adapted genera-synanthropic cyanobacteria. Research is needed to characterize synanthropic cyanobacteria, which will aid in developing tailored management approaches. A paradigm shift from domesticating to "rewilding" landscapes and modifying behaviors to facilitate cohabitation are solutions to reducing risks.

The land application of sewage sludge from wastewater treatment plants has been recognized as a major source of microplastic contamination in soil. Nevertheless, the fate and behavior of microplastics in soil remain uncertain, particularly their distribution and transport, which are poorly understood. This study does a bibliometric analysis and visualization of relevant research publications using the CiteSpace software. It explores the limited research available on the topic, highlighting the potential for it to emerge as a research hotspot in the future. Chinese researchers and institutions are paying great attention to this field and are promoting close academic cooperation among international organizations. Current research hot topics mainly involve microplastic pollution caused by the land application of sewage sludge, as well as the detection, environmental fate, and removal of microplastics in soil. The presence of microplastics in sludge, typically ranging from tens of thousands to hundreds of thousands of particles (p)/kg, inevitably leads to their introduction into soil upon land application. In China, the estimated annual accumulation of microplastics in the soil due to sludge use is approximately 1.7 × 10¹³ p. In European countries, the accumulation ranges from 8.6 to 71 × 10¹³ p. Sludge application has significantly elevated soil microplastic concentrations, with higher application rates and frequencies resulting in up to several-fold increases. The primary forms of microplastics found in soils treated with sludge are fragments and fibers, primarily in white color. These microplastics consist primarily of components such as polyamide, polyethylene, and polypropylene. The vertical transport behavior of microplastics is influenced by factors such as tillage, wind, rainfall, bioturbation, microplastic characteristics (e.g., fraction, particle size, and shape), and soil physicochemical properties (e.g., organic matter, porosity, electrical conductivity, and pH). Research indicates that microplastics can penetrate up to 90 cm into the soil profile and persist for decades. Microplastics in sewage sludge-amended soils pose potential long-term threats to soil ecosystems and even human health. Future research should focus on expanding the theoretical understanding of microplastic behavior in these soils, enabling the development of comprehensive risk assessments and informed decision-making for sludge management practices. PRACTITIONER POINTS: Microplastics in sewage sludge range from tens to hundreds of thousands per kilogram. Sludge land application contributes significantly to soil microplastic pollution. The main forms of microplastics in sludge-amended soils are fragments and fibers. Microplastics are mainly composed of polyamide, polyethylene, and polypropylene. Microplastics can penetrate up to 90 cm into the soil profile and persist for decades.

This study aims to improve COD, NH₃-N, and turbidity removal from Bingöl's leachate using a single-reactor integrated electrocoagulation (EC)-coal-based powdered activated carbon (CBPAC) process under various experimental conditions. In the EC-CBPAC process, three stainless-steel cathodes and three aluminum electrodes were connected to the negative and positive terminals of the power supply, respectively. The initial concentrations in the leachate were 1044 mg O₂/L for COD, 204 mg/L for NH₃-N, and 57 NTU (or 71.25-mg (NH₂)2H₂SO₄/L) for turbidity, respectively. After a 40-min EC-CBPAC process, with a CBPAC dosage of 5 g/L and pH of 5 for COD and turbidity, and 9.5 for NH₃-N, the optimum removal efficiencies for COD, NH₃-N, and turbidity were achieved at 92%, 40%, and 91%, respectively. When the EC process was applied without CBPAC under the same experimental conditions, the removal efficiencies of COD, NH₃-N, and turbidity were 87%, 28%, and 54%, respectively. Before and after the EC-CBPAC process, the Brunauer-Emmett-Teller (BET) surface area, pore volume, and mean pore diameter of the CBPAC were found to be (888 m²/g, 0.498 cm³/g, and 22.28 Å) and (173 m²/g, 0.18 cm³/g, and 42.8 Å), respectively. The optimum pseudo-first-order (PFO) rate constants for COD, turbidity, and NH₃-N were determined to be 3.15 × 10^-2, 4.77 × 10^-2, and 8.8 × 10^-3 min^-1, respectively. With the current density increasing from 15 to 25 mA/cm², energy consumption, unit energy consumption, and total cost increased from 68.7 to 122.4 kWh/m³, 6.948 to 15.226 kWh/kg COD, and 0.85 to 1.838 $/kg COD, respectively. PRACTITIONER POINTS: EC-CBPAC process has greater COD, NH₃-N, and turbidity removal efficiency than EC process. COD and turbidity achieved their optimum disposal efficiencies at 92% and 91%, respectively, at pH 5 The most efficient disposal efficiency for NH₃-N was observed to be 40% at pH 9.5. EC-CBPAC process increased removal efficiencies for COD, NH₃-N, and turbidity by 20%, 19%, and 38%, respectively, compared with EC alone. The turbidity, NH₃-N, and COD disposal fitted PSO model due to high correlation values (R² 0.94-0.99).

Wastewater containing tetrabromobisphenol A (TBBPA), a commonly used flame retardant found in wastewater, can present significant toxic effects on biota, yet its impact on tropical freshwater environments is not well understood. This study explores the effectiveness of two independent anaerobic treatment systems, the acidogenic reactor (AR) and the methanogenic reactor (MR), for the ecotoxicity reduction of TBBPA-rich wastewater in four tropical freshwater species. Despite presenting good physicochemical performance and reduced toxicity of the influent for most species, AR and MR treatments remain acute and chronic toxicity. Overall, MR exhibited greater efficacy in reducing influent toxicity compared with AR. TBBPA bioaccumulation was observed in Chironomus sancticaroli after short-term exposure to 100% MR effluent. Multigenerational exposures highlighted changes in the wing length of C. sancticaroli, showing decreases after influent and AR exposures and increases after MR exposures. These findings underscore the need for ecotoxicological tools in studies of new treatment technologies, combining the removal of emerging contaminants with safeguarding aquatic biota. PRACTITIONER POINTS: Acidogenic and methanogenic reactors reduced the acute and chronic toxicity of wastewater containing tetrabromobisphenol A. Both treatments still exhibit toxicity, inducing short- and long-term toxic effects on four native tropical species. The aquatic species Pristina longiseta was most sensitive to effluents from acidogenic and methanogenic reactors. TBBPA concentrations recovered from Chironomus sancticaroli bioaccumulation analysis ranged from 1.07 to 1.35 μg g^-1. Evaluating new treatment technologies with multiple species bioassays is essential for a comprehensive effluent toxicity assessment and ensuring aquatic safety.

Ni-Mn@KL ozone catalyst was prepared for the efficient treatment of reverse osmosis membrane concentrates. The working conditions and reaction mechanism of the ozone-catalyzed oxidation by Ni-Mn@KL were systematically studied. Then, a comprehensive CRITIC weighting-coupling coordination evaluation model was established. Ni-Mn@KL was characterized by scanning electron microscopy, BET, X-ray diffraction, X-ray photoelectron spectroscopy, energy-dispersive spectrometry, and X-ray fluorescence spectrometry and found to have large specific surface area and homogeneous surface dispersion of striped particles. Under the optimum working conditions with an initial pH of 7.9 (raw water), a reaction height-to-diameter ratio of 10:1, an ozone-aeration intensity of 0.3 L/min, and a catalyst filling rate of 10%, the maximum COD removal rate was 60.5%. Free-radical quenching experiments showed that OH oxidation played a dominant role in the Ni-Mn@KL-catalyzed ozone-oxidation system, and the reaction system conformed to the second-order reaction kinetics law. Ni-Mn@KL catalysts were further confirmed to have good catalytic performance and mechanical performance after repeated utilization. PRACTITIONER POINTS: Ni-Mn@KL catalyst can achieve effective treatment of RO film concentrated liquid. High COD removal rate of RO membrane concentrated liquid was obtained at low cost. Ni-Mn@KL catalyst promotes ozone decomposition to produce ·OH and O₂ ^-· oxidized organic matter. The Ni-Mn@KL catalyst can maintain good stability after repeated use. A CRITIC weight-coupling coordination model was established to evaluate the catalytic ozonation.