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A preliminary fish survey of the estuaries on the east coast of South Africa, Mpande to Mtentwana: a comparative study 对南非东岸Mpande至Mtentwana河口的初步鱼类调查:比较研究
IF 1.5 4区 环境科学与生态学 Q4 WATER RESOURCES Pub Date : 2022-10-26 DOI: 10.17159/wsa/2022.v48.i4.3944
N. James, Td Harrison
A preliminary ichthyofaunal and physico-chemical survey of estuaries on the east coast of South Africa from the Mpande Estuary to the Mtentwana Estuary was undertaken between November 1997 and January 1998. Sixteen estuaries were surveyed along this stretch of coastline and these were grouped into three estuary types: small (< 10 ha) predominantly closed estuaries, moderate to large (> 10 ha) predominantly closed estuaries and predominantly open estuaries. Multivariate analyses revealed significant differences between the three groups in terms of both their physico-chemical characteristics (small predominantly closed estuaries were different from predominantly open estuaries) and their fish communities (all three estuary types were significantly different).  The estuaries in the study area fall within the subtropical/warm-temperate transition-zone and north of the subtropical/warm-temperate biogeographic break; tropical species dominated the fish communities of all the estuaries in terms of numbers of species and biomass. This survey represents one of the few fish surveys undertaken along this little-studied section of the coastline.
1997年11月至1998年1月期间,对南非东海岸从Mpande河口到Mtentwana河口的河口进行了初步的鱼类区系和物理化学调查。沿着这条海岸线调查了16个河口,并将这些河口分为三种类型:以封闭为主的小型河口(< 10公顷)、以封闭为主的中大型河口(10公顷)和以开放为主的河口。多变量分析显示,三组河口的理化特征(以封闭为主的小河口与以开放为主的小河口不同)和鱼类群落(三种河口类型均有显著差异)均存在显著差异。研究区河口处于亚热带/暖温带过渡带和亚热带/暖温带生物地理断裂带以北;在物种数量和生物量方面,各河口的鱼类群落均以热带物种为主。这次调查是沿着这条很少被研究的海岸线进行的为数不多的鱼类调查之一。
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引用次数: 0
South Africa needs a hydrological soil map: a case study from the upper uMngeni catchment 南非需要一份水文土壤地图:uMngeni上游集水区的案例研究
IF 1.5 4区 环境科学与生态学 Q4 WATER RESOURCES Pub Date : 2022-10-26 DOI: 10.17159/wsa/2022.v48.i4.3977
JJ van Tol, GM van Zijl
Accurate hydrological modelling to evaluate the impacts of climate and land use change on water resources is pivotal to sustainable management. Soil information is an important input in hydrological models but is often not available at adequate scale with appropriate attributes for direct parameterisation of the models. In this study, conducted in three quaternary catchments in the midlands of KwaZulu-Natal, three different soil information sets were used to configure SWAT+, a revised version of the Soil and Water Assessment Tool (SWAT). The datasets were: (i) the Land Type database (currently the only soil dataset covering the whole of South Africa), (ii) disaggregation of the Land Type database using digital soil mapping techniques (called DSMART), and (iii) a dataset where DSMART were complemented by field observations and interpretations of the hydropedological behaviour of the soils (DSMART+). Simulated streamflow was compared with measured streamflow at three weirs with long-term measurements, and the impact of the soil datasets on water balance simulations was evaluated. In general, the simulations were acceptable when compared to other studies, but could be improved through calibration and including small reservoirs in the model. The DSMART+ dataset yielded more accurate simulations of streamflow in all three catchments with Nash-Sutcliffe efficiencies increasing by between 9% and 67% when compared to the Land Type dataset. The value of the improved soil maps is, however, highlighted through the enhanced spatial detail of streamflow generation mechanisms and water balance components. The internal catchment processes are represented more accurately, and we argue that South Africa needs a detailed hydrological soil map for effective water resource management.
准确的水文模型来评估气候和土地利用变化对水资源的影响是可持续管理的关键。土壤信息是水文模型的一个重要输入,但往往不能在适当的尺度上获得具有适当属性的模型直接参数化。在这项研究中,在夸祖鲁-纳塔尔省中部的三个第四系集水区进行了研究,使用了三种不同的土壤信息集来配置SWAT+,这是水土评估工具(SWAT)的修订版。这些数据集是:(i)土地类型数据库(目前唯一覆盖整个南非的土壤数据集),(ii)使用数字土壤制图技术(称为DSMART)对土地类型数据库进行分类,以及(iii) DSMART通过实地观测和土壤水文行为解释补充的数据集(DSMART+)。将模拟流量与实测流量进行了比较,并对土壤数据集对水平衡模拟的影响进行了评价。总的来说,与其他研究相比,模拟是可以接受的,但可以通过校准和在模型中包括小型储层来改进。与Land Type数据集相比,DSMART+数据集对所有三个流域的流量进行了更准确的模拟,Nash-Sutcliffe效率提高了9%至67%。然而,改进后的土壤图的价值通过加强水流产生机制和水平衡成分的空间细节而得到突出体现。内部流域过程更准确地表示,我们认为南非需要一个详细的水文土壤图来有效地管理水资源。
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引用次数: 3
Environmental regulatory awareness of freshwater recreational bank anglers in South Africa 南非淡水休闲银行垂钓者的环境监管意识
IF 1.5 4区 环境科学与生态学 Q4 WATER RESOURCES Pub Date : 2022-10-26 DOI: 10.17159/wsa/2022.v48.i4.3986
A. Joubert, FP Retief, N. Smit, RC Alberts, V. Wepener, C. Roos
Freshwater recreational angling is growing in popularity internationally. Due to the potential negative environmental impacts, various regulatory systems exist. In South Africa, freshwater recreational angling is regulated through a complex legal framework, consisting of national and provincial legislation dating back to the 1960s. The legislation also relates to historical and current provincial boundaries, adding to the regulatory complexity. Due to this complexity, the question arises whether freshwater recreational bank anglers in South Africa are aware of the regulatory requirements applicable to them. Low levels of awareness could lead to non-compliance, which would suggest an ineffective regulatory system. The aim of this research was thus to determine the environmental regulatory awareness of freshwater recreational bank anglers in South Africa. This was achieved through a literature review of national and provincial legislation, as well as the rules applicable to organised freshwater recreational bank angling. An online survey was completed by 100 members of the South African Freshwater Bank Angling Federation (SAFBAF). The results of the survey indicate that the regulatory awareness of the sample of SAFBAF freshwater recreational anglers is low in certain key areas, such as bag and size limits for specific fish species, catch and release requirements, as well as legal definitions for alien and invasive and TOPS species listings. However, the low level of awareness can be ascribed to the complex regulatory system and not unwillingness of anglers to comply per se. It is recommended that (i) a single consolidated and simplified regulatory system for freshwater recreational bank angling be developed, and (ii) that angling organisational and competition rules be aligned with relevant regulatory requirements, to improve overall awareness and promote higher levels of regulatory compliance.
淡水休闲垂钓在国际上越来越受欢迎。由于潜在的负面环境影响,存在各种监管制度。在南非,淡水休闲垂钓是通过一个复杂的法律框架来管理的,包括可追溯到20世纪60年代的国家和省立法。立法还涉及历史和当前的省边界,增加了监管的复杂性。由于这种复杂性,南非的淡水休闲银行垂钓者是否意识到适用于他们的监管要求的问题就出现了。意识水平低可能导致不遵守,这表明监管体系无效。因此,本研究的目的是确定南非淡水休闲银行垂钓者的环境监管意识。这是通过对国家和省立法的文献综述以及适用于有组织的淡水休闲银行垂钓的规则实现的。南非淡水银行钓鱼联合会(SAFBAF)的100名成员完成了一项在线调查。调查结果表明,SAFBAF淡水休闲垂钓者样本在某些关键领域的监管意识较低,例如特定鱼类的袋和大小限制,捕捞和释放要求,以及外来和入侵物种和TOPS物种清单的法律定义。然而,低水平的意识可以归因于复杂的监管制度,而不是不愿意遵守本身。我们建议(i)为淡水康乐银行垂钓制定单一的综合及简化的规管制度,以及(ii)使垂钓的组织和比赛规则与相关的规管规定保持一致,以提高整体意识,并促进更严格地遵守规管规定。
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引用次数: 0
Membrane fouling in thermophilic aerobic membrane distillation bioreactor treating hospital wastewater 嗜热好氧膜蒸馏生物反应器处理医院废水的膜污染
IF 1.5 4区 环境科学与生态学 Q4 WATER RESOURCES Pub Date : 2022-10-26 DOI: 10.17159/wsa/2022.v48.i4.3930
Elif İnce, M. Ince, Handenur Yaşar, Yasin Abdullah Uslu
In the membrane distillation bioreactor (MDBR) process, flux increases with increasing feed temperature, but the presence of microorganisms limits the feed temperature. Also, the accumulation of cells and other substances on the membrane surface can affect the efficiency of MDBR. In this study, hospital wastewater was treated by thermophilic activated sludge MDBR. In the MDBR, the initial flux was 7.87 L‧m−2·h−1 and the stable flux was 3.88 L‧m−2·h−1. The particle size, zeta potential and hydrophobicity of the activated sludge in MDBR were 2.25 µm, −14 mV and 24%, respectively. In addition, EPS (extracellular polymeric substances) and SMP (soluble microbial products), having a significant effect on membrane fouling, were determined to be 201.50 mg·L−1 and 669.35 mg·L−1 in MDBR, respectively. Contact angle, FTIR (Fourier transform infrared), SEM (scanning electron microscope) and EDX (energy dispersive X-ray spectroscopy) measurements were also made on a virgin membrane and used membrane. Analysis of EDX, SEM and F-TIR showed that the membrane fouling was caused by CaCO3 and EPS.
在膜蒸馏生物反应器(MDBR)过程中,通量随进料温度的升高而增加,但微生物的存在限制了进料温度。此外,细胞和其他物质在膜表面的积聚也会影响MDBR的效率。本研究采用热敏活性污泥MDBR处理医院废水。在MDBR中,初始通量为7.87 L·m−2·h−1,稳定通量为3.88 L·m−2·h−1。MDBR中活性污泥的粒径为2.25µm, zeta电位为- 14 mV,疏水性为24%。此外,胞外聚合物(EPS)和可溶性微生物产物(SMP)对膜污染有显著影响,MDBR中的EPS和SMP分别为201.50 mg·L−1和669.35 mg·L−1。对原始膜和使用过的膜进行了接触角、FTIR(傅里叶变换红外)、SEM(扫描电子显微镜)和EDX(能量色散x射线光谱)测量。EDX、SEM和F-TIR分析表明,膜污染是由CaCO3和EPS引起的。
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引用次数: 1
A review of untreated household greywater quality to inform the water saving–risk trade-off in South Africa 对未经处理的家庭灰水质量的审查,以告知南非节水风险权衡
IF 1.5 4区 环境科学与生态学 Q4 WATER RESOURCES Pub Date : 2022-10-24 DOI: 10.17159/wsa/2022.v48.i4.3946
Heinz Erasmus Jacobs, Nicole Nel, Isobel Brink, Adesola Ilemobade
Interest in greywater reuse is increasing in South Africa, because of the potential to supplement scarce freshwater resources in the face of increasing demand and aridity.  This paper aims to inform the water saving–risk trade-off associated with residential untreated greywater use, through a statistical analysis of greywater quality results as sourced from prior South African studies. Greywater sources included in this review were the bathroom, kitchen, laundry, mixed and general residential sources. Variability in terms of each of the reported physical, chemical and microbiological constituents by source and between result sets was noted. Statistically significant differences were evident between the pH, conductivity and phosphorus values of certain sources. A risk assessment undertaken for each of the constituents revealed further variability. The constituent with the highest number of high-risk samples was total dissolved solids. The relatively high risk and negative consequences in greywater practices in terms of public health, the environment, and infrastructure, given this variability, provide insight into the trade-off with potential water savings. It is recommended that a more nuanced view of the potential potable savings associated with greywater reuse and also improved risk management is required by the user.
南非对回用灰水的兴趣日益增加,因为面对日益增长的需求和干旱,有可能补充稀缺的淡水资源。本文旨在通过对来自南非先前研究的灰水质量结果的统计分析,告知与住宅使用未经处理的灰水相关的节水风险权衡。本综述中的灰水来源包括浴室,厨房,洗衣房,混合和一般住宅来源。注意到报告的每一种物理、化学和微生物成分按来源和结果集之间存在差异。某些来源的pH值、电导率和磷值之间存在显著的统计学差异。对每种成分进行的风险评估揭示了进一步的可变性。高风险样品数量最多的成分是总溶解固体。鉴于这种可变性,灰水做法在公共卫生、环境和基础设施方面的风险和负面后果相对较高,因此可以深入了解其与潜在节水之间的权衡关系。建议用户对与灰水再利用相关的潜在饮用水节约和改进的风险管理有更细致的认识。
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引用次数: 0
Comparison of classic and chemometric methods used for phosphate removal from fresh human urine under optimum conditions 在最佳条件下从新鲜人尿中去除磷酸盐的经典和化学计量方法的比较
IF 1.5 4区 环境科学与生态学 Q4 WATER RESOURCES Pub Date : 2022-07-27 DOI: 10.17159/wsa/2022.v48.i3.3933
E Öztekin, S Çolak, H İnan
Human urine constitutes 1% of domestic wastewater and can be used to recover nitrogen and phosphorus when collected separately at source. Sustainable nutrient (nitrogen, phosphate, potassium) cycling requires the recovery of these valuable resources from human urine. As nitrogen and phosphorus are valuable nutrients needed for plant growth, these components of urine are an excellent fertilizer. Phosphorus can be applied in natural fertilizers and in addition the pollution load of wastewater treatment plants is reduced. Different nutrient removal and recovery methods from urine have been studied at lab scale, but none so far has reached technological competence and none has been extended to practical use. The focus of this study was to evaluate electrocoagulation as a process for the removal of phosphate from fresh human urine using iron plate electrodes. The effect of pH and current density on phosphate removal was investigated. While determining the optimum conditions for removal, classical and chemometric methods were compared. Using the central composite design (CCD), optimum conditions were determined with only 13 experiments, and time and labour savings were achieved compared to the classical method. Initial pH values and current density were controlled within the range of pH 5–9 and current density 12-40 mA/cm2.  From the obtained results, it was found that optimal initial current density is 40 mA/cm2 for both methods, and optimal pH is 7 for the classical method and 6.24 for CCD, which is the natural pH of human urine. Realization of phosphate removal using optimum conditions discovered with CCD, provides savings on experimental effort, time, chemicals and energy consumption, and will contribute to resource recovery, reduction of wastewater load and sustainable fertilizer production.
人尿占生活废水的1%,从源头单独收集可用于回收氮和磷。可持续的营养物质(氮、磷、钾)循环需要从人体尿液中回收这些宝贵的资源。由于氮和磷是植物生长所需的宝贵营养物质,尿液中的这些成分是极好的肥料。磷可以作为天然肥料施用,还可以减少污水处理厂的污染负荷。不同的从尿液中去除和回收营养物的方法已经在实验室规模上进行了研究,但到目前为止,还没有一种方法达到技术水平,也没有一种方法被推广到实际应用中。本研究的重点是评估电凝作为一种使用铁板电极从新鲜人尿中去除磷酸盐的方法。考察了pH和电流密度对除磷效果的影响。在确定最佳去除条件时,比较了经典法和化学计量法。采用中心复合设计(CCD),只需13次实验即可确定最佳条件,与传统方法相比节省了时间和人力。初始pH值和电流密度控制在5 ~ 9之间,电流密度控制在12 ~ 40 mA/cm2之间。结果表明,两种方法的最佳初始电流密度均为40 mA/cm2,经典方法的最佳pH为7,CCD方法的最佳pH为6.24,即人尿的自然pH值。利用CCD发现的最佳条件实现磷酸盐去除,节省了实验努力、时间、化学品和能源消耗,并将有助于资源回收、减少废水负荷和可持续肥料生产。
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引用次数: 1
Public perception of water re-use: building trust in alternative water sources in Malmesbury, South Africa 公众对水再利用的看法:在南非马姆斯伯里建立对替代水源的信任
IF 1.5 4区 环境科学与生态学 Q4 WATER RESOURCES Pub Date : 2022-07-27 DOI: 10.17159/wsa/2022.v48.i3.3872
Germaine Owen, Horman Chitonge
The recent drought in the Western Cape Province in South Africa has been marked as the worst since 1904.  The drought impacted severely on the availability of bulk water supply in many parts of the Western Cape Province, particularly the Cape Town Metro and surrounding districts. In order to alleviate water scarcity, wastewater recycling (water reuse) has been identified to have the potential to augment water supplies in the province. This paper argues that although water recycling has the potential to contribute towards alleviating water scarcity, studies have shown that public perceptions greatly influence the outcome of any water recycling scheme. The study collected data using face-to-face interviews, focus group discussions, and the application of the Story with a Gap participatory exercise. One of the key findings is that residents have to trust the municipal competencies and systems, and this can be achieved through meaningful engagement between the municipality and residents. We argue that rolling out a water reuse scheme by starting with affluent areas increases the likelihood of acceptance among low-income communities.
最近发生在南非西开普省的干旱是自1904年以来最严重的一次。干旱严重影响了西开普省许多地区的散装水供应,特别是开普敦地铁和周边地区。为了缓解水资源短缺,废水回收(水再利用)已被确定具有增加该省供水的潜力。本文认为,尽管水循环有可能有助于缓解水资源短缺,但研究表明,公众的看法极大地影响了任何水循环方案的结果。该研究通过面对面访谈、焦点小组讨论和将故事应用于Gap参与性练习来收集数据。其中一个重要发现是,居民必须信任市政当局的能力和系统,这可以通过市政当局和居民之间有意义的参与来实现。我们认为,从富裕地区开始推出水再利用计划,可以增加低收入社区接受该计划的可能性。
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引用次数: 0
How local communities access, utilise and evaluate inland fisheries, and their influence on fishery conservation status in northern Zimbabwe 当地社区如何获取、利用和评估内陆渔业及其对津巴布韦北部渔业保护状况的影响
IF 1.5 4区 环境科学与生态学 Q4 WATER RESOURCES Pub Date : 2022-07-27 DOI: 10.17159/wsa/2022.v48.i3.3885
Beaven Utete, Olga Laiza Kupika, Precious Mahlatini, Tapiwa Nyachowe
The conservation status of inland fishery resources is vulnerable worldwide, and this threatens the livelihoods of fishing-dependent communities. This case study aimed to: (i) establish the use and perception of fisheries and ecosystem services by locals, (ii) undertake a monetary valuation of the fisheries, (iii) determine the potential threats to the fisheries, and (iv) examine the social drivers and barriers for citizen science involvement. Lastly, (v) we evaluated how the above factors affected the conservation of fisheries at Mushumbi Pools, Zimbabwe. A cross-sectional survey of 69 households was conducted. Results of the study showed that locals utilised 17 fish species for social, economic, cultural and religious purposes. Locals attach high intrinsic socio-economic value to the fisheries resources and wetland ecosystem services provided by the Mushumbi Pools. Despite the sustained income from fisheries, the local market in Mushumbi Pools is actually undervaluing fisheries resources, as the fish prices in the area are very low compared to standard market prices countrywide. A larger proportion of the respondents (65%) cited poor land-tilling practices, heavy application of agropesticides and use of unsustainable fish harvesting methods as the main threats to fish diversity in Mushumbi Pools. Relaxed fishing concessions for women and children in specific fishing zones were key drivers for community participation in fisheries conservation. However, strict enforcement of fishing bans in breeding and nursery zones and restricted access to some parts of the Mushumbi Pools were the main barriers for local involvement in the conservation of fisheries resources. Without the fishing community’s participation there is no guaranteed sustainability of the fishery resources in the pools. Legitimising community access, ensuring fair valuation and utility rights is a key driver for successful management of inland fisheries resources in Sub-Saharan Africa.
在世界范围内,内陆渔业资源的保护状况是脆弱的,这威胁到依赖渔业的社区的生计。本案例研究旨在:(i)建立当地人对渔业和生态系统服务的使用和认知,(ii)对渔业进行货币评估,(iii)确定对渔业的潜在威胁,以及(iv)检查公民科学参与的社会驱动因素和障碍。最后,我们评估了上述因素如何影响津巴布韦Mushumbi Pools的渔业保护。对69户家庭进行了横断面调查。研究结果显示,本港有17种鱼类用作社会、经济、文化及宗教用途。当地人认为Mushumbi水塘提供的渔业资源和湿地生态系统服务具有很高的内在社会经济价值。尽管渔业带来了持续的收入,但Mushumbi Pools的当地市场实际上低估了渔业资源,因为与全国标准市场价格相比,该地区的鱼类价格非常低。较大比例的答复者(65%)指出,不良的耕作方式、大量使用农用农药和使用不可持续的鱼类捕捞方法是对Mushumbi池鱼类多样性的主要威胁。在特定渔区对妇女和儿童放宽捕鱼特许权是推动社区参与渔业养护的关键因素。然而,在繁殖区和苗圃区严格执行捕鱼禁令和限制进入Mushumbi池的某些部分是当地参与养护渔业资源的主要障碍。没有渔业社区的参与,就无法保证池中渔业资源的可持续性。使社区获取合法化、确保公平估值和公用事业权利是撒哈拉以南非洲内陆渔业资源成功管理的关键驱动因素。
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引用次数: 0
Experimental investigation of the discharge coefficient of labyrinth weirs with asymmetric cycles 非对称循环迷宫堰流量系数的试验研究
IF 1.5 4区 环境科学与生态学 Q4 WATER RESOURCES Pub Date : 2022-07-27 DOI: 10.17159/wsa/2022.v48.i3.3911
Hossein Elahifar, Omid Tayari, Najme Yazdanpanah, Mehdi Momeni
This  study investigated the discharge coefficient in asymmetric rectangular labyrinth weirs. A dimensional analysis was carried out which showed that the discharge coefficient is a function of dimensionless parameters, such as the ratio of asymmetric widths of left and right cycles (wL/wR), the ratio of the total hydraulic head to the weir height (Ht/P), and the weir length ratio (B/wavg). The experimental results for the discharge coefficient were found to decline as wL/wR increased or B/wavg decreased. For wL/wR = 1.19, the ratio B/wavg = 2.76 improves the discharge coefficient by nearly 12.7% compared to B/wavg = 3.1. For wL/wR = 1.42, the ratio B/wavg = 2.76 improves the discharge coefficient by nearly 34.2% compared to B/wavg = 3.1. For wL/wR = 1.70, the ratio B/wavg = 2.76 improves the discharge coefficient by nearly 30% compared to B/wavg = 3.1.
研究了不对称矩形迷宫堰的流量系数。量纲分析表明,流量系数是左右循环不对称宽度比(wL/wR)、总水头与堰高比(Ht/P)、堰长比(B/wavg)等无量纲参数的函数。实验结果表明,流量系数随水宽比增大或波宽比减小而减小。当wL/wR = 1.19时,B/wavg = 2.76比B/wavg = 3.1提高了近12.7%的流量系数。当wL/wR = 1.42时,B/wavg = 2.76比B/wavg = 3.1提高了近34.2%的流量系数。当wL/wR = 1.70时,B/wavg = 2.76比B/wavg = 3.1提高了近30%的流量系数。
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引用次数: 0
Optimization, characterization and adsorption properties of natural calcite for toxic As(III) removal from aqueous solutions 天然方解石去除水中有毒砷(III)的优化、表征及吸附性能
IF 1.5 4区 环境科学与生态学 Q4 WATER RESOURCES Pub Date : 2022-07-27 DOI: 10.17159/wsa/2022.v48.i3.3909
K. H. Shah, M. Fahad, Z. Ghazi, Sajjad Ali, Asim Shahzad, Salah ud Din
The potential of natural (N) and magnetized (M) forms of different rocks (calcite and dolomite) and clays (bentonite, kaolinite, and hematite) were evaluated for the removal of As(III) from aqueous solutions, in order to optimize and scrutinize the most suitable adsorbent. The order observed for efficiency of As(III) removal was N-calcite > N-dolomite > M-calcite > M-dolomite > N-bentonite > M-bentonite > M-kaolinite > N-kaolinite > M-hematite > N-hematite. On the basis of this analysis, natural calcite was further selected for in-depth analysis of various adsorption parameters such as time, pH, temperature, dosage, and concentration of As(III) ions. An excellent adsorption capacity of 19.05 mg‧g−1 was displayed by calcite for As(III), which was significantly higher than that previously reported for other studies. The characterization of adsorbent calcite was performed by various analytical techniques:XRD, XRF, FTIR, SEM-EDS, TG/DTA and PZC. The kinetic investigation revealed that the adsorbent successfully removed over 98% of As(III) from aqueous solution after 160 minutes of equilibration time. The adsorption data was well fitted to the Freundlich isotherm model and fairly described by the pseudo-second-order mechanism. The mean energy of adsorption (E) determined from the Dubinin-Radushkevich (D-R) model was less than 8 kJ‧mol-1 , which indicates a physical adsorption process. The calculated thermodynamic parameters revealed that the adsorption of As(III) by calcite is endothermic, favourable and spontaneous.
评估了不同岩石(方解石和白云石)和粘土(膨润土、高岭石和赤铁矿)的天然(N)和磁化(M)形式对水溶液中As(III)的去除潜力,以优化和审查最合适的吸附剂。As(III)的去除率顺序为n -方解石> n -白云石> m -方解石> m -白云石> n -膨润土> m -膨润土> m -高岭石> n -高岭石> m -赤铁矿> n -赤铁矿。在此基础上,进一步选择天然方解石,深入分析时间、pH、温度、用量、浓度等对as (III)离子的各种吸附参数。方解石对As(III)的吸附量为19.05 mg·g−1,明显高于其他研究报道。采用XRD、XRF、FTIR、SEM-EDS、TG/DTA、PZC等分析技术对吸附方解石进行了表征。动力学研究表明,经过160分钟的平衡时间,吸附剂成功地从水溶液中去除了98%以上的As(III)。吸附数据与Freundlich等温线模型拟合较好,用拟二级机理描述较好。Dubinin-Radushkevich (D-R)模型的平均吸附能(E)小于8 kJ·mol-1,表明吸附过程为物理吸附过程。计算的热力学参数表明,方解石对As(III)的吸附是吸热的、有利的和自发的。
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引用次数: 1
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