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Canola (Brassica napus L.) water use indicators as affected by sustained deficit irrigation and plant density in central Free State, South Africa 持续亏缺灌溉和植物密度对南非中部自由邦油菜水分利用指标的影响
IF 1.5 4区 环境科学与生态学 Q4 WATER RESOURCES Pub Date : 2023-04-28 DOI: 10.17159/wsa/2023.v49.i2.3965
KA Seetseng, JH Barnard, LD van Rensburg, CC du Preez
In South Africa canola (Brassica napus L.) is cultivated in rotation with wheat under winter rainfall in the Western Cape Province, primarily for seed to make oil. Expansion of the crop to the other 8 provinces is proposed to reduce shortages of locally produced plant oils. At the same time, canola can serve as a rotational crop for wheat in these summer rainfall provinces. In central Free State, information on evapotranspiration and various water use indicators for canola as influenced by sustained deficit irrigation and plant density is lacking. An experiment with a line source sprinkler irrigation system was therefore conducted, comprising of full irrigation as a control with 4 sustained deficit irrigation levels (mean reduction in irrigation depth per event of 67%, 52%, 34% and 19%) and 5 plant densities (25, 50, 75, 100 and 125 plants‧m−2). Mean seasonal maximum evapotranspiration amounted to 429 mm across plant densities. Plant density did not significantly influence seasonal evapotranspiration. Reducing the irrigation depth per event by more than 20% decreased seasonal evapotranspiration by a mean 3.5 mm per percentage increase in irrigation depth. A maximum biomass water productivity of 22 kg‧ha−1‧mm−1 was measured with full irrigation and a plant density of 75 plants‧m−2. Seed water productivity amounted to a high of 11 kg‧ha−1‧mm−1 with full irrigation and a plant density of 25 plants‧m−2. A percentage reduction in irrigation depth and increase in plant density above 25 plants‧m−2 will reduce seed water productivity by 0.071 and 0.033 kg‧ha−1‧mm−1, respectively. Sustained deficit irrigation increased water use efficiency by a mean 0.5% per percentage reduction in irrigation depth per event.
在南非,在西开普省,油菜(Brassica napus L.)在冬季降雨时与小麦轮作种植,主要用于种子制油。建议将这种作物推广到其他8个省份,以减少当地生产的植物油的短缺。同时,在这些夏季多雨的省份,油菜可以作为小麦的轮作作物。在自由邦中部,缺乏关于油菜籽受持续亏缺灌溉和植物密度影响的蒸散量和各种用水指标的资料。试验采用线源喷灌系统,采用4个持续亏缺灌溉水平(每次事件平均灌溉深度减少67%、52%、34%和19%)和5个植物密度(25、50、75、100和125株·m−2)进行全面灌溉作为对照。不同植物密度的季节平均最大蒸散量为429 mm。植物密度对季节蒸散量影响不显著。每次灌溉深度减少20%以上,灌溉深度每增加一个百分比,季节蒸散量平均减少3.5毫米。在充分灌溉和植物密度为75株·m - 2的情况下,生物量水分生产力最高为22 kg·ha·1·mm - 1。在充分灌溉和种植密度为25株·m−2的情况下,种子水分生产力高达11 kg·ha·1·mm−1。灌溉深度若减少百分之一,而种植密度若增加至25株·ha·1·mm−1以上,则种子水分生产力将分别减少0.071及0.033 kg·ha·1·mm−1。持续亏缺灌溉每减少一次灌溉深度,水利用效率平均提高0.5%。
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引用次数: 0
The use of stable isotopes to identify surface water–groundwater interaction in the Kruger National Park, South Africa 在南非克鲁格国家公园,使用稳定同位素来确定地表水与地下水的相互作用
IF 1.5 4区 环境科学与生态学 Q4 WATER RESOURCES Pub Date : 2023-04-28 DOI: 10.17159/wsa/2023.v49.i2.3992
RM Petersen, JM Nel, T Strydom, E Riddell, C Coetsee, E February
The role of groundwater, in general, is often overlooked in freshwater ecosystem management policies and in the management of South Africa’s flagship conservation area, the Kruger National Park (KNP). To address this gap, a generalised conceptual model of surface water–ground water (sw–gw) interactions in the southern and central regions of the KNP was developed. To do this, stable isotope ratios (d18O and d2H) of groundwater, rainfall and surface water were used to determine the extent to which the base flow of perennial, seasonal and ephemeral streams on different geologies (granite vs. basalt) is driven by rainfall or groundwater. These results show that the δ18O and δ2H ratios of perennial rivers are similar to that of groundwater, while seasonal and ephemeral rivers on basalts have values closer to rainfall. On granite substrates, however, the isotope ratios of the seasonal and ephemeral rivers have values closer to groundwater than rainfall. The larger seasonal Mbyamiti River had similar isotope ratios to that of groundwater, and the highly ephemeral Nwaswitsontso had episodic interaction with groundwater (i.e. isotopic ratios overlap occasionally). These results show that decisions necessary for the sustainable management of groundwater resources are better informed when the natural interaction, movement, and exchange between groundwater and rivers are understood. This has particular relevance for large conservation areas in southern Africa that are expected to experience more variable climates in the future with both increases in drought and rainfall intensities.
一般来说,在淡水生态系统管理政策和南非的旗舰保护区克鲁格国家公园(KNP)的管理中,地下水的作用经常被忽视。为了解决这一差距,开发了KNP南部和中部地区地表水-地下水(sw-gw)相互作用的广义概念模型。为此,使用地下水、降雨和地表水的稳定同位素比率(d18O和d2H)来确定不同地质(花岗岩与玄武岩)上的多年生、季节性和短暂溪流的基流受降雨或地下水驱动的程度。这些结果表明,多年生河流的δ18O和δ2H值与地下水相似,而玄武岩上的季节性和短暂性河流的δ18O和δ2H值更接近于降雨。然而,在花岗岩基质上,季节性和短暂性河流的同位素比值值更接近地下水,而不是降雨。较大的季节性Mbyamiti河与地下水具有相似的同位素比值,而高度短暂的Nwaswitsontso河与地下水具有偶然性的相互作用(即同位素比值偶尔重叠)。这些结果表明,当了解地下水与河流之间的自然相互作用、运动和交换时,地下水资源可持续管理所需的决策就会更好。这对南部非洲的大型自然保护区尤其重要,预计这些地区未来的气候将更加多变,干旱和降雨强度都将增加。
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引用次数: 0
Using SPI and SPEI for baseline probabilities and seasonal drought prediction in two agricultural regions of the Western Cape, South Africa 利用SPI和SPEI对南非西开普省两个农业区的基线概率和季节性干旱进行预测
IF 1.5 4区 环境科学与生态学 Q4 WATER RESOURCES Pub Date : 2023-04-28 DOI: 10.17159/wsa/2023.v49.i2.4026
SN Theron, E Archer, CJ Engelbrecht, S Midgley, S Walker
Drought is one of the most hazardous natural disasters in terms of the number of people directly affected. An important characteristic of drought is the prolonged absence of rainfall relative to the long-term average. The intrinsic persistence of drought conditions continuing from one month to the next can be utilized for drought monitoring and early warning systems. This study sought to better understand drought probabilities and baselines for two agriculturally important rainfall regions in the Western Cape, South Africa – one with a distinct rainfall season and one which receives year-round rainfall. The drought indices, Standardised Precipitation and Evapotranspiration Index (SPEI) and Standardised Precipitation Index (SPI), were assessed to obtain predictive information and establish a set of baseline probabilities for drought. Two sets of synthetic time-series data were used (one where seasonality was retained and one where seasonality was removed), along with observed data of monthly rainfall and minimum and maximum temperature. Based on the inherent persistence characteristics, autocorrelation was used to obtain a probability density function of the future state of the various SPI start and lead times. Optimal persistence was also established. The validity of the methodology was then examined by application to the recent Cape Town drought (2015–2018). Results showed potential for this methodology to be applied in drought early warning systems and decision support tools for the province.
就直接受影响的人数而言,干旱是最危险的自然灾害之一。干旱的一个重要特征是相对于长期平均水平,长时间缺乏降雨。干旱条件从一个月持续到下一个月的内在持续性可以用于干旱监测和预警系统。这项研究试图更好地了解南非西开普省两个农业上重要的降雨地区的干旱概率和基线——一个有独特的降雨季节,另一个全年降雨。通过对标准化降水和蒸散指数(SPEI)和标准化降水指数(SPI)进行评估,获得预测信息,建立干旱基线概率。使用了两组合成时间序列数据(一组保留季节性,另一组去除季节性),以及月降雨量和最低和最高温度的观测数据。基于SPI固有的持续特性,利用自相关得到了SPI各启动和提前期未来状态的概率密度函数。并建立了最优持久性。然后通过应用于最近的开普敦干旱(2015-2018)来检验该方法的有效性。结果表明,该方法有潜力应用于该省的干旱预警系统和决策支持工具。
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引用次数: 0
Comprehensive characterization of selected South African brines 选定的南非卤水的综合特性
IF 1.5 4区 环境科学与生态学 Q4 WATER RESOURCES Pub Date : 2023-04-28 DOI: 10.17159/wsa/2023.v49.i2.3957
Brenda Mehlo, Alison Lewis, Jemitias Chivavava
South Africa produces significant quantities of brines but there is insufficient information on their biological and physicochemical characteristics and nature, which limits the ability to propose sustainable brine handling procedures. This study aimed to comprehensively characterize selected brines from major brine-producing industries in South Africa. This was achieved through an analysis of the majority of the brine constituents, thereby allowing for the proposal of suitable brine handling procedures, the identification and harnessing of potential economic value, as well as the identification of the environmental impact of the brines. The brines were analysed for physical, metallic, organic, and inorganic constituents using a variety of methods including inductively coupled plasma-mass spectrometry (ICP-MS) and gas chromatography-mass spectrometry (GC-MS). The total dissolved solids (TDS) of most of the brines was below 35 000 mg/L and it was concluded that most South African brines may be brackish. All the brines contained toxic constituents in concentrations that exceeded set discharge and re-use limits. It was concluded that comprehensive characterization is crucial in understanding the quality of brines and is a crucial step in proposing suitable brine handling strategies.
南非生产大量盐水,但关于其生物和物理化学特性和性质的资料不足,这限制了提出可持续盐水处理程序的能力。本研究的目的是全面表征从南非主要卤水生产工业选定的卤水。这是通过对大多数卤水成分的分析来实现的,从而可以提出适当的卤水处理程序,确定和利用潜在的经济价值,以及确定卤水对环境的影响。采用电感耦合等离子体质谱(ICP-MS)和气相色谱-质谱(GC-MS)等多种方法对盐水进行物理、金属、有机和无机成分的分析。大多数南非卤水的总溶解固体(TDS)低于35000 mg/L,结论是大多数南非卤水可能是微咸的。所有卤水中有毒成分的浓度都超过了排放和再利用限制。综合表征是了解盐水质量的关键,也是提出合适的盐水处理策略的关键步骤。
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引用次数: 0
Water quality characteristics of Vanderkloof Dam and its potential for rainbow trout farming 万德克鲁夫大坝水质特征及其虹鳟鱼养殖潜力
IF 1.5 4区 环境科学与生态学 Q4 WATER RESOURCES Pub Date : 2023-04-28 DOI: 10.17159/wsa/2023.v49.i2.3919
KG Seanego, GC Pitcher, TA Probyn, A Du Randt, LM Mansfield
Vanderkloof Dam was periodically sampled between November 2014 and April 2016 for a range of water quality parameters to assess the potential for cage culture of rainbow trout, Oncorhyncus mykiss.  The dam is strongly stratified in summer and autumn, although upper water column temperatures remain relatively cool, largely <25°C. The dam is considered oligotrophic, characterised by phosphorus limitation of primary production, particularly during summer. Light is strongly attenuated in the epilimnion and heterotrophic community metabolism is observed through much of the water column. Surface nutrients are depleted through the summer with phytoplankton assemblages dominated by the green algae, Oocystis lacustris, Desmodesmus bicaudatus and Coelastrum microporum. The water column turns over during the winter and the nearly isothermal impoundment approaches 11°C. Nutrients are re-introduced into surface waters following winter mixing coincident with an increase in diatoms. The preferred environmental window for rainbow trout becomes severely contracted during the summer in that epilimnion temperatures exceed 21°C and thermocline/hypolimnion oxygen concentrations fall below 3 mg‧L−1. The coincidence of relatively high pH >9.5 could exacerbate these physiological challenges. Hydrological conditions for fish farming are most suitable in the proximity of the dam wall as opposed to further upstream. Here the hypoxic conditions that develop in the thermocline/hypolimnion during summer and autumn are less pronounced, particularly towards the southern bank, where concentrations of total suspended solids are generally <10 mg‧L−1 and water clarity is more favourable for visual feeders such as fish. Although rainbow trout may survive the adverse conditions prevalent during the summer, growth is likely to be compromised and susceptibility to disease may increase.
在2014年11月至2016年4月期间,对Vanderkloof大坝进行了定期采样,以获取一系列水质参数,以评估虹鳟网箱养殖的潜力。在夏季和秋季,大坝是强烈分层的,尽管上层水柱温度相对较低,但9.5℃可能会加剧这些生理挑战。相对于更上游的地方,靠近大坝的地方的水文条件最适合养鱼。在这里,夏秋季节在温跃层/低阴离子中形成的缺氧情况不太明显,特别是南岸,总悬浮固体浓度通常<10 mg·L−1,水的清澈度更有利于鱼类等视觉食性动物。虽然虹鳟鱼可以在夏季普遍存在的不利条件下存活,但生长可能受到损害,对疾病的易感性可能增加。
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引用次数: 0
Production of subsurface drip-irrigated okra under different lateral spacings and irrigation frequencies 不同侧距和灌溉频率下地下滴灌秋葵的产量
IF 1.5 4区 环境科学与生态学 Q4 WATER RESOURCES Pub Date : 2023-04-28 DOI: 10.17159/wsa/2023.v49.i2.3990
Narender Kumar, Sanjay Kumar, Darshana Duhan, Amandeep Singh, MS Sidhpuria, Sundeep Kumar Antil, Ashish Kumar, Vikas
In this study, an experiment was conducted to investigate the optimum lateral spacing and irrigation frequency for subsurface drip irrigated okra in the semi-arid region of Haryana (India). Two lateral spacings (45 cm and 60 cm) and four irrigation frequencies (daily, after 1, 2 and 3 days) were selected to grow okra in the Kharif season of 2019 and 2020. The effect on soil water dynamics, growth parameters, efficiency and yield were assessed using equal amounts of water under all the treatments on the basis of pan evaporation. The results from the study depict that the overall soil moisture decreased laterally, but increased vertically downward with the increase in the irrigation interval. On the basis of soil water dynamics, plant growth parameters, efficiency and yield of okra, it was concluded that subsurface drip irrigation with daily irrigation at 45 cm lateral spacing gives better performance than all other treatments in sandy loam soil. The present study highlights the significance of proper irrigation frequency and lateral spacing for maximum production of okra. Using these guidelines, the income of okra growers/farmers in the semi-arid region may be increased by choosing the best frequency and lateral spacing of subsurface drip irrigation.
本研究在印度哈里亚纳邦半干旱区进行了秋葵地下滴灌的最佳横向间距和灌溉频率试验。在2019年和2020年哈里夫季,选择了2个横向间距(45 cm和60 cm)和4个灌溉频率(每天、1天、2天和3天)种植秋葵。在蒸发皿蒸发量相等的基础上,评价了各处理对土壤水分动态、生长参数、效率和产量的影响。研究结果表明,随着灌溉间隔的增加,总体土壤湿度横向呈下降趋势,纵向呈下降趋势。综合土壤水分动态、植物生长参数、秋葵效率和产量等因素,在砂壤土上,地下滴灌日灌45 cm的处理效果较好。本研究强调了适当的灌溉频率和侧间距对秋葵产量最大化的重要性。在此指导下,半干旱区秋葵种植户可通过选择最佳地下滴灌频率和横向滴灌间距来提高收入。
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引用次数: 1
Estimation of the 2D cross-sectional area of the wetting pattern under drip irrigation and spatio-temporal variation of the components of the wetting pattern 滴灌条件下湿润型二维截面积估算及湿润型各组成部分的时空变化
IF 1.5 4区 环境科学与生态学 Q4 WATER RESOURCES Pub Date : 2023-04-24 DOI: 10.17159/wsa/2023.v49.i2.3942
Murat Kilic
The wetting pattern which occurs under surface drip irrigation is an important component for the optimum design of the system and for irrigation programming. The aim of this investigation was to devise a model which enables estimation of the 2D cross-sectional area of the wetting pattern which occurs under a surface dripper by an analytical method. The main parameters of the wetting pattern are the wetting diameter on the soil surface, the maximum wetted depth and maximum wetted width in the soil profile, and the depth of this maximum wetted width from the soil surface. In the laboratory experiments, water applications were carried out on two soil textures (clay loam and clay) with homogeneous soil profiles at two discharge rates over 125 min and 170 min periods. The sizes of the parameters of the wetting pattern were measured as consecutive series over 5-min intervals during the water application period. The general/main shape which represents the wetting patterns which occur under different irrigation conditions was defined and mathematically modelled. When the results were evaluated statistically, a correlation of 0.9128 was found between the momentary rates of change of the maximum depth of the wetting pattern predicted by the model and those measured in the experiment. The correlation between the momentary variations of accelerations of the same parameter was 0.9205. In addition, the size of the wetting pattern showed an increment in reducing velocities during the water application period. The results indicate that the model devised in this investigation can be used in the prediction of the cross-sectional area of the wetting pattern which occurs under a surface dripper.
地表滴灌下的湿润模式是滴灌系统优化设计和灌溉规划的重要组成部分。本研究的目的是设计一个模型,该模型可以通过分析方法估计表面滴管下发生的润湿模式的二维横截面积。湿化模式的主要参数是土壤表面的湿化直径、土壤剖面上的最大湿化深度和最大湿化宽度以及最大湿化宽度距离土壤表面的深度。在室内试验中,以两种土壤质地(粘壤土和粘土)为研究对象,在125 min和170 min的排水速率下进行了水处理。在施水期间,以连续5分钟的间隔测量润湿模式参数的大小。定义了在不同灌溉条件下发生的湿润模式的一般/主要形状,并建立了数学模型。结果表明,模型预测的最大润湿型深度瞬时变化率与实验测量值的相关系数为0.9128。同一参数下加速度瞬时变化的相关系数为0.9205。此外,在加水期间,润湿模式的大小表现出减少速度的增加。结果表明,所设计的模型可用于预测表面滴管下的润湿模式的横截面积。
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引用次数: 0
AquaSens: exploring the use of 16S rRNA next-generation sequencing to determine bacterial composition of various water matrices AquaSens:探索使用16S rRNA下一代测序来确定各种水基质的细菌组成
IF 1.5 4区 环境科学与生态学 Q4 WATER RESOURCES Pub Date : 2023-04-24 DOI: 10.17159/wsa/2023.v49.i2.3956
Nisreen Hoosain, Jeanne Korsman, Peter O Kimathi, Paidamoyo Kachambwa, Rembu Magoba, Shane L Murray
Access to clean water, one of the United Nation’s Sustainable Development Goals, is challenged by an increase in the presence of emerging microbial and other contaminants due to urbanization, among other factors. Traditionally, the presence of indicator microorganisms is determined using culturing methods. However, these classical methods cannot be used to determine the identities of ‘unknown’ bacteria and is limited to isolating the culturable state of microorganisms. Thus with culturing, the identities of many bacteria, particularly novel or non-culturable, may remain unknown. The use of a DNA-based method, 16S rRNA next-generation sequencing (NGS), can assist with determining the identities of bacterial populations in a water sample. The objective of this 16S rRNA NGS study was to investigate the bacterial community composition and diversity in a range of water sources. Water samples comprising of potable, surface, ground, marine, aquaculture, rain, wetland and swimming bath water matrices were subjected to 16S rRNA NGS using the Illumina 16S rRNA Metagenomics analysis pipeline. Operational taxonomic units were analysed and the identities of bacterial genera determined. In this study, genera of Acinetobacter, Mycobacterium, Pseudomonas, Legionella, Burkholderia, Yersinia, Staphylococcus and Vibrio were spread across the water matrices. Alpha (within sample) and beta (between samples) diversities for each bacterial community within the tested samples were also determined.
清洁水是联合国可持续发展目标之一,但由于城市化等因素,新出现的微生物和其他污染物的增加,对清洁水的获取提出了挑战。传统上,指示微生物的存在是通过培养方法来确定的。然而,这些经典方法不能用于确定“未知”细菌的身份,并且仅限于分离微生物的可培养状态。因此,通过培养,许多细菌的特性,特别是新的或不可培养的,可能仍然是未知的。使用基于dna的方法,16S rRNA下一代测序(NGS),可以帮助确定水样中细菌群体的身份。本16S rRNA NGS研究的目的是研究一系列水源中细菌群落的组成和多样性。使用Illumina 16S rRNA宏基因组学分析管道,对饮用水、地表水、地面水、海洋水、水产养殖水、雨水、湿地和游泳浴水基质进行16S rRNA NGS检测。分析了操作分类单位,确定了细菌属的身份。在本研究中,不动杆菌属、分枝杆菌属、假单胞菌属、军团菌属、伯克霍尔德氏菌属、耶尔森氏菌属、葡萄球菌属和弧菌属分布在水基质中。还确定了测试样品中每个细菌群落的α(样品内)和β(样品之间)多样性。
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引用次数: 1
On the use of late-time drawdown in interpreting aquifer pumping test 后期降差在含水层抽水试验解释中的应用
IF 1.5 4区 环境科学与生态学 Q4 WATER RESOURCES Pub Date : 2023-01-31 DOI: 10.17159/wsa/2023.v49.i1.3984
M Gomo
The review aims to provide a common understanding of the use of late-time drawdown to interpret aquifer pumping tests. The first part of the review provides an overview of the use of the late-time drawdown in literature to illustrate where and how the term is being used. A discussion on the practical implications of using the term and its significance is then presented. The review shows the use of the late-time drawdown in three main ways: the application of the Cooper and Jacob time-drawdown method, the description of the third segment of the unconfined aquifer drawdown-time curve, and when trying to estimate representative/effective transmissivity parameters in heterogeneous aquifers. Unlike the other two situations, the use of late-time data in typical unconfined aquifers is supported by the groundwater flow principles and hence has a meaningful application. The aspects highlighted in this review are important to improve the theoretical and practical knowledge required for analysing and interpreting aquifer pumping test data.
这篇综述的目的是为使用后期降差来解释含水层抽水试验提供一个共同的理解。回顾的第一部分概述了文献中使用的后期缩减,以说明该术语在何处以及如何使用。然后讨论了使用该术语的实际含义及其意义。回顾显示了三种主要的后期递减方法:Cooper和Jacob时间递减法的应用,无承压含水层递减时间曲线第三段的描述,以及在非均质含水层中尝试估计代表性/有效透射率参数。与其他两种情况不同,在典型的无承压含水层中使用后期数据得到地下水流动原理的支持,因此具有重要的应用价值。这篇综述强调的方面对于提高分析和解释含水层抽水试验数据所需的理论和实践知识是重要的。
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引用次数: 0
Adsorptive removal of BTEX compounds from wastewater using activated carbon derived from macadamia nut shells 用源自夏威夷坚果壳的活性炭吸附去除废水中的BTEX化合物
IF 1.5 4区 环境科学与生态学 Q4 WATER RESOURCES Pub Date : 2023-01-31 DOI: 10.17159/wsa/2023.v49.i1.3970
Kedibone Melaphi, Olawumi O Sadare, Geoffrey S Simate, Stephan Wagenaar, Kapil Moothi
In this study, adsorptive removal of benzene, toluene, ethylbenzene and xylenes (BTEX) from synthetic water using activated carbon adsorbent derived from macadamia nut shells was investigated. The surface functional groups of the synthesized adsorbents were assessed by Fourier transform infrared spectra. The specific surface area, pore size and pore volume at 77 K nitrogen adsorption, surface morphology, and the crystalline structure of the adsorbents were determined using Brunauer-Emmett-Teller, scanning electron microscopy and x-ray diffraction, respectively. Batch adsorption mode was used to evaluate the performance of the activated carbon.  The stock solutions of synthetic wastewater were prepared by dissolving 100 mg/L of each of the BTEX compound into distilled water in a 250 mL volumetric flask. Effect of initial concentration of BTEX compounds, contact time, and mass of adsorbent on the removal of BTEX compounds from the synthetic wastewater was investigated. The macadamia nut shell–derived activated carbon (MAC) proved to be an effective adsorbent for BTEX compounds, with a large surface area of 405.56 m2/g. The exposure time to reach equilibrium for maximum removal of BTEX was observed to be 20 min.  The adsorption capacity of the BTEX compounds by MAC followed the following adsorption order: benzene > toluene > ethylbenzene ˃ xylene.
研究了以澳洲坚果壳为原料制备的活性炭吸附剂对合成水中苯、甲苯、乙苯和二甲苯(BTEX)的吸附去除。利用傅里叶变换红外光谱对合成吸附剂的表面官能团进行了表征。采用brunauer - emmet - teller、扫描电镜和x射线衍射分别测定了吸附剂在77 K氮气吸附时的比表面积、孔径和孔体积、表面形貌和晶体结构。采用间歇吸附方式对活性炭的性能进行了评价。制备合成废水的原液,将每种BTEX化合物100 mg/L溶于250 mL容量瓶中的蒸馏水中。考察了BTEX化合物的初始浓度、接触时间和吸附剂质量对合成废水中BTEX化合物去除率的影响。夏威夷果壳活性炭(MAC)具有405.56 m2/g的表面积,是一种有效的BTEX类化合物吸附剂。观察到达到最大去除BTEX平衡的暴露时间为20 min。MAC对BTEX化合物的吸附量顺序为:苯>甲苯>乙苯_二甲苯。
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引用次数: 1
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