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SP-179: Fourth CANMET/ACI/JCI Conference: Advances in Concrete Technology最新文献

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New Super-plasticizers Based on Modified Melamine Polymer 基于改性三聚氰胺聚合物的新型高效增塑剂
I. Torresan, R. Khurana
Admixtures based on sulfonate melamine formaldehyde condensate polymer (SM) have been available commercially for more than three decades. These products are widely used by the precast concrete industry, but with some limitations on slump retention and early strength. To improve these properties, synthesis of a modified sulfonate melamine formaldehyde condensate polymer (MSM) was performed. In this paper its physical and chemical characteristics are reported. Dispersibility and adsorption tests, using cement pastes, were carried out to compare the superplasticizing effect of the new MSM polymer against the SM polymer. Concrete mixtures were also made to evaluate the performances of this MSM polymer in comparison with the other types of superplasticizers such as SM and beta-naphthalene sulfonate formaldehyde condensate (SN). Results of these tests show that MSM polymer has a better water reduction capacity, lower air content in the fresh concrete and higher early strength at 1 day as compared to the other superplasticizers under the test conditions. These characteristics are very much desired by the precast industry for easy placement of concrete and quick turn around of the formworks. Field tests also reported, confirm the laboratory findings.
基于磺酸三聚氰胺甲醛凝聚聚合物(SM)的外加剂已经在商业上使用了三十多年。这些产品广泛应用于预制混凝土行业,但在坍落度保持和早期强度方面存在一定的局限性。为了改善这些性能,合成了一种改性的磺酸三聚氰胺甲醛凝聚聚合物(MSM)。本文报道了其理化特性。采用水泥浆体进行了分散性和吸附试验,比较了新型MSM聚合物与SM聚合物的超塑效果。通过与其他类型的高效减水剂(如SM和-萘磺酸甲醛冷凝物(SN))进行比较,对该MSM聚合物的性能进行了评价。试验结果表明,在试验条件下,与其他高效减水剂相比,MSM聚合物具有更好的减水能力、较低的新拌混凝土空气含量和较高的1天早期强度。这些特性是预制行业非常需要的,便于混凝土的放置和模板的快速翻转。现场测试也证实了实验室的发现。
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引用次数: 0
Properties of High-Strength Porous Concrete 高强多孔混凝土的性能研究
H. Fujiwara, R. Tomita, T. Okamoto, A. Dozono, A. Obatake
A new method of producing high-strength porous concrete has recently been developed in Japan. In this method, porous concrete is produced by coating the coarse aggregates with a high-strength mortar, then applying vibration to fuse them. Porous concrete produced by this method has the following properties. It has a continuous void system with a volume-to-total-void ratio exceeding 85% and a compressive strength of 20 MPa or greater when water permeability is 2 cm/sec. The porous concrete produced exhibited good durability in freezing and thawing tests (ASTM C666, Procedure B) and, while the amount of drying shrinkage is about 60%, or smaller than that of conventional concrete, such shrinkage occurred very rapidly.
日本最近开发了一种生产高强多孔混凝土的新方法。在这种方法中,多孔混凝土是通过在粗骨料表面涂上高强度砂浆,然后施加振动使其融合而成的。用这种方法生产的多孔混凝土具有以下性能:它具有连续的空隙体系,体积与总空隙比超过85%,当透水性为2 cm/sec时,抗压强度达到20 MPa以上。所制备的多孔混凝土在冻融试验(ASTM C666,程序B)中表现出良好的耐久性,虽然干燥收缩量约为60%,或小于常规混凝土,但这种收缩发生得非常快。
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引用次数: 15
Shrinkage Reduction Type of Advanced Superplasticizer 减缩型高级高效减水剂
T. Sugiyama, A. Ohta, Y. Tanaka
Recently, accompanying the increase in higher strength and flowability of concrete, polycarboxylate-based superplasticizers have attracted much attention. In order to develop an advanced superplasticizer accommodating new functions, we attempted to develop polycarboxylate-based high-range water reducing superplasticizers with high durability as a new function. To increase the durability of concrete, we focused on shrinkage reduction, one of the factors affecting durability, and studied various compounds exhibiting shrinkage reduction. We investigated the relationship between their chemical structures and shrinkage reducing effects. In addition, we synthesized a new series of superplasticizers in which these compounds were attached to the structure of various polycarboxylate polymers, and determined the shrinkage reduction effect by testing concrete with these agents. As a result, we have developed a polycarboxylate-based advanced superplasticizer exhibiting excellent shrinkage reduction.
近年来,随着混凝土强度和流动性的提高,聚羧酸基减水剂受到了广泛的关注。为了开发具有新功能的高级减水剂,我们尝试开发具有高耐久性的聚羧酸基高范围减水剂作为新功能。为了提高混凝土的耐久性,我们重点研究了影响耐久性的因素之一——收缩减缩,研究了各种收缩减缩化合物。研究了它们的化学结构与减缩效果之间的关系。此外,我们还合成了一系列新的高效减水剂,这些减水剂附着在各种聚羧酸盐聚合物的结构上,并通过测试这些减水剂对混凝土的收缩效果。因此,我们开发了一种基于聚羧酸的高级高效减水剂,具有优异的缩水率。
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引用次数: 7
Studies of Polymer Cement Mortar for use as Permanent Forms 聚合物水泥砂浆永久成型材料的研究
K. Horii, T. Tsutsuzaki, K. Kohno
The purpose of this paper is to develop pre-casting permanent forms which are effective in improving the durability and appearance of concrete structures, conserving wood and modernizing cast-in-place concrete work. The influences of various materials used and accelerated curing methods on the properties of polymer cement mortar (PCM) applied to the forms were investigated. In these experiments, polymer dispersions composed of styrene-acryl (SA), polyacrylic ester (PAE), ethylene-vinyl acetate (EVA) and styrene-butadiene rubber (SBR) were used. Mixtures contained aggregate - crushed silica and ferro-nickel slag sand; cement - normal portland, high-early strength portland and white portland cement; and color pigment - red, green, yellow and black. Steam curing and oven-dry curing were carried out. The fluidity, compressive strength, flexural strength, resistance to abrasion, chloride ion penetration, carbonation and sulfate resistance, and surface color of PCM were examined. From these investigations, the following conclusions were obtained: The use of SA type polymer, ferro-nickel slag sand, high-early strength portland cement and color pigments were effective in getting PCM with high fluidity, mechanical strength, durability and tinting strength. Additionally, steam curing and oven-dry curing are practical for the early-age strength development of PCM.
本文的目的是开发预制永久形式,有效地提高混凝土结构的耐久性和外观,节约木材和现代化现浇混凝土工程。研究了不同材料和加速养护方式对聚合物水泥砂浆(PCM)性能的影响。在这些实验中,使用了由苯乙烯-丙烯酸酯(SA)、聚丙烯酸酯(PAE)、乙烯-醋酸乙烯酯(EVA)和丁苯橡胶(SBR)组成的聚合物分散体。含骨料破碎二氧化硅和镍铁渣砂的混合物;水泥——普通硅酸盐水泥、高早强硅酸盐水泥和白硅酸盐水泥;和颜色颜料-红,绿,黄,黑。进行了蒸汽固化和烘箱干燥固化。考察了PCM的流动性、抗压强度、抗弯强度、耐磨性、氯离子渗透性、抗碳化和抗硫酸盐性以及表面颜色。研究结果表明:采用SA型聚合物、镍铁渣砂、高早强硅酸盐水泥和彩色颜料可获得高流动性、高机械强度、高耐久性和高着色强度的PCM;此外,蒸汽固化和烘箱干燥固化对于PCM的早期强度发展是可行的。
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引用次数: 0
Application of Infrared Thermography Technique for Evaluation of Cracks in the Concrete Structures 红外热成像技术在混凝土结构裂缝评价中的应用
S. Nagataki, T. Kamada, A. Matsumoto
In this paper, a method to evaluation the crack size of concrete structures by infrared thermography was investigated. This method is based on the relation between the crack depth or width and thermal distribution in concrete. First, the influence of crack depth and width on thermal distribution was examined. Next, the influence of the distance between cracks and heater on thermal distribution was investigated. The effectiveness of this method was confirmed by the results of the experiment on flexural cracks in reinforced concrete beams. From these results, it was demonstrated that the thermal distribution measured at the surface of concrete by infrared thermography was effective in evaluating the crack size in concrete structures.
本文研究了一种利用红外热像仪评价混凝土结构裂缝尺寸的方法。该方法是基于裂缝深度或宽度与混凝土内部热分布的关系。首先,研究了裂纹深度和宽度对热分布的影响。其次,研究了裂纹与加热器之间的距离对热分布的影响。钢筋混凝土梁受弯裂缝试验结果验证了该方法的有效性。结果表明,红外热像仪测量混凝土表面的热分布是评价混凝土结构裂缝大小的有效方法。
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引用次数: 0
Determination of the Apparent Activation Energy of Concrete: Ea. Semi-Adiabatic Tests of Heat Development 混凝土表观活化能的测定。热发展的半绝热试验
L. D'aloia, G. Chanvillard
The "method of equivalent age" is one of the currently used nondestructive testing methods of concrete strength estimation. It is based on Arrhenius' law, which has shown itself to be the most accurate in describing the influence of temperature on concrete strength development at early ages. A proper estimation is directly related to a correct determination of the Apparent Activation Energy: Ea. This is the unique parameter which characterizes the concrete mixture and which can be found in Arrhenius' law. The major aim of this paper is to show how calorimetric tests under semi-adiabatic conditions can be an alternative to unwieldy compressive test procedures in determining Ea. The validity of the obtained Ea values has been verified by means of several mechanical tests. Moreover, the possibility of using either mortar or concrete is partially dealt with. The water to cement ratio appears to naturally be considered as a constant in proportioning an equivalent mortar. Finally, the evolution of the Apparent Activation Energy in relation to the degree of hydration is given. Hence, the widespread opinion that Ea depends on the degree of hydration is confirmed and a field of definition can be brought to the fore.
“等效龄期法”是目前常用的混凝土强度估算的无损检测方法之一。它基于阿伦尼乌斯定律,该定律在描述温度对早期混凝土强度发展的影响方面是最准确的。正确的估计直接关系到表观活化能的正确测定。表观活化能是表征混凝土混合料的唯一参数,可以在阿伦尼乌斯定律中找到。本文的主要目的是表明在半绝热条件下的量热试验如何可以替代笨拙的压缩试验程序来确定Ea。所获得的Ea值的有效性已通过几次力学试验得到验证。此外,还部分讨论了使用砂浆或混凝土的可能性。水灰比似乎自然地被认为是一个常数,在比例相等的砂浆。最后给出了表观活化能随水化程度的变化规律。因此,普遍认为Ea取决于水化程度的观点得到了证实,并且可以提出一个定义领域。
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引用次数: 0
Use of a Water-Repellent Admixture to Improve Concrete Performance 使用防水外加剂改善混凝土性能
M. Shoya, S. Sugita, Y. Tsukinaga, M. Aba, M. Ohba
In recent years, especially in Japan, various types of chemical admixtures have been developed, with emphasis on making highly durable concrete and on developing the highly flowable concrete for labor-saving. In this paper, one kind of water-repellent admixture incorporating highly reactive silica powder, denoted as WRP, was examined to confirm its effect on various concrete properties. The concept is not only to prevent water penetration due to water repellency provided by the siloxane compound but also to compensate for the hindered hydration due to its adsorption to cement particles by the use of the highly reactive pozzolanic material. The efficacy of the admixture was confirmed as to its ability reducing the water permeability with little lowering of mechanical properties dependent on the dosage of WRP. From the tests for carbonation, drying shrinkage, resistance to freezing and thawing and the air-void systems, the effect of WRP was confirmed as satisfactory for those properties.
近年来,特别是在日本,开发了各种类型的化学外加剂,重点是制造高耐久性混凝土和开发高流动性的混凝土,以节省劳动力。本文对一种含有高活性硅粉的拒水外加剂(WRP)进行了试验,以确定其对混凝土各项性能的影响。这个概念不仅是为了防止水渗透,由于硅氧烷化合物提供的拒水性,而且还补偿阻碍水化,由于其吸附到水泥颗粒使用高活性火山灰材料。结果表明,该掺合料在降低透水性的同时,其力学性能几乎不受WRP掺量的影响。从碳化、干燥收缩率、抗冻融性能和气孔系统试验中,证实了WRP的效果是令人满意的。
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引用次数: 2
High-Performance Concrete Mixture Proportioning 高性能混凝土配合比
K. Sobolev, S. Soboleva
The report generalizes the results of wide range investigations of silica fume based superplasticized high-performance concrete. The rules of the strength and rheological behavior of cement - silica fume - superplasticizer systems are discussed. Usage of optimal superplasticizer to silica fume ratio (as 1:10) allows to obtain ultra-dense packing for super fluid cement paste and provides high-performance properties of concrete. The mathematical models of fresh and hardened high-performance concrete based on processing and computerizing empirical results are created. The models provide a calculation of water/cement ratio required for the target compressive strength level up to 130 MPa as well as mixing water quantity for planning slump of 0-200 mm. For modelling purpose, concrete slump is considered as a function of aggregates proportioning, and volume and fluidity of cement paste. This approach became a basis of proposed high-performance concrete mixture proportioning method. Further, developing and integration of the mathematical models created a new computer program for high-performance concrete mixture proportioning. The program provides a solution for wide range design and optimization projects. The results of the computer program estimation can be easily transferred to any 3-dimensional plotting or data base program for consequent processing and performing.
该报告概括了硅灰基超塑高性能混凝土的广泛调查结果。讨论了水泥-硅灰-高效减水剂体系的强度和流变性能规律。使用最佳减水剂硅灰比(1:10)可以获得超流体水泥浆的超密填料,并提供混凝土的高性能。在对试验结果进行处理和计算机化的基础上,建立了新拌高性能混凝土和硬化高性能混凝土的数学模型。该模型提供了目标抗压强度达到130 MPa所需水灰比的计算以及规划坍落度为0 ~ 200 mm的掺水量。为了建模的目的,混凝土坍落度被认为是骨料比例、水泥浆体体积和流动性的函数。该方法为高性能混凝土配合比方法的提出奠定了基础。此外,数学模型的发展和整合创造了高性能混凝土配合比的新计算机程序。该程序为广泛的设计和优化项目提供了解决方案。计算机程序估计的结果可以很容易地转移到任何三维绘图或数据库程序进行后续处理和执行。
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引用次数: 8
Relationship Between Neutralization Depth and Concentration Distribution of CaCO3 -Ca(OH)2 in Carbonated Concrete 碳化混凝土中和深度与CaCO3 -Ca(OH)2浓度分布的关系
T. Fukushima, Y. Yoshizaki, F. Tomosawa, K. Takahashi
The relationship between the neutralization depth determined by a phenolphthalein 1% ethanol solution and the concentration distribution of CaCO3-Ca(OH)2 in carbonated concrete is discussed, based upon accelerated carbonation and outdoor exposure tests, and field survey research by making use of powder X-ray diffraction and thermal analytical methods. It was found that the neutralization depth exists in the partly carbonated zone of concrete where both CaCO3 and Ca(OH)2 are observed, and that carbonation front depth from which CaCO3 is not detected, exists much deeper in concrete. Further, it was confirmed that the neutralization depth is about half of the carbonation front depth. This fact is interpreted by theoretical research of unsteady state dynamic analysis for the diffusion of CO2 from the surface inwards into concrete accompanied by carbonation reaction with Ca(OH)2. Computer simulation was done for the converted CO2 concentration in carbonated concrete by using the effective diffusion coefficient estimated as a function of water cement ratio. If the converted CO2 concentration in the neutralization depth is assumed to be 10% of the surface concentration, the neutralization depth is almost the same as the depth calculated using Hamada's law which is considered to be adequately applicable for the progress of neutralization of concrete with a water cement ratio of 60% exposed outdoors in the rain. It is concluded that the relationship between the neutralization depth (X sub n) and the carbonation front depth (X sub f) is expressed by the following equation: X sub n = (1/2) X sub f.
通过加速碳化和室外暴露试验,并利用粉末x射线衍射和热分析方法进行现场调查研究,探讨了酚酞1%乙醇溶液测定的中和深度与碳化混凝土中CaCO3-Ca(OH)2浓度分布的关系。结果表明,中和深度存在于混凝土中CaCO3和Ca(OH)2均存在的部分碳化区,而未检测到CaCO3的碳化前沿深度存在于混凝土中更深的区域。进一步证实,中和深度约为碳酸化前缘深度的一半。这一事实通过与Ca(OH)2发生碳酸化反应的CO2从表面向混凝土内部扩散的非稳态动力学分析的理论研究得到了解释。利用估算的有效扩散系数作为水灰比的函数,对碳化混凝土中CO2的转化浓度进行了计算机模拟。如果假设中和深度的转换CO2浓度为表面浓度的10%,则中和深度与使用滨田定律计算的深度几乎相同,认为滨田定律可以充分适用于水灰比为60%的混凝土在雨中暴露在室外的中和过程。得到了中和深度(x_n)与碳酸化前缘深度(x_f)的关系式:x_n = (1/2) x_f。
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引用次数: 22
"Carbonation, Amount of Chloride Ion, and Corrosion of Steel Reinforced Concrete Buildings in HANSHIN Region" 阪神地区钢筋混凝土建筑的碳化、氯离子量与腐蚀
Y. Ohno, Y. Yamamoto
Many reinforced buildings were damaged by the Hygoken-Nanbu Earthquake of 1995. In order to clarify the actual state of carbonation of the concrete and the chloride ion content in concrete of buildings in the Hanshin area, the depths of carbonation and the amount of chloride ion were measured in 117 concrete samples that were obtained from 97 damaged buildings. The effects of carbonation depth and chloride ion content with regard to the corrosion of steel were also investigated. The measured carbonation depths were wildly scattered, with some of the concrete being heavily carbonated. The amounts of chloride ions in old river sand concrete were small. Large amounts of chloride ion were found mixed with sand, that came not only from the ocean but also from rivers, in the buildings that were built between 1960 and 1978. This chloride ion was thought to be induced through sea sand and an admixture. The concentration of chloride ions in concrete were small for buildings that had been constructed after the regulation of the amount of chloride in concrete that was instituted in 1986. A great deal of the steel embedded in the carbonated concrete was severely corroded. The degree of steel corrosion tended to increase with an increase in the amount of chloride ion as well as carbonation depth.
1995年Hygoken-Nanbu地震破坏了许多加固建筑。为了弄清阪神地区混凝土碳化的实际状态和建筑物混凝土中氯离子的含量,对97栋受损建筑物的117个混凝土样品进行了碳化深度和氯离子含量的测定。研究了碳化深度和氯离子含量对钢的腐蚀的影响。测量到的碳化深度非常分散,一些混凝土被严重碳化。老河砂混凝土中氯离子含量较低。在1960年至1978年间建造的建筑物中,发现了大量的氯离子混合在沙子中,这些沙子不仅来自海洋,也来自河流。这种氯离子被认为是通过海砂和一种混合物产生的。对于1986年制定的混凝土氯离子含量规定之后建造的建筑物来说,混凝土中氯离子的浓度很小。大量嵌在碳化混凝土中的钢材被严重腐蚀。钢的腐蚀程度随氯离子用量的增加和碳化深度的增加而增加。
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引用次数: 0
期刊
SP-179: Fourth CANMET/ACI/JCI Conference: Advances in Concrete Technology
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