Chemical Engineering Science最新文献

Bubble deformation and breakup due to strain-rate-induced stress is investigated for a laminar flow configuration. The bubble shape is assumed to be a prolate ellipsoid. A new model for bubble deformation under dynamic load is introduced in the form of an ordinary differential equation for the deformation energy. Breakup is identified with a critical value of the deformation. As an application case, the flow in a joining T-junction is considered with the ratio of the volume flow rate being unity and the outflow Reynolds number being 1800. Dilute, dispersed bubbles with a diameter of 0.5 mm are injected. High-speed shadowgraphy is used and bubble parameters are evaluated via image processing. The capillary number is obtained from a single-phase flow simulation providing the instantaneous shear rate at the position of the bubble. The deformation resulting from the proposed model is then compared with the measured deformation for an exemplary bubble trajectory.

Demetalation-metalation method has gained prominence for its higher metal loading, efficiency and shortened synthetic period, particularly in the incorporation of metal atoms with large radii into zeolite framework in recent years. An ammonia-regulated approach has been developed for selectively evolved deep-substituted Ti precursors in dealuminized beta zeolites, which enables a controlled promotion of metalation of Ti atoms. Additionally, this ammonia-regulated approach could also enhance 1-hexene kinetic adsorption by constructing mesopores, which is demonstrated by the lower reaction order of 1-hexene. The synthesized ammonia-regulated N-Ti-beta exhibits rich framework Ti species and a high specific surface area, leading to significantly improved 1-hexene epoxidation performance (conversion of 61%, selectivity of 98%, and a high H₂O₂ utilization efficiency of 93%). This study not only provides a new strategy to dynamically regulate evolution of Ti precursors by ammonia but also holds promise for advancing related industrial processes in demetalation-metalation methods.

The Euler-Euler/RANS approach is used to simulate the particle suspension in solid–liquid stirred vessels, with experimental validation conducted through the Electrical Sensing Zone Method (ESZ). An innovative evaluation method is introduced to quantify the critical impeller speed $N_c$ required for particles to achieve a specific uniform suspension state in dilute solutions. The impact of different vessel bottom shapes (flat, round, and W-shaped) on particle suspension characteristics is examined. The results indicate that optimizing the bottom shape to align with flow streamlines markedly enhances particle suspension, a conclusion supported by the Online Micro-sized Particle Analyzer (OMiPA). Further analysis shows baffle configurations transform tangential and axial velocities into radial velocity, which is not conducive to providing initial conditions for particle suspension. Overall, effective particle suspension relies on the interaction between main flow and turbulent fluctuations, with tangential and radial flows playing critical roles.

The reduction behavior of iron ore is the fundamental process in ferrous metallurgy. Considering the gas–solid interface-structure relationship, heterogeneous transfer-reaction behavior, and multiple reaction kinetics, this work provides an effective analytical tool to investigate the fluidized reduction of iron ore. The conical fluidized bed is numerically examined to be capable of preventing de-fluidization induced by the sticking behavior, due to the steady circulation of flow pattern and full fluidization of coarse agglomerates. Compared with the hydrogen concentration, the gas velocity shows a stronger influence on the agglomerate reduction rate for the more efficient gas–solid contact. For the simulated transitions of Fe₂O₃ → Fe₃O₄ → Fe_(1-x)O → Fe are assumed to overlap each other, there exist discrepancies between computed and theoretical reduction degrees. The experimental and numerical findings can be used to develop a methodology for optimizing the operational complexity and economic benefits of the fluidized reduction of iron ore.

Respirable coal mine dust (RCMD) inhalation is identified as the main cause of the resurgence of coal worker’s pneumoconiosis (CWP) since the mid-1990s. At present, the predominant dust control technology is the water spray system. However, in practice, the capture efficiency of RCMD by this technology is relatively low. To understand the capturing mechanism and develop improvement strategies, this research is focused on the surface chemistry study of RCMD and its impact on a water surface using a dynamic model. Proximate analysis, chemical, and mineral composition of a run-of-mine (ROM) coal sample from Appalachian region were analyzed using a proximate analyzer, Inductively Coupled Plasma Mass Spectrometry (ICP-MS), and X-ray Diffraction (XRD), respectively. Contact angles were measured by capillary rise test using the Washburn equation. Based on the dynamic model, the effects of particle size, density, contact angle, and surface tension on the critical sinking were investigated. It was pointed out in this work that reducing surface tension, in turn, decreases contact angle, which has been neglected in the literature. Regime maps for different minerals were created and showed that organic matter has the highest critical velocity due to its low density and high contact angle. Reducing water surface tension to the critical solid surface tension of coal around 30 mN/m could maximize the attachment efficiency. Scaling laws, constructed by force balance, led to the criteria of critical sinking: $U_{\text{cr}}\sim \sqrt{\frac{6\left(1-\cos \theta \right)}{\left(2D+1\right)}}\sqrt{\frac{{\gamma }_{\mathrm{lv}}}{{\rho }_{l}R}}$, i.e., ${\text{We}}_{\text{cr}}\sim \frac{12\left(1-\cos \theta \right)}{\left(2D+1\right)}$. A semi-empirical formula for critical velocity was obtained by fitting the simulation data, $U_{\mathrm{cr}}=1.09\sqrt{\frac{6\left(1-\cos \theta \right)}{\left(2D+1\right)}}\sqrt{\frac{{\gamma }_{\mathrm{lv}}}{{\rho }_{l}R}}$. Attachment efficiency was defined and formu