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Laser structuring of conducting films on transparent substrates for electronics devices 电子器件用透明基板上导电薄膜的激光结构
Pub Date : 2008-09-10 DOI: 10.1117/12.815322
G. Račiukaitis
Flat panel displays (FPD), flexible electronics and thin-film photovoltaics are booming in the last few years. Permanent annual growth and huge expectations in the market in the near future stimulate the development of versatile technologies for patterning thin-film materials on rigid and flexible substrates. Utilization of laser radiation provides diversity of processing means for structuring deposited films. The high selectivity and diminishing effect on the surrounding material as well as high speed are required in processing complex multilayered systems in the thin-film photovoltaics. Organic electronics imposes special requirements on the geometrical quality of conductors. The current situation with laser direct writing of thin-films in the production of FPD and solar cells as well as our results are presented. High repetition rate lasers with a short pulse duration offer new possibilities for high efficiency structuring of conducting, semi-conducting and isolating films. Laser structuring with the picosecond and nanosecond pulse duration was applied in shaping the thin films deposited on polymers and glass substrates. Absorption of laser radiation by the film material was essential to initiate its controllable removal. Use of UV laser radiation with fluences close to the ablation threshold made it possible to minimize surface contamination and the recast ridge formation during the ablation process. The flexible technique of patterning was applied in prototyping the components for the OLED matrix, RFID antennas and the thin-film solar cells. Well-defined shapes of isolating trenches and conductor lines were produced by laser ablation with the picosecond pulse duration.
平板显示器(FPD)、柔性电子产品和薄膜光伏在过去几年中蓬勃发展。在不久的将来,永久的年度增长和对市场的巨大期望刺激了在刚性和柔性基板上绘制薄膜材料的通用技术的发展。激光辐射的利用为沉积膜的结构提供了多种加工手段。在制备复杂的多层薄膜光伏系统时,需要高选择性和对周围材料的衰减效应以及高速度。有机电子学对导体的几何质量有特殊的要求。介绍了激光直接写入薄膜技术在FPD和太阳能电池生产中的应用现状和我们的研究结果。具有短脉冲持续时间的高重复频率激光器为高效构建导电、半导体和隔离薄膜提供了新的可能性。利用皮秒和纳秒脉冲持续时间的激光结构对聚合物和玻璃基板上沉积的薄膜进行了整形。薄膜材料对激光辐射的吸收是启动其可控去除的必要条件。使用接近烧蚀阈值的紫外激光辐射,可以最大限度地减少表面污染和烧蚀过程中重铸脊的形成。将柔性图像化技术应用于有机发光二极管(OLED)矩阵、射频识别(RFID)天线和薄膜太阳能电池组件的原型制作中。在皮秒脉冲持续时间下,激光烧蚀产生了形状清晰的隔离沟和导体线。
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引用次数: 9
Mid-infrared photoluminescence of PbSe film structures up to room temperature 室温下PbSe薄膜结构的中红外光致发光
Pub Date : 2008-09-10 DOI: 10.1117/12.815199
Z. Dashevsky, V. Kasiyan, G. Radovsky, E. Shufer, M. Auslender
Lead salt materials are of high interest for midinfrared optical emitters and detectors for molecular spectroscopy. The IV-VI narrow gap semiconductors have a multivalley band structure with band extrema at the L point of the Brillioun zone. Due to the favorable mirrorlike band structure, the nonradiative Auger recombination is reduced by one or two orders of magnitude below that of narrow gap III-V and II-VI semiconductor compounds1. The photoluminescence in the midinfrared range for PbSe film structures, excited by a semiconductor laser diode, is investigated. The PbSe films were prepared by Physical Vapor Deposition (PVD) using an electron gun. A PbSe crystal doped with 0.1 at% Bi was used as a source for the fabrication of thin layers. Starting from the assumption that the rate of nucleation is a predominate factor in determining grain size, thin films were fabricated on substrates that had been maintained at various temperatures of deposition process2. Amorphous glass and Kapton polyimide film was used as substrate. The growth rate was 0.2 nm/s. Films were thermally treated at high oxygen pressure in a heated encapsulated system. Microstructure has been studied using XRD, AFM and HRSEM. For PbSe structures photoluminescence at temperature as high as 300 K is demonstrated.
铅盐材料是中红外发射体和分子光谱探测器的重要材料。IV-VI窄隙半导体具有多谷能带结构,在亮带的L点处有能带极值。由于有利的镜面带结构,非辐射俄歇复合比窄间隙III-V和II-VI半导体化合物低一到两个数量级1。研究了在半导体激光二极管的激励下,PbSe薄膜结构在中红外范围内的光致发光。采用电子枪物理气相沉积(PVD)法制备PbSe薄膜。用掺有0.1 at% Bi的PbSe晶体作为制备薄层的源。假设成核速率是决定晶粒尺寸的主要因素,在沉积过程中保持不同温度的基底上制备薄膜2。采用非晶玻璃和卡普顿聚酰亚胺薄膜作为衬底。生长速率为0.2 nm/s。薄膜在加热封装系统中在高氧压力下进行热处理。采用XRD、AFM和HRSEM对其微观结构进行了研究。对于PbSe结构,可以在高达300 K的温度下实现光致发光。
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引用次数: 12
Self-organizing laser induced Au nanocrystall formation in conditions of surface plasmon resonance 表面等离子体共振条件下自组织激光诱导金纳米晶体的形成
Pub Date : 2008-09-10 DOI: 10.1117/12.815449
L. Fedorenko, M. Yusupov
The researches of the possibility of Au nanoparticles formation in conditions of surface plasmon resonance (SPR) at irradiation of the Au film / glass structure by YAG:Nd+3-laser nanosecond pulses of the p-polarization (tp = 10 ns) by fundamental (λ = 1.064 nm) and second harmonics (λ = 0.532 nm) are submitted. The morphology of an Au film surface before and after laser action, Au fragments sizes and their surface distribution were investigated by the atom force microscopy (AFM). The effect of Au nanoparticles formation was observed only at the second harmonic irradiation (λ= 0.532 μm) in SPR conditions in the Kretschmann configuration. The considerable difference between the average Au nanoparticles sizes δ created at the SPR conditions, R = Rmin, δ ~ 80 nm that was obtained in the case out of SPR R≠Rmin δ ~ 1350 nm is established. Threshold energy density of micro-ablation Pthn is determined, that one in the case of SPR Pthn ≈ 5.5 J•cm-2 was essentially lower than in the SPR absence, Pthn ≈ 8 J cm-2. The histogram obtained on the AFM data has shown a high degree of the height sizes homogeneity of Au nanoparticles. Under the AFM data a conclusion about the determining contribution of the plasmon - polariton subsystem in formation process of Au nanoparticles in SPR conditions at high levels of laser irradiation was made.
研究了YAG:Nd+3基频(λ = 1.064 nm)和次谐波(λ = 0.532 nm) p偏振(tp = 10 ns)激光纳秒脉冲辐照Au薄膜/玻璃结构时,在表面等离子体共振条件下形成Au纳米粒子的可能性。利用原子力显微镜(AFM)研究了激光作用前后的Au膜表面形貌、Au碎片尺寸及其表面分布。在Kretschmann构型中,仅在SPR条件下的二次谐波辐照(λ= 0.532 μm)下观察到金纳米颗粒的形成。在SPR条件下生成的平均金纳米颗粒尺寸δ R = Rmin, δ ~ 80 nm与在SPR条件下得到的δ R≠Rmin δ ~ 1350 nm有很大的差异。测定了微烧蚀Pthn的阈值能量密度,发现有SPR时Pthn≈5.5 J•cm-2,基本低于无SPR时的Pthn≈8 J cm-2。原子力显微镜数据的直方图显示了金纳米粒子高度尺寸的高度均匀性。根据原子力显微镜数据,得出了等离子体-极化子子系统在高强度激光辐照下SPR条件下金纳米粒子形成过程中的决定性作用。
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引用次数: 0
Investigation of As2S3-Al films for dot-matrix holographic recording 点阵全息记录用As2S3-Al薄膜的研究
Pub Date : 2008-09-10 DOI: 10.1117/12.815436
A. Bulanovs, V. Gerbreders, Ē. Sļedevskis, V. Pashkevich, J. Teteris
We have performed the investigation of dot matrix holographic recording in amorphous As2S3 chalcogenide films with different thickness on Al coated glass substrates. The control over the interference minimum of reflection during the evaporation process allowed obtaining As2S3-Al system with a minimum value of initial reflection in defined spectral region. The investigation of dependence of diffraction efficiency of holographic recording on both film thickness and initial conditions of reflectivity in the system was performed. The main advantage of this type of system is the possibility to increase optical sensitivity of material in predefined spectrum region for phase hologram recording.
本文研究了不同厚度的非晶硫化物As2S3薄膜在铝镀膜玻璃基板上的点阵全息记录。通过对蒸发过程中反射干扰最小值的控制,可以获得在规定光谱区域具有最小初始反射值的As2S3-Al体系。研究了全息记录衍射效率与薄膜厚度和系统反射率初始条件的关系。该系统的主要优点是可以提高材料在预定光谱区域的光学灵敏度,用于相位全息记录。
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引用次数: 1
The effects of external applied voltage on the nonlinear optical properties of a dye-doped nematic liquid crystal by using a single beam 外加电压对单束染料掺杂向列液晶非线性光学特性的影响
Pub Date : 2008-09-10 DOI: 10.1117/12.815901
M. H. Majles Ara, R. Bahramian, M. Abolhasani
We report the experimental data of typical liquid crystals (6CHBT and w1680) in the nematic phase doped with and without Sudan dyes. We investigated the effect of an ac-applied voltage on the nonlinear behavior of dye doped liquid crystal (DDLC). The z-scan technique is used to measure the amplitude and the sign of the nonlinear refractive indices DDLC. The amplitude of negative nonlinear refractive indices was (~10-5cm2/W). The nonlinear absorption coefficient β of DDLC was measured by using open aperture z- scan technique. Also the optical limiting (OL) response of DDLC was obtained. The novel effects on the far-field diffraction patterns of a Gaussian beam were depended on the external applied field. The measurements were performed using a CW He:Ne laser and CW Nd:Yag laser tuned at 632.8 nm and 532 nm, respectively. Also Gaussian beam propagated through a thin cell (sample thickness =11.8 μm).
本文报道了向列相中典型液晶(6CHBT和w1680)掺杂和不掺杂苏丹红染料的实验数据。研究了交流电压对掺杂染料液晶非线性特性的影响。采用z扫描技术测量了非线性折射率的振幅和符号。非线性负折射率的幅值为(~10-5cm2/W)。采用开孔z扫描技术测定了DDLC的非线性吸收系数β。得到了dlc的光限响应。对高斯光束远场衍射图的新影响取决于外加场。测量采用连续波He:Ne激光器和连续波Nd:Yag激光器,波长分别为632.8 nm和532 nm。高斯光束也能通过薄电池(样品厚度=11.8 μm)传播。
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引用次数: 1
Lattice vibrations study of InxGa1-xAsySb1-y quaternary alloys with low (In, As) content highly doped by tellurium grown by LPE LPE生长碲高掺杂低(In, As)含量InxGa1-xAsySb1-y季系合金的晶格振动研究
Pub Date : 2008-09-10 DOI: 10.1117/12.815961
J. Díaz-Reyes, E. López-Cruz, J. Mendoza-Álvarez
The quaternary alloy InxGa1-xAsySb1-y highly doped with tellurium was grown on substrates of p-type GaSb in the direction (100) by liquid phase epitaxy (LPE). The longitudinal (LO) and transverse (TO) optical modes were obtained using the modified random-element iso-displacement model (MREI model). The comparison of the experimental results with obtained by the MREI model allows to confirm that the bands correspond to the modes associated LO and TO of the binary compounds GaAs and (GaSb + InAs).
采用液相外延法(LPE)在p型GaSb衬底上沿(100)方向生长了高掺碲的季元合金InxGa1-xAsySb1-y。采用改进的随机元等位移模型(MREI)获得了纵向(LO)和横向(TO)光学模式。将实验结果与MREI模型的结果进行比较,可以确认这些波段对应于二元化合物GaAs和(GaSb + InAs)的LO和to的相关模式。
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引用次数: 2
Micro-Raman scattering and infrared spectra of hemoglobin 血红蛋白的微拉曼散射和红外光谱
Pub Date : 2008-09-10 DOI: 10.1117/12.815796
M. Polakovs, Ņ. Mironova-Ulmane, N. Kurjāne, E. Reinholds, M. Grube
Confocal micro-Raman and FT-IR spectroscopies have been used for detection of radiation influence of hemoglobin of patients examined by radio-isotopes diagnosis (Tc99m). After irradiation we observed some little changes of the Raman scattering bands which connected with out of plane porphyrine bending vibrations, also we observed additional band due to methemoglobin. Radiation of blood lead to the transition from hemoglobin (Fe2+) to methemoglobin (Fe3+) with a delocalization of iron from porphyrine plane. It was shown that FT-IR spectra indicate the radiation effects on hemoglobin.
共聚焦显微拉曼光谱和傅里叶变换红外光谱已被用于检测放射性同位素诊断(Tc99m)患者血红蛋白的辐射影响。在辐照后,我们观察到与卟啉的面外弯曲振动有关的拉曼散射带有一些微小的变化,并且我们还观察到高铁血红蛋白引起的额外带。血液的辐射导致从血红蛋白(Fe2+)到高铁血红蛋白(Fe3+)的转变,铁从卟啉平面脱位。结果表明,红外光谱显示了辐射对血红蛋白的影响。
{"title":"Micro-Raman scattering and infrared spectra of hemoglobin","authors":"M. Polakovs, Ņ. Mironova-Ulmane, N. Kurjāne, E. Reinholds, M. Grube","doi":"10.1117/12.815796","DOIUrl":"https://doi.org/10.1117/12.815796","url":null,"abstract":"Confocal micro-Raman and FT-IR spectroscopies have been used for detection of radiation influence of hemoglobin of patients examined by radio-isotopes diagnosis (Tc99m). After irradiation we observed some little changes of the Raman scattering bands which connected with out of plane porphyrine bending vibrations, also we observed additional band due to methemoglobin. Radiation of blood lead to the transition from hemoglobin (Fe2+) to methemoglobin (Fe3+) with a delocalization of iron from porphyrine plane. It was shown that FT-IR spectra indicate the radiation effects on hemoglobin.","PeriodicalId":273853,"journal":{"name":"International Conference on Advanced Optical Materials and Devices","volume":"37 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2008-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122871261","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 10
A method for deposition of tungsten trioxide (WO3) 一种沉积三氧化钨(WO3)的方法
Pub Date : 2008-09-10 DOI: 10.1117/12.815958
J. Martínez-Juárez, J. Díaz-Reyes
Thin films of tungsten oxide (WO3) have been grown by hot-filament metal oxide deposition (HFMOD) technique under atmospheric pressure and an oxygen atmosphere on glass substrates. The thin film of WO3 has been extensively studied as an electrochromic material and has numerous applications in electrochromic devices. In order to explore the possibility of using WO3 in electrochromic devices, a preliminary and thorough study of the structural and optical properties of the host material is an important step. By the X-ray diffraction analysis the single phase natures, monoclinic and orthorhombic structure of the films have been confirmed. The IR spectra were constituted of many broad peaks in the 1400-3500 cm-1 region That are assigned to ν(OH) and δ(OH) modes of adsorbed water. The corresponding WO3 vibrations are in infrared regions of 1453-400 cm-1 and 3454 cm-1, which correspond to W-O stretching, bending and lattice modes. By Transmittance measures determines that the optical bandgap is around 2.92 eV. We have observed that the good quality WO3 thin films can be satisfactorily grown by this technique.
在常压和氧气气氛下,采用热丝金属氧化物沉积(HFMOD)技术在玻璃衬底上生长了氧化钨(WO3)薄膜。WO3薄膜作为一种电致变色材料得到了广泛的研究,在电致变色器件中有着广泛的应用。为了探索在电致变色器件中使用WO3的可能性,对主体材料的结构和光学性质进行初步深入的研究是重要的一步。通过x射线衍射分析,证实了薄膜的单相性质、单斜结构和正交结构。红外光谱在1400 ~ 3500cm -1范围内由ν(OH)和δ(OH)模式的宽峰组成。对应的WO3振动在1453 ~ 400 cm-1和3454 cm-1的红外区域,分别对应W-O拉伸、弯曲和晶格模式。通过透光率测量,确定了光带隙在2.92 eV左右。我们观察到,用这种方法可以令人满意地生长出高质量的WO3薄膜。
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引用次数: 2
Evaluation of deep trap compensation ratio and recombination parameters by transient grating techniques 瞬态光栅技术评价深阱补偿比和复合参数
Pub Date : 2008-09-10 DOI: 10.1117/12.815623
A. Kadys, K. Jarašiūnas, P. Delaye, D. Verstraeten
We demonstrate a novel application of time-resolved transient grating technique for determination of deep trap occupation ratio in semi-insulating crystals. Light diffraction kinetics on a transient reflection grating with very small period (150 nm) provided conditions for studies of absorption nonlinearity and its discrimination from the coexisting free carrier and electro-optic ones. By numerical modeling of absorption grating kinetics in subnanosecond time domain, we determined the contributions of the recharged deep traps and two-photon absorption to diffraction kinetics and evaluated in this way the deep trap compensation ratio in differently grown GaAs crystals. Moreover, the decay time of the absorption grating provided the rate of carrier capture to these dominant deep traps, which have been recharged under illumination. Using this feature, we were able to monitor the thermal annealing process in vanadium-doped CdTe crystals: it has not effected the charge state of vanadium related deep traps, but reduced the concentration of the active residual carrier capture centers in the crystal.
我们展示了时间分辨瞬态光栅技术在半绝缘晶体中测定深阱占据比的新应用。极小周期(150 nm)瞬态反射光栅的光衍射动力学为研究吸收非线性及其与共存的自由载流子和电光载流子的区分提供了条件。通过亚纳秒时域吸收光栅动力学的数值模拟,确定了充电深阱和双光子吸收对衍射动力学的贡献,并以此评估了不同生长方式的砷化镓晶体的深阱补偿比。此外,吸收光栅的衰减时间提供了这些优势深阱的载流子捕获速率,这些深阱在照明下被充电。利用这一特性,我们能够监测掺钒CdTe晶体的热退火过程:它没有影响钒相关深阱的电荷状态,但降低了晶体中活性残余载流子捕获中心的浓度。
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引用次数: 1
Noise characteristics and reliability of high power white light emitting diodes based on nitrides 基于氮化物的大功率白光二极管的噪声特性和可靠性
Pub Date : 2008-09-10 DOI: 10.1117/12.816513
J. Matukas, V. Palenskis, J. Vyšniauskas, B. Saulys, S. Pralgauskaitė, A. Pincevičius
High power white light emission diode reliability and aging processes have been investigated. Optical, electrical and noise characteristics have been carried out for initial devices and during their aging. Analysis of noise characteristics help revealing of light emission diode aging processes and reliability problems. It is found that optical and electrical noise spectra changes reflect light emission diode aging. Noise characteristics, especially correlation factor between optical and electrical fluctuations, and current-voltage characteristics at low bias reveal physical processes that take place during investigated device aging and rapid its degradation. It is shown that reason of high power light emission diode degradation is related with defects presence in the device structure. Additional defects appear during LED operation and lead to the leakage current and non-radiative recombination increase.
对大功率白光二极管的可靠性和老化过程进行了研究。光学,电学和噪声特性进行了初始设备和他们的老化。噪声特性分析有助于揭示发光二极管的老化过程和可靠性问题。发现光电噪声谱的变化反映了发光二极管的老化。噪声特性,特别是光和电波动之间的相关因素,以及低偏置下的电流-电压特性揭示了在所研究的器件老化和快速退化过程中发生的物理过程。结果表明,大功率发光二极管的劣化与器件结构中存在的缺陷有关。LED在工作过程中会出现额外的缺陷,导致漏电流和非辐射复合增加。
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引用次数: 3
期刊
International Conference on Advanced Optical Materials and Devices
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