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Copper Bimetals and Their Nanocomposites 铜双金属及其纳米复合材料
Pub Date : 2020-03-11 DOI: 10.5772/intechopen.87930
H. Shokrvash, R. Rad, A. Massoudi, Reza Shokrvash
This chapter deals with the study of the electrolysis synthesis of copper matrix nanocomposites developed for the fabrication of nanoparticulate Cu-bimetals. In this chapter, we describe the successful synthesis of Cu matrix nanocomposites by the electro-deoxidation method. We think that this approach will make it possible to realistically integrate a series of copper-bimetals. This study makes a significant contribution to the literature because this method opens novel opportunity to the design of nanocomposite materials. Particularly, this opens up prospects for designing the new materials from immiscible metallic elements, which is the main topic in designing of alloys as well as materials science progression.
本章主要研究了电解法合成铜基纳米复合材料制备纳米铜双金属的方法。在本章中,我们描述了电脱氧法制备Cu基纳米复合材料的成功。我们认为这种方法将使实际集成一系列铜双金属成为可能。这项研究对文献有重大贡献,因为这种方法为纳米复合材料的设计开辟了新的机会。这为非混相金属元素设计新材料开辟了广阔的前景,是合金设计和材料科学发展的重要课题。
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引用次数: 1
Polymer Nanocomposite-Based Electrochemical Sensors and Biosensors 基于聚合物纳米复合材料的电化学传感器和生物传感器
Pub Date : 2020-03-11 DOI: 10.5772/intechopen.86826
B. John
Polymer nanocomposites (PNCs) play a significant role in modern day life and are widely studied for extensive properties which make them appealing to numerous applications. They are synthesized with scalable processing procedures with several nanoscale variations of fillers and forms leading to specific sensing applications. In this chapter, PNC-based electrochemical sensors and biosensors like DNA biosensors and immunosensors are discussed. These sensors related PNC applications uses nanofillers of various combinations like conductive polymers with graphene (Grp), carbon nanotubes (CNTs), and metal nanoparticles, which endow high electrical conductivity, effective surface area, and fast electron transfer rate. Currently, wearable devices based on electrochemical Sensors and biosensors have been of great interest in the detection of both physiological and environmental analytes.
聚合物纳米复合材料(pnc)在现代生活中发挥着重要作用,其广泛的性能得到了广泛的研究,使其具有广泛的应用前景。它们是通过可扩展的加工程序合成的,其中包含几种纳米级的填料和形式变化,从而导致特定的传感应用。本章讨论了基于pnc的电化学传感器和DNA生物传感器、免疫传感器等生物传感器。这些与PNC应用相关的传感器使用各种组合的纳米填料,如导电聚合物与石墨烯(Grp)、碳纳米管(CNTs)和金属纳米颗粒,它们具有高导电性、有效表面积和快速电子传递速率。目前,基于电化学传感器和生物传感器的可穿戴设备在生理和环境分析物的检测方面引起了极大的兴趣。
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引用次数: 12
Metallo-Dielectric Colloidal Films as SERS Substrate 金属-介电胶体膜作为SERS衬底
Pub Date : 2019-12-30 DOI: 10.5772/intechopen.90313
A. L. González, Arturo Gomez, M. Toledo-Solano
Along this chapter, we probe that the discrete dipole approximation models fairly well the optical response of periodic systems. Herein, we use it to model the reflectance and transmittance, at normal incidence, of colloidal films made of SiO 2 spheres. As the thickness increases from 1 to 12 layers, the photonic band gap shifts to the blue tending to the value corresponding to a 3D opal, 442 nm. A film with more than eight layers resembles the bulk properties of a 3D opal. Our results are compared to a real sample. Besides, we show that taking advantage of the wide and asymmetrical absorbance spectrum of an opal with Au NPs is possible to identify the contribution of each component in the overall spectrum, through a deconvolution analysis. Finally, we present the electric field intensity as the content of metal NP increases in a monolayer. We consider NPs one order of magnitude smaller than the silica spheres, and then, 6, 9, and 17 NPs are hosted in the void. Similar average electric field intensities, about 11 times the incident intensity, are obtained with Au and Ag NPs. But, the spots with these intensities cover a bigger area with Ag NPs than with Au NPs. and transmittance, at normal incidence, of colloidal films made of SiO 2 spheres with a specific diameter of 200 nm. We show that as the thickness increases from 1 to 12 layers, the center of the photonic band gap shifts to the blue tending to the value of 444 nm. This value is very close to the one corresponding to a 3D opal with HCP structure, 442 nm. Analyzing the trend of the position of the BG, a film with more than eight layers resembles that of a 3D artificial opal. We also compared our results with a 3D artificial opal made with silica spheres of the same size as the one studied by us. We found a good qualitative agreement, and the differences are attributed mainly to the presence of defects in the sample.
在本章中,我们探讨了离散偶极子近似很好地模拟了周期系统的光学响应。在这里,我们用它来模拟由二氧化硅球制成的胶体膜在正入射下的反射率和透射率。当厚度从1层增加到12层时,光子带隙向蓝色移动,趋向于3D蛋白石对应的值,442 nm。超过八层的薄膜类似于3D蛋白石的大块特性。我们的结果与实际样本进行了比较。此外,我们表明,利用具有Au NPs的蛋白石的宽和不对称吸光度光谱,可以通过反褶积分析来确定整个光谱中每个组分的贡献。最后,我们给出了电场强度随金属NP在单层中含量的增加而变化。我们认为NPs比二氧化硅球小一个数量级,然后在空隙中有6、9和17个NPs。Au和Ag纳米粒子的平均电场强度相似,约为入射强度的11倍。但是,具有这些强度的斑点覆盖了银NPs比金NPs更大的区域。在正常入射下,由比直径为200nm的二氧化硅球制成的胶体膜的透射率。我们发现,当厚度从1层增加到12层时,光子带隙中心向蓝移,并趋向于444 nm。该值与具有HCP结构的3D蛋白石对应的值非常接近,为442 nm。分析BG位置的变化趋势,一个超过8层的膜类似于一个3D人工蛋白石。我们还将我们的结果与与我们研究的相同大小的硅球制成的3D人工蛋白石进行了比较。我们发现了很好的定性一致,差异主要归因于样品中存在缺陷。
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引用次数: 2
Study of Structural and Melting Properties of Gold Nanorods 金纳米棒的结构与熔化性能研究
Pub Date : 2019-11-02 DOI: 10.5772/intechopen.84682
R. Essajai
MD simulations combined with the embedded-atom method have been applied to study the structural and melting properties of gold nanorods (AuNRs) of different sizes. The simulation results for the actual structure of AuNRs obtained after energy minimization processes revealed that the AuNRs with largest cohesive energies tend to be structurally more stable than those with smallest ones. Then, it was found that each actual structure of AuNR is classified as an irregular structure composed of a crystalline gold core covered by an amorphous gold shell. In addi-tion, the results showed that the melting of the AuNR surface is an inhomogeneous, gradually occurring process. Besides, it was established that the premelting ratio is inversely correlated with the AuNR size, indicating that the premelting phenomenon is more pronounced in large NP sizes than in small ones.
本文采用分子动力学模拟与嵌入原子法相结合的方法研究了不同尺寸金纳米棒的结构和熔化性能。经过能量最小化处理得到的实际结构的模拟结果表明,具有最大内聚能的aunr结构比具有最小内聚能的aunr结构更稳定。然后,发现unr的每个实际结构都被归类为由结晶金核覆盖无定形金壳组成的不规则结构。此外,研究结果表明,AuNR表面的熔化是一个不均匀的、逐渐发生的过程。此外,还建立了预熔比与AuNR尺寸成反比的关系,表明在大NP尺寸下预熔现象比在小NP尺寸下更为明显。
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引用次数: 0
Computational Analysis of Nanostructures for Li-Ion Batteries 锂离子电池纳米结构的计算分析
Pub Date : 2019-10-17 DOI: 10.5772/intechopen.88712
Jameela Fatheema, S. Rizwan
Due to the energy crisis, the focus on the study of new materials has increased vastly. For the increasing demand of renewable energy, there are different ways suggested to attain that, which include the rechargeable batteries and the need to achieve them at smaller costs and for longtime use. Lithium ion batteries have gained a lot of attention for that specific reason. Along with the experiments, the easier way to understand and increase the efficiency of these materials for LIBs is to study them through simulations and theoretically. Density functional theory (DFT)-based study gives us an insight into the internal workings of the compounds used in lithium ion batteries (LIBs). In this chapter, an analysis of different structures is presented for use in LIBs, which mainly includes carbon nanostructures or nanotubes as well as 2D material graphene. The various ways in which the carbon-based structure is enhanced include doping into the structure, heterostructure of graphene with other 2D materials, and adsorption of atoms like Si onto the surface. The adsorption of Li on these various structures and the varying binding energies and capacity with the changing structure along with the understanding at atomic and nanoscale are mentioned.
由于能源危机,对新材料研究的关注大大增加。对于不断增长的对可再生能源的需求,有不同的方法来实现这一目标,其中包括可充电电池,以及以更低的成本和长期使用的需要。由于这个原因,锂离子电池获得了很多关注。随着实验的进行,对lib来说,更容易理解和提高这些材料效率的方法是通过模拟和理论研究它们。基于密度泛函理论(DFT)的研究使我们能够深入了解锂离子电池(LIBs)中使用的化合物的内部工作原理。在本章中,分析了用于lib的不同结构,主要包括碳纳米结构或纳米管以及二维材料石墨烯。碳基结构增强的各种方法包括掺杂到结构中,石墨烯与其他二维材料的异质结构,以及在表面吸附Si等原子。介绍了锂在不同结构上的吸附,以及随着结构的变化而产生的结合能和结合能的变化,以及在原子和纳米尺度上的认识。
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引用次数: 3
Mechanical and Tribological Properties of Epoxy Nano Composites for High Voltage Applications 高压环氧纳米复合材料的力学和摩擦学性能
Pub Date : 2019-10-09 DOI: 10.5772/intechopen.88236
R. Aradhya, N. Renukappa
The tribological and mechanical properties of organomodified montmorillonite (oMMT)-incorporated Epoxy (Epoxy-oMMT), vinyl ester (vinyl ester-oMMT) and titanium dioxide (TiO 2 )-filled Epoxy (Epoxy-TiO 2 ) nanocomposites are discussed below. Implications of introducing oMMT and TiO 2 nanoparticles on mechanical and dry sliding wear properties are presented using micrographs of cast samples and through observations of wear affected surface of nanocomposites. Distribution of nanoparticles and their influence on properties are being emphasized for under-standing the wear properties. The data on mechanical and tribological properties determined experimentally are compared with published literature. The main focus is to highlight the importance of nanofillers in the design of wear-resistant thermoset polymer composites. A detailed study of strength and moduli of Epoxy-oMMT, Epoxy-TiO 2 and vinyl ester-oMMT nanocomposites was taken up as a part of the investigation. A discussion on density, hardness, tensile, flexural test data, and friction and wear of nanocomposites and analysis of results by comparison with prevalent theoretical models and published results of experiments are presented.
本文讨论了有机改性蒙脱土(oMMT)掺杂环氧树脂(Epoxy-oMMT)、乙烯基酯(vinyl ester-oMMT)和二氧化钛(TiO 2)填充环氧(Epoxy-TiO 2)纳米复合材料的摩擦学和力学性能。通过对铸造样品的显微照片和纳米复合材料磨损影响表面的观察,介绍了引入oMMT和tio2纳米颗粒对机械和干滑动磨损性能的影响。纳米颗粒的分布及其对性能的影响是了解耐磨性能的重点。实验测定的力学和摩擦学性能数据与已发表的文献进行了比较。重点是强调纳米填料在设计耐磨热固性聚合物复合材料中的重要性。对环氧树脂- ommt、环氧树脂- tio2和乙烯基酯- ommt纳米复合材料的强度和模量进行了详细的研究。讨论了纳米复合材料的密度、硬度、拉伸、弯曲试验数据、摩擦和磨损,并与流行的理论模型和已发表的实验结果进行了比较分析。
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引用次数: 0
Kinetic Features of Synthesis of Epoxy Nanocomposites 环氧纳米复合材料合成的动力学特征
Pub Date : 2019-07-12 DOI: 10.5772/INTECHOPEN.85137
V. Irzhak
Kinetic features of the formation of epoxy nanocomposites with carbon (nanotubes, graphene, and graphite), metal-containing, and aluminosilicate (montmorillonite and halloysite) fillers are considered. In contrast to linear polymers, epoxy nanocomposites are obtained only via the curing of epoxy oligomers in the presence of filler or the corresponding precursor. These additives may affect the kinetics of the process and the properties of the resulting matrix. A high reactivity of epoxy groups and a thermodynamic miscibility of epoxy oligomers with many substances make it possible to use diverse curing agents and to accomplish curing reactions under various technological conditions. The mutual effect of both a matrix and nanoparticles on the kinetics of the composite formation is discussed.
考虑了碳(纳米管、石墨烯和石墨)、含金属和铝硅酸盐(蒙脱土和高岭土)填料形成环氧纳米复合材料的动力学特征。与线性聚合物相比,环氧纳米复合材料只能通过在填料或相应前驱体的存在下固化环氧低聚物来获得。这些添加剂可能会影响该过程的动力学和所得基体的性能。环氧基团的高反应性和环氧低聚物与许多物质的热力学混溶性使得使用不同的固化剂和在不同的工艺条件下完成固化反应成为可能。讨论了基质和纳米颗粒对复合材料形成动力学的相互影响。
{"title":"Kinetic Features of Synthesis of Epoxy Nanocomposites","authors":"V. Irzhak","doi":"10.5772/INTECHOPEN.85137","DOIUrl":"https://doi.org/10.5772/INTECHOPEN.85137","url":null,"abstract":"Kinetic features of the formation of epoxy nanocomposites with carbon (nanotubes, graphene, and graphite), metal-containing, and aluminosilicate (montmorillonite and halloysite) fillers are considered. In contrast to linear polymers, epoxy nanocomposites are obtained only via the curing of epoxy oligomers in the presence of filler or the corresponding precursor. These additives may affect the kinetics of the process and the properties of the resulting matrix. A high reactivity of epoxy groups and a thermodynamic miscibility of epoxy oligomers with many substances make it possible to use diverse curing agents and to accomplish curing reactions under various technological conditions. The mutual effect of both a matrix and nanoparticles on the kinetics of the composite formation is discussed.","PeriodicalId":280616,"journal":{"name":"Nanorods and Nanocomposites","volume":"48 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127386157","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Graphene-Like Nanocomposites Graphene-Like纳米复合材料
Pub Date : 2019-06-19 DOI: 10.5772/INTECHOPEN.85513
Z. Rafiei-Sarmazdeh, S. Ahmadi
After discovering graphene and its extraordinary intrinsic, other graphene-like nanomaterials (GLNs) became a topic of interest to many scientists of the time. Recently, GLNs, nanosheets of sp 2 -hybridized atoms arranged in a two-dimensional lattice with impressive thermal, mechanical, and electrical properties, has attracted both academic and industrial interest because it can produce dramatic improve-ments in properties at very low filler content. Many studies have been performed on GLNs with various applications, including boron nitride nanosheets, transition metal dichalcogenides, and other two-dimensional (2D) nanomaterials. This rapid advance provides a strong appetence for further research on properties of GLNs, including mechanical, electrical and thermal properties and their potential applications in the nanocomposites industry.
在发现石墨烯及其非凡的内在特性之后,其他类石墨烯纳米材料(gln)成为当时许多科学家感兴趣的话题。最近,由sp - 2杂化原子组成的纳米片排列在二维晶格中,具有令人印象深刻的热学、力学和电学性能,引起了学术界和工业界的兴趣,因为它可以在非常低的填料含量下产生显著的性能改善。许多研究已经在各种应用上进行,包括氮化硼纳米片,过渡金属二硫族化合物和其他二维(2D)纳米材料。这一快速进展为进一步研究gln的力学、电学和热性能及其在纳米复合材料工业中的潜在应用提供了强有力的前景。
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引用次数: 0
Nanomaterials: An Overview of Nanorods Synthesis and Optimization 纳米材料:纳米棒的合成与优化综述
Pub Date : 2019-05-13 DOI: 10.5772/INTECHOPEN.84550
Alsultan Abdul Kareem Ghassan, N. Mijan, Y. Taufiq-Yap
Nanorods are nanostructures that are the object of fundamental and applied research. They may be prepared from carbon, gold, zinc oxide, and many other materials. They are bigger than individual atoms (measured in angstroms, 1 Å = 10 (cid:1) 10 m) and also than small molecules. The turning point for nanomaterials research was the discovery of carbon nanotubes in 1991. Their mechanical, electrical, and optical properties depend upon their size, allowing for multiple applications. Also, nanorods may be functionalized for different applications. In this Chapter, the methods of synthesis and analysis, and the applications of carbon, zinc oxide, gold, and magnetic nanorods are reviewed. route, sol-gel, vapor condensa-tion, spray pyrolysis, pulse laser decomposition, laser ablation, thermal evapora-tion, pulse combustion-spray pyrolysis, electro-mechanical, flame spray plasma, microwave plasma, low energy beam deposition, ball-milling, chemical vapor deposition, laser ablation, chemical reduction, co-precipitation, hybrid wet chemical route, physical evaporation, electrophoretic deposition, radio frequency (RF) magnetron sputtering,
纳米棒是一种纳米结构,是基础研究和应用研究的对象。它们可以由碳、金、氧化锌和许多其他材料制备。它们比单个原子大(以埃为单位,1 Å = 10 (cid:1) 10 m),也比小分子大。纳米材料研究的转折点是1991年碳纳米管的发现。它们的机械、电气和光学性能取决于它们的尺寸,允许多种应用。此外,纳米棒可以被功能化用于不同的应用。本章综述了碳纳米棒、氧化锌纳米棒、金纳米棒和磁性纳米棒的合成、分析方法及其应用。溶胶-凝胶、蒸汽冷凝、喷雾热解、脉冲激光分解、激光烧蚀、热蒸发、脉冲燃烧-喷雾热解、机电、火焰喷射等离子体、微波等离子体、低能束沉积、球磨、化学气相沉积、激光烧蚀、化学还原、共沉淀、混合湿化学路线、物理蒸发、电泳沉积、射频(RF)磁控溅射、
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引用次数: 40
Nanostructure Technology for EO/IR Detector Applications 纳米结构技术在EO/IR探测器中的应用
Pub Date : 2019-04-01 DOI: 10.5772/INTECHOPEN.85741
A. Sood, J. Zeller, G. Pethuraja, R. Welser, N. Dhar, P. Wijewarnasuriya
This chapter covers recent advances in the development of nanostructure-based material technologies to benefit next-generation electro-optical (EO) and infrared (IR) sensor and imager applications. Nanostructured materials can now be integrated into a variety of technological platforms, offering novel optoelectrical properties that greatly enhance device performance in many practical applications. Use of novel carbon nanotube (CNT) based materials has enabled new approaches for applying nanostructure design methodologies that can offer enhanced performance for low-cost bolometers for IR detection and imaging applications. We will discuss the development of carbon nanostructure based infrared detectors and arrays, including concepts that will provide high performance, high frame rate, and uncooled microbolometers for mid-wave infrared (MWIR) and long-wave infrared (LWIR) band detection. In addition, nanostructured antireflection (AR) coatings are being developed that significantly enhance transmission over a broad spectrum, providing substantial improvements in device performance compared to conven-tional thin film AR coatings. These nanostructured AR coatings have been demonstrated over visible to LWIR spectral bands on various substrates. In this chapter, we discuss both theoretical and measured results of these diverse nanostructure technologies to advance sensing performance over a wide range of spectral bands for defense, space, and commercial applications.
本章涵盖了纳米结构材料技术的最新进展,这些技术将有利于下一代光电(EO)和红外(IR)传感器和成像仪的应用。纳米结构材料现在可以集成到各种技术平台中,提供新颖的光电特性,大大提高了许多实际应用中的器件性能。新型碳纳米管(CNT)基材料的使用为应用纳米结构设计方法提供了新的途径,可以为用于红外探测和成像应用的低成本热辐射计提供更高的性能。我们将讨论基于碳纳米结构的红外探测器和阵列的发展,包括将为中波红外(MWIR)和长波红外(LWIR)波段检测提供高性能,高帧速率和非冷却微辐射热计的概念。此外,纳米结构的抗反射(AR)涂层正在开发中,它显著增强了广谱传输,与传统的薄膜AR涂层相比,在设备性能方面有了实质性的改进。这些纳米结构的AR涂层已经在各种基底上的可见光到低红外光谱波段上得到了证明。在本章中,我们讨论了这些不同纳米结构技术的理论和测量结果,以提高国防,空间和商业应用的广泛光谱波段的传感性能。
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引用次数: 14
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Nanorods and Nanocomposites
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