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Hydrocarbon-Impacted Soils Supported Mn for Organic Pollutant Oxidation 受碳氢化合物影响的土壤支持锰的有机污染物氧化作用
Pub Date : 2024-02-12 DOI: 10.31258/jamt.4.2.90-98
E. Saputra, Ahmad Fadli, B. Prawiranegara, A. Amri, D. Heltina, Syaiful Bahri, Ari Sandhyavitri, Fajar Restuhadi, H. Abid, Muhammad Rizwan Azhar, P. S. Utama
Hydrocarbon-impeded soil (HIS) is solid waste from spills or leaks during industrial activities that negatively impact the environment. This study aims to utilize HIS as catalyst support on MnO2 to degrade RhB (RhB) solution using Peroxymonosulfate (PMS) and to determine the optimum conditions for the catalyst to degrade RhB. The catalyst was synthesized by reacting HIS, calcined with KMnO4 with various catalyst supports with high and low Total contain Petroleum Hydrocarbon (TPH). The process degradation of Rhodamine Solution was carried out with various catalysts, PMS, and RhB concentrations. The catalyst was characterized using X-ray diffraction (XRD), Nitrogen gas adsorption-desorption (BET), and Scanning Electron Microscope-Energy Disperse Spectroscope (SEM-EDX). In this study,  the best catalyst performance was MnO2@H-TPH, which could activate PMS to degrade RhB with dye removal of 98% in about 180 min, at conditions 10 g/L RhB, 0.1 g/L catalyst, and 3 g/L PMS with the activation energy of 16.3 kJ/mol.
碳氢化合物受阻土壤(HIS)是工业活动中溢出或泄漏的固体废物,对环境造成负面影响。本研究旨在利用 HIS 作为二氧化锰上的催化剂载体,使用过一硫酸盐 (PMS) 降解 RhB 溶液,并确定催化剂降解 RhB 的最佳条件。催化剂是通过将 HIS 与煅烧过的 KMnO4 以及各种含石油烃(TPH)总量较高和较低的催化剂载体反应合成的。在使用不同催化剂、PMS 和 RhB 浓度的情况下,对罗丹明溶液进行了降解。使用 X 射线衍射 (XRD)、氮气吸附-解吸 (BET) 和扫描电子显微镜-能量分散光谱仪 (SEM-EDX) 对催化剂进行了表征。在这项研究中,催化剂性能最好的是 MnO2@H-TPH,在 10 g/L RhB、0.1 g/L 催化剂和 3 g/L PMS 的条件下,它可以活化 PMS 来降解 RhB,在约 180 分钟内染料去除率达到 98%,活化能为 16.3 kJ/mol。
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引用次数: 0
Hydrocarbon-Impacted Soils Supported Mn for Organic Pollutant Oxidation 受碳氢化合物影响的土壤支持锰的有机污染物氧化作用
Pub Date : 2024-02-12 DOI: 10.31258/jamt.4.2.90-98
E. Saputra, Ahmad Fadli, B. Prawiranegara, A. Amri, D. Heltina, Syaiful Bahri, Ari Sandhyavitri, Fajar Restuhadi, H. Abid, Muhammad Rizwan Azhar, P. S. Utama
Hydrocarbon-impeded soil (HIS) is solid waste from spills or leaks during industrial activities that negatively impact the environment. This study aims to utilize HIS as catalyst support on MnO2 to degrade RhB (RhB) solution using Peroxymonosulfate (PMS) and to determine the optimum conditions for the catalyst to degrade RhB. The catalyst was synthesized by reacting HIS, calcined with KMnO4 with various catalyst supports with high and low Total contain Petroleum Hydrocarbon (TPH). The process degradation of Rhodamine Solution was carried out with various catalysts, PMS, and RhB concentrations. The catalyst was characterized using X-ray diffraction (XRD), Nitrogen gas adsorption-desorption (BET), and Scanning Electron Microscope-Energy Disperse Spectroscope (SEM-EDX). In this study,  the best catalyst performance was MnO2@H-TPH, which could activate PMS to degrade RhB with dye removal of 98% in about 180 min, at conditions 10 g/L RhB, 0.1 g/L catalyst, and 3 g/L PMS with the activation energy of 16.3 kJ/mol.
碳氢化合物受阻土壤(HIS)是工业活动中溢出或泄漏的固体废物,对环境造成负面影响。本研究旨在利用 HIS 作为二氧化锰上的催化剂载体,使用过一硫酸盐 (PMS) 降解 RhB 溶液,并确定催化剂降解 RhB 的最佳条件。催化剂是通过将 HIS 与煅烧过的 KMnO4 以及各种含石油烃(TPH)总量较高和较低的催化剂载体反应合成的。在使用不同催化剂、PMS 和 RhB 浓度的情况下,对罗丹明溶液进行了降解。使用 X 射线衍射 (XRD)、氮气吸附-解吸 (BET) 和扫描电子显微镜-能量分散光谱仪 (SEM-EDX) 对催化剂进行了表征。在这项研究中,催化剂性能最好的是 MnO2@H-TPH,在 10 g/L RhB、0.1 g/L 催化剂和 3 g/L PMS 的条件下,它可以活化 PMS 来降解 RhB,在约 180 分钟内染料去除率达到 98%,活化能为 16.3 kJ/mol。
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引用次数: 0
Computational Fluid Dynamics Modeling of Fermentation Reactions in Bioethanol Fermentor: A Review 生物乙醇发酵罐中发酵反应的计算流体力学模型:综述
Pub Date : 2024-01-04 DOI: 10.31258/jamt.4.2.79-89
Ali Satria Wijaya, Novia Novia, Fitri Hadiah
Bioethanol is a renewable energy source that can replace fossil fuels. The advantages in terms of economy and its impact on the environment make bioethanol was chosen as a biofuel. Bioethanol can be produced from various types of biomasses with the help of microorganisms, namely yeast, for the fermentation process. In manufacturing, factors including temperature, concentration, pH, fermentation time, and stirring speed influence the fermentation process. Computational Fluid dynamics (CFD) package can be applied to observe the procedures in a fermenter. CFD simulates fluid movement, energy transport, chemical reactions, and other phenomena with the aim of clarifying their impact on the overall effectiveness of bioethanol production. In this journal, a review of the fermentation process with CFD modeling was made to look at the parameters and phenomena during the bioethanol production process. The analysis commences with an examination of the processes involved in bioethanol production and underscores the crucial role of fermentation in transforming renewable resources into bioethanol. Subsequently, it delves into the foundational principles of CFD and how they are incorporated into the modeling of bioethanol fermenters. Furthermore, the review highlights key advancements and innovations in CFD modeling techniques, such as multiphase models, turbulence modeling, and coupled simulations, aiming to capture the intricate interplay of physical and biological phenomena within fermentors. Insights into the impact of operating conditions, reactor design, and microbial behavior on bioethanol yield and quality are discussed, providing a comprehensive understanding of the complex system dynamics.
生物乙醇是一种可替代化石燃料的可再生能源。生物乙醇在经济性和对环境影响方面的优势使其被选为生物燃料。生物乙醇可在微生物(即酵母)的帮助下,通过发酵过程从各种生物质中生产出来。在生产过程中,温度、浓度、pH 值、发酵时间和搅拌速度等因素都会影响发酵过程。计算流体动力学(CFD)软件包可用于观察发酵罐中的程序。CFD 模拟流体运动、能量传输、化学反应和其他现象,目的是阐明它们对生物乙醇生产整体效果的影响。在本期刊中,我们利用 CFD 模型对发酵过程进行了回顾,以研究生物乙醇生产过程中的参数和现象。分析从研究生物乙醇生产过程开始,强调了发酵在将可再生资源转化为生物乙醇过程中的关键作用。随后,报告深入探讨了 CFD 的基本原理,以及如何将这些原理融入生物乙醇发酵罐的建模中。此外,该综述还重点介绍了 CFD 建模技术的主要进展和创新,如多相模型、湍流建模和耦合模拟,旨在捕捉发酵罐内物理和生物现象错综复杂的相互作用。研究讨论了操作条件、反应器设计和微生物行为对生物乙醇产量和质量的影响,从而提供了对复杂系统动态的全面理解。
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引用次数: 0
Various Methods of Strengthening Reinforced Concrete Beam-Column Joint Subjected Earthquake-Type Loading Using Fibre-Reinforced Polymers: A Critical Review 纤维增强聚合物加固地震荷载下钢筋混凝土梁柱节点的各种方法综述
Pub Date : 2023-08-30 DOI: 10.31258/jamt.4.2.42-55
Ridwan Ridwan, Yaser Jemaa, E. Yuniarto
Fibre-reinforced polymer (FRP) composites are extensively employed in concrete technology due to their exceptional mechanical strength and durability.  They serve a dual purpose, not only reinforcing damaged elements but also supporting heavier service loads and addressing long-term concerns in new infrastructure projects. Consequently, the objective of this review is to establish a comprehensive research database that focuses on evaluating the strengthening behaviour of reinforced concrete (RC) beam-column joints (BCJ) under earthquake loads through diverse types and application methods of FRP composites. The efficacy of these strengthening techniques is assessed by considering factors such as the loading capacity and dissipated energy of RC BCJ versus the joint confinement index provided by the fibre in the joint area. Through this state-of-the-art review, it becomes evident that FRP composites effectively enhanced the normalized load of specimens up to 27 kN/?MPa and enhanced the dissipated energy until 558.6 kN-mm for the case of specimens with a lower confinement index, less than 0.3. Additionally, the specimen strengthened with the deep embedment (DE) method resulted in a moderate normalized load and dissipated energy compared to those strengthened with the external bonded (EB) method. The test results indicated that the average normalized load and dissipated energy of the DE-strengthening method was 93% and 28.5% compared to that of the EB-strengthening method. These findings reveal that FRP composites offer distinct advantages in terms of load capacity and dissipated energy when used for strengthening earthquake-affected RC BCJ. Finally, based on the compilation of the previous works, this research proposes several techniques for utilizing FRP composites to enhance RC BCJ subjected to earthquake load.
纤维增强聚合物(FRP)复合材料因其优异的机械强度和耐久性而广泛应用于混凝土技术。它们具有双重作用,不仅可以加固损坏的部件,还可以支持更重的服务负载,并解决新基础设施项目中的长期问题。因此,本综述的目的是建立一个全面的研究数据库,重点是通过不同类型和FRP复合材料的应用方法来评估地震荷载下钢筋混凝土(RC)梁柱节点(BCJ)的加固行为。通过考虑RC BCJ的承载能力和耗散能量与关节区域纤维提供的关节约束指数等因素来评估这些强化技术的有效性。通过这项最新的研究,FRP复合材料可以有效地将试件的归一化载荷提高到27 kN/?当约束系数小于0.3时,耗散能达到558.6 kN-mm。此外,与采用外粘结(EB)方法加固的试件相比,采用深埋(DE)方法加固的试件具有中等的归一化载荷和耗散能量。试验结果表明,de强化法的平均归一化荷载和耗散能分别比eb强化法高93%和28.5%。这些研究结果表明,FRP复合材料在用于加固地震影响的RC BCJ时,在承载能力和耗散能量方面具有明显的优势。最后,在总结前人研究成果的基础上,提出了几种利用FRP复合材料增强地震荷载作用下RC BCJ的技术。
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引用次数: 0
Energy Router Applications in the Electric Power System 能源路由器在电力系统中的应用
Pub Date : 2023-07-25 DOI: 10.31258/jamt.4.2.56-68
B. Umar
Energy router is being investigated to replace conventional transformer in the electric grid. Improvement so far observed in use of converter makes possible the intelligent integration between systems with different characteristics’ in terms of frequency and voltage levels as well as exploitation of generation sources and storage systems typically operating in DC. Consequently, it is believed that Energy Router is able to interconnect different portions of electrical networks and at different voltage levels and types. The Energy Router is an assembly of converters isolated by a medium or high frequency transformer. In its design, different voltage levels and types are made available to achieve high results in terms of system integration, efficiency and flexibility. This paper evaluates the main potentials of this technology if widely introduced in the main power system. Starting from the single component description, a couple of possible applications are presented and discussed.
目前正在研究用能源路由器取代电网中的传统变压器。迄今为止,在使用变流器方面所取得的进步使得具有不同频率和电压水平特性的系统之间的智能集成成为可能,也使得对通常以直流方式运行的发电和储能系统的利用成为可能。因此,我们认为能源路由器能够在不同电压等级和类型的电网中实现不同部分的互联。能源路由器是一个由中频或高频变压器隔离的变流器组件。在其设计中,可提供不同的电压等级和类型,从而在系统集成、效率和灵活性方面实现更高的效果。本文评估了该技术在主电力系统中广泛应用的主要潜力。从单个组件的描述开始,介绍并讨论了一些可能的应用。
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引用次数: 0
Speed Control of Three Phase Induction Motor using PI Controller with Space Vector Width Modulation (SVPWM) Technique 基于空间矢量宽度调制(SVPWM)技术的PI控制器三相异步电动机速度控制
Pub Date : 2023-07-24 DOI: 10.31258/jamt.4.1.34-41
Iswadi Hasyim Rosma, A. Hamzah, A. L. N. Kasan, A. Abdulkarim, S. Abdelkader
This article aimed to design and simulated the speed control of a three-phase induction motor using a PI controller with Space Vector Pulse width modulation technique. The induction motor  used in this article is was designed at the Electrical Energy Conversion Laboratory, Riau University, with a power of 1.1 kW, 380 V, 2-pole. Meanwhile, the PI controller constants used in designing this induction motor were determined using the Fine Tunning method to obtain KP and KI values of 3.539 and 9.526, respectively. The tests were carried out by running simulations in three conditions, namely no load, full load, and variable load at a speed of 2800 rpm. The test results showed that the use of a PI controller can improve the speed response of induction motors by eliminating the steady state error. This is in addition to increasing the rise time response of the motor speed by 0.012s and 0.046s at no load and full load, respectively, when the rise time analysis is at the same value. It can also accelerate the motor to reach a peak speed of 0.247 s and 0.166s at no load and full load. In addition, SPVWM with PI controller can maintain speed setting even though there is a load change during operation, which can be verified with load testing.
本文旨在利用空间矢量脉宽调制技术的PI控制器设计和仿真三相感应电动机的速度控制。本文使用的感应电机是廖内大学电能转换实验室设计的,功率为1.1 kW, 380v, 2极。同时,采用Fine Tunning方法确定设计该感应电机所用PI控制器常数,得到KP为3.539,KI为9.526。试验在空载、满载和变载三种工况下进行模拟运行,转速为2800转/分。测试结果表明,采用PI控制器可以通过消除稳态误差来改善感应电机的速度响应。此外,当上升时间分析为相同值时,电机转速的上升时间响应在空载和满载时分别增加0.012s和0.046s。它还可以加速电机在空载和满载时达到0.247 s和0.166s的峰值速度。此外,带PI控制器的SPVWM在运行过程中即使有负载变化也能保持转速设置,这可以通过负载测试来验证。
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引用次数: 0
Failure Analysis of High-Pressure Turbine Blades in Steam Power Plants 蒸汽电厂高压涡轮叶片失效分析
Pub Date : 2023-07-18 DOI: 10.31258/jamt.4.1.24-33
Anggit Aji Purnomo, Sunaryo Sunaryo, A. K. Nasution
This paper describes the failure of high-pressure steam turbine blades. During the Serious Inspection, it was discovered that the ninth-stage high-pressure turbine blade had failed. The causes of blade failure are examined via visual inspection and destructive testing. The failure mechanism of the blades was determined by conducting mechanical properties testing, metallographic inspection, and energy spectrum analysis. The mechanical properties of the leaf and root blade specimens were within the range of blade steel for steam turbines according to the Chinese National Standard (GB/T 8732-2004), but the chemical composition was not identical. This is consistent with the root blade fracture pattern where the hardness value plotted from the test results is the lowest at the root blade location, which is the primary cause of fissure propagation.
介绍了高压汽轮机叶片的失效。在严重检查中,发现第9级高压涡轮叶片失效。叶片失效的原因是通过目测和破坏性测试来检查的。通过力学性能测试、金相检验和能谱分析,确定了叶片的失效机理。叶片和根叶片试样的力学性能符合中国国家标准(GB/T 8732-2004)对汽轮机叶片钢的要求,但化学成分不相同。这与根叶片断裂模式一致,从测试结果中绘制的硬度值在根叶片位置最低,这是裂纹扩展的主要原因。
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引用次数: 0
Improvements in Physical and Mechanical Properties of Asphalt by Addition of Low-cost Few-layers Graphene (FLG) 低成本少层石墨烯(FLG)对沥青物理力学性能的改善
Pub Date : 2023-06-25 DOI: 10.31258/jamt.4.1.18-23
A. Amri, M. Sugandi, S. P. Utami, Muhammad Shalahuddin, S. Saputro
Physical and mechanical properties of asphalt have been improved by adding of few-layers graphene (FLG). FLG was obtained from a simple, low-cost and environmentally friendly liquid shear exfoliation method using a kitchen blender. The melted asphalt at temperature of 150oC was mixed with FLG at various concentrations (10 mg/ml, 20 mg/ml and 30 mg/ml) and contents (0 wt%, 3 wt%, 6 wt%, and 9 wt%) by weight of asphalt. The homogenized mixture was taken for penetration and softening point tests, while the mixing with aggregates was carried out for Marshall stability and asphalt concrete flow tests. The characteristics of void in mixture (VIM), void filled with asphalt (VFA), and void in mineral aggregate (VMA) were also investigated. The penetration values decreased (or the asphalt hardness increased) linearly with increasing of FLG concentration and FLG content. The softening point of asphalt increased as the increasing of FLG concentration and FLG content in asphalt with the average softening point increase of about 5%. The Marshall stability and asphalt concrete flow increased with increasing of FLG concentrations and FLG content. However, the addition of FLG did not affect the VIM, VFA or VMA values. Overall, the addition of FLG improves the physical and mechanical properties of asphalt and has promising prospects due to low-cost and eco-friendly nature of FLG.
少量石墨烯(FLG)的加入改善了沥青的物理力学性能。FLG是一种简单、低成本、环保的液体剪切剥落方法。将温度为150℃的熔融沥青与按沥青重量计不同浓度(10mg /ml、20mg /ml和30mg /ml)和含量(0 wt%、3 wt%、6 wt%和9 wt%)的FLG混合。采用均质混合料进行渗透试验和软化点试验,加入骨料进行马歇尔稳定性试验和沥青混凝土流动试验。研究了混合料空隙(VIM)、沥青填充空隙(VFA)和矿物集料空隙(VMA)的特性。随着FLG浓度和FLG含量的增加,渗透值呈线性降低(或增加);随着沥青中FLG浓度和FLG含量的增加,沥青的软化点增加,平均软化点增加约5%。随着FLG浓度和FLG含量的增加,马歇尔稳定性和沥青混凝土流量增大。然而,FLG的加入对VIM、VFA和VMA值没有影响。总的来说,FLG的加入改善了沥青的物理力学性能,由于FLG的低成本和环保性,具有广阔的应用前景。
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引用次数: 0
Development of Cork-Bamboo-Latex as An Alternative Composite for Bottles Stoppers 软木-竹-乳胶瓶塞替代材料的研制
Pub Date : 2023-05-11 DOI: 10.31258/jamt.4.1.11-17
A. Soares Brito, Leonardo Nader Chagas, Juarez Vicente, A. Moreira, Cristiane Hess de Azevedo Meleiro, H. Corrêa, A. M. do Nascimento, Renata Nunes Oliveira
Agglomerated cork composites production has been arising as an alternative eco-friendly to cork stoppers use and attracts interest to create sustainable products and materials. A cork-bamboo-latex composite was developed by compression-molding and the interaction between three composite interfaces as well as their mechanical properties were evaluated by density measure, immersion test, FTIR, compression test, and microbial analysis aiming to produce an alternative material to wine closures. The results obtained were compared between the composite produced and the commercial agglomerated cork stoppers. It was possible to observe that the cork-bamboo-latex composite produced exhibited a good adhesion of all components and similar characteristics. However, it presented a slight increase in the density (from 0.37 g/cm3 to 0.65 g/cm3) and Young's modulus (from 0.033 MPa to 0.037 MPa) producing a stiffer material mainly due to bamboo presence. The migration of the stopper components (cork, bamboo, or latex) for the wine was not detected, as well as there was no visible interaction between wine and composite. In this work, the cork-bamboo-latex stopper fabricated presents a potential application as an alternative material to wine stoppers and stimulates the production of a sustainable material.
胶合软木复合材料的生产已经成为环保软木塞的替代品,并吸引了人们创造可持续产品和材料的兴趣。采用压缩成型的方法制备了一种软木-竹-乳胶复合材料,并通过密度测试、浸渍测试、红外光谱、压缩测试和微生物分析来评估三种复合材料界面之间的相互作用及其力学性能,旨在生产一种替代葡萄酒瓶塞的材料。并将所制备的复合材料与工业软木塞进行了比较。可以观察到,生产的软木-竹-乳胶复合材料具有良好的粘附性和相似的特性。然而,由于竹子的存在,密度(从0.37 g/cm3增加到0.65 g/cm3)和杨氏模量(从0.033 MPa增加到0.037 MPa)略有增加,产生了更硬的材料。没有检测到葡萄酒的塞子成分(软木、竹子或乳胶)的迁移,也没有发现葡萄酒和复合材料之间的明显相互作用。在这项工作中,软木-竹-乳胶制成的塞呈现出作为葡萄酒塞的替代材料的潜在应用,并刺激了可持续材料的生产。
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引用次数: 0
Electrochemical performance of aqueous electrolytes in porous carbon derived cassava peel electrode material-based for sustainable symmetrical supercapacitor 多孔碳基木薯皮电极材料中水电解质的电化学性能研究
Pub Date : 2023-03-20 DOI: 10.31258/jamt.4.1.1-10
E. Taer, Harahap Eva Wahyuni, A. Apriwandi, Taslim Rika
Electrolytes have been generally recognized as one of the most important components in enhancing the electrochemical performance of supercapacitors. On the other hand, aqueous electrolytes are considered prime candidates for the development of the next generation of symmetric supercapacitors due to their low-cost, environmentally friendly, high ionic conductivity, fine ionic size, and high capacitance. Herein, the symmetrical supercapacitor of the sustainable porous carbon-based electrode material was confirmed through various aqueous electrolytes consisting of neutral, basic, and acidic Na2SO4, KOH, and H2SO4. Activated carbon is obtained from high potential biomass sources of cassava peel waste. Activated carbon synthesis was performed with a comprehensive approach in order to obtain abundant pore structure, high porosity, and improved wettability through a combination of high-temperature chemical and physical activation. in addition, the electrode material is designed to resemble a solid disc without the addition of a synthetic binder. The evaluation of the disc dimensions showed high porosity in the obtained activated carbon. Furthermore, the symmetrical supercapacitor of the optimized electrode material exhibit excellent specific capacitances of 112, 150, and 183 F g-1 at 1 mV s-1 in the electrolytes Na2SO4, KOH, and H2SO4, respectively. In addition, the highest rate capability of 70% was confirmed in the H2SO4 acid electrolyte. Moreover, their coulombic efficiency can be maintained around 89% with low equivalent series resistance 0.21-0.42 ?. Therefore, the activated carbon-based supercapacitor symmetric cell device from cassava peel shows high performance for developing high-performance supercapacitor applications with guaranteed stability in aqueous electrolytes.
电解液是提高超级电容器电化学性能的重要组成部分之一。另一方面,水电解质由于其低成本、环保、高离子电导率、细离子尺寸和高电容而被认为是开发下一代对称超级电容器的主要候选者。本文通过中性、碱性和酸性Na2SO4、KOH和H2SO4等不同的水溶液,确定了可持续多孔碳基电极材料的对称超级电容器。活性炭是从木薯皮废料的高潜力生物质资源中获得的。通过高温化学活化和物理活化相结合,以获得丰富的孔隙结构、高孔隙度和改善的润湿性为目的,对活性炭进行了综合合成。此外,电极材料被设计成类似于固体圆盘,而不需要添加合成粘合剂。圆盘尺寸的评价表明,所得活性炭的孔隙率很高。在Na2SO4、KOH和H2SO4电解液中,对称超级电容器在1 mV s-1下的比电容分别为112、150和183 F -1。此外,在H2SO4酸性电解液中,其倍率最高可达70%。此外,它们的库仑效率可以保持在89%左右,等效串联电阻低0.21-0.42 ?因此,由木薯皮制成的活性炭基超级电容器对称电池装置在开发高性能超级电容器应用方面表现出了很高的性能,并保证了其在水性电解质中的稳定性。
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引用次数: 0
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Journal of Applied Materials and Technology
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