Herein, mixed–metal nanocomposite catalysts with various compositions (CoFe2O4/xFe2O3; x = 0, 0.25, 0.50, 0.75 and 1) were successfully fabricated by a co–precipitation method. The composition and morphology of the catalyst were systematically characterized. The catalyst with the highest Co content (CoFe2O4), exhibited the greatest efficiency for the acid orange 7 (AO7) degradation via peroxymonosulfate (PMS) activation. The effects of several experimental parameters including pH, CoFe2O4 loading, and PMS dosage on AO7 degradation were studied, and the catalytic activity was found to increase with the mentioned parameters. Moreover, CoFe2O4 displayed adequate reusability and was able to degrade AO7 for at least four consecutive cycles. In addition, the total organic carbon (TOC) removal of CoFe2O4 was determined while the catalyst stability was observed from the metal leaching in the treated solution. Furthermore, the magnetism of CoFe2O4 provides facile separation of the catalyst from the treated solution. Sulfate radicals (SO4•–) were identified as the main reactive species responsible for AO7 degradation.
{"title":"Peroxymonosulfate activation using CoFe2O4/Fe2O3 nanocomposite for Acid Orange removal","authors":"Mohamed Faisal Gasim, Qing-Sheng Gooi, Wen-Da Oh","doi":"10.31258/jamt.3.2.34-43","DOIUrl":"https://doi.org/10.31258/jamt.3.2.34-43","url":null,"abstract":"Herein, mixed–metal nanocomposite catalysts with various compositions (CoFe2O4/xFe2O3; x = 0, 0.25, 0.50, 0.75 and 1) were successfully fabricated by a co–precipitation method. The composition and morphology of the catalyst were systematically characterized. The catalyst with the highest Co content (CoFe2O4), exhibited the greatest efficiency for the acid orange 7 (AO7) degradation via peroxymonosulfate (PMS) activation. The effects of several experimental parameters including pH, CoFe2O4 loading, and PMS dosage on AO7 degradation were studied, and the catalytic activity was found to increase with the mentioned parameters. Moreover, CoFe2O4 displayed adequate reusability and was able to degrade AO7 for at least four consecutive cycles. In addition, the total organic carbon (TOC) removal of CoFe2O4 was determined while the catalyst stability was observed from the metal leaching in the treated solution. Furthermore, the magnetism of CoFe2O4 provides facile separation of the catalyst from the treated solution. Sulfate radicals (SO4•–) were identified as the main reactive species responsible for AO7 degradation.","PeriodicalId":287674,"journal":{"name":"Journal of Applied Materials and Technology","volume":"18 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-03-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116648157","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Olivia, Rudy Satriya Pratama, Ferisma Ratu Giri, I. R. Sitompul, Alfian ' Kamaldi, G. Wibisono, E. Saputra
Geopolymer hybrid concrete is prepared by activating fly ash bottom ash with an alkaline solution and curing with Ordinary Portland Cement (OPC). OPC could be added to the mixture to increase the reaction, promote hydration, and assist in curing at room temperature. Peat water is an acidic organic environment that may reduce the durability of concrete. The purpose of this research is to determine the effect of Portland cement on the properties of FABA geopolymer hybrid concrete exposed to peat water. Portland cement was used in geopolymer as an additive and a substitute. Compressive strength, porosity, and weight change were evaluated for both mixtures. The NaOH molarities were 10, 12, and 14M, the NaOH/sodium silicate ratios were 1.5, 2.0, and 2.5, and the Ordinary Portland Cement percentages were 0, 10, and 15%. Specimens were exposed to peat water for up to 91 days following 28 days of room temperature curing. The geopolymer mixture with 10M NaOH, 2.5M Ms, and 15% OPC had the highest compressive strength and the lowest porosity. The FABA geopolymer hybrid with OPC had a slightly greater compressive strength and a lower porosity than the geopolymer containing OPC as a cement replacement material. In addition, weight change is more stable in geopolymers containing OPC. Based on the performance of both mixes in peat water, it is recommended to use OPC as an additive in FABA geopolymer hybrid concrete.
{"title":"The Effect of Portland Cement on Fly Ash Bottom Ash Geopolymer Hybrid Concrete Exposed to Peat Water Environment","authors":"M. Olivia, Rudy Satriya Pratama, Ferisma Ratu Giri, I. R. Sitompul, Alfian ' Kamaldi, G. Wibisono, E. Saputra","doi":"10.31258/jamt.3.2.24-33","DOIUrl":"https://doi.org/10.31258/jamt.3.2.24-33","url":null,"abstract":"Geopolymer hybrid concrete is prepared by activating fly ash bottom ash with an alkaline solution and curing with Ordinary Portland Cement (OPC). OPC could be added to the mixture to increase the reaction, promote hydration, and assist in curing at room temperature. Peat water is an acidic organic environment that may reduce the durability of concrete. The purpose of this research is to determine the effect of Portland cement on the properties of FABA geopolymer hybrid concrete exposed to peat water. Portland cement was used in geopolymer as an additive and a substitute. Compressive strength, porosity, and weight change were evaluated for both mixtures. The NaOH molarities were 10, 12, and 14M, the NaOH/sodium silicate ratios were 1.5, 2.0, and 2.5, and the Ordinary Portland Cement percentages were 0, 10, and 15%. Specimens were exposed to peat water for up to 91 days following 28 days of room temperature curing. The geopolymer mixture with 10M NaOH, 2.5M Ms, and 15% OPC had the highest compressive strength and the lowest porosity. The FABA geopolymer hybrid with OPC had a slightly greater compressive strength and a lower porosity than the geopolymer containing OPC as a cement replacement material. In addition, weight change is more stable in geopolymers containing OPC. Based on the performance of both mixes in peat water, it is recommended to use OPC as an additive in FABA geopolymer hybrid concrete.","PeriodicalId":287674,"journal":{"name":"Journal of Applied Materials and Technology","volume":"20 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124796992","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zeolitic material in powder form was prepared from fly ash by direct activation treatment. The resulted fly ash-based zeolite was pelletizing and the effect of different inorganic (calcium hydroxide, bentonite, kaolinite) and organic (dextrin) binders with varying percentage was investigated. The zeolitic materials were analyzed by XRF, XRD, SEM, FTIR, TG-DTG and Nitrogen adsorption/desorption isotherm. Compression and impact tests have been used to study the deformation and breakage behaviour of spherical granules. The best performance was obtained by zeolite granular containing 5 wt.% bentonite and 5 wt.% kaolinite with mechanical strength and satisfactory water resistance. The synthesis of pelletized zeolite from by-products derived from coal combustion provides not only environmental and economic benefits, but also contributes to achieving the principles of sustainable development.
{"title":"Optimization of Pelleting Parameters for Producing Composite Pellets Using Zeolitic Material From Fly Ash","authors":"D. Fungaro, T. Bertolini","doi":"10.31258/jamt.3.2.13-23","DOIUrl":"https://doi.org/10.31258/jamt.3.2.13-23","url":null,"abstract":"Zeolitic material in powder form was prepared from fly ash by direct activation treatment. The resulted fly ash-based zeolite was pelletizing and the effect of different inorganic (calcium hydroxide, bentonite, kaolinite) and organic (dextrin) binders with varying percentage was investigated. The zeolitic materials were analyzed by XRF, XRD, SEM, FTIR, TG-DTG and Nitrogen adsorption/desorption isotherm. Compression and impact tests have been used to study the deformation and breakage behaviour of spherical granules. The best performance was obtained by zeolite granular containing 5 wt.% bentonite and 5 wt.% kaolinite with mechanical strength and satisfactory water resistance. The synthesis of pelletized zeolite from by-products derived from coal combustion provides not only environmental and economic benefits, but also contributes to achieving the principles of sustainable development.","PeriodicalId":287674,"journal":{"name":"Journal of Applied Materials and Technology","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128518564","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Vanessa Zuliani, Rafaela Boni Serata, J. C. Izidoro
Urbanization growing is nowadays highlighted in the big cities. Therefore, it is necessary to increase the production of cement, which is used in several areas of civil construction, to supplement the growing demand. Thus, the objective of this study was to determine the content of hexavalent soluble chromium in Portland cement samples from different cement industries in São Paulo state, Brazil, since this chemical species can cause adverse health effects as well as being a potential human carcinogenic for those who manipulate it. In Brazil, the emission of Cr6+ in the cement has no restrictions, since there is no current Brazilian law that determines the maximum concentration of it, whereas, in Europe, the current law 2003/53/EC establishes a maximum of 2 mg.kg-1. So, the Cr6+ content for different cement samples was determined by spectrophotometry based on the European standard EN196-10/2006. It was found by the analysis that among all types of cement produced in São Paulo, the only one that did not exceed the standard limit was the CP III, probably because this kind of cement has a high concentration of additions in its composition, responsible for diluting thereby chromium content. The other types of cement exceeded the established limit. It was concluded that Brazil urgently needs a law to regulate the hexavalent soluble chromium emission present in Portland cement to minimize the environmental and health effects that the cement out of specification may cause.
{"title":"Determination of soluble hexavalent chromium in samples of Portland cement from Brazilian cement manufacturers","authors":"Vanessa Zuliani, Rafaela Boni Serata, J. C. Izidoro","doi":"10.31258/jamt.3.2.7-12","DOIUrl":"https://doi.org/10.31258/jamt.3.2.7-12","url":null,"abstract":"Urbanization growing is nowadays highlighted in the big cities. Therefore, it is necessary to increase the production of cement, which is used in several areas of civil construction, to supplement the growing demand. Thus, the objective of this study was to determine the content of hexavalent soluble chromium in Portland cement samples from different cement industries in São Paulo state, Brazil, since this chemical species can cause adverse health effects as well as being a potential human carcinogenic for those who manipulate it. In Brazil, the emission of Cr6+ in the cement has no restrictions, since there is no current Brazilian law that determines the maximum concentration of it, whereas, in Europe, the current law 2003/53/EC establishes a maximum of 2 mg.kg-1. So, the Cr6+ content for different cement samples was determined by spectrophotometry based on the European standard EN196-10/2006. It was found by the analysis that among all types of cement produced in São Paulo, the only one that did not exceed the standard limit was the CP III, probably because this kind of cement has a high concentration of additions in its composition, responsible for diluting thereby chromium content. The other types of cement exceeded the established limit. It was concluded that Brazil urgently needs a law to regulate the hexavalent soluble chromium emission present in Portland cement to minimize the environmental and health effects that the cement out of specification may cause.","PeriodicalId":287674,"journal":{"name":"Journal of Applied Materials and Technology","volume":"193 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128391680","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Modern Power Distribution Networks (MPDNs) are no longer passive because Distributed Generations (DGs) are integrated with them to enhance system reliability and power quality. For this reason, load modeling has to be updated to capture the new dynamics of active DNs. This paper presents a composite load modeling for a grid-connected photovoltaic (PV) distribution network using the Levenberg-Marquardt algorithm in the deep learning feed-forward neural network approach. Load modeling is constructing a relationship between input excitation(s) and output response(s); it can be used for simulation studies, stability analysis, and control/protection design. A grid-connected PV distribution network was modeled in Matlab/Simulink and generates data for training and model estimation. The estimated model was tested and validated using a laboratory experimental test bed. Results of the model exhibit a good fitness of 99.8% and 97.2% in active and reactive power models respectively during training. While 97.84% and 94.65% respectively were obtained during testing. The estimation errors were found to be 0.0025 and 0.0049 for active and reactive powers respectively with 0.0473 and 0.0701 corresponding errors in testing.
现代配电网络(Power Distribution network, mpdn)不再是被动的，因为它集成了分布式代(Distributed generation, dg)，提高了系统的可靠性和电能质量。出于这个原因，必须更新负载建模，以捕获活动DNs的新动态。本文采用深度学习前馈神经网络方法中的Levenberg-Marquardt算法对并网光伏配电网进行了复合负荷建模。负载建模是建立输入激励和输出响应之间的关系;它可以用于仿真研究，稳定性分析和控制/保护设计。在Matlab/Simulink中对并网光伏配电网进行建模，生成数据进行训练和模型估计。利用实验室实验平台对模型进行了验证。结果表明，该模型在训练过程中对有功和无功模型的适应度分别达到99.8%和97.2%。其中97.84%和94.65%为检测所得。有功功率和无功功率的估计误差分别为0.0025和0.0049，测试误差分别为0.0473和0.0701。
{"title":"A Deep-Learning Approach to Load Modeling in Modern Power Distribution System","authors":"Musaed Mohammed, A. Abdulkarim","doi":"10.31258/jamt.3.2.1-6","DOIUrl":"https://doi.org/10.31258/jamt.3.2.1-6","url":null,"abstract":"Modern Power Distribution Networks (MPDNs) are no longer passive because Distributed Generations (DGs) are integrated with them to enhance system reliability and power quality. For this reason, load modeling has to be updated to capture the new dynamics of active DNs. This paper presents a composite load modeling for a grid-connected photovoltaic (PV) distribution network using the Levenberg-Marquardt algorithm in the deep learning feed-forward neural network approach. Load modeling is constructing a relationship between input excitation(s) and output response(s); it can be used for simulation studies, stability analysis, and control/protection design. A grid-connected PV distribution network was modeled in Matlab/Simulink and generates data for training and model estimation. The estimated model was tested and validated using a laboratory experimental test bed. Results of the model exhibit a good fitness of 99.8% and 97.2% in active and reactive power models respectively during training. While 97.84% and 94.65% respectively were obtained during testing. The estimation errors were found to be 0.0025 and 0.0049 for active and reactive powers respectively with 0.0473 and 0.0701 corresponding errors in testing.","PeriodicalId":287674,"journal":{"name":"Journal of Applied Materials and Technology","volume":"5 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121814153","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Dansarki Nanly Wesley, A. Abdulkarim, P. U. Okorie, A. H. Jabire, S. Saminu, N. Faruk, I. S. Madugu, A. U. Lawan, I. Rosma
The continuous demand for electrical energy by industries and domestic users have stressed the electricity consumption to a high level. Because most components of domestic and industrial systems are made of power electronics devices in their designs. In addition, modern electrical power distribution networks (DNs) are subjected to major disturbances. Consequently, today’s power system is laden with power quality problems such as excessive energy losses, voltage deviations, poor power factor (PF), voltage instability and reliability issues to mentioned just a few. To forestall these disturbances, Distribution Engineers have introduced the use of Custom Power Devices (CPDs) in order to reduce power losses so as improve power quality. Amongst CPDs, Distribution Static Compensator (D-STATCOM) proves most promising in minimizing power quality issues because it generates minimal harmonics, waste less power, has small size, high regulatory capability and cost effective. Researchers in recent years have focused on methodologies required for identifying the most suitable location and rating of D- STATCOM device based on divergent views. However, to date, only one author has so far reviewed a paper on this aspect of study. This paper discusses the latest study on appropriate installation and rating of D-STATCOM techniques for balanced and unbalanced radial distribution networks (UBRDNs). The paper has also provided a comprehensive literature study on the location of DSTATCOM in RDNs for power loss reduction and power quality enhancement. Comparative analyses of various techniques for development of DSTATCOM Objective functions and constraints; Merits and Demerits are presented.
{"title":"A Review on Optimal Siting and Sizing of DSTATCOM","authors":"Dansarki Nanly Wesley, A. Abdulkarim, P. U. Okorie, A. H. Jabire, S. Saminu, N. Faruk, I. S. Madugu, A. U. Lawan, I. Rosma","doi":"10.31258/jamt.3.1.30-42","DOIUrl":"https://doi.org/10.31258/jamt.3.1.30-42","url":null,"abstract":"The continuous demand for electrical energy by industries and domestic users have stressed the electricity consumption to a high level. Because most components of domestic and industrial systems are made of power electronics devices in their designs. In addition, modern electrical power distribution networks (DNs) are subjected to major disturbances. Consequently, today’s power system is laden with power quality problems such as excessive energy losses, voltage deviations, poor power factor (PF), voltage instability and reliability issues to mentioned just a few. To forestall these disturbances, Distribution Engineers have introduced the use of Custom Power Devices (CPDs) in order to reduce power losses so as improve power quality. Amongst CPDs, Distribution Static Compensator (D-STATCOM) proves most promising in minimizing power quality issues because it generates minimal harmonics, waste less power, has small size, high regulatory capability and cost effective. Researchers in recent years have focused on methodologies required for identifying the most suitable location and rating of D- STATCOM device based on divergent views. However, to date, only one author has so far reviewed a paper on this aspect of study. This paper discusses the latest study on appropriate installation and rating of D-STATCOM techniques for balanced and unbalanced radial distribution networks (UBRDNs). The paper has also provided a comprehensive literature study on the location of DSTATCOM in RDNs for power loss reduction and power quality enhancement. Comparative analyses of various techniques for development of DSTATCOM Objective functions and constraints; Merits and Demerits are presented.","PeriodicalId":287674,"journal":{"name":"Journal of Applied Materials and Technology","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131218055","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Simulation technology has assisted project stakeholders in predicting a range of the project results in the future under risks and uncertainties. The objectives of this article are to improve a comprehensive project planning in the perspective of the project scheduling by conducting simulations for the refurbishment of crude oil tank project risks using Monte Carlo simulations. The practical approaches for simulating the risks encompassed 3 stages: risk identification, assessment, and risk analysis using the Monte Carlo simulations. The implementation of Monte Carlo simulation in the form of stochastic approach however were not new, but the application of these approaches in the area of oil industrial projects was challenging. A Free Water Knock-Out (FWKO) tank project located in Duri, Indonesia was taken as a case study. The initial FWKO project duration was set up to be 180 working days, and it was delayed (up to 140% from the initial duration of the project planning). This study conducted deep questioner surveys from 25 oil industry stakeholders. It was identified 29 risk factors have been considered as the major causes of the project delay. The risk factors were then calculated qualitatively for performing risk indexes. Based on the risk simulations (after 1000 iterations) using Monte Carlo simulations utilizing @risk application package (under uncertainties) there was found that the possibility of this project would experience delays at the range of 47 days (126%) to 80 days (144%) from the initial project planning. This simulation had also identified the most sensitive activities causing project delays. The results was presented in the form of the spider graph diagram which assisted the project main stakeholders in developing a strategic decision during project planning phase.
{"title":"Simulations of the Crude Oil Tank Refurbishment Project Risks Using Monte Carlo","authors":"A. Sandhyavitri, Arvin Arvin, F. Restuhadi","doi":"10.31258/jamt.3.1.22-29","DOIUrl":"https://doi.org/10.31258/jamt.3.1.22-29","url":null,"abstract":"Simulation technology has assisted project stakeholders in predicting a range of the project results in the future under risks and uncertainties. The objectives of this article are to improve a comprehensive project planning in the perspective of the project scheduling by conducting simulations for the refurbishment of crude oil tank project risks using Monte Carlo simulations. The practical approaches for simulating the risks encompassed 3 stages: risk identification, assessment, and risk analysis using the Monte Carlo simulations. The implementation of Monte Carlo simulation in the form of stochastic approach however were not new, but the application of these approaches in the area of oil industrial projects was challenging. A Free Water Knock-Out (FWKO) tank project located in Duri, Indonesia was taken as a case study. The initial FWKO project duration was set up to be 180 working days, and it was delayed (up to 140% from the initial duration of the project planning). This study conducted deep questioner surveys from 25 oil industry stakeholders. It was identified 29 risk factors have been considered as the major causes of the project delay. The risk factors were then calculated qualitatively for performing risk indexes. Based on the risk simulations (after 1000 iterations) using Monte Carlo simulations utilizing @risk application package (under uncertainties) there was found that the possibility of this project would experience delays at the range of 47 days (126%) to 80 days (144%) from the initial project planning. This simulation had also identified the most sensitive activities causing project delays. The results was presented in the form of the spider graph diagram which assisted the project main stakeholders in developing a strategic decision during project planning phase.","PeriodicalId":287674,"journal":{"name":"Journal of Applied Materials and Technology","volume":"14 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122889527","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ridwan Rahman, Ilham Akbar, Rofriantona Rofriantona
This study explores the 3D FE modelling approach in determining the behaviour of shear-dominant responses of RC beams. Five RC beams (A1, A2, B1, C2 and C3) with different cross-sections, amount of tension reinforcement area, amount of shear reinforcement and the length of the span was analysed and the results were compared with the results of the experiment and 2D analysis available in published literature. RC beams analysed in this FE study were constructed as a discrete model using ABAQUS software. The concrete and the plate for loading as well as for supports were modelled using the C3D8R element while longitudinal steel bars and stirrups were modelled with the T3D2 element. The interaction between the steel bar and the concrete in the FE model was assumed perfectly bond. The material behaviour of concrete was modelled with the damage plasticity model where the yield or failure of the material was governed by the tensile cracking and the compressive crushing of the concrete by introducing the hardening variables. The results showed that crack propagation in the FE analysis matched the cracks observed in the test. The crack pattern on Beam A1, A2, B1 and C2 indicated that the specimens experienced flexure and shear failure while Beam C3 experienced less brittle behaviour. Estimates of strength and the load–deformation response of 3D analysis were certainly achieved with reasonable accuracy compared to that of 2D analysis. The difference of experiment-to-2D strength (Pu,exp - Pu,2D / Pu,exp) had a mean of 4.53 whereas the difference of experiment-to-3D strength (Pu,exp - Pu,3D / Pu,exp) had a mean of 1.83. Furthermore, the displacements at ultimate load gained in the 3D analysis were comparable to those of experiments. The difference of experiment-to-2D (du,exp - du,2D / du,exp) and experiment-to-3D (du,exp - du,3D / du,exp) midspan displacement had a mean of 19.91 and 10.89, respectively.
{"title":"3D Finite Element Model for Shear-dominant Failure of Reinforced Concrete Beams","authors":"Ridwan Rahman, Ilham Akbar, Rofriantona Rofriantona","doi":"10.31258/jamt.3.1.12-21","DOIUrl":"https://doi.org/10.31258/jamt.3.1.12-21","url":null,"abstract":"This study explores the 3D FE modelling approach in determining the behaviour of shear-dominant responses of RC beams. Five RC beams (A1, A2, B1, C2 and C3) with different cross-sections, amount of tension reinforcement area, amount of shear reinforcement and the length of the span was analysed and the results were compared with the results of the experiment and 2D analysis available in published literature. RC beams analysed in this FE study were constructed as a discrete model using ABAQUS software. The concrete and the plate for loading as well as for supports were modelled using the C3D8R element while longitudinal steel bars and stirrups were modelled with the T3D2 element. The interaction between the steel bar and the concrete in the FE model was assumed perfectly bond. The material behaviour of concrete was modelled with the damage plasticity model where the yield or failure of the material was governed by the tensile cracking and the compressive crushing of the concrete by introducing the hardening variables. The results showed that crack propagation in the FE analysis matched the cracks observed in the test. The crack pattern on Beam A1, A2, B1 and C2 indicated that the specimens experienced flexure and shear failure while Beam C3 experienced less brittle behaviour. Estimates of strength and the load–deformation response of 3D analysis were certainly achieved with reasonable accuracy compared to that of 2D analysis. The difference of experiment-to-2D strength (Pu,exp - Pu,2D / Pu,exp) had a mean of 4.53 whereas the difference of experiment-to-3D strength (Pu,exp - Pu,3D / Pu,exp) had a mean of 1.83. Furthermore, the displacements at ultimate load gained in the 3D analysis were comparable to those of experiments. The difference of experiment-to-2D (du,exp - du,2D / du,exp) and experiment-to-3D (du,exp - du,3D / du,exp) midspan displacement had a mean of 19.91 and 10.89, respectively.","PeriodicalId":287674,"journal":{"name":"Journal of Applied Materials and Technology","volume":"49 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124164069","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Y. Azis, C. D. Alfarisi, K. Komalasari, K. Khairat, Y. Sahan
Hydroxyapatite (HAp, Ca10(PO4)6(OH)2) is the most stable form of calcium phosphate and widely used in various medical applications, mainly in orthopedics and dentistry due to its close similarities with the inorganic mineral component of bone and teeth. This study aims to synthesize hydroxyapatite from duck eggshell using the precipitation method. The duck eggshell was calcined, hydrated (slaking) and underwent carbonation to form Precipitated Calcium Carbonate (PCC). Afterwards, (NH4)2HPO4 was added to produce HAp by varying the molar ratio of Ca/P by 1.67, 1.77 and 1.87 and stirring speed by 200, 250, 300rpm under basic condition (pH 10 – 11). The best results were obtained at a molar ratio of 1.77 with 200rpm stirring speed. Furthermore, the X-ray Diffraction (XRD) analysis showed that its crystals were hexagonal with sizes of 23.062nm, in the absence of other crystalline phases. Therefore, the hydroxyapatite was obtained in the agglomerates form with a specific surface area of ??55.929m2/g.
{"title":"Synthesis and Characterization of Hydroxyapatite from Duck Eggshell by Wet Precipitation Process","authors":"Y. Azis, C. D. Alfarisi, K. Komalasari, K. Khairat, Y. Sahan","doi":"10.31258/jamt.3.1.8-11","DOIUrl":"https://doi.org/10.31258/jamt.3.1.8-11","url":null,"abstract":"Hydroxyapatite (HAp, Ca10(PO4)6(OH)2) is the most stable form of calcium phosphate and widely used in various medical applications, mainly in orthopedics and dentistry due to its close similarities with the inorganic mineral component of bone and teeth. This study aims to synthesize hydroxyapatite from duck eggshell using the precipitation method. The duck eggshell was calcined, hydrated (slaking) and underwent carbonation to form Precipitated Calcium Carbonate (PCC). Afterwards, (NH4)2HPO4 was added to produce HAp by varying the molar ratio of Ca/P by 1.67, 1.77 and 1.87 and stirring speed by 200, 250, 300rpm under basic condition (pH 10 – 11). The best results were obtained at a molar ratio of 1.77 with 200rpm stirring speed. Furthermore, the X-ray Diffraction (XRD) analysis showed that its crystals were hexagonal with sizes of 23.062nm, in the absence of other crystalline phases. Therefore, the hydroxyapatite was obtained in the agglomerates form with a specific surface area of ??55.929m2/g.","PeriodicalId":287674,"journal":{"name":"Journal of Applied Materials and Technology","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125784833","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
J. C. Izidoro, D. Fungaro, L. Viviani, Rogério Cesar de Lara da Silva
Brine sludge (BS) is an industrial waste generated in large amounts by the Chlor-alkali industry and, usually disposed into industrial landfills. Because BS contains several chemical compounds, also presents a potential environmental impact. The feasibility of the utilization of brine sludge wastes for the preparation of value-added materials was investigated. The characterization of two brine sludge samples was performed in terms of chemical and physical composition, particle size distribution, X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), and thermal analysis (DTA/TG). Elements like Ca, Si, Na, Mg, Al, Cl, and Fe were identified in the samples. The XRD results confirmed the crystalline nature of compounds and indicated that the main compounds in brine sludge samples were calcium carbonate, sodium chloride, magnesium hydroxide, and quartz. FTIR showed the presence of varying functional groups like carbonate, siloxane, and hydroxide. The two brine sludge samples can be considered as a fine powder with the mean diameter (d50) of 4.984 µm and 24.574 µm, for the BS from Santo André and Cubatão, respectively. The results indicated that the brine sludge samples presented favorable characteristics to use limestone filler and binder alternative to Portland cement in the nonstructural construction materials. The incorporation of brine sludge in geopolymeric materials is another possible use in sustainable construction material products. The production of value-added products from brine sludge will be an important contribution towards sustainable development adopted by the Chlor-alkali industry.
{"title":"Brine sludge waste from a Chlor-alkali industry: characterization and its application for non-structural and structural construction materials","authors":"J. C. Izidoro, D. Fungaro, L. Viviani, Rogério Cesar de Lara da Silva","doi":"10.31258/jamt.3.1.1-7","DOIUrl":"https://doi.org/10.31258/jamt.3.1.1-7","url":null,"abstract":"Brine sludge (BS) is an industrial waste generated in large amounts by the Chlor-alkali industry and, usually disposed into industrial landfills. Because BS contains several chemical compounds, also presents a potential environmental impact. The feasibility of the utilization of brine sludge wastes for the preparation of value-added materials was investigated. The characterization of two brine sludge samples was performed in terms of chemical and physical composition, particle size distribution, X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), and thermal analysis (DTA/TG). Elements like Ca, Si, Na, Mg, Al, Cl, and Fe were identified in the samples. The XRD results confirmed the crystalline nature of compounds and indicated that the main compounds in brine sludge samples were calcium carbonate, sodium chloride, magnesium hydroxide, and quartz. FTIR showed the presence of varying functional groups like carbonate, siloxane, and hydroxide. The two brine sludge samples can be considered as a fine powder with the mean diameter (d50) of 4.984 µm and 24.574 µm, for the BS from Santo André and Cubatão, respectively. The results indicated that the brine sludge samples presented favorable characteristics to use limestone filler and binder alternative to Portland cement in the nonstructural construction materials. The incorporation of brine sludge in geopolymeric materials is another possible use in sustainable construction material products. The production of value-added products from brine sludge will be an important contribution towards sustainable development adopted by the Chlor-alkali industry.","PeriodicalId":287674,"journal":{"name":"Journal of Applied Materials and Technology","volume":"91 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131780348","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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