首页 > 最新文献

Laser Chemistry最新文献

英文 中文
Three-dimensional residue-free volume removal inside sapphire by high-temperature etching after irradiation of femtosecond laser Pulses 飞秒激光脉冲辐照后蓝宝石内部高温蚀刻三维无残留体积去除
Pub Date : 2008-09-30 DOI: 10.1155/2008/892721
S. Matsuo, Kensuke Tokumi, T. Tomita, S. Hashimoto
We applied the femtosecond laser-assisted etching technique, that is, irradiation of focused femtosecond laser pulses followed by selective chemical etching, to volume removal inside sapphire. At room temperature, volume etching only slightly advanced while residue remained inside the volume. By increasing the etching temperature, complete volume etching without residue was achieved. Complete etching was, however, accompanied by undesirable phenomena of surface pits or cracks, which are expected to be excluded through further improvement of processing.
我们将飞秒激光辅助刻蚀技术应用于蓝宝石内部的体积去除,即聚焦飞秒激光脉冲辐照后进行选择性化学刻蚀。在室温下,体积蚀刻仅略微推进,而残留在体积内。通过提高刻蚀温度,可以实现无残留的完整体积刻蚀。但在蚀刻完成后,会出现表面凹坑或裂纹等不良现象,希望通过进一步改进工艺加以消除。
{"title":"Three-dimensional residue-free volume removal inside sapphire by high-temperature etching after irradiation of femtosecond laser Pulses","authors":"S. Matsuo, Kensuke Tokumi, T. Tomita, S. Hashimoto","doi":"10.1155/2008/892721","DOIUrl":"https://doi.org/10.1155/2008/892721","url":null,"abstract":"We applied the femtosecond laser-assisted etching technique, that is, irradiation of focused femtosecond \u0000laser pulses followed by selective chemical etching, to volume removal inside sapphire. \u0000At room temperature, volume etching only slightly advanced while residue remained inside the \u0000volume. By increasing the etching temperature, complete volume etching without residue was \u0000achieved. Complete etching was, however, accompanied by undesirable phenomena of surface pits \u0000or cracks, which are expected to be excluded through further improvement of processing.","PeriodicalId":296295,"journal":{"name":"Laser Chemistry","volume":"22 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2008-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114032237","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 12
Ultrafast Four-Wave Optical Parametric Amplification in Transparent Condensed Bulk Media 透明凝聚体介质中的超快四波光参量放大
Pub Date : 2008-09-21 DOI: 10.1155/2008/534951
A. Dubietis, G. Tamosauskas, G. Valiulis, A. Piskarskas
We present a short overview of recent advances in ultrashort pulse four-wave optical parametric amplification in transparent condensed bulk media with Kerr nonlinearity. Highly efficient (10% to 15% pump-to-signal energy conversion) four-wave optical parametric amplification in water and fused silica is experimentally demonstrated. The amplification process highly benefits from 1-dimensional spatial soliton propagation regime, which sets in under proper combination of cylindrical beam focusing and noncollinear phase matching geometry with millijoule pumping. Under these operating conditions, strong four-wave coupling quenches catastrophic beam break-up and filamentation, and the setup operates reasonably below the damage threshold of the nonlinear medium. The proposed methodology offers a number of advantages as compared to guided-wave configurations in gaseous media.
本文简要介绍了具有克尔非线性的透明凝聚体介质中超短脉冲四波参量放大的最新进展。高效(10%至15%的泵-信号能量转换)四波光参量放大在水和熔融石英实验证明。放大过程得益于一维空间孤子传播机制,该机制是在圆柱束聚焦和非共线相位匹配几何结构与毫焦耳泵浦的适当结合下实现的。在这些工作条件下,强四波耦合抑制了灾难性的光束破裂和丝化,并且装置在非线性介质的损伤阈值以下合理地运行。与气体介质中的导波结构相比,所提出的方法具有许多优点。
{"title":"Ultrafast Four-Wave Optical Parametric Amplification in Transparent Condensed Bulk Media","authors":"A. Dubietis, G. Tamosauskas, G. Valiulis, A. Piskarskas","doi":"10.1155/2008/534951","DOIUrl":"https://doi.org/10.1155/2008/534951","url":null,"abstract":"We present a short overview of recent advances in ultrashort pulse four-wave optical parametric \u0000amplification in transparent condensed bulk media with Kerr nonlinearity. Highly efficient (10% to 15% pump-to-signal energy conversion) four-wave optical parametric amplification in water and fused silica is experimentally demonstrated. The amplification process highly benefits from 1-dimensional spatial soliton propagation regime, which sets in under proper combination of cylindrical beam focusing and noncollinear phase matching geometry with millijoule pumping. Under these operating conditions, strong four-wave coupling quenches catastrophic beam break-up and filamentation, and the setup operates reasonably below the damage threshold of the nonlinear medium. The proposed methodology offers a number of advantages as compared to guided-wave configurations in gaseous media.","PeriodicalId":296295,"journal":{"name":"Laser Chemistry","volume":"28 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2008-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116450859","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Induced Bragg Gratings in Optical Fibers and Waveguides Using an Ultrafast Infrared Laser and a Phase Mask 利用超快红外激光器和相位掩模在光纤和波导中诱导布拉格光栅
Pub Date : 2008-09-21 DOI: 10.1155/2008/416251
S. Mihailov, D. Grobnic, C. Smelser, P. Lu, R. Walker, H. Ding
Since its development in 2003, the technique of Bragg grating inscription in optical fibers and waveguides with ultrafast infrared radiation and a phase mask has proven to be as simple as the standard UV-laser grating writing techniques but far more versatile. The ultrafast IR laser-based process allows for the creation of grating structures in glassy and crystalline materials that are not typically UV photosensitive. In this article, we will review the studies that have been performed at the Communications Research Centre Canada on the grating formation processes as well as applications of the ultrafast laser technique to fabricate gratings in various optical fibers and waveguides.
自2003年发展以来,利用超快红外辐射和相位掩模在光纤和波导中刻字的布拉格光栅技术已被证明与标准紫外激光光栅刻字技术一样简单,但用途更加广泛。基于超快红外激光的工艺允许在玻璃和晶体材料中创建光栅结构,而这些材料通常不具有紫外线光敏性。在本文中,我们将回顾加拿大通信研究中心在光栅形成过程以及超快激光技术在各种光纤和波导中制造光栅的应用方面所进行的研究。
{"title":"Induced Bragg Gratings in Optical Fibers and Waveguides Using an Ultrafast Infrared Laser and a Phase Mask","authors":"S. Mihailov, D. Grobnic, C. Smelser, P. Lu, R. Walker, H. Ding","doi":"10.1155/2008/416251","DOIUrl":"https://doi.org/10.1155/2008/416251","url":null,"abstract":"Since its development in 2003, the technique of Bragg grating inscription in optical fibers and waveguides with ultrafast infrared radiation and a phase mask has proven to be as simple as the standard UV-laser grating writing techniques but far more versatile. The ultrafast IR laser-based process allows for the creation of grating structures in glassy and crystalline materials that are not typically UV photosensitive. In this article, we will review the studies that have been performed at the Communications Research Centre Canada on the grating formation processes as well as applications of the ultrafast laser technique to fabricate gratings in various optical fibers and waveguides.","PeriodicalId":296295,"journal":{"name":"Laser Chemistry","volume":"36 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2008-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132178524","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 41
Laser-Induced Photon-Branched Chain Reactionin a Chemically-Active Gas-Dispersed Medium 化学活性气体分散介质中激光诱导的光子支链反应
Pub Date : 2008-03-08 DOI: 10.1155/2008/839873
R. Letfullin, T. George, G. Duree
A promising avenue in the development of high-energy pulsed chemical HF/DF lasers and amplifiers is the utilization of a photon-branched chain reaction initiated in a two-phase active medium, that is, a medium containing a laser working gas and ultradispersed passivated metal particles. These particles are evaporated under the action of IR laser radiation which results in the appearance of free atoms, their diffusion into the gas, and the development of a photon-branching chain process, which involves photons as both reactants and products. The key obstacle here is the formation of a relatively large volume (in excess of 10 3 cm 3 ) of the stable active medium and filling this volume homogeneously for a short time with a submicron monodisperse metal aerosol, which has specified properties. In this paper, results are presented for an extensive study of laser initiation of a photon-branched chain reaction in a gas-dispersed H 2 – F 2 medium.
利用两相活性介质(即含有激光工作气体和超分散钝化金属粒子的介质)中引发的光子支链反应,是开发高能脉冲化学HF/DF激光器和放大器的一个有前途的途径。这些粒子在红外激光辐射的作用下蒸发,导致自由原子的出现,它们扩散到气体中,并形成光子分支链过程,其中光子既是反应物又是生成物。这里的主要障碍是形成相对较大体积(超过103cm 3)的稳定活性介质,并在短时间内均匀地填充具有特定特性的亚微米单分散金属气溶胶。本文介绍了在气体分散的h2 - f2介质中激光引发光子支链反应的广泛研究结果。
{"title":"Laser-Induced Photon-Branched Chain Reactionin a Chemically-Active Gas-Dispersed Medium","authors":"R. Letfullin, T. George, G. Duree","doi":"10.1155/2008/839873","DOIUrl":"https://doi.org/10.1155/2008/839873","url":null,"abstract":"A promising avenue in the development of high-energy pulsed chemical HF/DF lasers and amplifiers is the utilization of a photon-branched chain reaction initiated in a two-phase active medium, that is, a medium containing a laser working gas and ultradispersed passivated metal particles. These particles are evaporated under the action of IR laser radiation which \u0000 results in the appearance of free atoms, their diffusion into the gas, and the development of a photon-branching chain process, which involves photons as both reactants and products. The key obstacle here is the formation of a relatively large volume (in excess of 10 3 cm 3 ) of the stable active medium and filling this \u0000 volume homogeneously for a short time with a submicron monodisperse metal aerosol, which has specified properties. In this paper, results are presented for an extensive study of laser initiation of a photon-branched chain reaction in a gas-dispersed H 2 – F 2 medium.","PeriodicalId":296295,"journal":{"name":"Laser Chemistry","volume":"47 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2008-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"133144757","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Changes in Cell Viability of Wounded Fibroblasts following Laser Irradiation in Broad-Spectrum or Infrared Light 广谱或红外光激光照射后损伤成纤维细胞活力的变化
Pub Date : 2007-12-21 DOI: 10.1155/2007/71039
D. Hawkins, H. Abrahamse
Objective. This study aimed to establish if broad-spectrum or infrared (IR) light in combination with laser therapy can assist phototherapy to improve the cell function of wounded cells. Background. The effect of laser light may be partly or completely reduced by broad-spectrum light. Methods. Wounded human skin fibroblasts were irradiated with 5 J/ cm 2 using a helium-neon laser, a diode laser, or an Nd:YAG laser in the dark, in the light, or in IR. Changes in cell viability were evaluated by cell morphology, ATP cell viability, LDH membrane integrity, and caspase 3/7 as an early marker of apoptosis. Results. Wounded cells exposed to 5 J/ cm 2 using 632.8 nm in the dark or 830 nm in the light or 1064 nm in the dark showed an increase in ATP viability, an increase in cytokine expression, and a decrease in LDH cytotoxicity indicating that the metabolic activity of the wounded cells was stimulated. Conclusion. Wounded cells irradiated in IR light showed an undesirable thermal effect that was proportional to the duration of exposure.
目标。本研究旨在确定广谱或红外(IR)光联合激光治疗是否有助于光疗改善损伤细胞的细胞功能。背景。广谱光可以部分或完全减弱激光的作用。方法。使用氦氖激光器、二极管激光器或Nd:YAG激光器在黑暗、光照或红外条件下以5 J/ cm2照射受伤的人皮肤成纤维细胞。通过细胞形态、ATP细胞活力、LDH膜完整性和caspase 3/7作为细胞凋亡的早期标志物来评估细胞活力的变化。结果。损伤细胞在632.8 nm、830 nm、1064 nm的光照条件下暴露于5 J/ cm 2的环境中,ATP活力增加,细胞因子表达增加,LDH细胞毒性降低,表明损伤细胞的代谢活性受到刺激。结论。在红外光照射下受伤的细胞显示出与暴露时间成正比的不良热效应。
{"title":"Changes in Cell Viability of Wounded Fibroblasts following Laser Irradiation in Broad-Spectrum or Infrared Light","authors":"D. Hawkins, H. Abrahamse","doi":"10.1155/2007/71039","DOIUrl":"https://doi.org/10.1155/2007/71039","url":null,"abstract":"Objective. This study aimed to establish if broad-spectrum or infrared (IR) light in combination with laser therapy can assist phototherapy to improve the cell function of wounded cells. Background. The effect of laser light may be partly or completely reduced by broad-spectrum light. Methods. Wounded human skin fibroblasts were irradiated with 5 J/ cm 2 using a helium-neon laser, a diode laser, or an Nd:YAG laser in the dark, in the light, or in IR. Changes in cell viability were evaluated by cell morphology, ATP cell viability, LDH membrane integrity, and caspase 3/7 as an early marker of apoptosis. Results. Wounded cells exposed to 5 J/ cm 2 using 632.8 nm in the dark or 830 nm in the light or 1064 nm in the dark showed an increase in ATP viability, an increase in cytokine expression, and a decrease in LDH cytotoxicity indicating that the metabolic activity of the wounded cells was stimulated. Conclusion. Wounded cells irradiated in IR light showed an undesirable thermal effect that was proportional to the duration of exposure.","PeriodicalId":296295,"journal":{"name":"Laser Chemistry","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2007-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131366720","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 18
Cellular Damage in Diabetic Wounded Fibroblast Cells following Phototherapy at 632.8, 830, and 1064 nm 632.8、830和1064 nm光疗后糖尿病损伤成纤维细胞的细胞损伤
Pub Date : 2007-12-05 DOI: 10.1155/2007/80536
N. Houreld, H. Abrahamse
Objective. This study aimed to establish if laser irradiation induces cellular and genetic damage. Background. Phototherapy has been shown to induce wound healing in diabetic wounds, however little information is known regarding light-induced damage. Methods. Diabetic wounded fibroblasts were irradiated with 5 or 16 J/cm2 at 632.8, 830, and 1064 nm. Damage was assessed by measuring membrane and DNA damages. Cellular migration was determined by microscopy. Results. Cells irradiated with 5 J/cm2 at 632.8 and 830 nm showed a significant decrease in DNA damage while all cells irradiated with a fluence of 16 J/cm2 showed an increase in membrane and DNA damages. Conclusion. This study showed that the comet assay and LDH release were sensitive enough to pick up changes in laser-irradiated cells. This study also showed that cellular and genetic damage inflicted on diabetic wounded cells was dependent on dose and wavelength and that cells are able to recover and respond.
目标。本研究旨在确定激光照射是否会引起细胞和基因损伤。背景。光疗已被证明可诱导糖尿病伤口愈合,但关于光致损伤的信息知之甚少。方法。分别在632.8、830和1064 nm照射5或16 J/cm2的糖尿病损伤成纤维细胞。通过测量膜损伤和DNA损伤来评估损伤程度。显微镜下观察细胞迁移。结果。以5j /cm2辐照632.8和830 nm的细胞,DNA损伤显著减少,而以16j /cm2辐照的细胞,膜和DNA损伤均增加。结论。该研究表明,彗星试验和LDH释放足够敏感,可以捕捉到激光照射细胞的变化。该研究还表明,对糖尿病损伤细胞造成的细胞和遗传损伤依赖于剂量和波长,细胞能够恢复和应答。
{"title":"Cellular Damage in Diabetic Wounded Fibroblast Cells following Phototherapy at 632.8, 830, and 1064 nm","authors":"N. Houreld, H. Abrahamse","doi":"10.1155/2007/80536","DOIUrl":"https://doi.org/10.1155/2007/80536","url":null,"abstract":"Objective. This study aimed to establish if laser irradiation induces cellular and genetic damage. Background. Phototherapy has been shown to induce wound healing in diabetic wounds, however little information is known regarding light-induced damage. Methods. Diabetic wounded fibroblasts were irradiated with 5 or 16 J/cm2 at 632.8, 830, and 1064 nm. Damage was assessed by measuring membrane and DNA damages. Cellular migration was determined by microscopy. Results. Cells irradiated with 5 J/cm2 at 632.8 and 830 nm showed a significant decrease in DNA damage while all cells irradiated with a fluence of 16 J/cm2 showed an increase in membrane and DNA damages. Conclusion. This study showed that the comet assay and LDH release were sensitive enough to pick up changes in laser-irradiated cells. This study also showed that cellular and genetic damage inflicted on diabetic wounded cells was dependent on dose and wavelength and that cells are able to recover and respond.","PeriodicalId":296295,"journal":{"name":"Laser Chemistry","volume":"108 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2007-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131108774","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
Photostability of Uranine via Crossed-Beam Thermal Lens Technique 交叉光束热透镜技术研究铀的光稳定性
Pub Date : 2007-02-27 DOI: 10.1063/1.2711116
M. Z. el-din, K. Elsayed, M. Harith
Uranine is a diagnostic aid in ophthalmology and used as immuno‐histological stain. Photostability study on such important compound using crossed‐beam thermal lens (TL) technique was carried out. The study is based on the photodegradation (PD) behavior and rate regarding some parameters such as the incident laser power, wavelength, modulation frequency and sample concentration. The effects of such parameters on the TL signal and PD rate are discussed in details. The rate of PD is found to be proportional to the power of the pumping laser and concentration of the sample within the investigated range. The modulation frequency is found not to influence the PD rate. The photochemical quantum yield has been measured using potassium ferrioxalate actinometry and it was found to be very low.
在眼科中,铀是一种诊断试剂,可用作免疫组织学染色剂。利用交叉光束热透镜(TL)技术对这一重要化合物进行了光稳定性研究。该研究基于入射激光功率、波长、调制频率和样品浓度等参数对光降解(PD)行为和速率的影响。详细讨论了这些参数对TL信号和PD率的影响。PD的速率与抽运激光的功率和在所研究范围内样品的浓度成正比。发现调制频率不影响PD率。用草酸铁钾光光度法测定了光化学量子产率,发现它很低。
{"title":"Photostability of Uranine via Crossed-Beam Thermal Lens Technique","authors":"M. Z. el-din, K. Elsayed, M. Harith","doi":"10.1063/1.2711116","DOIUrl":"https://doi.org/10.1063/1.2711116","url":null,"abstract":"Uranine is a diagnostic aid in ophthalmology and used as immuno‐histological stain. Photostability study on such important compound using crossed‐beam thermal lens (TL) technique was carried out. The study is based on the photodegradation (PD) behavior and rate regarding some parameters such as the incident laser power, wavelength, modulation frequency and sample concentration. The effects of such parameters on the TL signal and PD rate are discussed in details. The rate of PD is found to be proportional to the power of the pumping laser and concentration of the sample within the investigated range. The modulation frequency is found not to influence the PD rate. The photochemical quantum yield has been measured using potassium ferrioxalate actinometry and it was found to be very low.","PeriodicalId":296295,"journal":{"name":"Laser Chemistry","volume":"104 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2007-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123147763","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Assisted Interpretation of Laser-Induced Fluorescence Spectra of Egg-Based Binding Media Using Total Emission Fluorescence Spectroscopy 全发射荧光光谱法辅助解释蛋基结合介质激光诱导荧光光谱
Pub Date : 2006-12-28 DOI: 10.1155/2006/82823
Austin Nevin, D. Anglos
Laser-induced fluorescence (LIF) spectroscopy can provide nondestructive, qualitative analysis of protein-based binding media found in artworks. Fluorescence emissions from proteins in egg yolk and egg white are due to autofluorescent aromatic amino acids as well as other native and age-related fluorophores, but the potential of fluorescence spectroscopy for the differentiation between binding media is dependent on the choice of a suitable excitation wavelength and limited by problems in interpretation. However, a better understanding of emission spectra associated with LIF can be achieved following comparisons with total emission fluorescence spectra where a series of consecutive emission spectra are recorded over a specific range. Results using nanosecond UV laser sources for LIF of egg-based binding media are presented which are rationalised following comparisons with total emission spectra. Specifically, fluorescence is assigned to tryptophan and oxidation products of amino acids; in the case of egg yolk, fatty-acid polymerisation and age-related degradation products account for the formation of fluorophores.
激光诱导荧光(LIF)光谱可以对艺术品中发现的基于蛋白质的结合介质进行无损的定性分析。蛋黄和蛋清中蛋白质的荧光发射是由于自身荧光的芳香氨基酸以及其他天然和年龄相关的荧光团,但荧光光谱区分结合介质的潜力取决于合适的激发波长的选择,并受到解释问题的限制。然而,在与总发射荧光光谱进行比较后,可以更好地了解与LIF相关的发射光谱,其中在特定范围内记录了一系列连续的发射光谱。通过与总发射光谱的比较,给出了用纳秒级紫外激光源对蛋基结合介质进行LIF的结果。具体来说,荧光被分配到色氨酸和氨基酸的氧化产物;就蛋黄而言,脂肪酸聚合和与年龄有关的降解产物是荧光团形成的原因。
{"title":"Assisted Interpretation of Laser-Induced Fluorescence Spectra of Egg-Based Binding Media Using Total Emission Fluorescence Spectroscopy","authors":"Austin Nevin, D. Anglos","doi":"10.1155/2006/82823","DOIUrl":"https://doi.org/10.1155/2006/82823","url":null,"abstract":"Laser-induced fluorescence (LIF) spectroscopy can provide nondestructive, qualitative analysis of protein-based binding media found in artworks. Fluorescence emissions from proteins in egg yolk and egg white are due to autofluorescent aromatic amino acids as well as other native and age-related fluorophores, but the potential of fluorescence spectroscopy for the differentiation between binding media is dependent on the choice of a suitable excitation wavelength and limited by problems in interpretation. However, a better understanding of emission spectra associated with LIF can be achieved following comparisons with total emission fluorescence spectra where a series of consecutive emission spectra are recorded over a specific range. Results using nanosecond UV laser sources for LIF of egg-based binding media are presented which are rationalised following comparisons with total emission spectra. Specifically, fluorescence is assigned to tryptophan and oxidation products of amino acids; in the case of egg yolk, fatty-acid polymerisation and age-related degradation products account for the formation of fluorophores.","PeriodicalId":296295,"journal":{"name":"Laser Chemistry","volume":"96 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2006-12-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130968524","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 21
Characterization of Laser-Generated Microparticles by Means of a Dust Monitor and SEM Imaging 用粉尘监测仪和扫描电镜成像表征激光产生的微粒
Pub Date : 2006-12-27 DOI: 10.1155/2006/31862
R. Wurster, S. Pentzien, A. Conradi, J. Krüger
Nanosecond laser (1064 nm wavelength) cleaning of artificially soiled paper as a model sample simulating a real-world artwork was performed. During the cleaning process, the ejection of particles was monitored in situ by means of a dust monitor (8 size classes, ranging from 0.3 μ m to > 2 μ m) and ex situ using a mini-cascade impactor (MKI, 5 stages). The cleaning result was analyzed by scanning electron microscopy (SEM) considering possible laser-induced damages to the substrate. Size distributions of emitted particles were measured depending on the processing parameters: laser fluence, F , and pulse number per spot, N . High numbers of large ( > 2 μ m) particles were collected by the mini-cascade impactor indicating a gas dynamical liftoff process. Obviously, these particles were not affected by the laser-matter interaction. The different methods (SEM, MKI, and dust monitor) are compared with respect to their usefulness for a proper interpretation of the cleaning results.
采用纳秒激光(波长1064nm)对模拟真实艺术品的人工污纸进行清洗。在清洗过程中,通过粉尘监测器(8个尺寸等级,范围从0.3 μ m到bbb20 μ m)原位监测颗粒的喷射,并使用微型级联冲击器(MKI, 5级)进行非原位监测。考虑到激光对基体可能造成的损伤,用扫描电镜对清洗结果进行了分析。发射粒子的尺寸分布根据加工参数进行测量:激光通量,F,和每点脉冲数,N。小型串级撞击器收集了大量的大颗粒(bbb20 μ m),表明这是一个气体动力升空过程。显然,这些粒子不受激光与物质相互作用的影响。不同的方法(SEM, MKI,和粉尘监测器)进行比较,就他们的有用性,以正确解释清洁结果。
{"title":"Characterization of Laser-Generated Microparticles by Means of a Dust Monitor and SEM Imaging","authors":"R. Wurster, S. Pentzien, A. Conradi, J. Krüger","doi":"10.1155/2006/31862","DOIUrl":"https://doi.org/10.1155/2006/31862","url":null,"abstract":"Nanosecond laser (1064 nm wavelength) cleaning of artificially soiled paper as a model sample simulating a real-world artwork was performed. During the cleaning process, the ejection of particles was monitored in situ by means of a dust monitor (8 size classes, ranging from 0.3 μ m to > 2 μ m) and ex situ using a mini-cascade impactor (MKI, 5 stages). The cleaning \u0000result was analyzed by scanning electron microscopy (SEM) considering possible laser-induced damages to the substrate. Size distributions of emitted particles were measured depending on the processing parameters: laser fluence, F , and pulse number per spot, N . High numbers of large ( > 2 μ m) particles were collected by the mini-cascade impactor indicating \u0000a gas dynamical liftoff process. Obviously, these particles were not affected by the laser-matter interaction. The different methods (SEM, MKI, and dust monitor) are compared with respect to their usefulness for a proper interpretation of the cleaning results.","PeriodicalId":296295,"journal":{"name":"Laser Chemistry","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2006-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116290282","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Laser Cleaning Tests on Archaeological Copper Alloys Using an ND:YAG Laser ND:YAG激光对考古铜合金的激光清洗试验
Pub Date : 2006-12-26 DOI: 10.1155/2006/75831
C. Korenberg, A. Baldwin
Laser cleaning tests were performed on five archaeological copper alloy objects using a Q-switched Nd:YAG laser at 1064 nm. As a comparison, a section of each object was cleaned mechanically. Prior to cleaning, cross-sections were prepared to characterise the corrosion crust and help to locate the position of the original surface. Laser cleaning was not successful at removing burial deposits on two of the objects. For the other three objects, the laser removed most of the corrosion crust. This was not always satisfactory, as cleaning was sometimes accompanied by the loss of the original surface. In addition, laser-cleaned surfaces were matt compared to mechanically cleaned surfaces. In some instances, the former had a disfiguring purple hue which was attributed to the formation of particles that could be seen when examining the surface using scanning electron microscopy. For all the objects examined here, superior results were obtained by mechanical cleaning.
采用1064 nm调q Nd:YAG激光对5件考古铜合金文物进行了激光清洗试验。作为比较,每个物体的一部分被机械清洗。在清洗之前,准备了截面来表征腐蚀外壳,并帮助定位原始表面的位置。激光清洗未能成功清除其中两件物品上的埋藏沉积物。对于另外三个物体,激光去除了大部分腐蚀外壳。这并不总是令人满意的,因为清洗有时伴随着原始表面的损失。此外,与机械清洗的表面相比,激光清洗的表面是哑光的。在某些情况下,前者有一种难看的紫色色调,这是由于在使用扫描电子显微镜检查表面时可以看到颗粒的形成。对于这里检查的所有物体,通过机械清洗获得了更好的结果。
{"title":"Laser Cleaning Tests on Archaeological Copper Alloys Using an ND:YAG Laser","authors":"C. Korenberg, A. Baldwin","doi":"10.1155/2006/75831","DOIUrl":"https://doi.org/10.1155/2006/75831","url":null,"abstract":"Laser cleaning tests were performed on five archaeological copper alloy objects using a Q-switched Nd:YAG laser at 1064 nm. As a comparison, a section of each object was cleaned mechanically. Prior to cleaning, cross-sections were prepared to characterise the corrosion crust and help to locate the position of the original surface. Laser cleaning was not successful at removing burial deposits on two of the objects. For the other three objects, the laser removed most of the corrosion crust. This was not always satisfactory, as cleaning was sometimes accompanied by the loss of the original surface. In addition, laser-cleaned surfaces were matt compared to mechanically cleaned surfaces. In some instances, the former had a disfiguring purple hue which was attributed to the formation of particles that could be seen when examining the surface using scanning electron microscopy. For all the objects examined here, superior results were obtained by mechanical cleaning.","PeriodicalId":296295,"journal":{"name":"Laser Chemistry","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2006-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131385819","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 15
期刊
Laser Chemistry
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1