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Methane Aromatization in a Fluidized Bed Reactor: Parametric Study 流化床反应器中甲烷芳构化的参数研究
IF 3.2 Q4 ENERGY & FUELS Pub Date : 2019-02-14 DOI: 10.3389/fenrg.2019.00008
J. Lasobras, J. Soler, J. Herguido, M. Menéndez, A. Jimenez, Mariana da Silva, M. J. Franco, I. Barrio, J. Lázaro
Methane aromatization is a promising technology for the transformation of natural gas to liquid products, but suffers the problem of catalyst deactivation by coke. A Two-zone fluidized bed reactor has been proposed as a tool to counteract the catalyst deactivation, by providing continuous catalyst regeneration in the same vessel where the main reaction is carried out. This work shows the effect of the main operating conditions (carburization temperature, reaction temperature, carburization time, nature of regenerating agent and feed flow and height of the hydrocarbon entry point) .
甲烷芳构化是将天然气转化为液体产品的一种很有前途的技术,但存在催化剂被焦炭失活的问题。双区流化床反应器已被提议作为一种工具,通过在进行主反应的同一容器中提供连续的催化剂再生来抵消催化剂失活。这项工作显示了主要操作条件(渗碳温度、反应温度、渗碳时间、再生剂的性质、进料流量和碳氢化合物进入点的高度)的影响。
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引用次数: 3
Novel Conceptual Architecture for the Next-Generation Electricity Markets to Enhance a Large Penetration of Renewable Energy 新一代电力市场的新概念架构以促进可再生能源的大规模渗透
IF 3.2 Q4 ENERGY & FUELS Pub Date : 2019-01-07 DOI: 10.3390/EN12132605
J. Rodríguez-García, D. Ribó-Pérez, C. Alvarez, E. Peñalvo-López
A transition to a sustainable energy system is essential. In this context, smart grids represent the future of power systems for efficiently integrating renewable energy sources and active consumer participation. Recently, different studies were performed that defined the conceptual architecture of power systems and their agents. However, these conceptual architectures do not overcome all issues for the development of new electricity markets. Thus, a novel conceptual architecture is proposed. The transactions of energy, operation services, and economic flows among the agents proposed are carefully analysed. In this regard, the results allow setting their activities’ boundaries and state their relationships with electricity markets. The suitability of implementing local electricity markets is studied to enforce competition among distributed energy resources by unlocking all the potential that active consumers have. The proposed architecture is designed to offer flexibility and efficiency to the system thanks to a clearly defined way for the exploitation of flexible resources and distributed generation. This upgraded architecture hereby proposed establishes the characteristics of each agent in the forthcoming markets and studies to overcome the barriers to the large deployment of renewable energy sources.
向可持续能源系统过渡至关重要。在这种背景下,智能电网代表了电力系统的未来,用于有效整合可再生能源和积极的消费者参与。最近,对电力系统及其代理的概念架构进行了不同的研究。然而,这些概念架构并不能解决新电力市场发展的所有问题。因此,提出了一种新颖的概念建筑。仔细分析了拟议代理人之间的能源交易、运营服务和经济流动。在这方面,研究结果允许设定他们的活动边界,并说明他们与电力市场的关系。研究了实施地方电力市场的适宜性,以通过释放活跃消费者的所有潜力来加强分布式能源之间的竞争。所提出的体系结构旨在为系统提供灵活性和效率,这要归功于灵活资源的开发和分布式发电的明确定义方式。在此提出的升级架构确立了即将到来的市场和研究中每个代理的特征,以克服可再生能源大规模部署的障碍。
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引用次数: 33
Characterization of Narrowband Noise and Channel Capacity for Powerline Communication in France 法国电力线通信窄带噪声和信道容量的特性
IF 3.2 Q4 ENERGY & FUELS Pub Date : 2018-11-02 DOI: 10.3390/EN11113022
I. Elfeki, S. Jacques, I. Aouichak, T. Doligez, Y. Raingeaud, J. L. Le Bunetel
Narrowband powerline communication (NB-PLC) systems represent a key step for the real development of smart grids’ applications in the medium voltage (MV) and low voltage (LV) networks. This article sums up the results of a complete experimental measurement campaign aimed at investigating the low voltage NB-PLC channel in the frequency range from 9 to 500 kHz in various sites (i.e., rural, urban etc.) located in France. The noise features in time-frequency representation are studied at five different sites between the transformer substation and the smart electricity meter. The main contribution of this study consists in estimating the theoretical channel capacity which constitutes a major interest for the users and actors of the electrical system. The channel capacity calculation shows reliable results in the US Federal Communications Commission (FCC) band (a few Mbits/s). The quality of the communication in the FCC band enables to integrate new smart grids’ applications and services based on the existing NB-PLC communication for advanced metering infrastructure (AMI).
窄带电力线通信(NB-PLC)系统是智能电网在中压和低压网络中应用真正发展的关键一步。本文总结了一个完整的实验测量活动的结果,旨在调查低频NB-PLC通道在频率范围从9到500千赫在不同的地点(即,农村,城市等)位于法国。研究了变电站与智能电能表之间5个不同位置的时频噪声特征。本研究的主要贡献在于估计理论信道容量,这构成了电力系统用户和参与者的主要兴趣。信道容量计算在美国联邦通信委员会(FCC)频段(几mbit /s)得到了可靠的结果。FCC频段的通信质量使得基于现有的先进计量基础设施(AMI)的NB-PLC通信集成新的智能电网应用和服务成为可能。
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引用次数: 18
Optimization of Hybrid Energy Storage Systems for Vehicles with Dynamic On-off Power Loads Using a Nested Formulation 基于嵌套公式的车辆动态开关电源混合储能系统优化
IF 3.2 Q4 ENERGY & FUELS Pub Date : 2018-10-10 DOI: 10.3390/EN11102699
Jiajun Liu, Huachao Dong, Tianxu Jin, Li Liu, Babak Manouchehrinia, Zuo-ying Dong
In this paper, identification of an appropriate hybrid energy storage system (HESS) architecture, introduction of a comprehensive and accurate HESS model, as well as HESS design optimization using a nested, dual-level optimization formulation and suitable optimization algorithms for both levels of searches have been presented. At the bottom level, design optimization focuses on the minimization of power loss in batteries, converter, and ultracapacitors (UCs), as well as the impact of battery depth of discharge (DOD) to its operation life, using a dynamic programming (DP)-based optimal energy management strategy (EMS). At the top level, HESS optimization of component size and battery DOD is carried out to achieve the minimum life-cycle cost (LCC) of the HESS for given power profiles and performance requirements as an outer loop. The complex and challenging optimization problem is solved using an advanced Multi-Start Space Reduction (MSSR) search method developed for computation-intensive, black-box global optimization problems. An example of load-haul-dump (LHD) vehicles is employed to verify the proposed HESS design optimization method and MSSR leads to superior optimization results and dramatically reduces computation time. This research forms the foundation for the design optimization of HESS, hybridization of vehicles with dynamic on-off power loads, and applications of the advanced global optimization method.
本文提出了合适的混合储能系统(HESS)体系结构的确定、全面准确的混合储能系统模型的引入,以及采用嵌套双级优化公式和适合两级搜索的优化算法对混合储能系统进行优化设计。在底层,设计优化的重点是最小化电池、转换器和超级电容器(UCs)的功率损耗,以及电池放电深度(DOD)对其使用寿命的影响,使用基于动态规划(DP)的最优能量管理策略(EMS)。在顶层,对组件尺寸和电池DOD进行HESS优化,以实现给定功率分布和性能要求的HESS的最小生命周期成本(LCC)。采用先进的多起点空间约简(MSSR)搜索方法解决了复杂而具有挑战性的优化问题,该方法是为计算密集型黑盒全局优化问题而开发的。以整车为例验证了所提出的HESS设计优化方法,结果表明,MSSR优化效果较好,大大缩短了计算时间。该研究为HESS的设计优化、动态开关功率负载车辆的混合动力以及先进的全局优化方法的应用奠定了基础。
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引用次数: 10
Development of the Theory of Chain Reactions and Analysis of Relatively Recently Studied Chain Processes 链式反应理论的发展和最近研究的链式过程分析
IF 3.2 Q4 ENERGY & FUELS Pub Date : 2018-01-20 DOI: 10.11648/J.JEECE.20170204.12
K. Mammadov
The history of the formation and development of the theory of chain reactions is briefly presented. In specific examples the mechanisms of branched chain processes, conditions inhibiting and accelerating chain reactions, criteria characterizing the chain nature of chemical processes are described. The modern state in the development of the theory of chain reactions is analyzed. The mechanisms describing regularities of formation of molecular products of the chain processes occurring in different systems with the use of different initiators at different conditions are discussed. A summary of the radical-chain character of the radiation sewing of elastomers /non stitched rubbers/ at high pressures (2 GPa) and at temperatures above 300°K is provided and the ionic character of this process at low temperatures (77°K) has been studied. Mechanisms of photolythic and radiolytic processes transformations of any organic pollutants and natural toxins in oxygen-free and oxygen-containing aqueous solutions are proposed. Significant decomposition of natural toxins is observed under influence of ionizing radiation of 60 Co source. The short description of the revealed chain processes proceeding in gaseous, liquid, amorphous and solid phases is provided. These studies are an essential contribution to researches in the field of studying of chain chemical processes.
简要介绍了链式反应理论的形成和发展的历史。在具体的例子中,描述了支链过程的机制,抑制和加速链反应的条件,表征化学过程链性质的标准。分析了链式反应理论的现代发展状况。讨论了不同体系中不同引发剂在不同条件下链式反应分子产物形成规律的机理。本文总结了弹性体/无缝橡胶/辐射缝在高压(2gpa)和300°K以上温度下的自由基链特性,并研究了低温(77°K)下辐射缝的离子特性。提出了光解和辐射解过程在无氧和含氧水溶液中转化有机污染物和天然毒素的机理。在60钴源电离辐射的影响下,观察到天然毒素的显著分解。提供了在气态、液态、非晶态和固相中所揭示的链式过程的简短描述。这些研究是对链式化学过程研究领域的重要贡献。
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引用次数: 0
Economic analysis of biomass torrefaction plants integrated with corn ethanol plants and coal-fired power plants 生物质焙烧厂与玉米乙醇厂和燃煤电厂相结合的经济分析
IF 3.2 Q4 ENERGY & FUELS Pub Date : 2013-06-01 DOI: 10.12989/ERI.2013.1.2.127
D. Tiffany, Won Fy Lee, V. Morey, N. Kaliyan
Torrefaction technologies convert assorted biomass feedstocks into energy- concentrated, carbon neutral fuel that is economically transported and easily ground for blending with fossil coals at numerous power plants around the world without needs to retrofit. Utilization of torrefied biomass in conventional electric generating units may be an increasingly attractive alternative for electricity generation as aging power plants in the world need to be upgraded or improved. This paper examines the economic feasibility of torrefaction in different scenarios by modeling torrefaction plants producing 136,078 t/year (150,000 ton/year) biocoal from wood and corn stover. The utilization of biocoal blends in existing coal-fired power plants is modeled to determine the demand for this fuel in the context of emerging policies regulating emissions from coal in the U.S. setting. Opportunities to co-locate torrefaction facilities adjacent to corn ethanol plants and coal-fired power plants are explored as means to improve economics for collaborating businesses. Life cycle analysis was conducted in parallel to this economic study and was used to determine environmental impacts of converting biomass to biocoal for blending in coal-fired power plants as well as the use of substantial flows of off-gasses produced in the torrefaction process. Sensitivity analysis of the financial rates of return of the different businesses has been performed to measure impacts of different factors, whether input prices, output prices, or policy measures that render costs or rewards for the businesses.
焙烧技术将各种生物质原料转化为能量集中的碳中性燃料,这种燃料运输经济,易于研磨,可以在世界各地的许多发电厂与化石煤混合,而无需改造。由于世界上老化的发电厂需要升级或改进,在常规发电机组中利用碳化生物质可能是一种越来越有吸引力的发电替代方案。本文通过模拟从木材和玉米秸秆中生产136,078吨/年(150,000吨/年)生物煤的焙烧工厂,考察了不同情景下焙烧的经济可行性。对现有燃煤电厂中生物煤混合物的利用进行了建模,以确定在美国监管煤炭排放的新政策背景下对这种燃料的需求。探索在玉米乙醇厂和燃煤电厂附近共同选址炼油设施的机会,作为提高合作企业经济效益的手段。生命周期分析与这项经济研究同时进行,并用于确定将生物质转化为生物煤用于燃煤发电厂的混合以及在焙烧过程中产生的大量废气的使用对环境的影响。对不同企业的财务回报率进行了敏感性分析,以衡量不同因素的影响,无论是投入价格,产出价格还是为企业提供成本或回报的政策措施。
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引用次数: 8
Optical and Morphological Properties of ZnO and TiO2 Derived Nanostructures Synthesized via a Microwave-Assisted Hydrothermal Method 微波辅助水热法合成ZnO和TiO2纳米结构的光学和形态性质
IF 3.2 Q4 ENERGY & FUELS Pub Date : 2012-02-29 DOI: 10.1155/2012/189069
N. Moloto, S. Mpelane, L. Sikhwivhilu, S. Ray
A microwave-assisted hydrothermal method was used to synthesize ZnO and TiO2 nanostructures. The experimental results show that the method resulted in crystalline monodispersed ZnO nanorods that have pointed tips with hexagonal crystal phase. TiO2 nanotubes were also formed with minimum bundles. The mechanism for the formation of the tubes was validated by HRTEM results. The optical properties of both ZnO and TiO2 nanostructures showed characteristics of strong quantum confinement regime. The photoluminescence spectrum of TiO2 nanotubes shows good improvement from previously reported data.
采用微波辅助水热法制备了ZnO和TiO2纳米结构。实验结果表明,该方法制备的ZnO纳米棒具有尖端尖的六方晶相。形成的TiO2纳米管束也最小。HRTEM结果验证了管状结构的形成机理。ZnO和TiO2纳米结构的光学性质均表现出强量子约束体系的特征。TiO2纳米管的光致发光光谱较先前报道的数据有明显改善。
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引用次数: 23
期刊
Advances in Energy Research
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