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The formation of a mechanism to improve the competitiveness of industrial enterprises in terms of import substitution 形成提高工业企业进口替代竞争力的机制
Pub Date : 2023-03-16 DOI: 10.20914/2310-1202-2022-3-460-465
L. A. Kalinnikova
Under the conditions of sanctions, many Russian industrial enterprises are faced with the acute issue of increasing competitiveness. However, its solution, unfortunately, largely goes beyond the scope of the activity of the enterprise itself, its management system, due to the increasingly complex global economic situation. Also the enterprises themselves often lack effective and efficient methods contributing to the system elaboration of the problem of competitiveness increase. It is proposed to solve the problem of increasing the competitiveness of Russian industrial enterprises in conditions of import substitution with the help of the formulated mechanism. It is a set of measures, through which the controlling system affects all the resources of the enterprise, as well as the controlled properties of the external environment. With the intention of implementing its competitive advantages.
在制裁条件下,许多俄罗斯工业企业面临着提高竞争力的严峻问题。然而,不幸的是,由于全球经济形势日益复杂,其解决方案在很大程度上超出了企业本身的活动范围,超出了其管理制度的范围。同时,企业本身往往缺乏有效和高效的方法,有助于系统地阐述竞争力提高的问题。提出了在进口替代条件下,借助所制定的机制来解决提高俄罗斯工业企业竞争力的问题。它是一套措施,通过控制系统影响企业的所有资源,以及外部环境的被控制属性。目的是实现其竞争优势。
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引用次数: 0
Modification of polyvinyl alcohol by ozonated oxidation in an aqueous solution 水溶液中臭氧氧化法改性聚乙烯醇
Pub Date : 2023-03-16 DOI: 10.20914/2310-1202-2022-4-192-199
L. N. Studenikina, A. V. Protasov, D. A. Borzenkov, A. A. Melnikov, S. Y. Domareva
Currently, the task of obtaining polyvinyl alcohol oligomers (PVA) is urgent to create functional materials of a new generation with specified properties. One of the methods of modification of PVS is ozonolysis, which has a number of advantages over other methods of oxidative degradation of polymers. The aim of the work is to evaluate the structural changes and physico–mechanical characteristics of film samples of PVS modified by ozonated oxidation. To carry out the oxidation process, a 5% aqueous solution of PVA brand 1799 was prepared. The ozone-oxygen mixture was obtained using an ozonizer of a known design. The oxidation of PVS was carried out in a glass thermostatically controlled flask at 70 ° C, blowing an ozone-oxygen mixture through an aqueous solution of PVS for 40 minutes. Sampling was carried out after 10, 20 and 40 minutes of oxidation. The films were obtained by irrigation followed by air drying, after which they were subjected to IR spectrometric analysis and strength indicators were determined. As a result of the study, it was found that the modification of PVA brand 1799 by ozonated oxidation in an aqueous medium is accompanied by the following change in IR spectrograms: in the region of 1400 - 1600 cm-1, a sharp decrease in the intensity of the peak corresponding to hydroxyl groups forming hydrogen bonds is observed for ozone-oxidized PVA, in the region of 1650 – 1700 cm-1, a pattern of decrease in intensity is noted the peak with an increase in the oxidation time of PVA with ozone, which indicates a decrease in the MM of the polymer as a result of oxidative degradation, in the region of 3400 – 3600 cm-1 marked a change in the nature of the spectrogram, which also indicates a change in the structure of hydrogen bonds in oxidized PVS; the physico-mechanical properties of film samples subjected to 40-minute ozonated oxidation of PVS change towards a decrease in both strength and elongation at break by an average of 4 times, the Young's modulus decreases by more than 3 times, and the stretching diagram changes character in the zone of highly elastic deformation (the intensity of stress growth decreases by 1.5-2 times as the film elongates during stretching) and the fracture zone (the diagram acquires a stepwise character without a sharp break), which is associated with a decrease in the molecular weight of the PVS, the acquisition of new functional groups, a change in the stereoregularity of the hydroxyl groups of the main polymer chains, an increase in amorphousness and a change in their relaxation time.
目前,制备具有特定性能的新一代功能材料迫切需要获得聚乙烯醇低聚物(PVA)。臭氧分解是改性PVS的方法之一,与其他聚合物氧化降解方法相比,臭氧分解具有许多优点。本研究的目的是评价臭氧氧化修饰的PVS薄膜样品的结构变化和物理力学特性。为了进行氧化过程,制备了5% PVA 1799的水溶液。使用已知设计的臭氧发生器获得臭氧-氧气混合物。PVS的氧化在70°C的玻璃恒温烧瓶中进行,将臭氧-氧气混合物吹过PVS水溶液40分钟。在氧化10、20和40分钟后取样。经冲洗、风干得到薄膜,对薄膜进行红外光谱分析并测定其强度指标。研究结果发现,在水介质中臭氧氧化对PVA 1799牌号进行改性后,其红外光谱图出现如下变化:在该地区1400 - 1600 cm - 1,峰的强度急剧降低相应的羟基形成氢键ozone-oxidized PVA观察到,在该地区1650 - 1700 cm - 1,强度下降的模式指出,峰值与PVA与臭氧的氧化时间的增加,这表明MM减少聚合物的氧化降解的结果,在该地区的3400 - 3600 cm - 1标志着一个谱图的性质的变化,这也表明氧化PVS中氢键结构发生了变化;经过40分钟臭氧氧化的PVS薄膜样品的物理力学性能变化为强度和断裂伸长率平均下降4倍,杨氏模量下降3倍以上;拉伸图在高弹性变形区(拉伸过程中应力增长强度随薄膜伸长而减小1.5-2倍)和断裂区(拉伸图呈现逐步变化特征,但没有急剧断裂)发生变化,这与PVS分子量的减小、新官能团的获得、主聚合物链羟基的立体规整性的改变有关。无定形性的增加和弛豫时间的改变。
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引用次数: 0
Evaluation of the mineral profile of wild plant raw materials and products of its processing for the creation of functional food products 野生植物原料及其加工产品的矿物特征评价,用于生产功能性食品
Pub Date : 2023-03-16 DOI: 10.20914/2310-1202-2022-4-103-109
K. A. Leshchukov, O. A. Kovaleva, O. S. Kireeva, T. N. Lazareva, N. N. Popovicheva
Vegetable raw materials and their processed products are a source of necessary biologically active nutrients and are widely used in food production when creating functional and specialized nutrition products. Studies of the mineral profile of wild cranberry berries (Vaccinium oxycoccos) growing in the Republic of Karelia and berry processing products (juice and cake) with different methods of processing raw materials have been carried out. Studies of the mineral composition of fresh cranberry berries and their processed products obtained by various methods showed a high content of essential macro- and microelements in fresh berries, juices and cakes and allowed us to establish the regularity of migration and distribution of micronutrients depending on the method of pre-processing of raw materials. The data obtained during the experiment allow us to judge the high mineral profile of wild cranberry berries and its processed products and the content of certain elements (in particular phosphorus and manganese) in a physiologically significant amount, which explains the prospect of using products of processing wild berry raw materials to enrich food with micronutrients. Studies of the mineral composition of edible packaging films based on concentrated cranberry juice have shown a higher mineral profile of all samples of films with the addition of juice obtained with pretreatment of berry raw materials with steam, regardless of the type of structure-forming matrix, which is due to a higher content of concentrated juice solids. It has been established that the pre-processing of berry raw materials with steam before extracting the juice, as well as its subsequent concentration, allows processing raw materials with maximum preservation of essential components with a high degree of biological activity.)
蔬菜原料及其加工产品是必需的生物活性营养素的来源,在食品生产中被广泛用于制造功能性和专业化的营养产品。对生长在卡累利阿共和国的野生蔓越莓浆果(Vaccinium oxycoccos)和浆果加工产品(果汁和蛋糕)的矿物特征进行了不同原料加工方法的研究。对各种方法获得的新鲜蔓越莓及其加工产品的矿物质组成的研究表明,新鲜浆果、果汁和蛋糕中必需的宏量元素和微量元素含量很高,这使我们能够根据原料的预处理方法确定微量元素的迁移和分布规律。实验中获得的数据使我们能够判断野生蔓越莓及其加工产品的高矿物质特征,以及某些元素(特别是磷和锰)在生理上的显著含量,这解释了利用野生蔓越莓原料加工产品丰富食品微量营养素的前景。对浓缩蔓越莓汁制成的可食用包装薄膜的矿物成分研究表明,无论结构形成基质的类型如何,加入蒸汽预处理莓类原料得到的果汁后,所有薄膜样品的矿物质特征都更高,这是由于浓缩果汁固体含量更高。已经确定,在提取果汁之前用蒸汽对浆果原料进行预处理,以及随后的浓缩,可以最大限度地保存具有高度生物活性的基本成分。
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引用次数: 0
Marketing activities on the entry stage of new product to the market 新产品进入市场阶段的市场营销活动
Pub Date : 2023-03-16 DOI: 10.20914/2310-1202-2022-3-466-471
A. S. Krasnov
The number of commercial transactions in the digital segment, as well as the number of new products on the market, is growing from year to year. The intensification of innovation observed in the market indicates a reduction in the time of the release of a new product, which increases the supply in the market. However, a wide product range does not always allow companies to get their target audience, which leads to a decrease in the efficiency of the company and a reduction in sales. The intensification of the development of new products forces the manufacturer to improve marketing activities at the output stage. The article clarifies the concept of a new product through a terminological analysis of domestic and foreign sources. For a refined definition, marketing tools were identified at the stage of bringing the product to the market and existing marketing models that describe the diffusion of innovations. An attempt was made to combine the model of E. Rogers and F. Bass with the product life cycle model, which made it possible to draw conclusions regarding marketing activities and the tools used when launching a product in relation to the target audience of a new product. The article analyzed the definition of "new product" in the context of bringing a new product to the market. For a refined definition, conclusions were drawn and made regarding the strategies for entering the market and the marketing tools used in their withdrawal. Not only the strategy and consumer orientation are determined, but also the role of the consumer in bringing a new product to the market, taking into account the E. Rogers innovation diffusion model, the F. Bass model and the product life cycle model.
数字领域的商业交易数量,以及市场上新产品的数量,每年都在增长。在市场上观察到的创新的加强表明新产品发布时间的减少,这增加了市场上的供应。然而,广泛的产品范围并不总能让公司获得他们的目标受众,这导致公司效率的降低和销售额的减少。新产品开发的加强迫使制造商在产出阶段改进营销活动。本文通过对国内外相关术语的分析,明确了新产品的概念。对于一个精炼的定义,营销工具是在将产品推向市场的阶段确定的,现有的营销模式描述了创新的扩散。尝试将E. Rogers和F. Bass的模型与产品生命周期模型相结合,从而可以得出关于营销活动和发布产品时使用的工具与新产品目标受众的关系的结论。本文在将新产品推向市场的背景下分析了“新产品”的定义。对于一个细化的定义,得出结论,并就进入市场的战略和在其退出使用的营销工具。考虑到E. Rogers的创新扩散模型、F. Bass模型和产品生命周期模型,不仅确定了战略和消费者定位,还确定了消费者在将新产品推向市场中的作用。
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引用次数: 0
Merchandising – a way to attract and retain customers 推销——一种吸引和留住顾客的方式
Pub Date : 2023-03-16 DOI: 10.20914/2310-1202-2022-3-454-459
G. V. Paramonov, L. V. Berketova
Merchandising, as one of the branches of marketing, is currently a rapidly developing field. It is noted that this term is approaching in number of formulations to the multi-valued term "quality". The authors of the article consider the concept of "merchandising" of goods. A general classification of merchandising (manufacturer and seller) is given, as well as its types (category and visual). The main techniques of merchandising include the following types: manipulating the flow of store visitors; positioning shelves; allocating limited space between competing offerings; using materials at the point of sale and installing special displays. It is noted that the consumer receives up to 80...86% of information through the most important sensory modality - vision. Due to the understanding of the importance of vision and sense of aesthetics and taste in merchandising has appeared a whole separate area - visual merchandising. This article discusses 25 types of POS materials ("Points of Sale Materials"). These include advertising wobblers, shelf talkers, hardposters, teabaggers, dorhangers, jumbies, magnetic bookmarks, nekhengers, menhoders and others. Examples are given of the use of basic merchandising principles in practice: bierdeckel - as an active advertising of the institution and drinks; the location of posters (or billboards) in front of the entrance to the public catering establishment; advertising stands in retail outlets for consumer appreciation of new foods; moulage dishes or popular products to attract consumer attention in stores, catering establishments and exhibitions; life-size figures, etc. POS materials should be aimed at performing five steps or stages of sale in terms of influencing the customer: attracting attention, arouse interest, creating desire, building confidence and direction of action. It is noted that the effective promotion of goods, works and services is possible only when the implementation of merchandising principles are approached from the positions of a systematic approach, which includes methodological work on teaching and training of specialists, merchandisers
商品营销作为市场营销的一个分支,目前是一个迅速发展的领域。值得注意的是,这个术语在许多表述上接近多值术语“质量”。本文的作者考虑了商品“商品化”的概念。给出了销售的一般分类(制造商和销售商),以及它的类型(类别和视觉)。商品推销的主要技巧包括以下几种:操纵商店访客的流量;定位货架;在竞争产品之间分配有限的空间;在销售点使用材料并安装特殊的显示器。值得注意的是,消费者收到多达80…86%的信息通过最重要的感觉方式——视觉。由于对视觉、审美和品味在商品营销中的重要性的认识,出现了一个完全独立的领域——视觉商品营销。本文讨论了25种POS材料(“销售点材料”)。这些包括广告摆动器,货架上的谈话器,硬海报,茶袋,背架,jumbies,磁性书签,nekhenger, menhoders和其他。举例说明了在实践中使用基本的销售原则:bierdeckel -作为机构和饮料的积极广告;公共餐饮场所入口处的招贴(广告牌)位置;零售店里的广告让消费者欣赏新食品;在商店、餐饮场所和展览会上宣传菜肴或流行产品,以吸引消费者的注意;真人大小的人物等。在影响顾客方面,POS材料应该针对销售的五个步骤或阶段:吸引注意力,引起兴趣,创造欲望,建立信心和行动方向。人们注意到,只有从系统的角度来执行销售原则,其中包括对专家、销售人员进行教学和培训的方法学工作,才能有效地促进商品、工作和服务
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引用次数: 0
Perspectives of computational fluid dynamics methods in the study of membrane processes 计算流体力学方法在膜过程研究中的展望
Pub Date : 2023-03-16 DOI: 10.20914/2310-1202-2022-4-32-38
A. I. Klyuchnikov, V. Y. Ovsyannikov, D. V. Klyuchnikova, A. M. Davydov
In mathematical modeling of membrane processes, the study of structural features of used membranes and the significant limitation of information in the formal description of their separation properties led to the development of physical models that take into account not only the features of structures of real membranes, but also their peculiarities of functioning. When compiling physical models of membrane processes, it is impossible to objectively quantify most of the factors due to their great diversity and variability, which distances the mathematical model from the real process. That is why methods of computational fluid dynamics reliably and efficiently perform calculations for all physical models and types, including stationary or transient flow, incompressible or compressible flow (from small subsonic to hypersonic), simulation of laminar or turbulent flows, Newtonian or non-Newtonian fluids, ideal or real gas. An electronic geometric model of the plant was built, a choice of mesh geometry with different densities was made to optimize the calculation time and solution accuracy for a particular case, the kinetic dependence of cell growth was calculated, the flow rates of feeding medium into the intra- and inter-fiber spaces of the bioreactor were determined, and the hydrodynamic conditions were analyzed.
在膜过程的数学建模中,对使用过的膜的结构特征的研究以及对其分离特性的形式化描述中信息的显著限制导致了物理模型的发展,这些模型不仅考虑了真实膜的结构特征,而且考虑了它们的功能特性。在编制膜过程物理模型时,由于其多样性和可变性,大多数因素无法客观量化,这使得数学模型与实际过程有一定距离。这就是为什么计算流体动力学方法可靠而有效地执行所有物理模型和类型的计算,包括静止或瞬态流动,不可压缩或可压缩流动(从小亚音速到高超音速),层流或湍流模拟,牛顿或非牛顿流体,理想或真实气体。建立了生物反应器的电子几何模型,针对具体情况选择了不同密度的网格几何形状以优化计算时间和求解精度,计算了细胞生长的动力学依赖性,确定了进料介质进入生物反应器纤维内和纤维间空间的流速,并分析了流体动力学条件。
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引用次数: 0
Financial literacy and consumer culture in behavioral economics as a condition for sustainable development 行为经济学中的金融素养与消费文化作为可持续发展的条件
Pub Date : 2023-03-16 DOI: 10.20914/2310-1202-2022-3-472-484
V. A. Chernov
The purpose of the work is to study the possibilities of improving financial literacy and economic culture, behavioral economics in conjunction with solving the problems of sustainable development in the economic, environmental and social spheres. The apparatus of "behavioral economics" is applied as a theoretical paradigm that takes into account "psychology" to analyze the behavior of subjects of industrial relations. In the work, the author links financial literacy, behavioral economics, economic culture with the problems of sustainable development, and also reveals the conditionality of this development by the need to increase: the culture of thinking, comprehension of moral values, the level of rational consumption. According to the research hypothesis, the solution of these problems is largely due to the quality of the content of the education and enlightenment system. Financial literacy is considered as a condition for increasing the culture of consumption. The research methodology is based on a dialectical approach, an inductive-deductive method, a descriptive analysis of the fundamentals of the behavior of economic agents: theoretical principles of rational choice (maximizing utility) and observed deviations from rational behavior (limited rationality, behavioral effects and systematic errors associated with them); consumer culture, etc. Projects to improve financial literacy in the higher education system are considered as an educational environment that should be used to form predicative thinking, increase economic culture, culture of thinking, financial literacy, consumer culture, as important components in achieving sustainable development. The author concludes that increasing the financial literacy of the population contributes to an increase in the culture of consumption, which consists in satisfying the natural needs of a person as opposed to irrational behavior and degradation-parasitic consumption, which not only lead to losses in the personal budget, but also increase the destruction of natural resources and the destruction of the biosphere. As a result, it is proposed to supplement the program of improving economic culture conducted by national institutions with the topic of improving consumer culture, to expand the content of the general cultural competencies of the Federal State Educational Institution with a more complete knowledge of dialectics, moral value orientations, and the ability of predicative thinking
这项工作的目的是研究在解决经济、环境和社会领域的可持续发展问题的同时提高金融知识和经济文化、行为经济学的可能性。将“行为经济学”作为一种考虑“心理学”的理论范式来分析劳资关系主体的行为。在工作中,作者将金融素养、行为经济学、经济文化与可持续发展的问题联系起来,并通过需要增加的思维文化、道德价值观的理解、理性消费水平揭示了这种发展的条件。根据研究假设,这些问题的解决在很大程度上取决于教育内容和启蒙体系的质量。金融素养被认为是提高消费文化的一个条件。研究方法基于辩证方法、归纳演绎方法、对经济主体行为基本原理的描述性分析:理性选择的理论原则(效用最大化)和观察到的理性行为偏差(有限理性、行为效应和与之相关的系统误差);消费文化等。高等教育系统中提高金融素养的项目被认为是一种教育环境,应该用来形成预测性思维,增加经济文化、思维文化、金融素养、消费文化,作为实现可持续发展的重要组成部分。作者的结论是,提高人口的金融素养有助于提高消费文化,这包括满足一个人的自然需求,而不是非理性行为和退化寄生消费,这不仅导致个人预算的损失,而且增加了对自然资源的破坏和对生物圈的破坏。因此,建议将改善消费文化作为国家机构开展的改善经济文化计划的补充,以更完整的辩证法知识、道德价值取向和预测思维能力来扩大联邦国家教育机构一般文化能力的内容
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引用次数: 0
Social audit as an instrument of crisis management in human resources management 社会审计在人力资源管理中作为危机管理的工具
Pub Date : 2023-03-16 DOI: 10.20914/2310-1202-2022-3-427-431
K. B. Djebbouri, A. I. Khorev
For a long time, auditing has been considered a discipline dedicated to the evaluation of financial and accounting information. Today, he has demonstrated his strengths in various areas of business, including the social component, the practice of social audit or its origin, but this discipline remains limited, despite its importance for human resource management. This article discusses social audit as an anti-crisis management tool. Modern social audit has methods that allow us to give a fairly accurate and objective description of the potential of the management body and to identify its real ability to innovate. And they allow you to have a positive impact on the risks associated with human resources management. The main purpose of this publication is to summarize a review of the literature on social auditing and its impact on human resource management risk management. The implementation of a human resource management tool, which is considered the key to socio-economic efficiency and human capital adaptation, is highlighted as a paramount task, despite the fact that most companies do not choose this practice. Based on the results of the analysis of bibliographic materials, it was found that social audit: has a positive impact on the practice of managing risks associated with human resource management; seen as an effective tool for identifying positive social and emotional indicators of improving social performance; the importance of social audit in the enterprise and its role in minimizing crises associated with personnel practices.
长期以来,审计一直被认为是一门专门评估财务和会计信息的学科。如今,他已经在各个商业领域展示了自己的优势,包括社会成分、社会审计的实践或其起源,但这一学科仍然有限,尽管它对人力资源管理很重要。本文讨论了社会审计作为一种反危机管理工具。现代社会审计的方法使我们能够相当准确和客观地描述管理机构的潜力,并确定其真正的创新能力。它们让你对与人力资源管理相关的风险产生积极的影响。本出版物的主要目的是对社会审计及其对人力资源管理风险管理的影响的文献进行综述。人力资源管理工具的实施被认为是社会经济效率和人力资本适应的关键,它被强调为一项首要任务,尽管大多数公司不选择这种做法。基于文献资料分析的结果发现,社会审计对人力资源管理相关风险管理实践具有积极影响;被视为确定改善社会表现的积极社会和情感指标的有效工具;社会审计在企业中的重要性及其在减少与人事实践相关的危机方面的作用。
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引用次数: 0
Application of drying acceleration to study the forms of moisture bond in currant fruits 应用干燥加速法研究醋栗果实水分结合形式
Pub Date : 2023-03-16 DOI: 10.20914/2310-1202-2023-1-17-23
S. T. Antipov, A. B. Emelyanov, E. V. Baturina, D. A. Kazartsev, D. S. Babenko, G. V. Posnova
The article discusses issues related to the study of the forms of connection of moisture removed during the drying process in black currant fruits. A study was carried out to determine the quantitative moisture content of various forms of communication by two methods and a comparative analysis was carried out. It is shown that the existing methods for studying the forms of moisture-material bonding have significant drawbacks and generally give a qualitative assessment of the state of moisture in the material or are very laborious and require long-term laboratory studies. The efficiency of the approach to determining the forms of moisture connection in black currant fruits is shown on the basis of graphical-analytical analysis of the drying kinetics, which allows qualitatively and quantitatively assessing the state of moisture in the fruits. With the help of a graphical editor, the curves of the drying kinetics of black currant fruits were processed and the dependences of the quantity called "drying acceleration" characterizing the rapidity of the change in the drying rate of currant fruits on the moisture content of the product were obtained. The analysis of the obtained curves is carried out, indicating the presence of extrema and points of inflection to the corresponding critical moisture content, as well as the presence of areas with a slowdown or acceleration of the drying rate change, allowing to establish the intervals of moisture removal with different binding energies. The approach under consideration makes it possible to give a quantitative and qualitative assessment of the physical state of moisture not only in currant fruits, but also in other food products, as well as reduce the time for analysis and improve the accuracy of the results.
本文讨论了黑加仑果实干燥过程中脱除水分的联系形式研究的有关问题。采用两种方法测定了各种通讯形式的定量水分含量,并进行了比较分析。研究表明,现有的研究水分-材料结合形式的方法有明显的缺点,通常只能对材料中的水分状态进行定性评估,或者非常费力,需要长期的实验室研究。在干燥动力学的图形分析分析的基础上,表明了确定黑加仑果实中水分连接形式的方法的效率,该方法可以定性和定量地评估果实中的水分状态。在图形化编辑器的帮助下,对黑加仑子的干燥动力学曲线进行了处理,得到了表征黑加仑子干燥速度变化快慢的“干燥加速度”量与产品含水量的关系。对得到的曲线进行分析,表明相应的临界含水率存在极值点和拐点,以及存在干燥速率变化减慢或加速的区域,从而可以建立不同结合能的除湿间隔。该方法不仅可以对葡萄干中的水分物理状态进行定量和定性评估,还可以对其他食品中的水分物理状态进行定量和定性评估,减少分析时间,提高结果的准确性。
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引用次数: 0
Properties and structural features of epoxycomposites reinforced with modified PAN- flagellum 改性聚丙烯腈-鞭毛增强环氧复合材料的性能及结构特征
Pub Date : 2023-03-16 DOI: 10.20914/2310-1202-2022-4-200-205
N. G. Zubova, V. M. Gerasimova, N. L. Levkina, T. P. Ustinova, K. B. Kostin
The performance characteristics of composite materials reinforced with polyacrylonitrile technical flagellum (PAN-TF), which has the reactivity of functional groups, can be improved by modifying it. The aim of the work was to study the effect of polyacrylonitrile fibrous materials, applied with AGM-9, A-187, A-174 and Duron OS 3151 modifiers, on the kinetics of the ED-20 epoxy resin curing process, structural features of the developed composites and their operational properties. The methods of kinetic research, differential scanning calorimetry (DSC), scanning electron microscopy and mechanical testing of composite materials were used in the work. The effect of modified PAN-TF on the change in the kinetics of the curing process of the epoxy binder is shown, characterized by an increase in the curing time, a decrease in the maximum curing temperature and a decrease in the activation energy of the curing ED-20. The results of kinetic studies are confirmed by the data of DSC epoxy compositions based on modified PAN-TF, which show a decrease in the maximum temperature and an increase in the thermal effects of the ED-20 curing process in the presence of the studied reinforcing systems compared with epoxy composite reinforced with unmodified flagellum. The structure formation of epoxy compositions under milder conditions ensures the formation of a contact zone between the elementary fibers and the binder, which contributes to an increase in the solidity of plastics compared to a composite based on the original PAN-TF. A comparative analysis of the strength properties of the studied composites showed that when applied to ED-20, there is an improvement in strength indicators. The assessment of kinetic parameters, structural features and strength properties of the developed composites reinforced with modified PAN-TF indicates an increase in the surface activity of fibrous materials as a result of their modification.
具有官能团反应性的聚丙烯腈技术鞭毛(PAN-TF)增强复合材料的性能可以通过改性得到改善。研究了AGM-9、A-187、A-174和Duron OS 3151改性剂对聚丙烯腈纤维材料ED-20环氧树脂固化过程动力学、复合材料结构特征和使用性能的影响。采用了动力学研究、差示扫描量热法(DSC)、扫描电镜和复合材料力学性能测试等方法。改性PAN-TF对环氧粘合剂固化过程动力学变化的影响,表现为固化时间增加,最高固化温度降低,固化ED-20的活化能降低。动力学研究的结果得到了基于改性PAN-TF的环氧复合材料DSC数据的证实,表明与未改性鞭毛增强的环氧复合材料相比,有改性PAN-TF的环氧复合材料在ED-20固化过程中最高温度降低,热效应增加。在较温和的条件下,环氧树脂组合物的结构形成确保了初级纤维和粘合剂之间形成接触区,与基于原始PAN-TF的复合材料相比,这有助于增加塑料的固体性。对所研究的复合材料的强度性能进行对比分析表明,应用于ED-20后,其强度指标均有改善。对改性PAN-TF增强复合材料的动力学参数、结构特征和强度性能进行了评价,结果表明改性后纤维材料的表面活性有所提高。
{"title":"Properties and structural features of epoxycomposites reinforced with modified PAN- flagellum","authors":"N. G. Zubova, V. M. Gerasimova, N. L. Levkina, T. P. Ustinova, K. B. Kostin","doi":"10.20914/2310-1202-2022-4-200-205","DOIUrl":"https://doi.org/10.20914/2310-1202-2022-4-200-205","url":null,"abstract":"The performance characteristics of composite materials reinforced with polyacrylonitrile technical flagellum (PAN-TF), which has the reactivity of functional groups, can be improved by modifying it. The aim of the work was to study the effect of polyacrylonitrile fibrous materials, applied with AGM-9, A-187, A-174 and Duron OS 3151 modifiers, on the kinetics of the ED-20 epoxy resin curing process, structural features of the developed composites and their operational properties. The methods of kinetic research, differential scanning calorimetry (DSC), scanning electron microscopy and mechanical testing of composite materials were used in the work. The effect of modified PAN-TF on the change in the kinetics of the curing process of the epoxy binder is shown, characterized by an increase in the curing time, a decrease in the maximum curing temperature and a decrease in the activation energy of the curing ED-20. The results of kinetic studies are confirmed by the data of DSC epoxy compositions based on modified PAN-TF, which show a decrease in the maximum temperature and an increase in the thermal effects of the ED-20 curing process in the presence of the studied reinforcing systems compared with epoxy composite reinforced with unmodified flagellum. The structure formation of epoxy compositions under milder conditions ensures the formation of a contact zone between the elementary fibers and the binder, which contributes to an increase in the solidity of plastics compared to a composite based on the original PAN-TF. A comparative analysis of the strength properties of the studied composites showed that when applied to ED-20, there is an improvement in strength indicators. The assessment of kinetic parameters, structural features and strength properties of the developed composites reinforced with modified PAN-TF indicates an increase in the surface activity of fibrous materials as a result of their modification.","PeriodicalId":31207,"journal":{"name":"Vestnik Voronezskogo Gosudarstvennogo Universiteta Inzenernyh Tehnologij","volume":"54 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135553356","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Vestnik Voronezskogo Gosudarstvennogo Universiteta Inzenernyh Tehnologij
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