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Hydrothermic reduction of rutile-ilmenite mineral producing an oxyhydride η-Ti2FeO0.2H2.8: Towards in-situ hydrogen production and storage 金红石-钛铁矿的水热还原产生氧酸酐 η-Ti2FeO0.2H2.8:实现原位制氢和储氢
Q4 Engineering Pub Date : 2024-03-11 DOI: 10.4314/njtd.v21i1.2133
I. A. Mohammed, S. I. Mustapha, F. Aderibigbe, H. U. Hambali, A. M. Afolabi, K. B. Muritala, U. M. Aliyu
As an alternative to the physical storage of hydrogen as compressed gas or liquid hydrogen requiring high-pressure tanks and cryogenic temperatures, the material-based storage of hydrogen in solids involves hydrogen uptake and release from the surface of adsorbents or within interstitials of hydrides. We report a hydrothermic reduction of rutile-ilmenite mineral into hydrogen-rich fibrous products, η-Ti2FeO0.2H2.8, in an ethanol-water system at 120°C for 4 hrs. As part of a project to generate hydrogen from water-ethanol system using advanced catalysts containing graphene oxide (GO) as carbon source, a system of 62.5 μg graphene oxide per g of rutile-ilmenite mineral was employed in a concentration of 50 mg/mL of ethanol-water solution. As well as in the original mineral, XRD of thermal annealed mineral between 500 and 800°C showed no hydride or phase change in rutile-ilmenite. With hydrothermal treatment of GO/rutile-ilmenite (50 mg/mL) in ethanol-water (1:1 v/v) at 120°C, a hydrogen-rich ferrotitanium hydride phase was formed, and there was a change in morphology from plate-like and granular particles into fibrous structures. Like the release of hydrogen by its ‘carriers’ (e.g., CaH2, NH4BH4, NaBH4, NH3, formic acid), it is anticipated that hydrogen was generated from the ethanol-water system in-situ, which reduced the rutile-ilmenite mineral into a hydride. EDX results showed that the reduction affected specifically the oxides of Fe and aluminosilicates in the mineral. The study demonstrated a possibility of in-situ hydrogen generation and storage via low-temperature graphene oxide hydrothermic reduction of rutile-ilmenite mineral in an ethanol-water system.
作为需要高压罐和低温的压缩气体或液态氢物理储存的替代方法,基于材料的固体氢储存涉及吸附剂表面或氢化物间隙中的氢吸收和释放。我们报告了金红石-钛铁矿在 120°C 的乙醇-水体系中经过 4 小时的水热还原成为富氢纤维状产物 η-Ti2FeO0.2H2.8。作为使用含有氧化石墨烯(GO)作为碳源的先进催化剂从水-乙醇体系中产生氢气项目的一部分,在浓度为 50 毫克/毫升的乙醇-水溶液中使用了每克金红石-钛铁矿矿物含 62.5 微克氧化石墨烯的体系。与原始矿物一样,500 至 800°C 热退火矿物的 XRD 显示金红石-钛铁矿中没有氢化物或相变。在 120°C 的乙醇-水(1:1 v/v)溶液中对 GO/金红石-钛铁矿(50 mg/mL)进行水热处理后,形成了富氢钛铁氢化物相,形态也从板状和颗粒状转变为纤维状结构。与氢的 "载体"(如 CaH2、NH4BH4、NaBH4、NH3、甲酸)释放氢一样,预计氢是从乙醇-水体系中原位生成的,从而将金红石-钛铁矿还原成氢化物。EDX 结果表明,还原作用特别影响了矿物中的铁氧化物和铝硅酸盐。该研究证明了在乙醇-水体系中通过低温氧化石墨烯热还原金红石-钛铁矿矿物实现原位制氢和储氢的可能性。
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引用次数: 0
A review on CO2 capture over novel adsorbents: Progress in robust zeolite adsorbent development 新型吸附剂捕获二氧化碳综述:强效沸石吸附剂的开发进展
Q4 Engineering Pub Date : 2024-03-11 DOI: 10.4314/njtd.v21i1.2235
H. U. Hambali, T. Jimoh, T. L. Peng, A. A. Umar, B. T. Mutiullah, J. A. Okolie
Indubitably, the combustion of fossils fuels has really hampered the preservation of the environment as it raises the content of CO2 in the atmosphere which consequentially results in global warming. Adsorption process remains the popular technique owing to its cost-effectiveness, faster reaction rates and flexible design. This review detailed the research progress in preparation of modified zeolite-based and novel adsorbents towards enhanced CO2 capture. In addition, the review presents an overview on available techniques of capturing CO2 and mechanism of reaction. Large surface area, distinctive mechanical characteristics and uniform dispersion of the exchangeable cations in the porous framework is prerequisite for high adsorption capacity and stability over zeolite materials. Novel nanostructured and polymeric zeolite composite materials seem promising because they offer solutions to energy-related problems while also contributing to environmental preservation. It is anticipated that this review could offer a conclusive roadmap in the pursuit of a cost-effective, industrially potent adsorbent suited for enhance CO2 capture.
毋庸置疑,化石燃料的燃烧确实阻碍了环境保护,因为它增加了大气中的二氧化碳含量,从而导致全球变暖。吸附工艺因其成本效益高、反应速度快和设计灵活等优点,仍然是最受欢迎的技术。本综述详细介绍了在制备改性沸石基和新型吸附剂以提高二氧化碳捕集能力方面的研究进展。此外,综述还概述了现有的二氧化碳捕集技术和反应机理。大表面积、独特的机械特性以及多孔框架中可交换阳离子的均匀分散是沸石材料具有高吸附容量和稳定性的先决条件。新型纳米结构和聚合物沸石复合材料似乎大有可为,因为它们既能解决与能源有关的问题,又能促进环境保护。预计本综述将为寻求适合提高二氧化碳捕获能力的、具有成本效益和工业效力的吸附剂提供一个结论性的路线图。
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引用次数: 0
Recent advances in smart manufacturing: a case study of small, medium, and micro enterprises (SMME) 智能制造的最新进展:中小型和微型企业(SMME)案例研究
Q4 Engineering Pub Date : 2024-03-11 DOI: 10.4314/njtd.v21i1.1905
K. A. Bello, M. Kanakana-Katumba, R. Maladzhi, C. O. Omoyi, Author Contributions Conceptualization, M. Kanakana-Katumba, K. methodology, M. G. .Bello, R. W. Kanakana-Katumba, Maladzhi C.O, K. Omoyi, Omoyi, .Bello
The digital revolution is the future pathway to experiencing business evolution. It will be difficult for any organization to remain in business without deploying fourth industry revolution (4IR) techniques. This review guides prospective business owners on the need to embrace Smart Manufacturing (SM) timely and appropriate to enhance their business performance indicators. Many manufacturing companies are facing challenges in adopting SM tools in their organization due to a lack of essential resources despite the benefits associated with SM. Therefore, this study systematically reviewed the criteria evaluation techniques in implementing digital factories. This work has analysed small, medium, and micro enterprises (SMME), with the view to enumerate the appropriate criteria to determine the level of digital technology tools adoption framework. It also highlights how to compensate for the inadequate technical and financial resources in SM. The guidelines for SM implementation adoption in SMME is a research gap that was missing in previous studies. SM benefits, challenges, applications, significance, impact, and future perspectives, are discussed. Evaluation Criteria for SM Adoption practices were also expounded. The framework used in this study will help SMME owners to adopt SM.
数字革命是未来企业发展的必经之路。如果不采用第四次工业革命(4IR)技术,任何组织都很难继续经营下去。本综述将指导未来的企业主及时、适当地采用智能制造(SM),以提高其业务绩效指标。尽管智能制造有诸多好处,但由于缺乏必要的资源,许多制造企业在采用智能制造工具方面面临挑战。因此,本研究系统回顾了实施数字化工厂的标准评估技术。这项工作对中小型和微型企业(SMME)进行了分析,目的是列举适当的标准,以确定数字技术工具采用框架的水平。它还强调了如何弥补中小微企业技术和财政资源不足的问题。在中小型企业中采用 SM 实施准则是以往研究中缺少的一个研究空白。报告讨论了 SM 的好处、挑战、应用、意义、影响和未来展望。此外,还阐述了采用 SM 做法的评估标准。本研究采用的框架将有助于中小型企业主采用 SM。
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引用次数: 0
Multi optimization in slot milling of CFRP composites through grey relational- based Taguchi analysis 通过基于灰色关系的田口分析实现 CFRP 复合材料槽铣加工的多重优化
Q4 Engineering Pub Date : 2024-03-11 DOI: 10.4314/njtd.v21i1.1762
A. Bahei El-Deen
Carbon fiber-reinforced plastic (CFRP) composite materials are challenging to machine due to their anisotropy and heterogeneity. Thus, the experimental study of milling CFRP composite material is very crucial. In the current study, based on Taguchi’s L9 orthogonal array, slot milling experiments were performed on CFRP composite samples to make a decision on a parametric optimization of multiple responses such as material removal rate (MRR), delamination factor (Fd) and surface roughness (Ra) using grey relational-based Taguchi analysis. The selected milling parameters are cutting speed (A), feed (B), and depth of cut (C). Based on Grey Relational Grade (GRG), Analysis of Variance (ANOVA) was used to determine the parameters' significant contributions and the parameters' optimal levels. The results showed, with a 95% confidence level, that all of the chosen cutting parameters have a substantial impact on all of the measured responses. Based on a confirmatory test performed under ideal milling conditions, MRR has been increased with an improvement of 31.25 %, Fd has been decreased with an improvement of 1.66% and Ra has been decreased with an improvement of 28.3%. These improvements in all measured responses are equivalent to an improvement of GRG by 3%.
碳纤维增强塑料(CFRP)复合材料因其各向异性和异质性,在加工方面具有挑战性。因此,铣削 CFRP 复合材料的实验研究非常重要。在本研究中,基于田口L9正交阵列,对CFRP复合材料样品进行了铣槽实验,利用基于灰色关系的田口分析法对材料去除率(MRR)、分层因子(Fd)和表面粗糙度(Ra)等多个响应进行参数优化。选定的铣削参数为切削速度 (A)、进给量 (B) 和切削深度 (C)。根据灰色关联等级(GRG),采用方差分析(ANOVA)确定参数的显著贡献和参数的最佳水平。结果表明,在 95% 的置信度下,所有选定的切割参数对所有测量响应都有重大影响。根据在理想铣削条件下进行的确认测试,MRR 提高了 31.25%,Fd 降低了 1.66%,Ra 降低了 28.3%。所有测量反应的改善相当于 GRG 改善了 3%。
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引用次数: 0
Comparative analysis of dual stator machines 双定子机器的比较分析
Q4 Engineering Pub Date : 2024-03-11 DOI: 10.4314/njtd.v21i1.1872
C. Awah
Electromagnetic performance of three different types of double stator permanent magnet machine is analyzed and compared in this study. The analyzed machines in this study are Machine 1, Machine 2 and Machine 3. These machines are designated as: M 1, M 2 and M 3, respectively. The studies are implemented using two-dimensional and three-dimensional finite element analysis (2D-FEA and 3D-FEA) methods. The predicted performance indices are: total harmonic distortion of the voltage, torque ripple, cogging torque, winding inductances, output torque and unbalanced magnetic force (UMF). The studies show that the investigated machine types have negligible reluctance torque and thus, similar axes inductance values. Therefore, the machines’ bulk torque components are contributed mainly by the magnets while the armature excitation sources yield lesser torque components. Amongst the compared machines, M 3 type has an outstanding performance in almost all the performance metrics, compared to M 2 and M 1 types. Nevertheless, M 1 machine type has some good attributes, particularly, with respect to its high output torque per applied magnet volume, in addition to its widest operating speed range ability. Low-speed high-torque applications are most suitable for the investigated machines in practice.
本研究对三种不同类型的双定子永磁电机的电磁性能进行了分析和比较。本研究分析的机器分别为机器 1、机器 2 和机器 3。这些机器被命名为M 1、M 2 和 M 3。研究采用二维和三维有限元分析(2D-FEA 和 3D-FEA )方法进行。预测的性能指标包括:电压总谐波失真、转矩纹波、齿槽转矩、绕组电感、输出转矩和不平衡磁力(UMF)。研究表明,所研究的机器类型的磁阻转矩可以忽略不计,因此轴电感值也相似。因此,机器的大部分转矩成分主要来自磁体,而电枢励磁源产生的转矩成分较少。与 M 2 和 M 1 机型相比,M 3 机型在几乎所有性能指标上都表现出色。不过,M 1 型机器也有一些优点,尤其是单位应用磁体体积输出扭矩大,而且工作速度范围最广。在实际应用中,低速高扭矩应用最适合所研究的机器。
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引用次数: 0
Analysis of 3D printing materials as potential Radiological Phantoms of Lung Organs for medical imaging purposes 分析 3D 打印材料作为肺部器官放射假体的潜在医学成像用途
Q4 Engineering Pub Date : 2024-03-11 DOI: 10.4314/njtd.v21i1.2148
M. Yunianto, F. Anwar, T. Ardyanto
Research has been conducted to analyze and characterize ten 3D printing materials as potential Radiological Phantoms of Lung Organs. Eight filaments of PLA, ABS, HIPS, Carbon, Nylon, TPU, PETG, and Wood were printed using an FDM type 3D printer, and two resins, PLA resin and Water washable resin, were printed using an SLA type 3D printer. The phantoms were printed with thickness variations of 3 mm, 6 mm, and 9 mm. 8 parameters were used to obtain the best material, namely material density, CT number, electron density (Ne), effective electron density (EDG), electron density per volume (EDV), effective atomic number (Zeff), material constituent elements, and elastic Modulus. Based on comparing the values of 8 parameters, the most potential to be used as phantom material for lung organs is PLA.
研究人员对作为肺部器官潜在辐射模型的十种三维打印材料进行了分析和表征。使用 FDM 型三维打印机打印了 PLA、ABS、HIPS、碳纤维、尼龙、TPU、PETG 和木材八种长丝,并使用 SLA 型三维打印机打印了 PLA 树脂和水洗树脂两种树脂。打印的模型厚度分别为 3 毫米、6 毫米和 9 毫米。为获得最佳材料,使用了 8 个参数,即材料密度、CT 数、电子密度(Ne)、有效电子密度(EDG)、单位体积电子密度(EDV)、有效原子序数(Zeff)、材料组成元素和弹性模量。根据 8 个参数值的比较,聚乳酸最有可能用作肺器官的模型材料。
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引用次数: 0
Numerical Analysis of the Thermodynamic Response of a Hollow Concrete Cylinder 空心混凝土圆柱体热力学响应的数值分析
Q4 Engineering Pub Date : 2024-02-26 DOI: 10.4314/njtd.v20i4.2076
T.T. Akano, H.O. Onovo, O. S. Osasuyi, S.A. Alabi
The stability and durability of concrete materials are essential factors in the construction industry. Environmental conditions, such as  temperature affect the tensile strength and durability of concrete structures. This work investigates the thermodynamic behaviour of  hollow cylindrical concrete using the finite element method (FEM). By deploying ANSYS®, the element mesh was created, and the  temperature distribution inside the hollow cylinder was calculated. The effect of the hollowness of the concrete on its heat absorption is  determined. The findings demonstrate that the temperature profiles changed radially throughout the concrete thickness. Moreover, it  was discovered that the temperature distribution was impacted by the airflow into the cylinder. The numerical experiment in this study  was essential in providing a comprehensive understanding of the behaviour of the concrete, particularly when exposed to higher heating  rates. This study contributes to the knowledge of the performance and stability of concrete materials. It also demonstrates that the  hollowness of the concrete enhances its heat-shielding performance. Furthermore, the inflow of air into the cylinder affects the  temperature distribution, with a higher influx of air resulting in lower temperatures. These findings can be utilised to develop appropriate  measures to enhance the performance and durability of concrete structures. 
混凝土材料的稳定性和耐久性是建筑业的基本要素。温度等环境条件会影响混凝土结构的抗拉强度和耐久性。本研究采用有限元法(FEM)研究了空心圆柱混凝土的热力学行为。通过部署 ANSYS®,创建了元素网格,并计算了空心圆柱体内部的温度分布。确定了混凝土空心程度对其吸热的影响。研究结果表明,在整个混凝土厚度范围内,温度分布呈径向变化。此外,还发现温度分布受到进入圆筒的气流的影响。本研究中的数值实验对于全面了解混凝土的行为,尤其是暴露于较高加热速率时的行为至关重要。这项研究有助于了解混凝土材料的性能和稳定性。研究还表明,混凝土的空心率提高了其热屏蔽性能。此外,空气流入气缸会影响温度分布,空气流入量越大,温度越低。这些发现可用于制定适当的措施,以提高混凝土结构的性能和耐久性。
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引用次数: 0
Impact of deposition voltage on the physical properties of rare earth element doped strontium sulphide for optoelectronic application 沉积电压对用于光电应用的稀土元素掺杂硫化锶物理性质的影响
Q4 Engineering Pub Date : 2024-02-26 DOI: 10.4314/njtd.v20i4.1709
S. O. Samuel, C. K. Ojoba, E. P. Ogherohwo, I. Ikhioya
In this study, electrochemical deposition was used to synthesize SrS-doped zirconium materials at a varying voltage of deposition. The  XRD result shows that SrS/Zr has a prominent peak intensity corresponding to 2theta values of 26.45o , 33.86o , 38.01o , and 51.49o . The  crystal lattice is shown by the prominent peak intensity with higher 2theta degree values; the appearance of an unindexed peak is caused  by the substrate utilized for the deposition. SrS surface morphology reveals a Clove-like surface with precipitate visible in the SrS  micrograph; the large grain size on the surface of the substrate exhibits photon absorption but lacks any signs of pinholes. At the  introduction of zirconium as a dopant to the SrS precursor, there was a drastic change in the precursor which is also noticed on the surface micrograph of the analyzed films. The films show a decrease in thickness from 129.14 to 120.09 nm and an increase in film  resistivity from 1.24 x 109 to 1.29 x 109 ohm.m, which further led to a decrease in conductivity from 8.06 x 108 to 7.75 x 108 S/m. The  impact of the deposition voltage on the reflectance reveals that lower voltage will stabilize the reflectance of SrS/Zr which will be useful  for photovoltaic applications. SrS has an energy bandgap of 1.50 eV while SrS/Zr with bandgap energy of 2.00 – 2.50 eV.  
本研究采用电化学沉积法,在不同的沉积电压下合成了掺杂 SrS 的锆材料。XRD 结果表明,SrS/Zr 的 2theta 值分别为 26.45o、33.86o、38.01o 和 51.49o,具有明显的峰值强度。晶格显示为 2theta 度值越高,峰强度越大;出现无指数峰是由于沉积时使用的基底造成的。SrS 表面形态显示出类似丁香的表面,在 SrS 显微照片中可以看到沉淀物;衬底表面的大晶粒尺寸显示出光子吸收,但没有任何针孔迹象。在 SrS 前驱体中引入锆作为掺杂剂时,前驱体发生了急剧变化,这一点在分析薄膜的表面显微照片上也能看到。薄膜厚度从 129.14 纳米减少到 120.09 纳米,薄膜电阻率从 1.24 x 109 欧姆.米增加到 1.29 x 109 欧姆.米,这进一步导致导电率从 8.06 x 108 S/m 减少到 7.75 x 108 S/m。沉积电压对反射率的影响表明,较低的电压将稳定 SrS/Zr 的反射率,这将有助于光伏应用。SrS 的能带隙为 1.50 eV,而 SrS/Zr 的能带隙为 2.00 - 2.50 eV。
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引用次数: 0
High Impedance Fault Detection and Localization Using Fully-Connected Convolutional Neural Network: A Deep Learning Approach 使用全连接卷积神经网络进行高阻抗故障检测和定位:深度学习方法
Q4 Engineering Pub Date : 2024-02-26 DOI: 10.4314/njtd.v20i4.2143
I. Abasi-Obot, A.B. Kunya, G. S. Shehu, Y. Jibril
The detection and localization of high impedance faults (HIF) in power systems are challenging due to the low fault current magnitude,  which often falls below the detection threshold of conventional devices. HIF events introduce harmonics into the network, posing risks to  the safety of connected equipment, including the potential for igniting fire which endangers lives and properties. In this study, Emanuel's  HIF model was used to generate HIF signatures resembling real HIF events. Model parameters were adjusted to mimic  various contact surface impedances. Two datasets were created: 'no-fault' data, simulating the network without HIF, and 'fault' data,  incorporating HIF waveforms by simulating single and multiple lines with the HIF model. The faulted line was divided into five segments along the 33 kV line to capture fault signatures at different locations. The generated data, including current waveforms and magnitudes,  were processed and divided into an 80:20 ratio for training, validation, and testing using a deep fully connected Convolutional Neural  Network for HIF detection and location. The results showed an impressive accuracy rate of 99.44% and 99.78% for detection and location  respectively, representing a significant advancement in HIF detection and location, and offering practical applications for enhancing  power line safety. 
电力系统中高阻抗故障 (HIF) 的检测和定位极具挑战性,因为故障电流幅度较低,通常低于传统设备的检测阈值。高阻抗故障事件会给网络带来谐波,给连接设备的安全带来风险,包括可能引发火灾,危及生命和财产安全。在这项研究中,伊曼纽尔的 HIF 模型用于生成与真实 HIF 事件相似的 HIF 信号。对模型参数进行了调整,以模拟各种接触面阻抗。创建了两个数据集:无故障 "数据,模拟没有 HIF 的网络;"故障 "数据,通过使用 HIF 模型模拟单条和多条线路,结合 HIF 波形。故障线路沿 33 千伏线路分为五段,以捕捉不同位置的故障特征。生成的数据(包括电流波形和幅值)经过处理后,按 80:20 的比例进行训练、验证和测试,使用深度全连接卷积神经网络进行 HIF 检测和定位。结果显示,检测和定位的准确率分别为 99.44% 和 99.78%,令人印象深刻,这表明在 HIF 检测和定位方面取得了重大进展,并为加强电力线安全提供了实际应用。
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引用次数: 0
Influence of stenosis severity on hemodynamics flow at low Reynolds numbers: A computational fluid dynamic study 狭窄严重程度对低雷诺数血流动力学流动的影响:计算流体动力学研究
Q4 Engineering Pub Date : 2024-02-26 DOI: 10.4314/njtd.v20i4.1621
I. A. Fetuga, O. Oluwatusin, S. Abolarin, O. O. Olakoyejo, A. O. Adelaja, D.Z. Olaoye, A.S. Adeleke, J. K. Gbegudu, K. S. Aderemi
No Abstract
无摘要
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引用次数: 0
期刊
Nigerian Journal of Technological Development
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