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Removal of heavy metals from domestic wastewater using Beneficiated Kaolin Clay, Silver Oxide and zinc Oxide nanocomposite 高岭土、氧化银和氧化锌纳米复合材料去除生活污水中的重金属
Q4 Engineering Pub Date : 2023-10-15 DOI: 10.4314/njtd.v20i3.1651
F.O. Ogundipe, M. Saidu, A.S. Abdulkareem, A.O Busari
This study describes the removal of total iron, cadmium, lead, copper, manganese, arsenic, mercury silver and zinc from domestic wastewater disposed of via sewers, using Beneficiated Kaolin Clay (BKC), BKC/Ag, BKC/ZnO and BKC/Ag/ZnO nanocomposite adsorbents produced by blending Silver Oxide (Ag) and Zinc Oxide (ZnO) nanoparticles with kaolin clay. High Resolution Transmission Electron Microscope (HRTEM) results showed that the produced adsorbents were polycrystalline in nature, while the interplanar spacing and average crystalline sizes are 1.775 – 4.712 nm and 26. 834 – 40.258 nm respectively, according to X-Ray Diffractometer (XRD) analysis. The Dispersive X – Ray Fluorescence (XRF) analysis indicated that SiO2/Al2O3 ratios for BKC/Ag, BKC/ZnO and BKC/Ag/ZnO nanocomposites adsorbents were 1.5170, 1.4818 and 1.5231 respectively. Brunauer – Emmett – Teller (BET) analysis showed that the desorption average pore sizes fell in the mesopore widths of 13.8994 – 16.9233 nm and surface areas of 1.0545 - 14.5126 m2.g-1. The removal efficiencies of the produced adsorbents followed this trend: BKC/Ag/ZnO > BKC/Ag > BKC/ZnO > BKC. These adsorbents were excellent in the removal of total iron, cadmium, lead, copper, manganese, arsenic, mercury silver and zinc pollutants from domestic wastewater, and hence, recommended for large scale production.
本研究利用高岭土、BKC/Ag、BKC/ZnO和BKC/Ag/ZnO纳米复合吸附剂,将氧化银(Ag)和氧化锌(ZnO)纳米颗粒与高岭土混合制备的纳米复合吸附剂,对生活污水中的总铁、镉、铅、铜、锰、砷、汞、银和锌进行了脱除。高分辨透射电镜(HRTEM)结果表明,制备的吸附剂具有多晶性质,其面间距为1.775 ~ 4.712 nm,平均晶粒尺寸为26。经x射线衍射仪(XRD)分析,分别为834 ~ 40.258 nm。色散X射线荧光(XRF)分析表明,BKC/Ag、BKC/ZnO和BKC/Ag/ZnO纳米复合吸附剂的SiO2/Al2O3比值分别为1.5170、1.4818和1.5231。Brunauer - Emmett - Teller (BET)分析表明,脱附平均孔径为13.8994 ~ 16.9233 nm,比表面积为1.0545 ~ 14.5126 m2.g-1。制备的吸附剂的去除率遵循以下趋势:BKC/Ag/ZnO >1 / Ag)比;1 /氧化锌比;汉堡王。这些吸附剂对生活废水中总铁、镉、铅、铜、锰、砷、汞、银、锌等污染物的去除效果优异,推荐用于大规模生产。
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引用次数: 0
Absorbent mixtures optimisation for COD and Ammonia Nitrogen reduction in stabilised leachate 稳定渗滤液中COD和氨氮减少的吸收剂混合物优化
Q4 Engineering Pub Date : 2023-10-15 DOI: 10.4314/njtd.v20i3.1321
M. H. Abubakar, Z. Daud, H. A. Abba
This paper describes the optimisation of mixed media for Chemical Oxygen Demand (COD) and Ammonia Nitrogen (NH3-N) removal from stabilised leachate by feldspar (FE), zeolite (ZE), activated carbon (AC), and cockle shells (CS) mixtures using D-optimal mixture design. Linear equations characterised the optimal mixture. The optimum mitigation of COD and NH3-N in landfill leachate was favourable at 12.5 mg/L, 9.72 mg/L, 6 mg/L, and 11.79 mg/L of adsorbent mixed dosage for FE, ZE, AC, and CS, respectively, with the desirability value of 0.886. The predicted R-squared values for NH3-N (0.9839) and COD (0.8972) were in close agreement with the adjusted R-squared values of 0.9940 and 0.9900 for COD and NH3-N, respectively, which validates the obtained regression models. The Lack of Fit F-values of 0.6015 (COD) and 0.4565 (NH3-N) are insignificant, indicating that the models accurately predict the removal. The Fourier transform infrared spectroscopy (FTIR) revealed that the predominant hydroxyl group consisted of –OH at spectra 3306.18 and 3338.74. The study also revealed that the D-optimal mixture design has extremely high application potential as it produces a good mixture design based on the remediation of contaminants from stabilised leachate.
本文介绍了长石(FE)、沸石(ZE)、活性炭(AC)和贝壳(CS)混合物对稳定渗滤液中化学需氧量(COD)和氨氮(NH3-N)去除的混合介质的优化设计。线性方程描述了最优混合物。FE、ZE、AC和CS在12.5 mg/L、9.72 mg/L、6 mg/L和11.79 mg/L的混合投加量下,对垃圾渗滤液中COD和NH3-N的抑制效果最佳,理想值为0.886。NH3-N(0.9839)和COD(0.8972)的预测r平方值与COD和NH3-N的调整r平方值分别为0.9940和0.9900非常吻合,验证了回归模型的正确性。COD和NH3-N的缺失拟合f值分别为0.6015和0.4565,均不显著,说明模型能够准确预测去除效果。傅里叶变换红外光谱(FTIR)显示,在光谱3306.18和3338.74处,羟基主要由-OH组成。该研究还表明,d -最优混合设计具有极高的应用潜力,因为它基于对稳定渗滤液中污染物的修复产生了良好的混合设计。
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引用次数: 0
Capacities and irreversibility of the vapour compression refrigeration system’s components using aluminium oxide (Al<sub>2</sub>O<sub>3</sub>) based nanolubricants 使用氧化铝(Al&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;3&lt;/sub&gt;)基纳米润滑剂的蒸汽压缩制冷系统组件的容量和不可逆性
Q4 Engineering Pub Date : 2023-10-15 DOI: 10.4314/njtd.v20i3.1459
M. Ogbonnaya, O. O. Ajayi, M.A. Waheed
Hydrochlorofluorocarbon and chlorofluorocarbon refrigerants commonly used in vapour compression refrigeration system (VCRS) have been phased out due to their negative impact on the ecosystem. R134a and R600a refrigerants were considered as their replacement, but they possess low thermal properties, thereby affecting the performance of the VCRS. In this study, the effect of varying aluminium oxide (Al2O3) nanoparticle size (10 nm, 20 – 30 nm and 80nm) and volume concentration (1%, 3%, 5% 10% and 20%) on the capacity and exergy efficiency of each component of VCRS for the optimisation of the VCRS performance and reduction of energy consumption was analysed using R134a and R600a refrigerants. The nanolubricant were prepared using the two-step method. The VCRS showed no significant deterioration in the performance of its components as confirmed for over 24 hours when nanorefrigerant was used. The compressor capacity of nanorefrigerant was lower than that of pure refrigerants while the addition of nanoparticle enhanced the refrigeration effect. The exergy efficiency of the vapour compression system improved with the addition of nanoparticles into the system, the exergy destruction caused by friction in the compressor significantly reduced, thereby reducing the energy consumed by the system.
蒸汽压缩制冷系统(VCRS)中常用的氢氯氟烃和氯氟烃制冷剂由于其对生态系统的负面影响已被逐步淘汰。R134a和R600a制冷剂被认为是它们的替代品,但它们的热性能较低,从而影响了VCRS的性能。在本研究中,采用R134a和R600a制冷剂,分析了不同氧化铝(Al2O3)纳米颗粒尺寸(10 nm, 20 - 30 nm和80nm)和体积浓度(1%,3%,5%,10%和20%)对VCRS各组分容量和能效的影响,以优化VCRS性能和降低能耗。采用两步法制备了纳米润滑剂。在使用纳米制冷剂的24小时内,VCRS各部件的性能没有明显的下降。纳米制冷剂的压缩容量低于纯制冷剂,而纳米颗粒的加入增强了制冷效果。随着纳米颗粒的加入,蒸汽压缩系统的火用效率得到了提高,压缩机内摩擦引起的火用破坏显著减少,从而降低了系统消耗的能量。
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引用次数: 0
Investigation of electric field enhancement and effects of discharge severity in an insulated power cable with multiple gaseous cavities 多气腔绝缘电力电缆电场增强及放电强度影响的研究
Q4 Engineering Pub Date : 2023-10-15 DOI: 10.4314/njtd.v20i3.1435
U. Musa, A. A. Mati, A. A. Mas’ud, G. S. Shehu, S. H. Sulaiman, J. M. Rodriguez-Serna
Gaseous cavities in the insulation of high voltage (HV) cables affect the electric field distribution and increase the electrical stress. This accelerates material ageing and creates partial discharge (PD) regions, which can cause cable failure. In this study, a simulation approach using a Finite Element Method (FEM) has been deployed to evaluate the discharge activity and electric field variation in cross-linked polyethylene (XLPE) insulated power cables. 2-Dimension models corresponding to sections of a practical three-core XLPE insulated cable were developed using COMSOL Multiphysics. Multiple cavities of different dimensions and configurations were considered. The results show that the electric field varies depending on the configuration and dimensions of the cavity. It was found that maximum field strength magnitude depends on the cavities, arrangement and location; an increase of up to 68.7% when compared to the case without cavities.
高压电缆绝缘中存在气腔,影响电场分布,增大电应力。这会加速材料老化并产生局部放电(PD)区域,从而导致电缆故障。本文采用有限元模拟方法对交联聚乙烯(XLPE)绝缘电力电缆的放电活动性和电场变化进行了研究。利用COMSOL Multiphysics软件建立了实际三芯交联聚乙烯绝缘电缆截面对应的二维模型。考虑了不同尺寸和结构的多个空腔。结果表明,电场随腔体的形状和尺寸而变化。结果表明,最大场强大小与空腔、布置和位置有关;与没有蛀牙的病例相比,增加了68.7%。
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引用次数: 0
Heat transfer enhancement using combined microchannel with vertical rectangular micro fins 垂直矩形微鳍组合微通道强化传热
Q4 Engineering Pub Date : 2023-10-15 DOI: 10.4314/njtd.v20i3.1454
N. Y. Godi
This paper focuses on the numerical optimisation of a combined hybrid microchannel heat sink with rectangular solid fins. The axial length and volume are fixed, and external structure is allowed to vary. The simulation was performed on an elemental unit cell of the microchannel heat sink . The purpose of the optimisation is to discover an optimal geometric arrangement in internal and external configurations that minimises peak temperature in the microchannel heat sink. A high-density uniform heat flux of 250 W/cm2 is assumed to be dissipated on the bottom wall of the unit cell by microelectronics circuit boards devices. Computational fluid dynamic code was used to discretized the fluid domain and solve a set of governing equations. The influence of hydraulic diameter, external structural shape and fluid velocity on peak temperature and global thermal resistance, is discussed. Coolant or water of Reynolds number range 400 to 500 in a forced convection laminar flow is introduced through the inlet of the computational domain to remove the heat at the bottom of the rectangular block microchannel. The results show that when the fluid velocity is increased from 9.8 to 12.3 m/s across the axial length of the micro heat sink, more heat is removed from the bottom of the combined heat sink. The results revealed that the pump power increased by 37.1% in combined microchannels with fins and from by 27.2% in finless micro heat sink. The result of the study is validated with what is documented in open literature for a traditional micro heat sink with circular flow channel and the trends agree.
本文重点研究了矩形固体翅片组合混合微通道散热器的数值优化。轴向长度和体积是固定的,外部结构允许变化。在微通道散热器的一个元素单元胞上进行了仿真。优化的目的是发现内部和外部配置的最佳几何排列,以最大限度地降低微通道散热器的峰值温度。假设微电子电路板器件在单元电池的底壁上散逸出250 W/cm2的高密度均匀热流。采用计算流体动力学程序对流体域进行离散化,求解一组控制方程。讨论了液压直径、外部结构形状和流体速度对峰值温度和总热阻的影响。通过计算域入口引入强制对流层流中的冷却剂或雷诺数为400 ~ 500的水,以去除矩形块微通道底部的热量。结果表明,当流体在微散热器轴向长度上的流速从9.8 m/s增加到12.3 m/s时,更多的热量从组合散热器底部排出。结果表明,带翅片组合微通道的泵浦功率比无翅片组合微散热器的泵浦功率提高了37.1%,比无翅片组合微散热器的泵浦功率提高了27.2%。该研究的结果与公开文献中记录的具有循环流通道的传统微型散热器的结果相验证,并且趋势一致。
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引用次数: 0
Leveraging on low-cost devices for wireless data acquisition in remote pipeline networks 利用低成本设备在远程管道网络中进行无线数据采集
Q4 Engineering Pub Date : 2023-10-15 DOI: 10.4314/njtd.v20i3.1587
I. C. Febaide, G. O. Uzedhe
Pipeline infrastructures are the most used means of transporting oil and gas from extraction point to production and sales point. These pipelines are exposed to various attacks either by natural occurrences, indiscriminate human activities around pipelines or direct criminal sabotage, and therefore require constant monitoring. The use of low-cost wireless devices for pipeline data acquisition as it applies to remote and difficult terrain is presented. Different methods and models have been suggested in literature with several existing systems such as SCADA, DCS, and satellite spectral imaging currently in use for pipeline operations. Among the challenges here is the need for lower operational costs, even at reduced response time demand. The Wireless Data Acquisition System (WDAS) presented simulates a pipeline system in a testbed in which a petroleum product is caused to flow and its parameters read, processed as data and wirelessly transmitted, through a wireless sensor network, to a remote device for monitoring. Results indicate a very short response time of about 3.0sec in the simulation at a percentage accuracy of 0.07% over 1km. It also shows that low-cost wireless sensor networking can provide a cost-effective means for pipeline infrastructure management and should be explored.
管道基础设施是将油气从采掘点输送到生产销售点的最常用手段。这些管道受到自然事件、管道周围不分青红皂白的人类活动或直接犯罪破坏的各种攻击,因此需要不断监测。提出了一种低成本的无线设备用于管道数据采集,适用于偏远和困难的地形。文献中提出了不同的方法和模型,包括目前用于管道操作的SCADA、DCS和卫星光谱成像等几种现有系统。这里的挑战之一是需要降低运营成本,即使在减少响应时间需求的情况下也是如此。提出的无线数据采集系统(WDAS)模拟了一个试验台中的管道系统,在该系统中,石油产品流动,其参数被读取、处理为数据,并通过无线传感器网络无线传输到远程设备进行监测。结果表明,模拟的响应时间非常短,约为3.0秒,每1公里的百分比精度为0.07%。这也表明,低成本的无线传感器网络可以为管道基础设施管理提供一种经济有效的手段,值得探索。
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引用次数: 0
Performance analysis of a permanent magnet synchronous motor with dual stator windings 双定子绕组永磁同步电机的性能分析
Q4 Engineering Pub Date : 2023-10-15 DOI: 10.4314/njtd.v20i3.1472
O. J. Tola, E. S. Obe, L. U. Anih
This paper presents the modelling and performance analysis of a line-start three-phase interior permanent magnet synchronous motor (IPMSM) with dual stator windings. The machine has two sets of windings, main and auxiliary windings. The main winding is connected to the supply while the auxiliary is connected to a balanced capacitor. The dynamic model equations are derived in the d-q rotor reference frame using the concept of winding function theory. The machine input impedance was construed from the steady-state equations, where the effects of capacitance on the performance of the motor were studied. An improved torque was obtained when a suitable capacitance was connected to the auxiliary winding. A point of good performance was established by enhancing its direct axis reactance and the quadrature axis reactance which depend on the size of the capacitor. It is shown that thenew configuration has better performance characteristics when compared with those of the traditional configuration in terms of output power, torque density and efficiency.
本文介绍了双定子绕组起动三相内嵌式永磁同步电动机的建模和性能分析。本机有主、辅两套绕组。主绕组连接到电源上,而辅助绕组连接到平衡电容器上。利用绕组函数理论的概念,推导了d-q转子参照系下的动力学模型方程。利用稳态方程解释了电机输入阻抗,研究了电容对电机性能的影响。当在辅助绕组上连接合适的电容时,获得了更好的转矩。根据电容器的尺寸增大其直轴电抗和交轴电抗,建立了良好的性能点。结果表明,与传统结构相比,新结构在输出功率、转矩密度和效率方面具有更好的性能特点。
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引用次数: 0
Maximising efficient water capacity through reservoir configuration with a case study for Malang City of Indonesia 通过水库配置最大化有效水量——以印度尼西亚玛琅市为例
Q4 Engineering Pub Date : 2023-10-15 DOI: 10.4314/njtd.v20i3.1616
G. Samudro, H. Samudro, S. Mangkoedihardjo
All forms of water supply systems had unique characteristics of idle capacity. However, achieving a sustainable water supply over the long term could not eliminate idle capacity. This paper discussed methods for providing efficient capacity without compromising long-term water requirements. The objective of efficient capacity was to reduce idle water capacity and water-carrying infrastructure. This study method reviews previous research results with an in-depth case of a piped water supply system in an urban area. The assessment method referred to the pattern of water demand by consumers. Fluctuations in water demand determined the dimensions of all water supply system components. The results of this study showed that water distribution determines the minimum idle capacity, which directs the need for priority areas for efficient capacity and opens reservoir placement options. Under these priority areas, a decentralised reservoir position resulted in an efficient system dimension. The closer the reservoir was to the consumer, the smaller the idle capacity, which was the contribution of the onsite reservoir. The critical implementation was based on the flexibility of the phasing of water supply and infrastructure. The flexibility addressed the use of flow rates for a certain period, diversification of water sources, and system configuration that determines the dimensions of the infrastructure and maximising utilisation.
各种形式的供水系统都有其独特的闲置能力。然而,实现长期可持续的供水并不能消除闲置的能力。本文讨论了在不影响长期用水需求的情况下提供有效容量的方法。有效能力的目标是减少闲置的供水能力和供水基础设施。本研究方法回顾了以往的研究成果,并以城市管道供水系统为例进行了深入的研究。评估方法参照了消费者的用水需求模式。用水需求的波动决定了所有供水系统部件的尺寸。研究结果表明,水量分布决定了最小闲置容量,从而指导了高效容量优先区域的需求,并开辟了水库布局选择。在这些优先区域,分散的储层位置产生了有效的系统尺寸。水库离用户越近,闲置容量越小,这是现场水库的贡献。关键的执行是基于供水和基础设施分期的灵活性。这种灵活性解决了一定时期内流量的使用、水源的多样化以及决定基础设施尺寸和最大化利用率的系统配置问题。
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引用次数: 0
Time series forecasting of electrical energy consumption using deep learning algorithm 基于深度学习算法的电能消耗时间序列预测
Q4 Engineering Pub Date : 2023-10-15 DOI: 10.4314/njtd.v20i3.1424
E. O. Edoka, V. K. Abanihi, H. E. Amhenrior, E. M. J. Evbogbai, L. O. Bello, V. Oisamoje
Energy consumption forecasting is an operation of predicting the future energy consumption of electrical systems using previous or historical data. The Long Short-term Memory (LSTM) Model; a deep learning model was used in this project to analyze the Short-term consumption forecast performance. This was carried out by using an energy consumption dataset obtained from the Transmission Company of Nigeria (TCN) Benin City regional 132/33KV transmission station. The dataset were daily load readings recorded in the half-hourly format from August to December 2021. The model was used to demonstrate the feasibility of generating an accurate short-term load forecast for the case study despite the peculiarity and insufficiency of the energy consumption readings. Mean Absolute Percentage Error (MAPE) and Root Mean Square Error (RMSE) are the statistical evaluation metrics used. The approach produces exceptional levels of accuracy, with MAPE of 0.010 and RMSE of 19.759 for a 100 time-step. The findings imply that the LSTM model can make accurate predictions with minimal error, and this Deep learning model may be a useful tool for short-term forecasting demand. This finding serves as a baseline for future research in this field of study and power system planning.
能源消耗预测是利用以往或历史数据预测电力系统未来能源消耗的一种操作。长短期记忆(LSTM)模型本项目采用深度学习模型对短期消费预测性能进行分析。这是通过使用从尼日利亚输电公司(TCN)贝宁市区域132/33KV输变站获得的能源消耗数据集进行的。该数据集是2021年8月至12月以半小时格式记录的每日负载读数。尽管能源消耗数据的特殊性和不足,但该模型证明了为案例研究生成准确的短期负荷预测的可行性。平均绝对百分比误差(MAPE)和均方根误差(RMSE)是使用的统计评估指标。该方法产生了非常高的准确性,100个时间步长的MAPE为0.010,RMSE为19.759。研究结果表明,LSTM模型可以以最小的误差进行准确的预测,并且这种深度学习模型可能是短期预测需求的有用工具。这一发现为未来在这一领域的研究和电力系统规划提供了基础。
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引用次数: 0
Physio-mechanical assessment and process mapping of AlSi10mg/Cu material for automobile application 汽车用AlSi10mg/Cu材料的物理力学评价及工艺制图
Q4 Engineering Pub Date : 2023-10-15 DOI: 10.4314/njtd.v20i3.1492
O. Olaniran, A. A. Adediran, A.A. Akinwande, O.S. Adesina, O.A. Mosadomi
In this study, copper (Cu) particles were used as a replacement for ceramic particles in an AlSi10Mg matrix to lessen the brittleness often associated with ceramic particles when used as fillers in aluminum matrix. AlSi10Mg was combined with 0, 2, 4, and 6% Cu, and microwave sintering was performed at 300, 450, and 600 °C. The composites produced were subjected to physical tests (porosity, density, shrinkage, and relative density), tensile tests (yield and ultimate strength, elastic modulus, and elongation), and microstructure test. Cu particles were observed to be dispersed at 2% and 4% sintering temperatures and clustered at 6% sintering temperatures, according to the microstructural images. The incorporation of 2% and 4% Cu decreased porosity, leading to increased yield, ultimate tensile strength, and elastic modulus respectively. It was noted that 6% Cu addition resulted in strength reduction owing to particle clusters. Sintering temperatures between 300 and 450 ℃ were favorable for all property investigated; nevertheless, temperatures above 600 °C were detrimental to property responses. The proposed process map revealed diverse response values for varying input combination parameters; hence, a Cu dosage of 4% at a sintering temperature of ≤ 450 °C is recommended.
在本研究中,使用铜(Cu)颗粒作为AlSi10Mg基体中陶瓷颗粒的替代品,以减轻陶瓷颗粒作为铝基体填料时常伴随的脆性。将AlSi10Mg与0、2、4、6%的Cu复合,在300、450、600℃下进行微波烧结。所制备的复合材料进行了物理测试(孔隙率、密度、收缩率和相对密度)、拉伸测试(屈服强度和极限强度、弹性模量和伸长率)和微观结构测试。在2%和4%的烧结温度下,Cu颗粒呈分散状态,在6%的烧结温度下,Cu颗粒呈聚集状态。2%和4% Cu的掺入降低了孔隙率,从而分别提高了屈服、极限抗拉强度和弹性模量。结果表明,6% Cu的加入导致了颗粒团簇的形成,从而降低了材料的强度。300 ~ 450℃的烧结温度对各项性能均有利;然而,高于600°C的温度对性能响应是有害的。所提出的过程图揭示了不同输入组合参数的不同响应值;因此,在≤450℃的烧结温度下,推荐使用4%的Cu用量。
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引用次数: 0
期刊
Nigerian Journal of Technological Development
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