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Insight into the oxidation mechanism of low-salt Sichuan-style sausages treated with inclusion complexes of tea-polyphenol/β-cyclodextrin/NaCl and electron beam irradiation using machine learning algorithms. 利用机器学习算法研究茶多酚/β-环糊精/NaCl包合物和电子束辐照处理低盐川菜香肠的氧化机理。
IF 9.8 1区 农林科学 Q1 CHEMISTRY, APPLIED Pub Date : 2026-04-15 Epub Date: 2026-02-18 DOI: 10.1016/j.foodchem.2026.148494
Ya Liu, Jiuhong Du, Wenyi Ran, Lihui Huang, Wenyue Yu, Huan Guo, Yue Xiao, Yanping Wu, Kai Zhong, Yina Huang, Hong Gao

Low-salt sausages are gaining popularity due to health risks from high salt intake. In this study, the effects of electron beam irradiation (EBI) at various doses (0, 3, 6 kGy) combined with inclusion complexes (ICs) of tea-polyphenol/β-cyclodextrin/NaCl on the quality of low-salt Sichuan-style sausages during ambient storage (25 °C) were investigated. Additionally, machine learning algorithms were employed, and the accuracy and R2 of both SVM and Extra Tree models exceeded 99.9%, highlighting the key oxidation biomarkers to establish the oxidation mechanism. ICs demonstrated enhanced antioxidant properties that effectively suppressed excessive oxidation in sausages accelerated by 3 kGy EBI, thereby reducing the oxidative products contributing off flavors while preserving desirable flavor compounds derived from spices, pepper oil and microbial metabolism. These findings offer novel insights into utilizing ICs and 3 kGy EBI for preserving low-salt Sichuan-style sausages while providing valuable information regarding potential volatile biomarker for detecting sausage oxidation levels.

由于高盐摄入对健康的危害,低盐香肠越来越受欢迎。本文研究了不同剂量(0、3、6 kGy)的电子束辐照(EBI)与茶多酚/β-环糊精/NaCl包合物(ICs)对低盐川菜香肠常温(25℃)贮藏质量的影响。此外,采用机器学习算法,SVM和Extra Tree模型的准确率和R2均超过99.9%,突出了关键氧化生物标志物,建立了氧化机制。ic显示出增强的抗氧化性能,有效抑制了香肠中3 kGy EBI加速的过度氧化,从而减少了氧化产物对风味的影响,同时保留了来自香料、辣椒油和微生物代谢的理想风味化合物。这些发现为利用ic和3kgy EBI保存低盐川味香肠提供了新的见解,同时为检测香肠氧化水平提供了潜在的挥发性生物标志物的有价值信息。
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引用次数: 0
Tailoring network structures of water-in-Oleogel emulsions by modulating oil-to-water ratios for the fabrication of croissants: Effects on rheological properties and final product texture 通过调节羊角面包制造中油水比来调整油凝胶中水的网络结构:对流变性能和最终产品质地的影响
IF 9.8 1区 农林科学 Q1 CHEMISTRY, APPLIED Pub Date : 2026-04-15 Epub Date: 2026-02-13 DOI: 10.1016/j.foodchem.2026.148425
Zhaohua Huang , Baozhong Guo , Deming Gong , Guowen Zhang
This study systematically investigated the effects of aqueous-phase content (Φ = 0–0.60) on the microstructure, rheological properties, and stability of carnauba wax-based water-in-oleogel emulsions, and evaluated their potential as shortening substitutes in croissants. Microscopic analyses confirmed the formation of W/O emulsion structures and wax crystal networks. Droplet size increased from 13.32 μm to 37.46 μm as Φ increased. Rheological measurements showed that the emulsion with Φ = 0.30 exhibited the highest elastic modulus and strongest resistance to deformation, with a creep recovery rate of 59.82%. Stability tests further demonstrated that this formulation possessed the greatest storage stability, with an oil-binding capacity of 98.1% after 21 days of storage. When applied to croissants, the Φ = 0.30 emulsion produced products showed no significant differences from the shortening control in appearance or textural attributes.
本研究系统研究了水相含量(Φ = 0-0.60)对巴西棕榈蜡基油凝胶水乳液的微观结构、流变性能和稳定性的影响,并评价了其作为牛角面包起酥油替代品的潜力。显微分析证实了W/O乳液结构和蜡晶网络的形成。随着Φ的增大,液滴粒径由13.32 μm增大到37.46 μm。流变学测试表明,Φ = 0.30的乳液弹性模量最高,抗变形能力最强,蠕变恢复率为59.82%。稳定性试验进一步表明,该配方具有最大的储存稳定性,在储存21 d后,其油结合能力为98.1%。当应用于牛角面包时,Φ = 0.30乳剂生产的产品在外观和质地属性上与起酥油对照组没有显著差异。
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引用次数: 0
Ultrasound-assisted sodium alginate impregnation enhances chlorophyll stability in Undaria pinnatifida 超声辅助海藻酸钠浸渍提高裙带菜叶绿素稳定性
IF 9.8 1区 农林科学 Q1 CHEMISTRY, APPLIED Pub Date : 2026-04-15 Epub Date: 2026-02-12 DOI: 10.1016/j.foodchem.2026.148392
Sainan Guo , Meiran Jin , Xiang Li , Bangfeng Yin , Yu Wang , Xiufang Dong , Hang Qi
Chlorophyll (Chl) degradation during thermal processing significantly compromises the color and nutritional quality of seaweed products. To improve color in Undaria pinnatifida (UP), ultrasound-assisted polysaccharide impregnation was combined with thermal processing. Kinetics at 70–120 °C showed first-order Chl degradation (Ea = 21.84 kJ/mol) and zero-order color change (ΔE). Through single-factor and response surface optimization, Sodium Alginate (SA, 0.25%) performed better than κ-carrageenan (κC), lowering ΔE from 21.73 to 1.78 and increasing Chl retention 103-fold versus the control under optimal conditions (120 min, 120 W). SA also raised antioxidant activity (DPPH scavenging: 81.2% vs. 52.3%). Electronic nose and Gas Chromatography Ion Mobility Spectrometry(GC-IMS)showed SA-ultrasound treatment suppressed off-flavors (W1W signal decreased 64.3%) and enriched pleasant volatiles. This offers a scalable method to simultaneously enhance color, nutrition, and flavor in seaweed products.
在热加工过程中叶绿素(Chl)的降解严重损害了海藻产品的颜色和营养品质。为改善裙带菜(UP)的色泽,采用超声辅助多糖浸渍与热处理相结合的方法。在70-120 °C条件下,Chl的一级降解(Ea = 21.84 kJ/mol)和零级变色(ΔE)。通过单因素和响应面优化,在最优条件(120 min, 120 W)下,0.25%的海藻酸钠(SA, 0.25%)比κ-卡拉胶(κC)的处理效果更好,将ΔE从21.73降低到1.78,使Chl的保留率比对照提高103倍。SA还提高了抗氧化活性(DPPH清除率:81.2% vs. 52.3%)。电子鼻和气相色谱-离子迁移谱分析(GC-IMS)表明,sa -超声处理抑制了异味(W1W信号降低了64.3%),增加了愉悦性挥发物。这提供了一个可扩展的方法,同时提高颜色,营养和风味的海藻产品。
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引用次数: 0
Ultrasound-induced ternary composite system for off-flavor reduction in thermally processed egg white proteins 超声诱导三元复合体系去除热加工蛋白中的异味
IF 9.8 1区 农林科学 Q1 CHEMISTRY, APPLIED Pub Date : 2026-04-15 Epub Date: 2026-02-10 DOI: 10.1016/j.foodchem.2026.148389
Mohamed Salama , Mostafa Gouda , Mahmoud Abou-Elsoud , Xiaomeng Li , Long Sheng , Zhaoxia Cai
Thermal processing of egg white proteins (EWPs) often results in a fishy odor in food products. Here, ternary composite systems (ECX) were developed using caseins (CNs) and xylitol (XY), aided by high-intensity ultrasound (HIU), to mitigate off-flavor formation. Volatile organic compounds (VOCs) were profiled by GC-IMS, while sensory changes were evaluated using an E-nose and E-tongue coupled with multivariate analysis. The results showed that 46 volatiles were detected, including 18 odor-active compounds. Notably, applying HIU to ECX for 10 min after heating significantly reduced trimethylamine (1.21 ± 0.05 a.u.) and 3-butenenitrile (0.77 ± 0.04) compared to the heated EWP control (2.67 ± 0.04 and 2.40 ± 0.09). Meanwhile, esters and aldehydes increased, indicating targeted modulation of key aroma compounds. Protein-polyol interactions improved E-nose and E-tongue profiles from boosted favorable volatiles (e.g., 1-butyl acetate, pentyl formate). In conclusion, HIU-assisted ECX offers a promising strategy for controlling off-flavors in heated high-protein beverages.
蛋清蛋白(EWPs)的热加工通常会导致食品中的鱼腥味。在这里,利用酪蛋白(CNs)和木糖醇(XY),在高强度超声(HIU)的辅助下,开发了三元复合体系(ECX),以减轻异味的形成。通过气相色谱- ims分析挥发性有机化合物(VOCs),同时使用电子鼻和电子舌结合多变量分析评估感官变化。结果表明,共检出46种挥发物,其中18种具有气味活性。值得注意的是,与加热后的EWP对照组(2.67±0.04和2.40±0.09)相比,加热后将HIU应用于ECX 10分钟可显著降低三甲胺(1.21±0.05 a.u)和3-丁腈(0.77±0.04)。与此同时,酯类和醛类化合物增加,表明关键香气化合物受到了定向调节。蛋白质-多元醇相互作用改善了e鼻和e舌的有利挥发物(如乙酸1丁酯、甲酸戊酯)。总之,hiu辅助ECX为控制加热高蛋白饮料中的异味提供了一种很有前途的策略。
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引用次数: 0
Impact of food processing methods and polyphenol interactions on the structural integrity and functionality of wheat gluten proteins 食品加工方法和多酚相互作用对小麦面筋蛋白结构完整性和功能的影响
IF 9.8 1区 农林科学 Q1 CHEMISTRY, APPLIED Pub Date : 2026-04-15 Epub Date: 2026-02-10 DOI: 10.1016/j.foodchem.2026.148371
Ziqi Guo , Bruna Monteiro , Sara da Silva , Daniela Milheiro , Susana Soares , Nuno Mateus , Victor Freitas , Jingren He , Ricardo Dias
The growing market for plant-based foods is accelerating reformulation of wheat gluten-containing products and the need to control gluten functionality through processing. Conventional operations (mixing/kneading, fermentation, drying, baking/steaming) and emerging technologies (thermal treatments, high pressure, microwave, ultrasound, pulsed electric fields, enzymatic and chemical modification) impose mechanical and thermo-oxidative stresses that restructure gluten across length scales. A central mediator is gluten-polyphenol interactions: polyphenols bind non-covalently and may form quinone-mediated covalent adducts under oxidative conditions, thereby reorganizing gluten networks, dough rheology and techno-functional performance. This review synthesizes evidence from real food matrices on how processing parameters tune these interactions and, in turn, influence digestibility, polyphenol bioaccessibility and immunoreactivity via epitope masking/exposure and changes in digestion-derived peptides. Key gaps include inconsistent reporting of processing intensity, limited consideration of matrix effects and polyphenol speciation, and non-standardized immunoassays. Future directions focus on linking processing, structure, interactions and outcomes in standardized workflows.
植物性食品市场的不断增长正在加速小麦含麸质产品的重新配方以及通过加工控制麸质功能的需要。传统操作(混合/揉制、发酵、干燥、烘焙/蒸制)和新兴技术(热处理、高压、微波、超声波、脉冲电场、酶和化学改性)施加机械和热氧化应力,使面筋在长度尺度上重组。一个中心介质是麸质-多酚相互作用:多酚非共价结合,并可能在氧化条件下形成醌介导的共价加合物,从而重组面筋网络、面团流变学和技术功能性能。这篇综述综合了来自真实食物基质的证据,说明加工参数如何调节这些相互作用,进而通过表位掩蔽/暴露和消化衍生肽的变化影响消化率、多酚生物可及性和免疫反应性。主要差距包括处理强度报告不一致,对基质效应和多酚形成的考虑有限,以及非标准化免疫测定。未来的方向将集中在标准化工作流程中的链接处理、结构、交互和结果。
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引用次数: 0
Determination of vitamin K1 (phylloquinone) and K2 (menaquinones 4–10) in a broad range of matrices by HPLC with electrochemical reduction and fluorescence detection 电化学还原-荧光高效液相色谱法测定多种基质中维生素K1(叶绿醌)和K2(萘醌4-10)的含量
IF 9.8 1区 农林科学 Q1 CHEMISTRY, APPLIED Pub Date : 2026-04-15 Epub Date: 2026-02-08 DOI: 10.1016/j.foodchem.2026.148327
Kari Elin Rød, Annbjørg Bøkevoll, Amalie Moxness Reksten, Lisbeth Dahl, Eystein Oveland
An analytical method for simultaneous determination of cis−/trans-forms of vitamin K1 (phylloquinone), β, γ-dihydro K1 and K2 (menaquinones 4–10) was developed and thoroughly validated for applicability to a broad range of food matrices, tissue fluids, and supplements. The extraction procedures and post-liquid-liquid extraction solvents were optimized to maximize recovery that ranged from 80 to 118%. A longer HPLC column and a gradient were applied for improved separation of vitamers as well as cis/trans-forms. External standard curves for the vitamin K forms were efficiently injected by an autosampler (R2 ≥ 0.999). Vitamin K was efficiently reduced to hydroquinone by an online post-column electrochemical reduction cell before fluorescence detection. By analyzing reference materials and spiked samples the average LOQs were approximately 0.1 μg/kg for all vitamers except for 0.2 μg/kg for MK-6 and MK-10. The intra- and inter-day precision, expressed as 2RSD, were typically around 8% for K1 and 10% for the K2 forms.
建立了一种同时测定维生素K1(叶绿醌)、β、γ-二氢K1和K2(甲基萘醌4-10)顺式/反式的分析方法,并对其适用于广泛的食品基质、组织液和补充剂进行了全面验证。优化提取工艺和液-液后萃取溶剂,回收率为80% ~ 118%。采用更长的高效液相色谱柱和梯度,以提高维生素和顺式/反式的分离。自进样器有效地注入了维生素K形式的外部标准曲线(R2 ≥ 0.999)。在荧光检测前,利用在线柱后电化学还原池将维生素K有效还原为对苯二酚。除MK-6和MK-10的loq为0.2 μg/kg外,其余维生素的loq均为0.1 μg/kg。以2RSD表示的日内和日间精度,K1形式通常约为8%,K2形式约为10%。
{"title":"Determination of vitamin K1 (phylloquinone) and K2 (menaquinones 4–10) in a broad range of matrices by HPLC with electrochemical reduction and fluorescence detection","authors":"Kari Elin Rød,&nbsp;Annbjørg Bøkevoll,&nbsp;Amalie Moxness Reksten,&nbsp;Lisbeth Dahl,&nbsp;Eystein Oveland","doi":"10.1016/j.foodchem.2026.148327","DOIUrl":"10.1016/j.foodchem.2026.148327","url":null,"abstract":"<div><div>An analytical method for simultaneous determination of <em>cis</em>−/<em>trans</em>-forms of vitamin K1 (phylloquinone), β, γ-dihydro K1 and K2 (menaquinones 4–10) was developed and thoroughly validated for applicability to a broad range of food matrices, tissue fluids, and supplements. The extraction procedures and post-liquid-liquid extraction solvents were optimized to maximize recovery that ranged from 80 to 118%. A longer HPLC column and a gradient were applied for improved separation of vitamers as well as <em>cis</em>/<em>trans</em>-forms. External standard curves for the vitamin K forms were efficiently injected by an autosampler (R<sup>2</sup> ≥ 0.999). Vitamin K was efficiently reduced to hydroquinone by an online post-column electrochemical reduction cell before fluorescence detection. By analyzing reference materials and spiked samples the average LOQs were approximately 0.1 μg/kg for all vitamers except for 0.2 μg/kg for MK-6 and MK-10. The intra- and inter-day precision, expressed as 2RSD, were typically around 8% for K1 and 10% for the K2 forms.</div></div>","PeriodicalId":318,"journal":{"name":"Food Chemistry","volume":"508 ","pages":"Article 148327"},"PeriodicalIF":9.8,"publicationDate":"2026-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146138845","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent advances in toxicology, extraction, and analytical techniques for benzimidazole veterinary drug residues in food 食品中苯并咪唑兽药残留毒理学、提取及分析技术研究进展
IF 9.8 1区 农林科学 Q1 CHEMISTRY, APPLIED Pub Date : 2026-04-15 Epub Date: 2026-02-08 DOI: 10.1016/j.foodchem.2026.148310
Yingfei Liu , Jun Li , Yixin Ma , Xirui Pei , Xitian Peng , Di Chen
Benzimidazoles are an important class of anthelmintics used to control parasitic infections in food-producing animals. However, these drugs can cause toxicological effects such as embryotoxicity, teratogenicity, polyploidy, and gastrointestinal disturbances. Monitoring benzimidazole residues in animal-derived foods is essential for human health. This review outlines the structural characteristics, classification, and toxicity of benzimidazole veterinary drugs, with a focus on their effects on animals, the environment, and humans. It discusses recent advancements in sample preparation and detection techniques, highlighting novel adsorbents like molecularly imprinted polymers and metal–organic network composites for enhanced selectivity and adsorption capacity. Developments in chromatographic methods, ELISA, and sensor technologies for benzimidazole detection are also reviewed, showcasing improvements in analytical performance, including low detection limits and reliable recoveries in complex food matrices. This work offers insights into future challenges and opportunities in benzimidazole research to guide detection strategies and ensure food safety.
苯并咪唑是一类重要的驱虫药,用于控制食用动物的寄生虫感染。然而,这些药物可引起毒性作用,如胚胎毒性、致畸性、多倍体和胃肠道紊乱。监测动物源性食品中的苯并咪唑残留对人类健康至关重要。本文综述了苯并咪唑兽药的结构特点、分类和毒性,重点介绍了它们对动物、环境和人类的影响。它讨论了样品制备和检测技术的最新进展,重点介绍了新型吸附剂,如分子印迹聚合物和金属有机网络复合材料,以提高选择性和吸附能力。本文还回顾了苯并咪唑检测的色谱方法、ELISA和传感器技术的发展,展示了分析性能的改进,包括在复杂食品基质中的低检出限和可靠的回收率。这项工作为苯并咪唑研究的未来挑战和机遇提供了见解,以指导检测策略和确保食品安全。
{"title":"Recent advances in toxicology, extraction, and analytical techniques for benzimidazole veterinary drug residues in food","authors":"Yingfei Liu ,&nbsp;Jun Li ,&nbsp;Yixin Ma ,&nbsp;Xirui Pei ,&nbsp;Xitian Peng ,&nbsp;Di Chen","doi":"10.1016/j.foodchem.2026.148310","DOIUrl":"10.1016/j.foodchem.2026.148310","url":null,"abstract":"<div><div>Benzimidazoles are an important class of anthelmintics used to control parasitic infections in food-producing animals. However, these drugs can cause toxicological effects such as embryotoxicity, teratogenicity, polyploidy, and gastrointestinal disturbances. Monitoring benzimidazole residues in animal-derived foods is essential for human health. This review outlines the structural characteristics, classification, and toxicity of benzimidazole veterinary drugs, with a focus on their effects on animals, the environment, and humans. It discusses recent advancements in sample preparation and detection techniques, highlighting novel adsorbents like molecularly imprinted polymers and metal–organic network composites for enhanced selectivity and adsorption capacity. Developments in chromatographic methods, ELISA, and sensor technologies for benzimidazole detection are also reviewed, showcasing improvements in analytical performance, including low detection limits and reliable recoveries in complex food matrices. This work offers insights into future challenges and opportunities in benzimidazole research to guide detection strategies and ensure food safety.</div></div>","PeriodicalId":318,"journal":{"name":"Food Chemistry","volume":"508 ","pages":"Article 148310"},"PeriodicalIF":9.8,"publicationDate":"2026-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146138722","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermal processing of tomatoes by air frying and baking: effects on coloured and colourless carotenoid bioaccessibility 番茄的空气油炸和烘烤热处理:对有色和无色类胡萝卜素生物可及性的影响
IF 9.8 1区 农林科学 Q1 CHEMISTRY, APPLIED Pub Date : 2026-04-15 Epub Date: 2026-02-07 DOI: 10.1016/j.foodchem.2026.148311
Ana M. Benítez-González, Carla M. Stinco, Francisco J. Rodríguez-Pulido, Antonio J. Meléndez-Martínez
This study evaluated the effects of air frying (AF) and conventional baking (B) on the concentration and bioaccessible content of carotenoids (CBC) in cherry tomatoes, with a focus on both coloured (lycopene, β-carotene, lutein, ζ-carotene) and colourless (phytoene, phytofluene) compounds. Tomatoes were cooked at 180–200 °C for 2–20 min, and carotenoids were quantified by rapid-resolution liquid chromatography (RRLC). CBC was assessed using the standardized INFOGEST 2.0 in vitro digestion protocol. Both AF and B improved total CBC compared to raw tomatoes. Maximum CBC was achieved at 190 °C/10 min (AF) and 180 °C/20 min (B), with no significant differences. Colourless carotenoids were more thermally stable and bioaccessible than coloured ones. Phytoene and phytofluene retained high CBC even after prolonged cooking, while lycopene was heat-sensitive. AF reduced energy consumption by 78.6% versus baking. These results suggest that AF is a sustainable and efficient method for enhancing carotenoid bioaccessibility in tomatoes.
本研究评估了空气油炸(AF)和传统烘焙(B)对圣果中类胡萝卜素(CBC)的浓度和生物可及性含量的影响,重点关注了有色(番茄红素、β-胡萝卜素、叶黄素、β-胡萝卜素)和无色(植物烯、植物fluene)化合物。番茄在180-200 °C下煮2-20 min,用快速分辨液相色谱法(RRLC)定量类胡萝卜素。采用标准化的INFOGEST 2.0体外消化方案评估CBC。与生番茄相比,AF和B都提高了总CBC。最大CBC达到190 °C/10 min (AF)和180 °C/20 min (B),无显著差异。无色类胡萝卜素的热稳定性和生物可及性优于有色类胡萝卜素。即使经过长时间的烹调,植物烯和植物流感素仍保持较高的CBC,而番茄红素对热敏感。与烘焙相比,AF减少了78.6%的能耗。这些结果表明,AF是一种持续有效的提高番茄类胡萝卜素生物可及性的方法。
{"title":"Thermal processing of tomatoes by air frying and baking: effects on coloured and colourless carotenoid bioaccessibility","authors":"Ana M. Benítez-González,&nbsp;Carla M. Stinco,&nbsp;Francisco J. Rodríguez-Pulido,&nbsp;Antonio J. Meléndez-Martínez","doi":"10.1016/j.foodchem.2026.148311","DOIUrl":"10.1016/j.foodchem.2026.148311","url":null,"abstract":"<div><div>This study evaluated the effects of air frying (AF) and conventional baking (B) on the concentration and bioaccessible content of carotenoids (CBC) in cherry tomatoes, with a focus on both coloured (lycopene, β-carotene, lutein, ζ-carotene) and colourless (phytoene, phytofluene) compounds. Tomatoes were cooked at 180–200 °C for 2–20 min, and carotenoids were quantified by rapid-resolution liquid chromatography (RRLC). CBC was assessed using the standardized INFOGEST 2.0 in vitro digestion protocol. Both AF and B improved total CBC compared to raw tomatoes. Maximum CBC was achieved at 190 °C/10 min (AF) and 180 °C/20 min (B), with no significant differences. Colourless carotenoids were more thermally stable and bioaccessible than coloured ones. Phytoene and phytofluene retained high CBC even after prolonged cooking, while lycopene was heat-sensitive. AF reduced energy consumption by 78.6% versus baking. These results suggest that AF is a sustainable and efficient method for enhancing carotenoid bioaccessibility in tomatoes.</div></div>","PeriodicalId":318,"journal":{"name":"Food Chemistry","volume":"508 ","pages":"Article 148311"},"PeriodicalIF":9.8,"publicationDate":"2026-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146138724","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
MOF-based nanozyme incorporated composite film with prominent antibacterial activity and multiple functionalities for fruit preservation 基于mof的纳米酶具有优异的抗菌活性和多种水果保鲜功能
IF 9.8 1区 农林科学 Q1 CHEMISTRY, APPLIED Pub Date : 2026-04-15 Epub Date: 2026-02-08 DOI: 10.1016/j.foodchem.2026.148360
Yiyi Shi , Mengmeng Pan , Yan Wei , Wanchun Luo , Ying Ma , Liyun Ma , Ming Jiang , Feng Liu , Xu Yu , Li Xu
The food packaging films with tunable multiple functionalities like sustained antibacterial activity, good light blocking and suitable water vapor permeability present significant practical implications for food preservation. Herein, metal-organic framework (MOF) based nanozyme with oxidase-like activity was constructed simply by chelating platinum ions, named as MOF-Pt. MOF-Pt was then incorporated into the chitosan (CS) film to form the CS-MOF-Pt composite film. Compared to the pure CS film, CS-MOF-Pt film possessed extra excellent antibacterial effect and light blocking abilities in addition to enhanced hydrophobicity with water contact angle from 52.19° to 80.38°. When the CS-MOF-Pt film was used to pack blueberries and cherries, the shelf life of these fruits was obviously prolonged by 4–6 days, with good appearance and minimum weight and polyphenol loss, demonstrating the suitability of the CS-MOF-Pt film for fruit preservation. This study provides a new way for constructing antibacterial food packaging film with multiple functionalities.
具有持续抗菌活性、良好的阻光性和适宜的透气性等多种功能的食品包装薄膜在食品保鲜方面具有重要的实际意义。本文通过螯合铂离子构建了具有类似氧化酶活性的金属有机骨架纳米酶,命名为MOF- pt。然后将MOF-Pt掺入壳聚糖(CS)膜中,形成CS-MOF-Pt复合膜。与纯CS膜相比,CS- mof - pt膜具有更优异的抗菌效果和阻光能力,疏水性增强,水接触角从52.19°增加到80.38°。将CS-MOF-Pt薄膜用于蓝莓和樱桃的包装时,这些水果的保质期明显延长了4-6天,外观好,重量和多酚损失最小,表明CS-MOF-Pt薄膜适合水果保鲜。本研究为构建多功能抗菌食品包装膜提供了一条新途径。
{"title":"MOF-based nanozyme incorporated composite film with prominent antibacterial activity and multiple functionalities for fruit preservation","authors":"Yiyi Shi ,&nbsp;Mengmeng Pan ,&nbsp;Yan Wei ,&nbsp;Wanchun Luo ,&nbsp;Ying Ma ,&nbsp;Liyun Ma ,&nbsp;Ming Jiang ,&nbsp;Feng Liu ,&nbsp;Xu Yu ,&nbsp;Li Xu","doi":"10.1016/j.foodchem.2026.148360","DOIUrl":"10.1016/j.foodchem.2026.148360","url":null,"abstract":"<div><div>The food packaging films with tunable multiple functionalities like sustained antibacterial activity, good light blocking and suitable water vapor permeability present significant practical implications for food preservation. Herein, metal-organic framework (MOF) based nanozyme with oxidase-like activity was constructed simply by chelating platinum ions, named as MOF-Pt. MOF-Pt was then incorporated into the chitosan (CS) film to form the CS-MOF-Pt composite film. Compared to the pure CS film, CS-MOF-Pt film possessed extra excellent antibacterial effect and light blocking abilities in addition to enhanced hydrophobicity with water contact angle from 52.19° to 80.38°. When the CS-MOF-Pt film was used to pack blueberries and cherries, the shelf life of these fruits was obviously prolonged by 4–6 days, with good appearance and minimum weight and polyphenol loss, demonstrating the suitability of the CS-MOF-Pt film for fruit preservation. This study provides a new way for constructing antibacterial food packaging film with multiple functionalities.</div></div>","PeriodicalId":318,"journal":{"name":"Food Chemistry","volume":"508 ","pages":"Article 148360"},"PeriodicalIF":9.8,"publicationDate":"2026-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146138768","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of glycosylation, phenolic-binding, pH, and ionic strength on the structural, emulsifying, and antioxidant properties of millet bran gliadin: Mechanism insights 糖基化、酚结合、pH和离子强度对谷糠麦胶蛋白结构、乳化和抗氧化性能的影响:机理见解
IF 9.8 1区 农林科学 Q1 CHEMISTRY, APPLIED Pub Date : 2026-04-15 Epub Date: 2026-02-07 DOI: 10.1016/j.foodchem.2026.148354
Hui Wang , Ling Dang , Xinling Song , Jie Liu , Yajun Zheng , Na Cui , Zhihui Wei , Zihao Zhang , Yixuan Zhang
To improve the emulsification and antioxidant properties of millet bran gliadin, glycosylation and ferulic acid-covalent-binding were utilised in this study. Structural analysis showed that glycosylation and ferulic acid-covalent binding increased the molecular weight, β-sheet content, and crystallinity of the gliadin. Glycosylation increased the water-solubility (from 7.91 to 41.43 g/100 g) at pH 2–10 and improved its emulsifiability and emulsion stability at pH 2–4 (P < 0.05). Ferulic acid-covalent-binding improved hydrophobicity, emulsifiability (50.51 to 105.66 m2/g), emulsion stability (38.94% to 94.87%), ferrous-chelating activity (91.77% to 98.75%), and hydroxyl radical-scavenging activity (32.20% to 65.39%). Glycosylation and ferulic acid-covalent-binding improved the emulsion properties by enhancing interface sorption ability, solubility, or hydrophobicity and increasing zeta potential, centrifugal stability (51.16% to 84.45%), and reducing droplets size in the emulsions. Increasing the pH (4–8) improved solubility, interface sorption ability, zeta potential, emulsifying properties, and centrifugal stability. Alternatively, increasing ionic strength (0.2–0.8 mol/L) decreased the emulsifying properties.
采用糖基化和阿魏酸-共价键结合的方法来改善谷糠麦胶蛋白的乳化和抗氧化性能。结构分析表明,糖基化和阿魏酸-共价结合增加了麦胶蛋白的分子量、β片含量和结晶度。糖基化提高了pH 2-10下的水溶性(从7.91 g/100 g提高到41.43 g/100 g),改善了pH 2-4下的乳化性和乳液稳定性(P < 0.05)。阿魏酸-共价结合提高了疏水性、乳化性(50.51 ~ 105.66 m2/g)、乳液稳定性(38.94% ~ 94.87%)、铁螯合活性(91.77% ~ 98.75%)和羟基自由基清除活性(32.20% ~ 65.39%)。糖基化和阿魏酸-共价结合通过增强界面吸附能力、溶解度或疏水性、提高zeta电位、离心稳定性(51.16% ~ 84.45%)和减小乳状液中的液滴大小来改善乳状液的性能。增加pH(4-8)可改善溶解度、界面吸附能力、zeta电位、乳化性能和离心稳定性。增加离子强度(0.2 ~ 0.8 mol/L)会降低乳化性能。
{"title":"Effects of glycosylation, phenolic-binding, pH, and ionic strength on the structural, emulsifying, and antioxidant properties of millet bran gliadin: Mechanism insights","authors":"Hui Wang ,&nbsp;Ling Dang ,&nbsp;Xinling Song ,&nbsp;Jie Liu ,&nbsp;Yajun Zheng ,&nbsp;Na Cui ,&nbsp;Zhihui Wei ,&nbsp;Zihao Zhang ,&nbsp;Yixuan Zhang","doi":"10.1016/j.foodchem.2026.148354","DOIUrl":"10.1016/j.foodchem.2026.148354","url":null,"abstract":"<div><div>To improve the emulsification and antioxidant properties of millet bran gliadin, glycosylation and ferulic acid-covalent-binding were utilised in this study. Structural analysis showed that glycosylation and ferulic acid-covalent binding increased the molecular weight, β-sheet content, and crystallinity of the gliadin. Glycosylation increased the water-solubility (from 7.91 to 41.43 g/100 g) at pH 2–10 and improved its emulsifiability and emulsion stability at pH 2–4 (<em>P</em> &lt; 0.05). Ferulic acid-covalent-binding improved hydrophobicity, emulsifiability (50.51 to 105.66 m<sup>2</sup>/g), emulsion stability (38.94% to 94.87%), ferrous-chelating activity (91.77% to 98.75%), and hydroxyl radical-scavenging activity (32.20% to 65.39%). Glycosylation and ferulic acid-covalent-binding improved the emulsion properties by enhancing interface sorption ability, solubility, or hydrophobicity and increasing zeta potential, centrifugal stability (51.16% to 84.45%), and reducing droplets size in the emulsions. Increasing the pH (4–8) improved solubility, interface sorption ability, zeta potential, emulsifying properties, and centrifugal stability. Alternatively, increasing ionic strength (0.2–0.8 mol/L) decreased the emulsifying properties.</div></div>","PeriodicalId":318,"journal":{"name":"Food Chemistry","volume":"508 ","pages":"Article 148354"},"PeriodicalIF":9.8,"publicationDate":"2026-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146138783","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Food Chemistry
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