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Rare earth elements in Fe-Mn nodules from southern Baltic Sea – a preliminary study 波罗的海南部铁锰结核中的稀土元素初步研究
Pub Date : 2018-11-20 DOI: 10.5604/01.3001.0012.7118
K. Szamałek, S. Uścinowicz, Karol Zglinicki
Between 1976–1990, the Polish Geological Institute performed geological works in the Polish Maritime Areas. During these works, 260 occurrences of concretions were recorded from 7,500 sampled sites. In 1980, the threshold that separates the Bornholm Basin from the Słupsk Furrow was mapped. Numerous Fe-Mn nodules on the seabed were found in that area. The results of detailed analyses of nodule samples collected from four sites are presented in this paper. Analyzed nodules represent discoidal D, irregular I, and transitional D-I types. The nodules are characterized by varied chemical composition of main oxides (Fe, Mn). The maximum Fe2O3 content is 26.63% and MnO 23.18%. Total average amount of REE + Y in the samples is approximately 165.11 ppm, ΣLREE 145.72 ppm and ΣHREE 19.39 ppm. The LREE content is enriched in comparison to HREE. The majority of nodules consist of Fe-Mn oxy-hydroxide minerals with very low crystallinity (practically amorphous phases). The main confirmed Mn-phases are birnessite and todorokite. Other main components of the nodules are: detrital quartz, albite, microcline, glauconite and muscovite, clinochlore, and clay minerals: illite and chlorite. The rate of growth of Fe-Mn nodules has been estimated using a cobalt chronometer. The nodule growth rate ranges from 0.006 to 0.134 mm/yr –1. Based on the Fe, Mn and (Cu + Co + Ni) contents, the origin of studied nodules is determined as hydrogenetic, while using REE (Cesn/Cesn · vs. Nd) – as diagenetic.
1976年至1990年期间,波兰地质研究所在波兰海域进行了地质工作。在这些工程中,在7500个取样地点录得260宗结土个案。1980年,将博恩霍尔姆盆地与Słupsk沟分隔开来的界线被绘制出来。在该地区海底发现了大量铁锰结核。本文介绍了从四个地点采集的结核样本的详细分析结果。所分析的结节包括盘状D型、不规则I型和过渡性D-I型。结核的特征是主要氧化物(铁、锰)的化学成分不同。Fe2O3含量最高为26.63%,MnO含量最高为23.18%。样品中REE + Y的总平均含量分别为165.11 ppm、ΣLREE 145.72 ppm和ΣHREE 19.39 ppm。轻稀土(LREE)含量明显高于重稀土(HREE)。大多数结核是由结晶度很低的Fe-Mn氧-氢氧化物矿物组成(几乎是无定形相)。确定的锰相主要为硼云母矿和钙云母矿。结核的其他主要成分有:碎屑石英、钠长石、微斜长石、海绿石和白云母、斜长石以及粘土矿物:伊利石和绿泥石。铁锰结核的生长速度已经用钴原子钟来估计。结核生长速率为0.006 ~ 0.134 mm/yr -1。根据Fe、Mn和(Cu + Co + Ni)含量,确定结核成因为氢成因,REE (Cesn/Cesn·vs. Nd) -为成岩成因。
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引用次数: 7
Preliminary characteristics of rare earth elements and other trace elements in fine-grained deposits from the Triassic-Jurassic transition in the former Mid-Polish Trough 原中波兰海槽三叠系—侏罗系过渡期细粒矿床稀土元素及其他微量元素初步特征
Pub Date : 2018-11-20 DOI: 10.5604/01.3001.0012.6916
P. Brański
Fine-grained siliciclastic rocks from the Triassic-Jurassic transition (Rhaetian–Hettangian) in the former Mid-Polish Trough were the subject of the geochemical study at the Polish Geological Institute – National Research Institute in Warsaw. Ninety-four samples of claystones and mudstones from six archived drill cores were analysed by ICP-MS and XRF for rare earth elements (REE) and other trace elements. The results indicate that the sources of most of the claystones and mudstones were sedimentary rocks of the upper continental crust of old cratonic areas, where the protolith had a moderately felsic character. Weathering and recycling processes modified the original chemical composition to some extent. However, during Rhaetian and early Hettangian, some geochemical data in the south-eastern segment of the MPT suggest significant input from a mafic volcanic protolith. Moreover, a clear enrichment in rare-earth elements was observed in few samples, caused by admixtures of accessory minerals (being a main carrier of REE). Nevertheless, based on currently obtained data, the Rhaetian–Hettangian concentrations of REE (and other trace elements) in the MPT are low and they are of scientific indicative significance, not of raw material importance.
位于华沙的波兰地质研究所-国家研究所对前波兰中海槽三叠纪-侏罗纪过渡时期(Rhaetian-Hettangian)的细粒硅屑岩进行了地球化学研究。采用ICP-MS和XRF分析了6个存档岩心的94个粘土岩和泥岩样品的稀土元素和其他微量元素。结果表明,大部分泥岩和粘土岩的来源为古克拉通区上陆壳沉积岩,其原岩具有中等长英质特征。风化和再循环过程在一定程度上改变了原有的化学成分。然而,在雷蒂亚期和河塘期早期,MPT东南段的一些地球化学数据表明,基性火山原岩的输入非常重要。此外,少数样品中稀土元素明显富集,这是由副矿物(稀土元素的主要载体)的掺和引起的。然而,根据目前获得的数据,MPT中Rhaetian-Hettangian的REE(和其他微量元素)浓度较低,具有科学指示意义,而不是原料重要性。
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引用次数: 0
THE USE OF A NATURAL RESOURCE IN THE INTERIOR DESIGN OF THE MAIN BUILDING OF THE PEDAGOGICAL UNIVERSITY OF CRACOW 在克拉科夫师范大学主楼的室内设计中使用自然资源
Pub Date : 2018-11-20 DOI: 10.5604/01.3001.0012.6878
A. Wolska, Agnieszka Ciurej, Szymon Kowalik
The paper presents an interesting decorative flooring solution from 1973 on the ground and first floors of the main building of the Pedagogical University of Cracow, named after the Commission of National Education. This flooring is composed of irregular, variably coloured natural stone slabs: the so-called Holy Cross Mountains „marbles”. They represent several rock types from limestone quarries near Chęciny, including mainly Bolechowice, but also Szewce, Łabędziów and Jaźwica. These rocks are traditionally called marbles. However, in fact, petrographically, they are not metamorphic rocks, but strongly lithified and massive, partially crystallized limestones with numerous fossils. They are of Paleozoic age: Middle and Upper Devonian. The type of flooring composed of irregular panels of different sizes and colours is currently rarely used in interior design despite giving an aesthetically pleasing mosaic effect with an interesting pattern. The flooring made of assorted Holy Cross Mountains “marbles” can have a great educational value and great geotouristic significance. Selected and described rocks of different lithological types can be used to create a geotouristic educational path that will be helpful in teaching of subjects related to Earth sciences (e.g. geology, paleontology, rock materials).
本文介绍了一个有趣的装饰地板解决方案,从1973年开始,在克拉科夫师范大学主楼的地面和一楼,以国家教育委员会命名。地板由不规则的、颜色各异的天然石板组成:所谓的圣十字山“大理石”。它们代表了Chęciny附近石灰岩采石场的几种岩石类型,主要包括Bolechowice,但也包括Szewce, Łabędziów和Jaźwica。这些岩石传统上被称为弹珠。然而,实际上,从岩石学上看,它们不是变质岩,而是强烈的岩化和块状,部分结晶的石灰石,有许多化石。它们属于古生代:中、上泥盆世。这种由不同尺寸和颜色的不规则面板组成的地板目前很少用于室内设计,尽管它具有有趣的图案,具有令人愉悦的马赛克效果。由各种圣十字山“大理石”制成的地板具有很高的教育价值和地理旅游意义。选择和描述不同岩性类型的岩石可用于创建地理旅游教育路径,这将有助于教授与地球科学相关的学科(例如地质学,古生物学,岩石材料)。
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引用次数: 1
The impact of lithological variability of reservoir rocks on the quality parameters of the Cu-Ag deposit, Lubin–Głogów Copper District (LGCD) Lubin-Głogów铜区储层岩性变异对铜银矿质量参数的影响
Pub Date : 2018-11-20 DOI: 10.5604/01.3001.0012.6919
W. Kaczmarek, M. Wasilewska-Błaszczyk, M. Dudek
The article discusses the lithological and facies development of the copper ore deposit in the Fore-Sudetic Monocline in the so-called depression at the top of the Weissliegend. The lithological variability and quality parameters of the deposit in the exploitation field located between the Central and Northern elevations of Rudna, where the deposit profile is described as “typical”, i.e. the Cu-Ag mineralization occurs in all three basic lithological types of copper ore, is analyzed. The lithological variability of ores in depression zones is the reason why the degree of mineralization and the parameters of the economic deposit are highly variable. The authors focused on the mutual relationships between the neighbouring lithological units and the development of the balance deposit. To illustrate the variability of deposit parameters closely related to the lithological and facies development of the host rocks, three-dimensional lithological and geochemical models and isoline maps of the thickness of individual specific copper ore types were made using geostatistical methods and based on field observations and sampling of the deposit.
本文讨论了前苏东单斜中所谓的韦斯里格顶坳陷的铜矿床的岩性和相发育。本文分析了位于鲁德纳中部和北部海拔之间的开采矿区的矿床的岩性变异性和质量参数,该矿区的矿床剖面被描述为“典型”,即铜银矿化发生在铜矿石的所有三种基本岩性类型中。凹陷带矿石的岩性变异性是成矿程度和经济矿床参数变化很大的原因。重点讨论了邻近岩性单元与平衡矿床发育之间的相互关系。为了说明与寄主岩石的岩性和相发育密切相关的矿床参数的变异性,利用地质统计学方法,在实地观察和矿床取样的基础上,绘制了个别特定铜矿石类型的三维岩性和地球化学模型和厚度等值线图。
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引用次数: 2
THE ASSESSMENT OF USEFULNESS OF LIMESTONES FROM THE KLESZCZÓW GRABEN (BEŁCHATÓW LIGNITE DEPOSIT – SZCZERCÓW FIELD) AS POTENTIAL SO2 SORBENTS IN THE POWER INDUSTRY – PROBLEMS OF GEOLOGICAL DOCUMENTING 评估kleszczÓw地堑(beŁchatÓw褐煤矿床- szczercÓw油田)石灰石在电力工业中作为潜在二氧化硫吸附剂的用途-地质文献问题
Pub Date : 2018-11-20 DOI: 10.5604/01.3001.0012.6876
E. Hycnar, J. Mucha, T. Ratajczak, M. Wasilewska-Błaszczyk
Jurassic limestones of the Kleszczów Graben are among the most important accompanying raw materials in the Bełchatów lignite deposit. In recent years, there has been a need to recognize their suitability as SO2 sorbents for use in the energy industry. The limestones are characterized by high lithological variability. They show both high hardness and compactness, and are weakly concise or even silty. At the top parts, they are subjected to karst processes. The lower parts are affected by secondary mineralization processes, among which the silicification process is most advanced. The effects of other transformation processes, such as compaction, cementation, dissolution and recrystallization of calcite are also visible. These processes contributed to a significant diversification of the mineral and chemical composition of limestone, and differentiation of physico-chemical and physical-mechanical parameters responsible for assessing the suitability for their commercial use as a raw material for the production of SO2 sorbents. Other problems associated with documenting the limestones in the Bełchatów deposit are related to their lesser importance compared to the main mineral. Its degree of exploration is low, characterized by a lower density of exploratory boreholes and significantly longer average lengths of samples collected from drill cores. At the present stage of the accompanying mineral exploration, only a preliminary estimation of limestone resources as potential SO2 sorbents is possible. The precise estimation will be possible after constructing a 3D model of criterion parameters and developing an extraction scenario.
Kleszczów地堑侏罗系灰岩是Bełchatów褐煤矿床最重要的伴生原料之一。近年来,有必要认识到它们作为SO2吸附剂在能源工业中的适用性。石灰石的特点是岩性变异性高。它们显示出高硬度和致密性,并且是弱简洁甚至粉质。在顶部,它们遭受岩溶作用。下部受二次矿化作用影响,其中硅化作用最超前。方解石的压实、胶结、溶解和再结晶等其他转变过程的影响也很明显。这些过程促进了石灰石矿物和化学成分的显著多样化,以及物理-化学和物理-机械参数的分化,这些参数负责评估石灰石作为生产二氧化硫吸附剂原料的商业用途的适用性。与记录Bełchatów矿床中的石灰石有关的其他问题是,与主要矿物相比,它们的重要性较低。它的勘探程度较低,其特点是勘探钻孔密度较低,从岩心中采集的样品平均长度明显较长。在目前伴随的矿产勘探阶段,只能初步估计石灰石资源作为潜在的二氧化硫吸附剂是可能的。在建立准则参数的三维模型和开发提取方案后,将有可能进行精确的估计。
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引用次数: 2
Problems of social acceptance of mining activities and ways of minimizing them in the EU countries 欧盟国家社会对采矿活动的接受问题及减少采矿活动的方法
Pub Date : 2018-11-20 DOI: 10.5604/01.3001.0012.7117
B. Radwanek-Bąk
Social acceptance for mining activity is one of the important elements determining its success. In addition to formal and legal conditions related to the nature of protection and spatial planning, it is one of the major barriers that limit or even hold back this activity. Over the last several years, a constant increase in such unacceptance can be observed in both Poland and most of the European countries, although the degree of occurrence of this phenomenon is diverse. It is confirmed by surveys carried out by the author as part of the already completed EU Minerals4EU project. The paper discusses the results of these studies and attempts to explain the reasons for the negative attitude of societies to mining activity. The activities undertaken to change the attitude are also presented, in particular the Social Impact Assessment (SIA). The objectives of the assessment are similar to the purposes of generally applicable Environmental Impact Assessments: identification of all possible limitations of planned exploitation, and their evaluation and minimization, necessary to obtain a favourable environmental decision, and, in the case of the SIA, to obtain social acceptance for the planned mining investment. In some EU countries, e.g. Denmark and Greenland, the development of a separate SIA report is a compulsory element of concession proceedings. The paper discusses the adopted formal scope of this document and the advantages of such a solution, enabling the anticipated operation of the future investor to achieve the planned goal.
社会对采矿活动的接受程度是决定其成功的重要因素之一。除了与保护和空间规划的性质有关的正式和法律条件外,这也是限制甚至阻碍这一活动的主要障碍之一。在过去几年中,在波兰和大多数欧洲国家,可以观察到这种不被接受的情况不断增加,尽管这种现象发生的程度各不相同。作为已经完成的EU Minerals4EU项目的一部分,作者进行的调查证实了这一点。本文讨论了这些研究的结果,并试图解释社会对采矿活动持消极态度的原因。还介绍了为改变态度而开展的活动,特别是社会影响评估。评估的目标与一般适用的环境影响评估的目的相似:确定计划开采的所有可能的限制,并评价和尽量减少这些限制,这是获得有利的环境决定所必需的,就新环境评估而言,是获得社会对计划采矿投资的接受所必需的。在一些欧盟国家,例如丹麦和格陵兰,制定单独的SIA报告是特许权程序的强制性内容。本文讨论了本文件采用的形式范围以及该解决方案的优势,使未来投资者的预期操作能够实现计划目标。
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引用次数: 2
Geological modelling with pseudosamples on example of Głogów Głęboki-Przemysłowy Cu-Ag ore deposit 以Głogów Głęboki-Przemysłowy铜银矿床为例的伪样品地质模拟
Pub Date : 2018-11-20 DOI: 10.5604/01.3001.0012.7115
M. Twardowski, P. Hoffmann, D. Mróz
The 3D pseudosampling modelling method has been applied to reconstruct the occurrence of Weissliegendes elevations in Głogów Głęboki-Przemysłowy mining area of Cu-Ag ore deposit. Two different approaches have been utilized and compared: (1) Basic model created from surface drillholes samples, and (2) modified by introducing the pseudosamples for better reflection of Weissliegendes elevation outlines. Comparison between two models was shown in the form of maps and ore resources estimation.
应用三维伪采样建模方法重建了Głogów Głęboki-Przemysłowy铜银矿区Weissliegendes高程的产状。采用了两种不同的方法并进行了比较:(1)利用地表钻孔样本建立基本模型;(2)通过引入伪样本对模型进行修改,以更好地反映Weissliegendes高差轮廓。以地图和矿产资源估算的形式对两种模型进行了比较。
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引用次数: 0
Characteristic of coaly shale aggregate and its application for the road construction 煤页岩骨料的特性及其在道路建设中的应用
Pub Date : 2018-11-20 DOI: 10.5604/01.3001.0012.7101
A. Duszyński, W. Jasiński, A. Pryga-Szulc
The waste obtained directly from exploitation of coal and/or from storage is the subject of the paper. The purpose is to describe the properties such material called in this paper the coaly shale aggregate and their applicability as the sterling material for the road construction. Usefulness of such material is normalized by the National Technical Assessment standards.
直接从煤炭开采和/或储存中获得的废物是本文的主题。目的是描述本文所称的煤页岩骨料的性能及其作为道路施工标准材料的适用性。这些材料的使用符合国家技术评价标准。
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引用次数: 2
Recent developments in Raw Materials Policy in the European Union: perspective of EuroGeoSurveys as a data supplier 欧盟原材料政策的最新发展:欧洲地质调查局作为数据供应商的观点
Pub Date : 2018-11-20 DOI: 10.5604/01.3001.0012.6902
J. Vidovič, S. Šolar
Mineral Raw Materials are of strategic importance for Europe’s economic growth and societal development. The European Commission addressed this challenge through the Raw Materials Initiative (RMI), stakeholders’ platform, the European Innovation Platform on Raw Materials (EIP-RM), and Horizon 2020 funding. The aim is to ensure security and sustainability of mineral raw materials supply from EU domestic and other primary and secondary sources and management of competing uses of the European surface and subsurface. The sustainable supply of raw materials from European sources requires an improved knowledge base of raw materials within the EU, namely the European Union Raw Materials Knowledge Base (EURMKB), where EuroGeoSurveys, the Geological Surveys of Europe, is one of the key data providers. Current European Commission policies have the same objectives that will be fully implemented in near future. The Mobility Package and its implementation activities (such as European Battery Alliance) and tools (including Horizon Europe) will strengthen the raw materials position in an overall EU policy setting.
矿物原料对欧洲经济增长和社会发展具有重要的战略意义。欧盟委员会通过原材料倡议(RMI)、利益相关者平台、欧洲原材料创新平台(EIP-RM)和地平线2020基金来应对这一挑战。其目的是确保来自欧盟国内和其他主要和次要来源的矿物原料供应的安全和可持续性,并管理欧洲地表和地下的竞争用途。欧洲来源的原材料的可持续供应需要在欧盟内部改进原材料知识库,即欧盟原材料知识库(EURMKB),其中欧洲地质调查是主要数据提供者之一。欧盟委员会目前的政策具有相同的目标,这些目标将在不久的将来得到全面实施。移动包及其实施活动(如欧洲电池联盟)和工具(包括地平线欧洲)将加强原材料在欧盟整体政策设置中的地位。
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引用次数: 4
Practical aspects of estimating the quantitative mineral composition of copper-bearing sedimentary rocks on the basis a calculation procedure analogical to the CIPW norm 在模拟CIPW标准的基础上定量估算含铜沉积岩矿物组成的实际问题
Pub Date : 2018-11-20 DOI: 10.5604/01.3001.0012.6912
I. Nowak
The paper presents a possibility of estimating the content of ore minerals based on chemical analyses of copper-bearing sedimentary rock samples from the North-Sudetic Synclinorium and from the Fore-Sudetic Monocline using a calculation procedure similar to the CIPW norm. The mineralogical data was obtained by means of an optical microscope and an electron microprobe (EPMA). The quantitative composition of gangue minerals was determined using the XRD method, and of the ores by the computer microscopic image analysis (CAMI). The actual set of gangue and ore minerals, their chemical composition, and proportions of copper ores were determined in the samples. Elements that are the main components of identified minerals were selected. The calculation procedure has been developed in accordance with the mineralogical and chemical data. The set of ore minerals determined based on the calculation of the weight ratios is consistent with the microscopic observations of copper-bearing rocks. The obtained ore contents are similar or slightly higher in poorly mineralized samples and slightly lower in highly mineralized samples in comparison to the results of the CAMI method. These differences may be due to different methods of averaging samples (powdered, averaged rock samples, and a thin section). The calculated ore proportions are consistent with those obtained by the CAMI method. The study calculations of the quantitative ore mineral composition using the calculation procedure analogical to the CIPW norm can be used to a preliminary approximation of the quantity of ores in geological prospection and exploration studies, but they require testing of more variants of the element partition between the set of minerals.
本文提出了一种基于北苏东向斜和前苏东单斜含铜沉积岩样品的化学分析,利用类似CIPW规范的计算方法来估计矿石矿物含量的可能性。通过光学显微镜和电子探针(EPMA)获得矿物学数据。采用x射线衍射(XRD)和计算机显微图像分析(CAMI)对矿石进行了定量分析。在样品中测定了脉石和矿石矿物的实际组合、化学成分和铜矿石的比例。选取已鉴定矿物的主要成分元素。根据矿物学和化学资料制定了计算程序。根据重量比计算确定的矿石矿物组与含铜岩石的微观观察结果一致。与CAMI方法的结果相比,获得的矿石含量在低矿化样品中相似或略高,而在高矿化样品中略低。这些差异可能是由于不同的平均方法(粉末、平均岩石样品和薄片)。计算的矿石比例与CAMI法计算的结果一致。利用类似CIPW规范的计算程序对定量矿石矿物组成进行研究计算,可用于地质找矿和勘查研究中矿石数量的初步近似,但需要对矿石组间元素划分的更多变体进行测试。
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引用次数: 0
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Biuletyn Państwowego Instytutu Geologicznego
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