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Experimental Evaluation of Carbon Nanotubes for High-Stiffness Damping Augmentation in Carbon/Epoxy Composites 碳纳米管对碳/环氧复合材料高刚度阻尼增强的实验评价
Pub Date : 2018-11-07 DOI: 10.12783/ASC33/26036
Jeffrey J. Kim, C. Bakis, E. Smith
Carbon nanotubes (CNTs) are promising materials for increasing the damping of fiber reinforced composites on account of a hypothesized stick-slip dissipation mechanism. The current investigation aims to increase the damping of a carbon/epoxy composites by adding different types and amounts of CNTs to the interlayer regions. [90] , [0] and [0/±45] carbon/epoxy laminates were manufactured using various types and concentrations of CNTs and surfactant. Dynamic behavior was characterized in terms of the storage and loss moduli and loss factor under tensile cyclic loading. For [0] and [0/±45] laminates, the maximum increases in loss factor and loss modulus of roughly 400-600% were obtained with 10 volume percent CNT yarns aligned in the 0-deg. loading direction. The storage modulus of these laminates was not appreciably affected by the CNT yarns. Aligned CNT yarns provided higher damping than equivalent amounts of unaligned CNT buckypapers. In a series of tests on 0-deg. laminates with and without aligned CNT yarns, damping increased with strain amplitude but not with mean strain, while damping in the baseline laminate was nearly invariant with strain. This series of tests also detected no lower threshold of strain for the onset of slip by CNT and a 10x reduction in the rate of increase of damping with strain amplitude when the amplitude exceeded 190 μ.
碳纳米管(CNTs)是一种很有前途的材料,可以增加纤维增强复合材料的阻尼,因为它具有假设的粘滑耗散机制。目前的研究旨在通过在层间区域添加不同类型和数量的碳纳米管来增加碳/环氧复合材料的阻尼。使用不同类型和浓度的碳纳米管和表面活性剂制备了[90]、[0]和[0/±45]碳/环氧复合材料。在拉伸循环荷载作用下,用储存量、损耗模量和损耗因子来表征其动力特性。对于[0]和[0/±45]层压板,当10根体积百分比的碳纳米管纱线在0度方向排列时,损耗因子和损耗模量的最大增幅约为400-600%。加载方向。这些层压板的存储模量不受碳纳米管纱线的明显影响。对齐的碳纳米管纱线比等量的未对齐碳纳米管纸提供更高的阻尼。在0度的一系列测试中。有碳纳米管纱线和没有对准碳纳米管纱线的层合板,阻尼随应变幅值而增加,但不随平均应变而增加,而基线层合板的阻尼随应变几乎不变。该系列试验还发现,碳纳米管滑移发生的应变阈值不低,当应变幅值超过190 μ 时,阻尼随应变幅值的增长率降低了10倍。
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引用次数: 1
Changes in Micro-Phase Separation of Di-Block Copolymer Melts Induced by a Circle Fiber 圆纤维诱导双嵌段共聚物熔体微相分离的变化
Pub Date : 2018-11-07 DOI: 10.12783/asc33/25966
Y. Oya, Nao Umemoto, T. Okabe
Using self-consistent field theory (SCFT), we computed phase-separated structure of di-block copolymer to apply this structure for the matrix of a composite. For this purpose, we combined SCFT with finite element method, which enables us to consider the effect of a smoothed boundary of a carbon fiber on the phase separation. In the result, a circularly shaped carbon fiber disturbs the phase separated structure: changes from lamella phase to cylinder phase are induced by a circle fiber and this induction is emphasized with increasing the fiber radius. Furthermore, we found that four parameters, block-ratio ( f ), polymer length ( N ) and Flory-Huggins parameter (  ), volume fraction of fiber (VM) are independently important to determine the equilibrium phase structures in a matrix penetrated by a circle fiber, even if only f and N are essential in the bulk phase.
利用自洽场理论计算了二嵌段共聚物的相分离结构,并将该结构应用于复合材料的基体。为此,我们将SCFT与有限元方法相结合,使我们能够考虑碳纤维光滑边界对相分离的影响。结果表明,圆形碳纤维干扰了相分离结构,圆形纤维诱导了从片层相到圆柱相的变化,并且随着纤维半径的增大,这种诱导作用更加明显。此外,我们发现四个参数,嵌段比(f),聚合物长度(N)和Flory-Huggins参数(),纤维体积分数(VM)对于确定圆形纤维穿透的基体中的平衡相结构是独立重要的,即使只有f和N在体相中是必不可少的。
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引用次数: 0
Nanocomposites: Manufacturing, Microstructural Characterization and Mechanical Testing 纳米复合材料:制造、微观结构表征和力学测试
Pub Date : 2018-11-07 DOI: 10.12783/ASC33/26060
Petar Dotchev, Seyed Hamid Reza Sanei, E. Steinmetz, Jason J. Williams
Carbon Nanotubes (CNT) offer exceptional thermal, electrical and mechanical properties. While an increase in thermal and electrical conductivity can be readily achieved by addition of CNT to a polymer base, the subsequent effect on mechanical properties must be investigated. In this study, nanocomposite samples were manufactured using injection molding process. Multiwall Carbon Nanotube (MWCNT) masterbatch with 15 wt.% MWCNT concentrations were diluted with PA 6/6 pellets to create five different CNT concentration ranging from 3 wt.% in 3 wt.% increments. The neat polymer sample was also manufactured as a control specimen. Mechanical properties such as Young’s modulus, Tensile strength and elongations were determined to see the effect of CNT content on overall properties. Scanning Electron Microscopy (SEM) images were used to evaluate the uniform distribution of CNT in the polymer phase. The results showed that the stiffness increased as the CNT content increased, however, the increase in strength reached a threshold value around 6 wt.% beyond which the strength decreased. It was observed that the elongation decreased significantly by addition of CNT into the polymer. The elongation dropped from an average of 190% for the neat sample to 5% for 15 wt.% CNT content sample. Such decrease in elongation might render the polymer unsuitable for the application it has been designed for. The findings of this study show that improving thermal and electrical properties of polymers does not come without a sacrifice on mechanical properties.
碳纳米管(CNT)具有优异的热学、电学和机械性能。虽然通过在聚合物基体中添加碳纳米管可以很容易地提高导热性和导电性,但必须研究其对机械性能的后续影响。本研究采用注射成型工艺制备纳米复合材料样品。将MWCNT浓度为15 wt.%的多壁碳纳米管(MWCNT)母粒用PA 6/6颗粒稀释,以产生5种不同的碳纳米管浓度,从3 wt.%到3 wt.%的增量。制备了整齐的聚合物样品作为对照样品。机械性能,如杨氏模量,拉伸强度和伸长率被确定,看看碳纳米管含量对整体性能的影响。利用扫描电镜(SEM)图像评价碳纳米管在聚合物相中的均匀分布。结果表明,随着碳纳米管含量的增加,刚度增加,但强度增加达到6 wt.%左右的阈值,超过该阈值强度下降。结果表明,碳纳米管的加入显著降低了聚合物的伸长率。伸长率从纯碳纳米管样品的平均190%下降到15 wt.%碳纳米管含量样品的5%。这种伸长率的降低可能使聚合物不适合其设计的应用。这项研究的结果表明,提高聚合物的热学和电学性能不会不牺牲机械性能。
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引用次数: 4
3D Printed Continuous Fibre Composites: Exploiting Design Flexibility to Achieve Application Specific Properties 3D打印连续纤维复合材料:开发设计灵活性,以实现特定的应用性能
Pub Date : 2018-11-07 DOI: 10.12783/ASC33/26148
M. Joosten, Matt Alizzi, C. Wiles, R. Varley
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引用次数: 0
Additive Processing of Sacrificial Polymers to Enable Pressure Sensing in Structural Composites 牺牲聚合物的增材加工以实现结构复合材料的压力传感
Pub Date : 2018-11-07 DOI: 10.12783/ASC33/26141
G. Tandon, A. Abbott, T. Gibson, J. Baur
Additive manufacturing of polymers and their composites is an area of increasing academic and industrial interest due to the ability to agilely create complex prototype structures. While efforts continue to attempt to directly print more structural composite element, an alternative approach is to use additive printing with traditional composite processing methods to enable structural multifunctional composite concepts. Within this paper we demonstrate the application of fused deposition printing of sacrificial polymer material to enable embedded microvascular channels within structural composites to enable pressure sensing of morphing structures and for installing pressure tappings for studying hypersonic fluid-structure interactions. Overall, this processing methodology enables many type of microvascular composites whose channels can be computer designed, additively printed, integrated with traditional laminate processing, and effectively evacuated to enable a variety of multifunctional concepts.
聚合物及其复合材料的增材制造是学术界和工业界越来越感兴趣的领域,因为它能够灵活地创建复杂的原型结构。在继续尝试直接打印更多结构复合材料元素的同时,另一种方法是使用传统复合材料加工方法的增材打印来实现结构多功能复合材料概念。在本文中,我们展示了牺牲聚合物材料的熔融沉积打印的应用,以实现在结构复合材料内嵌入微血管通道,从而实现变形结构的压力传感,并安装用于研究高超声速流体-结构相互作用的压力接头。总的来说,这种加工方法使许多类型的微血管复合材料成为可能,这些复合材料的通道可以通过计算机设计、增材打印、与传统的层压板加工相结合,并有效地抽真空,从而实现各种多功能概念。
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引用次数: 2
Optimization of Carbon Fiber Surfaces for Reinforcement in Advanced Polymer Composites 先进聚合物复合材料增强用碳纤维表面优化研究
Pub Date : 2018-11-07 DOI: 10.12783/ASC33/26105
L. Henderson, R. Varley, Filip Stojcevski, James D. Randall, Daniel J. Eyckens, B. Demir, T. Walsh
© 2018 by DEStech Publications, Inc. All rights reserved. This paper summarizes recent efforts within our research group to optimize the interfacial adhesion of carbon fiber reinforced polymer composites (CFRPs). This effort has been approached by several avenues including surface modification of carbon fibers, and the use of molecular dynamics to determine key interfacial interactions determining optimal adhesion. Typically, surface manipulation of carbon fibers is carried out using reductive electrochemical techniques, employing irreversible single electron reduction of aryldiazonium salts. Though recent efforts have shown oxidative surface grafting of carbon fibers is possible using the Kolbe decarboxylation reaction. Both approaches create a fiber which possesses a covalently bound surface modification, able to present a myriad of chemistries to the supporting resin. Determination of interfacial shear strength (IFSS), using single filament fragmentation in epoxy resin, has shown IFSS gains of over 150%, relative to pristine unsized fiber. Interrogation of the fiber-matrix interface using molecular dynamics simulation has shown that a large degree of the IFSS gains are derived from the molecular 'drag' effect of the surface bound molecules through the polymer phase. Further benefits of this approach can also be realized by combining the surface manipulation techniques with novel sizing agents, able to plasticize the localized resin around the carbon fiber, giving a gradient interphase. When used in concert, the synergistic effects of surface modification and interphase manipulation has realized IFSS gains >250% relative to control fibers.
©2018 by DEStech Publications, Inc。版权所有。本文综述了近年来本课题组在优化碳纤维增强聚合物复合材料(CFRPs)界面粘附性能方面所做的工作。这项工作已经通过几种途径实现,包括碳纤维的表面改性,以及使用分子动力学来确定决定最佳粘附性的关键界面相互作用。通常,碳纤维的表面处理是使用还原性电化学技术进行的,采用不可逆的芳基重氮盐单电子还原。尽管最近的研究表明,利用科尔贝脱羧反应,碳纤维的表面氧化接枝是可能的。这两种方法都产生了一种具有共价结合表面改性的纤维,能够向支撑树脂呈现无数种化学物质。使用环氧树脂中的单丝碎片来测定界面剪切强度(IFSS),结果表明,相对于原始未施胶纤维,IFSS增加了150%以上。利用分子动力学模拟对纤维-基质界面的研究表明,IFSS的增益很大程度上来自于表面结合分子通过聚合物相的分子“阻力”效应。这种方法的进一步好处还可以通过将表面操作技术与新型施胶剂相结合来实现,这种施胶剂能够使碳纤维周围的局部树脂增塑化,从而产生梯度界面。当协同使用时,表面改性和界面操作的协同效应使IFSS相对于对照纤维的增益>250%。
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引用次数: 1
Creating Flexible Structures Out of MDF Plates 创建柔性结构的中密度纤维板
Pub Date : 2018-11-07 DOI: 10.12783/ASC33/26181
Renzhe Chen, Mingliang Jiang, Negar Kalantar, M. Moreno, A. Muliana
Medium densify fiberboard (MDF) is a composite comprising of wood fibers and epoxy resin, with a typical density range between 600-800 kg/m3. It is currently used for secondary structures in buildings such as architectural walls and facades. MDFs are typically available in flat panel forms which can be cut into various shapes for architectural design purposes. One cutting method is known as kerfing, in which a series of cuts are made on a wood panel to create flexible structures mainly through bending and twisting deformations. In this study, we present a micromechanics model of cut patterns in order to understand the overall deformations of the kerf panel. Three different cut densities, i.e., one, two, and three cuts per quarter unit-cell, of a square spiral pattern are studied. The effect of different cut densities on the uniaxial stretching of the unit-cell is examined. An experimental test is also done on a unit-cell under uniaxial stretching. The responses from the experiment and model are compared.
中密度纤维板(MDF)是由木纤维和环氧树脂组成的复合材料,其典型密度范围在600-800 kg/m3之间。目前主要用于建筑物的二次结构,如建筑外墙等。mdf通常采用平板形式,可以切割成各种形状用于建筑设计。一种切割方法被称为切缝,在木板上进行一系列切割,主要通过弯曲和扭曲变形来创造灵活的结构。在这项研究中,我们提出了一个微观力学模型,以了解切缝板的整体变形。研究了方形螺旋图案的三种不同切割密度,即每四分之一单元格切割一次、两次和三次。研究了不同切割密度对单晶胞单轴拉伸的影响。并对单轴拉伸下的单胞进行了试验研究。比较了实验和模型的响应。
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引用次数: 4
Study of Skin-Stringer Separation in Postbuckled Composite Aeronautical Structures 后屈曲复合材料航空结构皮弦分离研究
Pub Date : 2018-11-07 DOI: 10.12783/ASC33/26048
Lucas Kootte, C. Bisagni, Carlos G. Davila, V. Ranatunga
Aeronautical composite stiffened structures have the capability to carry loads deep into postbuckling, yet they are typically designed to operate below the buckling load to avoid potential issues with durability and structural integrity. Large out-of-plane postbuckling deformation of the skin can result in the opening of the skin-stringer interfaces, especially in the presence of defects, such as impact damage. To ensure that skin-stringer separation does not propagate in an unstable mode that can cause a complete collapse of the structure, a deeper understanding of the interaction between the postbuckling deformation and the development of damage is required. The present study represents a first step towards a methodology based on analysis and experiments to assess and improve the strength, life, and damage tolerance of stiffened composite structures subjected to postbuckling deformations. Two regions were identified in a four-stringer panel in which skin-stringer separation can occur, namely the region of maximum deflection and the region of maximum twisting. Both regions have been studied using a finite element model of a representative single-stringer specimen. For the region of maximum deflection, a seven-point bending configuration was used, in which five supports and two loading points induce buckling waves to the specimen. The region of maximum twisting was studied using an edge crack torsion configuration, with two supports and two loading points. These two configurations were studied by changing the positions of the supports and the loading points. An optimization procedure was carried out to minimize the error between the out-of-plane deformation of the representative single-stringer specimen and the corresponding region of the fourstringer panel.
航空复合材料加筋结构能够承受深度屈曲后的载荷,但它们通常被设计为在屈曲载荷下工作,以避免耐久性和结构完整性的潜在问题。蒙皮的大的面外后屈曲变形会导致蒙皮-弦界面的打开,特别是在存在缺陷的情况下,如冲击损伤。为了确保蒙皮弦分离不会以不稳定模式传播,从而导致结构完全崩溃,需要更深入地了解屈曲后变形与损伤发展之间的相互作用。本研究代表了基于分析和实验的方法的第一步,以评估和提高受后屈曲变形的加筋复合材料结构的强度、寿命和损伤容限。在四弦板中确定了两个区域,其中皮肤弦分离可以发生,即最大挠度区域和最大扭转区域。这两个区域已经研究了一个有代表性的单弦试件的有限元模型。对于最大挠度区域,采用七点弯曲配置,其中五个支撑点和两个加载点对试件产生屈曲波。采用双支撑、双加载点的边缘裂纹扭转结构,对最大扭转区域进行了研究。通过改变支承位置和加载点,对这两种结构进行了研究。为了使具有代表性的单弦试件的面外变形与四弦板相应区域的面外变形之间的误差最小,进行了优化处理。
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引用次数: 2
Quantitative Microscopic Investigation of Mode I Fracture Surfaces of Nanosilica-Filled Epoxies 纳米二氧化硅填充环氧树脂I型断口的定量显微研究
Pub Date : 2018-11-07 DOI: 10.12783/ASC33/26014
Aniruddh Vashisth, T. Henry, C. Bakis
The addition of functionalized nanosilica (NS) particles to epoxy resins is known to improve certain mechanical properties such as modulus of elasticity and fracture toughness. In the current investigation, epoxies with and without NS reinforcement were investigated. Four NS concentrations were evaluated: 0, 15, 25 and a maximum wt% NS dependent on which of the two curing agents was used. The tensile modulus of elasticity and quasi-static Mode I fracture toughness were measured and the Mode I fracture surfaces were examined using a field emission scanning electron microscope for general imaging and a scanning laser confocal microscope for quantitative information on surface morphology. Fracture toughness, as measured by critical strain energy release rate (GIc), and fracture surface area increased monotonically with increased NS content in the epoxy cured with diethyltoluenediamine (DETDA). However, for the material cured at a higher temperature with 4-4’ diamino diphenyl sulfone (DDS), GIc and surface area reach their respective peaks at NS concentrations less than the maximum value. The primary morphological toughing mechanisms observed were particle pullout and crack deflection. The DDS cured system had higher surface area than DETDA system for any non-zero NS content, but less GIc. Analysis of the experimental results led to the conclusion that GIc of the DETDA was mostly explainable in the context of NS particle pullout, as both fracture surface area and GIc varied in rough proportion to NS content. In the DDS system, however, such proportional behavior was not observed and it is believed that competing mechanisms influence GIc at NS concentrations above 15 wt%.
在环氧树脂中添加功能化纳米二氧化硅(NS)颗粒可以改善某些力学性能,如弹性模量和断裂韧性。在本研究中,研究了带和不带NS增强的环氧树脂。评估了四种NS浓度:0、15、25和最大wt% NS,这取决于使用哪一种固化剂。测量了拉伸弹性模量和准静态I型断裂韧性,并利用场发射扫描电子显微镜进行一般成像和扫描激光共聚焦显微镜对I型断口表面形貌进行了定量分析。二乙基甲苯二胺(DETDA)固化环氧树脂的断裂韧性(以临界应变能释放率(GIc)测量)和断裂表面积随NS含量的增加而单调增加。而对于用4-4′二氨基二苯基砜(DDS)固化的材料,在NS浓度小于最大值时,GIc和比表面积均达到各自的峰值。观察到的主要形态增韧机制是颗粒拉出和裂纹挠曲。对于任何非零NS含量,DDS固化体系比DETDA体系具有更高的表面积,但GIc更少。通过对实验结果的分析,得出DETDA的GIc主要是在NS颗粒拉出的情况下解释的结论,因为断裂表面积和GIc都与NS含量大致成比例变化。然而,在DDS系统中,没有观察到这种比例行为,并且认为竞争机制在NS浓度高于15%时影响GIc。
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引用次数: 0
Conforming Element Mesh for Realistic Textile Composite Micro-Geometry 真实感纺织复合材料微几何的一致性单元网格
Pub Date : 2018-11-07 DOI: 10.12783/asc33/26102
A. Mazumder, Youqi Wang, C. Yen
In recent years, several computer tools, e.g., DFMA, TexGen and WiseTex have been developed to derive realistic yarn-level micro-geometries for textile composites. However, due to numerical errors, the generated micro-geometries by these computer design tools have unavoidably exhibited artificial surface interferences or narrow gaps between yarns. It is therefore problematic to directly input the micro-geometry into a commercial FEM code to generate a conforming element mesh. In this paper, a procedure is developed to generate a conforming FE mesh that matches actual yarn-toyarn and yarn-to-matrix surface inside a textile composite with a complex microgeometry. It improves the accuracy of micro-mechanics analysis. The procedure divides into five steps. Initially, the unit cell domain is discretized into a uniform cuboid finite element mesh and the yarn surface is discretized into triangular plane elements. The second step consists of calculating the intersecting points between yarn surface triangle elements and mesh gridlines in the z-direction. The third step is the removal of numerical error driven artificial surface interferences or narrow gaps between yarns. If the distance between two intersection points from two adjacent yarns is smaller than a specified tolerance, the two adjacent intersecting points are merged to the mid-point. A material type, defined by yarn number, interface or matrix, is assigned to each node. In the fourth step, the initial uniform cuboid finite element mesh is modified so as to match yarn boundaries to the finite element mesh. In the final step, material types/yarn numbers are assigned to each element based on nodal material types. If an element is composed of nodes of two different material types, it is split into two or more elements. As such, a conforming FEM mesh, which matches the element boundary to the yarn-to-yarn or yarn-to-matrix interface, can be generated.
近年来,已经开发了一些计算机工具,例如DFMA, TexGen和WiseTex,以获得纺织复合材料的真实纱线级微观几何形状。然而,由于数值误差,这些计算机设计工具生成的微观几何形状不可避免地会出现人工表面干扰或纱线之间的窄间隙。因此,直接将微观几何形状输入到商用有限元程序中以生成符合的单元网格是有问题的。在本文中,开发了一种程序,以产生符合实际的纱线-纱线和纱线-基体表面在纺织复合材料具有复杂的微观几何。提高了细观力学分析的精度。这个过程分为五个步骤。首先,将单位胞域离散为均匀长方体有限元网格,将纱线表面离散为三角形平面单元。第二步是计算纱线表面三角形元素与网格线在z方向上的交点。第三步是消除数值误差导致的人工表面干扰或纱线之间的窄间隙。如果两个相邻纱线的相交点之间的距离小于指定的公差,则两个相邻相交点合并到中点。为每个节点分配由纱号、界面或矩阵定义的材料类型。第四步,修改初始均匀长方体有限元网格,使纱线边界与有限元网格匹配。在最后一步中,根据节点材料类型为每个元素分配材料类型/纱线编号。如果一个元素由两种不同材质类型的节点组成,那么它将被分割成两个或多个元素。这样,就可以生成一个将单元边界与纱线-纱线或纱线-矩阵界面相匹配的一致性有限元网格。
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引用次数: 1
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American Society for Composites 2018
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