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Long-term air pollution trend analysis in Malaysia 马来西亚长期空气污染趋势分析
Pub Date : 2019-09-19 DOI: 10.2495/EI-V2-N4-309-324
J. Sentian, F. Herman, Chan Yit Yih And Jackson Chang Hian Wui
Air pollution has become increasingly significant in the last few decades as a major potential risk to public health in Malaysia due to rapid economic development, coupled with seasonal trans-boundary pollution. Over the years, air pollution in Malaysia has been characterised by large seasonal variations, which are significantly attributed to trans-boundary pollution. The aim of this study is to analyse the long-term temporal dynamic (1997–2015) of CO, NO x and PM 10 at 20 monitoring stations across Malaysia. Long-term pollutant trends were analysed using the Mann–Kendall test. For potential pollutant source analysis, satellite data and Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) backward trajectories model were employed. In all monitoring sites, we observed that the annual average concentrations of PM 10 were varied, with large coefficient variations. Meanwhile, CO and NOx were found to be less varied, with smaller coefficient variations, except in certain monitoring sites. Long-term analysis trends for CO attested to insignificant decreasing trends in 11 monitoring stations and increasing trends in seven stations. Meanwhile, NO x showed no significant trends in most stations. For PM 10 , five monitoring stations showed increasing trends, whereas 15 other stations showed decreasing trends. HYSPLIT backward trajectory analyses have shown that high seasonal PM 10 levels in most parts of Malaysia are due to trans-boundary pollution. Large-scale intense biomass burning in Indonesia, particularly during the southwest monsoon, has been identified as the main potential source. Long-term air pollution in Malaysia is characterised largely by trans-boundary pollution and is highly seasonal. In urban areas of Malaysian Peninsula, combinations of trans-boundary pollution and local emission sources were notably identified as important sources. Long-term PM 10 pollution in Malaysia shows small but significant decreasing trends. Therefore, to ensure that the effect of air pollution on human health is minimised, special attention needs to be focused on short-term pollution episodes, particularly during trans-boundary pollution events and extreme weather conditions such as El Niño.
在过去的几十年里,由于经济的快速发展,再加上季节性的跨界污染,空气污染已成为马来西亚公众健康的一个主要潜在风险,其影响日益严重。多年来,马来西亚空气污染的特点是季节性变化很大,这在很大程度上归因于跨界污染。本研究的目的是分析马来西亚20个监测站CO、NO x和PM 10的长期时间动态(1997-2015)。使用Mann-Kendall检验分析了污染物的长期趋势。潜在污染源分析采用卫星数据和混合单粒子拉格朗日积分轨迹(HYSPLIT)后向轨迹模型。在所有监测点中,我们观察到PM 10的年平均浓度变化,且系数变化较大。与此同时,CO和NOx的变化较小,除个别监测点外,系数变化较小。CO的长期分析趋势表明,11个监测站有显著的下降趋势,7个监测站有上升趋势。与此同时,大部分站点的NO x变化趋势不明显。pm10有5个监测站呈上升趋势,15个监测站呈下降趋势。HYSPLIT的反向轨迹分析表明,马来西亚大部分地区的季节性PM 10高水平是由于跨境污染造成的。印度尼西亚大规模强烈的生物质燃烧,特别是在西南季风期间,已被确定为主要的潜在来源。马来西亚的长期空气污染主要以跨界污染为特征,并且具有很强的季节性。在马来西亚半岛的城市地区,跨界污染和本地排放源的组合被特别确定为重要的来源。马来西亚的PM 10长期污染呈微小但显著的下降趋势。因此,为了确保尽量减少空气污染对人类健康的影响,需要特别注意短期污染事件,特别是在跨界污染事件和极端天气条件(如El Niño)期间。
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引用次数: 18
Environmental to bacco smoke exposure and The impact of a smoking ban in internet cafes, pubs and billiard halls around a university in Korea 韩国某大学周围的网吧、酒吧、台球厅禁止吸烟对环境的影响
Pub Date : 2019-09-19 DOI: 10.2495/EI-V2-N4-356-365
Kwonchul Ha, Donguk Park
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引用次数: 0
Chemical characteristics of water-soluble ions and metal elements in ambient particles of Saitama, Japan during the spring asian dustevent, 2017 2017年春季亚洲沙尘事件中日本埼玉市环境颗粒物中水溶性离子和金属元素的化学特征
Pub Date : 2019-09-19 DOI: 10.2495/EI-V2-N4-336-345
Weiqian Wang, Qingyue Wang
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引用次数: 1
The emission of Ultrafine Particles in the manufacture of fireplace ceramic tiles 壁炉砖生产过程中超细颗粒的排放
Pub Date : 2019-08-19 DOI: 10.2495/EI-V2-N4-325-335
K. Lach, Ivona Smolová
studies in the field of the adverse effect of inhaled particles show that not only particle mass is crucial but also particle size and specific surface are. The main objective of this study was to investigate and characterise ultrafine particle (ufp) emissions on workplace in the manufacture of ceramic tiles at two problematic places at ceramic tiles kiln and spraying glazing suspension. The process of creating of glaze on the surface of stove tiles is performed at temperatures reaching up to 1,100c. at this high temperature occurs fugitive emissions from glaze and ceramic consist of vapours and ufp containing various heavy metals such as pb, cr, cu, mo, Zr, etc. from glaze and ceramic, respectively. The data obtained from the measurements confirmed the significant emissions of ufp at the two chosen workplaces, but the composition of particles, their size distribution and other parameters differed from one to another. in case of the workplace near the kiln, the following parameters were noted: total concentration of particles ranging from 5.6 nm to 560 nm is 2×10–4×10 n/cm; median of size distribution is 37 nm, median of mass distribution is 153 nm, particle surface deposited in tracheobronchial (Tb) part of lungs is 200 μm/cm, particle surface deposited in alveolar (a) part of lungs is 450 μm/cm and the concentration of pb is 3,744 μg/m. in the case of the manual spraying of the glaze suspension on tiles, the following parameters were noted: total concentration of particles is 2×10 n/cm; median of size distribution is 11 nm, median of mass distribution is 177 nm, particle surface deposited in Tb part of lungs is 50 μm/cm, particle surface deposited in a part of lungs is 170 μm/cm and the concentration of pb is 1.9 μg/m. it can be concluded from the data above that both the measured workplaces meet the permissible exposure limit for lead, which is 50 μg/m. it is important to note that, in this study, the health impacts of ufp on staff and employees were not studied.
对吸入颗粒不良反应的研究表明,不仅颗粒质量至关重要,颗粒大小和比表面积也至关重要。本研究的主要目的是调查和表征瓷砖生产工作场所在瓷砖窑和喷涂玻璃悬浮液两个问题场所的超细颗粒(ufp)排放。在炉砖表面形成釉的过程是在高达1100摄氏度的温度下进行的。在这种高温下,釉料和陶瓷中的逸出物分别由釉料和陶瓷中含有铅、铬、铜、钼、锆等多种重金属的蒸气和杂质组成。从测量中获得的数据证实,在两个选定的工作场所有大量的ufp排放,但颗粒的组成、大小分布和其他参数各不相同。在靠近窑的工作场所,注意以下参数:5.6 nm至560 nm的颗粒总浓度为2×10-4×10 n/cm;大小分布中值为37 nm,质量分布中值为153 nm,肺气管支气管(Tb)部颗粒表面沉积量为200 μm/cm,肺泡(a)部颗粒表面沉积量为450 μm/cm, pb浓度为3744 μg/m。在手工喷涂瓷砖釉悬液的情况下,需要注意以下参数:颗粒总浓度为2×10 n/cm;粒径分布中值为11 nm,质量分布中值为177 nm,肺Tb部位颗粒表面沉积量为50 μm/cm,肺部分颗粒表面沉积量为170 μm/cm, pb浓度为1.9 μg/m。由上述数据可知,两个被测工作场所均满足铅的允许接触限值50 μg/m。值得注意的是,在本研究中,未研究ufp对工作人员和雇员的健康影响。
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引用次数: 0
The effect of temperature on the leaching of Cr, Cu, Fe, Ni and Zn from tailings, Ballangen deposit, Norway 温度对挪威巴兰根尾矿中Cr、Cu、Fe、Ni和Zn浸出的影响
Pub Date : 2019-08-19 DOI: 10.2495/EI-V2-N4-366-381
Jinmei Lu, F. Yuan, T. Leiviskä
In this study, the effect of temperature on the leaching of Cr, Cu, Fe, Ni and Zn from oxidized tailings, Ballangen deposit, Norway, was investigated by a laboratory batch leaching experiment. The leaching was conducted at four different temperatures 5°C, 10°C, 15°C and 20°C and 2 precipitation rates of 8 mm/week and 20 mm/week. The leachates from six leaching cycles were collected, and the concentrations of Cr, Cu, Fe, Ni and Zn were tested. The results showed that at a precipitation rate of 20 mm/ week, the leached amount of Cr, Fe, Cu was highest at a leaching temperature of 20°C and the lowest leached amount for Cr was observed at 10°C. 10°C seems to be a threshold temperature for the leaching of Cr. However, at a precipitation rate of 8 mm/week, the highest leached amount of Cr, Fe and Cu was observed at 5°C and the lowest leached amount for Cr and Fe was observed at 20°C. The relationship between the accumulated leached amount of Cr, Cu, Fe, Ni and Zn and leaching water volume was approximated by a logarithmic function at different temperatures. If the factor of precipitation is ignored, only the accumulated leached amount at different temperatures is considered. The accumulated leached amount of Cr, Fe and Cu is highest at a leaching temperature of 20°C, which is significantly higher than that at other leaching temperatures by the established statistical model. The accumulated leached amount of Ni at 15°C and 20°C is significantly higher than that at 5°C and 10°C. The accumulated leached amount of Zn was highest at a leaching temperature of 10°C, which was significantly higher than that at 15°C and 20°C by the statistical model. Zn tends to be leached out at low temperatures.
通过室内批量浸出试验,研究了温度对挪威Ballangen矿床氧化尾矿中Cr、Cu、Fe、Ni和Zn浸出的影响。在5°C、10°C、15°C和20°C 4种不同温度下进行浸出,沉淀速率分别为8 mm/周和20 mm/周。收集了6个浸出循环的渗滤液,测定了Cr、Cu、Fe、Ni和Zn的浓度。结果表明:在沉淀速率为20 mm/周的条件下,浸出温度为20℃时Cr、Fe、Cu的浸出量最高,10℃时Cr的浸出量最低;10℃似乎是Cr浸出的阈值温度,但在8 mm/周的沉淀速率下,5℃时Cr、Fe和Cu的浸出量最高,20℃时Cr和Fe的浸出量最低。在不同温度下,Cr、Cu、Fe、Ni和Zn的累积浸出量与浸出水量之间的关系近似为对数函数。如果忽略降水因素,则只考虑不同温度下的累积浸出量。在20℃的浸出温度下,Cr、Fe和Cu的累积浸出量最大,明显高于其他浸出温度下的累积浸出量。15°C和20°C条件下Ni的累积浸出量明显高于5°C和10°C条件下。在浸出温度为10℃时,Zn的累积浸出量最高,统计模型显示,Zn在浸出温度为15℃和20℃时的累积浸出量显著高于15℃和20℃时的累积浸出量。锌在低温下容易浸出。
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引用次数: 1
Pesticide levels in streams and sediments on the islands of Oahu and Kauai, Hawaii 夏威夷瓦胡岛和考艾岛溪流和沉积物中的农药含量
Pub Date : 2019-08-13 DOI: 10.2495/EI-V2-N3-283-299
S. Spengler, M. Heskett, Julia I. Gray
A survey water quality study was conducted between 2014 and 2017 to investigate the presence and concentration of pesticides in the nearshore marine environments on the islands of Oahu and Kauai. On Kauai, a total of 32 surface water and 16 sediment samples were collected from four streams and one irrigation ditch over multiple sampling events. On Oahu, a total of 27 surface water and 16 sediment samples were collected from six streams on the leeward side of the island over multiple sampling events, typically under baseflow conditions. The samples were analysed for 197 compounds spanning eight chemical classes of pesticides. Five herbicide (glyphosate, metolachlor, atrazine, imazapyr and MCPA) and one insecticide (imidacloprid) compounds were detected in the surface water samples collected. Seven insecticide (imidacloprid, carbaryl, chlordane, p,pʹ-DDD, p,pʹ-DDE, p,pʹ-DDT and dieldrin), five herbicide [glyphosate, aminomethylphosphonic acid (AMPA), diuron, DCPMU and pendimethalin] and one fungicide (azoxystrobin) compound were detected in the stream bed sediments collected. Detected pesticides spanned the pesticide class list, with seven of the eight classes of pesticides tested discovered. This study found widespread, low level contamination by both legacy and currently used pesticides in nearshore waters and river bed sediments on the islands of Oahu and Kauai. Based on the pesticide data obtained during the study, five streams on the island of Oahu (two leeward and three windward streams) were selected for additional high-frequency sampling for the broad-spectrum herbicide glyphosate (Roundup), due to this compound’s prevalence and the elevated concentration levels (compared to other pesticides) measured. These five streams flow through watersheds dominated by agricultural, residential and mixed-use land use and were sampled under both baseflow and storm conditions. The pervasiveness and overall concentration levels of glyphosate detected are greater than any other pesticide currently or historically present in Hawaiian streams. Glyphosate was detected in 95% of stream samples collected during storm events (59 samples, 798 ng/L median, 1,308 ng/L mean detects) and 60% of stream samples collected under baseflow conditions (103 samples, 152 ng/L median, 462 ng/L mean detects), respectively (detection limit = 50 ng/L). In addition, either glyphosate or its degradation product AMPA was detected in 100% of the stream bed sediment samples collected on Oahu and Kauai during the study. The higher glyphosate concentrations in measured stream samples collected under storm versus baseflow conditions is believed to result from the release of adsorbed glyphosate present in stream-bed sediments as they become re-suspended during the rapid rises in stream volumes that characterize Hawaiian stream during runoff events. The mean glyphosate concentration measured in streams that drain urban and mixed-use areas (1,020 and 1,050 ng/L, respectively) was slightly h
2014年至2017年期间进行了一项调查水质研究,以调查瓦胡岛和考艾岛近岸海洋环境中农药的存在和浓度。在考艾岛,通过多次采样,从四条溪流和一条灌溉渠共收集了32个地表水样本和16个沉积物样本。在瓦胡岛,通过多次采样,通常在基流条件下,从岛屿背风侧的六条溪流中收集了27个地表水和16个沉积物样本。对样本进行了分析,发现了197种化合物,涵盖8种化学类别的杀虫剂。在采集的地表水样品中检测到5种除草剂(草甘膦、甲草胺、阿特拉津、伊马唑韦和MCPA)和1种杀虫剂(吡虫啉)。在所采集的河床沉积物中共检出7种杀虫剂(吡虫啉、西威因、氯丹、p、p′-DDD、p、p′-DDE、p、p′-DDT和狄氏剂),5种除草剂(草甘膦、氨基甲基膦酸(AMPA)、二恶龙、DCPMU和对二甲肼)和1种杀菌剂(嘧菌酯)化合物。检测到的农药跨越了农药类别清单,在8类农药中发现了7类。这项研究发现,在瓦胡岛和考艾岛的近岸水域和河床沉积物中,遗留的和目前使用的农药都受到了广泛的、低水平的污染。根据研究期间获得的农药数据,选择瓦胡岛的五条河流(两条背风河流和三条迎风河流)进行额外的高频采样,对广谱除草剂草甘膦(Roundup)进行采样,因为该化合物普遍存在,且浓度水平(与其他农药相比)较高。这五条河流流经以农业、住宅和混合用途土地利用为主的流域,并在基流和风暴条件下进行了采样。检测到的草甘膦的普遍性和总体浓度水平比目前或历史上存在于夏威夷溪流中的任何其他农药都要高。在风暴条件下采集的溪流样本中,草甘膦的检出率为95%(59个样本,中位数为798 ng/L,平均检出率为1308 ng/L),在基流条件下采集的溪流样本中,草甘膦的检出率为60%(103个样本,中位数为152 ng/L,平均检出率为462 ng/L),检出限为50 ng/L。此外,在研究期间,在瓦胡岛和考艾岛收集的河床沉积物样本中100%检测到草甘膦或其降解产物AMPA。与基流条件相比,在风暴条件下收集的测量溪流样本中草甘膦浓度较高,这被认为是由于在径流事件期间夏威夷溪流特征的溪流体积迅速上升期间,河床沉积物中被吸附的草甘膦被重新悬浮,从而释放出来。在城市和混合用途地区的河流中测量到的草甘膦平均浓度(分别为1,020和1,050 ng/L)略高于在农业区的河流中测量到的浓度水平(760 ng/L)。在农业地区采集的河流样本中,草甘膦的检测频率高于城市和混合用途地区(分别为82%、69%和63%)。本研究中测量的河流水域及其相关河床沉积物中草甘膦的平均浓度比20世纪70年代中期在瓦胡岛城市和混合利用区水域和沉积物中测量到的最常见的持久性有机污染物(沉积物中α-氯丹和河流和海湾水域中五氯酚)的最大平均检测浓度高出7倍和10倍以上。
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引用次数: 2
Management of cumulative impacts: Lessons from Canterbury, New Zealand 累积影响的管理:来自新西兰坎特伯雷的经验
Pub Date : 2019-08-13 DOI: 10.2495/EI-V2-N3-259-271
Bryan Robert Jenkins
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引用次数: 1
Aspect of reproductive biology of Parachanna obscura, Gunther 1861 in a southwestern Nigerian reservoir 尼日利亚西南部水库Gunther 1861中暗箱伞虫的生殖生物学方面
Pub Date : 2019-08-13 DOI: 10.2495/EI-V2-N3-272-282
O. Kareem, A. Olanrewaju, O. Orisasona
African snakehead (Parachanna obscura) is a highly valued freshwater fish species in Nigeria, but its availability for economic and nutritional benefits is being threatened as a result of overdependence on wild source. Effort at bringing it to culture is, however, being limited by paucity of information on its biology among other challenges. Therefore, key aspects of the reproductive biology of this species were investigated as a prelude to artificially propagate it. 688 live samples comprise of 394 females (12.6–45.0cm TL) and 294 males (12.8–41.6cm TL) were fortnightly obtained in Eleyele Lake between November 2014 and October 2016 from fishermen majorly using longline, cast nets and gillnets of various mesh sizes. Morphometric parameters of fish were taken, and each sample dissected for sex identification following standard method. The maturation stages were analysed using macroscopic and standard histological techniques. The sex ratio of samples varied significantly (p< 0.05), with 1.34 females for every male. Five stages of oogenesis and three stages of spermatogenesis were obtained from samples analysed. Mean gonadosomatic index were significantly higher in May (2.26±0.86%), June (2.08±0.80%) and January (1.98±0.77%) for female samples and in June (0.18±0.06%) and December (0.21±0.06%) for male, implying peaks of gonadal development for the sexes. Length at first maturity calculated was 26.6 cm for males and 25.8 cm for females. The diameter of ova, however, varies from 0.60 to 1.42 mm. Absolute fecundity ranged between 336 (at 20.5cm total length) and 7,033 (at 36.7 cm total length). The relationship between fecundity and total length, weight, ovary length and ovary weight was linear and positive. This research provides key information necessary for artificial propagation of P. obscura.
非洲黑头鱼(Parachanna obscura)是尼日利亚一种价值很高的淡水鱼,但由于过度依赖野生来源,其经济和营养价值正受到威胁。然而,将其引入文化的努力受到缺乏其生物学信息和其他挑战的限制。因此,对该物种生殖生物学的关键方面进行了研究,作为人工繁殖的前奏。2014年11月至2016年10月,在eleyelle湖每两周采集688份活体样本,其中雌性样本394份(长度为12.6-45.0cm),雄性样本294份(长度为12.8-41.6cm),渔民主要使用不同网目大小的延绳钓、撒网和刺网。采集鱼类形态计量学参数,并按标准方法解剖标本进行性别鉴定。采用宏观和标准组织学技术分析成熟阶段。样本性别比差异显著(p< 0.05),男女比例为1.34比1。从分析的样本中获得了5个阶段的卵子发生和3个阶段的精子发生。雌性样本的平均性腺指数在5月(2.26±0.86%)、6月(2.08±0.80%)和1月(1.98±0.77%)显著高于雄性样本,6月(0.18±0.06%)和12月(0.21±0.06%)显著高于雄性样本,表明两性性腺发育达到高峰。雄鼠初成熟体长为26.6 cm,雌鼠为25.8 cm。而卵的直径在0.60 ~ 1.42毫米之间。绝对繁殖力介于336(全长20.5厘米)至7,033(全长36.7厘米)之间。繁殖力与总长度、体重、子房长度和子房重量呈线性正相关。本研究为暗室草人工繁殖提供了必要的关键信息。
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引用次数: 2
Bioadsorption of Cr (VI) in aqueous solutions by pseudomonas koreensis immobilized in alginate beads 海藻酸珠固定化高丽假单胞菌对水溶液中铬(VI)的生物吸附
Pub Date : 2019-08-13 DOI: 10.2495/EI-V2-N3-229-239
S. Torres, S. C. Hernández, L. Jimenez
Water pollution by Cr is challenging due to its high toxicity. Most of chromium is released by industrial processes. Different methods have been developed to remove heavy metals from water, but they are expensive and not efficient for low concentrations. Microorganisms have received attention since they are able to grow in stress conditions. Bacteria living in water bodies near to mining are resistant to heavy metals; then, they have potential for bioadsorption applications. The purpose of this work was to isolate a microorganism tolerant to Cr from water bodies near to a mining zone. The isolated, Pseudomonas koreensis, was immobilized in alginate beads and its efficiency to remove Cr from water was evaluated. For isolation, serial dilution of samples was conducted; microorganisms were cultured in EMB, MacConkey and Mannitol salt agar and incubated at 30–35 °C for 24 h. The dominant colonies were replanted in nutrient agar supplemented with chromium and they were incubated at 30–35 °C until growth evidence. Species identification was done according to Bergey’s Manual and by 16 S rDNA sequencing. Alginate beads were prepared by slow continuous deposition method. Isolated bacteria were set in batch reactors together with alginate beads and nutrient medium to promote microorganism immobilization. The biofilm presence was confirmed through SEM. A random experimental design was used to determine the best amount of adsorbent in lab scale batch reactors. The concentration was taken as variable considering 15, 25 and 40 g. Temperature, pH, stirring and concentration of Cr (VI) were fixed at 30°C, 6.6, 150 rpm and 10 ppm, respectively. Samples from 0 to 56 h were taken. A variance analysis was performed. Chromium removal of 97% at 32 h was reached. Significative difference was observed related to adsorbent concentration and time. The best results correspond to 40 g of adsorbent.
铬的高毒性使其水污染具有挑战性。大多数铬是由工业过程释放的。人们已经开发出不同的方法来去除水中的重金属,但它们都很昂贵,而且对低浓度的重金属效果不佳。微生物由于能够在逆境条件下生长而受到关注。矿区附近水体中的细菌对重金属具有抗性;因此,它们具有生物吸附应用的潜力。本研究的目的是从矿区附近的水体中分离出一种耐铬微生物。将分离得到的韩国假单胞菌固定在海藻酸珠中,并对其去除水中铬的效率进行了评价。分离时,对样品进行连续稀释;微生物分别在EMB、MacConkey和Mannitol盐琼脂中培养,30-35℃孵育24 h。优势菌落移入添加铬的营养琼脂中,30-35℃孵育至有生长迹象。根据Bergey’S Manual和16s rDNA测序完成物种鉴定。采用慢速连续沉积法制备海藻酸盐微球。将分离的细菌与海藻酸珠和营养培养基一起置于间歇式反应器中,以促进微生物的固定化。通过扫描电镜证实了生物膜的存在。采用随机实验设计确定了实验室规模间歇式反应器中吸附剂的最佳用量。浓度为变量,考虑15、25、40 g。温度、pH、搅拌和Cr (VI)浓度分别固定在30°C、6.6、150 rpm和10 ppm。取0 ~ 56 h的样品。进行方差分析。在32 h时,铬去除率达到97%。吸附剂浓度和时间有显著性差异。吸附剂用量为40 g时效果最佳。
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引用次数: 3
Application of high-purity zeolite a synthesized from different coal combustion by-products in carbon dioxide capture 不同煤燃烧副产物合成的高纯沸石在二氧化碳捕集中的应用
Pub Date : 2019-08-13 DOI: 10.2495/EI-V2-N3-215-228
J. C. Izidoro, D. Castanho, C. Rossati, D. Fungaro, S. Guilhen, T. Nogueira, M. Andrade
High-purity zeolites A were synthesized from different coal combustion by-products (baghouse filter fly ash, cyclone filter ash, and bottom ash) and characterized in terms of morphology, chemical, and mineralogical composition. The products were tested for carbon dioxide capture by using a continuous CO 2 flow system passing through a column packed with the adsorbent material, which was connected to an analyser that directly measures the concentration of CO 2 . The values of CO 2 adsorption capacities calculated for the unmodified Na-A zeolites (ZABF, ZACF, and ZABA) were 556.48, 494.29 and 654.82 mg g, respectively. These values were higher than those achieved by the calcium-modified zeolite samples. ZABA adsorbent presented the best performance in CO 2 capture when compared to the other adsorbent material and achieved an adsorption capacity 32% higher than a 4A commercial zeolite. In the adsorption cycles study, the percentage of CO 2 desorption by ZABA at the second and third cycles reached 93%, showing that zeolite A can be regenerated by heating at 150 oC. The use of coal ashes to obtain zeolites and the application of these products for the CO 2 adsorption can be an important strategy to mitigate both the problem of waste management and the greenhouse gases emission in coal-fired power plants.
以不同的煤燃烧副产物(袋滤飞灰、旋风滤灰和底灰)为原料合成了高纯度沸石A,并对其进行了形态、化学和矿物组成的表征。产品的二氧化碳捕获测试是通过一个连续的二氧化碳流系统,该系统通过一个填充了吸附剂材料的柱,该柱与直接测量二氧化碳浓度的分析仪相连。未改性的Na-A分子筛(ZABF、ZACF和ZABA)的CO 2吸附量分别为556.48、494.29和654.82 mg g。这些数值高于钙改性沸石样品所获得的数值。与其他吸附剂相比,ZABA吸附剂对co2的吸附性能最好,吸附量比4A型工业沸石高32%。在吸附循环研究中,ZABA在第二次和第三次循环中对CO 2的解吸率达到93%,表明在150℃下加热可以再生A沸石。利用煤灰制备沸石,并利用这些产品吸附co2,可以成为缓解燃煤电厂废物管理和温室气体排放问题的重要策略。
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International Journal of Environmental Impacts
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