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Sequential Extraction and Particle Size Analysis of Heavy Metals in Sediments Dredged from the Deûle Canal, France 法国德<s:1>勒运河疏浚沉积物中重金属的序贯提取及粒度分析
Pub Date : 2011-04-13 DOI: 10.2174/1874829501104010011
N. Sabra, H. Dubourguier, T. Hamieh
The Deule canal is one of the most polluted canals in northern France. It contains large volumes of polluted sediments. These have to be dredged and characterized before deciding about the technology suitable for their treatment. The sediments are thus subjected to a physico-chemical characterization comprising particle size classification and heavy metals sequential extraction studies. The total metallic concentrations exceed the French standards for several metals such as cadmium, zinc, lead or copper. On average, 92% of the total weight of each metal are present in the particles that are less than 53 � m in size. These particles represent about 85% of the suspended matter dry weight. The sequential extraction study reveals that most of the studied metals are strongly linked to the sediments because of their association with the sul- fides and with the organic matter.
迪尔运河是法国北部污染最严重的运河之一。它含有大量被污染的沉积物。在确定适合其处理的技术之前,必须对其进行疏浚和表征。因此,沉积物受到物理化学表征,包括粒度分类和重金属顺序提取研究。总金属浓度超过了镉、锌、铅或铜等几种金属的法国标准。平均而言,每种金属总重量的92%存在于尺寸小于53微米的颗粒中。这些颗粒约占悬浮物干重的85%。序贯提取研究表明,所研究的大多数金属与沉积物有很强的联系,因为它们与硫化物和有机质有联系。
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引用次数: 18
Texture Properties and Kinetic Parameters Associated to Carbon Materials Obtained from Sawdust of Algarroba Wood. 1. Application in Phenol Photodetoxification 木屑碳材料的结构特性和动力学参数研究。苯酚光解毒的应用
Pub Date : 2011-03-22 DOI: 10.2174/1874829501104010001
J. Matos, Carol Nahas, L. Rojas, M. Rosales
Carbon materials were obtained by pyrolysis of the sawdust of Algarroba wood under CO2 or N2 atmospheres at temperatures from 200oC up to 900oC. Carbon materials were characterized by surface and micropore areas, volume pore and mean pore diameter. An approach of the kinetic parameters (apparent constant-rates and activation energies) as- sociated with the synthesis of these carbon materials is also presented. From the kinetic data of thermal degradation of Al- garroba wood, three different pyrolysis zones were verified. First, an incipient carbonization between 200 up to 350oC, second an extensive carbonization between 350 up to 600oC, and a third step involving the pore formation at temperatures higher than 600oC. As a target application of carbon materials, results of phenol adsorption and phenol photodegradation under UV-irradiation indicated the potential of carbon materials in presence of TiO2 for treatment of polluted waters.
以Algarroba木屑为原料,在200 ~ 900℃的CO2或N2气氛下进行热解,得到炭素材料。用表面孔面积、微孔面积、体积孔和平均孔径对碳材料进行表征。本文还介绍了与这些碳材料合成有关的动力学参数(表观恒速率和活化能)的方法。根据Al- garroba木材热降解的动力学数据,验证了三个不同的热解区。第一步是在200 - 350℃之间的初始碳化,第二步是在350 - 600℃之间的广泛碳化,第三步是在高于600℃的温度下形成孔隙。作为碳材料的目标应用,在紫外照射下对苯酚的吸附和光降解结果表明,在TiO2存在下,碳材料在处理污染水体方面具有潜力。
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引用次数: 2
Methane Potential of Waste Activated Sludge and Fatty Residues: Impact of Codigestion and Alkaline Pretreatments 废活性污泥和脂肪残渣的甲烷潜力:共消化和碱性预处理的影响
Pub Date : 2010-10-13 DOI: 10.2174/1874829501003010071
H. Carrère, Y. Rafrafi, A. Battimelli, M. Torrijos, J. Delgenès, Gilles Ruysschaert
The aim of this study was to maximise methane production from waste activated sludge (WAS) originating from extended aeration process and presenting a low methane potential (190 mL CH4.g -1 OM). WAS co-digestion with fatty residues (FR, 560 mL CH4.g -1 OM) produced during pretreatments of the effluents from wastewater treatment plants in the Lille area and fatty wastewaters (FW, around 700 mL CH4.g -1 OM) collected from restaurants was assessed by batch experiments. Moreover saponification/alkali pretreatments improved kinetics of anaerobic digestion but had a low impact on methane potential (+ 6-7%) of the mixed waste composed of 66.6% of FW, 33.3% of WAS and 0.1% of FR. As results did not depend on pH ranging from 8 to 10 (addition of 0.12 to 0.21 gKOH gOM -1 ) nor temperature ranging from 80 to 120 °C, the least severe studied pretreatment conditions (80°C and pH=8) may be selected for further studies on con- tinuous anaerobic reactors.
本研究的目的是最大限度地利用源自延长曝气过程的废弃活性污泥(was)产生甲烷,并呈现出低甲烷潜力(190 mL CH4)。g -1 OM)。WAS与脂肪残基共消化(FR, 560ml CH4)。在里尔地区污水处理厂的废水和含脂废水(FW,约700 mL CH4)的预处理过程中产生的。采用批量试验的方法对餐馆采集的g -1 OM进行评价。此外皂化/碱预处理提高厌氧消化动力学但低影响甲烷的潜在(+ 6 - 7%)混合废物由弗兰克-威廉姆斯的66.6%,33.3%和0.1%的FR。结果不依赖于pH值从8到10(增加0.12到0.21 gKOH傻子1)和温度范围从80到120°C,最严重的研究了预处理条件(80°C和pH = 8),为进一步的研究可能会选择完全tinuous厌氧反应器。
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引用次数: 20
Study of Occupant Exposure of Drivers and Commuters with Temporal Variation of In-Vehicle Pollutant Concentrations in Public Transport Buses Operating on Alternative Diesel Fuels~!2010-07-03~!2010-07-26~!2010-09-08~! 代用柴油公交车驾驶员和通勤者乘员暴露与车内污染物浓度变化的研究2010-07-03 2010-07-26 2010-09-08
Pub Date : 2010-09-08 DOI: 10.2174/1874829501003010055
Akhil Kadiyala
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引用次数: 20
Inorganic Pollutants in Recovered Wood from Slovenia and Boards Made of Disintegrated Wood 来自斯洛文尼亚的回收木材和由分解木材制成的板材中的无机污染物
Pub Date : 2010-07-16 DOI: 10.2174/1874829501003010049
M. Humar
Due to increasing demands on wood, recovered wood is becoming more and more important. It is mainly used for energetic purposes and for particle board production. This material was polluted with various chemicals (surface coat- ings, biocides, concrete residues, etc.) during service life. These chemicals causes difficulties at the end of service life. In order to elucidate presence of inorganic pollutants in Slovenian recovered wood, 30 specimens were collected on city Ljubljana dump/sorting site, and analysed with x-ray fluorescence spectrometer (XRF). Those values were compared to the concentration of inorganic elements in boards made of disintegrated wood collected in Slovenian market. In recovered wood, as well as in imported particle boards increased concentrations of the following elements was confirmed: Cl, Cr, Fe, Cu, Zn and Pb. This indicates that at lest part of contaminated recovered wood is used for production of some particle boards.
随着人们对木材需求的不断增加,再生木材越来越受到重视。它主要用于能源用途和刨花板生产。这种材料在使用期间会受到各种化学物质(表面涂层、杀菌剂、混凝土残留物等)的污染。这些化学物质在使用寿命结束时造成困难。为了阐明斯洛文尼亚回收木材中无机污染物的存在,在卢布尔雅那市垃圾场/分选场采集了30个样品,并用x射线荧光光谱仪(XRF)进行了分析。这些数值与斯洛文尼亚市场上收集的分解木材制成的板中无机元素的浓度进行了比较。在回收木材中,以及在进口刨花板中,证实了以下元素的浓度增加:Cl、Cr、Fe、Cu、Zn和Pb。这表明,至少有一部分受污染的回收木材被用于生产一些刨花板。
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引用次数: 0
Coagulation-Flocculation and Air Stripping as a Pretreatment of Young Landfill Leachate 混凝-絮凝-空气剥离预处理垃圾渗滤液
Pub Date : 2010-05-11 DOI: 10.2174/1874829501003010042
T. Yilmaz, Selami Apaydın, A. Berktay
Leachate from sanitary landfills is a strong wastewater in terms of organic matter and ammonia. Both biologi- cal and chemical processes can be used for organic matter but ammonia reduction by nitrification-denitrification often poses problems due to inhibition. In this study, leachate from solid waste landfill in Konya Municipal area was used and organic matter and color removal were examined by using different chemical matters (Alum, FeCl3, FeSO4) in the pH ad- justment with lime, NaOH and H2SO4. For ammonium removal, air stripping and its removal efficiency were investigated. For organic matter removal, the highest efficiencies were achieved as 44% by using 9 g/L alum at pH 11 adjusted with lime and as 45% by using 15 g/L FeCl3 concentration at pH 3. Color removal studies in coagulation experiments indicated that the highest color removal efficiencies could be obtained when pH was adjusted with lime. The lowest coagulant con- centration 1 g/L yielded the similar removal efficiencies as the concentration increased. In ammonium removal with air stripping, the optimum flow rate was 1 L/min and the optimum aeration time was 8 hours.
卫生填埋场的渗滤液在有机物和氨方面是一种强废水。生物法和化学法都可以用于有机物,但由于抑制作用,通过硝化-反硝化法还原氨常常会出现问题。本研究以科尼亚市区垃圾填埋场的渗滤液为研究对象,采用不同化学物质(明矾、FeCl3、FeSO4)和石灰、NaOH、H2SO4调节pH,考察其对有机物和色度的去除。考察了空气汽提法去除氨氮的效果。对于有机物的去除,在pH为11时,使用9g /L的明矾,用石灰调节,达到了44%的最高效率;在pH为3时,使用15g /L的FeCl3,达到了45%的最高效率。混凝脱色实验表明,用石灰调节pH时脱色效率最高。混凝剂最低浓度为1 g/L时,随着浓度的增加,去除率相似。气提法脱铵时,最佳流量为1 L/min,最佳曝气时间为8 h。
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引用次数: 30
Multi Criteria and Landfill Site Selection Using Gis: A Case Study From Palestine~!2010-01-01~!2010-01-24~!2010-03-19~! 基于Gis的多准则垃圾填埋场选址——以巴勒斯坦为例2010-01-01 2010-01-24 2010-03-19
Pub Date : 2010-04-07 DOI: 10.2174/1874829501003010033
I. Mahamid, S. Thawaba
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引用次数: 19
On exergy and sustainable development in environmental engineering 论环境工程中的能源与可持续发展
Pub Date : 2010-03-04 DOI: 10.2174/1874829501003010021
G. Wall
Humankind faces the most serious challenge ever – sustainable development. A new paradigm based on respectof nature and awareness of natural mechanisms is needed. The concept of exergy and exergy b ...
人类面临着有史以来最严峻的挑战——可持续发展。需要一种基于尊重自然和认识自然机制的新范式。能量和能量的概念…
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引用次数: 25
Qualitative Evaluation of Particulate Matter Inside Public Transit Buses Operated by Biodiesel 生物柴油公交车内颗粒物的定性评价
Pub Date : 2010-03-04 DOI: 10.2174/1874829501003010013
Kaushik K. Shandilya, Ashok Kumar
The Environmental scanning electron microscopy (ESEM) has been used in a preliminary study to determine the size and morphology of fine particulate matter (PM). This was done with several samples collected inside public tran- sit buses fueled with a 20 percent biodiesel blend of biodiesel and ultra-low sulfur diesel (B20). As the technique is non- destructive, particles of interest can be relocated for further analysis. The practical issue of instrumentation compatibility is addressed. In addition, results showing SEM chemical images from several PM of particle size less than 10 � m (PM10) samples are reported. Shape analysis suggested the possible sources. Particle size distribution suggested a median and mean diameter of particles counted was 0.24±0.02� m and 0.27±0.04� m, respectively. The conclusion is that SEM meth- odology is a valuable tool for studying the distribution of particulate pollutants.
环境扫描电子显微镜(ESEM)已被用于确定细颗粒物(PM)的大小和形态的初步研究。这是在公共交通巴士内收集的几个样本,这些巴士使用20%的生物柴油和超低硫柴油(B20)混合燃料。由于该技术是非破坏性的,因此可以重新定位感兴趣的粒子进行进一步分析。解决了仪器兼容性的实际问题。此外,还报道了几种粒径小于10 μ m (PM10)的PM样品的SEM化学图像。形状分析表明了可能的来源。粒径分布显示,所测颗粒直径中位数为0.24±0.02 μ m,平均值为0.27±0.04 μ m。研究结果表明,扫描电镜是研究颗粒污染物分布的一种有价值的工具。
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引用次数: 17
Externalities of Soil Stabilization in the Construction of Main Transportation Infrastructures. The Case of the High Speed Railway in North Italy: Economical and Environmental Benefits 主要交通基础设施建设中土壤稳定的外部性。意大利北部高速铁路的案例:经济和环境效益
Pub Date : 2010-01-13 DOI: 10.2174/1874829501003010001
A. Benedetto
The technique of soil stabilization is usually adopted with the purpose of rendering plastic soils coherent to the standards and requirements of engineering projects. The environmental benefits of soil stabilization versus the use of traditional natural material from quarries are generally underestimated. The case study of one significant section of the Italian High Speed Railway is presented here. This section is a part of the line from Milan to Venice. The volume of material that is needed for the development of embankments amounts to about 3 million m 3 and 1.5 millions m 3 of aggregates are needed for concrete. At the same time the construction of foundations produces about 1 million m 3 of soil: 350,000 m 3 from foundations, 400,000 m 3 from diaphragms and drilled piles and 70,000 m 3 from helicoidal piles. The need to manage such a significant volume of soil suggests the need for the consideration of recycling the clay soil after lime stabilization. The technical compatibility is here verified. The total costs of all the actions derived from the Environmental Impact Assessment for environment protection is less than 8% of the savings produced by the stabilization of soil. It finally demonstrates that the question of non-renewable resource management, such as soil, is strategic also under an environmental protection perspective.
为了使塑性土符合工程标准和要求,通常采用土壤稳定技术。与使用采石场的传统天然材料相比,土壤稳定的环境效益通常被低估了。本文介绍了意大利高速铁路的一个重要路段的案例研究。这一段是从米兰到威尼斯的线路的一部分。发展堤坝所需的材料量约为300万立方米,混凝土需要150万立方米的骨料。同时,基础建设产生约100万立方米的土壤:35万立方米来自基础,40万立方米来自横膈膜和钻孔桩,7万立方米来自螺旋桩。需要管理如此大量的土壤,这表明需要考虑石灰稳定后粘土的再循环。这里验证了技术兼容性。从环境影响评价中得出的所有环境保护行动的总成本不到土壤稳定所产生的节省的8%。最后论证了在环境保护的视角下,土壤等不可再生资源的管理问题具有战略意义。
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引用次数: 1
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The Open Environmental Engineering Journal
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