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CHAPTER 9. Understanding Battery Aging Mechanisms 第9章。了解电池老化机制
Pub Date : 2019-04-02 DOI: 10.1039/9781788016124-00220
Dongjian Li, D. Danilov, H. Bergveld, R. Eichel, P. Notten
The aging mechanisms of Li-ion batteries are introduced in this chapter, and are experimentally investigated and modeled. From SEM it is found that the thickness of the solid electrolyte interface layers at the graphite electrode surface increase upon aging. Deformation of the graphite structure is confirmed by Raman spectroscopy. XPS analyses show that transition metals dissolved from cathode are deposited onto the graphite electrode. Cathode dissolution at elevated temperatures is further confirmed by ICP measurements. Apart from postmortem analyses, a novel non-destructive approach is proposed to quantify the graphite electrode decay. A comprehensive electrochemistry model is proposed to simulate the irreversible capacity loss under various aging conditions. The dependence of the capacity loss on aging conditions, such as storage state of charge, cycling current, temperature, etc. is simulated and the simulations are in good agreement with the experiments. The degradation model allows researchers to have an in-depth understanding of aging mechanisms and therefore helps manufacturers to improve battery performance by optimizing manufacturing procedures. Moreover, the model can be further used to predict the battery cycle life, which can be used to develop more accurate battery management systems to increase battery efficiency and safety.
本章介绍了锂离子电池的老化机理,并对其进行了实验研究和建模。SEM结果表明,随着老化,石墨电极表面的固体电解质界面层厚度逐渐增大。用拉曼光谱证实了石墨结构的变形。XPS分析表明,从阴极溶解的过渡金属沉积在石墨电极上。阴极在高温下的溶解被ICP测量进一步证实。除了死后分析外,还提出了一种新的非破坏性方法来量化石墨电极的衰变。提出了一种综合的电化学模型来模拟不同老化条件下的不可逆容量损失。模拟了容量损失与老化条件(如电荷存储状态、循环电流、温度等)的关系,仿真结果与实验结果吻合较好。该退化模型使研究人员能够深入了解老化机制,从而帮助制造商通过优化制造工艺来提高电池性能。此外,该模型还可以进一步用于预测电池循环寿命,用于开发更精确的电池管理系统,以提高电池的效率和安全性。
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引用次数: 5
CHAPTER 7. Creation of a New Design Concept for All-polymer-structured Batteries 第七章。全聚合物结构电池新设计理念的创造
Pub Date : 2019-03-14 DOI: 10.1039/9781788016124-00163
H. Horie
A battery technology has been developed that can transform the design and manufacturing concepts that have prevailed since the inception of batteries. Unlike existing batteries that are built on metallic bulk current collectors, all of the structures in the new battery, including electrodes, are primarily made of resin. The underlying concept of this development is called “large-scale integrated polymer”. Various characteristics are exhibited by a battery that uses resin as the main component. The battery has a physically flexible structure, increasing the degree of freedom of the device in which it is used and the risk of metal contamination during manufacturing, which might cause fire accidents, is reduced. Even if metal enters the battery from the outside, theoretically it is difficult to generate heat, and hence safety is enhanced. With the present structure of the battery, which consists of laminated layers of metal and resin, it is difficult to increase the size of the battery because of the application of external force and the internal stress due to charge and discharge; however, this is easily achieved in the new battery. The safety design, in case of abuse, may be approached from a new perspective. It also leads to higher power output and longer life.
一种电池技术已经被开发出来,它可以改变自电池诞生以来一直盛行的设计和制造理念。与现有的基于金属集热器的电池不同,新电池的所有结构,包括电极,主要由树脂制成。这一发展的基本概念被称为“大规模集成聚合物”。以树脂为主要成分的电池具有多种特性。该电池具有物理柔性结构,增加了使用该电池的设备的自由度,并降低了制造过程中可能导致火灾事故的金属污染风险。即使金属从外部进入电池,理论上也很难产生热量,因此提高了安全性。目前的电池结构是由金属和树脂层压而成,由于施加外力和充放电产生的内应力,很难增加电池的尺寸;然而,这在新电池中很容易实现。在滥用的情况下,安全设计可以从一个新的角度来考虑。它还导致更高的功率输出和更长的寿命。
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引用次数: 0
CHAPTER 2. Layered Ni-rich Cathode Materials 第二章。层状富镍正极材料
Pub Date : 2019-03-14 DOI: 10.1039/9781788016124-00026
Seung‐Taek Myung, Chang-Heum Jo, Aishuak Konarov
Recent lithium-ion battery (LIB) technologies power electric vehicles (EVs) to run approximately 220 miles in a single charge, and further effort to increase the energy density of LIBs is being made to run LIB-mounted EVs up to 300 miles in the next few years. Among several important components of LIBs, cathode materials play a significant role in contributing to cost, safety issues, and more importantly energy density. For this concern, Ni-rich cathode materials are indispensable because of their high capacity, reaching over 200 mAh g−1. To commercialize Ni-rich cathode material, tremendous work has been carried out to stabilize the crystal structure and minimize the side reaction with electrolytes, namely, doping, surface modification from nano- to microscale, densification of secondary particles, morphological alternation of primary particles in a secondary particle, and so on. The approaches that have pursued will be discussed in this chapter followed by a perspective.
最近的锂离子电池(LIB)技术为电动汽车提供了一次充电约220英里的动力,并且正在进一步努力提高锂离子电池的能量密度,以便在未来几年内使安装在锂离子电池上的电动汽车行驶300英里。在锂离子电池的几个重要组成部分中,阴极材料在成本、安全问题和更重要的能量密度方面发挥着重要作用。对于这一问题,富镍阴极材料是必不可少的,因为它们的高容量,达到超过200mah g−1。为了实现富镍正极材料的商业化,人们进行了大量的工作来稳定晶体结构,减少与电解质的副反应,即掺杂、从纳米到微观的表面改性、二次粒子的致密化、一次粒子在二次粒子中的形态改变等。所采取的方法将在本章中讨论,然后是一个观点。
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引用次数: 2
CHAPTER 10. Battery Storage for Grid Connected PV Applications 第十章。并网光伏应用的电池存储
Pub Date : 2019-03-14 DOI: 10.1039/9781788016124-00251
M. Vetter, S. Lux, J. Wüllner
With the increasing share of fluctuating renewables in power grids the need for, but also the value of, electrical energy storage is identified. Particularly advanced battery systems such as lithium ion offer various opportunities: they can be designed to be highly modular and are therefore flexible in usage and they offer comparably high efficiency as well as long calendar and cycle life times. Typical examples of such grid connected stationary applications are described in this chapter. These include small residential as well as commercial battery storage for increased self-consumption and self-sufficiency. The principles of system design and the integration of the key components such as inverter and energy management are described for such applications. Furthermore, test results of market available products show the achievements but also the remaining optimization potential, which has to be addressed in future developments. In particular, in the field of commercial and industrial applications, bankability and insurability are key for mass market dissemination. Therefore critical topics such as safety, reliability as well as performance are discussed in this chapter.
随着电网中波动的可再生能源份额的增加,电能存储的需求和价值也得到了确认。特别先进的电池系统,如锂离子电池,提供了各种机会:它们可以设计成高度模块化,因此使用灵活,它们提供相对较高的效率以及较长的日历和循环寿命。这一章描述了这种并网固定应用的典型例子。其中包括小型住宅和商业电池存储,以增加自用和自给自足。介绍了该应用的系统设计原则和逆变器、能源管理等关键部件的集成。此外,市场上现有产品的测试结果显示了成果,但也显示了剩余的优化潜力,这在未来的开发中需要解决。特别是在商业和工业应用领域,可融资性和可保险性是大众市场传播的关键。因此,本章将讨论诸如安全性、可靠性以及性能等关键主题。
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引用次数: 1
CHAPTER 5. Gel Polymer Electrolytes 第五章。凝胶聚合物电解质
Pub Date : 2019-03-14 DOI: 10.1039/9781788016124-00102
Dong‐Won Kim
An electrolyte is a major component that influences battery performance. The electrolytes for lithium-ion batteries can be mainly divided into liquid electrolyte, gel polymer electrolyte and solid electrolyte. The liquid electrolyte used in commercialized lithium-ion batteries is based on lithium salt dissolved in organic solvents. It provides high ionic conductivity, acceptable electrochemical stability and good cycle performance. However, the use of liquid electrolytes has brought risks associated with leakage and fire hazards due to the highly flammable nature of the organic solvents. Therefore, there is a pressing need for safer and more reliable electrolyte systems. Solid electrolytes provide a promising opportunity to tackle the safety issue. However, they show low ionic conductivities at ambient temperature and poor interfacial characteristics with electrodes, resulting in deteriorated cycling performance. In this respect, gel polymer electrolytes with combined advantages of both the liquid and solid electrolytes have received considerable attention due to their high ionic conductivity, good interfacial adhesion to electrodes and effective encapsulation of organic solvents in the cell, resulting in the suppression of solvent leakage and enhanced safety. This chapter reviews the state-of-the-art of gel polymer electrolytes for application in future lithium-ion batteries.
电解液是影响电池性能的主要成分。锂离子电池的电解质主要分为液体电解质、凝胶聚合物电解质和固体电解质。商用锂离子电池中使用的液体电解质是以溶解在有机溶剂中的锂盐为基础的。它具有较高的离子电导率、良好的电化学稳定性和良好的循环性能。然而,由于有机溶剂的高度可燃性,液体电解质的使用带来了与泄漏和火灾危险相关的风险。因此,迫切需要更安全、更可靠的电解质系统。固体电解质为解决安全问题提供了一个有希望的机会。然而,它们在环境温度下表现出较低的离子电导率,并且与电极的界面特性较差,导致循环性能恶化。在这方面,兼具液体和固体电解质优点的凝胶聚合物电解质因其高离子电导率、与电极的良好界面附着力以及对电池内有机溶剂的有效包封,从而抑制溶剂泄漏,增强安全性而备受关注。本章综述了凝胶聚合物电解质在未来锂离子电池中的应用。
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引用次数: 0
CHAPTER 3. Modification of Layered Oxide Cathode Materials 第三章。层状氧化物正极材料的改性
Pub Date : 2019-03-14 DOI: 10.1039/9781788016124-00044
J. Dong, M. Hietaniemi, Juho Välikangas, T. Hu, U. Lassi
Layer-structured cathode materials for lithium-ion batteries are considered. These materials, such as LCO, NCM, NCA, lithium rich cathode oxides and blended cathodes are well-known for the intercalation mechanism. Future of lithium-ion batteries is also strongly based on these cathode chemistries, but to overcome some drawbacks and challenges, the improved materials are needed. In this chapter, modification of layer-structured cathode materials by doping and coating are discussed. Especially, coating materials and doping methods are considered.
研究了锂离子电池的层状结构正极材料。这些材料,如LCO、NCM、NCA、富锂阴极氧化物和混合阴极,以其插层机制而闻名。锂离子电池的未来也强烈地基于这些阴极化学,但为了克服一些缺点和挑战,需要改进的材料。本章讨论了层状结构正极材料的掺杂和涂层改性。特别考虑了涂层材料和掺杂方法。
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引用次数: 1
CHAPTER 4. Solid Electrolytes for Lithium Metal and Future Lithium-ion Batteries 第四章。用于锂金属和未来锂离子电池的固体电解质
Pub Date : 2019-03-14 DOI: 10.1039/9781788016124-00072
G. G. Eshetu, X. Judez, Chunmei Li, M. Martínez-Ibañez, Eduardo Sánchez-Díez, L. M. Rodriguez-Martinez, Heng Zhang, M. Armand
All solid-state lithium batteries (ASSLBs), with the elimination of flammable liquid solvents and possible safe use of high capacity electrodes, are believed to unlock the bottlenecks in energy density and safety for current Li-ion batteries. Being sandwiched between a highly reductive anode and an oxidative cathode, the nature of solid electrolytes (SEs) plays a pivotal role in dictating the electrochemical performance of ASSLBs. In this chapter, a brief introduction to the transport properties of SEs and a detailed survey of the status of research on SEs are presented. In particular, attention is paid to the very recent interesting findings and breakthroughs in the field of SEs, instead of screening/analyzing the physicochemical and electrochemical properties of reported electrolytes, which have been scrutinized in recently published reviews. Furthermore, remarks and thoughts on the existing challenges and future outlook are depicted.
所有固态锂电池(ASSLBs)都消除了易燃的液体溶剂,并可能安全使用高容量电极,有望解决当前锂离子电池在能量密度和安全性方面的瓶颈。夹在高还原性阳极和氧化性阴极之间,固体电解质(SEs)的性质在决定asslb的电化学性能方面起着关键作用。在这一章中,简要介绍了粒子的输运性质,并对粒子的研究现状进行了详细的综述。特别要注意的是SEs领域最近有趣的发现和突破,而不是筛选/分析已报道的电解质的物理化学和电化学性质,这在最近发表的评论中已经被仔细审查。并对当前面临的挑战和未来展望进行了评述和思考。
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引用次数: 6
CHAPTER 1. New High-energy Anode Materials 第1章。新型高能阳极材料
Pub Date : 2019-03-14 DOI: 10.1039/9781788016124-00001
J. Niu, Shuai Kang
New anode materials that can deliver higher specific capacities compared to the traditional graphite in lithium-ion batteries (LIBs) are attracting more attention. In this chapter, we discuss the current research progress on high-energy-density anode materials including various carbons, MXenes, silicon, metals, metal oxides, metal sulfides and lithium metal. Electrochemical reaction mechanisms such as electrode volume change, solid-electrolyte interphase formation, and the corresponding solutions are discussed respectively. In particular the Li metal in rechargeable Li–metal batteries, Li–air/oxygen batteries and Li–sulfur batteries is described.
与传统的锂离子电池(LIBs)石墨相比,具有更高比容量的新型负极材料正受到越来越多的关注。在这一章中,我们讨论了高能量密度负极材料的研究进展,包括各种碳、MXenes、硅、金属、金属氧化物、金属硫化物和金属锂。分别讨论了电极体积变化、固-电解质间相形成等电化学反应机理及其解决方案。特别描述了可充电锂金属电池、锂空气/氧电池和锂硫电池中的锂金属。
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引用次数: 1
CHAPTER 11. Advancements in Manufacturing 第十一章。制造业的进步
Pub Date : 2019-03-14 DOI: 10.1039/9781788016124-00262
E. Kendrick
Lithium ion battery (LIB) manufacturing was established in the 1990s by Sony; however, advancements in the processes and the scientific understanding of those processes upon the final cell performances are still being understood. A standard process for LIB manufacturing includes: ink mixing, coating and drying, cell construction and design, and the formation and conditioning steps. The material properties determine the mixing methodologies, and hence the dispersion of the particles in a mix or a slurry. Advancements in mixing technologies have been observed at large scale with a continuous process, however at small scale high energy and high torque mixing are still the main mixing methods. The main coating technology for thick electrode lithium ion cells is the slot die or comma bar techniques; alternative techniques such as electrostatic sprayings, and electrophoretic coatings are still mainly used for thinner electrode coatings. Advancements are being made in electrostatic dry coating and laser technologies. One of the most costly manufacturing procedures is the formation and conditioning step, and this process can be shortened by short high voltage cycling rather than complete cycles. Due to the complex interplay of each process upon the final design, structure and hence properties of the lithium ion battery, when one parameter is changed, it can affect the final performance of the cell. The knock-on effects of the parameter changes are not completely understood until a cell has been manufactured and tested. This chapter discusses the manufacturing aspects of lithium and sodium ion batteries and the recent advancements in technology.
锂离子电池(LIB)制造由索尼公司于20世纪90年代建立;然而,这些过程的进展以及对这些过程对最终细胞性能的科学理解仍有待了解。LIB制造的标准流程包括:油墨混合,涂层和干燥,电池结构和设计,以及形成和调理步骤。材料特性决定了混合方法,从而决定了颗粒在混合物或浆料中的分散。在大尺度上,混合技术的进步是一个连续的过程,但在小尺度上,高能和高扭矩混合仍然是主要的混合方法。厚电极锂离子电池的主要涂层技术是槽模或逗号条技术;替代技术,如静电喷涂和电泳涂层仍然主要用于较薄的电极涂层。静电干燥涂层和激光技术也取得了进展。最昂贵的制造过程之一是形成和调理步骤,这一过程可以通过短的高压循环而不是完整的循环来缩短。由于每个过程对锂离子电池的最终设计,结构和性能的复杂相互作用,当一个参数改变时,它可以影响电池的最终性能。在制造和测试细胞之前,参数变化的连锁效应还不能完全理解。本章讨论了锂和钠离子电池的制造方面以及最近的技术进展。
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引用次数: 6
CHAPTER 12. Lithium-ion Battery Safety 第十二章。锂离子电池安全
Pub Date : 2019-03-14 DOI: 10.1039/9781788016124-00290
W. Walker, Omar A. Ali, Dwight H. Theriot
Lithium-ion (Li-ion) batteries dominate the global energy storage market. Unfortunately, safety concerns for the utilization and transportation of these advanced energy storage devices exist due to the inherent possibility of thermal runaway. This chapter provides a detailed description of what Li-ion battery thermal runaway is and how it is characterized. Discussion is given on several high visibility field failure incidents. An introduction is provided on the modeling methods and primary testing techniques used to characterize thermal runaway. Last, a brief discussion is given on future trends and expectations associated with Li-ion battery safety.
锂离子(Li-ion)电池主导着全球储能市场。不幸的是,由于热失控的固有可能性,这些先进的储能装置的使用和运输存在安全问题。本章详细介绍了什么是锂离子电池热失控及其特征。讨论了几起高能见度现场故障事件。介绍了用于表征热失控的建模方法和主要测试技术。最后,简要讨论了锂离子电池安全的未来趋势和预期。
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引用次数: 0
期刊
Future Lithium-ion Batteries
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