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DFT and TD-DFT study of novel triphenylamine based organic dyes for dye-sensitized solar cells 染料敏化太阳能电池用新型三苯胺基有机染料的DFT和TD-DFT研究
Pub Date : 2020-06-01 DOI: 10.1109/REDEC49234.2020.9163607
A. Slimi, M. Hachi, A. Fitri, A. Benjelloun, M. Benzakour, M. Mcharfi
Dye Sensitized Solar Cells (DSSC) are a low-cost alternative to our renewable energy sources in recent decades because they have a potential to achieve high power conversion efficiency (PCE) and their devices are easy to manufacture. For a better understanding of the charge transport process involved in the DSSCs, we studied the effect of conjugation on the electron structure and optical properties of triphenylamine derivatives, we carried out a theoretical study on six organic dyes synthesized by Yu et al. In this work, we studied the effect of different substituents on the electronic and optical properties of six triphenylamine dyes using quantum chemistry methods such as DFT and TDDFT. These calculations were undertaken by the functional hybrid exchange and correlation B3LYP and the base 6-31G (d, p). This model allowed us to determine the optimized structures and the electronic and optical properties (EHOMO, ELUMO, Egap, $lambda_{abs}$, Voc….) Of various dyes studied. We note that the dye P6 exhibits the lowest gap energy and reasonable Voc value. We also simulated the UV-visible spectrum by using the TD-DFT with two functionals CAM-B3LYP and WB97XD to give a look for their effect on optical properties introducing the effect of the solvent (THF). Our results show that the six studied dyes absorb in the visible and are a good promising choice for DSSCs.
染料敏化太阳能电池(DSSC)是近几十年来可再生能源的低成本替代品,因为它们具有实现高功率转换效率(PCE)的潜力,而且它们的设备易于制造。为了更好地理解DSSCs中的电荷输运过程,我们研究了共轭对三苯胺衍生物电子结构和光学性质的影响,我们对Yu等人合成的六种有机染料进行了理论研究。本文采用量子化学方法(DFT和TDDFT)研究了不同取代基对六种三苯胺染料的电子和光学性质的影响。这些计算是由B3LYP和碱基6-31G (d, p)的功能杂化交换和相关进行的。该模型使我们能够确定优化的结构和电子和光学性质(EHOMO, ELUMO, Egap, $lambda_{abs}$, Voc....)。各种染料的研究。我们注意到染料P6具有最低的间隙能和合理的Voc值。我们还利用具有CAM-B3LYP和WB97XD两个官能团的TD-DFT模拟了紫外可见光谱,并引入了溶剂(THF)的影响,研究了它们对光学性质的影响。结果表明,所研究的六种染料在可见光下的吸收是一种很有前途的DSSCs选择。
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引用次数: 1
Adaptive Backstepping Control and Stabilization of VSC-HVDC Systems VSC-HVDC系统的自适应反演控制与镇定
Pub Date : 2020-06-01 DOI: 10.1109/REDEC49234.2020.9163905
Kazi Mohamed amine, Machkour Nadia, Majdoul Radouane
today, electricity transmission capacity is growing due to renewable energy generation and the needs of the electricity market. The result is a major breakthrough in the development of HVDC transport systems to overcome the limitations of HVAC transport systems. This progress is linked to the innovation of new topologies of power converters which play a key role in providing the high reliability, good efficiency and cost-effectiveness of HVDC transport systems. This article discusses a non-linear control approach based on the Adaptive Backstepping method in order to regulate the DC bus voltage and ensure stability of the HVDC system despite disturbances. The validity of the proposed control is tested by simulation in the Matlab/Simulink environment under different operating conditions and effectively demonstrates its contribution to improving the performance of our system.
今天,由于可再生能源发电和电力市场的需求,输电能力正在增长。其结果是HVDC输电系统发展的重大突破,克服了HVAC输电系统的局限性。这一进展与电力转换器新拓扑结构的创新有关,它在提供高压直流输电系统的高可靠性、高效率和成本效益方面发挥着关键作用。本文讨论了一种基于自适应反步法的非线性控制方法,以调节直流母线电压,保证高压直流系统在扰动下的稳定性。在Matlab/Simulink环境中,通过不同工况下的仿真验证了所提控制方法的有效性,有效地证明了所提控制方法对提高系统性能的贡献。
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引用次数: 0
Treatment of dairy waste by anaerobic digestion to produce methane as green energy 厌氧消化处理乳制品废弃物,产生沼气作为绿色能源
Pub Date : 2020-06-01 DOI: 10.1109/REDEC49234.2020.9163848
Jean H. El Achkar, Rita Ziade, N. Louka, R. Maroun, Zeina Hobaika
Treatment and management of lactoserum from dairy industry has become a global issue. In fact, generated effluents have high organic loads (lactose, protein, vitamin, minerals etc.) constituting a major source of environmental pollution. In a sustainable green approach, anaerobic digestion is considered a promising solution for the treatment of lactoserum or cheese whey. At first, we conducted a biochemical characterization showing a lactose composition of 52 and 46 g/kg, for sweet and acidic cheese whey, respectively, with an average COD of about 70 g/kg. The biodegradability of sweet lactoserum showed an extremely high value of 97% equivalent to 0.34 $mathrm{N}mathrm{m}^{3}mathrm{C}mathrm{H}_{4}cdot mathrm{k}mathrm{g} mathrm{C}mathrm{O}mathrm{D}^{-1}$. However, low biodegradability was noted for acidic lactoserum with a value of17%. This highlights the importance of the use of the sweet one in terms of energy recovery. For the optimization of the process, we also tried an incursion towards little explored tracks by evaluating the intensification of methane production, applying ultrasounds pretreatment on inoculum. The best yield was obtained after sonication with an energy input of 90 kJ/kg.
乳业乳血清的处理和管理已成为一个全球性的问题。事实上,所产生的废水具有高有机负荷(乳糖、蛋白质、维生素、矿物质等),是环境污染的主要来源。在可持续的绿色方法中,厌氧消化被认为是处理乳血清或奶酪乳清的有前途的解决方案。首先,我们进行了生化表征,显示甜味和酸性奶酪乳清的乳糖组成分别为52和46 g/kg,平均COD约为70 g/kg。甜乳血清的生物降解率高达97%,相当于0.34 $mathrm{N}mathrm{m}^{3}mathrm{C}mathrm{H}_{4}cdot mathrm{k}mathrm{g} mathrm{C}mathrm{O}mathrm{D}^{-1}$。然而,酸性乳血清的生物降解率较低,为17%。这突出了在能量回收方面使用甜味的重要性。为了优化工艺,我们还尝试通过对接种物进行超声预处理来评估甲烷产量的增加,从而进入探索较少的轨道。在输入能量为90 kJ/kg的超声条件下,产率最高。
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引用次数: 1
Autonomous Solar-Based Aquaponics: Towards Agricultural Sustainability in Lebanon and the Region 自主太阳能水培:在黎巴嫩和该地区实现农业可持续发展
Pub Date : 2020-06-01 DOI: 10.1109/REDEC49234.2020.9163832
Haytham M. Dbouk, Fawzi G. Khalife
With the exponential growth that affected the world population during the past two centuries, huge demand for food resulted, and traditional practices could not meet such overwhelming amounts. Newly developed techniques became a must to secure the food need, and aquaponics being one of these technologies, rose as a unique system that mimics the natural lifecycle. Aquaponics systems are still being enhanced to facilitate their use and increase their efficiency. This paper introduces an autonomous solar-based aquaponics system that utilized solar energy to meet water temperature demands of the fish and plants within the system. A pilot system is also presented and results are shown and discussed, illustrating the added efficiency and benefits such integration offers to aquaponics. The experimental results obtained during the past 6 months show that this system offers 30% productivity increase upon 60% saving in required space for this planting and 40% water savings.
在过去的两个世纪里,随着影响世界人口的指数增长,对食物的巨大需求产生了,传统的做法无法满足这种压倒性的需求。新开发的技术成为确保食物需求的必要条件,而鱼菜共生技术是这些技术之一,作为一种模仿自然生命周期的独特系统而崛起。水培系统仍在改进,以方便其使用和提高其效率。本文介绍了一种利用太阳能来满足系统内鱼类和植物对水温需求的自主式太阳能鱼菜共生系统。还介绍了一个试验系统,并对结果进行了展示和讨论,说明了这种集成为鱼菜共生提供的额外效率和效益。过去6个月的试验结果表明,该系统可提高30%的生产力,节省60%的种植面积,节约40%的水。
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引用次数: 1
Assessing the Effect of Temperature on Degradation Modes of PV Panels 温度对光伏板退化模式影响的评估
Pub Date : 2020-03-24 DOI: 10.1109/redec49234.2020.9163604
B. Nehme, N. M'Sirdi, T. Akiki, B. Zeghondy
PV panels are affected by many degradation modes. We list the Potential Induced Degradation, the Light Induced Degradation, the UltraViolet Light Degradation, the Moisture Induced Degradation, and the Cell Cracks. These degradation modes are affected by external environmental conditions as irradiance, temperature and humidity. The common factor that affects the degradation modes is temperature. The degradation process follows an Arrhenius equation; it is exponentially related to temperature. In this paper we evaluate precisely the effect of temperature on the degradation process of PV panels.
光伏板受到多种退化模式的影响。我们列出了电位诱导降解、光诱导降解、紫外光降解、水分诱导降解和细胞裂纹。这些降解模式受辐照度、温度和湿度等外部环境条件的影响。影响降解模式的常见因素是温度。降解过程遵循阿伦尼乌斯方程;它与温度呈指数关系。本文精确地评价了温度对光伏板降解过程的影响。
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引用次数: 4
Sliding Mode Observer Design for Battery State of Charge estimation 电池充电状态估计的滑模观测器设计
Pub Date : 2020-03-23 DOI: 10.1109/REDEC49234.2020.9163592
H. Bouchareb, K. Saqli, N. M'Sirdi, M. O. Bentaie, A. Naamane
In this paper, Lithium-Ion battery is modeled as a second-order RC Equivalent Circuit Model (ECM). The battery has been analysed and physically simulated by a software using infinite dimensional equations (Comsol) to get realistic data. The latter has been used to estimate the parameters of this model. Furthermore, the battery State of Charge (SOC) is then estimated based on an improved Sliding Mode Observer (SMO).
本文将锂离子电池建模为二阶RC等效电路模型(ECM)。使用无限维方程软件(Comsol)对电池进行了分析和物理模拟,以获得真实的数据。后者已被用来估计该模型的参数。此外,基于改进的滑模观测器(SMO)估计电池的充电状态(SOC)。
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引用次数: 2
期刊
2020 5th International Conference on Renewable Energies for Developing Countries (REDEC)
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