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Properties, Selection, Processing, Characterization and Applications of Aluminium - Boron Carbide Metal Matrix Composites: A Comprehensive Review 铝-碳化硼金属基复合材料的性能、选择、加工、表征及应用综述
Pub Date : 2023-07-01 DOI: 10.13189/ujms.2023.110101
A. Dixit, H. B, Ashok B C, A. S L
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引用次数: 0
Nanotoxicity of Emerging NMC-Family Energy Storage Nanomaterials 新兴nmc家族储能纳米材料的纳米毒性研究
Pub Date : 2022-06-01 DOI: 10.13189/ujms.2022.100101
Temitope D. Soneye, Oladipo O. Olatunji, E. Adesanya
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引用次数: 0
Fabrication and Characterization of Li2CO3 Modified Low Temperature Sintered PZT-5H Compositions for Multilayer Piezoelectric Ceramics Li2CO3改性低温烧结PZT-5H多层压电陶瓷复合材料的制备与表征
Pub Date : 2021-12-01 DOI: 10.13189/ujms.2021.090201
Mert Gül, Aysegül Toktaş, Hakan Güleç, M. Gürbüz, A. Dogan
In the use of piezocermic applications, piezoceramic compositions have high d 33 (>500 pC/N) and Kt (2000) such as PZT-5H. However, these ceramics can be sintered at high temperatures up to 1200˚C). Since these require the use of Ag-Pd inner electrodes with higher Pd ratio, multilayer ceramics are not preferred due to their high costs. In this study, it was aimed to reduce the sintering temperature without dramatically losing the electrical properties of the PZT-5H ceramics with high d 33 , kp and dielectric constant values. In this context, the PZT-5H composition was modified with different proportions of Li 2 CO 3 and sintered for 2-4 hours at different sintering temperatures such as 875˚C-1250˚C depending on the ratio of additions. The piezoelectric and ferroelectric properties of the ceramics were investigated and obtained values were compared with undoped PZT-5H. It was observed that the d 33 values of the different amount of Li 2 CO 3 added compositions sintered at optimum sintering temperature are close that the composition without additives. In this way, it is predicted that 9/1 Ag/Pd and Ag inner electrode materials can be used in multilayer production and their costs can be reduced.
在压电陶瓷应用中,压电陶瓷成分具有高d33 (>500 pC/N)和Kt(2000),如PZT-5H。然而,这些陶瓷可以在高达1200˚C的高温下烧结。由于这些都需要使用具有更高Pd比的Ag-Pd内电极,多层陶瓷由于其高成本而不是首选。在本研究中,旨在降低烧结温度,而不显着损失具有高d33, kp和介电常数值的PZT-5H陶瓷的电学性能。在此背景下,采用不同比例的Li 2 CO 3对PZT-5H组分进行改性,并根据添加量的不同,在875℃-1250℃的不同烧结温度下烧结2 ~ 4 h。研究了该陶瓷的压电和铁电性能,并与未掺杂的PZT-5H进行了比较。结果表明,在最佳烧结温度下烧结的不同添加量的li2co3组分的d33值与未添加添加剂的组分接近。预测9/1 Ag/Pd和Ag内电极材料可用于多层生产,降低成本。
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引用次数: 0
Electrospun Chitosan/Silver Doped-Hydroxyapatite Nano-Fibers on Thermal Conductivity Modified Si3N4 Ceramics with Different Sintering Cooling Rate 电纺丝壳聚糖/掺银羟基磷灰石纳米纤维在不同烧结冷却速率下导热改性Si3N4陶瓷上的研究
Pub Date : 2021-06-01 DOI: 10.13189/ujms.2021.090101
M. Gürbüz, Pınar Uyan
Dental implants are exposed to cycle loadings and thermal changes. The thermal properties of the materials in dentistry are important in terms of the biological changes that these materials will create in living tissues. The normal temperature of the oral cavity varies between 32-37℃, while eating, it can vary between 0-80℃ with hot-cold foods which led to the trauma and implant deteriorations. Si3N4 ceramic is a good candidate to solve these problems due to its inertness, high fracture toughness, strength, high thermal shock resistance and low density. Also, the surface modification of Si3N4 is important to enhance the interaction between the implant and bone. In recent years, biodegradable organic biomaterials as CTs (CTs) and silver doped hydroxyapatite (HAPs) combinations have a great attention to improve the Si3N4 effectiveness. In this study, MgO, SiO2, and Y2O3 included substrates were fabricated for fast and slow cooling rate during sintering in dental applications. CTs/HAPs fibers were coated with the electrospinning method to develop a modified Si3N4 substrate. The crystal structure, microstructure and thermal diffusivity measurement of the substrates and spun surfaces were characterized with XRD, SEM and Laser Flash Method. From the results, the higher density (3.25g/cm3) and thermal conductivity (46.35W/mK) for Si3N4 were observed for the fast cooling process during sintering compared with the slow cooling process (3.22g/cm3 and 44.60 W/mK). The hardness and strength of the fast cooled substrate were measured as 1350 HV and 1800 MPa which are greater than the slowly cooled samples (1190 HV, 1670 MPa). CTs /HAPs fibers are homogeneously deposited with electrospinning on the surface of the fast cooled Si3N4 substrate to develop the surface functionality. This functionalized substrate can be a candidate in dental applications.
牙种植体暴露于循环载荷和热变化。牙科材料的热性能对于这些材料将在活组织中产生的生物变化非常重要。口腔的正常温度在32-37℃之间,而进食时,由于冷热食物,口腔温度可在0-80℃之间变化,导致创伤和种植体变质。氮化硅陶瓷具有惰性、高断裂韧性、高强度、高抗热震性和低密度等优点,是解决这些问题的良好选择。此外,Si3N4的表面修饰对于增强种植体与骨的相互作用也很重要。近年来,可生物降解的有机生物材料如ct (CTs)和掺银羟基磷灰石(HAPs)的组合物在提高氮化硅的有效性方面受到了极大的关注。在本研究中,MgO, SiO2和Y2O3的基体在牙科应用的烧结过程中具有快速和缓慢的冷却速度。采用静电纺丝法包覆ct /HAPs纤维,制备了改性的Si3N4衬底。采用XRD、SEM和激光闪蒸法对衬底和纺丝表面的晶体结构、微观结构和热扩散率进行了表征。结果表明,在烧结过程中,快速冷却Si3N4的密度(3.25g/cm3)和导热系数(46.35W/mK)高于缓慢冷却Si3N4的密度(3.22g/cm3和44.60 W/mK)。快速冷却的基体硬度和强度分别为1350 HV和1800 MPa,高于缓慢冷却的基体硬度和强度分别为1190 HV和1670 MPa。通过静电纺丝将CTs /HAPs纤维均匀沉积在快速冷却的Si3N4衬底表面,以开发表面功能。这种功能化基质可以作为牙科应用的候选材料。
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引用次数: 0
Development and Testing of High Performance Nylon12 (PA12) Based Natural Fiber Composites 高性能尼龙12 (PA12)基天然纤维复合材料的研制与试验
Pub Date : 2020-12-01 DOI: 10.13189/UJMS.2020.080301
Siddhartha Brahma, Garo Tritrian, S. Pillay, Na Lu, H. Ning
Kenaf based nylon 12 (PA12) composites were successfully made using hydroentanglement and film stack compression molding. The combination of natural fibers with an engineering polymer with a relatively low melting temperature can potentially have high strength and modulus composites. The chopped kenaf fibers were treated in a NaOH solution. The NaOH treatment is used to improve the roughness of the surface and also expose cellulose fibers within the fibers to help improve bonding with the resin. Tensile tests of samples with treated and untreated fibers with a fiber weight fraction of 40% show that the treated fiber composite has an improvement of 13% and 18% in its strength and modulus respectively. The resulting fibers were used to make preforms using hydroentanglement process. The process of hydroentanglement is typically used in making paper products. The use of this process to make composite materials using chopped fibers is a very unique approach adopted for this research. Three different fiber weight fractions were looked at namely 40%, 50% and 60%. Tensile and flexure testing of the samples showed a consistent increase with an increase in the fiber weight fraction. Morphological characterization of the fibers showed that treatment removed excess fluff and dirt and also had striations on the fiber which would lead to better fiber wet-out. SEM images of the fractured surface of the sample with 50% by weight of kenaf fibers showed that there was some fiber bundling as expected leading to dry zones within the composite which could potentially lead to crack initiation. The novelty of the research is developing preforms using chopped natural fibers using hydroentanglement process and the ability to combine these natural fibers with low melting point PA 12 leading to obtaining high strength composite without compromising the structural integrity of the kenaf fibers.
采用水缠结和膜堆压缩成型技术成功制备了红麻基尼龙12 (PA12)复合材料。天然纤维与具有较低熔融温度的工程聚合物的结合可能具有高强度和模量的复合材料。在NaOH溶液中对红麻纤维进行处理。氢氧化钠处理用于改善表面的粗糙度,也暴露纤维内的纤维素纤维,以帮助改善与树脂的结合。对纤维质量分数为40%的经处理纤维和未处理纤维的拉伸试验表明,经处理的纤维复合材料的强度和模量分别提高了13%和18%。所得纤维采用水缠结工艺制备预成型。水缠结过程通常用于制造纸制品。利用该工艺制备短切纤维复合材料是本研究采用的一种非常独特的方法。研究人员观察了三种不同的纤维重量分数,即40%、50%和60%。样品的拉伸和弯曲测试表明,纤维重量分数的增加与纤维重量分数的增加一致。纤维的形态表征表明,处理去除了多余的绒毛和污垢,纤维上也有条纹,这将导致更好的纤维湿化。含有50%红麻纤维的试样断裂表面的SEM图像显示,如预期的那样,存在一些纤维束,导致复合材料内部出现干燥区,这可能导致裂纹萌生。该研究的新颖之处在于利用水缠结工艺开发使用短切天然纤维的预成型材料,并将这些天然纤维与低熔点pa12相结合,从而在不损害红麻纤维结构完整性的情况下获得高强度复合材料。
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引用次数: 0
Study of the High Performance Ceramic-Matrix Composites (CMC's) by Combustion in the TiO2–Al–C System 高性能陶瓷基复合材料在TiO2-Al-C体系中的燃烧研究
Pub Date : 2020-06-01 DOI: 10.13189/ujms.2020.080201
B. Bendjemil, J. Noudem, M. Mouyane, J. Bernard, Yannick Guel, D. Houivet
The purpose of this work is to decrease or eliminate porosities of ETER-VC (Electrothermal Explosion Reaction-Volume Combustion) products with the sintering additives. The Ti–C system has been synthesized for its advantages for refractory, abrasive and structural applications. We attempted to densify TiC by using iron addition; this metal is introduced through a reaction 3TiO3+Al+C. This mixture reacted exothermically (ϪH298 = -1072.7 kJ) and this heat is released according to the Fe addition using the following reaction: 3TiO3+4Al+3C+xFe→3TiC+2Al2O3+xFe. .X-ray diffraction analysis indicated that intermetallic Fe3Al, TiC and Al2O3 are the main phases formed in the reinforced high performance ceramic-matrix composites. The increasing of x wt. % iron decreased the lattice parameter of TiC. Field emission scanning electron microscopy examinations showed that the addition of Fe decreased TiC particle size and changed their growth controlling mechanism. Also, Raman spectroscopy analysis demonstrate that at higher Fe contents, oxygen dissolved in the TiC crystal structure leading to the formation of titanium oxy-carbide with lower lattice parameter and residual un-reacted carbon in the products. The adiabatic temperatures for the reactions containing x wt. % Fe estimated using the thermodynamic data according to Merzhanov criteria. Thus, doping method is finally used to fabricate materials by ETER-VC combustion mode for industrial applications.
本工作的目的是用烧结添加剂减少或消除e - vc(电热爆炸反应-体积燃烧)产品的孔隙率。Ti-C体系因其在耐火材料、磨料和结构方面的优点而被合成。我们尝试用铁的加入使TiC致密化;这种金属是通过3TiO3+Al+C反应引入的。该混合物进行了放热反应(ϪH298 = -1072.7 kJ),并根据Fe的加入进行了以下反应:3TiO3+4Al+3C+xFe→3TiC+2Al2O3+xFe。x射线衍射分析表明,增强高性能陶瓷基复合材料中主要形成了Fe3Al、TiC和Al2O3金属间相。随着xwt . %铁含量的增加,TiC的晶格参数降低。场发射扫描电镜观察表明,Fe的加入降低了TiC的粒径,改变了其生长控制机制。拉曼光谱分析表明,当铁含量较高时,氧溶解在TiC晶体结构中,形成晶格参数较低的碳化氧钛,产物中残留未反应碳。根据Merzhanov准则,用热力学数据估计了含x wt. % Fe的反应的绝热温度。因此,掺杂的方法最终被用于以ETER-VC燃烧方式制造工业应用的材料。
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引用次数: 0
Effects of Transition Energy on Intra-Band Photoluminescence of Zinc Oxide (ZnO) Semiconductor under Low injection Level 低注入能级下跃迁能对氧化锌半导体带内光致发光的影响
Pub Date : 2019-07-01 DOI: 10.13189/UJMS.2019.070301
Getu Endale
This paper presents the effects of the transition energies on photoluminescence intensities in Zinc Oxide compound semiconductor due to the intra-band transition of free carriers. The excitation of free carriers from the valence band to conduction band and from different localized state to the conduction band by the illumination of sufficient energy is considered. A theoretical model for minority carrier trapping is also investigated to explain the dependence of the photoluminescence on the trap energy. Variation of photoluminescence intensities along with localized state energy and transition energy is considered at different temperatures. As temperature increases the photoluminescence due to the transition of free electrons from the conduction band to the valence band, from the conduction band to the localized states and from the localized states to the valence band are increasing.
本文研究了自由载流子带内跃迁对氧化锌化合物半导体光致发光强度的影响。考虑了在足够能量的照射下,自由载流子从价带激发到导带,从不同定域态激发到导带。本文还研究了少数载流子捕获的理论模型,以解释光致发光对捕获能量的依赖。考虑了不同温度下光致发光强度随局域态能和跃迁能的变化。随着温度的升高,由于自由电子从导带跃迁到价带、从导带跃迁到局域态、从局域态跃迁到价带而产生的光致发光都在增加。
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引用次数: 2
Optimization of Manufacturing of Operational Amplifier Manufactured by Using Field-effect Heterotransistor to Decrease Their Dimensions 场效应异质晶体管运算放大器尺寸减小的工艺优化
Pub Date : 2019-04-01 DOI: 10.13189/UJMS.2019.070202
E. Pankratov
In this paper we introduce an approach to decrease dimensions of operational amplifier based on field-effect heterotransistors. Dimensions of the elements will be decreased due to manufacture heterostructure with specific structure, doping of required areas of the heterostruc-ture by diffusion or ion implantation and optimization of annealing of dopant and/or radiation defects.
本文介绍了一种基于场效应异质晶体管的运算放大器降维方法。由于制造具有特定结构的异质结构,通过扩散或离子注入掺杂异质结构所需区域以及优化掺杂和/或辐射缺陷的退火,元件的尺寸将减小。
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引用次数: 0
Optical Properties of Lead Doped Titanium Oxide of Thin Films Prepared by Sol-Gel Method at Low Temperature 溶胶-凝胶法制备铅掺杂氧化钛薄膜的低温光学性质
Pub Date : 2019-04-01 DOI: 10.13189/UJMS.2019.070203
F. Abbas, R. Bensaha
The present paper reports on the structural and optical properties of undoped and 5% Pb-doped TiO 2 thin films deposited on glass and silicon substrates prepared by the sol-gel technique have been investigated. Dip-coated thin films have been examined at different annealing temperatures (400-500℃). The results shows that Pb-doped TiO 2 thin films start to crystallize at low temperature (400℃). The morphology and surface structure of the films were studied by scanning electron microscopy (SEM) and atomic force microscopy (AFM) reveals a nanoporous structure of anatase and brookite with particle sizes ranging between 20 nm and 100 nm. Refractive index and porosity were calculated from the measured transmittance spectrum. SE study permits to determine the annealing temperature effect on the optical properties and the optical gap of the Pb-doped TiO 2 thin films. Photoluminescence (PL) spectrum revealed that emission increase with annealing temperature. A slight shift of transmission curves to higher wavelengths is observed for curves of Pb-doped TiO 2 thin films in comparison with those undoped, this was explained by the lowering of the band gap of TiO 2 .
本文研究了用溶胶-凝胶法制备的未掺杂和掺5%铅的二氧化钛薄膜在玻璃和硅衬底上的结构和光学性质。在不同的退火温度(400-500℃)下对浸涂薄膜进行了研究。结果表明:掺杂pb的tio2薄膜在低温(400℃)下开始结晶;通过扫描电子显微镜(SEM)和原子力显微镜(AFM)对膜的形貌和表面结构进行了研究,发现膜的粒径在20 ~ 100 nm之间,为锐钛矿和板铜矿的纳米孔结构。根据测得的透射光谱计算折射率和孔隙率。SE研究可以确定退火温度对掺杂pb的tio2薄膜光学性能和光学间隙的影响。光致发光(PL)光谱显示,随着退火温度的升高,发光量增加。与未掺杂的tio2相比,掺杂pb的tio2薄膜的透射曲线有轻微的向更高波长偏移,这是由于tio2的带隙减小所致。
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引用次数: 3
Double Interfacial Layers Effect on Optical Third-order Nonlinear Susceptibility, Refraction Index, and Absorption Coefficient of a Metal/ Dielectric Composite 双界面层对金属/介电复合材料三阶非线性磁化率、折射率和吸收系数的影响
Pub Date : 2019-04-01 DOI: 10.13189/UJMS.2019.070201
Berhanu Aragie
We investigate the way of enhancing the optical third order susceptibility, the refractive index, and absorption coefficient of a composite media in which identical nonlinear nanospheres having double interfacial layer randomly embedded in the linear host medium. We observe two maxima peaks of the nonlinear properties. We also show that the effect of double interfacial layers on the third order susceptibility, the refractive index, and absorption coefficient depends on the volume fraction metal/ dielectric nanosphers and the nature of the double interfacial layers. Under appropriate condition (nature of the two interfacial layer) we found two maximum peaks of the nonlinear properties. We also compare with the same composite without interfacial layer and in the presence of single interfacial layer and our finding shows that because of additional interfacial layer the effective medium exhibit a better third-order susceptibility, refractive index, and absorption coefficient.
研究了在线性介质中随机嵌入具有双界面层的非线性纳米球,提高其三阶光学磁化率、折射率和吸收系数的方法。我们观察到非线性性质的两个最大峰。我们还发现双界面层对三阶磁化率、折射率和吸收系数的影响取决于金属/介电纳米球的体积分数和双界面层的性质。在适当的条件下(两个界面层的性质),我们发现了非线性性质的两个最大峰。结果表明,由于增加了界面层,有效介质具有更好的三阶磁化率、折射率和吸收系数。
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引用次数: 0
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Universal Journal of Materials Science
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