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Results from the further development of CGI inversion on simulation and field data systems 在模拟和实地数据系统上进一步开发 CGI 反演的结果
Pub Date : 2024-03-25 DOI: 10.1556/24.2023.00131
Á. Gyulai, E. Turai, M. K. Baracza, Endre Nádasi, George Dankó
A new series expansion-based method, the Combined Geoelectric Weighted Inversion (CGWI) procedure is presented and tested by using synthetic and in-field measured datasets. The method is an improved version of the Combined Geoelectric Inversion (CGI) robustified by involving Cauchy-Steiner weights in an Iteratively Reweighted Least Squares technique. The new procedure is compared to the Fourier series expansion-based 1.5D and the CGI methods as well as to the broadly applied RES2DINV inversion procedure. The field measurements are performed during stone exploration in an active quarry on the south-western slopes of the Mátra mountains, in northern Hungary. It is shown that the CGWI method gives stable and robust parameter estimation with acceptable accuracy. The comparison with other inversion methods is based on data distances, estimation errors and correlation parameters calculated on the base of the parameter correlation matrix.
提出了一种基于序列扩展的新方法--组合地电加权反演(CGWI)程序,并使用合成数据集和现场测量数据集进行了测试。该方法是组合地电反演(CGI)的改进版,在迭代加权最小二乘法技术中加入了考奇-斯泰纳权重。新程序与基于傅立叶级数展开的 1.5D 和 CGI 方法以及广泛应用的 RES2DINV 反演程序进行了比较。实地测量是在匈牙利北部马特拉山西南山坡的一个活跃采石场进行的石料勘探过程中进行的。结果表明,CGWI 方法可提供稳定、可靠的参数估计,其准确性可以接受。与其他反演方法的比较基于数据距离、估计误差和根据参数相关矩阵计算的相关参数。
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引用次数: 0
Comparison of different preparation methods for oxygen isotope determination of phosphate in mammal tooth enamel 哺乳动物牙釉质中磷酸盐氧同位素测定不同制备方法的比较
Pub Date : 2023-11-06 DOI: 10.1556/24.2023.00132
Gabriella Ilona Kiss, Péter Szabó, Marianna Túri, István Futó, János Kovács, László Palcsu
Abstract We tested several sample pre-treatment protocols for the study of oxygen isotope ratios in the phosphate phase of mammalian enamel of ten different fossil samples. We investigated the effect of different pre-treatment methods and the duration of the hydrogen fluoride treatment on enamel samples from skeletal phosphate with known δ 18 O values. The samples had been measured previously, so we could compare the ratios measured in our laboratory with the previous values to choose the best chemical preparation procedure. Four pre-soaking methods and two different time intervals of 2 mol dm −3 hydrogen fluoride treatment were compared during our experiments. In our experimental conditions, the distilled water wash and the 6 h of soaking in hydrogen fluoride gave the closest results to the expected δ -values. The steps of the tested preparation processes were repeated at least three times on each sample, so the reproducibility of the process could be also investigated.
摘要为了研究10个不同化石样品的哺乳动物牙釉质磷酸盐相的氧同位素比值,我们测试了几种样品预处理方案。研究了不同预处理方法和氟化氢处理时间对已知δ 18o值的磷酸骨釉质样品的影响。样品之前已经测量过了,所以我们可以将我们实验室测量的比例与之前的值进行比较,以选择最佳的化学制备程序。实验中比较了4种预浸泡方法和2 mol dm−3氟化氢处理的2种不同时间间隔。在我们的实验条件下,蒸馏水洗涤和氟化氢浸泡6 h的结果与期望的δ值最接近。所测试的制备过程的步骤在每个样品上重复至少三次,因此该过程的再现性也可以进行调查。
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引用次数: 0
Pebbles, graphs and equilibria: Higher order shape descriptors for sedimentary particles 卵石、图和平衡:沉积颗粒的高阶形状描述符
Pub Date : 2023-11-06 DOI: 10.1556/24.2023.00135
Balázs Ludmány, Gábor Domokos
Abstract While three-dimensional measurement technology is spreading fast, its meaningful application to sedimentary geology still lacks content. Classical shape descriptors (such as axis ratios, circularity of projection) were not inherently three-dimensional, because no such technology existed. Recently a new class of three-dimensional descriptors, collectively referred to as mechanical descriptors, has been introduced and applied for a broad range of sedimentary particles. First-order mechanical descriptors (registered for each pebble as a pair {S, U} of integers), refer to the respective numbers of stable and unstable static equilibria and can be reliably detected by hand experiments. However, they have limited ability of distinction, as the majority of coastal pebbles fall into primary class . Higher-order mechanical descriptors offer a more refined distinction. However, for the extraction of these descriptors (registered as graphs for each pebble), hand measurements are not an option and even computer-based extraction from 3D scans offers a formidable challenge. Here we not only describe and implement an algorithm to perform this task, but also apply it to a collection of 271 pebbles with various lithologies, illustrating that the application of higher-order descriptors is a viable option for geologists. We also show that the so-far uncharted connection between the two known secondary descriptors, the so-called Morse–Smale graph and the Reeb-graph, can be established via a third order descriptor which we call the master graph.
摘要在三维测量技术迅速普及的同时,其在沉积地质中的有意义应用还缺乏内容。经典的形状描述符(如轴比、投影圆度)本质上不是三维的,因为没有这样的技术存在。最近,一种新的三维描述符被引入,并被广泛应用于沉积颗粒的描述。一阶力学描述符(为每个卵石注册为一对整数{S, U}),指的是稳定和不稳定静态平衡的各自数量,可以通过手工实验可靠地检测到。然而,它们的区分能力有限,因为大多数海岸卵石属于初级类。高阶机械描述符提供了更精细的区分。然而,对于这些描述符的提取(为每个鹅卵石注册为图形),手工测量不是一种选择,甚至基于计算机的3D扫描提取也带来了巨大的挑战。在这里,我们不仅描述和实现了执行该任务的算法,而且还将其应用于具有不同岩性的271块鹅卵石的集合,说明应用高阶描述符对于地质学家来说是一个可行的选择。我们还证明了两个已知的二级描述符,即所谓的Morse-Smale图和reeb图之间迄今为止未知的联系,可以通过我们称之为主图的三阶描述符来建立。
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引用次数: 0
Stable hydrogen isotope compositions of tourmalines from the Sopron metamorphic complex: Metamorphic closure temperature and fluid composition Sopron变质杂岩中电气石的稳定氢同位素组成:变质闭合温度和流体组成
Pub Date : 2023-11-06 DOI: 10.1556/24.2023.00137
Attila Demény
Abstract Stable hydrogen isotope compositions of metamorphic rocks and minerals can provide information on the origin of metamorphic fluids, which is especially important in systems that had experienced multiple metamorphic events. The Sopron orthogneiss-micaschist complex is a good target as it records signs of Variscan and Alpine metamorphic events as well as Variscan granitic magmatism. In this study tourmaline-bearing rocks (pegmatitic orthogneisses and kyanite-chlorite-muscovite schists) of the Sopron metamorphic complex were sampled and their tourmaline grains were analyzed for stable hydrogen isotope compositions (δ 2 H). The δ 2 H values (−23 ± 1‰, relative to V-SMOW) are in accordance with a fluid flux from devolatilization of subducted, seawater-containing rocks. Tourmaline-chlorite hydrogen isotope fractionations correspond to about 550 °C, indicating that δ 2 H values formed close to peak metamorphic temperatures are preserved without retrograde isotope exchange during cooling.
变质岩和矿物稳定的氢同位素组成可以提供变质流体起源的信息,这在经历多次变质事件的体系中尤为重要。Sopron正长岩-云母岩杂岩是一个很好的研究对象,因为它记录了Variscan变质事件和Alpine变质事件以及Variscan花岗岩浆活动的迹象。本文采集了Sopron变质杂岩中含电气石的岩石(花岗质正长岩和蓝绿绿白云母片岩),分析了其电气石颗粒的稳定氢同位素组成(δ 2 H), δ 2 H值(相对于V-SMOW为- 23±1‰)与俯冲、含海水岩石的脱挥发流体通量一致。电气石-绿泥石氢同位素分馏对应于550℃左右,表明冷却过程中δ 2 H值在接近变质峰温度时形成,没有发生逆同位素交换。
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引用次数: 0
Long-term performance of simultaneous measurement of stable isotopes of oxygen and carbon in cellulose with a high-temperature pyrolysis/gas chromatography/isotope ratio mass spectrometry system at the Institute for Geological and Geochemical Research 地质和地球化学研究所高温热解/气相色谱/同位素比值质谱系统同时测量纤维素中氧和碳的稳定同位素的长期性能
Pub Date : 2023-03-30 DOI: 10.1556/24.2023.00134
Z. Kern, Daniela Maria Llanos Campana, I. Hegyi
A high-temperature pyrolysis/gas chromatography/isotope ratio mass spectrometry system was established at the Institute for Geological and Geochemical Research in 2013. A dedicated field of application of the system is the simultaneous measurement of stable carbon and oxygen isotope ratios in the cellulose of modern, relict and subfossil plant tissues and sediments. The measurement protocol was fine-tuned during the first year of operation and documented in detail in this report. To quantify the long-term reproducibility of the simultaneous measurement of stable isotopes of oxygen and carbon in cellulose, a 2σ range inferred from repeated measurements of a Quality Assurance standard can be recommended: 0.16 and 0.20‰, for δ13C and δ18O, respectively. An extensive set of samples with known pyrolysis-based δ13C data was analyzed in combustion mode and the paired results were used to assess the necessity of adjustment of the pyrolysis-based δ13C measurements. The variances of the two datasets were not significantly different; the slope (intercept) of the regression was indistinguishable from unity (zero), suggesting that probably owing to the relatively frequent cleaning of the pyrolysis furnace, pyrolysis-based δ13C data neither suffer from a variance bias nor require a specific adjustment.
地质和地球化学研究所于2013年建立了高温热解/气相色谱/同位素比值质谱系统。该系统的一个专门应用领域是同时测量现代、残余和化石下植物组织和沉积物的纤维素中稳定的碳和氧同位素比率。测量方案在运行的第一年进行了微调,并在本报告中进行了详细记录。为了量化同时测量纤维素中氧和碳的稳定同位素的长期再现性,可以推荐从质量保证标准的重复测量推断出的2σ范围:δ13C和δ18O分别为0.16和0.20‰。在燃烧模式下分析了一组具有已知基于热解的δ13C数据的大量样品,并使用配对结果来评估调整基于热解的Δ13C测量的必要性。两个数据集的方差没有显著差异;回归的斜率(截距)与单位(零)无法区分,这表明可能由于热解炉的清洁相对频繁,基于热解的δ13C数据既不存在方差偏差,也不需要具体调整。
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引用次数: 0
Applications of automated Petrel workflows in 3D reservoir geologic modelling – A case study 自动海燕工作流程在三维油藏地质建模中的应用-一个案例研究
Pub Date : 2022-09-14 DOI: 10.1556/24.2022.00129
I. Nemes
Mature fields have been playing a significant role in the oil and gas realm recently, and redevelopment and optimization efforts are being made globally to prolong the lifetime of these resources. The aim of this study is to showcase the benefits of hydrocarbon reservoir modelling, with a special focus on various aspects of Petrel workflows. This article is a direct continuation of Nemes et al. (2021), which described the Phase 1 geomodel of the same field described in this study. The Phase 2 geomodel – the scope of the current article – is based on a significantly more complete, more detailed, and fundamentally rebuilt dataset compared to Phase 1. The seismic and petrophysical interpretations were updated, and additional data sources were incorporated into the analysis. The geomodel was created in Schlumberger's Petrel software, and during the building of it, a comprehensive 800-plus-step, full-cycle, automated workflow was outlined. The created workflow makes the model update faster by a minimum of five times, makes it more transparent and decreases the risk of human error. The created workflow describes the entire geomodelling process from data loading, via surface adjustments, structural modelling, and property modelling, to a closing of the loop with volumetric calculation. The whole workflow can be rerun easily, and beside the updates made to the geomodel, a full range of quality-check supporting calculations and visualizations were created in order to provide the user with full control. The geomodel showcased here is a key building block of the ongoing and planned development and redevelopment activities in the field, serves as a tool for well and workover planning, water injection system adjustments and a direct input to dynamic simulation, and also provides direct inputs to the documentation of an updated field development plan.
最近,成熟油田在石油和天然气领域发挥了重要作用,全球正在进行再开发和优化工作,以延长这些资源的使用寿命。本研究的目的是展示油气藏建模的好处,特别关注Petrel工作流的各个方面。本文是Nemes等人。(2021),其中描述了本研究中描述的同一领域的第一阶段地质模型。与第一阶段相比,第二阶段的地理模型(本文的范围)基于一个明显更完整、更详细、从根本上重建的数据集。更新了地震和岩石物理解释,并将额外的数据源纳入分析。地质模型是在斯伦贝谢的Petrel软件中创建的,在构建过程中,概述了一个800多步、全周期、自动化的综合工作流程。创建的工作流使模型更新速度至少快五倍,使其更加透明,并降低人为错误的风险。创建的工作流程描述了整个地质建模过程,从数据加载到表面调整、结构建模和特性建模,再到体积计算的闭环。整个工作流程可以很容易地重新运行,除了对地理模型进行更新外,还创建了一系列支持计算和可视化的质量检查,以便为用户提供完全的控制。这里展示的地质模型是油田正在进行和计划中的开发和再开发活动的关键组成部分,是油井和修井规划、注水系统调整和动态模拟的直接输入工具,也为更新油田开发计划的文件提供了直接输入。
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引用次数: 0
Fully spherical 3D datasets on sedimentary particles: Fast measurement and evaluation 沉积颗粒的全球面三维数据集:快速测量和评估
Pub Date : 2022-09-14 DOI: 10.1556/24.2022.00124
Eszter Fehér, Balázs Havasi-Tóth, Balázs Ludmány
Recently it became increasingly evident that the statistical distributions of size and shape descriptors of sedimentary particles reveal crucial information on their evolution and may even carry the fingerprints of their provenance as fragments. However, to unlock this trove of information, measurement of traditional geophysical shape descriptors (mostly detectable on 2D projections) is not sufficient; fully spherical 3D imaging and mathematical algorithms suitable to extract new types of inherently 3D shape descriptors are necessary. Available 3D imaging technologies force users to choose either speed or full sphericity. Only partial morphological information can be extracted in the absence of the latter (e.g., LIDAR imaging). In the case of fully spherical imaging, speed was proved to be prohibitive for obtaining meaningful statistical samples, and inherently 3D shape descriptors were not extracted. Here we present a new method by complementing a commercial, portable 3D scanner with simple hardware to quickly obtain fully spherical 3D datasets from large collections of sedimentary particles. We also present software for the automated extraction of 3D shapes and automated measurement of inherently 3D-shape properties. This technique allows for examining large samples without the need for transportation or storage of the samples, and it may also facilitate the collaboration of geographically distant research groups. We validated our software on a large sample of pebbles by comparing previously hand-measured parameters with the results of automated shape analysis. We also tested our hardware and software tools on a large pebble sample in Kawakawa Bay, New Zealand.
最近,越来越明显的是,沉积颗粒的大小和形状描述符的统计分布揭示了它们进化的关键信息,甚至可能以碎片的形式携带其来源的指纹。然而,为了解开这一信息宝库,传统的地球物理形状描述符(大多在2D投影上可检测)的测量是不够的;全球面3D成像和适合于提取新类型的固有3D形状描述符的数学算法是必要的。可用的3D成像技术迫使用户选择速度或全球度。在没有后者的情况下(例如,LIDAR成像),只能提取部分形态信息。在全球面成像的情况下,速度被证明无法获得有意义的统计样本,并且无法提取固有的3D形状描述符。在这里,我们提出了一种新方法,用简单的硬件补充商业便携式3D扫描仪,从大量沉积颗粒中快速获得全球形3D数据集。我们还提供了用于自动提取三维形状和自动测量固有三维形状特性的软件。这项技术可以在不需要运输或储存样本的情况下检查大样本,还可以促进地理位置遥远的研究小组的合作。我们通过将之前手工测量的参数与自动形状分析的结果进行比较,在大量卵石样本上验证了我们的软件。我们还在新西兰川川湾的一个大卵石样本上测试了我们的硬件和软件工具。
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引用次数: 2
First report on dendrochronological and radiocarbon studies of subfossil driftwood recovered across the Mureş/Maros Alluvial Fan Mureş/Maros冲积扇上发现的亚化石浮木的树木年代学和放射性碳研究的第一份报告
Pub Date : 2022-03-10 DOI: 10.1556/24.2021.00120
Z. Kern, M. Árvai, P. Urdea, F. Timofte, E. Antalfi, Sándor Fehér, Tamás Bartyik, G. Sipos
Visiting three gravel pits and three natural outcrops across the Mureş/Maros Alluvial Fan, 58 samples were collected from subfossil driftwood recovered from coarse-grained fluvial sediment layers, while no subfossil wood was found at three additional gravel pits. Dendrochronological and radiocarbon analysis of these relict wood can support the temporal extension of the regional dendrochronological reference datasets and their dating can provide a useful contribution to the reconstruction of the landscape evolution of the Mureş/Maros Alluvial Fan. The tree-ring widths of the subfossil samples were measured. Dendrochronological synchronization resulted in two oak chronologies which encompassed five, and two reliably cross-dated series covering 191 years (MURchr1) and 127 years (MURchr2), respectively. Based on the 14C ages the subfossil driftwood material represents Middle and Late Holocene ages. The occasionally up to 6 m-thick fluvial sediment covering relatively young, < 1000-yr-old wood, indicates intense accumulation at the apex of the Mureş/Maros Alluvial Fan, which explains the documented rapid and significant Holocene avulsions.
访问了Mureş/Maros冲积扇的三个砾石坑和三个天然露头,从粗粒河流沉积物层中回收的亚化石浮木中采集了58个样本,而在另外三个砾石池中没有发现亚化石木。这些残余木材的树木年代和放射性碳分析可以支持区域树木年代参考数据集的时间扩展,它们的年代测定可以为重建Mureş/Maros冲积扇的景观演变提供有用的贡献。测量了亚化石样本的树木年轮宽度。树木年代同步产生了两个橡树年表,包括五个,以及两个可靠的交叉年代系列,分别涵盖191年(MURchr1)和127年(MUR chr2)。根据14C年龄,亚化石漂流木材料代表全新世中期和晚期。偶尔高达6 m厚的河流沉积物覆盖着相对年轻、树龄<1000年的木材,表明Mureş/Maros冲积扇顶部有强烈的堆积,这解释了有记录的全新世快速而显著的剥蚀。
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引用次数: 0
Cave monitoring in Hungary: An overview 匈牙利洞穴监测:概述
Pub Date : 2021-12-20 DOI: 10.1556/24.2021.00109
In this study, already published and new monitoring data are compiled from the Baradla and Béke caves in the Aggtelek Karst, from the Vacska Cave in the Pilis Mountains as well as from the Szemlőhegy and Pálvölgy caves in the Buda Hills. Recent investigations (2019–2020) include monitoring of climatological parameters (e.g., temperature, CO2) measured inside and outside the caves, and the chemical, trace element and stable isotopic compositions of drip waters. In the Baradla Cave, the main focus of the investigation was on the stable isotope composition and the temperature measurements of drip water. In the Vacska Cave, which belongs to the Ajándék-Ariadne cave system, CO2 measurements and drip water collection were conducted in order to perform chemical and stable isotope measurements. In the Szemlőhegy and Pálvölgy caves, the chemical and stable isotope compositions of drip waters at six sites were determined. These datasets were used to characterize the studied caves and the hydrological processes taking place in the karst, and to trace anthropogenic influences. Climatological investigation revealed seasonality in CO2 concentration related to outside temperature variation, indicating a variable ventilation regime in the caves. In addition, the contributions of the winter and summer precipitation to the drip water were also estimated, in order to evaluate the main infiltration period. The knowledge of these parameters plays a crucial role in constraining the carbonate precipitation within the cave. Thus, the dataset compiled in this study can provide a basis for the interpretation of speleothem-based proxies.
在这项研究中,已经发表的和新的监测数据汇编自Aggtelek喀斯特的Baradla和b洞穴,来自皮利斯山脉的Vacska洞穴以及布达山的Szemlőhegy和Pálvölgy洞穴。最近的调查(2019-2020)包括监测洞穴内外测量的气候参数(如温度、二氧化碳),以及水滴的化学、微量元素和稳定同位素组成。在巴拉德拉洞穴,研究的重点是稳定同位素组成和滴水的温度测量。Vacska洞穴属于Ajándék-Ariadne洞穴系统,为了进行化学和稳定同位素测量,我们进行了CO2测量和滴水收集。在Szemlőhegy和Pálvölgy洞穴中,测定了6个地点滴落水的化学和稳定同位素组成。这些数据集用于描述所研究的溶洞和喀斯特发生的水文过程,并追踪人为影响。气候学调查显示,CO2浓度的季节性变化与外部温度变化有关,表明洞穴内存在不同的通风机制。此外,还估算了冬季和夏季降水对滴落水的贡献,以评价主要入渗期。这些参数的掌握对控制洞内碳酸盐沉积起着至关重要的作用。因此,本研究编制的数据集可以为基于洞穴的代理解释提供依据。
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引用次数: 1
Development and dolomitization of Anisian isolated carbonate platforms in the Transdanubian Range, Hungary 匈牙利外多瑙河山脉Anisian孤立碳酸盐台地发育与白云化
Pub Date : 2021-12-17 DOI: 10.1556/24.2021.00110
J. Haas, Tamás Budai, Gyulai Orsolya, Orgy CZUPPONp
In the Middle Anisian, extensional tectonic movements led to the development of isolated carbonate platforms in the area of the southwestern part of the Transdanubian Range. The platforms are made up of meter-scale peritidal–lagoonal cycles bounded by subaerial exposure surfaces. One of the platform successions (Tagyon Platform) consists predominantly of limestone that contains partially and completely dolomitized intervals, whereas the other one (Kádárta Platform) is completely dolomitized. Drowning of the platforms took place in the latest Pelsonian to the early Illyrian interval when submarine highs came into existence and then condensed pelagic carbonate successions with volcanic tuff interbeds were deposited on the top of the drowned platforms from the late Illyrian up to the late Ladinian. The comparative study of dolomitization of the coeval platforms, affected by different diagenetic histories, is discussed in the current paper. Traces of probably microbially-mediated early dolomitization were preserved in the slightly dolomitized successions of the Tagyon Platform. This might also have been present in the successions of the Kádárta Platform, but was overprinted by geothermal dolomitization along the basinward platform margin and by pervasive reflux dolomitization in the internal parts of the platform. The Carnian evolution of the two submarine highs was different, and this may have significantly influenced the grade of the shallow to deeper burial dolomitization.
中阿尼西期伸展构造运动使外多瑙河山脉西南部地区发育了孤立的碳酸盐岩台地。这些平台由米尺度的潮汐-泻湖旋回组成,由地面暴露面包围。其中一个台地序列(塔格扬台地)主要由石灰岩组成,其中包含部分和完全白云化的层段,而另一个台地序列(Kádárta台地)则完全白云化。台地沉陷发生在晚佩尔森期至早伊利里亚期,此时海底隆起形成,晚伊利里亚期至晚拉底宁期在台地顶部沉积了具有火山凝灰岩互层的凝析海相碳酸盐岩序列。本文讨论了受不同成岩历史影响的同时期台地白云化的对比研究。在塔吉渊地台的轻度白云化序列中保存了可能由微生物介导的早期白云化痕迹。这可能也存在于Kádárta台地层序中,但被盆地向内台地边缘的地热白云化和台地内部普遍的回流白云化所覆盖。两个海底隆起的卡尼期演化不同,这可能对浅埋至深埋白云化程度有重要影响。
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引用次数: 0
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Central European Geology
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