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Silicification and organic matter preservation in the Anisian Muschelkalk: Implications for the basin dynamics of the central European Muschelkalk Sea 安尼西亚Muschelkalk的硅化和有机质保存:对中欧Muschelkalk海盆地动力学的启示
Pub Date : 2017-03-01 DOI: 10.1556/24.60.2017.002
A. Götz, M. Montenari, G. Costin
Anisian Muschelkalk carbonates of the southern Germanic Basin containing silicified ooidal grainstone are interpreted as evidence of changing pH conditions triggered by increased bioproductivity (marine phytoplankton) and terrestrial input of plant debris during maximum flooding. Three distinct stages of calcite ooid replacement by silica were detected. Stage 1 reflects authigenic quartz development during the growth of the ooids, suggesting a change in the pH–temperature regime of the depositional environment. Stages 2 and 3 are found in silica-rich domains. The composition of silica-rich ooids shows significant Al2O3 and SrO but no FeO and MnO, indicating that late diagenetic alteration was minor. Silicified interparticle pore space is characterized by excellent preservation of marine prasinophytes; palynological slides show high abundance of terrestrial phytoclasts. The implications of our findings for basin dynamics reach from paleogeography to cyclostratigraphy and sequence stratigraphy, since change...
日耳曼盆地南部的Anisian Muschelkalk碳酸盐岩含有硅化鲕粒岩,被解释为最大洪水期间生物生产力增加(海洋浮游植物)和陆地植物碎屑输入引发pH条件变化的证据。方解石被二氧化硅取代的三个不同阶段被检测到。第1阶段为自生石英发育阶段,表明沉积环境ph -温度变化。阶段2和阶段3位于富硅域。富硅流体中Al2O3和SrO含量显著,而FeO和MnO含量不显著,表明晚期成岩蚀变较小。硅化颗粒间孔隙空间的特点是保存较好;孢粉玻片显示大量陆生植物碎屑。我们的发现对盆地动力学的意义从古地理延伸到旋回地层学和层序地层学。
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引用次数: 2
Recently forming stalagmites from the Baradla Cave and their suitability assessment for climate-proxy relationships 巴拉德拉洞穴最近形成的石笋及其气候代理关系的适宜性评估
Pub Date : 2017-02-27 DOI: 10.1556/24.60.2017.001
A. Demény, A. Németh, Z. Kern, G. Czuppon, M. Molnár, S. Leél-Őssy, M. Óvári, J. Stieber
Determination of the long-term behavior of cave systems and their response to changing environmental conditions is essential for further paleoclimate analyses of cave-hosted carbonate deposits. For this purpose, four actively forming stalagmites were collected in the Baradla Cave where a three-year monitoring campaign was also conducted. Based on textural characteristics and radiocarbon analyses, the stalagmites are composed of annual laminae, whose counting was used to establish age–depth relationships. Fast and slowly growing stalagmites have different stable carbon and oxygen isotope compositions as well as trace element contents that could be attributed to differences in drip water migration pathways. The stable isotope compositions were compared with meteorological data of the last ∼100 years indicating that carbon isotope compositions of the stalagmites may reflect changes in precipitation amount, while oxygen isotope compositions are more related to temperature variations. The combined textural–geo...
确定洞穴系统的长期行为及其对变化的环境条件的响应对于进一步分析洞穴型碳酸盐矿床的古气候至关重要。为此目的,在巴拉德拉洞穴中收集了四个正在形成的石笋,并进行了为期三年的监测活动。根据石笋的结构特征和放射性碳分析,石笋由年际纹层组成,利用纹层数建立了石笋的年龄-深度关系。速生石笋和慢生石笋具有不同的稳定碳、氧同位素组成和微量元素含量,这可能与滴落水迁移途径的差异有关。将稳定同位素组成与近100年的气象资料进行比较,表明石笋的碳同位素组成可能反映降水量的变化,而氧同位素组成与温度变化的关系更大。结合纹理-地理…
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引用次数: 16
Benthic algae as major precursors of oil-prone kerogen – A case study from the Hungarian Middle Miocene 底栖藻类是亲油干酪根的主要前体——以匈牙利中新世中为例
Pub Date : 2016-11-14 DOI: 10.1556/24.59.2016.004
I. Vető, K. Báldi, S. Ćorić, M. Hetényi, A. Demény, I. Futó
This study is intended to clarify the depositional environment of a 180-m-thick, immature, limy Middle Miocene oil source rock interval, cored in the Zala Basin, western Hungary. For this purpose, a highly interdisciplinary approach was applied combining simple, standard micropaleontological, isotopic, and organic geochemical methods, rarely applied together. Foraminifera were studied for estimating bottom oxygenation and water depth, while nannoplankton biostratigraphy permitted for estimating the rate of sedimentation. The studied source rocks were deposited in a rather shallow sea, below well-oxygenated bottom water. The abundant epiphytic foraminiferal fauna proves that the bottom was densely inhabited by benthic algae, while the high δ13Corg (>–22‰) clearly indicates massive benthic algal contribution to the kerogen. Mass accumulation rate of the limy upper part of the NN5 nannoplankton biozone, the oil source interval included, was very high (551 t/m2/Ma). In spite of moderate productivity and good ...
本研究旨在厘清匈牙利西部Zala盆地一个厚180 m、未成熟、灰质中中新世烃源岩段的沉积环境。为此,采用了一种高度跨学科的方法,将简单、标准的微古生物学、同位素和有机地球化学方法结合起来,很少同时应用。研究有孔虫用于估算海底氧合和水深,而纳米浮游生物地层学用于估算沉积速率。所研究的烃源岩沉积在一个相当浅的海洋中,在含氧良好的底部水下面。丰富的附生有孔虫动物群证明了底栖藻类的密集分布,而高δ13Corg(> ~ 22‰)则表明底栖藻类对干酪根有大量贡献。包括油源段在内的NN5纳米浮游生物带边缘上部的质量积累速率非常高(551 t/m2/Ma)。尽管生产率中等,而且……
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引用次数: 1
Petrology and paleokarst features of the Gomba hydrocarbon reservoir (central Hungary) 匈牙利中部贡巴油气储层岩石学及古岩溶特征
Pub Date : 2016-11-11 DOI: 10.1556/24.59.2016.003
M. Bauer, T. Tóth, B. Raucsik, István Garaguly
The pre-Cenozoic basement of central Hungary is partly made up of different types of carbonate rocks. These carbonates are often good hydrocarbon reservoirs, and hydrocarbon production is significant in this region in Hungary. Nonetheless, the petrography of the reservoir rocks has not yet been investigated in detail. In this study, the results of the investigations of the lithology of a carbonate hydrocarbon reservoir from central Hungary (Gomba Field) are presented. Based on this work, two types of pure limestone, a dolomitic limestone and a polymictic breccia, could be distinguished in the study area. The limestone types are similar to the Kisfennsik Limestone Member and the Berva Limestone of the Bukk Mountains, but they contain significant amounts of framboidal pyrite and dead oil as vein fillings. The breccia is predominantly composed of angular carbonate clasts and minor metamorphic and sedimentary rock fragments in a chaotic pattern. The breccia has some grains that may be speleothems (e.g., stala...
匈牙利中部前新生代基底部分由不同类型的碳酸盐岩组成。这些碳酸盐岩通常是良好的油气储集层,在匈牙利的这一地区油气产量显著。然而,储层岩石学尚未得到详细的研究。本文介绍了匈牙利中部(Gomba油田)碳酸盐岩油气藏的岩性研究结果。在此基础上,研究区可划分出白云岩灰岩和多晶角砾岩两类纯灰岩。灰岩类型与Bukk山脉的Kisfennsik灰岩段和Berva灰岩相似,但含有大量的树状黄铁矿和死油作为脉体充填物。角砾岩主要由角状碳酸盐碎屑和少量变质岩和沉积岩碎屑组成,呈混沌状。角砾岩有一些可能是洞穴的颗粒(例如,石笋……
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引用次数: 7
The role of melt depletion versus refertilization in the major element chemistry of four-phase spinel peridotite xenoliths 熔体耗损与再肥化在四相尖晶石橄榄岩包体主元素化学中的作用
Pub Date : 2016-10-18 DOI: 10.1556/24.59.2016.002
A. Embey-Isztin
Mantle peridotites are interpreted as either residues after partial melting and melt extraction or products of igneous refertilization of refractory peridotites. The simple distinction between these models is difficult to assess because in chemical variation diagrams, both processes lead essentially to the same results. The only exception is the Ti-in-Cpx versus Ti-in-whole-rock plots, which can successfully discriminate between these models. In this study, a modified version of Ti-in-Cpx versus Mg#-in-olivine plots was applied to ∼1,500 spinel peridotite xenoliths from worldwide localities. The results showed that the vast majority of shallow mantle samples are consistent with the partial melting model; however, a minority of samples may indicate refertilization of formerly refractory mantle domains.
地幔橄榄岩可以解释为部分熔融和熔融萃取后的残余物,也可以解释为难熔橄榄岩火成岩再作用的产物。这些模型之间的简单区别很难评估,因为在化学变化图中,两种过程基本上导致相同的结果。唯一的例外是cpx中的ti和整块岩石中的ti图,它们可以成功地区分这些模型。在这项研究中,一种改良版的Ti-in-Cpx和Mg - In -橄榄石地块被应用于来自世界各地的约1500个尖晶石橄榄岩捕虏体。结果表明,绝大多数浅层地幔样品符合部分熔融模式;然而,少数样品可能表明以前难熔的地幔域的再作用。
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引用次数: 2
Tectonic evolution of the Zagros Orogen in the realm of the Neotethys between the Central Iran and Arabian Plates: An ophiolite perspective 伊朗中部和阿拉伯板块之间新特提斯时期扎格罗斯造山带的构造演化:一个蛇绿岩的视角
Pub Date : 2016-08-16 DOI: 10.1556/24.59.2016.001
M. S. Ajirlu, M. Moazzen, R. Hajialioghli
The Zagros Orogenic Belt includes the Fold and Thrust Belt, the High Zagros Belt, the Outer Zagros Ophiolitic Belt, the Sanandaj–Sirjan Metamorphic Belt, the Inner Zagros Ophiolitic Belt, and the Urumieh–Dokhtar Magmatic Belt. We divide the High Zagros evolutionary history into five stages: (1) triple junction formation, (2) continental lithosphere rifting, (3) generation, spreading, and maturation of the Neotethys Ocean, (4) subduction of the oceanic lithosphere, and (5) collision. The Neotethys triple junction, located at the southeastern corner of the Arabian Plate, formed during the Late Silurian–Early Carboniferous. Subsequently, this triple junction became a rift basin due to normal faulting and basalt eruption. The rifting stage occurred during the Late Carboniferous–Early Permian. Thereafter, extension of the basin continued, leading to spreading and maturation of the Neotethys oceanic basin during the Late Permian–Late Triassic. Probably at the end of the Late Triassic, closure of the Paleotethys...
扎格罗斯造山带包括褶皱冲断带、高扎格罗斯造山带、外扎格罗斯蛇绿岩带、萨南达杰—锡尔扬变质带、内扎格罗斯蛇绿岩带和乌鲁木齐—多克塔尔岩浆带。我们将高扎格罗斯的演化历史划分为5个阶段:(1)三联结形成阶段,(2)大陆岩石圈裂陷阶段,(3)新特提斯洋的生成、扩张和成熟阶段,(4)大洋岩石圈俯冲阶段,(5)碰撞阶段。新特提斯三合带形成于晚志留世-早石炭世,位于阿拉伯板块东南角。随后,由于正断层作用和玄武岩喷发作用,该三联结演化为裂谷盆地。裂谷期发生在晚石炭世—早二叠世。此后,盆地继续伸展,导致新特提斯洋盆在晚二叠世-晚三叠世扩张成熟。可能是在晚三叠纪末期,古特提斯末期…
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引用次数: 37
High-tech metal potential in Finland with emphasis on rare earth elements (REE), titanium and lithium 芬兰的高科技金属潜力,重点是稀土元素(REE)、钛和锂
Pub Date : 2015-12-01 DOI: 10.1556/24.58.2015.4.1
O. Sarapaa, N. Kärkkäinen, Timo Ahtola, Thair Al-Ani
This article evaluates the known rare earth elements (REE), Ti and Li occurrences and exploration potential in Finland, based on existing data combined with new geochemistry and mineralogy, heavy mineral studies, geophysical measurements, geologic mapping and recent drilling of new targets. The potential rock types for REE include carbonatite (Sokli, Korsnas), alkaline rocks (Otanmaki, Lamujarvi, and Iivaara), rapakivi granite and pegmatite (Kovela), and kaolin-bearing weathering crusts in eastern and northern Finland. The highest REE concentrations occur in late magmatic carbonatite veins in the fenite area of the Sokli carbonatite complex. Detailed mineralogical investigations have revealed three distinct types of REE mineralization as phosphates, carbonates and silicates in the studied areas. Mineralogical and mineral chemical evidence demonstrates that hydrothermal processes are responsible for the REE mineralization in the studied rocks and confirms that such processes are predominant in the formatio...
本文根据现有数据,结合新的地球化学和矿物学、重矿物研究、地球物理测量、地质填图和最近钻探的新目标,对芬兰已知的稀土元素(REE)、Ti和Li的赋存和勘探潜力进行了评价。稀土元素的潜在岩石类型包括芬兰东部和北部的碳酸盐岩(Sokli、Korsnas)、碱性岩石(Otanmaki、Lamujarvi和Iivaara)、rapakivi花岗岩和伟晶岩(Kovela)以及含高岭土风化壳。稀土元素含量最高的是索克利碳酸盐岩杂岩的白云岩区晚期岩浆碳酸岩脉。详细的矿物学调查显示,研究区内稀土矿化类型主要为磷矿、碳酸盐矿和硅酸盐矿。矿物学和矿物化学证据表明,热液作用是研究岩石中稀土矿化的主要原因,并证实热液作用在形成过程中占主导地位。
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引用次数: 5
Thermal metamorphism of the Mócs meteorite (L6) revealed by optical microscopy and BSE imaging 通过光学显微镜和BSE成像揭示Mócs陨石(L6)热变质作用
Pub Date : 2015-12-01 DOI: 10.1556/24.58.2015.4.3
I. Gyollai, S. Bérczi, K. Fintor, S. Nagy, A. Gucsik
The Mocs chondrite was studied by optical microscopy, element mapping, as well as scanning electron microscope backscattered electron (SEM—BSE) imaging, in order to gain a better understanding of the thermal metamorphic as well as post-shock annealing evolution and the mineralogical signatures in this meteorite. The studied thin section of Mocs meteorite contains 26 chondrules with a variety of chondrule textures, which are characterized by a blurry rim. The chondrules mostly consist of pyroxene and olivine, whereas feldspars occur only in the recrystallized groundmass, chondrule mesostasis, and mineral melt inside and beyond the shock veins. It was found that the matrix was completely recrystallized. According to the scanning electron microscope and optical microscope observations mentioned above, it can be concluded that the Mocs chondrite is a 6.5 petrographic type.
为了更好地了解Mocs球粒陨石的热变质、冲击后退火演化和矿物学特征,对其进行了光学显微镜、元素测绘和扫描电镜(SEM-BSE)成像研究。所研究的Mocs陨石薄片包含26个具有多种球粒结构的球粒,其特征是边缘模糊。球粒主要由辉石和橄榄石组成,而长石只存在于重结晶的地质体、球粒介稳态和激波脉内外的矿物熔体中。结果表明,基体完全再结晶。根据上述扫描电镜和光学显微镜观察,可以得出Mocs球粒陨石为6.5级岩相类型。
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引用次数: 1
The effect of temperature on the strength of two different granites 温度对两种不同花岗岩强度的影响
Pub Date : 2015-12-01 DOI: 10.1556/24.58.2015.4.5
A. Török, Á. Török
The paper provides information on the mechanical properties of granitic rocks that were subjected to heat. Two types of granitic rocks were tested under laboratory conditions at temperatures of 23 °C, 300 °C and 600 °C. The granitic rock from Bataapati (Moragy Granite) is a pinkish leucocratic monzogranitic type while the second type is grey granite from Mauthausen (Austria). The samples were placed in furnace and temperature raised to 300 °C. Other set of samples were heated to 600 °C. Mechanical tests were performed on non-heated and heated samples and the test results were compared. Heating to 300 °C caused a slight increase in the uniaxial compressive strength and in indirect tensile strength, with reference to the samples kept at 23 °C. A drastic drop in both values was observed when samples were heated to 600 °C. The density of the samples did not show a major change up to 300 °C. On the contrary, a decrease in ultrasonic pulse velocity was observed, with an additional significant loss when samples ...
本文提供了花岗岩在受热作用下的力学性质的资料。在23°C、300°C和600°C的实验室条件下对两种花岗岩进行了测试。来自Bataapati (Moragy Granite)的花岗质岩石是一种粉红色的白色二长花岗岩类型,而第二种类型是来自Mauthausen(奥地利)的灰色花岗岩。将样品放入炉中,升温至300℃。另一组样品加热至600℃。对未加热和加热试样进行力学试验,并对试验结果进行比较。与保持在23℃的样品相比,加热到300℃导致单轴抗压强度和间接抗拉强度略有增加。当样品加热到600°C时,观察到这两个值急剧下降。样品的密度在300℃以下没有明显变化。相反,观察到超声波脉冲速度下降,当样品…
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引用次数: 25
Sideritic—kaolinitic and green clay layers in the Mecsek Mountains (SW Hungary): Indicators of Middle Triassic volcanism—Myth or reality? 匈牙利西南部Mecsek山脉的石质-高岭石质和绿粘土层:中三叠世火山的标志——神话还是现实?
Pub Date : 2015-12-01 DOI: 10.1556/24.58.2015.4.4
G. Lukoczki, Tamás Budai, T. Németh
Sideritic—kaolinitic and green clay layers were previously reported from the Mecsek Mountains (SW Hungary) as indicators of Tethyan volcanism in the otherwise germanotype Middle Triassic succession. The aim of the present study is to provide a review and a critical re-evaluation of the previously published data on both the sideritic—kaolinitic layers (the so-called “Manfa Siderite”) and the green clay layers. New results of mineralogical investigation of the green clay layers are also presented. The Middle Triassic volcanic origin of the “Manfa Siderite” cannot be confirmed. In addition to a possible volcanic contribution, the sideritic—kaolinitic layers were probably formed in a freshwater swamp under humid, tropical climatic conditions, whereby weathering in an organic-rich, acidic environment led to the formation of “underclays” and siderite in the coal-bearing formations of Late Triassic to Early Jurassic age. These layers were probably tectonically placed over Middle Triassic carbonates. The illitic ...
以前在匈牙利西南部的Mecsek山脉(Mecsek Mountains)发现的菱铁矿-高岭石和绿色粘土层被认为是德耳曼型中三叠世特提斯火山活动的标志。本研究的目的是对先前发表的关于菱铁矿-高岭石层(所谓的“Manfa菱铁矿”)和绿色粘土层的数据进行回顾和批判性的重新评估。并介绍了绿粘土层矿物学研究的新成果。“曼法菱铁矿”的中三叠世火山成因尚不能确定。除了可能的火山作用外,菱铁矿-高岭石层可能形成于潮湿的热带气候条件下的淡水沼泽中,在富含有机物的酸性环境中风化导致了晚三叠世至早侏罗世含煤地层中的“下粘土”和菱铁矿的形成。这些地层可能在构造上位于中三叠世碳酸盐岩之上。恶魔……
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引用次数: 1
期刊
Central European Geology
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