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Full colour RGB OLEDs on CMOS for active-matrix OLED microdisplays 用于有源矩阵OLED微显示器的CMOS上全彩色RGB OLED
Pub Date : 2006-12-05 DOI: 10.1117/12.680758
D. Kreye, M. Toerker, U. Vogel, J. Amelung
Microdisplays are used in various optical devices such as headsets, viewfinders and helmet-mounted displays. The use of organic light emitting diodes (OLEDs) in a microdisplay on silicone substrate provides the opportunity of lower power consumption and higher optical performance compared to other near-to-eye display technologies. Highly efficient, low-voltage, top emitting OLEDs are well suitable for the integration into a CMOSprocess. By reducing the operating voltage for the OLEDs below 5V, the costs for the CMOS process can be reduced significantly, because a standard process without high-voltage option can be used. Various OLED stacks on silicone substrate are presented, suitable for full colour (RGB) applications. Red and green emitting phosphorescent OLEDs and blue emitting fluorescent OLEDs all with doped charge transport layers were prepared on a two metal layer CMOS test substrate without active transistor area. Afterwards, the different test displays were measured and compared with respect to their performance (current, luminance, voltage, luminance dependence on viewing angle, optical outcoupling etc.)
微显示器用于各种光学设备,如头戴式耳机、取景器和头盔显示器。与其他近眼显示技术相比,在硅基板上的微显示器中使用有机发光二极管(oled)提供了更低功耗和更高光学性能的机会。高效、低电压、顶发射的oled非常适合集成到cmos工艺中。通过将oled的工作电压降低到5V以下,可以显著降低CMOS工艺的成本,因为可以使用没有高压选项的标准工艺。介绍了适合全彩(RGB)应用的硅基板上的各种OLED堆栈。在无有源晶体管面积的两金属层CMOS测试衬底上制备了掺杂电荷输运层的红色、绿色发光磷光oled和蓝色发光荧光oled。然后,测量并比较不同测试显示器的性能(电流、亮度、电压、亮度对视角的依赖性、光学解耦等)。
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引用次数: 12
Tuning hole transport in a highly dispersed blend of chemically similar polyfluorene copolymers 高度分散的化学性质相似的聚芴共聚物共混物中的调谐孔传输
Pub Date : 2006-12-05 DOI: 10.1117/12.681024
M. J. Harding, R. Maher, L. Cohen, A. Campbell
Here we report results of time-of-flight (ToF) measurements on blends of different ratios of poly(9,9-dioctylfluorene-cobis- N,N'-(4-methoxylphenyl)-bis-N,N'-phenyl-1,4-phenylenediamine) (PFMO) and the structurally similar poly(9,9- dioctylfluorene-co-N-(4-methoxyphenyl)diphenylamine) (TFMO). It is shown that the hole mobility can be tuned over three orders of magnitude with a mobility minimum at 10% PFMO and 90% TFMO. We also use Raman microscopy to demonstrate that the blends do not phase separate within the one micron resolution of our experiment.
本文报道了不同比例的聚(9,9-二辛基芴-cobis- N,N'-(4-甲氧基苯基)-双-N,N'-苯基-1,4-苯二胺)(PFMO)和结构相似的聚(9,9-二辛基芴-co-N-(4-甲氧基苯基)二苯胺(TFMO)共混物的飞行时间(ToF)测量结果。结果表明,在10%的PFMO和90%的TFMO下,空穴迁移率可以调整3个数量级。我们还使用拉曼显微镜来证明混合物在我们实验的一微米分辨率内不会相分离。
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引用次数: 2
Three-dimensional chemical and physical analysis of the degradation mechanisms in organic photovoltaics 有机光伏降解机理的三维化学和物理分析
Pub Date : 2006-11-03 DOI: 10.1117/12.680403
K. Norrman, Jan Alstrup, M. Jørgensen, M. Lira-Cantú, N. Larsen, F. Krebs
Insufficient lifetimes of organic photovoltaics are manifested in a reduced photovoltaic response, which is a consequence of physical and chemical degradation of the photovoltaic device. To prevent degradation it is vital to gain detailed insight into the degradation mechanisms. This is possible by utilizing state-of-the-art characterization techniques such as TOF-SIMS, XPS, AFM, SEM, interference microscopy and fluorescence microscopy as well as isotopic labeling (18O2 and H218O). By a combination of lateral and vertical analyses of the devices we obtain in-depth and in-plane information on the reactions and changes that take place in the various layers and interfaces. Examples will be presented that describe the advantages and disadvantages of various characterization techniques in relation to obtaining information on the degradation behavior of complete photovoltaic devices.
有机光伏器件寿命不足表现为光伏响应降低,这是光伏器件物理和化学降解的结果。为了防止降解,深入了解降解机制是至关重要的。这可以通过利用最先进的表征技术,如TOF-SIMS, XPS, AFM, SEM,干涉显微镜和荧光显微镜以及同位素标记(18O2和H218O)来实现。通过对器件的横向和纵向分析的结合,我们获得了在不同层和界面中发生的反应和变化的深入的平面信息。将给出描述各种表征技术的优点和缺点的例子,这些技术与获得有关完整光伏器件的降解行为的信息有关。
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引用次数: 7
Effect of side-chains on low band gap polymer photovoltaic devices 侧链对低带隙聚合物光伏器件的影响
Pub Date : 2006-11-03 DOI: 10.1117/12.683077
Yan Yao, Chenjun Shi, Q. Pei, Yang Yang
The effect of side-chains on the molecular weight and the optical and electrical property of a low band gap copolymer poly{(9,9-dioctylfluorene)-2,7-diyl-alt-[4,7-bis(3-decyloxythien-2-yl)-2,1,3-benzothiadiazole]-5',5"-diyl} (PF-co-DTB) was studied. The decyloxy side-chains help to increase molecular weight (Mw = 115,000) and decrease the band gap (1.78 eV) as well as the oxidation potential (-5.4 eV). Zero-field mobility of 2×10-5 cm2/Vs is measured in hole-only devices. Photovoltaic devices based on PF-co-DTB/fullerene bulk-heterojunction show power conversion efficiency of up to 1.6% under air mass 1.5G, 100 mW/cm2 illumination. Side-chains effect on the photovoltaic devices studies show the trade-off between short circuit current increase and open-circuit voltage drop. Thermal annealing on device performance is also discussed.
研究了侧链对低带隙共聚物{(9,9-二辛基芴)-2,7-二基-alt-[4,7-双(3-癸氧基-2-基)-2,1,3-苯并噻唑]-5′,5′-二基}(PF-co-DTB)分子量和光电性能的影响。烷基氧侧链有助于增加分子量(Mw = 115,000),减小带隙(1.78 eV)和氧化电位(-5.4 eV)。零场迁移率为2×10-5 cm2/Vs,在纯空穴器件中测量。在空气质量为1.5G、100mw /cm2的光照条件下,基于PF-co-DTB/富勒烯异质结的光伏器件的功率转换效率高达1.6%。对光伏器件侧链效应的研究表明了短路电流增大与开路电压下降之间的权衡关系。讨论了热退火对器件性能的影响。
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引用次数: 0
Correlation between the temperature dependences of short-circuit current and carrier mobility in P3HT:PCBM blend solar cells P3HT:PCBM混合太阳能电池中短路电流的温度依赖性与载流子迁移率的相关性
Pub Date : 2006-11-03 DOI: 10.1117/12.678890
Seunguk Noh, Jiyoung Kim, Changhee Lee, Moon-Jae Lee, Byung-Jun Jung, D. Hwang, Soo‐Hyoung Lee, Hyunjune Kim
Thermal annealing has been widely used to improve device performances of organic solar cells with regioregular (RR) poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl C61-butyric acid methyl ester (PCBM) bulk heterojunction blends. Especially, short-circuit current density (Jsc) of the thermally-annealed device is significantly increased compared to that of the non-annealed one. The Jsc is proportional to the product of the carrier mobility and the number of photogenerated carriers which depends on the photocarrier generation efficiency and carrier recombination lifetime. Therefore, the enhanced Jsc implies that the thermal annealing can increase either the mobility and/or lifetime of the photogenerated carriers. In order to understand which parameter is more affected by thermal annealing, we compared the temperature dependence of the Jsc and carrier mobility of P3HT:PCBM (1:1, weight%) blend solar cells. The carrier mobility, measured from a time-of-flight photoconductivity (TOF-PC) measurement, increases from about 10-5 cm2/Vs to the order of 10-4 cm2/Vs as the temperature increases from 300 K to 360 K and then saturates above 360 K up to 400 K. This behavior is very similar to the temperature dependence of the current density of the P3HT:PCBM solar cell devices with the same blend ratio. Therefore, this correlation indicates that the thermal annealing increases the carrier mobility by improving morphological order of the blend film and thereby enhances the Jsc of the P3HT:PCBM blend solar cells.
热退火已被广泛应用于提高区域规则(RR)聚(3-己基噻吩)(P3HT)和[6,6]-苯基c61 -丁酸甲酯(PCBM)本体异质结共混物有机太阳能电池的器件性能。特别是与未退火器件相比,热退火器件的短路电流密度(Jsc)显著增加。Jsc与载流子迁移率和光生载流子数量的乘积成正比,这取决于光载流子的产生效率和载流子的复合寿命。因此,增强的Jsc意味着热退火可以增加光生载流子的迁移率和/或寿命。为了了解哪个参数受热退火的影响更大,我们比较了P3HT:PCBM(1:1,重量%)混合太阳能电池的Jsc和载流子迁移率的温度依赖性。通过飞行时间光电导率(TOF-PC)测量,载流子迁移率随着温度从300 K增加到360 K,从约10-5 cm2/Vs增加到10-4 cm2/Vs,然后在360 K以上饱和至400 K。这种行为与相同混合比的P3HT:PCBM太阳能电池器件电流密度的温度依赖性非常相似。因此,这种相关性表明,热退火通过改善共混膜的形态顺序来提高载流子迁移率,从而提高P3HT:PCBM共混太阳能电池的Jsc。
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引用次数: 1
Alternative device concepts for future requirements of organic photovoltaic cells 未来有机光伏电池需求的替代装置概念
Pub Date : 2006-11-03 DOI: 10.1117/12.682226
C. Waldauf, P. Denk, M. Morana, C. Brabec, K. Coakley, Pavel Schilinsky, S. Choulis
The challenge to reversing the layer sequence of organic photovoltaics (OPVs) is to prepare a selective contact bottom cathode and to achieve a suitable morphology for carrier collection in the inverted structure. We report the creation of an efficient electron selective bottom contact based on a solution-processed Titania layer on top of Indium Tin Oxide. The use of o-xylene as the casting solvent creates an efficient carrier collection network with little vertical phase segregation, providing sufficient performance for both regular as well as inverted solar cells. We demonstrate inverted layer sequence OPVs with AM 1.5-calibrated power conversion efficiencies of over 3%.
反转有机光伏(opv)层序的挑战是制备选择性接触底部阴极,并在反转结构中实现合适的载流子收集形态。我们报告了基于氧化铟锡顶部的溶液处理二氧化钛层的高效电子选择性底部接触的创建。使用邻二甲苯作为铸造溶剂创建了一个有效的载流子收集网络,几乎没有垂直相分离,为常规和倒置太阳能电池提供足够的性能。我们演示了具有AM 1.5校准功率转换效率超过3%的反向层序opv。
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引用次数: 1
A geosynchronous imaging Fourier transform spectrometer (GIFTS) for hyperspectral atmospheric remote sensing: instrument overview and preliminary performance results 用于高光谱大气遥感的地球同步成像傅立叶变换光谱仪(GIFTS):仪器概述和初步性能结果
Pub Date : 2006-10-30 DOI: 10.1117/12.684135
J. Elwell, G. Cantwell, D. Scott, R. Esplin, G. Hansen, S. Jensen, M. Jensen, S. Brown, L. Zollinger, V. Thurgood, M. Esplin, R. Huppi, G. Bingham, H. Revercomb, F. Best, D. Tobin, J. Taylor, R. Knuteson, W. Smith, R. Reisse, R. Hooker
The Geosynchronous Imaging Fourier Transform Spectrometer (GIFTS) was developed for the NASA New Millennium Program (NMP) Earth Observing-3 (EO-3) mission. This paper discusses the GIFTS measurement requirements and the technology utilized by the GIFTS sensor to provide the required system performance. Also presented are preliminary results from the recently completed calibration of the instrument. The GIFTS NMP mission challenge was to demonstrate new and emerging sensor and data processing technologies to make revolutionary improvements in meteorological observational capability and forecasting accuracy using atmospheric imaging and hyperspectral sounding methods. The GIFTS sensor is an imaging FTS with programmable spectral resolution and spatial scene selection, allowing radiometric accuracy and atmospheric sounding precision to be traded in near-real time for area coverage. System sensitivity is achieved through the use of a cryogenic Michelson interferometer and two large-area, IR focal plane detector arrays. Due to funding limitations, the GIFTS sensor module was completed as an engineering demonstration unit, which can be upgraded for flight qualification. Capability to meet the next generation geosynchronous sounding requirements has been successfully demonstrated through thermal vacuum testing and rigorous IR calibration activities.
地球同步成像傅立叶变换光谱仪(GIFTS)是为美国宇航局新千年计划(NMP)地球观测3号(EO-3)任务开发的。本文讨论了gift的测量要求和gift传感器所采用的技术,以提供所需的系统性能。本文还介绍了最近完成的仪器校准的初步结果。gift NMP任务的挑战是展示新的和新兴的传感器和数据处理技术,利用大气成像和高光谱探测方法革命性地提高气象观测能力和预报精度。gift传感器是一种具有可编程光谱分辨率和空间场景选择的成像FTS,允许辐射测量精度和大气探测精度在近实时的区域覆盖范围内进行交易。系统灵敏度是通过使用一个低温迈克尔逊干涉仪和两个大面积,红外焦平面探测器阵列。由于资金限制,gift传感器模块作为一个工程演示单元完成,可以进行升级以获得飞行资格。通过热真空测试和严格的红外校准活动,成功证明了满足下一代地球同步探测要求的能力。
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引用次数: 24
Sounding the upper mesosphere using broadband solar occultation: the SOFIE experiment 利用宽带掩星探测上层中间层:SOFIE实验
Pub Date : 2006-10-30 DOI: 10.1117/12.682050
L. Gordley, M. Hervig, J. Russell, C. Fish, Gregory J. Paxton, John C. Burton, M. McHugh
The Solar Occultation For Ice Experiment (SOFIE) is scheduled for launch onboard the Aeronomy of Ice in the Mesosphere (AIM) satellite in March 2007. SOFIE is designed to measure polar mesospheric clouds (PMCs) and the environment in which they form. SOFIE will conduct solar occultation measurements in 16 spectral bands that are used to retrieve vertical profiles of temperature, O3, H2O, CO2, CH4, NO, and PMC extinction at 10 wavelengths. Thirty occultations are observed each day covering latitudes from 65° - 85°S and 65° - 85°N. The PMC measurements are simultaneous with temperature and gas measurements that are unaffected by PMC signal. This data set will be the first of its kind, and allow new advancements in the understanding of the upper mesosphere.
冰掩星实验卫星(SOFIE)计划于2007年3月在“大气冰学”卫星(AIM)上发射。SOFIE旨在测量极地中间层云(pmc)及其形成的环境。SOFIE将在16个光谱波段进行太阳掩星测量,用于检索10个波长的温度、O3、H2O、CO2、CH4、NO和PMC消光的垂直剖面。每天观测到30次掩星,覆盖纬度从65°- 85°S和65°- 85°N。PMC测量与温度和气体测量同时进行,不受PMC信号的影响。这个数据集将是第一个这样的数据集,并允许对上层中间层的理解取得新的进展。
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引用次数: 3
Fiber optic gyros: the vision realized 光纤陀螺:愿景实现
Pub Date : 2006-10-23 DOI: 10.1117/12.683457
G. Pavlath
Over thirty five years have elapsed since the fiber optic gyro was proposed by Vali and Shorthill. In those decades, fiber gyros have matured. They are competing head to head with existing technologies such as mechanical gyros and RLGs in tactical, navigation and strategic applications and are winning. Northrop Grumman has produced the majority of fiber optic gyros and fiber optic gyro based inertial products in the world. This paper will cover the various Northrop fiber gyro products, the platforms they are used on, as well as production and top level system data.
自Vali和Shorthill提出光纤陀螺以来,已经过去了35年。在那几十年里,光纤陀螺已经成熟。它们在战术、导航和战略应用领域与机械陀螺仪和rlg等现有技术展开正面竞争,并正在取得胜利。诺斯罗普·格鲁曼公司生产了世界上大多数光纤陀螺和基于光纤陀螺的惯性产品。本文将涵盖各种诺斯罗普光纤陀螺仪产品,它们所使用的平台,以及生产和顶级系统数据。
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引用次数: 37
Detection of vibrations in the audio range using photorefractive polymers 使用光折变聚合物检测音频范围内的振动
Pub Date : 2006-10-06 DOI: 10.1117/12.681104
S. Mansurova, M. Espinosa, P. Rodriguez, M. Gather, K. Meerholz
We report on the use of a photorefractive polymer composite as the active material for a planar photo- EMF detector suitable for the adaptive detection of optical phase modulated signals in the audio range (10Hz-10KHz). The composite is based on a conjugated triphenyldiamine- phenylenevinylene polymer (TPD-PPV) and is sensitized with a highly soluble fullerene derivative (PCBM). We demonstrate experimentally that the responsitivity of such polymer based detectors can be remarkably enhanced if the polymer sample is biased by an external dc field. This effect is theoretically explained by the strong dependence of the charge carrier generation rate on the external dc field, which is an inherent property of organic photoconductors.
我们报道了使用光折变聚合物复合材料作为平面光EMF检测器的活性材料,适用于自适应检测音频范围(10Hz-10KHz)的光相位调制信号。该复合材料是基于共轭三苯基二胺-苯乙烯聚合物(TPD-PPV),并用高可溶性富勒烯衍生物(PCBM)敏化。我们通过实验证明,如果聚合物样品被外部直流场偏置,这种基于聚合物的探测器的响应性可以显著增强。这种效应从理论上解释为电荷载流子产生率对外部直流场的强烈依赖,这是有机光导体的固有特性。
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引用次数: 0
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