Pub Date : 2022-12-01DOI: 10.52215/rev.bgs.2022.83.3.59
Victoria Vangelova, D. Dimitrova, Simona Simeonova, Stefani Kehajaova
The concentrations of trace elements in sphalerite from blocks 7, 700 and 149-south of the copper-gold high (to intermediate) sulphidation Chelopech deposit were determined by LA-ICP-MS. Their average contents in ppm based on 27 analyses are: Cu (2124) > Fe (4166) > Cd (1302) > Pb (504) > Sb (460) > Mn (439) > As (337) > Ga (173) > Ge (152) > Ag (143) > Hg (97) > In (37) > Tl (33) > Se (25) > Ti (15) > Mo (12) > Sn (7) > Te, Au (6) > V (5) > Pd (4) > Bi (3) > W (1) > Co (0.3).
采用LA-ICP-MS测定了高(中)硫化切洛佩奇铜矿南7、700和149区块闪锌矿中微量元素的含量。根据27次分析，它们的平均ppm含量为:Cu (2124) > Fe (4166) > Cd (1302) > Pb (504) > Sb (460) > Mn (439) > As (337) > Ga (173) > Ge (152) > Ag (143) > Hg (97) > in (37) > Tl (33) > Se (25) > Ti (15) > Mo (12) > Sn (7) > Te, Au (6) > V (5) > Pd (3) > W (1) > Co(0.3)。
{"title":"New data on trace elements in sphalerite from the Chelopech deposit: a LA-ICP-MS study","authors":"Victoria Vangelova, D. Dimitrova, Simona Simeonova, Stefani Kehajaova","doi":"10.52215/rev.bgs.2022.83.3.59","DOIUrl":"https://doi.org/10.52215/rev.bgs.2022.83.3.59","url":null,"abstract":"The concentrations of trace elements in sphalerite from blocks 7, 700 and 149-south of the copper-gold high (to intermediate) sulphidation Chelopech deposit were determined by LA-ICP-MS. Their average contents in ppm based on 27 analyses are: Cu (2124) > Fe (4166) > Cd (1302) > Pb (504) > Sb (460) > Mn (439) > As (337) > Ga (173) > Ge (152) > Ag (143) > Hg (97) > In (37) > Tl (33) > Se (25) > Ti (15) > Mo (12) > Sn (7) > Te, Au (6) > V (5) > Pd (4) > Bi (3) > W (1) > Co (0.3).","PeriodicalId":40733,"journal":{"name":"Spisanie Na B Lgarskoto Geologichesko Druzhestov-Review of the Bulgarian Geological Society","volume":" ","pages":""},"PeriodicalIF":0.2,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42494562","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-12-01DOI: 10.52215/rev.bgs.2022.83.3.93
V. Grozdev, R. Vassileva, I. Peytcheva
The usual main purpose of the zircon investigation is to determine the precise age of particular rocks, applying the U-Pb isotope method. In this study we attempt to reveal the vast potential of zircons in understanding the magmatic and modification processes, as well as the structure of the deeper Earth’s interior, using the analysis of the zircon population of the major volcanic variety in the Ruen tectono-magmatic zone, Kyustendil area, SW Bulgaria. The ascending magmas crosscut different rock types and units along their path to the Earth’s surface. Using the zircon crystal analysis, we may make consideration about the age and chemical characteristics of these units. The trace and rare earth element (REE) content of the zircons brings insights for the rock formation time and discloses characteristics of the deeper parts of the Earth’s crust.
{"title":"The rare earth elements in zircons as pathfinder of geological events","authors":"V. Grozdev, R. Vassileva, I. Peytcheva","doi":"10.52215/rev.bgs.2022.83.3.93","DOIUrl":"https://doi.org/10.52215/rev.bgs.2022.83.3.93","url":null,"abstract":"The usual main purpose of the zircon investigation is to determine the precise age of particular rocks, applying the U-Pb isotope method. In this study we attempt to reveal the vast potential of zircons in understanding the magmatic and modification processes, as well as the structure of the deeper Earth’s interior, using the analysis of the zircon population of the major volcanic variety in the Ruen tectono-magmatic zone, Kyustendil area, SW Bulgaria. The ascending magmas crosscut different rock types and units along their path to the Earth’s surface. Using the zircon crystal analysis, we may make consideration about the age and chemical characteristics of these units. The trace and rare earth element (REE) content of the zircons brings insights for the rock formation time and discloses characteristics of the deeper parts of the Earth’s crust.","PeriodicalId":40733,"journal":{"name":"Spisanie Na B Lgarskoto Geologichesko Druzhestov-Review of the Bulgarian Geological Society","volume":" ","pages":""},"PeriodicalIF":0.2,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46853775","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-12-01DOI: 10.52215/rev.bgs.2022.83.3.247
M. Krastanov
The purpose of this article is to provide greater clarity on rockfall phenomena and the reasons for their occurrence. Rockfall are gravitational phenomena that occur in rocky terrain with a significant slope of more than 50 degrees. They are characterized by their instantaneous development, the complexity of their prediction and assessment. Rockfalls causes significant damage to buildings and infrastructure, as well as human casualties. This is also the case with the rockfall on the road I-1 Sofia-Botevgrad in the area of the village of Vrachesh at the foot of the Shuntova Chuka hill (652.3 m) in the Bilo Planina Mountain. The rockfall affected part of the electricity transmission network in the area, the road infrastructure and poses a potential danger to people who use the water of the spring at the base of the rock massif.
{"title":"Rockfall on the road I-1 Sofia-Botevgrad in the area of the village of Vrachesh","authors":"M. Krastanov","doi":"10.52215/rev.bgs.2022.83.3.247","DOIUrl":"https://doi.org/10.52215/rev.bgs.2022.83.3.247","url":null,"abstract":"The purpose of this article is to provide greater clarity on rockfall phenomena and the reasons for their occurrence. Rockfall are gravitational phenomena that occur in rocky terrain with a significant slope of more than 50 degrees. They are characterized by their instantaneous development, the complexity of their prediction and assessment. Rockfalls causes significant damage to buildings and infrastructure, as well as human casualties. This is also the case with the rockfall on the road I-1 Sofia-Botevgrad in the area of the village of Vrachesh at the foot of the Shuntova Chuka hill (652.3 m) in the Bilo Planina Mountain. The rockfall affected part of the electricity transmission network in the area, the road infrastructure and poses a potential danger to people who use the water of the spring at the base of the rock massif.","PeriodicalId":40733,"journal":{"name":"Spisanie Na B Lgarskoto Geologichesko Druzhestov-Review of the Bulgarian Geological Society","volume":" ","pages":""},"PeriodicalIF":0.2,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44517075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-12-01DOI: 10.52215/rev.bgs.2022.83.3.342
B. Valchev, V. Sachanski, Radostin Pazderov, S. Pristavova
As part of a cross-border cooperation program project between Bulgaria and Greece (Interreg), the geotourism potential of the municipality of Madan has been assessed. The assessment was made of the possibilities for the conversion of abandoned mine workings into tourist sites. Eight (8) geotopes are described and the creation of 2 geo-trails is proposed.
{"title":"New look to the Madan region, Central Rhodope – mining tourism and geological phenomena","authors":"B. Valchev, V. Sachanski, Radostin Pazderov, S. Pristavova","doi":"10.52215/rev.bgs.2022.83.3.342","DOIUrl":"https://doi.org/10.52215/rev.bgs.2022.83.3.342","url":null,"abstract":"As part of a cross-border cooperation program project between Bulgaria and Greece (Interreg), the geotourism potential of the municipality of Madan has been assessed. The assessment was made of the possibilities for the conversion of abandoned mine workings into tourist sites. Eight (8) geotopes are described and the creation of 2 geo-trails is proposed.","PeriodicalId":40733,"journal":{"name":"Spisanie Na B Lgarskoto Geologichesko Druzhestov-Review of the Bulgarian Geological Society","volume":" ","pages":""},"PeriodicalIF":0.2,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43537554","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-12-01DOI: 10.52215/rev.bgs.2022.83.3.217
S. Matev
The present study characterizes some microclimatic differences on the northern slope of the Western Rhodopes Mountains. The data for the analysis are based on the observations at three points: Brestovitsa at the foot, Bryanovshtitsa on the slope and Vurhovruh hut on the ridge, during July and August. Average temperatures, average minimum and maximum temperatures as well as the absolute minimum and maximum temperatures were established. They decrease naturally in accordance with altitude change, showing a dependence on synoptic conditions and microclimatic differences. The vertical temperature gradient is calculated for the studied parameters, with the largest values for the absolute maximum temperature amounting to 1.1 °C and the smallest for the absolute minimum and mean minimum temperature amounting to 0.5 °C. The largest values of the vertical temperature gradient for all parameters were observed between Brestovitsa and Bryanovstitsa.
{"title":"Micrometeorological measurements of air temperature in part of the northern slope of the Western Rhodopes (preliminary results)","authors":"S. Matev","doi":"10.52215/rev.bgs.2022.83.3.217","DOIUrl":"https://doi.org/10.52215/rev.bgs.2022.83.3.217","url":null,"abstract":"The present study characterizes some microclimatic differences on the northern slope of the Western Rhodopes Mountains. The data for the analysis are based on the observations at three points: Brestovitsa at the foot, Bryanovshtitsa on the slope and Vurhovruh hut on the ridge, during July and August. Average temperatures, average minimum and maximum temperatures as well as the absolute minimum and maximum temperatures were established. They decrease naturally in accordance with altitude change, showing a dependence on synoptic conditions and microclimatic differences. The vertical temperature gradient is calculated for the studied parameters, with the largest values for the absolute maximum temperature amounting to 1.1 °C and the smallest for the absolute minimum and mean minimum temperature amounting to 0.5 °C. The largest values of the vertical temperature gradient for all parameters were observed between Brestovitsa and Bryanovstitsa.","PeriodicalId":40733,"journal":{"name":"Spisanie Na B Lgarskoto Geologichesko Druzhestov-Review of the Bulgarian Geological Society","volume":" ","pages":""},"PeriodicalIF":0.2,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43752792","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-12-01DOI: 10.52215/rev.bgs.2022.83.3.335
Еugenia Tarassova, A. Benderev
The thermal waters and the historical heritage in the area of Hisarya were the focus of the field trip held during the XXII International Congress of the CBGA in Plovdiv.
{"title":"The thermal water in the Hisarya region – from the Roman baths to the\u0000present days (field trip of XXII Congress of CBGA)","authors":"Еugenia Tarassova, A. Benderev","doi":"10.52215/rev.bgs.2022.83.3.335","DOIUrl":"https://doi.org/10.52215/rev.bgs.2022.83.3.335","url":null,"abstract":"The thermal waters and the historical heritage in the area of Hisarya were the focus of the field trip held during the XXII International Congress of the CBGA in Plovdiv.","PeriodicalId":40733,"journal":{"name":"Spisanie Na B Lgarskoto Geologichesko Druzhestov-Review of the Bulgarian Geological Society","volume":" ","pages":""},"PeriodicalIF":0.2,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42215494","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-12-01DOI: 10.52215/rev.bgs.2022.83.3.69
N. Bonev, Zornitsa Dotseva, M. Chiaradia
We report on the isotopic compositions of the Jurassic supra-subduction zone Evros ophiolite mafic rocks exposed in the eastern Circum-Rhodope Belt in the Thrace region of northeastern Greece. These mafic units consist of low-Ti gabbroic and basaltic rocks, which Nd-Sr-Pb isotopes are compatible with dominant mantle-derived Mid-Ocean Ridge Basalt (MORB) component mixed with a detectable amount of crustal material and/or sediment involved in their melt source in the subduction zone. These isotopic features are consistent with an intra-oceanic arc origin of the mafic ophiolite rocks, and the Evros ophiolite Nd and Pb isotopes are comparable to those of the counterpart mafic rocks from the Mandritsa Unit in the eastern Rhodope Massif of southern Bulgaria.
{"title":"Comparative Nd-Sr-Pb isotopes geochemistry of the eastern Circum-Rhodope belt ophiolitic mafic suites, Greece-Bulgaria","authors":"N. Bonev, Zornitsa Dotseva, M. Chiaradia","doi":"10.52215/rev.bgs.2022.83.3.69","DOIUrl":"https://doi.org/10.52215/rev.bgs.2022.83.3.69","url":null,"abstract":"We report on the isotopic compositions of the Jurassic supra-subduction zone Evros ophiolite mafic rocks exposed in the eastern Circum-Rhodope Belt in the Thrace region of northeastern Greece. These mafic units consist of low-Ti gabbroic and basaltic rocks, which Nd-Sr-Pb isotopes are compatible with dominant mantle-derived Mid-Ocean Ridge Basalt (MORB) component mixed with a detectable amount of crustal material and/or sediment involved in their melt source in the subduction zone. These isotopic features are consistent with an intra-oceanic arc origin of the mafic ophiolite rocks, and the Evros ophiolite Nd and Pb isotopes are comparable to those of the counterpart mafic rocks from the Mandritsa Unit in the eastern Rhodope Massif of southern Bulgaria.","PeriodicalId":40733,"journal":{"name":"Spisanie Na B Lgarskoto Geologichesko Druzhestov-Review of the Bulgarian Geological Society","volume":" ","pages":""},"PeriodicalIF":0.2,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44543012","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-12-01DOI: 10.52215/rev.bgs.2022.83.3.23
V. Kostov-Kytin, R. Nikolova, M. Kadiyski, Iliya Dimitrov
Samples of scapolite from the marble quarry from the Samurski Dol locality, situated nearby Chepelare, Central Rhodopes, Bulgaria have been subjected to chemical analyses and single crystal X-ray diffraction studies. The obtained values for the meionite component (Me) range between 70 and 75. The crystal structure of the studied sample has been solved in both I4/m and P42/n space groups, traditionally assigned to scapolite members. The paper provides new insight on the choice of correct space group for description of scapolites crystal structures, with a view of the preferred positions by silicon and aluminum ions and their framework ordering.
{"title":"Crystal structure of scapolite from Samurski Dol, Chepelare region, Central Rhodopes, Bulgaria","authors":"V. Kostov-Kytin, R. Nikolova, M. Kadiyski, Iliya Dimitrov","doi":"10.52215/rev.bgs.2022.83.3.23","DOIUrl":"https://doi.org/10.52215/rev.bgs.2022.83.3.23","url":null,"abstract":"Samples of scapolite from the marble quarry from the Samurski Dol locality, situated nearby Chepelare, Central Rhodopes, Bulgaria have been subjected to chemical analyses and single crystal X-ray diffraction studies. The obtained values for the meionite component (Me) range between 70 and 75. The crystal structure of the studied sample has been solved in both I4/m and P42/n space groups, traditionally assigned to scapolite members. The paper provides new insight on the choice of correct space group for description of scapolites crystal structures, with a view of the preferred positions by silicon and aluminum ions and their framework ordering.","PeriodicalId":40733,"journal":{"name":"Spisanie Na B Lgarskoto Geologichesko Druzhestov-Review of the Bulgarian Geological Society","volume":" ","pages":""},"PeriodicalIF":0.2,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47428056","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-12-01DOI: 10.52215/rev.bgs.2022.83.3.31
Daniela Nikolova
The focus of this study is the mineralogical interpretation of the determined geochemical associations in the Milin Kamak deposit. Based on the results of the factor analysis, an attempt was made for interpretation of the factor axes by mineralogical studies and EPMA analysis. Three factor associations are related to the hydrothermal ore-forming processes. The main factor axes related to Au is quartz-polymetallic stage and is represented by pyrite, marcasite, arsenopyrite, pyrrhotite, sphalerite, galena and chalcopyrite.
{"title":"Mineral associations in the geochemical halos of Milin Kamak ore deposit, Bulgaria","authors":"Daniela Nikolova","doi":"10.52215/rev.bgs.2022.83.3.31","DOIUrl":"https://doi.org/10.52215/rev.bgs.2022.83.3.31","url":null,"abstract":"The focus of this study is the mineralogical interpretation of the determined geochemical associations in the Milin Kamak deposit. Based on the results of the factor analysis, an attempt was made for interpretation of the factor axes by mineralogical studies and EPMA analysis. Three factor associations are related to the hydrothermal ore-forming processes. The main factor axes related to Au is quartz-polymetallic stage and is represented by pyrite, marcasite, arsenopyrite, pyrrhotite, sphalerite, galena and chalcopyrite.","PeriodicalId":40733,"journal":{"name":"Spisanie Na B Lgarskoto Geologichesko Druzhestov-Review of the Bulgarian Geological Society","volume":" ","pages":""},"PeriodicalIF":0.2,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47785432","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-12-01DOI: 10.52215/rev.bgs.2022.83.3.27
A. Nikolov
Geopolymers based on natural zeolite clinoptilolite were activated with different concentration of sodium aluminate and potassium hydroxide and the influence on compressive strength, density and water absorption were evaluated. The microstructure was analyzed by XRD, FTIR and SEM. The obtained geopolymers are comprised of newly formed zeolite phases – phillipsite, zeolite A.
{"title":"Sodium aluminate activated geopolymers based on natural zeolite clinoptilolite","authors":"A. Nikolov","doi":"10.52215/rev.bgs.2022.83.3.27","DOIUrl":"https://doi.org/10.52215/rev.bgs.2022.83.3.27","url":null,"abstract":"Geopolymers based on natural zeolite clinoptilolite were activated with different concentration of sodium aluminate and potassium hydroxide and the influence on compressive strength, density and water absorption were evaluated. The microstructure was analyzed by XRD, FTIR and SEM. The obtained geopolymers are comprised of newly formed zeolite phases – phillipsite, zeolite A.","PeriodicalId":40733,"journal":{"name":"Spisanie Na B Lgarskoto Geologichesko Druzhestov-Review of the Bulgarian Geological Society","volume":" ","pages":""},"PeriodicalIF":0.2,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47926241","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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