Progress in Surface Science最新文献

英文中文

Vibrational signatures in layered materials 层状材料的振动特征

IF 7.2 2区工程技术 Q1 CHEMISTRY, PHYSICAL

Progress in Surface Science

Pub Date : 2026-01-08 DOI: 10.1016/j.progsurf.2025.100808

I.G. Shuttleworth

Van der Waals (vdW) complexes, surfaces and interfaces are a current ‘hot-topic’ in surface science. Their importance for surfaces, layered structures and interfaces stems from weak interlayer binding which allows strain to be applied relatively easily, particularly when compared to more rigid covalently bound systems, and used to tune the behaviour and properties of the material. Most ab-initio studies of extended vdW systems focus on the geometric (layering) and electronic properties, including fundamental quantities like the work function. Far fewer investigations highlight the thermal properties of these layers, including in many cases even the most basic phonon characterization.

In this article the utility of dynamical studies of layered and interfacial vdW systems will be highlighted. The weak coupling between the layers of a vdW interface enables efficient coupling between modes; however, ‘veering’, the effects of the orientation of subsequent layers and strain engineering can limit the redistribution of vibrational energy. This article will discuss some case studies of these effects and discuss their limitations; in particular, examples involving graphene, black phosphorus and hBN will be included together with a discussion of systematic design strategies which have been currently seen to optimize thermal energy transfer in these materials.

范德华（vdW）配合物、表面和界面是当前表面科学的“热门话题”。它们对表面、层状结构和界面的重要性源于弱层间结合，这使得应变相对容易施加，特别是与更严格的共价结合系统相比，并用于调整材料的行为和性能。大多数扩展vdW系统的从头算研究都集中在几何（分层）和电子特性上，包括功函数等基本量。很少有研究强调这些层的热特性，包括在许多情况下甚至是最基本的声子表征。在本文中，将重点介绍分层和界面vdW系统的动力学研究。vdW接口层之间的弱耦合使模式之间的有效耦合成为可能；然而，“转向”，后续层的方向和应变工程的影响可以限制振动能量的重新分配。本文将讨论这些影响的一些案例研究，并讨论它们的局限性；特别是，涉及石墨烯、黑磷和hBN的例子将包括在一起，并讨论系统设计策略，这些策略目前已被视为优化这些材料中的热能传递。

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引用次数: 0

The role of laser surface texturing for environmentally friendly surface engineering applications: a review 激光表面纹理在环境友好型表面工程中的应用综述

IF 7.2 2区工程技术 Q1 CHEMISTRY, PHYSICAL

Progress in Surface Science

Pub Date : 2025-12-25 DOI: 10.1016/j.progsurf.2025.100807

Laura Cepauskaite, Regita Bendikiene

Laser Surface Texturing (LST) is a precise and versatile method for modifying the surface of materials to improve their functional properties in various industrial applications. This review highlights the most important achievements of LST, focusing on its ability to tailor surface properties such as wettability, mechanical properties, corrosion resistance, and biocompatibility. The main results show that LST is a sustainable and effective alternative to traditional surface modification methods, reducing the need for chemical treatment and excess material use. The review also describes the transformative potential of LST for future innovations in materials science and engineering, while pointing out current limitations and areas for further research.

激光表面变形（LST）是一种精确和通用的方法，用于修改材料的表面，以改善其在各种工业应用中的功能特性。这篇综述强调了LST最重要的成就，重点是其定制表面性能的能力，如润湿性、机械性能、耐腐蚀性和生物相容性。主要结果表明，LST是一种可持续和有效的替代传统表面改性方法，减少了化学处理的需要和多余的材料使用。该综述还描述了LST对材料科学和工程未来创新的变革潜力，同时指出了当前的局限性和进一步研究的领域。

引用次数: 0

Influence of space charge carriers and active plasma components of DC Townsend discharge on the surface transformation of nano-sized Bi films 直流Townsend放电中空间载流子和活性等离子体组分对纳米Bi膜表面转变的影响

IF 7.2 2区工程技术 Q1 CHEMISTRY, PHYSICAL

Progress in Surface Science

Pub Date : 2025-10-29 DOI: 10.1016/j.progsurf.2025.100798

Emrah Koç , Bahtiyar G. Salamov

Under the conditions of low-temperature plasma, this work proposes a new controllable express method for transformation of nano-sized Bi films into semiconducting Bi₂O₃ films in a modified plasma microreactor with GaAs photosensitive plate. The transformation mechanism of Bi films depends on the current density, charge transferred, and exposure time. From the mechanism of formation of Bi₂O₃ semiconductor film, we have established: 1) that this is a surface process that moves deeper into the Bi film when the operation parameters change; 2) the band gap value of the Bi₂O₃ semiconductor film obtained from Tauc’s plot is E_g ≈ 3 eV; 3) that this process is provided by the combined kinetic energy of electrons and oxygen ions.

本文提出了一种在低温等离子体条件下，在GaAs光敏板修饰的等离子体微反应器中，将纳米Bi薄膜转化为半导体Bi2O3薄膜的可控表达方法。铋薄膜的转化机理与电流密度、转移电荷和曝光时间有关。从Bi2O3半导体膜的形成机理出发，我们确定了：1)这是一个当操作参数改变时向Bi膜深处移动的表面过程；2)由Tauc图得到的Bi2O3半导体膜带隙值为Eg≈3 eV；3)这个过程是由电子和氧离子的联合动能提供的。

引用次数: 0

PVD coatings on open-cell 3D foams for electrochemical applications: A review PVD涂层在开孔三维泡沫材料上的电化学应用综述

IF 7.2 2区工程技术 Q1 CHEMISTRY, PHYSICAL

Progress in Surface Science

Pub Date : 2025-10-23 DOI: 10.1016/j.progsurf.2025.100797

Loris Chavée , Stéphane Lucas , Nicolas Stein , Thierry Brousse , Emile Haye

The deposition of functional coatings by Physical Vapor Deposition (PVD) on open-cell 3D foams represents a burgeoning area within material science, especially for electrochemical applications. Due to the novelty of this field and the unique geometry of the foams, the use of PVD on these substrates is a breakthrough innovation for functional material development. However, several challenges remain, e.g. understanding film growth mechanisms on foams, their impact on electrochemical processes, and optimizing the performance of coated foams across various applications through an understanding of the electrochemical phenomena occurring inside and on the surface of the coated foams. This review provides the first thorough overview of the current state-of-the-art in this area and suggests innovative solutions to the challenges encountered. It reports the various properties of films on foams reported in literature, compares the electrochemical performance of PVD-coated foams for Oxygen Evolution Reaction (OER)/Hydrogen Evolution Reaction (HER) catalysis, and energy storage applications, and discusses the mechanisms that explain their performance. Additionally, the review offers an analysis of existing research and introduces a novel numerical methodology, integrating Direct Simulation Monte Carlo (DSMC), Particle-in-Cell Monte Carlo (PICMC), and kinetic Monte Carlo (kMC) techniques to facilitate the characterization of coatings within the foams.

通过物理气相沉积（PVD）在开孔3D泡沫上沉积功能涂层代表了材料科学中一个新兴的领域，特别是在电化学应用方面。由于该领域的新颖性和泡沫的独特几何形状，在这些基板上使用PVD是功能材料开发的突破性创新。然而，仍然存在一些挑战，例如，了解泡沫上的薄膜生长机制，它们对电化学过程的影响，以及通过了解涂层泡沫内部和表面发生的电化学现象来优化涂层泡沫在各种应用中的性能。这篇综述首次全面概述了这一领域的最新技术，并提出了应对所遇到挑战的创新解决方案。综述了文献报道的泡沫薄膜的各种性能，比较了pvd包覆泡沫在析氧反应(OER)/析氢反应（HER）催化和储能应用中的电化学性能，并讨论了其性能的解释机制。此外，本文还对现有研究进行了分析，并介绍了一种新的数值方法，该方法集成了直接模拟蒙特卡罗（DSMC）、细胞内粒子蒙特卡罗（PICMC）和动力学蒙特卡罗（kMC）技术，以促进泡沫内涂层的表征。

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引用次数: 0

Nanostructured anodic iron oxides for photoelectrochemical applications: recent advances and perspectives 纳米结构阳极氧化铁在光电化学中的应用：最新进展与展望

IF 7.2 2区工程技术 Q1 CHEMISTRY, PHYSICAL

Progress in Surface Science

Pub Date : 2025-10-22 DOI: 10.1016/j.progsurf.2025.100796

Karolina Syrek , Magdalena Gurgul-Bednarczyk , Małgorzata Płachta , Bartłomiej Orczykowski , Marta Michalska-Domańska , Leszek Zaraska

The growing global demand for energy has positioned photoelectrochemical water splitting as a highly promising method for producing gaseous hydrogen. For this process to be sufficiently effective, the use of semiconductor electrodes with specific properties is required. Among the already proposed semiconductors for this purpose, iron oxides are particularly promising. Therefore, this review paper aims to discuss recent advancements in the fabrication of nanostructured iron oxides through an anodic oxidation of metallic iron and, above all, the possibilities of utilizing these materials in photoelectrochemical systems. The first part of the paper discusses the procedure of Fe anodization with particular emphasis on the correlation between synthesis conditions and the morphology, composition, and properties of the obtained oxide layers. The most important part of the paper is a detailed discussion of the applications of anodically generated iron oxides in photoelectrochemical systems. Strategies for modifying Fe₂O₃ layers to enhance their photoelectrochemical properties have also been presented. Finally, examples of other applications of anodic iron oxides, as well as challenges and perspectives of the anodic oxidation method, were described.

日益增长的全球能源需求使得光电化学水分解成为一种非常有前途的生产气态氢的方法。为了使这一过程足够有效，需要使用具有特定性质的半导体电极。在已经提出的用于此目的的半导体中，氧化铁尤其有前途。因此，本文旨在讨论通过金属铁的阳极氧化制备纳米结构氧化铁的最新进展，尤其是在光电化学系统中利用这些材料的可能性。本文的第一部分讨论了铁阳极氧化的过程，特别强调了合成条件与所得到的氧化层的形貌、组成和性能之间的关系。本文最重要的部分是详细讨论了阳极生成的氧化铁在光电化学体系中的应用。本文还提出了改进Fe2O3层以提高其光电化学性能的策略。最后，介绍了阳极氧化铁的其他应用实例，以及阳极氧化方法的挑战和前景。

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引用次数: 0

Time-resolved photoemission spectroscopy of quantum materials using high harmonic generation: probing electron-phonon interactions and non-equilibrium dynamics 使用高谐波产生的量子材料的时间分辨光发射光谱：探测电子-声子相互作用和非平衡动力学

IF 7.2 2区工程技术 Q1 CHEMISTRY, PHYSICAL

Progress in Surface Science

Pub Date : 2025-10-21 DOI: 10.1016/j.progsurf.2025.100795

Takeshi Suzuki , Kozo Okazaki

Recent advancements in ultrafast laser systems and high harmonic generation (HHG) techniques have enabled time-resolved photoemission spectroscopy on femtosecond timescales, opening up unprecedented opportunities to explore quantum materials in both time and momentum space. In this review, we present recent representative studies utilizing HHG-laser-based time- and angle resolved photoemission spectroscopy for a variety of quantum materials. We particularly highlight electron–phonon interactions and non-equilibrium dynamics in time and frequency domain, through which rich information about non-equilibrium electron–phonon couplings and related phenomena has been clearly revealed.

超快激光系统和高谐波产生（HHG）技术的最新进展使飞秒时间尺度上的时间分辨光发射光谱成为可能，为在时间和动量空间上探索量子材料开辟了前所未有的机会。在这篇综述中，我们介绍了近年来利用hhg激光的时间和角度分辨光谱学对各种量子材料的代表性研究。我们特别强调了电子-声子相互作用和时域和频域的非平衡动力学，通过它可以清楚地揭示非平衡电子-声子耦合和相关现象的丰富信息。

引用次数: 0

Advances and perspectives in laser texturing for adhesion enhancement: a comprehensive research progress 激光纹理增强附着力的研究进展与展望：综合研究进展

IF 7.2 2区工程技术 Q1 CHEMISTRY, PHYSICAL

Progress in Surface Science

Pub Date : 2025-08-18 DOI: 10.1016/j.progsurf.2025.100781

Xinbin Zhang , Rongping Wang , Shaopeng Meng , Wenhua Chen , Liucheng Zhou , Weifeng He , Xinlei Pan

As a prominent connection technique in modern industry, adhesive technology provides advantages unattainable by conventional methods. It is widely applied in diverse industries, including electronics, medical devices, automotive, and aerospace. Laser surface texturing facilitates the high-precision fabrication of micro/nano-scale surface features, enabling simultaneous control over surface morphology, roughness, and contact angle, thereby enhancing adhesive joint strength. This review focuses on the interfacial bonding strength enhancement achieved via laser texturing technology. We systematically analyze the laser sources, operational classifications, and underlying material interaction mechanisms of laser texturing. Incorporating biomimetic science, this review synthesizes recent advances in texture-induced interface regulation and bonding reinforcement mechanisms. Finally, we discuss the persisting challenges and emerging research directions in laser-texturing-enabled bonding strength improvement.

粘接技术作为现代工业中一种重要的连接技术，具有传统方法无法企及的优越性。它被广泛应用于不同的行业，包括电子，医疗设备，汽车和航空航天。激光表面织构有利于微/纳米尺度表面特征的高精度制造，可以同时控制表面形貌、粗糙度和接触角，从而提高粘接强度。本文综述了利用激光织构技术提高界面结合强度的研究进展。我们系统地分析了激光变形的激光源、操作分类和潜在的材料相互作用机制。结合仿生科学，本文综述了近年来在纹理诱导界面调节和键合增强机制方面的研究进展。最后，我们讨论了激光织构增强键合强度的持续挑战和新兴研究方向。

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引用次数: 0

One-step etching fabrication of superhydrophobic CuO/Cu2O/CuCl hybrid films with integrated anti-corrosion, self-cleaning and long-term stability 一步蚀刻制备具有综合防腐、自清洁和长期稳定性的超疏水CuO/Cu2O/CuCl杂化膜

IF 8.7 2区工程技术 Q1 CHEMISTRY, PHYSICAL

Progress in Surface Science

Pub Date : 2025-06-01 DOI: 10.1016/j.progsurf.2025.100778

Hang You , Yi Peng , Ting Li , Zhengwen Zhang , Yuanqiang Luo

To address the issue of corrosion damage to copper in printed circuit boards (PCBs), electronic components, and other precision parts, the application of superhydrophobic surface technology is utilized to enhance its corrosion resistance properties. In this study, a superhydrophobic CuO/Cu₂O/CuCl composite surface was fabricated via a facile one-step chemical etching and modification process. The surface morphology was tailored by optimizing microstructural roughness, while the effects of etching time, etchant concentration, and modification duration on wettability were systematically investigated. Various characterization technologies, such as SEM, X-ray diffraction, and X-ray photoelectron spectroscopy, were utilized to examine surface morphologies, crystalline phases, chemical composition, and wettability. The engineered surface exhibited exceptional superhydrophobicity, with a contact angle (CA) of 161.4 ± 0.3° and a sliding angle (SA) below 3°. Electrochemical assessments revealed outstanding corrosion inhibition efficiency (99.98 %) in 3.5 wt% NaCl solution, corroborated by post-immersion corrosion morphology analysis. Furthermore, the coating demonstrated robust self-cleaning functionality and sustained superhydrophobicity for over 360 days under ambient conditions, highlighting its potential for real-world applications.

为了解决印刷电路板（pcb）、电子元件和其他精密零件中铜的腐蚀损伤问题，利用超疏水表面技术提高其耐腐蚀性能。在本研究中，通过简单的一步化学蚀刻和改性工艺制备了超疏水CuO/Cu2O/CuCl复合表面。通过优化微结构粗糙度来定制表面形貌，并系统地研究了蚀刻时间、蚀刻剂浓度和改性时间对润湿性的影响。各种表征技术，如扫描电镜、x射线衍射和x射线光电子能谱，被用来检查表面形貌、晶体相、化学成分和润湿性。该表面具有良好的超疏水性，接触角（CA）为161.4±0.3°，滑动角（SA）小于3°。电化学评估表明，在3.5 wt% NaCl溶液中，其缓蚀效率为99.98%，浸后腐蚀形貌分析也证实了这一点。此外，该涂层显示出强大的自清洁功能和在环境条件下持续超过360天的超疏水性，突出了其在实际应用中的潜力。

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引用次数: 0

Unveiling the exciton formation in time, energy and momentum domain in layered van der Waals semiconductors 揭示层状范德华半导体中激子在时间、能量和动量领域的形成

IF 8.7 2区工程技术 Q1 CHEMISTRY, PHYSICAL

Progress in Surface Science

Pub Date : 2025-06-01 DOI: 10.1016/j.progsurf.2025.100777

Valentina Gosetti , Jorge Cervantes-Villanueva , Selene Mor , Davide Sangalli , Alberto García-Cristóbal , Alejandro Molina-Sánchez , Vadim F. Agekyan , Manuel Tuniz , Denny Puntel , Wibke Bronsch , Federico Cilento , Stefania Pagliara

Resolving the early-stage dynamics of exciton formation following non-resonant photoexcitation in time, energy, and momentum is quite challenging due to their inherently fast timescales and the proximity of the excitonic state to the bottom of the conduction band. In this study, by combining time- and angle-resolved photoemission spectroscopy with ab initio numerical simulations, we capture the timing of the early-stage exciton dynamics in energy and momentum, starting from the photoexcited population in the conduction band, progressing through the formation of free excitons, and ultimately leading to their trapping in lattice deformations. The chosen material is bismuth tri-iodide (BiI

_{3}

), a layered semiconductor with a rich landscape of excitons in the electronic structure both in bulk and in monolayer form. The obtained results, providing a full characterization of the exciton formation, elucidate the early stages of the physical phenomena underlying the operation of the ultrafast semiconductor device.

解决非共振光激发后激子形成的时间、能量和动量的早期动力学是相当具有挑战性的，因为它们固有的快速时间尺度和激子状态接近导带的底部。在本研究中，通过将时间和角度分辨光谱学与从头算数值模拟相结合，我们捕捉到了能量和动量的早期激子动力学的时间，从导带中的光激发居群开始，经过自由激子的形成，最终导致它们在晶格变形中被捕获。所选择的材料是三碘化铋（BiI3），这是一种层状半导体，在电子结构中具有丰富的激子，无论是块状还是单层形式。所获得的结果，提供了激子形成的完整表征，阐明了超快半导体器件运行的物理现象的早期阶段。

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引用次数: 0

Functionalized forward osmosis membrane for nutrient recovery and enrichment from wastewater: Recent advances and future perspective 功能化正向渗透膜用于废水中营养物的回收和富集：最新进展和未来展望

IF 8.7 2区工程技术 Q1 CHEMISTRY, PHYSICAL

Progress in Surface Science

Pub Date : 2025-06-01 DOI: 10.1016/j.progsurf.2025.100779

Mengyi Zhang , Pei Sean Goh , Woei Jye Lau , Yifei Liu

Wastewater represents a valuable resource, offering the potential for nutrient recovery that can address the increasing demand for natural resources while fostering a sustainable future. Forward osmosis (FO) membranes stand out as a promising technology for nutrient extraction due to their excellent ability to retain organic matter, their low energy requirements. However, several obstacles hinder the large-scale implementation of FO membranes for nutrient reclamation and enrichment. Overcoming challenges such as insufficient ion selectivity, suboptimal water flux, and a heightened vulnerability to fouling during extended use is essential for improving the performance and feasibility of FO systems. This review aims to provide a comprehensive evaluation of recent advancements in functionalized FO membranes specifically designed for nutrient recovery and enrichment in wastewater treatment. It critically examines the limitations of traditional FO membranes and explores innovative modification strategies, like surface modifications and nanomaterial integrations, that have been developed to enhance membrane performance. In addition, the review incorporates emerging yet underexplored directions, such as the integration of artificial intelligence (AI)-driven membrane design and the application of novel materials like covalent organic frameworks (COFs). By focusing on these aspects, this work offers valuable insights into the advancement of FO membrane technology for sustainable nutrient recovery.

废水是一种宝贵的资源，提供了养分回收的潜力，可以解决对自然资源日益增长的需求，同时促进可持续的未来。正渗透（FO）膜因其优异的保留有机物的能力和较低的能量需求而成为一种有前途的营养提取技术。然而，一些障碍阻碍了FO膜用于营养物回收和富集的大规模实施。克服诸如离子选择性不足、水通量不理想以及在长时间使用过程中易受污染等挑战，对于提高FO系统的性能和可行性至关重要。本文综述了近年来用于污水处理中营养物质回收和富集的功能化FO膜的研究进展。它批判性地审视了传统FO膜的局限性，并探索了创新的改性策略，如表面改性和纳米材料集成，这些策略已经被开发出来以提高膜的性能。此外，该综述还纳入了新兴但尚未开发的方向，例如人工智能（AI）驱动膜设计的集成以及共价有机框架（COFs）等新型材料的应用。通过对这些方面的关注，本工作为推进FO膜技术的可持续营养回收提供了有价值的见解。

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引用次数: 0

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