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Visible quantum cutting in green-emitting BaF2: Gd3+, Tb3+ phosphor: An approach toward mercury-free lamps 绿色发光BaF2: Gd3+, Tb3+荧光粉的可见量子切割:迈向无汞灯的途径
IF 0.2 Pub Date : 2017-10-01 DOI: 10.1016/j.spjpm.2017.06.005
Shreeniwas K. Omanwar , Shailesh R. Jaiswal , Niraj S. Sawala , Kishor A. Koparkar , Pankaj A. Nagpure , Vinod B. Bhatkar

Visible quantum cutting (QC) has been observed in green emitting BaF2 co-doped with Gd3+, Tb3+ phosphor via down-conversion (DC) synthesized by wet chemical method. Powder X-ray diffraction (XRD) analysis shows structural purity of synthesized phosphors. The excitation (PLE) and PL spectra in the vacuum ultraviolet (VUV) or UV region were measured with the help of 4B8-VUV spectroscopy experimental station of the Beijing Synchrotron Radiation Facility (BSRF). In the QC process, one VUV–UV photon absorbed is cut into more than one visible photons emitted by Tb3+ through cross relaxation (CR) and direct energy transfer (DET) between Tb3+ and Tb3+ or Tb3+ and Gd3+, depending on the excitation wavelength. From the emission spectra monitored at different wavelength excitation, the two-step energy transfer process is investigated and theoretically calculated quantum efficiency observed 148% and 177% at the excitation wavelength of 174 nm and 219 nm respectively.

通过湿化学法下转换(DC)合成的Gd3+, Tb3+荧光粉共掺杂的绿色发光BaF2,观察到可见的量子切割(QC)现象。粉末x射线衍射(XRD)分析表明了合成的荧光粉的结构纯度。利用北京同步辐射设施(BSRF)的4B8-VUV光谱实验站测量了真空紫外(VUV)和紫外区的激发(PLE)和PL光谱。在QC过程中,根据激发波长的不同,通过Tb3+与Tb3+或Tb3+与Gd3+之间的交叉松弛(CR)和直接能量转移(DET),将被吸收的一个uv - uv光子切割成Tb3+发射的多个可见光子。根据不同波长激发下监测到的发射光谱,研究了两步能量传递过程,理论计算的量子效率在激发波长为174 nm和219 nm处分别为148%和177%。
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引用次数: 4
The contribution of the albedo for photons to the intensity of hard X-ray emission of solar flares 光子反照率对太阳耀斑硬x射线发射强度的贡献
IF 0.2 Pub Date : 2017-10-01 DOI: 10.1016/j.spjpm.2017.09.008
Evgeniya P. Ovchinnikova, Yuri E. Charikov, Aleksander N. Shabalin, Gennady I. Vasilyev

The albedo contribution to the total hard X-ray solar-flare emission has been considered. First, the distribution of primary hard X-ray photons localized along the flare loop was found, and finally, the Monte Carlo calculations of the Compton scattered hard X-ray photons were performed. The albedo for photons was shown to contribute to the total X-ray flux only in the energy range from 30 to 100 keV. The backscattered photon flux depends on the loop's position and on the localization of the source of primary radiation along the loop. For an isotropic distribution of primary photons, the backscattered photons’ contribution to the total flux is maximal for the loop in the center of the Sun and reduces when shifting to a limb. In the case of an anisotropic source the angle at which the contribution is maximal depends on the degree of anisotropy and on X-ray directivity in the source.

考虑了反照率对总硬x射线太阳耀斑发射的贡献。首先,发现了沿耀斑环定域的原始硬x射线光子的分布,最后,对康普顿散射硬x射线光子进行了蒙特卡罗计算。光子的反照率仅在30至100 keV的能量范围内对x射线总通量有贡献。后向散射光子通量取决于环的位置和沿环的一次辐射源的定位。对于主光子的各向同性分布,后向散射光子对总通量的贡献在太阳中心环处最大,在移至边缘时减小。在各向异性源的情况下,贡献最大的角度取决于各向异性的程度和源的x射线指向性。
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引用次数: 1
The EOS choice effect on the simulated results obtained for an underwater electrical explosion of conductors EOS选择对导体水下电爆炸模拟结果的影响
IF 0.2 Pub Date : 2017-10-01 DOI: 10.1016/j.spjpm.2017.09.001
Aleksey I. Ryakhovskiy, Valeriy I. Antonov, Nikolay V. Kalinin

In the paper, the effect of the choice of equations of state (EOSs) depicting the states of metal plasma and water on the simulated results obtained for an underwater electrical explosion of conductors has been analyzed. In order to compare various EOSs, a one-dimensional, cylindrically symmetrical, magnetohydrodynamic model of an underwater wire explosion was employed. The simulated results were compared with the experimental data on both micro- and nanosecond explosions of aluminum and copper wires. The right choice of EOSs and the model of transportation coefficients allowed us to improve the agreement between the experimental and simulated data and to replicate the thermodynamic evolution of the system more closely. The comparison revealed the most appropriate EOSs for application to simulation of an electrical explosion.

本文分析了描述金属等离子体和水状态的状态方程的选择对导体水下电爆炸模拟结果的影响。为了比较不同的爆炸效应,采用一维圆柱对称的水下钢丝爆炸磁流体力学模型。将模拟结果与铝、铜线微秒和纳秒爆炸实验数据进行了比较。正确选择EOSs和输运系数模型可以提高实验数据和模拟数据之间的一致性,更接近地复制系统的热力学演化过程。通过比较,得出了适用于电爆炸模拟的最合适的EOSs。
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引用次数: 2
Stabilization of the NOP ferroelectric phase in potassium nitrate–barium titanate ferroelectric composites 硝酸钾-钛酸钡铁电复合材料中NOP铁电相的稳定性
IF 0.2 Pub Date : 2017-10-01 DOI: 10.1016/j.spjpm.2017.09.006
Olga A. Alekseeva , Aleksandr А. Naberezhnov , Elena V. Stukova , Valeriy G. Simkin

The study of temperature evolution of KNO3 (NOP) structure in ferroelectric (1−x)KNO3 + (x)BaTiO3 composites with BaTiO3 concentrations х = 0.25, 0.50 and 0.53 has been carried out on cooling with the use of the neutron diffraction technique. It was shown that, on cooling, the phase transition temperature (Tc) from the high-temperature paraelectric phase into the ferroelectric one did not depend on barium titanate concentration and practically coincided with Tc for pure NOP. Moreover, it was found that the admixture of BaTiO3 essentially enlarged the temperature range of NOP ferroelectric phase stability in the composites with BaTiO3 concentrations x = 0.25 and 0.50. The suppression of the ferroelectric phase was observed for the composite with x = 0.53.

利用中子衍射技术研究了铁电(1−x)KNO3 + (x)BaTiO3复合材料(BaTiO3浓度为 = ,0.25,0.50和0.53)中KNO3 (NOP)结构的温度演化。结果表明,在冷却时,从高温准电相到铁电相的相变温度(Tc)与钛酸钡浓度无关,与纯NOP的Tc基本一致。此外,在BaTiO3浓度为x = 0.25和0.50的复合材料中,BaTiO3的掺入实质上扩大了NOP铁电相稳定性的温度范围。当x = = 0.53时,铁电相被抑制。
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引用次数: 0
The splitting features of a frequency spectrum of a gyroscope based on elastic waves in solids: An isolated imperfect ring as an example 基于固体中弹性波的陀螺仪频谱的分裂特征:一个孤立的不完美环为例
IF 0.2 Pub Date : 2017-10-01 DOI: 10.1016/j.spjpm.2017.09.004
Sergei V. Seregin

The calculation results on dynamic characteristics of a geometrically imperfect ring turning out of shape in its plane have been exemplified by a simpler computational model for a ring resonator of a gyroscope based on elastic waves in solids. The specific malconformations were shown to be responsible for a splitting of the bending frequency spectrum of such rings. In so doing the spectral mismatch may appear in cases different from the ideas of modern theory.

The splitting of the bending frequency spectrum was established to occur not only in the cases when the number of formative waves being equal to that of malconformation waves of the ring (as it is commonly believed at present) but also in the cases when the number of formative waves being two, three, four and so on times more than that of malconformation waves.

通过一个基于固体弹性波的陀螺环形谐振器的简单计算模型,给出了几何不完美环在其平面内变形时的动态特性计算结果。特定的畸变被证明是导致这种环的弯曲频谱分裂的原因。在这样做时,光谱不匹配可能出现在不同于现代理论的情况下。确定了弯曲频谱的分裂不仅发生在形成波数与环的畸变波数相等的情况下(目前普遍认为),而且发生在形成波数是畸变波数的两倍、三倍、四倍等情况下。
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引用次数: 4
Stage-by-stage modeling of the mechanism of semiconductor–metal phase transition in vanadium dioxide 二氧化钒中半导体-金属相变机理的逐级模拟
IF 0.2 Pub Date : 2017-10-01 DOI: 10.1016/j.spjpm.2017.09.002
Aleksander V. Il'inskiy , Marina E. Pashkevich , Eugeniy B. Shadrin

The algorithm of stage-by-stage qualitative modeling of the mechanism of a semiconductor–metal phase transition in vanadium dioxide has been proposed. The basis for the model is a statement that the transition is complex in character and consists of the anhysteretic, purely electronic Моtt transition occurring over a wide temperature range, and the temperature-abrupt structural Peierls transition having a thermal hysteresis. The initial stage of the model is based on the solution of a quantum-mechanical problem of an electronic spectrum of a linear vanadium-ion's chain. The model is completed by consideration of correlation effects and a martensitic character of the structural transition through taking consecutively account of results obtained by X-ray, spectroscopic, impedansmetric and magnetic resonance methods.

提出了二氧化钒中半导体-金属相变机理的逐级定性建模算法。该模型的基础是这样一个陈述,即转变具有复杂的性质,由在宽温度范围内发生的非滞后、纯电子Моtt转变和具有热滞后的温度-突变结构Peierls转变组成。该模型的初始阶段是基于求解线性钒离子链的电子谱的量子力学问题。该模型考虑了相关效应和结构转变的马氏体特征,并综合考虑了x射线、光谱、阻抗和磁共振等方法的结果。
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引用次数: 2
Operational matrices to solve nonlinear Riccati differential equations of arbitrary order 求解任意阶非线性Riccati微分方程的运算矩阵
IF 0.2 Pub Date : 2017-10-01 DOI: 10.1016/j.spjpm.2017.08.001
Kourosh Parand , Mehdi Delkhosh

In this paper, an effective numerical method to achieve the numerical solution of nonlinear Riccati differential equations of arbitrary (integer and fractional) order has been developed. For this purpose, the fractional order of the Chebyshev functions (FCFs) based on the classical Chebyshev polynomials of the first kind have been introduced, that can be used to obtain the solution of these equations. Also, the operational matrices of fractional derivative and product for the FCFs have been constructed. The obtained results illustrated demonstrate that the suggested approaches are applicable and valid.

本文提出了一种求解任意(整数阶和分数阶)非线性Riccati微分方程数值解的有效数值方法。为此,引入了基于第一类经典切比雪夫多项式的切比雪夫函数的分数阶,可用于求解这些方程。并构造了分数阶导数和乘积的运算矩阵。结果表明,所提出的方法是可行的、有效的。
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引用次数: 8
Testing of various schemes with quasi-one-dimensional reconstruction of gasdynamic variables in the case of unstructured-grid calculations 非结构网格计算中各种气体动力变量准一维重建方案的测试
IF 0.2 Pub Date : 2017-10-01 DOI: 10.1016/j.spjpm.2017.09.010
Elizaveta V. Kolesnik, Evgueni M. Smirnov

Several schemes of the second-order approximation worked out in the literature for unstructured-grid-based computations of gasdynamic flows are described. The convective fluxes on the control-volume's faces are evaluated using Roe's approximate Riemann solver. The MUSCL approach with the use of various quasi-one-dimensional schemes of reconstruction of gasdynamic variables and limiters making the solution monotonic is applied in order to improve the approximation accuracy. Comparative analysis of the working capacity of the schemes under consideration has been carried out through solving two problems of inviscid gas flow. Namely, the transonic NACA-0012 airfoil flow and the superpersonic flow in a duct with a central ramp were computed. The smoothness of solution, obtained with different schemes, dissipativity features of the schemes and computational process stability were evaluated.

本文介绍了几种基于非结构网格的气体动力流计算的二阶近似格式。利用罗伊近似黎曼解算器计算了控制体表面的对流通量。为了提高近似精度,采用了MUSCL方法,利用各种气体动力变量的准一维重建格式和限制项使解单调。通过对两个无粘气体流动问题的求解,对所考虑方案的工作能力进行了对比分析。即,计算了NACA-0012翼型的跨声速流动和具有中心坡道的管道中的超声速流动。评价了不同方案解的光滑性、方案的耗散特性和计算过程的稳定性。
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引用次数: 1
High-efficiency and robust M-estimates of the scale parameter on the Q-estimate basis 在q估计的基础上对尺度参数进行高效稳健的m估计
IF 0.2 Pub Date : 2017-10-01 DOI: 10.1016/j.spjpm.2017.09.012
Pavel O. Smirnov, Ivan S. Shirokov, Georgiy L. Shevlyakov

The commonly employed highly efficient and robust Q-estimate of the scale parameter proposed by Rousseeuw and Croux has been approximated using computationally fast Huber M-estimates. The suggested M-estimates were shown to be robust and highly efficient for an arbitrary underlying data distribution due to correctly choosing the approximation parameters. The following indicators of the efficiency and robustness of M-estimates of scale were computed: their asymptotic variances, influence functions and breakdown points. Special attention was given to the particular cases of the Gaussian and Cauchy distributions. It is noteworthy that for the Cauchy distribution, the suggested robust estimate of scale coincides with the maximal likelihood estimate. Finally, the computation time of these highly efficient and robust estimates of scale is 3–4 times less than for the corresponding Q-estimates.

常用的由Rousseeuw和Croux提出的尺度参数的高效鲁棒q估计已经使用计算速度快的Huber m估计进行了近似。由于正确选择近似参数,所建议的m估计对于任意底层数据分布具有鲁棒性和高效率。计算了尺度m估计的效率和稳健性的以下指标:它们的渐近方差、影响函数和崩溃点。特别注意高斯分布和柯西分布的特殊情况。值得注意的是,对于柯西分布,建议的稳健估计规模与最大似然估计一致。最后,这些高效且稳健的规模估计的计算时间比相应的q估计少3-4倍。
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引用次数: 1
Simulation of an on-the-fly measuring system of a descent module under uncertainty of the lunar-surface composition 月面成分不确定条件下下降舱实时测量系统仿真
IF 0.2 Pub Date : 2017-10-01 DOI: 10.1016/J.SPJPM.2017.09.003
Irina A. Kislitsyna, G. Malykhina
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引用次数: 2
期刊
St Petersburg Polytechnic University Journal-Physics and Mathematics
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