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Picosecond reorientational dynamics in polymer solutions 聚合物溶液中的皮秒重定向动力学
Pub Date : 2008-06-04 DOI: 10.1063/1.36830
E. Quitevis, K. G. Casey, T. W. Sinor
The reorientational dynamics of two oxazine dyes, cresyl violet and oxazine 1, have been studied in dilute and semidilute solutions of poly(ethylene oxide) in methanol. The approach to this study is to use a synchronously pumped dye laser to do picosecond visible pump-probe measurements of transient absorption recovery.
研究了甲酰紫和恶嗪1这两种恶嗪染料在稀、半稀聚环氧乙烷甲醇溶液中的重定向动力学。本研究的方法是使用同步泵浦染料激光器进行皮秒可见泵浦探针瞬态吸收恢复测量。
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引用次数: 0
Quasiperiodic and chaotic motions in intense field multiphoton processes 强场多光子过程中的准周期和混沌运动
Pub Date : 2008-06-04 DOI: 10.1063/1.36851
S. Chu
The question of the behavior of quantum systems in time-dependent fields whose classical counterparts exhibit chaotic behavior is addressed. For any nondissipative bounded quantum system under the influence of polychromatic (i.e., quasiperiodic) fields, it is proved by means of the many-mode Floquet theory1 that the autocorrelation function will recur infinitely often in the course of time, indicating no strict quantum stochasticity is possible.2 In particular, for an N-level quantum system undergoing multiphoton transitions, its dynamic behavior is described by the quasiperiodic motion of an (N2 – 1)-dimensional coherence vector S in accord with the SU(N) dynamic symmetries. On the other hand, for any dissipative quantum system, SU(N) symmetries are broken, and chaotic behavior is observed as the coherence vector Sevolves from an initially (N2 – 1)-dimensional space to a lower-dimensional space. The recurrence and chaotic phenomena are illustrated for two- and three-level quantum systems driven by intense bichromatic laser fields.2
讨论了量子系统在时变场中的行为问题,其经典对应物表现出混沌行为。对于任何受多色场(即准周期场)影响的非耗散有界量子系统,利用多模Floquet理论证明了自相关函数在时间过程中会无限频繁地重复出现,表明不可能存在严格的量子随机性特别是,对于经历多光子跃迁的N能级量子系统,其动力学行为可以用符合SU(N)动态对称性的(N2 - 1)维相干向量S的准周期运动来描述。另一方面,对于任何耗散量子系统,SU(N)对称性被打破,并且当相干向量从初始(N2 - 1)维空间向低维空间自旋时观察到混沌行为。讨论了在强双色激光场驱动下的二能级和三能级量子系统的递归现象和混沌现象
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引用次数: 1
Dynamics of cluster dissociation 簇解离动力学
Pub Date : 2008-06-04 DOI: 10.1063/1.36739
R. Keesee, A. Castleman
Studies of cluster ionization and dissociation are of wide-ranging interest as they contribute to a further understanding of inter-molecular energy flow and energy disposal following multiphoton ionization, as well as on the changing properties of matter undergoing transitions from the gas to condensed phase. A major advance in the study of unimolecular dissociation and the spectroscopy of clusters has become available through the use of multi-photon ionization methods coupled with time-of-flight reflectron techniques. Using single and two-color pulsed lasers, the excess energy introduced into a cluster can be controlled. The power of the method is demonstrated by results of recent investigations of cluster fragmentation following internal ion-molecule reactions in hydrogen bonded cluster systems. The role of dissociation and the influence of the thermochemical stability of cluster ions in affecting the appearance of magic numbers in certain cluster distributions is discussed. The application of this method in studying spectral shifts and determining ionization potentials of probe molecules following successive clustering with a solvent species is also presented.
簇电离和解离的研究具有广泛的兴趣,因为它们有助于进一步理解多光子电离后的分子间能量流动和能量处置,以及物质从气体到凝聚态转变的变化性质。通过使用多光子电离方法和飞行时间反射技术,单分子解离和团簇光谱研究取得了重大进展。使用单色和双色脉冲激光器,可以控制引入集群的多余能量。最近对氢键团簇系统内部离子-分子反应后团簇破碎的研究结果证明了该方法的有效性。讨论了离解作用和簇离子热化学稳定性对某些簇分布中幻数出现的影响。本文还介绍了该方法在研究光谱位移和测定探针分子与溶剂连续聚类后的电离势方面的应用。
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引用次数: 0
Doppler-free two-photon-excited fluorescence spectroscopy of OH in flames 火焰中羟基的无多普勒双光子激发荧光光谱
Pub Date : 1988-04-01 DOI: 10.1364/JOSAB.5.000749
J. Goldsmith, L. Rahn
We have used Doppler-free two-photon-excited fluorescence spectroscopy to fully resolve the pressure-broadened line shape of OH A2Σ+ ← X2Π transitions in low-pressure flames. This method uses two counterpropagating laser beams to excite the transition. Since the Doppler shifts for the two beams exactly cancel, the resulting signal consists of a sharp Doppler-free peak centered on a Doppler-broadened and much weaker background. Because measurements were made in the postflame gases of low-pressure stoichiometric hydrogen–oxygen flames, water was the dominant collision partner. A narrowband pulse-amplified cw ring dye laser system with a FWHM bandwidth of 45 MHz at 620 nm made it possible to fully resolve the OH linewidth at pressures down to 20 Torr. All the observed transitions consisted of doublets due to hyperfine splitting of the OH A2Σ+ state. Values of the broadening and shift of OH transition line shapes due to collisions with water measured using this technique are reported.
我们利用无多普勒双光子激发荧光光谱完全解析了低压火焰中OH A2Σ+←X2Π跃迁的压力加宽线形。该方法使用两个反向传播的激光束来激发跃迁。由于两束的多普勒频移完全抵消,因此产生的信号由一个以多普勒加宽和弱得多的背景为中心的无多普勒尖峰组成。因为测量是在低压氢-氧化学计量火焰的火焰后气体中进行的,所以水是主要的碰撞伙伴。在620nm处,FWHM带宽为45mhz的窄带脉冲放大连续波环形染料激光系统可以在低至20torr的压力下完全解析OH线宽。所有观察到的跃迁都是由OH A2Σ+态的超精细分裂引起的双重态组成的。本文报道了用该技术测量的氢氧根与水碰撞时过渡线形状的加宽和位移值。
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引用次数: 11
Diffusive and convective evaporation of irradiated droplets 辐照液滴的扩散和对流蒸发
Pub Date : 1987-12-01 DOI: 10.1063/1.36868
R. Armstrong, A. Zardecki
The evaporation of a spherically symmetric liquid droplet subject to a high-irradiance laser flux is investigated on the basis of a hydrodynamic description of the system composed of the ejected vapor and ambient gas. For low irradiance beams, diffusive mass transport and conductive energy transport are the dominant interactions between the droplet and its environment.1 In this isobaric case, changes in the state of the ambient medium are small. For higher-flux beams, convective mass transport becomes significant, and droplet vaporization is accompanied by the production of strong shock waves in the surrounding gas. Following Knight,2jump conditions at the droplet boundary aid us in solving the hydrodynamic boundary value problem. An extension of Knight’s analysis to include both diffusive and convective mass flux allows the transition regime between the low-flux isobaric case and the high-flux shock-wave dominated case to be investigated. Numerical solutions illustrating droplet vaporization and ambient-medium hydrodynamic effects are presented for selected droplet-beam configurations.
基于喷射蒸汽和周围气体组成的系统的流体力学描述,研究了球对称液滴在高辐照激光通量作用下的蒸发现象。对于低辐照度光束,弥漫性质量输运和导电性能量输运是液滴与环境的主要相互作用在这种等压情况下,环境介质的状态变化很小。对于高通量光束,对流质量输运变得显著,液滴汽化伴随着周围气体中强激波的产生。根据Knight,液滴边界处的2个跳跃条件有助于我们求解水动力边值问题。对Knight的分析进行扩展,使其包括扩散和对流质量通量,从而可以研究低通量等压情况和高通量激波主导情况之间的过渡状态。给出了所选液滴束结构下液滴汽化和环境-介质流体动力效应的数值解。
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引用次数: 18
Magnetic trapping of neutral atoms 中性原子的磁捕获
Pub Date : 1987-09-25 DOI: 10.1063/1.36786
T. Bergeman, H. Metcalf
Magnetic trapping of laser-cooled neutral atoms has been demonstrated at NBS and is progressing in other laboratories. Confinement of any object requires exchanging kinetic for potential energy, and for neutral atoms, this necessarily derives from shifts of internal energy levels. This is implemented through the force experienced by the atomic magnetic moment in a carefully designed, highly inhomogeneous field. Since magnetic fields of convenient strength can shift atomic energy levels by only a few gigahertz (temperature ≌ 0.1 K), neutral atom traps are very shallow and must be loaded with very cold atoms. We present some motivations for using magnetic traps and then discuss the constraints and optimal configurations of various arrangements. For example, no trap can be isotropic. Next we discuss both the classical and quantum mechanical motions of trapped atoms. These motions are important for at least two reasons: First, several schemes under study for further cooling depend on knowing the position and velocity of the atoms, as well as the vector field at each point along the orbit. Second, magnetic traps depend on the atomic moment remaining aligned with the field as the atom orbits in the trap, and this precludes rapid motion through a low-field region.
激光冷却中性原子的磁捕获已经在NBS得到证实,并且在其他实验室正在取得进展。限制任何物体都需要将动能转换为势能,而对于中性原子,这必然源于内部能级的变化。这是通过原子磁矩在一个精心设计的、高度不均匀的场中所经历的力来实现的。由于方便强度的磁场只能将原子能级移动几兆赫兹(温度≌0.1 K),中性原子陷阱非常浅,必须装载非常冷的原子。我们提出了使用磁阱的一些动机,然后讨论了各种布置的约束和最佳配置。例如,没有陷阱可以是各向同性的。接下来我们讨论被困原子的经典运动和量子力学运动。这些运动之所以重要,至少有两个原因:首先,几个正在研究的进一步冷却方案依赖于知道原子的位置和速度,以及轨道上每一点的矢量场。其次,当原子在磁阱中绕轨道运行时,磁阱依赖于原子矩保持与磁场对齐,这就阻止了原子在低磁场区域的快速运动。
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引用次数: 1
Kinetic spectroscopy using a color center laser 使用色心激光器的动力学光谱学
Pub Date : 1987-09-25 DOI: 10.1063/1.36776
J. W. Stephens, Jeffrey L. Hall, W. Yan, H. Solka, Marilyn L. Richnow, R. Curl, G. Glass, F. Tittel
Infrared kinetic spectroscopy is being developed using a pulsed excimer laser for ultraviolet photolysis and a color center laser spectrometer as an infrared probe in the 2.3–3.0-μm region. Sub­microsecond time resolution is possible with the 14-ns excimer laser pulses and the InSb detectors currently employed. Previous work on the Br, OH, and NH2 radicals has led to the development of three monitoring schemes based on the use of either balanced detectors, magnetic rotation, or short-time monitoring. Kinetic studies of the NH2 + NO reaction have measured the branching ratio of the two primary product channels by monitoring a number of precursors and products. Current work on the C2H radical produced by photolysis of acetylene has indicated an ~ 1-μs lifetime for this radical, demonstrating the ability to detect short-lived species. Other work includes the production of highly reactive O(1D) atoms by the photolysis of O3, providing a method for generating free radicals from stable molecules by hydrogen atom abstraction. Additional studies on the spectroscopy and kinetics of other free radicals are discussed.
采用脉冲准分子激光器进行紫外光解,色心激光光谱仪作为红外探针,在2.3 ~ 3.0 μm范围内进行红外动力学光谱研究。目前使用的14ns准分子激光脉冲和InSb探测器可以实现亚微秒时间分辨率。先前对Br、OH和NH2自由基的研究导致了基于平衡检测器、磁旋转或短时间监测的三种监测方案的发展。NH2 + NO反应的动力学研究通过对前体和产物的监测,测量了两个主要产物通道的分支率。目前对乙炔光解产生的C2H自由基的研究表明,该自由基的寿命为~ 1 μs,证明了检测短寿命物质的能力。其他工作包括通过O3的光解产生高活性的O(1D)原子,提供了一种通过提取氢原子从稳定分子中产生自由基的方法。讨论了其他自由基的光谱和动力学的进一步研究。
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引用次数: 1
Parametric processes and gain saturation in resonantly enhanced optical phase conjugation in Na vapor near a two-photon resonance 双光子共振附近Na蒸气共振增强光学相位共轭的参量过程和增益饱和
Pub Date : 1987-09-25 DOI: 10.1063/1.36726
R. Wunderlich, W. R. Garrett, M. Payne
Experimental studies have been made of conjugate wave generation in a Na metal vapor heat pipe. Detailed measurements of gain profiles, pump beam absorption, and parametric wave generation at infrared frequencies for phase conjugation near the two-photon resonance with the Na 4d2D5/2 state, yield details of the effects of parasitic processes on degenerate four-wave mixing. Studies are conducted with an excimer-pumped dye laser system with ~4 ns pulses of < 10mJ/pulse, traversing Na vapor heat pipe. Included in the measurements are pump beam depletion, probe and conjugate beam intensities, and infrared light which is generated by the strong pump beams through stimulated Raman (SR) and amplified spontaneous emission processes. The role of ac Stark shifting in degenerate four-wave mixing near the 4d level is studied. We find a new effect involving a large contribution to the ac Stark effect from the internally generated SR photons. We observe a rapid onset with pressure of stimulated Raman emission accompanied by a dramatic increase in the ac Stark profile of the 4d level, and the sharp onset of gain saturation for the phase conjugate signal, due to the competition of these two processes. This effect results in an ac Stark coefficient which can be very nonlinear in laser power and Na pressure.
对金属钠蒸汽热管中共轭波的产生进行了实验研究。在Na 4d2D5/2态的双光子共振附近,对增益曲线、泵浦光束吸收和红外频率下的参数波产生进行了详细的测量,得到了寄生过程对简并四波混频影响的细节。采用~ 4ns脉冲< 10mJ/脉冲,穿过Na蒸汽热管的准分子泵浦染料激光系统进行了研究。测量包括泵浦光束损耗、探针和共轭光束强度,以及强泵浦光束通过受激拉曼(SR)和放大自发发射过程产生的红外光。研究了交流斯塔克位移在近四维能级简并四波混频中的作用。我们发现了一个新的效应,涉及到内部产生的SR光子对ac Stark效应的巨大贡献。由于这两个过程的竞争,我们观察到受激拉曼发射随压力的快速开始,伴随着4d水平ac Stark剖面的急剧增加,以及相位共轭信号的增益饱和的急剧开始。这种效应导致了交流斯塔克系数在激光功率和钠压方面的非线性。
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引用次数: 0
Laser-induced etching 激光蚀刻
Pub Date : 1987-09-25 DOI: 10.1063/1.36825
C. Ashby
There are three categories of laser-assisted chemical reactions which have been employed to etch metals, semiconductors, and other inorganic materials. Lasers can be used to locally heat a solid to accelerate the rate of a thermally activated process. This is the most universally applicable method of laser-induced etching. Alternatively, the laser can be used to generate reactive gas-phase or liquid-phase species by photolytic decomposition of precursor molecules. Appropriate reactants have been identified for a wide variety of materials. Finally, the laser can be used to create photo-generated electrons and holes in semiconductors; these carriers then participate directly in the etching process. Highly selective etching can be achieved by capitalizing on the surface electronic properties which influence carrier generation or subsequent behavior. These three types of laser-induced reaction are reviewed.
有三种类型的激光辅助化学反应已被用于蚀刻金属、半导体和其他无机材料。激光可用于局部加热固体,以加快热激活过程的速率。这是最普遍适用的激光诱导蚀刻方法。或者,激光可以通过前体分子的光解分解来产生反应性气相或液相物质。对于各种各样的材料,已经确定了合适的反应物。最后,激光可用于在半导体中产生光生电子和空穴;然后这些载流子直接参与蚀刻过程。通过利用影响载流子产生或后续行为的表面电子特性,可以实现高度选择性的蚀刻。对这三种激光诱导反应进行了综述。
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引用次数: 2
Tissue diagnostics using laser-induced fluorescence techniques 组织诊断使用激光诱导荧光技术
Pub Date : 1987-09-25 DOI: 10.1063/1.36807
P. S. Andersson, J. Ankerst, E. Kjellén, S. Montán, K. Svanberg, S. Svanberg
The fluorescence emission from tissue subject to UV light excitation can be utilized for diagnostic purposes. The discrimination between tumors and normal tissue is of particular interest. The natural tissue fluorescence can be used but improved results are obtained using the agent hematoporphyrin derivative that is selectively retained in tumors. We have used laser-induced fluorescence for point measurements1 as well as for multicolor imaging2 of different kinds of rat tissue. For optimized characterization it is important to utilize the full spectral information and to form dimensionless contrast functions of measured spectral intensities. The importance of selecting the proper excitation wavelength is emphasized. The development of clinical instrumentation for point measurements and imaging is discussed.
受紫外光激发的组织的荧光发射可用于诊断目的。肿瘤和正常组织之间的区别是一个特别有趣的问题。可以使用天然组织荧光,但使用选择性保留在肿瘤中的血卟啉衍生物可获得更好的结果。我们已经使用激光诱导荧光技术进行点测量,并对不同种类的大鼠组织进行多色成像。为了优化表征,重要的是利用全光谱信息并形成测量光谱强度的无量纲对比函数。强调了选择合适的激发波长的重要性。讨论了临床点测量和成像仪器的发展。
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引用次数: 3
期刊
International Laser Science Conference
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