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Morphological and Thermal Properties of Polystyrene/Poly (Vinyl Chloride) Blends 聚苯乙烯/聚氯乙烯共混物的形态和热性能
IF 0.8 Q4 Materials Science Pub Date : 2022-08-31 DOI: 10.18280/rcma.320407
Nassira Tourta, A. Meghezzi, H. Boussehel
The present study investigated the morphological and thermal properties of polystyrene and polyvinyl chlorides blends (PS/PVC). The PS and PVC mixed by the solution casting by using cyclohexanone the ratios presented are 100/0,80/20,50/50,20/80 and 0/100 according to the weight of PS/PVC. Where the mixture formation is confirmed by Fourier transform infrared (FT-IR), thermal gravimetric analysis (TGA), and differential scanning calorimetry (DSC) respectively. The spectral FT-IR results showed that the blend of PS/PVC did not have molecular reactions. The thermal gravimetry was used to achieve the thermal stability of the polymer blends. Two degrees of glass transition temperature were observed for each mixture. The results of DSC supported the absence of miscibility in the blend. The distribution of the phases in the virgin and blends was studied through scanning electron microscopy (SEM).
研究了聚苯乙烯和聚氯乙烯共混物(PS/PVC)的形态和热性能。用环己酮将PS和PVC溶液浇铸后,根据PS/PVC的重量分别配制成100/0、80/20、50/50、20/80和0/100的比例。其中混合物的形成分别由傅里叶变换红外(FT-IR)、热重分析(TGA)和差示扫描量热法(DSC)证实。光谱FT-IR结果表明,PS/PVC共混物未发生分子反应。用热重法测定了聚合物共混物的热稳定性。每种混合物的玻璃化转变温度为2度。DSC结果支持混合物中不存在混相。通过扫描电子显微镜(SEM)研究了原始和共混物中相的分布。
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引用次数: 1
Enhancement of Optical Parameters for PVA/PEG/Cr2O3 Nanocomposites for Photonics Fields 光子场中PVA/PEG/Cr2O3纳米复合材料光学参数的提高
IF 0.8 Q4 Materials Science Pub Date : 2022-08-31 DOI: 10.18280/rcma.320406
M. K. Mohammed, M. H. Abbas, A. Hashim, B. Rabee, M. Habeeb, N. Hamid
In this study, many samples have been synthesized by using solution casting technique with different additive content of Chromium oxide nanoparticle (Cr2O3NPs), poly vinylalcohol (PVA) and polyethylene glycol (PEG). The UV-Vis. spectrophotometer used to record the absorbance spectrum in the range of (200-800) nm. The absorption of UV waves is improved while the transmittance is reduced when Cr2O3 NPs were added to the polymeric system which are useful for a number of applications including low-cost UV protection and solar radiation shield. When Cr2O3 NPs concentrations increased, the optical energy gap for indirect transition (allowed and forbidden) was decreased. Furthermore, all the optical constant has been improved.
在本研究中,采用溶液浇铸技术合成了许多具有不同添加剂含量的氧化铬纳米颗粒(Cr2O3NP)、聚乙烯醇(PVA)和聚乙二醇(PEG)的样品。UV Vis。分光光度计,用于记录(200-800)nm范围内的吸收光谱。当将Cr2O3 NP添加到聚合物体系中时,UV波的吸收得到改善,而透射率降低,这对于许多应用是有用的,包括低成本的UV保护和太阳辐射屏蔽。当Cr2O3 NPs浓度增加时,用于间接跃迁(允许和禁止)的光学能隙减小。此外,所有的光学常数都得到了改善。
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引用次数: 1
The Effect of Chromium on the Chemical and Physical Properties of Industrial Sludge Based Geopolymer 铬对工业污泥基地聚合物理化性能的影响
IF 0.8 Q4 Materials Science Pub Date : 2022-06-30 DOI: 10.18280/rcma.320305
E. Imad, Fath Allah Rabie, Fakih Lanjri Asmaa, A. Mohammed, B. Laila
This paper investigates the immobilization of chromium in the industrial sludge-based geopolymer. Mechanical, physical and microstructure properties were used to characterize different samples. The results show that lower heavy metals addition has less effect on the compressive strength. However, excessive addition of Cr(VI) (1.5 and 3%) causes a deterioration of geopolymer matrix with a significant drop of the compressive strength. The compressive strength shows that the use of sodium hydroxide as an alkaline activator is not suitable for chromium immobilization. The use of 1.5 and 3% amount of chromium increases the conductivity of leachates, which explains a change in the microstructure of materials. This is in agreement with the results of compressive strength. XRD patterns of all samples show an amorphous structure with less effect of chromium on the crystalline phases. SEM of the reference sample demonstrates a dense structure of binder. However, the porosity of the matrix increases with the addition of 3% Cr(VI).
研究了铬在工业污泥基地聚合物中的固定化。采用力学、物理和显微组织性能对不同样品进行表征。结果表明,较低的重金属添加量对抗压强度影响较小。然而,过量添加Cr(VI)(1.5%和3%)会导致地聚合物基体劣化,抗压强度显著下降。抗压强度表明,使用氢氧化钠作为碱性活化剂不适合固定铬。使用1.5%和3%的铬增加了渗滤液的导电性,这解释了材料微观结构的变化。这与抗压强度的结果一致。所有样品的XRD图谱均显示为非晶态结构,铬对晶相的影响较小。参考样品的SEM显示出致密的粘结剂结构。然而,随着Cr(VI)含量的增加,基体的孔隙率增加。
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引用次数: 0
Effect of Graphite Addition on Aluminum Hybrid Matrix Composite by Powder Metallurgy Method 石墨添加对粉末冶金法制备铝混杂基体复合材料的影响
IF 0.8 Q4 Materials Science Pub Date : 2022-06-30 DOI: 10.18280/rcma.320303
M. Syahid, A. Hayat, Aswar
The requirement for optimal strength and lightweight materials is a challenge in today's automotive industry. In this study, the synthesis of aluminum matrix hybrid composites containing magnesium and copper with the addition of graphite 0, 1, 3, and 5% by volume was carried out using powder metallurgy techniques and investigated the effect of the treatment given. The investigation of composite properties was carried out by testing density, porosity, hardness, wear rate, XRD, and SEM investigations integrated with EDS. Optimal conditions indicated composite with a content of 5% volume of graphite with the lowest porosity level of 5.10%, the relative density of 88.67%, and the highest hardness at 50.37 HV, followed by superior wear resistance. This result is supported by observing secondary phase formation and microstructure through XRD and SEM-EDS. The addition of graphite in the composite supports optimizing physical and mechanical properties as a lightweight composite. It deserves to be considered as an alternative material for automotive components.
在当今的汽车工业中,对最佳强度和轻质材料的要求是一个挑战。在本研究中,采用粉末冶金技术,分别添加体积分数为0、1、3和5%的石墨,合成了含镁、铜的铝基杂化复合材料,并考察了处理的效果。通过密度、孔隙率、硬度、磨损率、XRD、SEM、EDS等测试手段对复合材料的性能进行了研究。最佳工艺条件为:石墨体积含量为5%时,复合材料孔隙率最低为5.10%,相对密度为88.67%,硬度最高为50.37 HV,耐磨性最佳。通过XRD和SEM-EDS对二次相形成和微观结构的观察支持了这一结果。在复合材料中添加石墨支持优化作为轻质复合材料的物理和机械性能。它值得被认为是汽车零部件的替代材料。
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引用次数: 2
Tribological and Mechanical Performance of Epoxy Reinforced by Fish Scales Powder 鱼鳞粉增强环氧树脂的摩擦学和力学性能
IF 0.8 Q4 Materials Science Pub Date : 2022-06-30 DOI: 10.18280/rcma.320306
Ali Kifah Ghazi, Ayad Abid Muhmmed, Nabil kadhim Taieh, M. Mejbel
The study was conducted to use fish scales powder as animal biomass to prepare epoxy composites. Fish scales powder is beneficial in reducing environmental pollutants. The fish scales powder was added to the epoxy matrix for improving the interfacial bonding between the scales and the epoxy matrix. However, a direct method was used to prepare epoxy composites, and samples were cut according to ASTM standards for mechanical and tribological tests. Interfacial interaction between the fish scales powder and epoxy was investigated by FTIR and SEM. It was found that the fish scales powder contents affect the mechanical properties and tribological behaviour of produced composites. Compared to pure epoxy, the load of 10 wt.% fish scales powder increased the tensile strength by 16.0%. As well as, the coefficient of friction was reduced by 16.0% and wear resistance was enhanced by 48.58%. The improvements in the performance of composites are contributed to the hydrogen bonding formed between fish scales powder and epoxy matrix.
以鱼鳞粉为动物生物质制备环氧树脂复合材料。鱼鳞粉有利于减少环境污染物。将鱼鳞粉添加到环氧树脂基体中,以改善鱼鳞与环氧树脂基体之间的界面结合。然而,使用直接方法制备环氧树脂复合材料,并根据ASTM标准切割样品进行机械和摩擦学测试。通过红外光谱和扫描电镜研究了鱼鳞粉与环氧树脂的界面相互作用,发现鱼鳞粉的含量对复合材料的力学性能和摩擦学性能有影响。与纯环氧树脂相比,10 wt.%鱼鳞粉的负载使复合材料的抗拉强度提高了16.0%,摩擦系数降低了16.0%、耐磨性提高了48.58%。鱼鳞粉与环氧树脂基体形成氢键是复合材料性能提高的原因。
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引用次数: 5
Glycerol /Phthalic Anhydride Novel Nano Composite for Microwave Absorbing Applications 甘油/邻苯二酸酐新型微波吸收纳米复合材料
IF 0.8 Q4 Materials Science Pub Date : 2022-06-30 DOI: 10.18280/rcma.320304
Batool Abdul Rasool Zaki, F. Rashid, Mohammad N. Al-Baiati
High-efficiency radar wave absorbing material was prepared utilizing nanoparticles poly (glycerol /phthalic anhydride), and the effect of using these nanocomposites with thermal paint on the properties of electromagnetic absorbing was analyzed and investigated. Results show that when the percentage of nano polymers is increased from 1% to 3%, with the presence of 2.5% of iron oxide, the reflectivity loss value rises dramatically. For the reflectivity up to 27.2dB at a frequency of 8.3 GH and a bandwidth of (8.1-8.2GH), there is a clear attenuation of the radar waves, which is confined within a bandwidth of GH (9-9.3GH). This material can be utilized as a high- efficiency radar wave absorbing applications.
利用纳米聚甘油/邻苯二酸酐制备了高效的雷达波吸波材料,并分析和研究了这些纳米复合材料与热敏涂料的使用对电磁吸波性能的影响。结果表明,当纳米聚合物的掺量从1%增加到3%,氧化铁的掺量为2.5%时,反射率损失值急剧上升。在8.3 GH频率和(8.1-8.2GH)带宽下,反射率高达27.2dB时,雷达波有明显的衰减,其衰减被限制在(9-9.3GH)带宽范围内。该材料可作为高效的雷达波吸收材料应用。
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引用次数: 1
Synthesis and Characterization of Erbium Doped Lead Zirconate Titante Thin Films 掺铒锆酸铅钛酸盐薄膜的合成与表征
IF 0.8 Q4 Materials Science Pub Date : 2022-06-30 DOI: 10.18280/rcma.320301
Rusul Ahmed Shakir, Marwan T. Mezher, R. Géber
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引用次数: 1
Compressive and Tensile Properties of ABS Material as a Function of 3D Printing Process Parameters ABS材料的压缩和拉伸性能与3D打印工艺参数的关系
IF 0.8 Q4 Materials Science Pub Date : 2022-06-30 DOI: 10.18280/rcma.320302
H. B. Ali, J. K. Oleiwi, F. Othman
Additive Manufacturing (AM) technologies have been emerged as a fabrication method to obtain engineering components within a short span of time. 3D printing, also referred as additive layer manufacturing technology is one of the powerful methods of rapid prototyping (RP) technique that fabricates three-dimensional engineering components. fused deposition modelling (FDM) is one of the most commonly used additive manufacturing (AM) methods, with applications in modelling, prototyping, and production. Acrylonitrile–butadiene–styrene (ABS) is a widely used industrial thermoplastic that is also the most commonly used material in FDM technology. Understanding the impact of FDM build settings on material characteristics is essential for predicting the behaviour of ABS components. The purpose of this study is to determine the impact of specimen tensile and compressive behaviour on ABS components produced using FDM. The Ultimaker+2 printer is used to create ABS thermoplastic samples for the investigation. The samples are put through their tests using a modified form of ASTM D638 for tensile strength and ASTM D695 for compressive strength. An Instron testing machine is used to put the printed parts to the test. The approach employed was Design of Experiment (DOE). Three primary criteria are used in the plastics experiment: infill density, layer thickness, and infill pattern. We measured the tensile and compressive strengths of zigzag and gyroid specimens, as well as cross specimens. The highest compressive strength at break (25.01 MPa), Young's modulus (2.473 GPa), fracture strength (21.016 MPa), and ultimate tensile stress (23.1 MPa) were all discovered in a sample with 60% infill density, 0.05mm layer thickness, and a GYROID infill pattern.
增材制造(AM)技术已经成为一种在短时间内获得工程部件的制造方法。3D打印,也被称为增材层制造技术,是制造三维工程部件的快速成型(RP)技术的强大方法之一。熔融沉积建模(FDM)是最常用的增材制造(AM)方法之一,在建模、原型制作和生产中都有应用。丙烯腈-丁二烯-苯乙烯(ABS)是一种应用广泛的工业热塑性塑料,也是FDM技术中最常用的材料。了解FDM构建设置对材料特性的影响对于预测ABS组件的行为至关重要。本研究的目的是确定试样的拉伸和压缩行为对使用FDM生产的ABS组件的影响。Ultimaker+2打印机用于制作ABS热塑性塑料样品。样品使用ASTM D638抗拉强度和ASTM D695抗压强度的改进形式进行测试。使用Instron试验机对打印出来的零件进行测试。采用试验设计(DOE)方法。在塑料实验中使用三个主要标准:填充密度、层厚度和填充模式。我们测量了锯齿形、旋转形和交叉形试件的抗拉强度和抗压强度。当充填密度为60%、充填层厚度为0.05mm、充填方式为GYROID时,试样的断裂抗压强度最高(25.01 MPa),杨氏模量最高(2.473 GPa),断裂强度最高(21.016 MPa),极限拉应力最高(23.1 MPa)。
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引用次数: 3
Effect of Spacing Between Baffles on the Dynamic and Thermal Behavior of Water in a Shell-and-Tube Heat Exchanger 折流板间距对管壳式换热器中水的动态和热行为的影响
IF 0.8 Q4 Materials Science Pub Date : 2022-06-30 DOI: 10.18280/rcma.320307
A. Youcef, R. Saim
A numerical simulation of a turbulent flow of water in three shell and tube heat exchangers equipped with 6, 8, 10 segmental baffles as the working fluid at Reynolds numbers ranging from 24327, 33356, 42569 are performed. The conservation equations of mass, momentum and energy are solved by the finite volume method based on the SIMPLE algorithm for coupling velocity-pressure, the mathematical model k-ε within the Fluent software is used in the different cases presented. The temperature, the velocity, the friction factor, the heat transfer coefficient, the pressure drop in the shell, the total heat transfer rate between the tubes and the fluid, the overall performance factor are studied for the three spacing between baffles. This work contributes largely to the understanding of turbulent flows and also shows the effect of the baffles number on the heat transfer in the heat exchangers. The velocity of flow in the shell increases by 1.49% and 1.62% and 1.73% of the reference velocity. The results show an increase in the outlet temperature, heat transfer coefficient 1.09% and 1.28%, pressure drop 1.7% and 2.82%, the total heat transfer rate 1.08% and 1.18% because of the increase in number of baffles. The results obtained in this study are in good agreement and correspond to the results given by the literature.
对雷诺数为2432733562569的三个装有6、8、10节段挡板的管壳式换热器中的湍流进行了数值模拟。基于SIMPLE速度-压力耦合算法,采用有限体积法求解质量、动量和能量守恒方程,并在不同情况下使用Fluent软件中的数学模型k-ε。研究了三个挡板间距下的温度、速度、摩擦系数、传热系数、壳体压降、管与流体之间的总传热率、整体性能系数。这项工作在很大程度上有助于理解湍流,也显示了挡板数量对换热器传热的影响。壳体中的流速分别比参考速度增加了1.49%、1.62%和1.73%。结果表明,由于挡板数量的增加,出口温度、传热系数分别增加了1.09%和1.28%,压降分别增加了1.7%和2.82%,总传热率分别增加了1.0%和1.18%。本研究中获得的结果与文献中给出的结果一致。
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引用次数: 1
Effect of Size and Volume on the Breaking Properties of Fragile Materials: The Case of Laminate for Orthopedic Acrylic Glass-Perlon Use 尺寸和体积对易碎材料断裂性能的影响——以整形用丙烯酸玻璃- perlon层压板为例
IF 0.8 Q4 Materials Science Pub Date : 2022-04-30 DOI: 10.18280/rcma.320202
S. Achouri, B. Redjel, M. Bourebia
The stresses at break of fragile materials like acrylic resin and composite material for orthopedic use measured in bending are higher than those measured in direct traction. Tests on a composite material for orthopedic use laminated with 6 glass-perlon-acrylic layers (PV-2P-VP) for orthopedic use made it possible to identify its mechanical characteristics and to highlight the influence of the direction of cutting of the samples. The mechanical properties of this material indicate dispersion in the direction of the orientation of the molding which shows values of stress at break and of the Young's modulus which are reduced compared to the values measured in the perpendicular direction. The choice motivates the statistical approach which leads us to apply the Weibull model to assess the dangerousness of a stress in terms of probability of failure. The theoretical predictions are in good agreement with the experimental values. The morphological study of the fracture facies makes it possible to draw up an inventory of the various mechanisms at the origin of the damage and the rupture of these materials and thus to locate the most dominant.
易碎材料如整形用丙烯酸树脂和复合材料弯曲时的断裂应力高于直接牵引时的断裂应力。对一种骨科用复合材料进行了测试,该复合材料具有6层用于骨科的玻璃-perlon-丙烯酸层(PV-2P-VP),从而可以识别其机械特性并突出样品切割方向的影响。这种材料的力学性能表明在成型方向上的分散,这表明断裂时的应力值和杨氏模量与垂直方向上的测量值相比减小了。选择激发了统计方法,导致我们应用威布尔模型来评估失败概率方面的压力的危险性。理论预测与实验值吻合较好。对断裂相的形态学研究使我们有可能对这些材料的破坏和破裂的起源的各种机制编制一份清单,从而找到最主要的机制。
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引用次数: 1
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Revue des Composites et des Materiaux Avances-Journal of Composite and Advanced Materials
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