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SEPARATION OF AMERICIUM FROM AGED PLUTONIUM DIOXIDE 从老化的二氧化钚中分离镅
IF 0.6 Pub Date : 2018-08-20 DOI: 10.12943/CNR.2017.00015
G. Cota-Sanchez, K. Leeder, D. Bureau, M. Watson, Chris MacCready, D. Turgeon, D. Woods
The Recycle Fuel Fabrication Laboratory (RFFL) is a licensed nuclear facility designed to produce experimental quantities of mixed oxide fuel for reactor physics tests and demonstration irradiations. Since its refurbishment in 1996, several fuel fabrication campaigns and research projects have been completed. The RFFL is the only facility in Canada capable of handling significant quantities of plutonium and other actinides. In this context, effort has been put forth in recent years to demonstrate capabilities in new fields, such as actinide chemistry. One of the first experiments in actinide chemistry conducted in the Facility was devoted to the separation and purification of 241Am from aged PuO2. The experimental work presented here, was conducted to establish actinide separation capability at the RFFL and demonstrate the staff expertise to perform these types of separations. The separation experiments were carried out using ion exchange columns packed with basic anion exchange AG1-X4 resin. More than 92% of the 241Am contained in the starting PuO2 solution was recovered in the experiments; however, some plutonium was also found in the washing effluent fraction. The final americium concentration of the washing effluent fraction was estimated to be about 50% of the total heavy elements present. More than 93% of the purified plutonium retained in the column was eluted. The experimental results are discussed in terms of the speciation behaviour of the Am–Pu–N–H2O systems using E-pH thermodynamic equilibrium diagrams and the maximum ionic exchange capacity of the resin.
循环燃料制造实验室(RFFL)是一个获得许可的核设施,旨在生产实验量的混合氧化物燃料,用于反应堆物理测试和演示辐照。自1996年翻修以来,已经完成了几个燃料制造活动和研究项目。RFFL是加拿大唯一能够处理大量钚和其他锕系元素的设施。在这种背景下,近年来人们努力展示在新领域的能力,如锕系元素化学。在该设施中进行的锕系元素化学的首批实验之一致力于从老化的PuO2中分离和纯化241Am。这里介绍的实验工作是为了在RFFL建立锕系元素分离能力,并展示员工进行这些类型分离的专业知识。使用填充有碱性阴离子交换AG1-X4树脂的离子交换柱进行分离实验。在实验中回收了起始PuO2溶液中所含241Am的92%以上;然而,在洗涤废水中也发现了一些钚。洗涤流出物部分的最终镅浓度估计为存在的总重元素的约50%。保留在该柱中的纯化钚有93%以上被洗脱。使用E-pH热力学平衡图和树脂的最大离子交换容量,从Am–Pu–N–H2O体系的物种形成行为的角度讨论了实验结果。
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引用次数: 2
CHARACTERIZATION OF PLUTONIUM DISTRIBUTION IN THO2–PUO2 MIXED OXIDES BY ELECTRON PROBE MICROANALYSIS THO2-PUO2混合氧化物中钚分布的电子探针微区分析
IF 0.6 Pub Date : 2018-08-20 DOI: 10.12943/CNR.2017.00014
D. Woods, M. Saoudi, C. Mayhew, R. Ham-su
Thoria–plutonia (ThO2–PuO2) pellets with a nominal composition of 9.0 wt% PuO2 were prepared using a fabrication route similar to an industrial process for production of urania–plutonia (UO2–PuO2) mixed oxide fuel. The green fuel pellets were separated into 2 batches and the sintering of each batch was carried out under a reducing atmosphere at 1820 °C or 1750 °C. The distribution of plutonium (Pu) in the sintered pellets was investigated by electron probe microanalysis using X-ray mapping and quantitative point analyses. The results show that the pellet samples consist of Pu-rich agglomerates with Pu content close to that of the mastermix blend and a thorium (Th)-rich matrix. The matrix and the Pu-rich agglomerates are separated by a transition zone with Pu content varying from practically nil to the Pu content of the Pu-rich agglomerates. X-ray maps taken from random regions of the centre of the pellets show different sizes of Pu-rich agglomerates irregularly dispersed in the Th-rich matrix. Image analysis of the Pu X-ray maps indicate that the average diameter of the Pu-rich agglomerates of the material sintered at 1820 °C and 1750 °C were 68 μm and 161 μm, respectively.
采用与工业生产铀-钚(UO2-PuO2)混合氧化物燃料相似的工艺路线,制备了标称组成为9.0 wt% PuO2的钍-钚(ThO2-PuO2)球团。将绿色燃料球团分成2批,每批在1820℃或1750℃的还原气氛下进行烧结。采用电子探针微量分析、x射线作图和定量点分析等方法研究了烧结球团中钚(Pu)的分布。结果表明,球团样品由富Pu团聚体和富钍(Th)基体组成,其Pu含量与母料混合物相近。基体与富Pu团聚体之间存在一个过渡带,其Pu含量从几乎为零到富Pu团聚体的Pu含量不等。从颗粒中心随机区域拍摄的x射线图显示,不同大小的富铅团块不规则地分散在富th基质中。x射线图的图像分析表明,在1820℃和1750℃烧结时,材料的富Pu团聚体的平均直径分别为68 μm和161 μm。
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引用次数: 1
THE IMPACT OF CONCRETE AND POST-TENSIONING CABLE DEGRADATION ON STRAIN MEASUREMENTS OF CONCRETE CONTAINMENT BUILDINGS 混凝土和后张拉索劣化对混凝土围护结构应变测量的影响
IF 0.6 Pub Date : 2017-12-04 DOI: 10.12943/CNR.2017.00012
Yuqing Ding, S. Jaffer
Concrete containment buildings (CCBs) are important safety structures in nuclear power plants; however, degradation may occur in CCBs as they age. For post-tensioned CCBs, prestressing losses could occur and may affect the CCBs’ performance under accident conditions. CANDU CCBs contain cement-grouted post-tensioning (P-T) cables. The grouting of P-T cables prevents direct monitoring of prestressing losses by traditional lift-off testing. Instrumented monitoring has been recommended as an indirect approach by some guidelines for integrity evaluation of CCBs with grouted prestressing systems. As part of the investigation on the relationship between instrumentation data and the integrity of CCBs, sensitivity analyses have been performed using finite element models to develop an understanding of the sensitivity of strain changes to degradation factors that contribute to prestressing losses, such as creep and shrinkage of the concrete, stress relaxation, and deterioration of prestressing systems. Strain measurements from a CANDU CCB were analysed to assess the measurement noise, which was compared with the predicted strain changes due to degradation to evaluate whether the degradation of concrete and prestressing systems can be captured by strain instrumentation. The analysis reveals that the strain changes due to degradation, except the creep and shrinkage during the early years of CCBs, were comparable with the level of noise observed in the measured strain data. Degradation mechanisms related to prestressing losses have conflicting effects on strain changes and are difficult to assess individually. Therefore, it could be difficult to detect the prestressing losses and the effect of individual degradation issues using strain instrumentation.
混凝土安全壳是核电站的重要安全结构;然而,随着年龄的增长,CCB可能会发生退化。对于后张式CCB,可能会发生预应力损失,并可能影响CCB在事故条件下的性能。CANDU CCB包含水泥灌浆后张拉(P-T)电缆。P-T电缆的灌浆防止了通过传统的剥离测试直接监测预应力损失。一些指南建议将仪器监测作为一种间接方法,用于灌浆预应力系统CCB的完整性评估。作为仪器数据与CCBs完整性之间关系研究的一部分,已经使用有限元模型进行了敏感性分析,以了解应变变化对导致预应力损失的退化因素的敏感性,如混凝土的蠕变和收缩、应力松弛,以及预应力系统的劣化。对CANDU CCB的应变测量结果进行了分析,以评估测量噪声,并将其与由于退化而预测的应变变化进行了比较,以评估应变仪器是否可以捕捉到混凝土和预应力系统的退化。分析表明,除了CCBs早期的蠕变和收缩外,退化引起的应变变化与测量应变数据中观察到的噪声水平相当。与预应力损失相关的退化机制对应变变化有着相互矛盾的影响,很难单独评估。因此,使用应变仪可能很难检测预应力损失和单个退化问题的影响。
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引用次数: 0
CASE STUDIES OF NUCLEAR RESEARCH SOFTWARE DEVELOPMENT 核研究软件开发案例研究
IF 0.6 Pub Date : 2017-12-04 DOI: 10.12943/CNR.2017.00013
Huiping Yan, S. Yatabe
Experimental and operational data are valuable assets for the field of nuclear science and technology. It is very important to develop software tools to assist scientists to manage the data effectively and to conveniently access and share the data. This paper presents 5 case studies on software development pertaining to topical areas such as nuclear fuel performance, waste management, biological research, reactor physics, and chemistry analysis at Canadian Nuclear Laboratories (CNL). Each case study illustrates the design and development of the database and user interface for its target research area and end users. While datasets based on flat files are still used in reactor physics studies, full-scale relational databases are developed for most of the other studies. The user interfaces developed for these areas include web applications, desktop applications, and mobile applications. These software tools have become essential parts of the research activities at CNL.
实验和运行数据是核科学和技术领域的宝贵资产。开发软件工具以帮助科学家有效地管理数据并方便地访问和共享数据是非常重要的。本文介绍了加拿大核实验室(CNL)关于核燃料性能、废物管理、生物研究、反应堆物理和化学分析等主题领域的软件开发的5个案例研究。每个案例研究都说明了其目标研究领域和最终用户的数据库和用户界面的设计和开发。虽然基于平面文件的数据集仍在反应堆物理研究中使用,但大多数其他研究都开发了全尺寸的关系数据库。为这些领域开发的用户界面包括web应用程序、桌面应用程序和移动应用程序。这些软件工具已成为CNL研究活动的重要组成部分。
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引用次数: 0
EMERGING AREAS OF SHIELDING RESEARCH—A BIRD’S EYE VIEW 屏蔽研究的新兴领域&鸟瞰
IF 0.6 Pub Date : 2017-09-15 DOI: 10.12943/CNR.2017.00008
R. Dranga, F. Adams
Shielding analysis and design are important tools for ensuring that humans and the environment are protected from the detrimental effects of high levels of radiation. The fundamental principles and methodologies for shielding analysis and design, especially for reactor applications, have been developed and refined since the 1940s and the beginning of nuclear power research programs in Canada and internationally. Other applications are gaining importance due to both increased need and technological advances. In this work, a high-level survey of emerging areas in shielding research and development is provided. Areas of topical interest include remote reactor monitoring, source reconstruction and inverse shielding methods, waste management and decommissioning applications, accelerator, cyclotron, and other advanced medical shielding applications, space exploration, and new materials development. Each of these areas of interest is evaluated based on current capacity of the research community. They are also evaluated in terms of the benefits for the scientific community and industry arising from performing research including development of new technologies and techniques.
屏蔽分析和设计是确保人类和环境免受高水平辐射有害影响的重要工具。屏蔽分析和设计的基本原则和方法,特别是反应堆应用,自20世纪40年代以来,以及加拿大和国际上核能研究项目的开始,已经得到了发展和完善。由于需求的增加和技术的进步,其他应用越来越重要。在这项工作中,对屏蔽研究和开发的新兴领域进行了高水平的调查。感兴趣的领域包括远程反应堆监测、源重建和反屏蔽方法、废物管理和退役应用、加速器、回旋加速器和其他先进的医疗屏蔽应用、太空探索和新材料开发。每一个感兴趣的领域都是根据研究界目前的能力进行评估的。它们还根据进行研究(包括开发新技术和技术)对科学界和工业的好处进行评估。
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引用次数: 0
ON THE USE OF A CENTRAL THORIUM FUEL ELEMENT IN PRESSURE-TUBE HEAVY-WATER REACTOR FUEL BUNDLES 中心钍燃料元件在压力管式重水反应堆燃料束中的应用
IF 0.6 Pub Date : 2017-09-15 DOI: 10.12943/CNR.2017.00009
M. McDonald, M. Moore, D. Wojtaszek, Nicholas Chornoboy, G. Edwards
An incremental approach to introducing thorium to the conventional pressure-tube heavy-water reactor natural uranium fuel cycle is investigated. The approach involves the replacement of the centre fuel element of the bundle with an element of thorium dioxide. Increasing the operating margin of a key safety parameter, the coolant void reactivity, is a prime motivating factor. The analyses showed that the simple use of a single pin of thorium is unlikely to be economically advantageous due to a large burnup penalty and increased fuel costs. However, a slight reduction in the void reactivity is observed, and this approach does allow the exploitation of the energy potential available in thorium as an alternative nuclear fuel resource through the development of a U-233 resource. This bundle concept may also be advantageous from a fuel disposal point of view, as the fuel requires less time in storage before emplacement in a deep geological repository.
研究了在常规压管重水堆天然铀燃料循环中引入钍的增量方法。该方法包括用二氧化钍元素替换管束的中心燃料元素。增加一个关键安全参数(冷却剂空隙反应性)的运行裕度是一个主要的激励因素。分析表明,由于大量的燃耗和增加的燃料成本,简单使用一针钍在经济上不太可能有利。然而,观察到空隙反应性略有降低,这种方法确实允许通过开发U-233资源,利用钍作为替代核燃料资源的潜力。从燃料处理的角度来看,这种束的概念也可能是有利的,因为在将燃料放入深层地质储存库之前,燃料需要较少的储存时间。
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引用次数: 2
CHALLENGES FOR PHYSICS-BASED MODELS OF A RADIONUCLIDE DISPERSAL DEVICE 放射性核素扩散装置物理模型面临的挑战
IF 0.6 Pub Date : 2017-09-15 DOI: 10.12943/CNR.2017.00005
D. Hummel, L. Ivan
A “dirty bomb” is a type of hypothetical radiological dispersal device (RDD) that has been the subject of significant safety and security concerns given the disruption that would result in a postulated terrorist attack. Reliable and accurate predictions of dispersion of radiological material from an RDD are absolutely necessary for first responders and emergency decision makers to plan effective response strategies. Development of high-fidelity, mechanistic models of a dirty bomb are complicated because dispersion over areas with the greatest risk of contamination is highly sensitive to the source of contaminant particles, and this source term is governed by processes over much smaller temporal and spatial length scales than the dispersion. New work on accelerating high-fidelity models of RDDs has been initiated that looks to incorporate the multiscale aspects of the problem and enhance predictive capabilities that may assist in anti-terrorism activities.
“脏弹”是一种假想的放射性扩散装置(RDD),考虑到可能导致假想恐怖袭击的破坏,它一直是重大安全和安保问题的主题。对RDD放射性物质扩散的可靠和准确预测对于急救人员和应急决策者制定有效的应对策略是绝对必要的。脏弹高保真度机械模型的开发是复杂的,因为在污染风险最大的地区的扩散对污染物颗粒的来源高度敏感,而这个源项是由比扩散小得多的时间和空间长度尺度上的过程控制的。关于加速RDD高保真度模型的新工作已经启动,旨在纳入问题的多尺度方面,并增强可能有助于反恐活动的预测能力。
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引用次数: 0
DEVELOPMENT OF A HYDROGEN MANAGEMENT CONCEPT FOR THE CANADIAN SUPERCRITICAL WATER-COOLED REACTOR 加拿大超临界水冷堆氢管理概念的发展
IF 0.6 Pub Date : 2017-09-15 DOI: 10.12943/CNR.2017.00004
L. Gardner, D. Ryland, S. Suppiah
Accidental hydrogen production in nuclear reactors has been a significant focus of nuclear reactor safety for decades. However, since the accident at Fukushima Daiichi nuclear generating station, hydrogen safety in nuclear reactors is a more relevant topic. As new reactor concepts, such as the supercritical water-cooled reactor (SCWR), are designed and developed the risk of unintentional hydrogen generation is not eliminated; however, it can be mitigated in the design. A systematic assessment of the hydrogen risk from both normal and accident conditions in the Canadian SCWR design was performed, in which various techniques to mitigate the hydrogen combustion potential were considered. While the rate of hydrogen generation under normal operating conditions was found to be low when held at supercritical water conditions, conservative estimates suggest that a significant quantity of hydrogen may be produced and released to the containment building in a severe accident. As a result, a hydrogen–oxygen management concept has been proposed to mitigate the hydrogen produced in a severe accident that includes a nitrogen-inerted containment building to reduce the combustion potential of hydrogen and the installation of passive autocatalytic recombiners for oxygen management. This hydrogen–oxygen management concept results in significant design changes and likely significant economic and operational impacts on the Canadian SCWR design.
几十年来,核反应堆中的意外氢气生产一直是核反应堆安全的一个重要焦点。然而,自从福岛第一核电站发生事故以来,核反应堆中的氢气安全是一个更相关的话题。随着新反应堆概念的设计和开发,如超临界水冷反应堆(SCWR),无意中产生氢气的风险并没有消除;然而,它可以在设计中减轻。在加拿大SCWR设计中,对正常和事故条件下的氢气风险进行了系统评估,其中考虑了降低氢气燃烧潜力的各种技术。虽然在超临界水条件下,正常运行条件下的氢气生成率较低,但保守估计表明,在严重事故中,可能会产生大量氢气并释放到安全壳厂房。因此,提出了一种氢氧管理概念,以减少严重事故中产生的氢气,其中包括一座氮惰性安全壳建筑,以降低氢气的燃烧潜力,并安装用于氧气管理的非能动自催化复合器。这种氢氧管理概念导致了重大的设计变更,并可能对加拿大SCWR设计产生重大的经济和运营影响。
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引用次数: 0
POTENTIAL MITIGATION STRATEGIES FOR PREVENTING STRESS CORROSION CRACKING FAILURES IN HIGH-BURNUP CANDU FUEL 防止高燃耗candu燃料应力腐蚀开裂失效的潜在缓解策略
IF 0.6 Pub Date : 2016-09-28 DOI: 10.12943/CNR.2016.00011
M. Piro, D. Sunderland, W. Revie, S. Livingstone, I. Dimayuga, A. Douchant, Michael Wright
Potential mitigation strategies for preventing stress corrosion cracking (SCC) failures in CANDU fuel cladding that are based on lessons learned on both domestic and international fronts are discussed in this paper. Although SCC failures have not been a major concern in CANDU reactors in recent decades, they may resurface at higher burnup for conventional fuels or with nonconventional fuels that are currently being investigated, such as MOX or thoria-based fuels. The motivation of this work is to provide the foundation for considering possible remedies for SCC failures. Three candidate remedies are discussed, namely improved fabrication methods for fuel appendages, barrier-liner cladding, and fuel doping. In support of this effort, recent advances in experimental characterization methods are described—methods that have been successfully used in non-nuclear materials that can be used to further elucidate SCC behaviour in CANDU fuel. The overall objective is to outline a path forward for characterizing material behaviour as an essential part of investigating remedies to SCC failure. This will allow increased fuel discharge burnup, maximum linear power, and plant manoeuvrability, while maintaining a high degree of reliability.
基于国内外的经验教训,本文讨论了防止CANDU燃料包壳应力腐蚀开裂(SCC)失效的潜在缓解策略。尽管近几十年来SCC失效并不是CANDU反应堆的主要问题,但它们可能会在常规燃料或目前正在研究的非常规燃料(如MOX或钍基燃料)的高燃耗下重新出现。这项工作的动机是为考虑SCC失败的可能补救措施提供基础。讨论了三种候选补救措施,即改进燃料附件的制造方法,屏障衬里包层和燃料掺杂。为了支持这一努力,本文描述了实验表征方法的最新进展,这些方法已成功地用于非核材料,可用于进一步阐明CANDU燃料中的SCC行为。总体目标是概述材料行为特征的前进道路,作为调查SCC失效补救措施的重要组成部分。这将允许增加燃料排放燃耗,最大线性功率和工厂机动性,同时保持高度的可靠性。
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引用次数: 3
期刊
CNL Nuclear Review
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