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Alkali-reduced Bauxite Residue as Novel SCM 碱还原铝土矿渣作为新型SCM
IF 1 Q4 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2020-12-01 DOI: 10.2478/ncr-2020-0015
Tobias Danner, M. Sletnes, H. Justnes
Abstract Bauxite residue is a major waste stream available in large volumes globally that can cause risks to the surrounding environment (e.g. ecotoxicity) when disposed and stored by conventional methods. There is yet no large-scale application and the utilization as supplementary cementitious material might be the best way to re-use bauxite residue. The main obstacle for the utilization of bauxite residue in the construction industry is the high alkalinity. This paper presents first results of a study on alkali reduction of bauxite residue by acetic acid treatment and the potential application of this alkali reduced bauxite residue as pozzolan in cementitious binders. A process of alkali reduction is presented that can help solving waste management problems of alumina refineries by transforming bauxite residue to a less hazardous waste, while producing a reactive pozzolan and Na-acetate that can find application in the construction and infrastructure market. 90% alkalinity reduction of bauxite residue could be achieved by simply washing with diluted acetic acid. Alkali-reduced bauxite residue showed good pozzolanic reactivity regarding portlandite consumption, bound water and 28-day compressive strength of mortars with 20% replacement of OPC.
铝土矿渣是全球范围内大量存在的一种主要废物流,当采用传统方法处理和储存铝土矿渣时,会对周围环境造成风险(如生态毒性)。目前还没有大规模的应用,作为补充胶凝材料加以利用可能是铝土矿渣资源化利用的最佳途径。铝土矿渣在建筑工业中利用的主要障碍是高碱度。本文介绍了用醋酸法对铝土矿渣进行碱还原的初步研究结果,以及碱还原后的铝土矿渣作为胶结剂中灰岩的潜在应用前景。提出了一种碱还原工艺,通过将铝土矿渣转化为危害较小的废物,可以帮助解决氧化铝精炼厂的废物管理问题,同时生产可在建筑和基础设施市场上应用的活性火山灰和醋酸钠。铝土矿渣用稀释的醋酸简单洗涤,碱度可降低90%。碱还原铝土矿渣在硅酸盐用量、束缚水和OPC置换量为20%的砂浆28天抗压强度方面表现出良好的火山灰反应性。
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引用次数: 3
Utilization of Bio Ashes in Cement-based Materials: A Case Study in Cooperation with Pulp and Paper and Energy Production Industries in Sweden 生物灰在水泥基材料中的利用:与瑞典纸浆、造纸和能源生产行业合作的案例研究
IF 1 Q4 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2020-12-01 DOI: 10.2478/ncr-2020-0017
A. Babaahmadi, Gilles Plusquellec, E. L’Hôpital, U. Mueller
Abstract Worldwide increased concern of the CO2 emissions has led to the replacement of coal by biomass in combustion-based power plants. However, this would cause the scarcity of fly ash, one of the most well-known rest products from coal combustion, which is used as supplementary cementitious materials (SCM) in construction sector to reduce the large environmental footprint of cement production. Seeking to find alternative SCMs, this article aims to demonstrate the viability of using bio ashes in Sweden as SCM, which, due to lack of studies validating their value, are landfilled today. According to the obtained results, bio ashes produced at pulp and paper industries have a considerably consistent chemical composition and exhibit a satisfactory pozzolanic behaviour. Nevertheless, according to the conclusions of this study, the pozzolanicity of these alternative binders is not reflected equally with respect to the most known reactivity tests for common SCMs. The results imply that although “R3” tests method infers the pozzolanic characteristics of the bio ashes in focus of this study, the “activity index test” as well as “calcium consumption test” indicate otherwise.
在世界范围内,对二氧化碳排放的日益关注导致了以燃烧为基础的发电厂用生物质代替煤炭。然而,这将导致粉煤灰的稀缺,粉煤灰是最著名的煤炭燃烧余物之一,在建筑部门被用作补充胶凝材料(SCM),以减少水泥生产的巨大环境足迹。为了寻找替代SCM,本文旨在证明在瑞典使用生物灰烬作为SCM的可行性,由于缺乏验证其价值的研究,今天被填埋。根据所获得的结果,纸浆和造纸工业生产的生物灰具有相当一致的化学成分,并表现出令人满意的火山灰行为。然而,根据这项研究的结论,相对于最已知的普通SCMs的反应性测试,这些替代粘合剂的火山灰性并没有得到平等的反映。结果表明,虽然“R3”试验方法推断出了本研究重点生物灰的火山灰特征,但“活性指数试验”和“钙消耗试验”却表明并非如此。
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引用次数: 1
Concrete and Sustainability – Some Thoughts from a Swedish Horizon 具体和可持续性——来自瑞典地平线的一些思考
IF 1 Q4 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2020-12-01 DOI: 10.2478/ncr-2020-0019
J. Silfwerbrand
Abstract Concrete production, especially the cement production, stands for 5-8 percent of the global CO2 emissions. Since concrete is the most frequently used man-made construction materials, this fact is not surprising. Concrete is also the only realistic alternative in order to improve the living circumstances in many countries around the world. Due to its size, the concrete sector has a great responsibility for limiting the consequences of the on-going climate change. The Swedish cement producer Cementa has an ambitious zero vision stating zero CO2 emissions in year 2030. The measures include energy efficiency, bio mass instead of fossil fuels, blended cements, CO2 uptake through carbonation and Carbon Capture Storage (CCS). This paper discusses these measures but also others such as optimization of the concrete mix, optimization of the structural geometry and prolongation of the service life. The paper is ended by a section on adaptation since concrete will also have an important role concerning protection of the built environment for climate change. Protection structures against flood, reconstruction of dams, new waste-water systems and bright permeable concrete pavements reflecting sunlight and improving drainage after heavy rain constitute some examples.
混凝土生产,特别是水泥生产,占全球二氧化碳排放量的5- 8%。由于混凝土是最常用的人造建筑材料,这一事实并不令人惊讶。为了改善世界上许多国家的生活环境,混凝土也是唯一现实的选择。由于其规模,混凝土行业在限制持续气候变化的后果方面负有重大责任。瑞典水泥生产商Cementa有一个雄心勃勃的零愿景,即到2030年实现零二氧化碳排放。这些措施包括能源效率、生物质量代替化石燃料、混合水泥、通过碳化和碳捕获储存(CCS)吸收二氧化碳。本文对这些措施进行了探讨,并对混凝土配合比优化、结构几何优化、延长使用寿命等措施进行了探讨。本文的最后一节是关于适应的,因为混凝土在保护建筑环境以应对气候变化方面也起着重要作用。防洪保护结构、水坝重建、新的废水处理系统和反射阳光的透水混凝土路面以及改善大雨后的排水系统就是一些例子。
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引用次数: 2
Bauxite Residue as Supplementary Cementitious Material – Efforts to Reduce the Amount of Soluble Sodium 铝土矿渣作为补充胶凝材料——减少可溶性钠含量的努力
IF 1 Q4 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2020-06-01 DOI: 10.2478/ncr-2020-0001
Tobias Danner, H. Justnes
Abstract This study investigates the feasibility of using bauxite residue (BR) as supplementary cementitious material (SCM) for the cement and concrete industry. It is shown from pastes of BR and calcium hydroxide, that BR is highly pozzolanic in nature. The early hydration of cement pastes with BR is accelerated while long-term strength is reduced probably due to the alkaline nature of BR. To be used as cement replacement material in concrete, attempts have been made to reduce the alkali content of BR, in particular to reduce the chance of alkali-aggregate reactions. Co-calcination of BR with kaolin or washing and cooking of BR with calcium hydroxide or calcium hydroxide and gypsum resulted in considerable reduction of alkali content; up to 75%. At the same time the reactivity of the BR was reduced but still being higher compared to fly ash already used in the cement industry.
摘要本研究探讨了铝土矿渣(BR)作为水泥和混凝土工业补充胶凝材料(SCM)的可行性。从BR和氢氧化钙的膏体中可以看出,BR的性质是高度火山灰的。掺有丁腈橡胶的水泥浆体早期水化加速,但长期强度降低,可能是由于丁腈橡胶的碱性。为了作为混凝土中的水泥替代材料,人们试图降低BR中的碱含量,特别是减少碱-骨料反应的机会。BR与高岭土共烧或BR与氢氧化钙或氢氧化钙与石膏洗涤蒸煮,碱含量显著降低;高达75%。同时,与水泥工业中已使用的粉煤灰相比,BR的反应性有所降低,但仍高于粉煤灰。
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引用次数: 9
Encapsulation Techniques and Test Methods of Evaluating the Bacteria-Based Self-Healing Efficiency of Concrete: A Literature Review 基于细菌的混凝土自愈效能的封装技术和测试方法:文献综述
IF 1 Q4 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2020-06-01 DOI: 10.2478/ncr-2020-0006
R. Roy, E. Rossi, J. Silfwerbrand, H. Jonkers
Abstract Crack formation in concrete structures due to various load and non-load factors leading to degradation of service life is very common. Repair and maintenance operations are, therefore, necessary to prevent cracks propagating and reducing the service life of the structures. Accessibility to affected areas can, however, be difficult as the reconstruction and maintenance of concrete buildings are expensive in labour and capital. Autonomous healing by encapsulated bacteria-based self-healing agents is a possible solution. During this process, the bacteria are released from a broken capsule or triggered by water and oxygen access. However, its performance and reliability depend on continuous water supply, protection against the harsh environment, and densification of the cementitious matrix for the bacteria to act. There are vast methods of encapsulating bacteria and the most common carriers used are: encapsulation in polymeric materials, lightweight aggregates, cementitious materials, special minerals, nanomaterials, and waste-derived biomass. Self-healing efficiency of these encapsulated technologies can be assessed through many experimental methodologies according to the literature. These experimental evaluations are performed in terms of quantification of crackhealing, recovery of durability and mechanical properties (macro-level test) and characterization of precipitated crystals by healing agent (micro-level test). Until now, quantification of crack-healing by light microscopy revealed maximum crack width of 1.80mm healed. All research methods available for assesing self-healing efficiency of bacteria-based healing agents are worth reviewing in order to include a coherent, if not standardized framework testing system and a comparative evaluation for a novel incorporated bacteria-based healing agent.
摘要混凝土结构由于各种荷载和非荷载因素而产生裂缝,导致使用寿命下降的现象十分普遍。因此,维修和维护操作是必要的,以防止裂缝扩展和减少结构的使用寿命。然而,由于混凝土建筑物的重建和维护在劳动力和资本方面都很昂贵,因此很难进入受灾地区。利用包封的细菌自愈剂进行自主愈合是一种可能的解决方案。在这个过程中,细菌从破裂的胶囊中释放出来,或者被水和氧气的接触触发。然而,它的性能和可靠性取决于持续的供水、对恶劣环境的保护以及胶凝基质的致密性,以使细菌发挥作用。包封细菌的方法有很多,最常用的载体有:包封在聚合材料、轻质聚集体、胶凝材料、特殊矿物、纳米材料和废物衍生的生物质中。这些封装技术的自愈效率可以根据文献通过许多实验方法进行评估。这些实验评估是在裂纹愈合的量化、耐久性和力学性能的恢复(宏观水平测试)和愈合剂沉淀晶体的表征(微观水平测试)方面进行的。到目前为止,通过光镜对裂纹愈合进行量化,发现最大愈合的裂纹宽度为1.80mm。所有可用于评估细菌基愈合剂自愈效率的研究方法都值得回顾,以便包括一个连贯的(如果不是标准化的)框架测试系统和对新型合并细菌基愈合剂的比较评估。
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引用次数: 8
Making Concrete Pavements Competitive by Using the Standardized Framework for Comparisons of Infrastructure Projects in Terms of Cost-Efficiency and Climate Impact 使用标准化框架比较基础设施项目的成本效益和气候影响,使混凝土路面具有竞争力
IF 1 Q4 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2020-06-01 DOI: 10.2478/ncr-2020-0004
L. Strömberg, J. Silfwerbrand, A. Ansell, S. Hintze
Abstract Despite the new Swedish client requirement to reduce the climate impact from the construction of roads, there has been relatively little research so far on how the optimization measures regarding the environmental impact of road pavements can be integrated in the traditional design. An increase in axle weights, changes of the traditional ways of travel, e.g. the use of automated and guided vehicles, and stricter customer requirements on reducing the climate impact require new approaches to steer the road and pavement industry towards more climate neutral solutions. This paper analyzes the latest standards for sustainability assessment of engineering works in an attempt to adjust these standards for assessing various road design options in a comparable and fair way, also when various materials are included.
尽管瑞典的新客户要求减少道路建设对气候的影响,但迄今为止,关于如何将道路路面对环境影响的优化措施融入传统设计的研究相对较少。车轴重量的增加、传统出行方式的改变(例如使用自动驾驶和引导车辆)以及客户对减少气候影响的更严格要求,都需要采用新的方法来引导道路和路面行业朝着更加气候中性的解决方案发展。本文分析了工程可持续性评估的最新标准,试图以可比和公平的方式调整这些标准,以评估各种道路设计方案,也包括各种材料。
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引用次数: 2
Non-destructive Test Methods for Corrosion Detection in Reinforced Concrete Structures 钢筋混凝土结构腐蚀检测的无损检测方法
IF 1 Q4 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2020-06-01 DOI: 10.2478/ncr-2019-0005
Hornbostel Karla, Tobias Danner, M. Geiker
Abstract Several inspection methods can be used to assess the corrosion state of steel reinforcement in concrete. Especially for periodical field surveys and monitoring, non-destructive testing (NDT) methods are to be preferred as they do not cause any or very limited damage to the existing concrete. In this paper, the corrosion state of three reinforced concrete beams exposed to marine environment for 25 years was evaluated by measuring three parameters; electrochemical potential, concrete resistivity and corrosion rate. The measurements were performed with commercial devices. It was found that all devices are applicable for field inspections. Among the methods selected for the study, the electrochemical potential measured in a fine grid and analysed statistically offered the best possibility of evaluating the corrosion state; preferably in combination with selected excavations for determination of the level of corrosion.
摘要混凝土中钢筋的腐蚀状态可采用多种检测方法进行评估。特别是对于定期的现场调查和监测,无损检测(NDT)方法是首选,因为它们不会对现有混凝土造成任何或非常有限的破坏。本文通过测量3个参数,对3根钢筋混凝土梁在海洋环境中暴露25年的腐蚀状态进行了评价;电化学电位,混凝土电阻率和腐蚀速率。测量是用商用设备进行的。发现所有设备都适用于现场检查。在选择的研究方法中,在细网格中测量电化学电位并进行统计分析提供了评估腐蚀状态的最佳可能性;优选与选定的挖掘相结合,以确定腐蚀水平。
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引用次数: 1
Activation Energy for the Concrete Maturity Model – Part 2: New Model for Temperature Dependent Ea 混凝土成熟度模型的活化能-第二部分:温度相关Ea的新模型
IF 1 Q4 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2020-06-01 DOI: 10.2478/ncr-2020-0010
C. V. Nielsen
Abstract The article addresses the modelling of the maturity of concrete. The apparent activation energy is the backbone of the Arrhenius model, which is typically used to model the maturity of concrete. The maturity (or the equivalent age) is influenced by the curing temperature and it is applied when modelling the hydration process and the hardening of concrete for instance in order to forecast the early-age strength to determine the time for removal of formwork or the time for prestressing. Part 1 of the article describes the background for the maturity model and the tests carried out as part of a large test programme at the DTI concrete lab. The tests were applying iso-thermal curing temperatures from 5°C to 60°C for various durations before measuring the compressive strength. Part 2 of the article presents a model for the activation energy based on these test results. An alternative formulation of the maturity model is suggested and compared with other similar concrete tests found in the literature for early-age strengths. The alternative model is shown to give better accuracy when modelling the early-age strengths of concrete. The tests include five different concretes, using three different cement types and the addition of fly ash.
摘要本文讨论了混凝土成熟度的建模问题。表观活化能是阿伦尼乌斯模型的主干,该模型通常用于模拟混凝土的成熟度。成熟度(或等效龄期)受养护温度的影响,在模拟混凝土的水化过程和硬化过程时,例如,为了预测早期强度,以确定拆除模板的时间或预应力的时间,成熟度(或等效龄期)被应用。本文的第1部分描述了成熟度模型的背景,以及作为DTI混凝土实验室大型测试程序的一部分所进行的测试。测试在测量抗压强度之前,在5°C至60°C的不同时间内应用等温固化温度。文章的第二部分基于这些测试结果给出了活化能的模型。提出了成熟度模型的替代公式,并与文献中发现的早期强度的其他类似具体测试进行了比较。在模拟混凝土早期强度时,替代模型显示出更好的准确性。试验包括五种不同的混凝土,使用三种不同的水泥类型,并添加了粉煤灰。
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引用次数: 0
Activation Energy for the Concrete Maturity Model – Part 1: Compressive Strength Tests at Different Curing Temperatures 混凝土成熟度模型的活化能。第1部分:不同养护温度下的抗压强度试验
IF 1 Q4 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2020-06-01 DOI: 10.2478/ncr-2020-0002
C. V. Nielsen, M. Kaasgaard
Abstract The article addresses the modelling of the maturity of concrete. The apparent activation energy is the backbone of the Arrhenius model, which is typically used to model the maturity of concrete. The maturity (or the equivalent age) is influenced by the curing temperature and it is applied when modelling the hydration process and the hardening of concrete for instance in order to forecast the early-age strength to determine the time for removal of formwork or the time for prestressing. Part 1 of the article describes the background for the maturity model and the test series carried out at the DTI concrete lab. Laboratory tests at different curing temperatures (from 5°C to 60°C) are presented and the compressive strength results are modelled according to the original Freiesleben Hansen and Pedersen maturity model that has been applied in the field for many years. The tests include five different concretes, using three different cement types and the addition of fly ash. There are significant differences especially when considering the later-age strength modelling at either low temperatures or at high temperature curing.
摘要本文讨论了混凝土成熟度的建模问题。表观活化能是阿伦尼乌斯模型的主干,该模型通常用于模拟混凝土的成熟度。成熟度(或等效龄期)受养护温度的影响,在模拟混凝土的水化过程和硬化过程时,例如,为了预测早期强度,以确定拆除模板的时间或预应力的时间,成熟度(或等效龄期)被应用。本文的第1部分描述了成熟度模型的背景和在DTI混凝土实验室进行的一系列测试。介绍了在不同养护温度(从5°C到60°C)下的实验室测试,并根据在该领域应用多年的原始Freiesleben Hansen和Pedersen成熟度模型对抗压强度结果进行了建模。试验包括五种不同的混凝土,使用三种不同的水泥类型,并添加了粉煤灰。特别是考虑低温和高温固化下的后期强度模型时,存在显著差异。
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引用次数: 4
Bonded Concrete Overlays: A Brief Discussion on Restrained Shrinkage Deformations and Their Prediction Models 粘结混凝土覆盖层:浅谈约束收缩变形及其预测模型
IF 1 Q4 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2019-12-01 DOI: 10.2478/ncr-2019-0019
Wojciech Cyron, M. Nilsson, M. Emborg, U. Ohlsson
Abstract Bonded concrete overlays (BCO) on bridge decks are beneficial solutions due to their superior properties as compared to the typical asphalt pavement. A significant number of overlays suffer however, from occurrence of cracks and delamination due to poor bond, and restrained shrinkage and thermal dilation. Over the past years different appraisals for estimation of the restrained deformations have been developed, from micro-scale models, based on poromechanics, to empirical equations as given in B3 or B4 models suggested by Bažant. This paper provides a short overview of calculation models along with a brief theoretical explanation of shrinkage mechanism.
摘要与典型的沥青路面相比,粘结混凝土覆盖层(BCO)在桥面上具有优越的性能,是一种有益的解决方案。然而,由于粘结不良、收缩和热膨胀受到抑制,大量覆盖层会出现裂纹和分层。在过去的几年里,对受约束变形的估计已经发展了不同的评价,从基于孔隙力学的微观尺度模型,到Bažant建议的B3或B4模型中给出的经验方程。本文简要介绍了各种计算模型,并对收缩机理作了简要的理论解释。
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引用次数: 2
期刊
Nordic Concrete Research
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