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OIL AND GAS POTENTIAL AND STUDY OF RESERVOIR PROPERTIES OF THE CRETACEOUS DEPOSITS OF THE YEVLAKH-AGDJABEDI DEPRESSION yevlakh-agdjabedi凹陷白垩系油气潜力及储层物性研究
IF 0.3 Pub Date : 2021-01-01 DOI: 10.17721/1728-2713.95.05
K. Mukhtarova, G. Nasibova, M. Ismayilova
The aim of the study is to substantiate the prospects for the oil and gas content of the Upper Cretaceous effusive and carbonate deposits by studying their reservoir parameters. Previous studies have established that a sedimentary complex, present in the geological structure of the Muradkhanly field, is lithologically represented by clays, siltstones, sands and sandstones, dolomites, limestones, tuffs, Upper Cretaceous porphyrites. Since this lithofacies composition of the section is of great importance as a reservoir rock, volcanic sandy tuffs, mudstones and dense sandstones of the Upper Cretaceous age have been comprehensively investigated throughout the territory. We studied carbonates of this age and found that they have compaction of varying extent and are divided into 3 groups: weakly, moderately and strongly compacted and this, in turn, has considerable effect upon the rock porosity. At the beginning of the study, the reservoir features of Meso-Cenozoic sediments in the Yevlakh-Agdjabedi depression [YAD] were studied mainly on the basis of terrigenous rocks that refer to the Cenozoic. In our studies, Cretaceous deposits were studied, which are represented by effusive, carbonate rocks with secondary reservoir properties. The reservoir properties of chalk deposits in the YAD areas were investigated on the basis of studies of core samples in laboratories. It was found that the reservoir rocks of the area under investigation are volcanic, volcanic-sedimentary and carbonate, that is, they mainly consist of fractured limestones, marls and dolomites. Studies have shown that the oil and gas content of the depression is associated mainly with carbonate and effusive reservoirs. To assess the prospects for the oil-bearing capacity of the YAD, geological sections were studied in terms of the reservoir properties of a number of structures, and on the basis of the obtained core samples data. Trend maps were compiled using the "Surfer" software. Analysis of the maps allows identifying the corresponding zones of carbonate content, permeability, porosity, characterized by high, medium and low values. According to the carbonate readings, the studied territory does not have a strict distribution pattern and, according to the permeability distribution data, it is divided into two zones: the northern zone with average and the southern one with low values. There is, to a certain extent, pattern for variation of the values of carbonate content and permeability, and this can be explained by the secondary transformation of the reservoir properties of carbonate rocks, as a result of which permeability and porosity changed. Porosity distribution, to some extent, is aligned with permeability. Inverse relationship between the values of porosity and permeability can be explained with the filling of voids with cement material in the rock formation environment. Currently, in order to continue exploration and drilling works, comprehensive geological and geophysical studie
研究的目的是通过对上白垩统喷涌沉积和碳酸盐岩沉积储层参数的研究,为其油气含量预测提供依据。先前的研究已经确定,Muradkhanly油田地质构造中存在一个沉积复合体,其岩性以粘土、粉砂岩、砂和砂岩、白云岩、灰岩、凝灰岩、上白垩统斑岩为代表。由于该剖面岩相组成作为储层具有重要意义,因此在全区对上白垩统火山砂凝灰岩、泥岩和致密砂岩进行了全面研究。对该时代碳酸盐岩进行了研究,发现它们具有不同程度的压实作用,可分为弱压实、中等压实和强压实3组,这对岩石孔隙度有相当大的影响。研究之初,叶夫拉克-阿格贾贝迪坳陷中-新生代沉积储层特征主要以新生代陆源岩为研究对象。本研究以白垩纪沉积为研究对象,以具有次生储层性质的碳酸盐岩为代表。在实验室岩心研究的基础上,对YAD地区白垩矿床的储层性质进行了研究。研究区储层岩性主要为火山、火山-沉积和碳酸盐岩,即以裂缝灰岩、泥灰岩和白云岩为主。研究表明,坳陷油气含量主要与碳酸盐岩和涌出型储层有关。为评价该区的含油前景,根据获得的岩心样品数据,对多个构造的储层性质进行了地质剖面研究。趋势图是用“Surfer”软件编制的。通过对这些图的分析,可以识别相应的碳酸盐岩含量、渗透率、孔隙度,并以高、中、低值为特征。根据碳酸盐岩读数,研究区域没有严格的分布模式,根据渗透率分布数据,将研究区域划分为北部平均值区和南部低值区。碳酸盐岩含量和渗透率值的变化具有一定的规律,这可以解释为碳酸盐岩储层物性的次生转化,从而导致了渗透率和孔隙度的变化。孔隙度的分布在一定程度上与渗透率一致。孔隙度与渗透率的反比关系可以用水泥材料在地层环境中充填空隙来解释。目前,为了继续进行勘探和钻探工作,正在进行全面的地质和地球物理研究,通过比较所获得的数据,将能够更详细地评价每个构造的前景。
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引用次数: 0
INTERPRETATION OF THE 3D GEOELECTRICAL MODEL OF THE STEPPE CRIMEA BOWELS. EUPATORIA AND SAKI PROFILES 克里米亚草原腹地三维地电模型的解释。尤帕托利亚和saki简介
IF 0.3 Pub Date : 2021-01-01 DOI: 10.17721/1728-2713.95.04
T. Burakhovich, A. Kushnir, V. Ilienko
The interpretation of the segment of the deep three-dimensional Crimean region geoelectrical model within the Saki and Yevpatoria profiles, built on the basis of the Earth's low-frequency electromagnetic field experimental observations, was obtained in 2012 by the INSTITUTE OF GEOPHYSICS named after S.I.Subbotin. The main result of the analysis is the identification of vertical and horizontal alternation of high and low resistivity, both in the earth's crust and in the upper mantle. It is shown that the geoelectrical sections along all the profile sections of the model are characterized by a dip to the north of the consolidated basement surface depth and, accordingly, an increase of the near-surface layer conductivity. The conductivity anomaly in the consolidated earth's crust was revealed in the depth interval of 5-10 km with resistivity (ρ) of 5 Ohmꞏm, galvanically connected with the sedimentary cover. Deeper than 10 km, homogeneous and inhomogeneous layers in ρ alternate: 10-60 km with ρ = 1000 Ohmꞏm; 60-90 km with ρ = 100 and 1000 Ohmꞏm; 90-110 km with ρ = 1000 Ohmꞏm; 110-140 km with ρ = 40 and 1000 Ohmꞏm, the contact corresponds to the different ρ of normal geoelectrical sections of different-aged structures of the Scythian plate and the East European platform; also horizontally layered normal section. It has been analyzed that earthquake sources of the Steppe Crimea seismic region are concentrated in geoelectrically inhomogeneous zones and tend to contact structures with ρ differ - above the upper margin, outside and between the conductivity anomalies in the consolidated rocks of the earth's crust. The considered material confidently indicates the confinement of hydrocarbon manifestations to the high electrical conductivity anomalies identified according to the data of geoelectromagnetical sounding and three-dimensional modeling, which are characterized by subvertical channels galvanically connected with sedimentary deposits, and layering in the earth's crust and upper mantle. Geoelectrical inhomogeneities, which reflect the current state of the earth's crust and upper mantle and are probably due to the influence of modern mantle fluids, correspond to manifestations of seismicity and hydrocarbon content.
Saki和Yevpatoria剖面内的克里米亚地区深层三维地电模型段的解释是基于地球低频电磁场实验观测,由以s.i.s ubotin命名的地球物理研究所于2012年获得的。分析的主要结果是确定了地壳和上地幔中高低电阻率的垂直和水平交替。结果表明:该模型所有剖面的地电剖面均表现为固结基底地表深度向北倾斜,近地表电导率随之增大。胶结地壳电导率异常在深度5 ~ 10 km,电阻率(ρ)为5 Ohmꞏm,与沉积盖层电偶联。深度大于10 km, ρ均质层和非均质层交替分布:10-60 km, ρ = 1000 Ohmꞏm;60-90 km ρ = 100和1000欧姆ꞏm;90-110 km ρ = 1000欧姆ꞏm;110 ~ 140 km, ρ = 40和1000 Ohmꞏm,接触对应于斯基泰板块和东欧地台不同年龄构造正电剖面的不同ρ值;也是水平分层的正常切片。分析了克里米亚草原震区的震源集中在地电不均匀带,并倾向于接触ρ值不同的构造——在地壳固结岩石的上缘之上、外部和电导率异常之间。根据地球电磁测深和三维模拟资料,确定了以亚垂直通道与沉积层电连接、地壳和上地幔分层为特征的高电导率异常是油气表现的主要制约因素。地电不均匀性反映了地壳和上地幔的现状,可能是受现代地幔流体的影响,与地震活动性和碳氢化合物含量的表现相对应。
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引用次数: 1
GEOLOGY OF GRAPHITE DEPOSITS OF UKRAINE AND PROSPECTS OF EXTRACTION IN MODERN CONDITIONS 乌克兰石墨矿床地质及现代条件下的开采前景
IF 0.3 Pub Date : 2021-01-01 DOI: 10.17721/1728-2713.94.08
G. Rudko
Extraction of graphite and its use in various spheres of production and technology play a significant role in the economies of many countries. Distinctive characteristics of graphite, which is one of the most common forms of carbon in nature (good electrical conductivity, low hardness, resistance to heat and aggressive environments), are widely used by scientists in various scientific developments. After British researchers of Russian origin from the University of Manchester Andre Geim and Konstantin Novoselov published an article about properties of the first studied two-dimensional graphene crystal in the journal Science in 2004, and numerous studies of properties of the new material, the demand for graphite ore has been increasing, and, according to some forecasts, it will amount to more than $ 400 million by 2026. Natural flake graphite can be used in new technologies, such as graphene, which is now used in various scientific experiments, as well as in the production of lithium-ion batteries, fuel cells, nuclear and solar power plants. Geological conditions of the Zavallivske graphite deposit, which is the main source of graphite in Ukraine, have been briefly presented in the paper, and perspectives of identified areas that can become an additional reserve of graphite ore have been outlined. Significant prognosis resources of graphite in new deposits, which have been recently discovered in Ukraine (Burtynske, Balakhivske, Sachkinsko-Troitske, a number of new sites within the Zavallia area), allow not only to maintain at the appropriate level, but also, if necessary, expand existing mineral raw material base, so Ukraine could become one of the world's largest suppliers of graphite products. Graphene has a great mechanical strength and a very high thermal conductivity. An extremely high mobility of electrons makes graphene a perspective material for the application in various fields, in particular, as a future basis for nanoelectronics and possible replacement of silicon in integrated circuits. Results on the application of unique properties of graphene have been presented.
石墨的提取及其在各种生产和技术领域的应用在许多国家的经济中发挥着重要作用。石墨是自然界中最常见的碳形式之一,其独特的特性(导电性好、硬度低、耐热和耐腐蚀性环境)被科学家广泛应用于各种科学发展中。2004年,来自英国曼彻斯特大学的俄罗斯研究人员安德烈·海姆和康斯坦丁·诺沃塞洛夫在《科学》杂志上发表了一篇关于第一个研究过的二维石墨烯晶体的性质的文章,以及对这种新材料性质的大量研究之后,对石墨矿的需求一直在增加,根据一些预测,到2026年,石墨矿的需求将超过4亿美元。天然鳞片石墨可用于新技术,如石墨烯,目前用于各种科学实验,以及锂离子电池、燃料电池、核能和太阳能发电厂的生产。本文简要介绍了Zavallivske石墨矿床的地质条件,这是乌克兰石墨的主要来源,并概述了可成为石墨矿额外储量的已确定区域的前景。最近在乌克兰新发现的石墨矿床(Burtynske, Balakhivske, Sachkinsko-Troitske, Zavallia地区的一些新地点)中有重要的预测资源,不仅可以保持在适当的水平,而且在必要时还可以扩大现有的矿物原料基础,因此乌克兰可以成为世界上最大的石墨产品供应商之一。石墨烯具有很高的机械强度和非常高的导热性。极高的电子迁移率使石墨烯成为应用于各个领域的前景材料,特别是作为纳米电子学的未来基础和集成电路中硅的可能替代品。介绍了石墨烯独特性能的应用结果。
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引用次数: 0
IMPACT OF COMPRESSIONAL STRESSES WITHIN THE SOUTH CASPIAN MEGADEPRESSION UPON EVOLUTION AND OIL AND GAS CONTENT OF LOCAL UPLIFTS 南里海特大坳陷内挤压应力对局部隆升演化及油气含量的影响
IF 0.3 Pub Date : 2021-01-01 DOI: 10.17721/1728-2713.94.09
V. Gurbanov, N. Narimanov, G. Nasibov
The following structural elements in the South Caspian megadepression (SCMD) have been considered: the interfluve of the Kura and Gabirri, the Absheron and Baku archipelagoes, the Lower Kur depression (LKD) and the Godin massif, that stand out geodynamically, from point of view of structural and tectonic evolution and oil and gas content. To solve this problem, the geodynamic environment of the SCMD has been analyzed based on the geodynamic chart of the Central segment of the Mediterranean folding belt compiled by the author, as well as the orientation chart of compressional stresses in the SCD and the methodology, developed for the first time ever, for their qualitative assessment within the structural elements by means of compiling isomorphic maps. The latter make it possible to determine the intensity and nature of the propagation of compressional stresses, the specifics of their impact on folding, oil and gas generation and formation of hydrocarbon accumulations. The Kur-Gabirri interfluve is situated in the west of the SCMD between the closely located Greater and Lesser Caucasian collisions. It is characterized by oil and gas bearing and potential sublatitudinally oriented linear folds, complicated by faulting and mud volcanism. The values of isolines of the isomorphic map and their density are indicative of high intensity of the north-west oriented compressional stresses here. The Absheron archipelago is a western element of the Absheron-Balkhan residual subduction. According to the isomorphic map with a dense network of isolines of sublatitudinal orientation, the archipelago is complicated by linear folding, as well as thrusts, transverse strike-slip faults, mud volcanism, oil and gas content, and oil and gas manifestations indicating the build-up of intense compressional stresses here. Evolution of folds within the Baku archipelago and the Lower Kur depression took place under the stresses of longitudinal and transverse bending. The faintly pronounced linearity of the compressional stresses is apparently associated with the formation of the Western Board of the SCD in the form of a regional submeridianal uplift. It developed under the impact of compressional stresses arising from the effect of the northeastern projection of the Arabian plate on the Iranian one. LKD is an onshore extension of the Baku archipelago. Its anticline zones, regional faults, mud volcanism and oil and gas content continue in the latter. The Godin Massif is the easternmost structural element of those considered with a faintly pronounced reflected folding of unknown prospects. Isolines of the isomorphic map are not directly associated with local uplifts, which is indicative of the absence of clearly pronounced compressional stresses here. The analysis made it possible to determine the degree of development of compressional stresses, their impact upon formation of the sedimentary section, folding, mud volcanism and oil and gas content of the considered
从构造和构造演化以及油气含量的角度来看,南里海大坳陷(SCMD)的以下构造要素已被考虑:库拉和加比尔里的穿插、阿布歇隆和巴库群岛、下库尔坳陷(LKD)和戈丁地块。为解决这一问题,本文根据笔者编制的地中海褶皱带中段地球动力学图和首次发展的地中海褶皱带挤压应力方位图,以及编制同构图对构造要素内挤压应力进行定性评价的方法,对地中海褶皱带的地球动力学环境进行了分析。后者可以确定挤压应力传播的强度和性质,以及它们对褶皱、油气生成和油气聚集形成的具体影响。Kur-Gabirri断裂带位于SCMD西部,位于大高加索碰撞和小高加索碰撞之间。其主要特征是含油气和潜在的次纬度定向线状褶皱,并受断裂和泥火山作用的影响。同构图等值线的值及其密度反映了该区西北向的高强度挤压应力。阿布歇隆群岛是阿布歇隆-巴尔汗残余俯冲带的西部部分。根据具有密集的次垂直方向等值线网络的同构图,列岛具有复杂的线性褶皱,以及逆冲、横向走滑断层、泥火山作用、油气含量和油气表现,表明这里存在强烈的挤压应力。巴库群岛和下库尔坳陷内部褶皱的演化是在纵向和横向弯曲应力作用下发生的。压应力的微弱线性明显地与SCD西部板块以区域淹没隆起的形式形成有关。它是在阿拉伯板块向东北投射对伊朗板块产生的挤压应力的影响下发展起来的。LKD是巴库群岛的陆上延伸。后者继续存在背斜带、区域断裂、泥火山作用和油气含量。戈丁地块是最东端的构造元素,被认为具有隐约明显的未知前景的反射折叠。同构图的等值线与局部隆起没有直接联系,这表明这里没有明显的挤压应力。通过分析,可以确定挤压应力的发育程度,以及它们对沉积剖面、褶皱、泥火山作用和所考虑的构造元素的油气含量的影响。
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引用次数: 1
SCHLICH MINERALOGICAL ANALYSIS FOR RESEARCH OF MODERN BOTTOM SEDIMENTS 现代海底沉积物研究中的Schlich矿物学分析
IF 0.3 Pub Date : 2021-01-01 DOI: 10.17721/1728-2713.93.03
V. Ivanchenko, L. Berozkina, V. Stetsenko, L. Kovalchuk
Gold and other heavy minerals often form scaly, leafy, needle-like or split crystals, dendrites of complex shape, individuals and aggregates with a large number of internal cavities. Significant mobility of these particles in water and air streams causes their separation from the psammitic component of sediment and deposition together with clay minerals. During preparatory stages for mineralogical analysis, such crystals of heavy minerals fall into slime part. According to classical algorithm of schlich mineralogical analysis slime part is thrown away. So it leads to losses of rich minerals and an incorrect analysis. The main purpose of the article is to present the new algorithm for the preparation of the bottom sediments samples for the mineralogical analysis and to demonstrate practical benefits of it. Authors propose the meliorated methods of mineralogical analysis considering comprehensive study of test material. The real natural composition of ore minerals in the sediments consists of adding the data "heavy concentrate-1" and "heavy concentrate-2". This provides an increase in industrial value of minerals by 10-30%, compared with the methods of prospecting that operate today. Such detailed analysis showed that modern bottom sediments include both natural components and man-made materials (plastic, polyethylene, synthetic fibers and fabrics, fuel, various types of petroleum products, metallurgical and household waste). Mineralogical analysis can be used as an ecological method for assessing the environmental pollution and reviewing the types of pollutants. The estimation of mineral reserves according to new methodology opens opportunities for profitable field development of poor polymetallic deposits. The study of bottom sediments by such a method indicates the need to clean hydrogeoecosystems and stimulates the development of new recycling methods in the economy and the waste-free production, for example, cleaning beaches from heavy metals and waste, complex sludge processing after dredging works in riverbeds, berths and port waters.
金等重矿物常形成鳞片状、叶状、针状或裂状晶体、形状复杂的树突、具有大量内腔的个体和集合体。这些颗粒在水和气流中的显著流动性导致它们与沉积物的沙质成分分离,并与粘土矿物一起沉积。在矿物学分析的准备阶段,这类重矿物晶体落入泥态。根据经典的施里希矿物学分析算法,将矿泥部分丢弃。因此,它会导致丰富矿物质的损失和错误的分析。本文的主要目的是提出一种制备用于矿物学分析的海底沉积物样品的新算法,并论证其实际效益。提出了综合研究试验材料的矿物学分析改进方法。沉积物中矿石矿物的真实自然组成是“重精矿-1”和“重精矿-2”数据的相加。与目前使用的勘探方法相比,这种方法使矿物的工业价值增加了10-30%。这种详细的分析表明,现代海底沉积物既包括天然成分,也包括人造材料(塑料、聚乙烯、合成纤维和织物、燃料、各种石油产品、冶金和家庭废物)。矿物学分析可以作为一种评价环境污染和审查污染物类型的生态学方法。根据新方法估计矿产储量为贫多金属矿床的有利可图的油田开发提供了机会。用这种方法对底部沉积物的研究表明,需要清洁水文地质生态系统,并刺激经济和无废物生产中新的回收方法的发展,例如,清除海滩上的重金属和废物,在河床、泊位和港口水域进行疏浚工程后处理复杂的污泥。
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引用次数: 0
THEORETICAL PRINCIPLES OF SAVING GROUNDWATER USE INFOGEOFRAMES IN HYDROGEOLOGY 水文地质学中节约地下水利用信息框架的理论原理
IF 0.3 Pub Date : 2021-01-01 DOI: 10.17721/1728-2713.94.14
O. Shevchenko, D. Khrushchov
Theoretical bases of information support of geological prospecting researches and works on use and protection of underground waters are considered. The methodology of information support is based on the principles of target infogeological structuring of the geological environment on the basis of traditional methods of formational analysis taking into account hydrogeological (hydrodynamic and hydrochemical) components. Prospects for the introduction of a system of frame organization of the geological environment in infogeological modeling are discussed. In the applied sense, research focuses on that part of the underground hydrosphere that is now or in the future able to meet the needs of mankind in drinking, mineral, technical, industrial, thermal waters. The principles of management of groundwater resources based on the ratio of renewable natural (dynamic resources, which make up the majority of open hydrodynamic systems in the zone of intensive water exchange), renewable manmade (artificial or disturbed resources) and non-renewable components (capacitive reserves and semi-closed structures). Accordingly, during the operation of deposits, not only the calculated value of the allowable level reduction but also the "allowable balance" of groundwater should be observed. It is also proposed to define and agree on the boundaries of deposits and boundary conditions. The latter should be responsible not only for the water intake production, but also to demonstrate the degree of hydrodynamic, hydrochemical, geological protection and the risk of quantitative and qualitative depletion. Groundwater extraction must be balanced by restoring their reserves, which can be achieved by combined alternate water use of surface and groundwater sources, the creation of infiltration basins and more. On this conceptual basis, a system of information support for research and work on the use and protection of groundwater is proposed, which in the long run should be as close as possible to world standards.
探讨了地勘工作和地下水利用与保护工作信息支持的理论依据。信息支持方法是在传统地层分析方法的基础上,考虑水文地质(水动力和水化学)成分,建立地质环境目标信息地质构造原理。讨论了在信息地质建模中引入地质环境框架组织体系的前景。在应用意义上,研究的重点是现在或将来能够满足人类饮用、矿物、技术、工业和温泉水需求的地下水圈部分。地下水资源管理的原则是基于可再生自然资源(动态资源,它构成了密集水交换区开放水动力系统的大部分)、可再生人造资源(人工或干扰资源)和不可再生成分(电容储量和半封闭结构)的比例。因此,在水库运行过程中,不仅要遵守允许水位下降的计算值,还要遵守地下水的“允许平衡”。此外,还建议对矿床边界和边界条件进行界定和统一。后者不仅要负责取水生产,而且要证明水动力、水化学、地质保护的程度以及定量和定性枯竭的风险。地下水的开采必须通过恢复其储量来平衡,这可以通过地表水和地下水资源的交替使用、建立渗透盆地等方法来实现。在这一概念的基础上,建议建立一个资料支助系统,用于地下水的使用和保护的研究和工作,从长远来看,该系统应尽可能接近世界标准。
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引用次数: 0
THE DETERMINATION OF SOURCE MECHANISMS OF SMALL EARTHQUAKES BY MOMENT TENSOR INVERSION 矩张量反演确定小震震源机制
IF 0.3 Pub Date : 2021-01-01 DOI: 10.17721/1728-2713.92.15
D. Malytskyy, D. Mikesell
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引用次数: 1
NANOSTRUCTURES IN THE SURFACE LAYERS OF COAL MATTER 煤物质表层的纳米结构
IF 0.3 Pub Date : 2021-01-01 DOI: 10.17721/1728-2713.95.07
V. Portnov, V. Yurov, N. Reva, A. Mausymbaeva, S. Imanbaeva
According to modern concepts, the surface layer of compounds is understood as the ultrathin cover, the properties, structure and composition are different from the crystalline substrate with this layer and this layer is in thermodynamic equilibrium. The surface layer consists of two layers - d(I) with thickness h = d, at which the phase transition occurs, and d(II) with the lower limit h≈10d, at which the physical properties of the crystal begin to manifest themselves. The thickness of the surface layer d(I) is determined by one fundamental parameter, the molar (atomic) volume of the element (Ʊ= M/ρ, M is molar mass (g/mol), ρ is density (g/cm3)). The average statistical structural unit of coal corresponds to higher fullerenes with the number of carbon atoms in the cluster >100, which is the unique feature of the coal substance, which is not a crystalline structure, but a complex polymer with a supramolecular structure. The thickness of the surface layer of the coal substance is two orders of magnitude greater than the thickness of pure metals and is close to the thickness of the surface layer of higher fullerenes C96 (135 nm). The increasing of the coal substance's porosity of 90 % is led to increasing the thickness d(I) of the surface layer by the order of magnitude, that is 2 microns. In this regard, the "apparent" change in the radius of a coal particle means a change in its mass, proportional to the release of methane from the solid solution. The dependence of the complete decomposition's time of coal methane is τ0 on the parameter |λ|. The equation which is obtained, includes the ratio of the heat flux introduced into the reservoir volume due to the internal heat release process to the heat flux which is carried away from the volume due to thermal conductivity. If this ratio exceeds a certain critical value of the unity's order, the thermal explosion occurs, leading to the decomposition of coal methane. The size effects in the d(I) layer are determined by the entire group of atoms in the system (collective processes). Such "quasi-classical" size effects are observed only in nanoparticles and nanostructures. The d(I) layer for coal matter extends from 151.5 nm (Anthracite) to 214.2 nm (Brown). The dimensional temperature of the carbon nanoparticle at the initial temperature T0 = 300 K will be at least Tm = 872 K. This corresponds to particles of the order of half a micron. Coal particles with the radius of about one micron (or marked half a micron) in the case of decomposition of coal matter are heated to temperatures at which spontaneous combustion of nanoparticles is possible. Hygroscopic moisture in the genetic line of coal has the certain pattern of change and correlates with the thickness of their surface layer.
根据现代概念,化合物的表面层被理解为超薄的覆盖层,其性质、结构和组成与晶体基底不同,该层处于热力学平衡状态。表面层由两层组成,厚度为h = d的d(I)层发生相变,下限为h≈10d的d(II)层开始体现晶体的物理性质。表面层的厚度d(I)由一个基本参数决定,即元素的摩尔(原子)体积(Ʊ= M/ρ, M是摩尔质量(g/mol), ρ是密度(g/cm3))。煤的平均统计结构单元对应于团簇中碳原子数>100的更高的富勒烯,这是煤物质的独特特征,它不是晶体结构,而是具有超分子结构的复杂聚合物。煤物质的表面层厚度比纯金属的厚度大两个数量级,接近于高富勒烯C96的表面层厚度(135 nm)。煤质孔隙率增加90%,导致表层厚度d(I)增加了一个数量级,即2 μ m。在这方面,煤颗粒半径的“表观”变化意味着其质量的变化,与固溶体中甲烷的释放成正比。煤甲烷的完全分解时间τ0与参数|λ|有关。所得到的方程包括由于内部放热过程引入储层体积的热流通量与由于导热性而从体积带走的热流通量之比。如果该比值超过某一单位阶的临界值,就会发生热爆炸,导致煤层气分解。d(I)层的尺寸效应是由系统中的整个原子群(集体过程)决定的。这种“准经典”尺寸效应只在纳米粒子和纳米结构中观察到。煤的d(I)层从151.5 nm(无烟煤)延伸到214.2 nm(褐煤)。在初始温度T0 = 300 K时,纳米碳颗粒的尺寸温度至少为Tm = 872 K。这相当于半微米量级的粒子。在煤质分解的情况下,半径约为1微米(或标记为半微米)的煤颗粒被加热到纳米颗粒可能自燃的温度。煤的成因线吸湿性含水率有一定的变化规律,并与煤的表层厚度有关。
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引用次数: 1
ECOLOGICAL AND ECONOMIC EFFICIENCY OF THE PEAT SORBENTS USAGE FOR SOLVING ENVIRONMENTAL PROBLEMS 泥炭吸附剂解决环境问题的生态经济效益
IF 0.3 Pub Date : 2021-01-01 DOI: 10.17721/1728-2713.92.14
E. Yaroshovets, E. Remezova
It is known that currently the content of organic and inorganic toxic impurities in natural objects is several times higher than the maximum allowable concentration, resulting in increased recreational load. The article is devoted to the topical ecological problem of water and soil pollution by emergency oil spills and oil products. Contaminated water has a negative effect on humans, aquatic life, plants, microorganisms and adjacent areas. Peculiarities of oil pollution of aquatic ecosystems are given and methods of water treatment by use of sorbents are considered. One of the most promising and effective methods of water purification - sorption, using vegetable raw materials, peat - is considered and analyzed. The effectiveness of such sorbents in the elimination of oil pollution has been established. The problem of cleaning water bodies, replacing scarce and expensive filters from synthetic and other materials with cheaper and more available from local raw materials are now becoming particularly acute and relevant. It should be noted that obtaining these sorbents is expedient in environmental and economic terms due to the low cost of materials, easiness of production, high sorption properties, the possibility of recycling. The economic possibility of Manevychi district for the development of peat raw materials for further placement of the enterprise for the production of peat sorbents is analyzed. Information on general technical properties of peat of Koza-Berezina deposit in Manevychi district of Volyn region is analyzed. The article considers the ecological and economic feasibility and proposes the use of peat in the region in the production of oil sorbents.
据了解,目前自然物中有机和无机有毒杂质的含量比最大允许浓度高出数倍,造成游憩负荷增加。这篇文章专门讨论了由紧急石油泄漏和石油产品引起的水和土壤污染的生态问题。受污染的水对人类、水生生物、植物、微生物和邻近地区都有负面影响。给出了水生生态系统油类污染的特点,探讨了利用吸附剂进行水处理的方法。对以泥炭为原料的植物吸附法进行了研究和分析。这类吸附剂在消除石油污染方面的有效性已得到证实。清洁水体、用更便宜和更容易获得的当地原材料取代稀有和昂贵的合成材料和其他材料过滤器的问题现在变得特别尖锐和重要。值得注意的是,获得这些吸附剂在环境和经济方面是有利的,因为材料成本低,易于生产,高吸附性能,可回收利用。分析了马尼维奇地区发展泥炭原料的经济可能性,并对泥炭吸附剂生产企业的进一步布局进行了分析。分析了沃林地区马内维奇地区科扎-别列济纳矿床泥炭的一般技术性质。本文考虑了生态和经济的可行性,提出了在该地区利用泥炭生产吸油剂。
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引用次数: 2
CHARACTERISTICS OF HYDROGEOLOGICAL MASSIVES OF THE GREATER, LITTLE CAUCASUS AND TALYSH (AZERBAIJAN) TAKING INTO ACCOUNT GLOBAL CLIMATE CHANGE 考虑到全球气候变化的大高加索、小高加索和塔里什(阿塞拜疆)水文地质块体特征
IF 0.3 Pub Date : 2021-01-01 DOI: 10.17721/1728-2713.94.12
I. Tagiyev, V. Kerimov, J. Sherifov
Issues of global warming lead to dramatic changes in hydrological and hydrogeological conditions. The Caspian Sea and mountain ranges have a great influence on the formation of the climate. Many believed that climate models and predictions are probabilistic in nature, but some will think that global climate change is important today. It is necessary to take into account that climate change is global, it occurs everywhere on our planet and affects every state and every person. Purpose: Clarification of the influence of the relief and the proximity of the Caspian Sea which determines the differences and distribution of air temperature, precipitation and other climate elements. The annual amount of precipitation falls in the cold half of the year in the form of snow, the melting of which causes violent spring floods on the rivers, evaporation and sufficient relative moisture. The characteristics of climatic zones show their close relationship with the nature of the relief and with the hypsometric position of the terrain above sea level. Ground waters within the Greater, Lesser Caucasus and Talysh are distributed everywhere. In the Greater Caucasus, there are mainly distributed gravels of the Kusar Formation (QIV), and within the Khvalynskaya, Khazar, Bakinskaya and Kusarskaya formations, clay interlayers divide the general flow of groundwater into several horizons of pressure water, the same pattern also takes place in the Lesser Caucasus and Talysh. Climate change, the nature of precipitation distribution, the growing season of plants, pH-pH, an increase in the average global temperature causing various side effects, the frequency of extreme weather events, a rise or decrease in the water level, ultimately all this affects all elements of the hydrological river systems and calculated industrial reserves of groundwater. Deforestation contributes to global warming and one of the main reasons for the intensification of the greenhouse effect, negatively affects the water cycle, the transpiration process stops. We should participate in the process of reducing CO2 emissions, pay attention to the increase of forest areas, reduction of water pollution, transfer to unconventional renewable solar and wind power, accelerate the introduction of alternative energy deposits of thermal waters.
全球变暖的问题导致了水文和水文地质条件的剧烈变化。里海和山脉对气候的形成有很大的影响。许多人认为气候模型和预测本质上是概率性的,但有些人会认为全球气候变化在今天很重要。有必要考虑到气候变化是全球性的,它发生在我们星球上的任何地方,影响到每个州和每个人。目的:澄清里海的地形和邻近程度的影响,里海决定了气温、降水和其他气候要素的差异和分布。一年的降水量在寒冷的半年以雪的形式出现,雪的融化会引起河流的猛烈的春季洪水,蒸发和充足的相对湿度。气候带的特征与地形的性质和海拔高度的高低密切相关。大高加索、小高加索和塔利什地区的地下水分布在各地。在大高加索地区,主要分布有Kusar组砾石,在Khvalynskaya组、Khazar组、Bakinskaya组和Kusarskaya组内,粘土夹层将一般的地下水流划分为几个层位的压力水,在小高加索地区和Talysh地区也发生了同样的模式。气候变化、降水分布的性质、植物的生长季节、pH-pH值、全球平均气温的上升造成的各种副作用、极端天气事件的频率、水位的上升或下降,最终所有这些都会影响水文河流系统的所有要素和地下水的计算工业储量。森林砍伐是造成全球变暖和温室效应加剧的主要原因之一,对水循环产生负面影响,使蒸腾过程停止。我们应该参与减少二氧化碳排放的过程,关注森林面积的增加,减少水污染,向非常规的可再生太阳能和风能转移,加快引进替代能源矿床的热水。
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引用次数: 0
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Visnyk of Taras Shevchenko National University of Kyiv-Geology
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