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2013 IEEE International Conference on Solid Dielectrics (ICSD)最新文献

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Effects of low temperature on treeing phenomena of silicone rubber 低温对硅橡胶树形现象的影响
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619910
T. Han, B. Du, Jingang Su, Yu Gao, Zongle Ma
In this paper, room temperature vulcanized (RTV) silicone rubber (SiR) was employed as test sample to investigate the relationship between electrical tree propagation characteristics and the low experiment temperature. Power frequency voltage was applied on the SiR specimens through the needle-plate electrode with the same radius of needle tips to initiate the electrical tree at different low experiment temperatures. Both the structures and growth characteristics of electrical tree in SiR were observed by using a digital camera and a microscope system. Obtained results show that electrical tree in RTV SiR is white gap tree channel which maybe composed of silicone compounds instead of carbonized channel in XLPE. Electrical tree in SiR all initiate from single branch, and the width of initiative single branch channel varies a lot with the electrical tree structure. The structure of at experiment temperature from 0 °C to -70 °C in RTV SiR can be classified into three categories, which are branch, bush and pine branch tree. The distribution of tree structures changes with the experiment temperature. At the temperature of -70 °C, pine branch tree take up a great proportion, however, bush tree becomes the dominant structure when the temperature rise up to -50 °C and -30 °C. All kinds of electrical tree grow rapidly in the first beginning of the treeing propagation, and this process lasts only a few minutes.
本文以室温硫化(RTV)硅橡胶(SiR)为试验材料,研究了电树繁殖特性与低温的关系。通过针尖半径相同的针板电极对SiR试件施加工频电压,在不同低温下启动电树。利用数码相机和显微镜系统对树的结构和生长特性进行了观察。结果表明,RTV SiR中的电树是由硅酮化合物组成的白间隙树通道,而不是XLPE中的碳化通道。SiR中的电树都是从单个分支发起的,并且随着电树结构的不同,发起的单个分支通道的宽度变化很大。RTV SiR在0℃~ -70℃实验温度下的结构可分为枝状、灌木状和松枝状三种。树形结构的分布随实验温度的变化而变化。在-70℃时,以松枝树为主,而在-50℃和-30℃时,以灌木树为主。各种电树在树形繁殖初期生长迅速,这一过程仅持续几分钟。
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引用次数: 7
Effects of direct fluorination on surface charge of polyimide/Al2O3 nanocomposite films 直接氟化对聚酰亚胺/Al2O3纳米复合膜表面电荷的影响
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619754
W. Du, B. Du, Jie Li, H. Du, Yu Gao, Kai Zhang
With advantage of excellent thermostability, mechanical property, polyimide films have been widely used in the aerial, nuclear, microelectronic industry. However, The dielectric breakdown of the polyimide films caused by surface charge often occurs and becomes one of main problems to the safety and reliability of insulation system. Addition of nanoparticles into polyimide films can improve the insulating properties compared with undoped material. Fluorination as the change of the chemical component in surface layer of polymers should give rise to the corresponding change in electrical properties of the surface layer thus influence the charge injection from electrodes when they are used as an insulator. In this paper, the study aimed at clarifying the effect of nanoparticles and fluorination on the surface charge accumulation and decay behaviors of polyimide films have been carried out. Polyimide/Al2O3 nanocomposite films were prepared with the weight percent of 0, 1, 3, 5, 7 wt% respectively. Samples were surface fluorinated in a laboratory vessel at about 328K (55 °C) using a F2/N2 mixture with 20% F2 by volume and 0.05 MPa (500 mbar) for 30 minutes. Corona charging tests were performed at room temperature with a relative humidity of ~ 40%. The charge distribution was measured by means of an electrostatic voltmeter. Obtained results show the dependence of the charge density as well as the charge decay rate upon the nanoparticle content and the fluorination, varying as a function of the charging time. It is suggested that the nanoparticles and the fluorination can significantly affect the decay rate of the surface charge in polyimide nanocomposite films.
聚酰亚胺薄膜具有优异的热稳定性和力学性能,广泛应用于航空、核、微电子等工业领域。然而,由于表面电荷引起的聚酰亚胺薄膜的介电击穿现象经常发生,成为影响绝缘系统安全可靠性的主要问题之一。与未掺杂的材料相比,在聚酰亚胺薄膜中加入纳米粒子可以改善其绝缘性能。氟化作为聚合物表面层化学成分的变化,应引起表面层电学性质的相应变化,从而影响电极作为绝缘体时从电极注入的电荷。本文旨在阐明纳米粒子和氟化对聚酰亚胺薄膜表面电荷积累和衰减行为的影响。制备了质量分数分别为0、1、3、5、7 wt%的聚酰亚胺/氧化铝纳米复合膜。样品在实验室容器中表面氟化,温度约为328K(55°C),使用F2/N2混合物,体积为20% F2, 0.05 MPa (500 mbar), 30分钟。电晕充电试验在室温下进行,相对湿度为~ 40%。电荷分布是用静电伏特计测量的。得到的结果表明,电荷密度和电荷衰减率与纳米颗粒含量和氟化程度有关,并随充电时间而变化。结果表明,纳米粒子和氟化对聚酰亚胺纳米复合膜表面电荷的衰减速率有显著影响。
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引用次数: 1
Preparation of core-shell structured polystyrene/BaTiO3 nanoparticles via in situ RAFT polymerization for high-performance dielectric nanocomposites 采用原位RAFT聚合法制备核壳结构聚苯乙烯/BaTiO3纳米颗粒高性能介电纳米复合材料
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619763
Ke Yang, Xingyi Huang, Fei Liu, P. Jiang
The incorporation of high-dielectric-constant ceramic nano-filler into polymer matrix is an important approach to prepare polymer composites with excellent dielectric performance. However, the easy aggregation of inorganic nano-filler generally not only results in poor film quality and inhomogeneities, but also affects the dielectric performance. Herein, a novel route to prepare core-shell structured nanocomposites with excellent dielectric performance is reported. The promising approach using in situ RAFT polymerization to graft polystyrene (PS) from the BaTiO3 surface, and the insulating polymer shells not only act as interlayers to prevent the agglomeration of the nanoparticles, but also act as the matrix. The PS shell thickness could be well controlled by adjusting the feed ratio of styrene to BaTiO3. The dielectric performance of the PS@BaTiO3 nanocomposites is studied by broadband dielectric spectroscopy from 1 Hz to 1 MHz at room temperature. The dielectric constant of the nanocomposites is significantly enhanced (more than 7.9 times) as the BaTiO3 content increasing and the dielectric loss is maintained in a relatively low level (<; 0.015). Moreover, the dielectric constant of such nanocomposites has weak frequency dependence in a very wide frequency range.
在聚合物基体中掺入高介电常数的纳米陶瓷填料是制备具有优异介电性能的聚合物复合材料的重要途径。然而,无机纳米填料容易聚集,不仅会导致薄膜质量差和不均匀性,而且会影响介电性能。本文报道了一种制备具有优异介电性能的核壳结构纳米复合材料的新方法。利用原位RAFT聚合在BaTiO3表面接枝聚苯乙烯(PS)是一种很有前景的方法,其绝缘聚合物外壳不仅可以作为防止纳米颗粒团聚的中间层,还可以作为基体。通过调整苯乙烯与BaTiO3的投料比,可以很好地控制PS的壳厚。利用1 Hz ~ 1 MHz的宽带介电光谱研究了PS@BaTiO3纳米复合材料在室温下的介电性能。随着BaTiO3含量的增加,纳米复合材料的介电常数显著提高(超过7.9倍),介电损耗维持在较低的水平(<;0.015)。此外,这种纳米复合材料的介电常数在很宽的频率范围内具有较弱的频率依赖性。
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引用次数: 1
Fast charge pulses: The evidence and its interpretation 快电荷脉冲:证据及其解释
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619736
G. Montanari, D. Fabiani, L. Dissado
Cross-linked polyethylene and flexible epoxy resin samples have shown a conduction mechanism, never observed before, consisting of repeated ultra-fast charge pulses travelling across insulation with much higher mobility those of traditional charge carriers. This phenomenon seems to be governed by mechanical relaxation of polymer chains. Indeed, materials mechanically rigid, such as e.g. glassy epoxy, do not exhibit this behavior, unless addition of nanoadditives can increase partially the material flexibility, thereby allowing charge pulses to be incepted. Moreover, it was observed that the application of an external mechanical force can influence significantly fast charge pulse features. This would demonstrate that such a conduction mechanism is not governed by traps, but it is driven by the contribution of polarization and the resultant electromechanical compression. This is able to generate solitons, in the form of charge pulses, whose amplitude, mobility and repetition rate are influenced by the mechanical properties of the polymer.
交联聚乙烯和柔性环氧树脂样品显示了一种以前从未观察到的传导机制,由重复的超快电荷脉冲组成,这些脉冲以比传统电荷载流子高得多的迁移率穿过绝缘。这种现象似乎是由聚合物链的机械松弛所控制的。事实上,机械刚性的材料,如玻璃环氧树脂,不会表现出这种行为,除非添加纳米添加剂可以部分增加材料的柔韧性,从而允许电荷脉冲被接收。此外,观察到外部机械力的应用可以显著影响快充脉冲特性。这将证明这种传导机制不是由陷阱控制的,而是由极化和由此产生的机电压缩的贡献驱动的。这能够产生电荷脉冲形式的孤子,其振幅、迁移率和重复率受到聚合物机械性能的影响。
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引用次数: 10
Flashover of composite insulators induced by bird excretion 鸟类排泄物引起复合绝缘子的闪络
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619781
Huafeng Su, Z. Jia, Z. Guan
This paper simulates a.c. 110 kV and 220 kV composite insulator flashover induced by bird excretion. It finds that contaminated wet composite insulators are more likely to suffer from bird excretion flashovers than dry clean ones. Wet contaminated composite insulator flashover induced by bird excretion is the combination of arcing along the insulator surface and the breakdown along the dry arc distance. Meanwhile, dry clean composite insulator flashover induced by bird excretion is usually only the result of air breakdown along the dry arc distance. The maximum value of the distance between the bird excretion falling passage and contaminated wet insulator shed to induce flashovers is higher than that of a dry clean one. Some of the unexplained flashovers may actually be induced by bird excretion.
本文模拟了交流110 kV和220 kV鸟类排泄物引起的复合绝缘子闪络。研究发现,受污染的湿复合绝缘体比干燥的干净绝缘体更容易受到鸟类排泄物的影响。鸟类排泄物引起的湿污复合绝缘子闪络是沿绝缘子表面起弧和沿干弧距离击穿的结合。同时,鸟类排泄物引起的干净复合绝缘子闪络通常只是沿干弧距离空气击穿的结果。鸟粪跌落通道与受污染的湿绝缘子棚架之间引起闪络的距离最大值高于干燥洁净的绝缘子棚架。一些无法解释的闪厥实际上可能是由鸟类排泄物引起的。
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引用次数: 3
Effect of surface fluorination on space charge behavior at LDPE/EPDM interface 表面氟化对LDPE/EPDM界面空间电荷行为的影响
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619657
L. Lan, Q. Zhong, Y. Yin, Xuguang Li
Joints and terminations in polymer insulated HVDC cable system have been identified as weak points with much higher failure probability than the cable itself. This is mainly due to space charge accumulation at interfaces between different insulating materials. According to the Maxwell-Wagner-Sillars polarization theory, the accumulation of interfacial charge depends on conductivity and permittivity mismatch. Fluorination had been reported as a surface modification method of polymer dielectrics, which may lead to remarkable increase in permittivity and conductivity, thus could be a possible way to reduce space charge at the insulation interface of cable and its accessory. This paper presents the results of pulsed electro-acoustic (PEA) measurement of space charge distribution in LDPE/EPDM double-layer sample subjected to a DC field. Original and fluorinated LDPE layer were both used to study the effect of surface fluorination on space charge behavior at LDPE/EPDM interface. The results show that a significant amount of space charge accumulated at the interface of the original-LDPE/EPDM sample. And the property of the interfacial charge changed a lot after the LDPE layer is surface fluorinated.
聚合物绝缘高压直流电缆系统的接头和终端是其薄弱环节,其失效概率比电缆本身高得多。这主要是由于不同的绝缘材料之间的界面空间电荷积累。根据Maxwell-Wagner-Sillars极化理论,界面电荷的积累取决于电导率和介电常数的失配。氟化是聚合物电介质表面改性的一种方法,可显著提高其介电常数和电导率,是降低电缆及其附件绝缘界面空间电荷的一种可能方法。本文介绍了脉冲电声(PEA)测量直流电场作用下LDPE/EPDM双层样品中空间电荷分布的结果。采用原始LDPE层和氟化LDPE层,研究了表面氟化对LDPE/EPDM界面空间电荷行为的影响。结果表明,在原始ldpe /EPDM样品的界面处积累了大量的空间电荷。对LDPE层进行表面氟化处理后,界面电荷的性质发生了很大的变化。
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引用次数: 22
Partial discharge investigation and electric field analysis of different oscillation modes of water droplets on the surface of polymeric insulator under tangential AC electric field stress 切向交流电场应力作用下聚合物绝缘子表面水滴不同振荡模式的局部放电研究及电场分析
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619788
M. Nazemi, V. Hinrichsen
For this contribution, different oscillation modes of a 20 microliter water droplet on the hydrophobic surface of a silicone rubber insulator under tangential AC electric field stress were investigated, using a high speed camera. Since the deformation of water droplet increases the local electric field stress at the triple zones, an electric field analysis at the triple zone is performed to find the worst case of water droplet oscillation modes. Different kinds of water droplet deformation at four dominant oscillation modes, namely mode No. 1 to mode No. 4, which were found experimentally, are simulated and compared. These results show that mode Nos. 1 and 3 provide higher electric field values at the triple zone in comparison to mode Nos. 2 and 4. In parallel, partial discharge inception voltages of a 20 microliter water droplet located on the hydrophobic surface of a silicone rubber insulator under tangential AC electric field stress are measured in the frequency range of 20 Hz to 100 Hz. With the aid of frame analysis of the captured videos, the mode number of water droplet oscillation at each frequency is obtained, and the measured partial discharge inception voltages at each oscillation mode are compared with electric field simulation results. Partial discharge investigations confirmed that the water droplets oscillating at mode Nos. 1 and 3 have lower inception voltages compared to PD inception voltages of water droplets that oscillate at mode Nos. 2 and 4. These measurements also show that inception voltage makes a step whenever the oscillation mode of water droplet changes.
为此,利用高速摄像机研究了20微升水滴在切向交流电场应力作用下硅橡胶绝缘子疏水表面的不同振荡模式。由于水滴的变形增加了三区局部电场应力,因此对三区电场进行了分析,找出了水滴振荡模态的最坏情况。对实验发现的1 ~ 4模态4种主要振荡模态下的不同水滴变形进行了模拟和比较。结果表明,与模式2和模式4相比,模式1和模式3在三区提供更高的电场值。同时,在交流切向电场应力作用下,测量了硅橡胶绝缘子疏水表面上20微升水滴在20 ~ 100 Hz频率范围内的局部放电起始电压。通过对采集到的视频进行帧分析,得到了水滴在各频率下振荡的模态数,并将各振荡模态下实测的局部放电起始电压与电场仿真结果进行了比较。局部放电研究证实,与模式2和4振荡的水滴相比,模式1和模式3振荡的水滴具有更低的PD启动电压。这些测量结果还表明,当水滴的振荡模式发生变化时,起始电压也会发生步进。
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引用次数: 11
Investigations on the dielectric properties of syntactic foams and the change of their dielectric properties due to water immersion 复合泡沫材料的介电性能及浸水对其介电性能的影响
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619868
A. Wagner, J. Knauel
Syntactic foam is a light weight high voltage insulation material that consists of micro-scale hollow particles, so called hollow microspheres (HMS) embedded in a polymeric matrix. The material properties of this hybrid material can be customized to special needs concerning the required properties. For outdoor applications the independence of the properties of insulation materials on the presence of water is necessary. Therefore the dielectric properties of syntactic foam and their behavior when immersed in water are investigated. Plate specimens of 3 mm thickness are stored over a period of 50 days in deionized water tempered to 50°C for the purpose of accelerated water absorption. The relative permittivity as well as the dissipation factor of various compositions of syntactic foam before and after water immersion are compared. The foam compositions vary in the matrix material and the HMS shell material. Further, the compositions vary in the filling degree as well as the HMS diameter. Hence, the influences of these parameters are also investigated. It is observed that the change in the dielectric properties of syntactic foam due to water ingress depends on the polymer matrix, the filler type and the filling degree.
复合泡沫是一种轻质高压绝缘材料,由嵌入聚合物基体的微尺度中空颗粒,即中空微球(HMS)组成。这种混合材料的材料性能可以根据需要的特殊需要进行定制。对于室外应用,绝缘材料的性能与水的存在无关是必要的。为此,研究了复合泡沫的介电性能及其在水中的浸没行为。为了加速吸水,将厚度为3mm的板样在回火至50℃的去离子水中保存50天。比较了不同成分复合泡沫材料在浸水前后的相对介电常数和耗散系数。泡沫成分在基体材料和HMS壳材料中有所不同。此外,所述组合物在填充程度以及HMS直径方面有所不同。因此,还研究了这些参数的影响。研究发现,复合泡沫的介电性能受聚合物基体、填料类型和填充程度的影响。
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引用次数: 1
The influence of compatibilizer on structural morphology and dielectric property of crosslinked polyethylene/montmorillonite nanocomposites 相容剂对交联聚乙烯/蒙脱土纳米复合材料结构形态和介电性能的影响
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619869
L. Xiufeng, Xu Man, L. Xin, Zhang Kai, Xie Darong, Tong Jianping, Cao Xiaolong
In this paper, a series of montmorillonite/Cross-linked polyethylene nanocomposites containing different compatililizer (vinyl acetate copolymer (EVA) or ethylene-ethyl acrylate (EEA)) are prepared by melting blending method. The influence of compatibilizer on the dielectric property of the nanocomposites is studied. DSC is used to study the melting and crystallization behaviors of nanocomposites with and without compatibilizer. Dielectric spectrum of the nanocomposite is tested in room temperature. Dielectric constant and loss factor of different nanocomposites in wide frequency range are analyzed and the dynamic polarization behavior is discussed by the universal relaxation law (URL). Based on the structure characteristics, the effect of compatibilizer on the nanocomposite polarization is obtained.
本文采用熔融共混法制备了一系列含有不同相容剂(醋酸乙烯共聚物(EVA)或丙烯酸乙酯(EEA))的蒙脱土/交联聚乙烯纳米复合材料。研究了相容剂对纳米复合材料介电性能的影响。采用DSC研究了有增容剂和不含增容剂的纳米复合材料的熔融结晶行为。在室温下测试了纳米复合材料的介电谱。分析了不同纳米复合材料在宽频率范围内的介电常数和损耗因子,并利用通用弛豫定律讨论了纳米复合材料的动态极化行为。根据相容剂的结构特点,研究了相容剂对纳米复合材料极化性能的影响。
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引用次数: 1
Measurement and simulation of partial discharge activity within a void cavity in a polymeric power cable model 聚合物电力电缆模型中空穴内局部放电活度的测量与模拟
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619829
H. Illias, M. Othman, M. Tunio, A. Bakar, H. Mokhlis, G. Chen, P. Lewin, A. M. Ariffin
In high voltage power cable, partial discharge (PD) phenomenon may occur within defects that exist in its insulation system. The insulation is normally made of a dielectric material, typically polymeric materials. Repetition of PD activity at the defect site may cause insulation breakdown when the defect grows until it bridges the electrodes between the insulation. Consequently, breakdown of the whole cable will occur. Thus, measurement of PD activity within cable insulation system has been extensively used to monitor the condition of power cables in service. A void cavity is one of the most common PD sources when a cable insulation is stressed under high electric field. In this work, measurements of PD activity within an artificial cylindrical void in the insulation layer of a 22 kV cross-linked polyethylene (XLPE) cable was performed. A two-dimensional model of a cable insulation geometry with a void was also developed using finite element analysis (FEA) software. The model was used to calculate the electric field magnitude in the void within the cable insulation under different conditions of voids and insulation. From this work, an understanding on PD phenomenon within a cylindrical void in a power cable insulation can be enhanced.
在高压电力电缆中,由于绝缘系统存在缺陷,会产生局部放电现象。绝缘材料通常由介电材料制成,通常是聚合物材料。缺陷部位PD活性的重复可能会导致绝缘击穿,当缺陷生长直到绝缘之间的电极架桥。因此,整个电缆将发生故障。因此,电缆绝缘系统内PD活性的测量已被广泛用于电力电缆运行状态的监测。当电缆绝缘在高电场作用下受力时,空穴是最常见的局部放电源之一。在这项工作中,测量了22 kV交联聚乙烯(XLPE)电缆绝缘层人工圆柱形空隙内的PD活性。利用有限元分析(FEA)软件建立了含空洞电缆绝缘几何结构的二维模型。利用该模型计算了不同空穴和绝缘条件下电缆绝缘空穴内的电场大小。通过这项工作,可以加深对电力电缆绝缘中圆柱形空隙内局部放电现象的理解。
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引用次数: 19
期刊
2013 IEEE International Conference on Solid Dielectrics (ICSD)
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