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2013 IEEE International Conference on Solid Dielectrics (ICSD)最新文献

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In situ space charge profile measurements on electronic irradiated material by LIMM 用LIMM测量电子辐照材料的原位空间电荷分布
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619708
S. Bouchareb, V. Griseri, L. Berquez
Material used in space aircraft are in contact with a large panel of charged particles. Dielectrics can store charges up to a certain extend above which electrostatic discharges might occur. To prevent these phenomena that can be harmful for the embarked electronic devices, the electrical behavior of those materials under irradiation must be studied. In the present case, we are only interested in the effect of electrons on dielectrics materials properties. To do so, an irradiation chamber has been equipped with various characterization tools to perform measurements in-situ. This work is focused on in situ space charge measurements by Pulse Electro Acoustic (PEA) technique and Laser Intensity Modulated Method (LIMM) during and post-irradiation. Experimental space charge distributions obtained by both techniques will be presented and discussed taking into account the measurement arrangements.
航天飞机上使用的材料与一大块带电粒子接触。电介质能储存电荷到一定的限度,超过这个限度就可能发生静电放电。为了防止这些现象对装载的电子设备造成危害,必须对这些材料在辐照下的电学行为进行研究。在本例中,我们只对电子对介电材料性质的影响感兴趣。为此,辐照室配备了各种表征工具来进行原位测量。本文主要研究了脉冲电声(PEA)技术和激光强度调制(LIMM)技术在辐照过程和辐照后的原位空间电荷测量。在考虑测量安排的情况下,将介绍和讨论两种技术获得的实验空间电荷分布。
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引用次数: 4
Space charge dynamics in silica-based polyethylene nanocomposites 硅基聚乙烯纳米复合材料的空间电荷动力学
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619800
Yan Wang, George Chen, A. Vaughan
Space charge formation is a well known phenomenon that affects the overall dielectric properties of insulation systems. Space charge occurs when the rate of charge accumulation is different from the rate of removal and involves moving and trapped charges, which modify the electric field distribution within the material. As a result of this, the internal field within the dielectric is locally increased, which then leads to faster degradation and premature failure. Several techniques have been used to probe the space charge behavior of novel dielectric materials, especially in connection with the emerging topic of polymer nanocomposites - material systems that exhibit unique insulation characteristics due to the presence of nanometer-sized inclusions. In this paper, we report on an investigation into space charge dynamics in silica-based polyethylene nanocomposites, where the nanofiller has been modified with respect to its surface chemistry. For this, the pulsed electro-acoustic technique has been used. Experimental observations indicate that the incorporation of nanosilica into polyethylene results in homocharge development near both electrodes. However, with appropriate surface treatment of the filler, homocharges formation was successfully suppressed. Possible relationships between the space charge development and dielectric breakdown properties of the nanocomposites are discussed.
空间电荷形成是一种众所周知的影响绝缘系统整体介电性能的现象。当电荷积累速率不同于去除速率时,空间电荷就会发生,并且涉及到移动和捕获的电荷,这改变了材料内部的电场分布。这样做的结果是,电介质内部的场局部增加,从而导致更快的退化和过早失效。几种技术已被用于探测新型介电材料的空间电荷行为,特别是与聚合物纳米复合材料的新兴主题有关-由于纳米尺寸内含物的存在而表现出独特绝缘特性的材料系统。在本文中,我们报告了对硅基聚乙烯纳米复合材料的空间电荷动力学的研究,其中纳米填料在其表面化学方面进行了改性。为此,采用了脉冲电声技术。实验观察表明,纳米二氧化硅掺入聚乙烯中,在两个电极附近产生了同电荷。然而,通过适当的填料表面处理,成功地抑制了同电荷的形成。讨论了空间电荷发展与纳米复合材料介电击穿性能之间的可能关系。
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引用次数: 19
Dynamic behavior of surface charge on direct-fluorinated polyimide films 直接氟化聚酰亚胺薄膜表面电荷的动态行为
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619907
B. Du, Jie Li, W. Du, H. Du, Yu Gao, Lin Yang
Polyimide film, as a special type of engineering plastic film, is a kind of basic insulating material and is widely applied in the aerial, nuclear, microelectronic industry, turn to turn insulation and turn to ground insulation of inverter-fed motors. However, with the disadvantage of organic polymer, its corona-resistance property is not good enough, which makes insulation early failures occur frequently. The existence of surface charge has a great effect on breakdown characteristic and is the main reason leading to dielectric breakdown. Fluorination as change the chemical component in surface layer of polymers should give rise to the corresponding change in electrical properties of the surface layer thus influence the charge injection from electrodes when they are used as an insulator. This paper presents a study aimed at clarifying the effect of fluorination time on surface charge accumulation and decay behaviors of fluorinated polyimide film. Samples were surface fluorinated in a laboratory vessel at about 328K (55 °C) using a F2/N2 mixture with 20% F2 by volume and 0.05 MPa (500 mbar) for respectively 15, 30, 45 and 60 minutes. Corona charging tests were performed at room temperature with a relative humidity of ~ 40%. The charge distribution was measured by means of an electrostatic voltmeter. Obtained results show the dependence of the charge density as well as the charge decay rate upon the fluorination time of samples, varying as a function of the charge polarity and charging time.
聚酰亚胺薄膜作为一种特殊类型的工程塑料薄膜,是一种基础绝缘材料,广泛应用于航空、核、微电子工业、变频电机的匝对匝绝缘和匝对地绝缘。然而,有机聚合物的缺点是其抗电晕性能不够好,使得绝缘早期失效时有发生。表面电荷的存在对介质击穿特性有很大影响,是导致介质击穿的主要原因。氟化由于改变了聚合物表层的化学成分,应引起其表层电学性质的相应变化,从而影响电极作为绝缘体时从电极注入的电荷。本文研究了氟化时间对氟化聚酰亚胺薄膜表面电荷积累和衰减行为的影响。样品在实验室容器中表面氟化,温度约为328K(55°C),使用F2/N2混合物,体积为20% F2, 0.05 MPa (500 mbar),分别为15、30、45和60分钟。电晕充电试验在室温下进行,相对湿度为~ 40%。电荷分布是用静电伏特计测量的。得到的结果表明,样品的电荷密度和电荷衰减率随氟化时间的变化而变化,随电荷极性和充电时间的变化而变化。
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引用次数: 2
Ionic conductivities of calcium-phosphate glasses 磷酸钙玻璃的离子电导率
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619746
J. Martin, D. Budina, J. Zakel, M. Schafer, K. Weitzel
The transport of potassium and rubidium ions through glasses containing the respective alkali ion as mobile species has been investigated by means of bombardment induced ion transport (BIIT) and impedance spectroscopy (IS). The conductivities as well as the activation energies derived from the two approaches are in agreement lending further support to the recently developed BIIT approach.
利用轰击诱导离子传输(BIIT)和阻抗谱(IS)研究了钾离子和铷离子在含碱离子的玻璃中的传输。两种方法得到的电导率和活化能是一致的,这进一步支持了最近开发的BIIT方法。
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引用次数: 2
Discharge behaviors of electrical breakdown across nanometer vacuum gaps 电击穿纳米真空间隙的放电行为
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619828
G. Meng, Yonghong Cheng, Liang Chen, Yu Chen, Kai Wu
Micro-electro-mechanical systems (MEMS) and Nano-electro-mechanical systems (NEMS) are emerging technologies that uses tools and techniques in the microelectronics industry to build microscopic machines. Electrostatic force is often employed to drive the motion components in MEMS and NEMS devices, which could cause extremely high electric field (more than 108 V/m) between two metal conductors. However, the high field intensity may result in electrical breakdown across the conductors in case of improper operations or overvoltage. Therefore, this paper presented a novel experimental technique to study the discharge behaviors across nanometer gaps between 20 nm and 300 nm. The influence of gap separations on breakdown characteristics and the voltage contrast effect in the gap spacing were both investigated. Results showed that the field electron emission did not play a dominate role in the electrical breakdown process across nanometer gaps, which was different from the classical theory of vacuum breakdown, and the breakdown voltage increased as the increase of gap separations. Besides, the voltage contrast effect in the gap spacing was also observed through the scanning electron microscope, which was related to the electric field intensity.
微机电系统(MEMS)和纳米机电系统(NEMS)是利用微电子工业中的工具和技术来构建微观机器的新兴技术。在MEMS和NEMS器件中,经常采用静电力驱动运动元件,这可能会在两个金属导体之间产生极高的电场(超过108 V/m)。但是,如果操作不当或过电压,高场强可能导致导体之间的电击穿。因此,本文提出了一种新的实验技术来研究20 ~ 300 nm纳米间隙内的放电行为。研究了间隙间距对击穿特性的影响以及间隙间距中的电压对比效应。结果表明,与经典的真空击穿理论不同,场电子发射在纳米间隙的电击穿过程中并不起主导作用,击穿电压随着间隙间距的增加而增加。此外,还通过扫描电镜观察了间隙间距中的电压对比效应,该效应与电场强度有关。
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引用次数: 6
Experimental study on the electrical and thermal properties of epoxy-crepe paper composites for use in UHV DC bushing condensers 特高压直流套管式冷凝器用环氧树脂-绉纸复合材料的电学和热学性能试验研究
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619730
Shiling Zhang, Zongren Peng, Liu Peng, X. Ning
Entire performance of UHVDC resin impregnated paper (RIP) bushings in operation condition has an intimate connection with electrical and thermal properties of epoxy/crepe paper composites used in bushing condenser. Firstly, some samples of pure epoxy and epoxy/crepe composites which are identical to those used in actual RIP bushings were fabricated. Then micro morphology of these samples has been observed by scanning electron microscopy (SEM) and polarized light microscopy (PLM). Some electrical performance measurements were carried out including AC breakdown characteristics, bulk resistivity versus temperature characteristics and dielectric spectroscopy with broadband dielectric spectra. Meanwhile, thermal property containing thermal conductivity versus temperature characteristic has also been obtained experimentally. Finally, with these parameters of composites, electric field and temperature distribution inside bushing condenser has also been simulated by finite element method (FEM).
超高压直流树脂浸渍纸(RIP)衬套在运行状态下的整体性能与衬套冷凝器用环氧树脂/绉纸复合材料的电学和热学性能密切相关。首先,制备了一些与实际RIP衬套相同的纯环氧树脂和环氧/绉复合材料样品。然后用扫描电子显微镜(SEM)和偏振光显微镜(PLM)观察样品的微观形貌。进行了交流击穿特性、体电阻率随温度特性和宽带介电光谱等电性能测量。同时,还通过实验得到了含导热系数的热性能。最后,在复合材料参数的基础上,采用有限元法对套管式冷凝器内部的电场和温度分布进行了数值模拟。
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引用次数: 9
The impact of the colorants on the aging properties of HTV silicone rubber 着色剂对HTV硅橡胶老化性能的影响
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619733
Congzhen Xie, Shan Liu, H. Niu, Licheng Li
The sheath and the shed in China are made of high temperature vulcanized (HTV) silicone rubber. The ferric oxide powder is widely used as red colorant, and it cannot disperse uniformly in the rubber for the reason that the ferric oxide powder is inorganic. In the paper, adding way and the amount of the ferric oxide powder are changed in the specimen-making process. Through hot air aging test, the changes of the specimen's electrical performances, mechanical properties and microstructure are considered, so the influence of the colorant on the specimen's property under hot air environment has been discussed. The results show that color masterbatch which is made of ferric oxide in advance, added in the rubber mixing process can improve the dispersion of the ferric oxide in the rubber, so that the ferric oxide can help reduce degradation of performance due to thermal-oxidative-aging. The radicals which are produced in silicone rubber's aging process could be trapped by the iron ions, which can be oxidated by oxygen in the air soon, and the amount of iron ions are not changed before and after the reaction. Therefore, increasing the content of iron oxide has no significant effect to improve the heat aging performance of the silicone rubber.
护套和棚在中国是由高温硫化(HTV)硅橡胶。氧化铁粉作为红色着色剂被广泛使用,由于氧化铁粉是无机物,在橡胶中不能均匀分散。本文对制备过程中氧化铁粉的添加方式和用量进行了探讨。通过热风老化试验,考虑了试样的电性能、力学性能和微观组织的变化,探讨了着色剂对热风环境下试样性能的影响。结果表明,在橡胶混炼过程中加入预先制备的氧化铁色母粒,可以改善氧化铁在橡胶中的分散,从而降低因热氧化老化而导致的性能下降。硅橡胶老化过程中产生的自由基会被铁离子捕获,很快被空气中的氧气氧化,反应前后铁离子的数量不发生变化。因此,增加氧化铁的含量对提高硅橡胶的热老化性能没有明显的效果。
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引用次数: 2
Influence of trap depths on space charge formation and accumulation characteristics in low density polyethylene 陷阱深度对低密度聚乙烯空间电荷形成和聚集特性的影响
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619662
Guochang Li, Shengtao Li, D. Min, N. Zhao, Yuanwei Zhu
In extra high voltage transmission systems, the accumulation of space charges in polymeric materials have an important influence on the aging and breakdown of power equipments. It has been reported that space charges are mainly determined by trap distribution. Therefore, it is important to understand the influence of trap depths on space charges accumulation in insulating material. In this paper, based on charge migration, trapping and detrapping processes, an unipolar charge transport model has been adopted. The influence of trap depths on space charge in low density polyethylene can be obtained through solving the charge continuity equation, Poisson equation and first order charge trapping/ detrapping dynamic equation. The calculation results show that the free electron density and trapped electron density decrease gradually with the increase of sample position. With the trap depth increases, the total number of trapped electrons also increases, but the total number of free electrons decreases gradually. When the trap depth is larger than 1.1 eV, the total number of space charges in material keeps an equilibrium value. This research provides a theoretical guidance for diagnosing aging degree of insulating equipments in the future.
在超高压输电系统中,高分子材料中空间电荷的积累对电力设备的老化和故障有重要影响。据报道,空间电荷主要由陷阱分布决定。因此,了解陷阱深度对绝缘材料中空间电荷积累的影响是非常重要的。本文采用了基于电荷迁移、俘获和脱陷过程的单极电荷输运模型。通过求解电荷连续性方程、泊松方程和一阶电荷捕获/去捕获动力学方程,可以得到陷阱深度对低密度聚乙烯空间电荷的影响。计算结果表明,随样品位置的增加,自由电子密度和捕获电子密度逐渐减小。随着陷阱深度的增加,被困电子的总数也增加,但自由电子的总数逐渐减少。当陷阱深度大于1.1 eV时,材料中的空间电荷总数保持一个平衡值。该研究为今后绝缘设备的老化程度诊断提供了理论指导。
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引用次数: 4
Evaluation of apparent trap-controlled mobility and trap depth in polymeric HVDC mini-cables 聚合物高压直流微型电缆中陷阱控制的表观迁移率和陷阱深度的评价
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619748
D. van der Born, I. Tsekmes, P. Morshuis, J. J. Smit, T. J. Person, S. J. Sutton
Polymeric insulation materials have not been used in HVDC cable systems until recently because of the tendency of polymers to deplete accumulated charges very slowly. Research on space charge injection, conduction and trapping mechanisms can reveal information about which materials are the best candidates for HVDC cable insulation. In this paper, space charge de-trapping and extraction processes are evaluated in polymeric mini-cables consisting of several different XLPE based insulation materials and PE based semi-conductive layers. The main difference between the materials can be found in the type and concentration of additives. De-trapping and extraction of accumulated space charge in the insulation is investigated with the help of depolarization measurements, which are performed with the Pulsed Electro-Acoustic (PEA) method for cable geometry objects.
聚合物绝缘材料直到最近才在高压直流电缆系统中使用,因为聚合物消耗累积电荷的速度非常慢。对空间电荷注入、传导和俘获机制的研究可以揭示哪些材料是高压直流电缆绝缘的最佳候选材料。本文研究了由几种不同的交联聚乙烯基绝缘材料和聚乙烯基半导电层组成的聚合物微型电缆的空间电荷脱陷和提取工艺。这两种材料的主要区别在于添加剂的种类和浓度。利用脉冲电声(PEA)方法对电缆几何物体进行去极化测量,研究了绝缘中累积空间电荷的去除和提取。
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引用次数: 3
Development rules of inter-turn partial discharge defects on oil-paper insulation 油纸绝缘匝间局部放电缺陷的发展规律
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619715
Jinqing Wei, Yangchun Cheng, Guangzhen Wang, Zhihai Rong, Changjin Diao, Xiao Tian
In power transformers, the main reason why insulation faults occur is that partial discharge (PD) produces insulation deterioration at the weakest point of the insulation structure and ultimately lead to insulation breakdown. The insulation defects exist in the form of electrical trees or carbon channels reduce the effective insulating distance. Take the opaqueness of pressboard into consideration, the carbon channels generated by PD can't be easily observed. Therefore, in this paper, tests based on inter-turn partial discharge model are conducted to study the development rules of oil-paper insulation material defects. Constant voltage application was adopted in this series of tests. High voltage of 40 kV is applied on the inter-turn electrode specimens for different time in different groups of tests. After test, insulation tapes are stripped from inter-turn electrodes layer by layer so as to observe the carbon channels clearly. Results indicate that the development process of the carbon channel can be roughly divided into three stages. Analysis of discharge feature reveals two different shapes of q-φ scatter diagrams, the shape of seeds and the shape of inverted tacks. The shape shown in scatter diagram could be used as effective criteria to diagnose the inter-turn insulation defects produced by partial discharge at later stage.
在电力变压器中,发生绝缘故障的主要原因是局部放电(partial discharge, PD)在绝缘结构最薄弱处产生绝缘劣化,最终导致绝缘击穿。绝缘缺陷以电树或碳通道的形式存在,减小了有效绝缘距离。考虑到压制板的不透明性,PD产生的碳通道不易观察到。因此,本文基于匝间局部放电模型进行试验,研究油纸绝缘材料缺陷的发展规律。本系列试验采用恒压应用。在不同组试验中,对匝间电极试样施加不同时间的40kv高压。测试结束后,将匝间电极上的绝缘胶带逐层剥离,以便清晰地观察碳通道。结果表明,碳通道的发育过程大致可分为三个阶段。通过对流量特征的分析,得出了两种不同形状的q-φ散点图:种子形状和倒钉形状。散点图所示的形状可作为诊断后期局部放电产生的匝间绝缘缺陷的有效判据。
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引用次数: 6
期刊
2013 IEEE International Conference on Solid Dielectrics (ICSD)
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