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2013 IEEE International Conference on Solid Dielectrics (ICSD)最新文献

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Evaluation of defect levels formed in the nano-porous titanium oxide layer of dye-sensitized solar cell 染料敏化太阳能电池纳米多孔氧化钛层缺陷程度的评价
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619830
M. Yoshiura, F. Yoshida
The development of the dye-sensitized solar cell (DSC) has been expected to supply another solar cell other than the silicon solar cells, for its convenient production processes. The nano-porous titanium oxide (TiO2) layer, photo-electrode of DSC, is constructed on a F-doped SnO2 transparent electrode(FTO), before the dye deposition. The structure of the porous TiO2 layer, such as the existence of charge traps, seems to influence the photoelectric conversion efficiency of DSC. The possibility of estimating the photo-electrode efficiency by the charge trap structure was studied with thermally stimulated current (TSC) measurement. As a result of the TSC measurement, four charge traps were detected in the electrode and were evaluated the energy trap depths of 0.07 eV, 0.138 eV, 0.385 eV and 0.381 eV. The escape frequency factors were also evaluated in large span from 10 s-1 to 108 s-1.
染料敏化太阳能电池(DSC)由于其生产工艺方便,被认为是硅太阳能电池以外的另一种太阳能电池。在染料沉积之前,在掺f的SnO2透明电极(FTO)上构建纳米多孔氧化钛(TiO2)层,作为DSC的光电极。多孔TiO2层的结构,如电荷陷阱的存在,似乎会影响DSC的光电转换效率。利用热刺激电流(TSC)测量方法研究了利用电荷阱结构估计光电极效率的可能性。通过TSC测量,在电极中检测到4个电荷陷阱,并评估了能量陷阱深度为0.07 eV, 0.138 eV, 0.385 eV和0.381 eV。在10 s-1 ~ 108 s-1的大跨度范围内,对其逃逸频率因子进行了评价。
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引用次数: 0
Discharge behaviors of electrical breakdown across nanometer vacuum gaps 电击穿纳米真空间隙的放电行为
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619828
G. Meng, Yonghong Cheng, Liang Chen, Yu Chen, Kai Wu
Micro-electro-mechanical systems (MEMS) and Nano-electro-mechanical systems (NEMS) are emerging technologies that uses tools and techniques in the microelectronics industry to build microscopic machines. Electrostatic force is often employed to drive the motion components in MEMS and NEMS devices, which could cause extremely high electric field (more than 108 V/m) between two metal conductors. However, the high field intensity may result in electrical breakdown across the conductors in case of improper operations or overvoltage. Therefore, this paper presented a novel experimental technique to study the discharge behaviors across nanometer gaps between 20 nm and 300 nm. The influence of gap separations on breakdown characteristics and the voltage contrast effect in the gap spacing were both investigated. Results showed that the field electron emission did not play a dominate role in the electrical breakdown process across nanometer gaps, which was different from the classical theory of vacuum breakdown, and the breakdown voltage increased as the increase of gap separations. Besides, the voltage contrast effect in the gap spacing was also observed through the scanning electron microscope, which was related to the electric field intensity.
微机电系统(MEMS)和纳米机电系统(NEMS)是利用微电子工业中的工具和技术来构建微观机器的新兴技术。在MEMS和NEMS器件中,经常采用静电力驱动运动元件,这可能会在两个金属导体之间产生极高的电场(超过108 V/m)。但是,如果操作不当或过电压,高场强可能导致导体之间的电击穿。因此,本文提出了一种新的实验技术来研究20 ~ 300 nm纳米间隙内的放电行为。研究了间隙间距对击穿特性的影响以及间隙间距中的电压对比效应。结果表明,与经典的真空击穿理论不同,场电子发射在纳米间隙的电击穿过程中并不起主导作用,击穿电压随着间隙间距的增加而增加。此外,还通过扫描电镜观察了间隙间距中的电压对比效应,该效应与电场强度有关。
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引用次数: 6
The Monte Carlo Method for the study of an electrical discharge 研究放电的蒙特卡罗方法
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619673
L. Zeghichi, L. Mokhnache, M. Djebabra
The aim of this work is to present the contribution of the Monte Carlo Method to simulate the basic phenomena in an electrical discharge, taking into account the different processes of atomic collisions (elastic or inelastic), in the case of oxygene and in a plan-plan system. Results have been compared with modelisation results to verify the breakdown criteria. The determination of the ambient electrical field depends on distributions of charged particles; by solving the Maxwell equations we get the resulting radial field.
这项工作的目的是介绍蒙特卡罗方法的贡献,以模拟放电中的基本现象,考虑到原子碰撞的不同过程(弹性或非弹性),在氧的情况下,在一个计划-计划系统。结果与建模结果进行了比较,以验证击穿标准。环境电场的确定取决于带电粒子的分布;通过求解麦克斯韦方程组,我们得到了得到的径向场。
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引用次数: 4
Effect of crystallinity and morphology on dielectric properties of PEEK at elevated temperature 结晶性和形貌对PEEK高温介电性能的影响
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619864
J. Ho, T. Jow
Poly(aryl ether ether ketone) (PEEK) is one of the primary candidates for a high temperature capacitor dielectric as a result of its outstanding mechanical strength and thermal stability. However, its breakdown strength is unsatisfactory (~400 MV/m) and high field (>100 MV/m) volumetric resistivity at elevated temperature is largely unknown. In this work, the inter-relationship among crystallinity, morphology, breakdown strength, and volumetric resistivity of PEEK at elevated temperature is studied in order to gain insight to factors which adversely affect breakdown. This paper presents preliminary results of the study.
聚芳醚醚酮(PEEK)是高温电容器电介质的主要候选材料之一,因为它具有出色的机械强度和热稳定性。然而,它的击穿强度不理想(~400 MV/m),高场(>100 MV/m)高温下的体积电阻率很大程度上是未知的。在这项工作中,研究了PEEK在高温下的结晶度、形貌、击穿强度和体积电阻率之间的相互关系,以了解影响击穿的不利因素。本文介绍了研究的初步结果。
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引用次数: 14
Evaluation of apparent trap-controlled mobility and trap depth in polymeric HVDC mini-cables 聚合物高压直流微型电缆中陷阱控制的表观迁移率和陷阱深度的评价
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619748
D. van der Born, I. Tsekmes, P. Morshuis, J. J. Smit, T. J. Person, S. J. Sutton
Polymeric insulation materials have not been used in HVDC cable systems until recently because of the tendency of polymers to deplete accumulated charges very slowly. Research on space charge injection, conduction and trapping mechanisms can reveal information about which materials are the best candidates for HVDC cable insulation. In this paper, space charge de-trapping and extraction processes are evaluated in polymeric mini-cables consisting of several different XLPE based insulation materials and PE based semi-conductive layers. The main difference between the materials can be found in the type and concentration of additives. De-trapping and extraction of accumulated space charge in the insulation is investigated with the help of depolarization measurements, which are performed with the Pulsed Electro-Acoustic (PEA) method for cable geometry objects.
聚合物绝缘材料直到最近才在高压直流电缆系统中使用,因为聚合物消耗累积电荷的速度非常慢。对空间电荷注入、传导和俘获机制的研究可以揭示哪些材料是高压直流电缆绝缘的最佳候选材料。本文研究了由几种不同的交联聚乙烯基绝缘材料和聚乙烯基半导电层组成的聚合物微型电缆的空间电荷脱陷和提取工艺。这两种材料的主要区别在于添加剂的种类和浓度。利用脉冲电声(PEA)方法对电缆几何物体进行去极化测量,研究了绝缘中累积空间电荷的去除和提取。
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引用次数: 3
Chromatic classification of RF signals for partial discharges and noise characterization 部分放电和噪声表征射频信号的色度分类
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619863
J. Ardila-Rey, J. Martínez-Tarifa, M. Mejino, R. Albarracín, M. Rojas-Moreno, G. Robles
Electromagnetic radiation emissions from partial discharges (PD) can be measured, which could be helpful for avoiding unwanted asset disconnections in the power grid for insulation evaluation. These radio-frequency (RF) measurements do not require galvanic contact with high-voltage (HV) devices, which seems to be a clear advantage, but the lack of synchronization voltage makes PD source recognition a difficult task. Moreover, the presence of RF noise sources in the wideband required for PD detection, can lead to false warnings in the HV apparatus evaluation. In this paper, some specific parameters for signal characterization have been used in three-dimensional maps: signal energy, bandwidth and characteristic frequency. A digital acquisition system has been programmed to measure thousands of emissions from environmental noise and controlled PD sources in laboratory experiments. The aim of this paper is to state if this signal classification technique is reliable for PD and noise characterization in the RF range.
可以测量局部放电(PD)的电磁辐射发射,这有助于避免电网中不必要的资产断开,从而进行绝缘评估。这些射频(RF)测量不需要与高压(HV)设备进行电接触,这似乎是一个明显的优势,但缺乏同步电压使得PD源识别成为一项困难的任务。此外,在PD检测所需的宽带中存在射频噪声源,可能导致高压设备评估中的误报。本文在三维地图中使用了信号表征的一些具体参数:信号能量、带宽和特征频率。一个数字采集系统已经被编程来测量实验室实验中来自环境噪声和受控PD源的数千种排放。本文的目的是说明这种信号分类技术在射频范围内的PD和噪声表征是否可靠。
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引用次数: 5
Comparative investigation on dielectric property and thermal conductivity of in situ polymerized and solution mixed polymer nanocoposites 原位聚合和溶液混合聚合物纳米复合材料介电性能和导热性能的比较研究
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619783
Liyuan Xie, Yanhui Huang, Fei Liu, Xingyi Huang, P. Jiang
Barium titanate@ poly (methyl methacrylate) (BT@PMMA) nanocomposites were prepared via in situ atom transfer radical polymerization (ATRP). It was observed that the BT nanoparticles were coated with PMMA and excellently dispersed in the polymer matrix. Compared with the BT/PMMA nanocomposites prepared by the traditional solution blending, BT@PMMA nanocomposites show higher thermal conductivity and lower dielectric loss. The result is attributed to the strong interfacial bonding between the BT nanoparticles and the PMMA matrix.
采用原位原子转移自由基聚合(ATRP)法制备钛酸钡@聚甲基丙烯酸甲酯(BT@PMMA)纳米复合材料。结果表明,BT纳米颗粒被PMMA包覆,并在聚合物基体中分散良好。与传统溶液共混制备的BT/PMMA纳米复合材料相比,BT@PMMA纳米复合材料具有更高的导热性和更低的介电损耗。这一结果归因于BT纳米颗粒与PMMA基体之间的强界面结合。
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引用次数: 0
Is graphene oxide an insulating material? 氧化石墨烯是绝缘材料吗?
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619690
Xingyi Huang, Fei Liu, P. Jiang, Toshikatsu Tanaka
Graphene and graphene oxide are increasingly attracting worldwide attention from academia and industry. The physical properties of graphene have been documented recently, and we have known that the sea of electrons in the two-dimensional, single layer of sp2 hybridized carbon atoms causes graphene to act both as electrical and thermal conductors. In contrast, graphene oxide, an oxidized graphene sheet with carboxylic acid at the edges and phenol hydroxyl and epoxide groups on the basal plane, is generally considered to be an insulating material. Is graphene oxide is an insulating material? This work tries to answer this question by measuring the temperature-dependent electrical property of graphene oxide paper by using a broadband dielectric spectroscopy.
石墨烯和氧化石墨烯越来越受到世界学术界和工业界的关注。石墨烯的物理性质最近被记录下来,我们已经知道,二维单层sp2杂化碳原子中的电子海洋使石墨烯既充当导电体又充当导热体。相比之下,氧化石墨烯通常被认为是一种绝缘材料,它是一种氧化的石墨烯片,边缘有羧酸,基面上有酚羟基和环氧化物基团。氧化石墨烯是绝缘材料吗?这项工作试图通过使用宽带介电光谱测量氧化石墨烯纸的温度依赖性电学特性来回答这个问题。
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引用次数: 23
Corona test of grading ring for UHV insulators using gradient equivalent method 用梯度等效法进行特高压绝缘子分级环电晕试验
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619904
Naiyi Li, Tianxi Xie, Zongren Peng, Shiling Zhang
Corona test is necessary for verifying the validity of grading ring design for insulators on ac transmission lines. But there seems a lack of standards about simulation test method for ultra-high voltage (UHV) power fittings, such as grading ring for insulators. This paper describes a test approach that specifically applies to grading ring for UHV insulators. First, based on finite-element (FE) calculation, a gradient equivalent coefficient which reflects difference of electric stresses acting on surface of grading rings mounted on different sites is determined. Next, refer to IEC and national standard, an available test voltage is corrected by previous coefficient considering interactions of three-dimensional environment. Finally, the corona test of a type of grading ring for UHV suspension composite insulators is performed using above method as an example. This method shows good effect by field observation on tangent towers with an ultraviolet camera and the tested grading rings have been applied in the UHV pilot project in China successfully.
电晕试验是验证交流输电线路绝缘子分级环设计有效性的必要手段。但对于特高压电源配件的模拟试验方法,如绝缘子分级环等,目前还缺乏规范。本文介绍了一种专门适用于特高压绝缘子分级环的测试方法。首先,在有限元计算的基础上,确定了反映不同位置级配环表面电应力差异的梯度等效系数;其次,参考IEC和国家标准,考虑三维环境的相互作用,对可用的试验电压进行先前系数的修正。最后,以某型特高压悬浮复合绝缘子分级环为例进行了电晕试验。该方法经紫外相机切线塔现场观测,效果良好,试验的分级环已成功应用于中国特高压中试工程。
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引用次数: 4
Test stand for high voltage insulator partial discharge testing with ultra short X-ray pulses 超短x射线脉冲高压绝缘子局部放电试验台架
Pub Date : 2013-10-08 DOI: 10.1109/ICSD.2013.6619870
D. Tehlar, U. Riechert, G. Behrmann, Markus Schraudolph
Top quality high voltage pre-test of solid insulating material requires long test intervals because the initiation of partial discharge (PD) in voids not only demands a sufficiently high electric field, but also the availability of a start electron. The latter leads to a statistical distribution of the time to PD inception, such that long test intervals are required to rule out the presence of voids. This makes 100% screening economically infeasible. However, if the PD is activated using ionizing radiation, the necessary test interval can be reduced to a minimum, without risking that small voids will be missed. It has already been shown that pulsed X-rays are able to trigger PD in voids and not affect the measured PD magnitude. Based on this method, known as Pulsed X-ray Induced Partial Discharge (PXIPD), a test stand for routine testing of insulators up to 420 kV has been developed and put into commercial operation. A very low measurement noise level permits an automatic analysis of the results. Already more than 20,000 insulators for installation in GIS have been screened using this PXIPD method on an industrial scale. Investigation of insulators with natural defects demonstrates the effectiveness and reliability of this new system. In combination with the short test cycle time and the ability to unambiguously link PD to a specific insulator the system allows for a leaner GIS production.
高质量的固体绝缘材料高压预试验需要较长的试验间隔,因为在空隙中引起局部放电不仅需要足够高的电场,而且需要有起始电子。后者导致PD开始时间的统计分布,因此需要较长的测试间隔来排除空洞的存在。这使得100%筛查在经济上不可行。但是,如果使用电离辐射激活PD,则可以将必要的测试间隔减少到最小,而不会有错过小空隙的风险。已经证明,脉冲x射线能够在空隙中触发PD,而不影响测量的PD大小。基于脉冲x射线感应局部放电(PXIPD)方法,研制了420 kV以下绝缘子常规测试试验台,并投入商业运行。非常低的测量噪声水平允许对结果进行自动分析。已经有超过20,000个安装在GIS中的绝缘子已经在工业规模上使用这种PXIPD方法进行了筛选。对具有自然缺陷的绝缘子的研究表明了该系统的有效性和可靠性。结合较短的测试周期时间和将PD明确连接到特定绝缘子的能力,该系统允许更精简的GIS生产。
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引用次数: 0
期刊
2013 IEEE International Conference on Solid Dielectrics (ICSD)
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