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Experimental Determination of Heat Transfer using a Polymer Solution Shower during Induction Hardening* 感应硬化过程中聚合物溶液阵雨传热的实验测定*
IF 0.6 Q3 Materials Science Pub Date : 2021-08-01 DOI: 10.1515/htm-2021-0007
M. Kadanik, L. Burgschat, M. Reich, S. Petersen, O. Kessler
Abstract Heat treatment simulation of inductive surface hardening of large bearing rings is a challenging multi-physical task. Besides the determination of material and process parameters of induction heating, the quenching process must be modelled to obtain realistic results concerning surface hardening depth as well as information about residual stresses and distortions of the bearing rings. A common method to model quenching processes is to determine heat transfer coefficients for the specific process depending on component surface temperature. This method was used to characterize the shower cooling process using an aqueous polymer solution of a modified polyalkylene glycol (PAG) type. A specifically designed test set-up allowed to determine the heat transfer coefficients for different distances between shower and hot specimen as well as for different impingement angles of the fluid relative to gravitation. Additionally, the calculated heat transfer coefficients were checked and corrected by FEM simulations.
大型轴承套圈感应表面硬化的热处理模拟是一项具有挑战性的多物理任务。除了确定感应加热的材料和工艺参数外,还必须对淬火过程进行建模,以获得有关表面硬化深度以及轴承套圈残余应力和变形的真实结果。对淬火过程进行建模的一种常用方法是根据部件表面温度确定特定过程的传热系数。该方法用于表征使用改性聚烷基二醇(PAG)型聚合物水溶液的淋浴冷却过程。一个专门设计的测试装置,可以确定淋浴和热样品之间不同距离的传热系数,以及流体相对于重力的不同撞击角度。通过有限元模拟对计算得到的换热系数进行了校核和修正。
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引用次数: 1
Tribological Stress Behaviour of Cast Iron without and with Surface Treatment under Concentrated Contact Load* 铸铁在集中接触载荷下未经和经过表面处理的摩擦学应力行为*
IF 0.6 Q3 Materials Science Pub Date : 2021-08-01 DOI: 10.1515/htm-2021-0010
A. Holst, A. Buchwalder, R. Zenker
Abstract The graphite inclusions typical of grey solidified cast iron materials reduce the load-bearing capacity under locally concentrated pressure and simultaneous sliding stress. Surface treatment processes such as nitriding and electron beam remelting are known to improve the local stress behaviour. In this paper, the effects of the above-mentioned individual processes and their combination on the tribological stress behaviour of ferritic and pearlitic cast irons with different graphite morphologies are discussed. The results obtained in the model wear test ball-plate show that the specific wear coefficient of the investigated cast irons with different graphite morphology can already be reduced by at least one order of magnitude by an approx. 0.5–0.9 mm thick remelted surface layer with a surface hardness of 650–750 HV1. This treatment eliminates the graphite and produces ledeburitic carbides instead. The potential of an additional nitriding treatment depends on the parameters used, i. e. the nitrided layer thickness produced as well as the phase composition and the pore fraction of the compound layer. Based on stress calculations, the experimentally determined main influences such as the coefficient of friction, the pore fraction in the compound layer and the magnitude of the Hertzian pressure on the contact stress could essentially be confirmed.
灰质凝固铸铁材料中典型的石墨夹杂物在局部集中压力和同时滑动应力作用下降低了承载能力。表面处理工艺,如氮化和电子束重熔,已知可以改善局部应力行为。本文讨论了上述各过程及其组合对不同石墨形貌铁素体和珠光体铸铁摩擦学应力行为的影响。在模型磨损试验球盘上得到的结果表明,所研究的不同石墨形貌的铸铁的比磨损系数已经可以近似地降低至少一个数量级。重熔面层厚0.5-0.9 mm,表面硬度650-750 HV1。这种处理消除了石墨,而产生了雷氏体碳化物。附加氮化处理的潜力取决于所使用的参数,即产生的氮化层厚度以及化合物层的相组成和孔隙分数。通过应力计算,基本确定了实验确定的摩擦系数、复合层孔隙率、赫兹压力大小等对接触应力的主要影响。
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引用次数: 1
Optimized Nitriding for Subsequent Induction Heat Treatment 为后续感应热处理优化氮化
IF 0.6 Q3 Materials Science Pub Date : 2021-08-01 DOI: 10.1515/htm-2021-0008
S. Hoja, D. Nadolski, M. Steinbacher, R. Fechte-Heinen
Abstract Nitriding is used to achieve a high hardness in the surface layer through the precipitation of nitrides. However, to realize high nitriding hardness depths, treatment times of many hours are necessary, which usually also result in a decrease in strength within the nitrided layer and base material. With induction heat treatment, on the other hand, high hardness depths can be achieved in a very short time. However, the maximum hardness increase is limited by the alloy content of the material. By combining nitriding and induction hardening, high hardness depths can be achieved in short treatment times as an alternative to deep nitriding. In addition to a significant saving in process energy surface layer properties that cannot be achieved with the individual processes are expected. In order to fully exploit the potential of the combination treatment, at first suitable conditions must be set during nitriding for the subsequent induction hardening. In the present work, nitriding layers with low-porosity compound layers as well as only diffusion layers were produced and analyzed on typical nitriding and tempering steels for this purpose.
渗氮是通过氮化物的析出在表层获得高硬度的方法。然而,为了实现高氮化硬度深度,需要进行长时间的处理,这通常也会导致氮化层和基材内部强度的下降。另一方面,通过感应热处理,可以在很短的时间内获得高硬度深度。然而,最大的硬度增加受限于材料的合金含量。通过结合氮化和感应淬火,可以在短时间内获得高硬度深度,作为深氮化的替代方案。除了显著节省工艺能量外,还期望单个工艺无法实现的表面层特性。为了充分发挥组合处理的潜力,首先必须在渗氮过程中为后续的感应淬火设定合适的条件。本文在典型的渗氮回火钢上制备了含低孔隙率复合渗氮层和纯扩散渗氮层,并进行了分析。
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引用次数: 2
Influence of Deep Rolling and Induction Hardening on Microstructure Evolution of Crankshaft Sections made from 38MnSiVS5 and 42CrMo4 深滚和淬火对38MnSiVS5和42CrMo4曲轴型材组织演变的影响
IF 0.6 Q3 Materials Science Pub Date : 2021-06-01 DOI: 10.1515/htm-2021-0002
A. Fischer, B. Scholtes, T. Niendorf, M. S. A. Fischer, Dr.-Ing. habil. Berthold Scholtes, Prof. Dr.-Ing. Thomas Niendorf
Abstract In order to improve properties of complex automotive components, such as crankshafts, in an application-oriented way, several surface hardening treatments can be applied. Concerning the material performance the definition of adequate process parameters influences the resulting surface properties and, thus, the effectiveness of surface hardening treatments. To analyze most relevant process-microstructure-property relationships, the present paper reports results obtained by two different well-established surface hardening procedures, i. e. deep rolling as a mechanical treatment and induction hardening as a thermal treatment. For each hardening process widely used crankshaft steel grades, i. e. a medium carbon 38MnSiVS5 microalloyed steel and a quenched and tempered 42CrMo4 were selected and thoroughly characterized upon processing, using equal parameter settings. The results reveal that deep rolling in contrast to induction hardening proves to be a less sensitive surface layer treatment with regard to small differences in the initial microstructure, the chemical composition and the applied process parameters. Differences in microstructure evolution with respect to the applied surface hardening treatment are studied and discussed for the highly stressed fillet region of automotive crankshaft sections for all conditions. In this context, high-resolution SEM-based techniques such as EBSD and ECCI are proven to be very effective for fast qualitative evaluation of induced microstructural changes.
为了提高曲轴等复杂汽车零部件的性能,可采用多种表面硬化处理方法。关于材料性能,适当的工艺参数的定义影响得到的表面性能,从而影响表面硬化处理的有效性。为了分析大多数相关的工艺-显微组织-性能关系,本文报告了两种不同的已建立的表面硬化程序所获得的结果,即深滚作为机械处理和感应淬火作为热处理。对于每一种淬火工艺,都选择了广泛使用的曲轴钢牌号,即中碳38MnSiVS5微合金钢和调质42CrMo4钢,并在加工时使用相同的参数设置进行了彻底的表征。结果表明,与感应淬火相比,深轧是一种较不敏感的表面层处理,其初始组织、化学成分和应用的工艺参数差异较小。研究和讨论了各种条件下汽车曲轴高应力圆角区域的表面硬化处理在微观组织演变方面的差异。在这种情况下,高分辨率扫描电镜技术,如EBSD和ECCI,被证明是非常有效的快速定性评价诱发的微观结构变化。
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引用次数: 3
Characterization of Graded Subsurface Zones in Industrial Case-Hardening Using a Non-Destructive Testing System 用无损检测系统表征工业硬化中分级次表层
IF 0.6 Q3 Materials Science Pub Date : 2021-06-01 DOI: 10.1515/htm-2021-0006
R. Gansel, C. Zimmermann, L. Fricke, M. Lüdtke, H. Klümper-Westkamp, R. Fechte-Heinen, H. Maier, D. Zaremba
Abstract For process monitoring and quality assurance of case-hardened components, the determination of the case-hardening depth in the manufacturing process after hardening of the subsurface layer is a quality verification that is often required in industry. Currently, these quality assurance tests can only be realized with destructive measures. During case-hardening, the essential microstructural formation, and thus the key component properties are developed during the heat treatment in the cooling section. The testing technique used in the present study is based on the analysis of harmonic signals of eddy current testing. The aim of this project was to achieve an early identification of incorrect cooling processes in the case of a known transformation behaviour of the components during cooling. The data collected in the industrial hardening process show that an evaluation of the carburizing process on the basis of the case-hardening depth can be carried out non-destructively during component cooling and in the cooled state with the use of eddy current technology.
摘要为了对淬火件进行工艺监控和质量保证,在制造过程中对次表层淬火后的淬火深度进行确定是工业中经常需要进行的质量验证。目前,这些质量保证测试只能通过破坏性措施来实现。在淬火过程中,在冷却段的热处理过程中形成基本的显微组织,从而形成关键的部件性能。本研究采用的检测技术是基于涡流检测的谐波信号分析。该项目的目的是在已知组件在冷却过程中的转换行为的情况下,实现对不正确冷却过程的早期识别。在工业淬火过程中收集的数据表明,利用涡流技术可以在部件冷却和冷却状态下无损地进行基于表面硬化深度的渗碳过程评估。
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引用次数: 0
Influence of Turn-Rolling on the Residual Stresses and Microstructure of C45E and the Effects on Fatigue Life under Cyclic Loading 旋转轧制对C45E残余应力和组织的影响及循环载荷下疲劳寿命的影响
IF 0.6 Q3 Materials Science Pub Date : 2021-06-01 DOI: 10.1515/htm-2021-0003
B. Denkena, P. Kuhlemann, B. Breidenstein, M. Keitel, N. Vogel
Abstract The microstructure and the residual stress state have a significant influence on the service life of the component. The deep rolling process already enables a significant increase in the strength and service life of highly stressed components. By using the hybrid manufacturing process of turn rolling, the edge zone properties can be influenced to such an extent that the service life is further increased compared to conventional deep rolling. In addition to a change in the residual stress state, the use of the turning process temperature also leads to a significant grain refinement in the edge zone area, which has a positive effect on the component service life. This modification of the edge zone can be significantly influenced by the machining speed.
摘要构件的微观组织和残余应力状态对构件的使用寿命有重要影响。深轧工艺已经能够显著提高高应力部件的强度和使用寿命。通过采用车削轧制的混合制造工艺,可以在一定程度上影响边缘区性能,从而使其使用寿命比常规深轧进一步提高。除了残余应力状态的变化外,车削工艺温度的使用还导致边缘区区域的晶粒细化,这对部件的使用寿命有积极的影响。这种边缘区域的变化受加工速度的影响很大。
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引用次数: 1
Tribocorrosion Mechanisms of Martensitic Stainless Steels 马氏体不锈钢的摩擦腐蚀机理
IF 0.6 Q3 Materials Science Pub Date : 2021-06-01 DOI: 10.1515/htm-2021-0004
A. Gassner, L. Waidelich, H. Palkowski, J. Wilde, H. Mozaffari-Jovein
Abstract In the present study, the influence of the electrochemical potential on the tribocorrosion behavior of X20Cr13 in 0.15 molar NaCl-solution was investigated with the aid of a universal-tribometer under potentiostatic control. The resulting material loss was determined through laser confocal microscopy, while the morphology of the wear tracks and the deformation of the material structure near the surface were observed using light and scanning electron microscopy. The results showed a clear dependence of the material loss and the wear mechanisms from the applied potential. Within the cathodic region, a small amount of the material degradation could be attributed to a strong adhesion and resulting strain hardening as a consequence of an electrochemical weakening and mechanical destruction of the passive layer. The maximum of wear during polarization at the free corrosion potential under friction was explained by galvanic coupling between the wear track and the passive surface near the stability threshold between Fe2+-Ion and Fe2O3 development. Through increasing Polarization onto the free corrosion potential in the absence of friction and into the passive region, a decrease in material loss could be observed which is presumably attributed to the stable passive layer that inhibits electrochemical degradation and favors the formation of a grain refinement zone that slows down mechanical destruction.
在恒电位控制下,利用通用摩擦计研究了电化学电位对X20Cr13在0.15 mol / l nacl溶液中摩擦腐蚀行为的影响。通过激光共聚焦显微镜确定了材料的损失,同时使用光学和扫描电子显微镜观察了磨损痕迹的形态和近表面材料结构的变形。结果表明,材料损耗和磨损机制与应用电位有明显的相关性。在阴极区域内,少量的材料降解可归因于强附着力和由此产生的应变硬化,这是钝化层的电化学弱化和机械破坏的结果。在摩擦作用下,在自由腐蚀电位处发生极化时的最大磨损可以解释为在Fe2+-离子与Fe2O3发展之间的稳定阈值附近,磨损轨迹与被动表面之间存在电偶联。通过在没有摩擦的情况下增加极化到自由腐蚀电位并进入被动区域,可以观察到材料损失的减少,这可能归因于稳定的被动层,它抑制了电化学降解,有利于晶粒细化区的形成,从而减缓了机械破坏。
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引用次数: 1
Investigation of Compound Layer Structures after Nitriding and Nitrocarburizing of Quenched and Tempered Steels 调质钢渗氮和氮碳共渗后复合层组织的研究
IF 0.6 Q3 Materials Science Pub Date : 2021-06-01 DOI: 10.1515/htm-2021-0005
M. Sommer, S. Hoja, M. Steinbacher, R. Fechte-Heinen
Abstract A compound layer is formed by ingress of nitrogen from an external nitrogen source into the surface layer and the formation of nitrides when the solubility of nitrogen in the bulk material is exceeded. In the surface layer, where the nitrogen concentration is at its maximum level, the nitrides form a closed layer. The compound layer continues to contain alloy nitrides which have formed from the carbides and other precipitates from the bulk material. The properties of the compound layer have a decisive influence on the wear and fatigue behavior of the loaded surfaces. The current investigations deal with the extensive characterization of compound layers that have been produced in heat treatment processes with the aim of producing stress-resistant nitriding layers. The commonly used nitriding and quench and temper (Q&T) steels 31CrMoV9 and 42CrMo4 served as examination material. The structure of the compound layers was varied within the nitriding trials regarding the phase composition, porosity and layer thicknesses. The phase composition of the compound layers was determined by special etching, scanning electron microscopy (SEM), X-ray diffraction and GDOES.
摘要当氮在块状材料中的溶解度超过时,外部氮源的氮进入表层并形成氮化物,从而形成复合层。在氮浓度最高的表层,氮化物形成一个封闭的层。复合层继续含有由块状材料的碳化物和其他析出物形成的合金氮化物。复合层的性能对加载表面的磨损和疲劳性能有决定性的影响。目前的研究涉及在热处理过程中产生的化合物层的广泛表征,目的是生产抗应力氮化层。以常用的渗氮淬火回火(Q&T)钢31CrMoV9和42CrMo4作为试验材料。在渗氮过程中,复合层的结构在相组成、孔隙率和层厚等方面发生了变化。采用特殊蚀刻、扫描电子显微镜(SEM)、x射线衍射和GDOES测定了复合层的相组成。
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引用次数: 4
Numerical Study to Understand the Distortion Behavior of a Weight-Reduced Counter Gear* 了解减重反齿轮畸变行为的数值研究*
IF 0.6 Q3 Materials Science Pub Date : 2021-04-01 DOI: 10.1515/htm-2020-0009
J. Kagathara, T. Lübben
Abstract Objectives in the field of lightweight construction can be achieved by changing the component design, among other things. However, a design suitable for production would have to be taken into account, since serious distortion problems can occur after the final heat treatment due to reduced stiffness or asymmetries in the mass distribution. To illustrate this problem area, case hardening experiments using the example of a weight-reduced counter gear made of 20MnCr5 were carried out and have shown significantly different distortion behavior depending on the geometry and process parameters. However, it is difficult or even impossible to understand such a distortion behavior only through experiments, since many different variables can be responsible for dimensional and shape changes. In this context, a simulation tool can be very helpful to identify important variables that cause dimensional and shape changes and to understand the associated processes. This paper attempts to answer some open questions that arise from experiments on distortion behavior through simulations. ◼
轻量化结构领域的目标可以通过改变组件设计等方式来实现。然而,必须考虑到适合生产的设计,因为在最终热处理后,由于刚度降低或质量分布不对称,可能会出现严重的变形问题。为了说明这一问题领域,使用20MnCr5制成的重量减轻的反向齿轮进行了壳体硬化实验,并显示出根据几何形状和工艺参数显着不同的变形行为。然而,仅仅通过实验来理解这种变形行为是困难的,甚至是不可能的,因为许多不同的变量可以负责尺寸和形状的变化。在这种情况下,模拟工具对于识别导致尺寸和形状变化的重要变量以及理解相关过程非常有帮助。本文试图通过模拟来回答变形行为实验中出现的一些开放性问题。◼
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引用次数: 2
A Model to Predict the Microstructural Constituents after Quenching and Partitioning of Martensitic Stainless Steels 马氏体不锈钢淬火及分配后组织成分预测模型
IF 0.6 Q3 Materials Science Pub Date : 2021-04-01 DOI: 10.1515/htm-2020-0008
S. Kresser, R. Schneider, H. Zunko, C. Sommitsch
Abstract The typical heat treatment of martensitic stainless steels comprises hardening and subsequent tempering. Depending on the application and size of the component, tempering is carried out either at low temperatures (< 300 °C) or at high temperatures (> 500 °C). In this paper, tempering at lower temperatures is examined. First, the austenitizing step is considered in greater detail and an optimized formula for the calculation of the MS temperature of such steel grades is created in order to enable to be modelled. For the calculations, the austenite composition is determined at different austenitizing temperatures using thermodynamic simulation. Furthermore, the transformation of austenite into martensite during quenching is described with the help of the Koistinen-Marburger equation. The second part deals with effects in the material at low holding temperatures. Here, the influence of different hardening temperatures and interception temperatures of the quenching procedure is investigated. There is no complete partitioning at temperatures of 300 °C. Certain tempering processes can also take place, such as the formation of transition carbides, so-called M3C carbides. A typical tempering with formation of stable Cr-rich carbides does not occur at this low temperature. Finally, the calculated results of the model correlate well with microstructural investigations (XRD, LOM). ◼
马氏体不锈钢的典型热处理包括淬火和回火。根据应用和部件的尺寸,回火可以在低温(< 300°C)或高温(> 500°C)下进行。本文对低温回火进行了研究。首先,更详细地考虑了奥氏体化步骤,并创建了用于计算此类钢牌号的MS温度的优化公式,以便能够建模。为了计算,利用热力学模拟确定了不同奥氏体化温度下的奥氏体成分。此外,还利用Koistinen-Marburger方程描述了淬火过程中奥氏体向马氏体的转变。第二部分处理在低温下对材料的影响。研究了淬火过程中不同淬火温度和淬火截留温度的影响。在300℃的温度下没有完全的分解。某些回火过程也会发生,例如形成过渡碳化物,即所谓的M3C碳化物。在这个低温下不会发生典型的回火,形成稳定的富铬碳化物。最后,模型计算结果与微观结构研究(XRD, LOM)吻合良好。◼
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引用次数: 3
期刊
HTM-Journal of Heat Treatment and Materials
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