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COPING WITH SPACE ENVIRONMENT: TESTING SOLID PROPELLANTS FOR IN-ORBIT USE 应对空间环境:在轨使用固体推进剂试验
IF 0.7 Q3 Materials Science Pub Date : 2023-01-01 DOI: 10.1615/intjenergeticmaterialschemprop.v22.i5.30
Marcel Holler, Guenter Mussbach, A. Weigand, Robin Putzar, Axel Ringeisen, Karl Wieland Naumann, Ferran Valencia Bel
The results of a risk reduction study are presented, proving the suitability of solid rocket motors (SRMs) to de-orbit satellites at the end of their lifetime. In a risk reduction program, three basic unexplored questions regarding this technological approach were investigated: (1) what are the effects of the size and type of particles ejected during the operation of SRMs; (2) what is the effect of the micrometeoroid impact on the solid propellant; and (3) what are the effects of prolonged exposure to space radiation during the 20-year expected satellite lifetime of satellites? Using a series of sophisticated and newly developed research approaches, it was shown that solid rocket propellants can withstand harsh space conditions over an extensive period of time. All of the tests were performed using a well-established, metal-free high-performance ammonium perchlorate/hydroxyl-terminated polybutadiene propellant fully qualified by military standards.
介绍了一项降低风险研究的结果,证明了固体火箭发动机(SRMs)在卫星寿命结束时脱离轨道的适用性。在一个降低风险的项目中,研究了关于这种技术方法的三个基本问题:(1)在srm运行期间喷射的颗粒的大小和类型有什么影响;(2)微流星体撞击对固体推进剂的影响是什么;(3)在卫星20年预期寿命期间,长时间暴露于空间辐射会产生什么影响?使用一系列复杂和新开发的研究方法,表明固体火箭推进剂可以在很长一段时间内承受恶劣的太空条件。所有试验都是使用一种完善的、无金属的高性能高氯酸铵/端羟基聚丁二烯推进剂进行的,完全符合军事标准。
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引用次数: 0
Theoretical investigation on combustion heterogeneity in interior ballistics of mortar using Population Balance Equation 基于人口平衡方程的砂浆内弹道燃烧非均匀性理论研究
Q3 Materials Science Pub Date : 2023-01-01 DOI: 10.1615/intjenergeticmaterialschemprop.2023048571
Matthias Pautard, Christian Chauveau, Fabien Halter
The ever-rolling progress of weapon systems has proven to demand an increase in precision in the models to be able to achieve further improvements. In the field of Interior Ballistics, one of the elements that remains excluded from most models is the combustion heterogeneity due to non-equilibrium of pressure. This paper presents a zero-dimensional model of a mortar. It includes two chambers: the combustion chamber and the cartridge with combustion heterogeneity occurring between these two chambers. The model adapted to this kind of problem is the Population-Balance-Equation (PBE). A successful attempt to solve the PBE numerically in this case, using the class method, is presented in this work to theoretically address the quantification of the impact of combustion heterogeneities too often ignored.
武器系统的不断发展已被证明需要提高模型的精度,以便能够实现进一步的改进。在内弹道领域,由于压力不平衡导致的燃烧非均质性一直被排除在大多数模型之外。本文提出了迫击炮的零维模型。它包括两个室:燃烧室和燃烧不均匀发生在这两个室之间的药筒。适用于这类问题的模型是人口-平衡方程(PBE)。在这种情况下,使用类方法在数值上解决PBE的成功尝试,在这项工作中提出了理论上解决燃烧非均质性影响的量化问题,这些影响往往被忽视。
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引用次数: 0
Comparison of the specific impulse calculated with the ISPBKW code and 2 different empirical relationships encoded into the “Research output software for energetic materials 用ISPBKW代码计算的比冲与“含能材料研究输出软件”中编码的2种不同经验关系的比较
IF 0.7 Q3 Materials Science Pub Date : 2023-01-01 DOI: 10.1615/intjenergeticmaterialschemprop.2023047992
Sabrina Wahler, T. Klapötke
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引用次数: 0
Hypergolic ignition of solid fuels with reactive additives using hydrogen peroxide as an oxidizer 使用过氧化氢作为氧化剂的活性添加剂的固体燃料自燃点火
IF 0.7 Q3 Materials Science Pub Date : 2023-01-01 DOI: 10.1615/intjenergeticmaterialschemprop.2023048649
Wei-che Lin, G. Young
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引用次数: 1
Index Volume 22, 2023 索引卷22,2023
Q3 Materials Science Pub Date : 2023-01-01 DOI: 10.1615/intjenergeticmaterialschemprop.v22.i6.50
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引用次数: 0
Ignition of Nitromethane-based Propellant Mixtures 硝基推进剂混合物的点火
Q3 Materials Science Pub Date : 2023-01-01 DOI: 10.1615/intjenergeticmaterialschemprop.2023049577
Maxim Kurilov, Lennart Ziemer, Volker Weiser, Sophie Ricker, Christoph Kirchberger, Stefan Schlechtriem
Hydrazine is a commonly used propellant in spacecraft and satellite propulsion, but its toxic and carcinogenic properties, and consequently the high costs associated with its handling, have led the propulsion community to seek "green" alternatives. Our research group is exploring the use of nitromethane, a low-toxicity substance and a staple laboratory solvent, as the primary ingredient for a green monopropellant. However, nitromethane's ignition is challenging, requiring a certain level of pressure for stable combustion. To improve ignition and combustion behavior, we screened additives including transition metal acetylacetonates and other organometallic compounds. Gas-tight vessels in a DSC device and single droplet combustion tests were used to measure the influence of additives on the exotherm onset and peak in nitromethane thermal decomposition. The screening showed that some transition metal acetylacetonates and other organometallic compounds effectively enhance thermal decomposition in sealed-vessel DSC measurements. Ferrocene had the most significant influence: adding 2 wt. % of this substance to nitromethane caused the decomposition peak to shift from 384 to 280 °C. In single droplet combustion tests, the addition of Ferrocene caused a quite high reduction of the total droplet life time in an oxygen-deprived atmosphere at 3 bar, making it a strong candidate for the use as an ignition and combustion catalyst in a nitromethane-based monopropellant.
联氨是航天器和卫星推进中常用的推进剂,但它的毒性和致癌性,以及处理它的高成本,促使推进界寻求“绿色”替代品。我们的研究小组正在探索使用硝基甲烷,一种低毒物质和主要实验室溶剂,作为绿色单体推进剂的主要成分。然而,硝基甲烷的点火是具有挑战性的,需要一定水平的压力才能稳定燃烧。为了改善点火和燃烧性能,我们筛选了过渡金属乙酰丙酮酸酯和其他有机金属化合物。采用DSC装置中的气密容器和单液滴燃烧试验,测量了添加剂对硝基甲烷热分解放热开始和峰值的影响。筛选表明,在密封容器DSC测量中,一些过渡金属乙酰丙酮酸酯和其他有机金属化合物有效地促进了热分解。二茂铁的影响最为显著:在硝基甲烷中加入2 wt. %的二茂铁,使分解峰从384°C转移到280°C。在单液滴燃烧试验中,二茂铁的加入使液滴在3巴缺氧气氛下的总寿命大大缩短,使其成为在硝基单推进剂中用作点火和燃烧催化剂的有力候选者。
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引用次数: 0
A Novel Method to Analyze the Self-Excited and Pulsed T-burner Experimental Data at Wide Pressure and Frequency Ranges 宽压力、宽频率自激脉冲t型燃烧器实验数据分析新方法
IF 0.7 Q3 Materials Science Pub Date : 2023-01-01 DOI: 10.1615/intjenergeticmaterialschemprop.2023046469
S. Ganesan, S. Chakravarthy, B. S. Subhash Chandran
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引用次数: 0
Numerical investigation of interface stability in reduced gravity 失重条件下界面稳定性的数值研究
IF 0.7 Q3 Materials Science Pub Date : 2023-01-01 DOI: 10.1615/intjenergeticmaterialschemprop.2023048294
Sesha N. C. Govindan, M. Dreyer
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引用次数: 0
WATER AS AN ENVIRONMENTALLY FRIENDLY PROPELLANT FOR A MULTI-FUNCTIONAL SPACECRAFT ARCHITECTURE 水作为一种环保推进剂用于多功能航天器结构
IF 0.7 Q3 Materials Science Pub Date : 2023-01-01 DOI: 10.1615/intjenergeticmaterialschemprop.v22.i2.20
Jesús Manuel Muñoz Tejeda, A. Schwertheim, A. Knoll
Water can be utilized as spacecraft propellant to dramatically reduce the environmental impact of constructing and operating a satellite. In this work, a multi-mode chemical-electrical propulsion system, in which water was used as the propellant in both high thrust chemical and high specific impulse electrical maneuvres, was studied. This type of system allows the spacecraft architecture community to divest from traditional propellants such as hydrazine and xenon, thus reducing the production of highly toxic chemicals and dramatically reducing the carbon footprint of propulsion systems. Water has the lowest toxicity, carbon footprint, and price of any current or proposed propellant, and has been shown in laboratory testing to be a feasible alternative compared to traditionally used propellants. The unique role it can play across multiple spacecraft subsystems suggests that the commercial adoption of water as a propellant will reduce cost and mass while also reducing the environmental impact of the satellites of tomorrow. This technology has the ability to enable the development of modular, multifunctional, competitive, and environmentally friendly spacecraft architectures.
水可以用作航天器推进剂,大大减少建造和运行卫星对环境的影响。本文研究了一种以水为推进剂进行大推力化学和高比冲电气机动的多模式化学-电力推进系统。这种类型的系统使航天器建筑界摆脱了传统的推进剂,如肼和氙气,从而减少了剧毒化学物质的产生,并大大减少了推进系统的碳足迹。水的毒性、碳足迹和价格都是目前或拟议的推进剂中最低的,并且在实验室测试中显示,与传统使用的推进剂相比,水是一种可行的替代品。它可以在多个航天器子系统中发挥的独特作用表明,将水作为推进剂的商业采用将降低成本和质量,同时也减少未来卫星对环境的影响。该技术能够实现模块化、多功能、竞争性和环境友好型航天器架构的开发。
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引用次数: 0
ASSESSING FUEL FRAGMENTATION IN AN OXIDIZING ATMOSPHERE FOR HYBRID ROCKET PROPELLANT SAFETY COMPREHENSION 用于混合火箭推进剂安全理解的氧化气氛中燃料碎裂评估
Q3 Materials Science Pub Date : 2023-01-01 DOI: 10.1615/intjenergeticmaterialschemprop.2023049522
Akiyo Takahashi, Takumi Ohde, Daigo Ogasawara, Subaru Tsubokura, Kenichi Takahashi, Yoshiaki Takahashi, Tei Saburi, Shiro Kubota
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引用次数: 0
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International Journal of Energetic Materials and Chemical Propulsion
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