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The Improving Conditions for the Aerobic Bacteria Performing the Degradation of Obsolete Pesticides in Polluted Soils 好氧细菌降解污染土壤中过期农药的改良条件
IF 3.8 Q1 Environmental Science Pub Date : 2021-01-01 DOI: 10.1177/1178622120982590
T. Doolotkeldieva, S. Bobusheva, Mahabat Konurbaeva
Currently, in the territory of Kyrgyzstan, 50 storage facilities of obsolete pesticides exist; they store about 5000 tons of these hazardous chemicals. The storage conditions have become unusable for a long time. They pose a serious threat to the people living there, livestock, and the environment. The main purpose of this research was the use of selected bacteria with cytochrome P450 genes for the bioremediation of polluted soils around the burial sites in model soil experiments. In the first trial of biodegradation experiments, one contaminated soil was used without any changes in chemical contents, and in the second, the physical and chemical contents of the soil were improved to maintain the bioremediation conditions. The soils in both variants were treated 3 times (ie, once a month) with suspensions of a single culture or a blend of active bacteria (1 × 108 cells/mL) selected from in vitro biodegradation experiments. Two control units without the addition of the bacteria culture were also run. The quantification of targeted persistent organic pollutants (POPs) before and after biodegradation was performed by capillary gas chromatography (GC) coupled to a mass spectrometer. In 6 months, obsolete pesticides such as dieldrin, α-endosulfan, β-endosulfan, and 4-heptachlor-epox pure were able to degrade almost completely, up to 98% to 99.0%, by the blend of bacteria and the single culture of bacteria. Endrin aldehyde showed more resistance as the blend of bacteria was able to degrade it to 59.77%. To improve the aerobic degradation for elimination of pesticides from contaminated soils, it is necessary to create optimal agrotechnical and agrochemical conditions.
目前,吉尔吉斯斯坦境内有50个废弃农药储存设施;他们储存了大约5000吨这种危险化学品。储存条件已变得无法使用很长一段时间。它们对生活在那里的人们、牲畜和环境构成严重威胁。本研究的主要目的是在模型土壤实验中,使用选定的具有细胞色素P450基因的细菌对埋葬地点周围的污染土壤进行生物修复。在生物降解实验的第一次试验中,使用了一种化学含量没有任何变化的污染土壤,在第二次试验中提高了土壤的物理和化学含量,以保持生物修复条件。两种变体的土壤都用单一培养物或活性细菌混合物的悬浮液处理3次(即每月一次)(1 × 108个细胞/mL)。还运行了两个没有添加细菌培养物的对照单元。生物降解前后目标持久性有机污染物的定量通过毛细管气相色谱(GC)与质谱仪相结合进行。在6 几个月后,狄氏剂、α-硫丹、β-硫丹和4-庚氯-天花纯等废弃农药通过细菌混合和单一细菌培养几乎完全降解,降解率高达98%至99.0%。Endrin醛表现出更强的抗性,因为细菌的混合物能够将其降解至59.77%。为了改善好氧降解以消除污染土壤中的农药,有必要创造最佳的农业技术和农业化学条件。
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引用次数: 7
Climate Change and Extreme Temperature Trends in the Baja California Peninsula, Mexico 墨西哥下加利福尼亚半岛的气候变化和极端温度趋势
IF 3.8 Q1 Environmental Science Pub Date : 2021-01-01 DOI: 10.1177/11786221211010702
P. Martínez-Austria, José Alejandro Jano-Pérez
Climate change is one of the greatest threats that our civilization is facing because increases in extreme temperatures severely affect humans, the economy, and ecosystems. General circulation models, which adequately predict climate change around the world, are less accurate at regional levels. Therefore, trends must be locally assessed, particularly in regions such as the Baja California Peninsula, which is a thin mass of land surrounded by the Pacific Ocean and the Gulf of California. Herein, we discuss extreme temperature trends in the Baja California Peninsula and whether they are statistically significant based on the Spearman’s nonparametric statistical test. For these purposes, 18 weather stations covering the entire region were analyzed, revealing that maximum temperatures for the hottest months are rising at a rate that is consistent with the RCP 8.5 scenario. Changes in minimum temperatures were also analyzed.
气候变化是我们文明面临的最大威胁之一,因为极端温度的升高严重影响人类、经济和生态系统。能够充分预测世界各地气候变化的大环流模型在区域层面上的准确性较差。因此,必须对趋势进行局部评估,特别是在下加利福尼亚半岛等地区,下加利福尼亚半岛是一片被太平洋和加利福尼亚湾包围的薄土地。在此,我们讨论了下加利福尼亚半岛的极端温度趋势,以及基于Spearman非参数统计检验,这些趋势是否具有统计学意义。为此,对覆盖整个地区的18个气象站进行了分析,结果表明,最热月份的最高气温正在以与RCP 8.5情景一致的速度上升。还分析了最低温度的变化。
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引用次数: 6
Characterization and Classification of Soils of Zamra Irrigation Scheme, Northeastern Ethiopia 埃塞俄比亚东北部Zamra灌溉方案土壤的特征和分类
IF 3.8 Q1 Environmental Science Pub Date : 2021-01-01 DOI: 10.1177/11786221211026577
W. Sebnie, E. Adgo, H. Kendie
Understanding soil types of a given area is an important prerequisite to design optimum management strategies such as irrigation water management. The study was thus conducted on characterization and classification of Zamra irrigation scheme in Abergelle district of Amhara Region, which has an area of 196.16 ha. For this study, 53 auger observations, four profile pits, extensive visual observations, reconnaissance survey, and descriptions of soil profiles and laboratory analysis were used to study the morphological and physicochemical properties of the soils of the scheme. Twelve disturbed and undisturbed soil samples were collected from all profiles of each genetic horizon for laboratory analysis. The soils of the study area were identified based on Food and Agricultural Organization of the United Nations/World Reference Base for Soil Resources (FAO/WRB) 2015. The results revealed that the textural classes of all profiles of the study site ranged from sandy clay loam to sandy loam. The chemical properties of the soil in terms of total nitrogen, organic matter, and available phosphorus were in the very low and low categories as per the criteria developed by Tekalign and Olsen, respectively, whereas exchangeable bases (Ca, Mg, K, and Na), cation exchange capacity, and extractable micronutrients (Fe, Mn, Zn, and Cu) were medium to high. Based on morphological, physical, and chemical analyses, the soils were classified as Leptic Regosols (Eutric, Loamic; 21.99% of the area), Vertic Cambisols (Hypereutric; 17.87%), Haplic Regosols (Eutric; 36.69%), and Rhodic Nitisols (Eutric; 23.44%). Therefore, management techniques that enhance soil fertility (including crop rotations, manuring, fallow periods, proper management of crop residues, and leguminous cover crops) and water-saving technologies suitable to the terrain of the area are the best options to enhance land productivity in the area.
了解特定地区的土壤类型是设计最佳管理策略(如灌溉用水管理)的重要前提。因此,本研究对阿姆哈拉地区面积为196.16 ha的Abergelle区Zamra灌溉方案的特征和分类进行了研究。通过53个螺旋钻观测、4个剖面坑、广泛的目视观测、勘察调查、土壤剖面描述和实验室分析,研究了该方案土壤的形态和物理化学性质。从每个遗传层的所有剖面中收集了12个受干扰和未受干扰的土壤样品进行实验室分析。研究区土壤类型根据联合国粮农组织/世界土壤资源参考基地(FAO/WRB) 2015年数据进行识别。结果表明,研究地点各剖面的质地类别均为砂质粘土壤土至砂质壤土。根据Tekalign和Olsen制定的标准,土壤的化学性质在全氮、有机质和速效磷方面分别处于非常低和低的类别,而交换碱(Ca、Mg、K和Na)、阳离子交换容量和可提取微量营养素(Fe、Mn、Zn和Cu)则处于中等至高的类别。基于形态、物理和化学分析,将其划分为富营养化土壤;21.99%的面积),垂直Cambisols (Hypereutric;17.87%), Haplic Regosols (Eutric;36.69%), Rhodic Nitisols (Eutric;23.44%)。因此,提高土壤肥力的管理技术(包括轮作、施肥、休耕期、适当管理作物残茬和豆科覆盖作物)和适合该地区地形的节水技术是提高该地区土地生产力的最佳选择。
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引用次数: 5
2021: The New Normal and the Air, Soil and Water Research Perspective 2021:新常态与大气、土壤和水研究视角
IF 3.8 Q1 Environmental Science Pub Date : 2021-01-01 DOI: 10.1177/1178622120988318
E. Bandala, J. Rodrigo‐Comino, M. T. Latif
With over 64.1 million cases worldwide (by December 1, 2020) and a death toll surpassing 1.48 million the COVID-19 pandemics has filled not only with fear and isolation our day-to-day lives but also with a significant amount of disinformation, the unreliability of data, and lack of trust on the response of governmental officers and authorities that, sadly, can be translated in loss of lives in our closest circles (colleagues, friends, family). At Air, Soil and Water Research (ASW), we believe that knowledge is the only way out of this and any other crisis faced by humankind, and our team has been working elbow-to-elbow (but online) to offer the best quality research and scientific knowledge that will certainly assist for better decision making and led towards the best path to get us through this so hard time.
全球病例超过6410万例(截至2020年12月1日),死亡人数超过148万,新冠肺炎大流行不仅让我们的日常生活充满了恐惧和孤立,而且也带来了大量虚假信息、数据的不可靠性,以及对政府官员和当局的反应缺乏信任,令人遗憾的是,可以转化为我们最亲密圈子(同事、朋友、家人)的生命损失。在空气、土壤和水研究所(ASW),我们相信知识是摆脱这场危机和人类面临的任何其他危机的唯一途径,我们的团队一直在密切合作(但在网上),提供最优质的研究和科学知识,这必将有助于更好地做出决策,并为我们度过这段艰难时期找到最佳途径。
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引用次数: 0
Temporal Aspects in Air Quality Modeling—A Case Study in Wrocław 空气质量建模中的时间因素——以弗罗茨瓦夫为例
IF 3.8 Q1 Environmental Science Pub Date : 2020-12-01 DOI: 10.1177/1178622120975829
J. Kamińska, E. Lucena-Sánchez, G. Sciavicco
Anthropogenic environmental pollution is a known and indisputable issue, and the importance of searching for reliable mathematical models that help understanding the underlying process is witnessed by the extensive literature on the topic. In this article, we focus on the temporal aspects of the processes that govern the concentration of pollutants using typical explanatory variables, such as meteorological values and traffic flows. We develop a novel technique based on multiobjective optimization and linear regression to find optimal delays for each variable, and then we apply such delays to our data to evaluate the improvement that can be obtained with respect to learning an explanatory model with standard techniques. We found that optimizing delays can, in some cases, improve the accuracy of the final model up to 15%.
人为环境污染是一个众所周知且无可争议的问题,关于该主题的大量文献证明了寻找有助于理解潜在过程的可靠数学模型的重要性。在本文中,我们将使用典型的解释变量(如气象值和交通流量)来关注控制污染物浓度的过程的时间方面。我们开发了一种基于多目标优化和线性回归的新技术来寻找每个变量的最优延迟,然后我们将这些延迟应用于我们的数据,以评估与使用标准技术学习解释模型相比可以获得的改进。我们发现,在某些情况下,优化延迟可以将最终模型的准确性提高15%。
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引用次数: 1
Temporal Variations and Potential Source Areas of Fine Particulate Matter in Bangkok, Thailand 泰国曼谷细颗粒物的时间变化和潜在来源区
IF 3.8 Q1 Environmental Science Pub Date : 2020-12-01 DOI: 10.1177/1178622120978203
S. Kanchanasuta, S. Sooktawee, A. Patpai, P. Vatanasomboon
Particulate matter (PM) less than 2.5 micron (PM2.5) issue is 1 of the important targets of concern by the United Nations’ Sustainable Development Goals. Bangkok is a megacity and facing air pollution problems. This study analyzed PM, PM2.5 and PM less than 10 micron (PM10), monitoring data from stations located in Bangkok, and aimed to present their variations in diurnal, weekly, and intra-annual timescales. High PM concentrations are related to calm wind. The diurnal variation of PM2.5/PM10 suggested a greater accumulation of PM2.5 than PMcoarse during the low wind speed. Potential source areas affecting PM rising at each monitoring station were identified using statistical technique, bivariate polar plot, and conditional bivariate probability function. Results showed that Ratchathewi District Monitoring Station identified 3 potential source areas related to emissions from transportation sources creating rising PM concentrations. The first potential source was located in the northwest direction, namely, the Rama VI Road close to the conjunction with Ratchawithi Road. The second potential source area was located around the cross-section between Phaya Thai Road and Rama I Road, while the third was located at the intersection of the Phaya Thai Road to Yothi Street and Rang Nam Road. These potential source areas constitute useful information for managing and reducing PM.
颗粒物(PM)小于2.5 微米(PM2.5)问题是联合国可持续发展目标关注的重要目标之一。曼谷是一个特大城市,面临着空气污染问题。本研究分析了PM、PM2.5和小于10的PM 微米(PM10),曼谷监测站的监测数据,旨在呈现其在日、周和年内时间尺度上的变化。高PM浓度与无风有关。PM2.5/PM10的日变化表明,在低风速期间,PM2.5的积累量大于PMcoarse。利用统计技术、二元极坐标图和条件二元概率函数确定了影响每个监测站PM上升的潜在源区。结果显示,Ratchathewi地区监测站确定了3个与造成PM浓度上升的交通源排放有关的潜在源区。第一个潜在来源位于西北方向,即靠近Ratchawithi路交界处的Rama VI路。第二个潜在震源区位于Phaya Thai路和Rama I路之间的横截面附近,而第三个位于Phaya泰国路至Yothi街和Rang Nam路的交叉口。这些潜在的来源区域构成了管理和减少PM的有用信息。
{"title":"Temporal Variations and Potential Source Areas of Fine Particulate Matter in Bangkok, Thailand","authors":"S. Kanchanasuta, S. Sooktawee, A. Patpai, P. Vatanasomboon","doi":"10.1177/1178622120978203","DOIUrl":"https://doi.org/10.1177/1178622120978203","url":null,"abstract":"Particulate matter (PM) less than 2.5 micron (PM2.5) issue is 1 of the important targets of concern by the United Nations’ Sustainable Development Goals. Bangkok is a megacity and facing air pollution problems. This study analyzed PM, PM2.5 and PM less than 10 micron (PM10), monitoring data from stations located in Bangkok, and aimed to present their variations in diurnal, weekly, and intra-annual timescales. High PM concentrations are related to calm wind. The diurnal variation of PM2.5/PM10 suggested a greater accumulation of PM2.5 than PMcoarse during the low wind speed. Potential source areas affecting PM rising at each monitoring station were identified using statistical technique, bivariate polar plot, and conditional bivariate probability function. Results showed that Ratchathewi District Monitoring Station identified 3 potential source areas related to emissions from transportation sources creating rising PM concentrations. The first potential source was located in the northwest direction, namely, the Rama VI Road close to the conjunction with Ratchawithi Road. The second potential source area was located around the cross-section between Phaya Thai Road and Rama I Road, while the third was located at the intersection of the Phaya Thai Road to Yothi Street and Rang Nam Road. These potential source areas constitute useful information for managing and reducing PM.","PeriodicalId":44801,"journal":{"name":"Air Soil and Water Research","volume":null,"pages":null},"PeriodicalIF":3.8,"publicationDate":"2020-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/1178622120978203","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44967536","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 14
Report of Particulate Matter Emissions During the 2015 Fire at Fuel Tanks in Santos, Brazil 2015年巴西桑托斯燃料箱火灾期间颗粒物排放报告
IF 3.8 Q1 Environmental Science Pub Date : 2020-11-01 DOI: 10.1177/1178622120971251
Daniela Oliveira da Silva, Bruna Hayashida Arôxa, V. Klausner, E. Bastos, A. Prestes, A. Pacini
We report a study of the particulate matter emissions related to the 2015 fire outbreak at a fuel tank storage facility located at Santos, a coastal city in Brazil. The facility, managed by the company Ultracargo, had oil tanks (filled with gasoline and ethanol) destroyed by fire that lasted more than a week, between 2nd and 9th April. In this article, we present the atmospheric concentration analysis of particulate matter (PM10) measured over the entire month of April 2015 by the 2 closest stations that integrate the air quality monitoring system of the São Paulo State Environmental Company (CETESB). The results were compared with similar data from the same period of the yesteryear (April 2014). The results were also complemented by the air masses trajectories over the region (obtained with HYSPLIT/NOAA software). Our results do indicate a subtle increase in the particulate concentration during the days of the fire, followed by a fast dissipation over the subsequent weeks. The observed plume dispersion discussion is made considering the meteorological patterns of the region and other environmental and health reported impacts related to the accident.
我们报告了一项关于2015年巴西沿海城市桑托斯燃料箱储存设施火灾相关颗粒物排放的研究。该设施由Ultracargo公司管理,油箱(装满汽油和乙醇)在4月2日至9日持续了一个多星期的大火中被烧毁。在本文中,我们介绍了2015年4月由两个最近的站点测量的大气颗粒物(PM10)浓度分析,这两个站点整合了圣保罗州环境公司(CETESB)的空气质量监测系统。结果与去年同期(2014年4月)的类似数据进行了比较。该结果还得到了该地区气团轨迹的补充(通过HYSPLIT/NOAA软件获得)。我们的研究结果确实表明,在火灾发生的几天里,颗粒物浓度有轻微的增加,随后的几周内,颗粒物浓度迅速消散。考虑到该地区的气象模式以及与事故有关的其他环境和健康影响,对观测到的羽流扩散进行了讨论。
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引用次数: 0
Arbuscular Mycorrhizal Fungi Colonization in the Rhizosphere of Aspilia pruliseta Schweif. ext Schweif in the Semiarid Eastern Kenya 丛枝菌根真菌在紫苏根际的定殖。肯尼亚东部半干旱地区的extSchweif
IF 3.8 Q1 Environmental Science Pub Date : 2020-11-01 DOI: 10.1177/1178622120969190
James Peter Muchoka, Daniel Njiru Mugendi, Paul Nthakanio Njiruh, C. Onyari, Paul Kamau Mbugua, Ezekiel Mugendi Njeru
The use of arbuscular mycorrhizal fungi (AMF) to enhance soil phosphate uptake is a biological technique considered to cure phosphate deficiency in soils. This study investigated association of Aspilia pruliseta Schweif shrub with AMF in Kenya. The study aims at profiling a tropical shrub with multiple ecological benefits that could reduce addition of chemical phosphatic fertilizer into the soil and reverse negative consequences of eutrophication. Sampling was purposive to have areas with or without Aspilia pruliseta vegetation growing. A small amount (10 g) of the soil from 27 composite samples was used for spore count determination and a similar amount for next generation sequencing. Spore counts varied significantly among soil textural types, sample locations, and soil depth. Sandy loam had the highest spore counts with a mean average of 404 spores. The spore count decreased significantly (P < .05) with the depth of soil from a mean of 514 spores to 185 along the rhizosphere. The intensity of spore morphotypes was significantly higher at P < .05 for soils whose vegetation was covered with Aspilia pruliseta than those without. Aspilia pruliseta vegetation used together with sandy loam soil could culture commercial mycorrhiza fungi production for use in agrisystems.
利用丛枝菌根真菌(AMF)提高土壤对磷的吸收是一种被认为可以治疗土壤缺磷的生物技术。本研究调查了肯尼亚的Aspilia pruliseta Schweif灌木和AMF的关系。该研究旨在分析一种具有多种生态效益的热带灌木,这种灌木可以减少向土壤中添加化学磷肥,并扭转富营养化的负面后果。采样的目的是让有或没有鸭嘴草植被的地区生长。少量(10 g) 来自27个复合样品的土壤中的一个用于孢子计数测定,并将类似数量用于下一代测序。孢子数在土壤质地类型、样品位置和土壤深度之间存在显著差异。沙壤土的孢子数最高,平均为404个孢子。孢子数显著下降(P < .05),根际土壤深度从平均514个孢子到185个孢子。孢子形态类型的强度在P < .05的土壤比没有覆盖的土壤。与沙壤土一起使用的鸭嘴草植被可以培养商业菌根真菌生产,用于农业系统。
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引用次数: 1
Adsorptive Removal of Phosphate From Wastewater Using Ethiopian Rift Pumice: Batch Experiment 埃塞俄比亚裂谷浮石吸附去除废水中的磷酸盐:间歇试验
IF 3.8 Q1 Environmental Science Pub Date : 2020-11-01 DOI: 10.1177/1178622120969658
Yohannis Fetene, T. Addis
Phosphorous from municipal and industrial wastewater is the main cause of eutrophication of rivers and lakes, because effluent quality from conventional secondary wastewater treatment plants does not meet the discharge standard that demands further treatment. Therefore, we investigated pumice as a potential low-cost adsorbent for the tertiary treatment of phosphate from municipal wastewater. The phosphate adsorption process reached equilibrium after 60 minutes contact time and achieved a removal efficiency of 94.4% ± 0.7% for an adsorbent dose of 10 g/L in 3 mg/L phosphate solution. The highest phosphate removal was recorded at pH 7. The experimental data best fitted with the Redlich-Peterson isotherm and the pseudo-second-order kinetic models. The coexisting anions decreased phosphate adsorption in the order of mixture >SO42– > HCO3− > NO3− > Cl− > CO3−. Pumice removed 95% ± 0.2% of phosphate from effluents of the secondary treatment unit of a municipal wastewater treatment plant. Furthermore, effective regeneration of saturated pumice was possible with a 0.2 M NaOH solution. Therefore, pumice could be a technically workable low-cost reusable adsorbent for phosphate removal from wastewater as a tertiary treatment to curb eutrophication of surface waters. However, further column adsorption study is recommended for a continuous flow system to optimize process design variables and scale up for field applications.
城市和工业废水中的磷是导致河流和湖泊富营养化的主要原因,因为传统的二级污水处理厂的出水质量不符合排放标准,需要进一步处理。因此,我们研究了浮石作为一种潜在的低成本吸附剂,用于城市污水中磷酸盐的三级处理。磷酸盐吸附过程在60后达到平衡 分钟的接触时间,并获得94.4%的去除效率 ± 0.7%,吸附剂剂量为10 g/L,3 mg/L磷酸盐溶液。pH值为7时磷酸盐去除率最高。实验数据与Redlich-Peterson等温线和拟二阶动力学模型最为吻合。共存的阴离子降低了磷酸盐的吸附,其顺序为混合物>SO42- > HCO3− > NO3− > Cl− > CO3−。浮冰去除率95% ± 城市污水处理厂二级处理装置废水中0.2%的磷酸盐。此外,使用0.2 M NaOH溶液。因此,浮石可以作为一种技术上可行的低成本可重复使用的吸附剂,用于废水中的磷酸盐去除,作为抑制地表水富营养化的三级处理。然而,建议对连续流系统进行进一步的柱吸附研究,以优化工艺设计变量并扩大现场应用规模。
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引用次数: 9
Hydroxyl Radical Generation by Recyclable Photocatalytic Fe3O4/ZnO Nanoparticles for Water Disinfection 可回收光催化Fe3O4/ZnO纳米颗粒生成羟基自由基用于水消毒
IF 3.8 Q1 Environmental Science Pub Date : 2020-11-01 DOI: 10.1177/1178622120970954
Oscar D. Máynez-Navarro, M. Méndez-Rojas, D. X. Flores-Cervantes, J. Sánchez-Salas
Advanced oxidation processes based on photocatalytic generation of •OH radicals have emerged as promising technologies for the removal of recalcitrant pollutants in water. However, their poor recyclability has reduced their potential large-scale application. Herein, a Fe3O4-embedded ZnO system has been prepared and its photocatalytic •OH radicals activity was evaluated by monitoring the photo-assisted bleaching of p-nitrosodimethylaniline (pNDA). Water disinfection performance was determined by measuring Escherichia coli inactivation under different conditions. Bleaching of nearly 80% of the initial pNDA concentration after just 120 minutes under UV365nm irradiation was determined. Bacterial inactivation at different concentrations (0.1, 1.0, and 5.0 mg mL−1) of the Fe3O4/ZnO nanocomposite was determined, finding that the best performance was obtained at 0.1 mg mL−1 (90%) just after the first 30 minutes under UV irradiation. The materials are easily magnetically recovered and their performance evaluated after 3 consecutive cycles of reuse. These magnetic and photoactive nanocomposites showed improved performance and could be used for wastewater treatment or disinfection processes of water.
基于光催化生成•OH自由基的高级氧化工艺已成为去除水中顽固污染物的有前途的技术。然而,它们较差的可回收性降低了它们大规模应用的潜力。本文制备了fe3o4包埋ZnO体系,并通过监测对亚硝基二甲苯胺(pNDA)的光辅助漂白,评价了其光催化•OH自由基活性。通过测定不同条件下大肠杆菌的灭活情况,确定水的消毒性能。在UV365nm照射下,仅120分钟后,pNDA的漂白率接近初始浓度的80%。研究了Fe3O4/ZnO纳米复合材料在不同浓度(0.1、1.0和5.0 mg mL−1)下的灭活效果,发现在0.1 mg mL−1下的灭活效果最好,在紫外线照射30分钟后达到90%。这些材料很容易被磁性回收,并且在连续重复使用3个周期后,它们的性能得到了评估。这些具有磁性和光活性的纳米复合材料表现出更好的性能,可用于废水处理或水的消毒过程。
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引用次数: 6
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Air Soil and Water Research
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