The effects of gossypol resin and NDP-6 reagents, as well as the Z-1 composition prepared in the ratio of NDP-6 + gossypol resin = 9:1 on the corrosion aggressiveness of formation water and freezing temperature of high-paraffin model oil were investigated for the first time in laboratory conditions. During the experiments, a model oil sample prepared in a 2:1 ratio of commercial oil from Narimanov and Absheron fields of SOCAR was used as a research object. The electrochemical corrosion medium was a formation water sample taken from well No. 1082 of “Bibiheybatneft” OGPI, SOCAR. It was determined that compared to individual reagents, the new composition has a more effective impact on the corrosion rate in H2S formation water and the freezing temperature of high-paraffin oil sample. As a result of the conducted research, it was found out that as the concentration of reagents increases, the efficiency of the effect also increases. Thus, the highest protection efficiency for gossypol resin was observed at a concentration of 110 mg/l, resulting in the corrosion rate of 0.09 g/m2 · h (98% corrosion protection efficiency). The most effective indicator for NDP-6 depressant additive was at 1000 g/t, reducing the freezing temperature of high-paraffin model oil from +16°С to –2°С. However, the strongest effect was observed in Z-1 composition. At a concentration of 700 g/t, it reduced the corrosion rate in the formation water from 4.30 g/m2 · h to 0.04 g/m2 · h (99% corrosion protection efficiency) and the freezing temperature of model oil from +16°С to –9°C, respectively (163% of the effect on freezing temperature). Thus, based on the results obtained from the experiments, the efficiency of individual reagents and the composition based on both reagents was calculated. The highest efficiency was observed at a concentration of 700 g/t for the composition “NDP-6 + gossypol resin = 9:1” (conditional name – Z-1).
{"title":"Study of the effect of the composition of high-paraffin oil on their freezing temperature and on the corrosion aggressivity of formation water","authors":"S. Pashayeva","doi":"10.18668/ng.2024.02.06","DOIUrl":"https://doi.org/10.18668/ng.2024.02.06","url":null,"abstract":"The effects of gossypol resin and NDP-6 reagents, as well as the Z-1 composition prepared in the ratio of NDP-6 + gossypol resin = 9:1 on the corrosion aggressiveness of formation water and freezing temperature of high-paraffin model oil were investigated for the first time in laboratory conditions. During the experiments, a model oil sample prepared in a 2:1 ratio of commercial oil from Narimanov and Absheron fields of SOCAR was used as a research object. The electrochemical corrosion medium was a formation water sample taken from well No. 1082 of “Bibiheybatneft” OGPI, SOCAR. It was determined that compared to individual reagents, the new composition has a more effective impact on the corrosion rate in H2S formation water and the freezing temperature of high-paraffin oil sample. As a result of the conducted research, it was found out that as the concentration of reagents increases, the efficiency of the effect also increases. Thus, the highest protection efficiency for gossypol resin was observed at a concentration of 110 mg/l, resulting in the corrosion rate of 0.09 g/m2 · h (98% corrosion protection efficiency). The most effective indicator for NDP-6 depressant additive was at 1000 g/t, reducing the freezing temperature of high-paraffin model oil from +16°С to –2°С. However, the strongest effect was observed in Z-1 composition. At a concentration of 700 g/t, it reduced the corrosion rate in the formation water from 4.30 g/m2 · h to 0.04 g/m2 · h (99% corrosion protection efficiency) and the freezing temperature of model oil from +16°С to –9°C, respectively (163% of the effect on freezing temperature). Thus, based on the results obtained from the experiments, the efficiency of individual reagents and the composition based on both reagents was calculated. The highest efficiency was observed at a concentration of 700 g/t for the composition “NDP-6 + gossypol resin = 9:1” (conditional name – Z-1).","PeriodicalId":45266,"journal":{"name":"Nafta-Gaz","volume":null,"pages":null},"PeriodicalIF":0.5,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140467851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Guseyn R. Gurbanov, Vali Kh. Nurullayev, A. Gasimzade
A sample of crude oil from Umbaki oil field, characterized by the property of forming an aggregative and kinetically stable water-oil emulsion has been studied in the work. To conduct the research, Dissolvan-4411, Difrol-9426, Sarol-412, Dissolvan-13280 and ND-12 demulsifiers were examined at concentrations of 200, 400 and 600 g/t and the optimal consumption rate was determined. Laboratory experiments were carried out at temperatures of 20, 40 and 60°C. 10 compositions were prepared with a 1:1 ratio of each reagent, based on the optimal consumption rate of 600 g/t. The compositions are reagents with the same purpose, prepared on the basis of demulsifiers. New compositions of W-series were prepared on the basis of the most preferred compositions of A-series. The efficiency of demulsification was investigated, and, experiments were carried out to measure the quantities of asphaltene, resin and paraffin sediments, as well as the remaining amounts of salts and mechanical mixtures after demulsification of oil. The results of the conducted experimental studies revealed that the effect of compositions is superior to the effect of individual reagents. This is explained by the synergism effect between the reagents. As a result, the impact of compositions on the rheology of stable water-oil emulsions becomes stronger. The amount of chloride salts, mechanical mixtures and asphaltene-resin-paraffin compounds in the oil also decreases sharply. Finally, the dependence of the thickness of the best-performing W series compositions on viscosity, which is an important rheological parameter of oil, is shown in a diagram. The W-2 composition is recommended for wide application in mining conditions as a multifunctional reagent in the oil industry.
{"title":"The use of new effective compositions for decomposing a stable water-oil emulsion","authors":"Guseyn R. Gurbanov, Vali Kh. Nurullayev, A. Gasimzade","doi":"10.18668/ng.2024.02.05","DOIUrl":"https://doi.org/10.18668/ng.2024.02.05","url":null,"abstract":"A sample of crude oil from Umbaki oil field, characterized by the property of forming an aggregative and kinetically stable water-oil emulsion has been studied in the work. To conduct the research, Dissolvan-4411, Difrol-9426, Sarol-412, Dissolvan-13280 and ND-12 demulsifiers were examined at concentrations of 200, 400 and 600 g/t and the optimal consumption rate was determined. Laboratory experiments were carried out at temperatures of 20, 40 and 60°C. 10 compositions were prepared with a 1:1 ratio of each reagent, based on the optimal consumption rate of 600 g/t. The compositions are reagents with the same purpose, prepared on the basis of demulsifiers. New compositions of W-series were prepared on the basis of the most preferred compositions of A-series. The efficiency of demulsification was investigated, and, experiments were carried out to measure the quantities of asphaltene, resin and paraffin sediments, as well as the remaining amounts of salts and mechanical mixtures after demulsification of oil. The results of the conducted experimental studies revealed that the effect of compositions is superior to the effect of individual reagents. This is explained by the synergism effect between the reagents. As a result, the impact of compositions on the rheology of stable water-oil emulsions becomes stronger. The amount of chloride salts, mechanical mixtures and asphaltene-resin-paraffin compounds in the oil also decreases sharply. Finally, the dependence of the thickness of the best-performing W series compositions on viscosity, which is an important rheological parameter of oil, is shown in a diagram. The W-2 composition is recommended for wide application in mining conditions as a multifunctional reagent in the oil industry.","PeriodicalId":45266,"journal":{"name":"Nafta-Gaz","volume":null,"pages":null},"PeriodicalIF":0.5,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140465073","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The article presents a comparative analysis of different variants of installing rotary counterweights on the crank in the mechanical drive of the new design of the pumping unit used in oil production. It also addresses the assessment of torque on the output shaft of the gearbox and the balancing coefficient of the mechanical drive. In examining the rotary balancing approach for the new design of the pumping unit, various options for installing counterweights on the crank during rotary balancing were analyzed. Analytical expressions were proposed to determine the torques on the output shaft of the gearbox. Calculations based on the technical parameters of classic pumping units of the СK series revealed that the installation of counterweights on the crank during rotary balancing in the new design of the beamless pumping unit machine significantly affects the torque on the output shaft of the gearbox and the balancing of the pumping unit. They also revealed that although the torque on the output shaft of the gearbox is small in the pumping unit equipped with two counterweights of the same weight and located at the same distance, in this configuration, the output shaft of the gearbox experiences a substantial cantilever load due to excessive weight of the counterweights, leading to a significant reduction in the durability of the gearbox. In the other two options, when installing a single counterweight on the crank, the torque on the output shaft of the pumping unit’s gearbox is approximately from 5 to 10% greater than in the first variant, resulting in additional energy losses. In the pumping machine equipped with two counterweights of equal weight but located at different distances from the center of rotation, the torque on the output shaft of the gearbox is reduced, similar to the first variant. However, due to the weight of the counterweights, it also imposes a substantial cantilever load on the output shaft, leading to a significant reduction in the service life of the gearbox. Additionally, in this option, unlike the first, the balancing coefficient is approximately 3% less.
{"title":"Comparative analysis of different variants of installing rotary counterweights on the crank of the new design of beamless pumping unit","authors":"B. Ahmedov, Isa Khalilov, A. Hajiyev","doi":"10.18668/ng.2024.02.02","DOIUrl":"https://doi.org/10.18668/ng.2024.02.02","url":null,"abstract":"The article presents a comparative analysis of different variants of installing rotary counterweights on the crank in the mechanical drive of the new design of the pumping unit used in oil production. It also addresses the assessment of torque on the output shaft of the gearbox and the balancing coefficient of the mechanical drive. In examining the rotary balancing approach for the new design of the pumping unit, various options for installing counterweights on the crank during rotary balancing were analyzed. Analytical expressions were proposed to determine the torques on the output shaft of the gearbox. Calculations based on the technical parameters of classic pumping units of the СK series revealed that the installation of counterweights on the crank during rotary balancing in the new design of the beamless pumping unit machine significantly affects the torque on the output shaft of the gearbox and the balancing of the pumping unit. They also revealed that although the torque on the output shaft of the gearbox is small in the pumping unit equipped with two counterweights of the same weight and located at the same distance, in this configuration, the output shaft of the gearbox experiences a substantial cantilever load due to excessive weight of the counterweights, leading to a significant reduction in the durability of the gearbox. In the other two options, when installing a single counterweight on the crank, the torque on the output shaft of the pumping unit’s gearbox is approximately from 5 to 10% greater than in the first variant, resulting in additional energy losses. In the pumping machine equipped with two counterweights of equal weight but located at different distances from the center of rotation, the torque on the output shaft of the gearbox is reduced, similar to the first variant. However, due to the weight of the counterweights, it also imposes a substantial cantilever load on the output shaft, leading to a significant reduction in the service life of the gearbox. Additionally, in this option, unlike the first, the balancing coefficient is approximately 3% less.","PeriodicalId":45266,"journal":{"name":"Nafta-Gaz","volume":null,"pages":null},"PeriodicalIF":0.5,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140463923","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Wodór odgrywa coraz istotniejszą rolę w kontekście dążenia do neutralności klimatycznej poprzez odejście od paliw kopalnych. Nie tylko jest on nośnikiem energii, ale także stanowi surowiec oraz rozwiązanie do magazynowania energii pozyskiwanej ze źródeł odnawialnych. Technologia power-to-gas, która umożliwia konwersję energii elektrycznej na wodór, stanowi kluczowy element tego procesu. Unia Europejska wyznaczyła ambitny cel redukcji emisji CO2 o 55% do 2030 roku, określając go nazwą „Gotowi na 55”. Wodór odnawialny ma znaczący wkład w realizację tego celu. Produkcja wodoru przy wykorzystaniu energii odnawialnej zależy od dostępności źródeł odnawialnych i od polityki energetycznej poszczególnych krajów, zwłaszcza w kontekście unijnym. W 2021 roku Polska ogłosiła Polską Strategię Wodorową do roku 2030 z perspektywą do 2040 roku. Dokument ten zawiera sześć głównych celów dotyczących rozwoju gospodarki wodorowej, obejmujących: energetykę, transport, przemysł, produkcję wodoru, przesył, dystrybucję i magazynowanie, a także tworzenie stabilnego otoczenia regulacyjnego. Strategia ta wpisuje się w ogólną politykę europejską dotyczącą wzrostu roli wodoru jako nośnika energii. Realizacja celów strategii wodorowej ma przyczynić się do dekarbonizacji sektorów o dużym zapotrzebowaniu na energię, w szczególności transportu. Unia Europejska stara się również rozwijać infrastrukturę wodorową, aby przyspieszyć dojście do neutralności klimatycznej. European Hydrogen Backbone to jedna z inicjatyw promujących wodór jako nośnik energii i infrastrukturę wodorową. W przeszłości działania Unii Europejskiej skupiały się głównie na dekarbonizacji sektora elektroenergetycznego, ale teraz uwaga skierowana jest także na produkcję wodoru jako kluczowy element transformacji energetycznej. Wzrost produkcji energii elektrycznej ze źródeł odnawialnych, w tym z elektrolizy wody, jest niezbędny, aby osiągnąć cele związane z produkcją wodoru odnawialnego. Ważne jest, aby woda używana w procesie elektrolizy wody była dostarczana ze źródeł odnawialnych, co można osiągnąć poprzez umowy zakupu energii odnawialnej. Istnieją też określone kryteria dotyczące czasu i geografii, które muszą być spełnione, aby wodór mógł być uznany za odnawialny. Certyfikacja wodoru RFNBO (ang. renewable fuels of non-biological origin) jest ważnym elementem tego procesu. Systemy certyfikacji, takie jak System KZR INiG, potwierdzają, że wodór spełnia określone standardy zrównoważonego rozwoju i może być uznawany za odnawialny nośnik energii. Certyfikaty te są istotne zarówno na poziomie krajowym, jak i międzynarodowym, zwłaszcza w kontekście eksportu wodoru do Unii Europejskiej.
{"title":"Wymagania wobec wodoru RFNBO","authors":"Katarzyna Mojsiejewska, D. Rogowska","doi":"10.18668/ng.2024.02.04","DOIUrl":"https://doi.org/10.18668/ng.2024.02.04","url":null,"abstract":"Wodór odgrywa coraz istotniejszą rolę w kontekście dążenia do neutralności klimatycznej poprzez odejście od paliw kopalnych. Nie tylko jest on nośnikiem energii, ale także stanowi surowiec oraz rozwiązanie do magazynowania energii pozyskiwanej ze źródeł odnawialnych. Technologia power-to-gas, która umożliwia konwersję energii elektrycznej na wodór, stanowi kluczowy element tego procesu. Unia Europejska wyznaczyła ambitny cel redukcji emisji CO2 o 55% do 2030 roku, określając go nazwą „Gotowi na 55”. Wodór odnawialny ma znaczący wkład w realizację tego celu. Produkcja wodoru przy wykorzystaniu energii odnawialnej zależy od dostępności źródeł odnawialnych i od polityki energetycznej poszczególnych krajów, zwłaszcza w kontekście unijnym. W 2021 roku Polska ogłosiła Polską Strategię Wodorową do roku 2030 z perspektywą do 2040 roku. Dokument ten zawiera sześć głównych celów dotyczących rozwoju gospodarki wodorowej, obejmujących: energetykę, transport, przemysł, produkcję wodoru, przesył, dystrybucję i magazynowanie, a także tworzenie stabilnego otoczenia regulacyjnego. Strategia ta wpisuje się w ogólną politykę europejską dotyczącą wzrostu roli wodoru jako nośnika energii. Realizacja celów strategii wodorowej ma przyczynić się do dekarbonizacji sektorów o dużym zapotrzebowaniu na energię, w szczególności transportu. Unia Europejska stara się również rozwijać infrastrukturę wodorową, aby przyspieszyć dojście do neutralności klimatycznej. European Hydrogen Backbone to jedna z inicjatyw promujących wodór jako nośnik energii i infrastrukturę wodorową. W przeszłości działania Unii Europejskiej skupiały się głównie na dekarbonizacji sektora elektroenergetycznego, ale teraz uwaga skierowana jest także na produkcję wodoru jako kluczowy element transformacji energetycznej. Wzrost produkcji energii elektrycznej ze źródeł odnawialnych, w tym z elektrolizy wody, jest niezbędny, aby osiągnąć cele związane z produkcją wodoru odnawialnego. Ważne jest, aby woda używana w procesie elektrolizy wody była dostarczana ze źródeł odnawialnych, co można osiągnąć poprzez umowy zakupu energii odnawialnej. Istnieją też określone kryteria dotyczące czasu i geografii, które muszą być spełnione, aby wodór mógł być uznany za odnawialny. Certyfikacja wodoru RFNBO (ang. renewable fuels of non-biological origin) jest ważnym elementem tego procesu. Systemy certyfikacji, takie jak System KZR INiG, potwierdzają, że wodór spełnia określone standardy zrównoważonego rozwoju i może być uznawany za odnawialny nośnik energii. Certyfikaty te są istotne zarówno na poziomie krajowym, jak i międzynarodowym, zwłaszcza w kontekście eksportu wodoru do Unii Europejskiej.","PeriodicalId":45266,"journal":{"name":"Nafta-Gaz","volume":null,"pages":null},"PeriodicalIF":0.5,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140466531","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
One of the important reserves for the growth of oil and gas production is the acceleration of emergency recovery work in production and exploration wells at minimal cost. A significant amount of work in downhole conditions is performed using downhole destructive and cutting tools. Each oil and gas producing country annually uses more than 100 standard sizes, thousands of cutting tool sets: downhole, annular, combined, pilot, internal and external pipe cutters, as well as reamers for cutting side “windows” in production strings. Therefore, the need for them is growing significantly every year. The conducted experiments show that during the operation of cutting tools, the working abrasive-cutting part of the tool wears out and collapses, but the body, other elements and the connecting thread remain suitable for further operation. Therefore, the restoration of working bodies, consisting of crushed particles of used borehole cutting tools, is an urgent scientific and technical task for the oil and gas industry. When repairing oil and gas wells, as well as eliminating the most complex accidents, more than a hundred standard sizes of downhole cutting and destructive tools are used. Currently, an acute shortage of this equipment in oilfield facilities makes it necessary to reconsider the technologies for restoring downhole cutting and destructive tools and introduce them into production. The conducted studies show that there is not enough information about the thickness and height of the layers of the material applied to the damaged area of the cutting and destructive tool, as well as the information necessary for the optimal mode of its operation and its effectiveness after restoration. Composite materials are widely used in the preparation of cutting-chopping and destructive elements of oil-field tools and equipment used in the drilling, operation and repair of wells. In order to increase the cutting capacity of the cutting part of the tool, it is necessary to investigate the advantages of tungsten-carbide (TC) type composite materials compared to other materials and ensure their resistance to high temperatures. As a result of theoretical studies, the stress-deformation state of the contact areas of the composite elements, where the working areas of the cutting and destructive tools are reinforced, and the dependence of the productivity of the composite materials on the speed of transition to metal and the sizes of the composite grains were determined by using the finite element method (two-dimensional simplex elements).
{"title":"The advantage of composite materials used in downhole cutting tools","authors":"Amir G. Mustafayev, Chingiz R. Nasirov","doi":"10.18668/ng.2024.01.03","DOIUrl":"https://doi.org/10.18668/ng.2024.01.03","url":null,"abstract":"One of the important reserves for the growth of oil and gas production is the acceleration of emergency recovery work in production and exploration wells at minimal cost. A significant amount of work in downhole conditions is performed using downhole destructive and cutting tools. Each oil and gas producing country annually uses more than 100 standard sizes, thousands of cutting tool sets: downhole, annular, combined, pilot, internal and external pipe cutters, as well as reamers for cutting side “windows” in production strings. Therefore, the need for them is growing significantly every year. The conducted experiments show that during the operation of cutting tools, the working abrasive-cutting part of the tool wears out and collapses, but the body, other elements and the connecting thread remain suitable for further operation. Therefore, the restoration of working bodies, consisting of crushed particles of used borehole cutting tools, is an urgent scientific and technical task for the oil and gas industry. When repairing oil and gas wells, as well as eliminating the most complex accidents, more than a hundred standard sizes of downhole cutting and destructive tools are used. Currently, an acute shortage of this equipment in oilfield facilities makes it necessary to reconsider the technologies for restoring downhole cutting and destructive tools and introduce them into production. The conducted studies show that there is not enough information about the thickness and height of the layers of the material applied to the damaged area of the cutting and destructive tool, as well as the information necessary for the optimal mode of its operation and its effectiveness after restoration. Composite materials are widely used in the preparation of cutting-chopping and destructive elements of oil-field tools and equipment used in the drilling, operation and repair of wells. In order to increase the cutting capacity of the cutting part of the tool, it is necessary to investigate the advantages of tungsten-carbide (TC) type composite materials compared to other materials and ensure their resistance to high temperatures. As a result of theoretical studies, the stress-deformation state of the contact areas of the composite elements, where the working areas of the cutting and destructive tools are reinforced, and the dependence of the productivity of the composite materials on the speed of transition to metal and the sizes of the composite grains were determined by using the finite element method (two-dimensional simplex elements).","PeriodicalId":45266,"journal":{"name":"Nafta-Gaz","volume":null,"pages":null},"PeriodicalIF":0.5,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140520676","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Od kilku lat na całym świecie bardzo często poruszane są zagadnienia dotyczące emisji dwutlenku węgla do środowiska oraz problemów z tym związanych. Niektóre kraje postanowiły stanąć do walki i szukać sposobów na zmniejszenie ilości produkowanego dwutlenku węgla i ewentualnej możliwości jego bezpiecznego składowania. Zanieczyszczenie środowiska oraz wzrost emisji dwutlenku węgla do atmosfery stanowią obecnie główne problemy dotyczące gospodarki światowej, a w szczególności krajowej. Jednym ze sposobów składowania CO2 jest jego sekwestracja, czyli podziemne składowanie i deponowanie w strukturach geologicznych, między innymi w wyeksploatowanych złożach ropy i gazu oraz poziomach solankowych. Kolejnym sposobem może być zatłaczanie dwutlenku węgla do złoża ropy, co stanowi jedną z efektywniejszych metod wspomagania wydobycia. W naszym kraju na najbliższe lata planuje się wiercenia otworów przeznaczonych do sekwestracji dwutlenku węgla. Do cementowania tych otworów powinny być użyte zaczyny uszczelniające, które wykazują podwyższoną odporność na działanie CO2 oraz odpowiednio niskie porowatość i przepuszczalność. Przemysł naftowy w Polsce do uszczelniania kolumn rur okładzinowych stosuje konwencjonalne zaczyny cementowe na bazie cementu portlandzkiego A-42,5R lub wiertniczego „G” wraz z innymi składnikami regulującymi parametry zaczynów i stwardniałych zaczynów cementowych. Powszechnie stosowane w otworach wiertniczych zaczyny uszczelniające mogą ulegać korozji węglanowej, dlatego konieczne jest prowadzenie badań oraz analiza oddziaływania CO2 nie tylko na zmianę parametrów mechanicznych stwardniałych zaczynów, ale również na zmiany struktury porowej stwardniałych zaczynów i ich szczelności w czasie. Celem badań była analiza wpływu korozji węglanowej na zmianę struktury porowej oraz przepuszczalności dla gazu stwardniałych zaczynów cementowych w funkcji czasu ich sezonowania. Badaniom laboratoryjnym poddano stwardniałe zaczyny cementowe wykonane według receptur powszechnie stosowanych w przemyśle naftowym podczas uszczelniania kolumn rur okładzinowych w temperaturach od 60°C do 80°C. Próbki stwardniałych zaczynów cementowych przetrzymywano w wodzie wodociągowej i analogicznie sezonowano w wodzie nasyconej CO2 oraz poddawano badaniom po upływie założonego czasu. Analizowany był wpływ dwutlenku węgla na zmiany przepuszczalności dla gazu i porowatości stwardniałych zaczynów cementowych w funkcji czasu ich sezonowania. Przeprowadzone badania ukazały wpływ korozji węglanowej na strukturę stwardniałych zaczynów cementowych oraz na zmiany szczelności płaszcza cementowego w czasie oraz możliwości ich zastosowania w wyeksploatowanych złożach ropy i gazu przeznaczonych do składowania dwutlenku węgla. Z wybranych receptur zaczynów cementowych sporządzono próbki stwardniałych zaczynów cementowych. Zaczyny cementowe wiązały przez 48 godzin w ustalonej temperaturze i ciśnieniu (warunki otworopodobne). Otrzymane próbki stwardniałego zaczynu cementowego poddano bada
{"title":"Wpływ korozji węglanowej na szczelność kamieni cementowych w otworach przeznaczonych do sekwestracji","authors":"Ł. Kut","doi":"10.18668/ng.2024.01.02","DOIUrl":"https://doi.org/10.18668/ng.2024.01.02","url":null,"abstract":"Od kilku lat na całym świecie bardzo często poruszane są zagadnienia dotyczące emisji dwutlenku węgla do środowiska oraz problemów z tym związanych. Niektóre kraje postanowiły stanąć do walki i szukać sposobów na zmniejszenie ilości produkowanego dwutlenku węgla i ewentualnej możliwości jego bezpiecznego składowania. Zanieczyszczenie środowiska oraz wzrost emisji dwutlenku węgla do atmosfery stanowią obecnie główne problemy dotyczące gospodarki światowej, a w szczególności krajowej. Jednym ze sposobów składowania CO2 jest jego sekwestracja, czyli podziemne składowanie i deponowanie w strukturach geologicznych, między innymi w wyeksploatowanych złożach ropy i gazu oraz poziomach solankowych. Kolejnym sposobem może być zatłaczanie dwutlenku węgla do złoża ropy, co stanowi jedną z efektywniejszych metod wspomagania wydobycia. W naszym kraju na najbliższe lata planuje się wiercenia otworów przeznaczonych do sekwestracji dwutlenku węgla. Do cementowania tych otworów powinny być użyte zaczyny uszczelniające, które wykazują podwyższoną odporność na działanie CO2 oraz odpowiednio niskie porowatość i przepuszczalność. Przemysł naftowy w Polsce do uszczelniania kolumn rur okładzinowych stosuje konwencjonalne zaczyny cementowe na bazie cementu portlandzkiego A-42,5R lub wiertniczego „G” wraz z innymi składnikami regulującymi parametry zaczynów i stwardniałych zaczynów cementowych. Powszechnie stosowane w otworach wiertniczych zaczyny uszczelniające mogą ulegać korozji węglanowej, dlatego konieczne jest prowadzenie badań oraz analiza oddziaływania CO2 nie tylko na zmianę parametrów mechanicznych stwardniałych zaczynów, ale również na zmiany struktury porowej stwardniałych zaczynów i ich szczelności w czasie. Celem badań była analiza wpływu korozji węglanowej na zmianę struktury porowej oraz przepuszczalności dla gazu stwardniałych zaczynów cementowych w funkcji czasu ich sezonowania. Badaniom laboratoryjnym poddano stwardniałe zaczyny cementowe wykonane według receptur powszechnie stosowanych w przemyśle naftowym podczas uszczelniania kolumn rur okładzinowych w temperaturach od 60°C do 80°C. Próbki stwardniałych zaczynów cementowych przetrzymywano w wodzie wodociągowej i analogicznie sezonowano w wodzie nasyconej CO2 oraz poddawano badaniom po upływie założonego czasu. Analizowany był wpływ dwutlenku węgla na zmiany przepuszczalności dla gazu i porowatości stwardniałych zaczynów cementowych w funkcji czasu ich sezonowania. Przeprowadzone badania ukazały wpływ korozji węglanowej na strukturę stwardniałych zaczynów cementowych oraz na zmiany szczelności płaszcza cementowego w czasie oraz możliwości ich zastosowania w wyeksploatowanych złożach ropy i gazu przeznaczonych do składowania dwutlenku węgla. Z wybranych receptur zaczynów cementowych sporządzono próbki stwardniałych zaczynów cementowych. Zaczyny cementowe wiązały przez 48 godzin w ustalonej temperaturze i ciśnieniu (warunki otworopodobne). Otrzymane próbki stwardniałego zaczynu cementowego poddano bada","PeriodicalId":45266,"journal":{"name":"Nafta-Gaz","volume":null,"pages":null},"PeriodicalIF":0.5,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140516607","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
For the first time, the impact of the composition of gossypol resin and IB-1 reagent, prepared in a 3:1 ratio and conventionally named HS-1, on the corrosion rate in hydrogen sulfide formation water has been investigated under laboratory conditions. Concentrations of 20, 40, 60, 80 mg/l of the new composition were used. During the experiments, a formation water sample taken from well No. 1082 of “Bibiheybatneft” OGPD, SOCAR, served as the electrochemical corrosion medium for the study. To conduct a comparative analysis, gossypol resin, IB-1 inhibitor, and HS-1 composition were used. Concentrations of 50, 100, 150, 200 mg/l of gossypol resin and 10, 15, 20, and 25 mg/l of IB-1 inhibitor were employed in the experiments. Numerous laboratory experiments revealed that the optimal consumption rate for the HS-1 inhibitor is 100 mg/l, for gossypol resin it is 200 mg/l, and for the IB-1 inhibitor it is 25 mg/l. These experiments were conducted under dynamic conditions over six hours. It was determined that the newly developed HS-1 composition offers superior protection in an aggressive medium containing hydrogen sulfide compared to its constituent components, gossypol resin, and IB-1 inhibitor. Specifically, as the concentration of gossypol resin in formation water increases from 50 to 200 mg/l, the corrosion protection effect ranges from 60–82%. When the concentration of IB-1 inhibitor varies between 10–25 mg/l in a hydrogen sulfide medium, the protection effect lies between 65-90%. In the aggressive medium of hydrogen sulfide formation water, increasing the concentration of the new HS-1 composition from 30–80 mg/l results in an enhancement of its electrochemical corrosion protection effect, ranging from 74–98%. Upon analyzing the results of numerous laboratory experiments, it was found that the optimal consumption rate of gossypol resin for corrosion protection in an aggressive medium with hydrogen sulfide is 200 mg/l, the consumption rate of IB-1 inhibitor is 25 mg/l, and for the HS-1 composition is 80 mg/l. The corrosion rates for gossypol resin in the concentrations of 50, 100, 150, 200 mg/l is 1.72, 1.38, 1.12, 0.78 g/m2 · h and retardation coefficient is 2.50, 3.10, 3.84, 5.51, respectively. Corrosion rate of IB-1 inhibitor concentration in the amount of 10, 15, 20, and 25 mg/l is 1.5, 1.12, 0.78, 0.43, and retardation coefficient is 2.86, 3.84, 5.51, 10.0, respectively. The corrosion rates for the new HS-1 composition at concentrations of 20, 40, 60, 80 mg/l is 1.12, 0.73, 0.34, 0.08, and the retardation coefficient is 3.84, 5.89, 12.64, 53.75, respectively. Comparing the corrosion rate values obtained for all three reagents with the corrosion rate for hydrogen sulphide formation water shows that new HS-1 composition has a higher effectiveness compared to its constituent components.
{"title":"The inhibitory effect of selected reagents on carbon steel corrosion in formation water containing hydrogen sulfid","authors":"Guseyn R. Gurbanov, S. Pashayeva","doi":"10.18668/ng.2024.01.07","DOIUrl":"https://doi.org/10.18668/ng.2024.01.07","url":null,"abstract":"For the first time, the impact of the composition of gossypol resin and IB-1 reagent, prepared in a 3:1 ratio and conventionally named HS-1, on the corrosion rate in hydrogen sulfide formation water has been investigated under laboratory conditions. Concentrations of 20, 40, 60, 80 mg/l of the new composition were used. During the experiments, a formation water sample taken from well No. 1082 of “Bibiheybatneft” OGPD, SOCAR, served as the electrochemical corrosion medium for the study. To conduct a comparative analysis, gossypol resin, IB-1 inhibitor, and HS-1 composition were used. Concentrations of 50, 100, 150, 200 mg/l of gossypol resin and 10, 15, 20, and 25 mg/l of IB-1 inhibitor were employed in the experiments. Numerous laboratory experiments revealed that the optimal consumption rate for the HS-1 inhibitor is 100 mg/l, for gossypol resin it is 200 mg/l, and for the IB-1 inhibitor it is 25 mg/l. These experiments were conducted under dynamic conditions over six hours. It was determined that the newly developed HS-1 composition offers superior protection in an aggressive medium containing hydrogen sulfide compared to its constituent components, gossypol resin, and IB-1 inhibitor. Specifically, as the concentration of gossypol resin in formation water increases from 50 to 200 mg/l, the corrosion protection effect ranges from 60–82%. When the concentration of IB-1 inhibitor varies between 10–25 mg/l in a hydrogen sulfide medium, the protection effect lies between 65-90%. In the aggressive medium of hydrogen sulfide formation water, increasing the concentration of the new HS-1 composition from 30–80 mg/l results in an enhancement of its electrochemical corrosion protection effect, ranging from 74–98%. Upon analyzing the results of numerous laboratory experiments, it was found that the optimal consumption rate of gossypol resin for corrosion protection in an aggressive medium with hydrogen sulfide is 200 mg/l, the consumption rate of IB-1 inhibitor is 25 mg/l, and for the HS-1 composition is 80 mg/l. The corrosion rates for gossypol resin in the concentrations of 50, 100, 150, 200 mg/l is 1.72, 1.38, 1.12, 0.78 g/m2 · h and retardation coefficient is 2.50, 3.10, 3.84, 5.51, respectively. Corrosion rate of IB-1 inhibitor concentration in the amount of 10, 15, 20, and 25 mg/l is 1.5, 1.12, 0.78, 0.43, and retardation coefficient is 2.86, 3.84, 5.51, 10.0, respectively. The corrosion rates for the new HS-1 composition at concentrations of 20, 40, 60, 80 mg/l is 1.12, 0.73, 0.34, 0.08, and the retardation coefficient is 3.84, 5.89, 12.64, 53.75, respectively. Comparing the corrosion rate values obtained for all three reagents with the corrosion rate for hydrogen sulphide formation water shows that new HS-1 composition has a higher effectiveness compared to its constituent components.","PeriodicalId":45266,"journal":{"name":"Nafta-Gaz","volume":null,"pages":null},"PeriodicalIF":0.5,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140525343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
E. Iskenderov, Alovsat N. Baghirov, Lala M. Shikhiyeva
The article deals with the issues of assessing the conditions of hydrate formation when mixing natural gas flows of various standards. An urgent problem of operation, especially of offshore subsea gas pipelines, is the prediction of the time, place and expected intensity of hydrate formation. Depending on the changing operating mode of the gas pipeline, dispatch service specialists must be able to adjust the process control tactics on their own, as quickly as possible. The predisposition of a particular gas pipeline to hydrate is also important for the dispatching service. Changes in the volumes of gas entering the region under consideration from different sources, due to the constant change in gas production, create the need to mix gases of different standards and pump them into subsea gas pipeline. To avoid hydrate formation, it is important to predict the thermobaric conditions that will be formed in the gas pipeline by considering the characteristics such as a volume in the mixture and the moisture content of the gas. The processes of hydrate formation proceed quickly and if the beginning of the process is overlooked, the problem of significant or complete blockage of the gas pipeline might appear. The paper gives a systematization of the risk of hydrate formation depending on several infrastructural factors – the presence of a preliminary gas drying system and a system for starting and receiving cleaning pistons. A method is proposed for estimating the moisture content and dew point temperature of a natural gas mixture by the condition and the proportion of primary flows. It has been shown that the addition of a small volume of undried gas to the main dried gas significantly increases the risk of hydrate formation. A formula is given for calculations for a mixture of multiple natural gas flows. The advantage of this method is the quick calculations, and the absence of the need for huge mathematical calculations and laboratory studies. This is an important element in the activities of the dispatch service, limited by a lack of time in the process of preventing hydrate formation.
{"title":"Method for assessing the hydrate formation from a mixture of natural gas flows of varying degrees of moisture content","authors":"E. Iskenderov, Alovsat N. Baghirov, Lala M. Shikhiyeva","doi":"10.18668/ng.2024.01.05","DOIUrl":"https://doi.org/10.18668/ng.2024.01.05","url":null,"abstract":"The article deals with the issues of assessing the conditions of hydrate formation when mixing natural gas flows of various standards. An urgent problem of operation, especially of offshore subsea gas pipelines, is the prediction of the time, place and expected intensity of hydrate formation. Depending on the changing operating mode of the gas pipeline, dispatch service specialists must be able to adjust the process control tactics on their own, as quickly as possible. The predisposition of a particular gas pipeline to hydrate is also important for the dispatching service. Changes in the volumes of gas entering the region under consideration from different sources, due to the constant change in gas production, create the need to mix gases of different standards and pump them into subsea gas pipeline. To avoid hydrate formation, it is important to predict the thermobaric conditions that will be formed in the gas pipeline by considering the characteristics such as a volume in the mixture and the moisture content of the gas. The processes of hydrate formation proceed quickly and if the beginning of the process is overlooked, the problem of significant or complete blockage of the gas pipeline might appear. The paper gives a systematization of the risk of hydrate formation depending on several infrastructural factors – the presence of a preliminary gas drying system and a system for starting and receiving cleaning pistons. A method is proposed for estimating the moisture content and dew point temperature of a natural gas mixture by the condition and the proportion of primary flows. It has been shown that the addition of a small volume of undried gas to the main dried gas significantly increases the risk of hydrate formation. A formula is given for calculations for a mixture of multiple natural gas flows. The advantage of this method is the quick calculations, and the absence of the need for huge mathematical calculations and laboratory studies. This is an important element in the activities of the dispatch service, limited by a lack of time in the process of preventing hydrate formation.","PeriodicalId":45266,"journal":{"name":"Nafta-Gaz","volume":null,"pages":null},"PeriodicalIF":0.5,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140527152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The article presents the use of mathematical statistics to determine controllable factors that influence the coefficient of friction in a dual-flow three-stage spur gear transmission of a newly designed sucker rod pumping unit. The load acting on the bearing units, the rotational speed of the main and auxiliary shafts, and the diametrical gap between the shaft and the bushing were assessed through tests. The tests were carried out in random order. The multivariate testing was used to determine the number of tests to be performed as well as the test conditions in order to achieve the required accuracy bushing. In the statistical analysis of the results, the Cochrane criterion was applied to verify the homogeneity of the variance values. Student's t-test was used to verify the significance of the coefficients included in the regression equation, Fisher’s F-test was used to determine the suitability of the adopted output function for describing the real object of study, i.e., the adequacy of the model, and sensitivity coefficients were used to assess the influence of the corresponding parameters on the optimization parameter. The analysis also considered the dispersion of optimization parameters, measurement repeatability, and errors in the model coefficients. Experimental values of the criteria, along with the dispersion of the adequacy and repeatability of the mathematical model, were evaluated to determine whether the model is fully suitable for the object of study. The impact of significant factors and their combinations, as well as their critical values, were assessed by comparing calculated values of the criteria. The significance or insignificance of the corresponding coefficients of the regression equation was determined. To investigate the impact of these controlled factors — load, rotational speed of the main and auxiliary shafts, and the diametrical gap between the auxiliary shaft and the bushing — on the sliding friction coefficient, a modernized device was developed. This device simulates the operating conditions of a double friction sliding bearing in a dual-flow, three-stage spur gearbox bushing. The experiments were conducted using I-40A industrial oil at room temperature. It has been determined that these factors significantly impact the coefficient of friction in a double friction bearing. Consequently, it is necessary to calculate their limit values to ensure the bearing assembly operates without failure during the required service life. Compared to other examined parameters, the optimization parameter, i.e., the coefficient of friction, is most significantly influenced by the diametrical gap between the auxiliary shaft and the bushing, and least affected by the magnitude of the load acting on the bearing assembly. The overall impact of controlled factors on the coefficient of friction is minimal. Employing the test planning method, a mathematical formula was derived, enabling the determination of the coefficient of friction in a
文章介绍了利用数理统计确定影响新设计的抽油杆抽油机双流三级正齿轮传动装置摩擦系数的可控因素。通过试验评估了作用在轴承单元上的载荷、主轴和辅轴的转速以及轴与衬套之间的直径间隙。测试以随机顺序进行。多变量测试用于确定测试次数和测试条件，以达到所需的衬套精度。在对结果进行统计分析时，采用了科克伦标准来验证方差值的均匀性。学生 t 检验用于验证回归方程中系数的显著性，费雪 F 检验用于确定所采用的输出函数是否适合描述实际研究对象，即模型的适当性，敏感性系数用于评估相应参数对优化参数的影响。分析还考虑了优化参数的分散性、测量的可重复性和模型系数的误差。对标准的实验值以及数学模型的充分性和可重复性的分散性进行了评估，以确定模型是否完全适合研究对象。通过比较标准的计算值，评估了重要因素及其组合的影响以及临界值。确定了回归方程中相应系数的显著性或不显著性。为了研究负载、主轴和辅助轴的转速以及辅助轴和衬套之间的直径间隙这些受控因素对滑动摩擦系数的影响，开发了一种现代化的装置。该装置模拟了双流三级正齿轮箱衬套中双摩擦滑动轴承的工作条件。实验使用室温下的 I-40A 工业油进行。实验确定，这些因素对双摩擦轴承的摩擦系数有重大影响。因此，有必要计算它们的极限值，以确保轴承组件在规定的使用寿命内无故障运行。与其他检查参数相比，优化参数（即摩擦系数）受辅助轴和衬套之间直径间隙的影响最大，而受作用在轴承组件上的载荷大小的影响最小。受控因素对摩擦系数的总体影响很小。利用测试规划方法，推导出了一个数学公式，无需在接触参数的极限衬套值范围内进行额外测试，即可确定双滑动摩擦轴承的摩擦系数。
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Artykuł przedstawia wyniki badań nad doszczelnieniem matrycy kamieni cementowych otrzymanych z zaczynów cementowych przeznaczonych do podziemnych magazynów wodoru w kawernach solnych. W recepturach zaczynów cementowych została zwiększona ilość dodatku mikrocementu oraz podjęto próbę zastosowania wybranych rodzajów nanomateriałów. Receptury cementowe opracowane zostały w INiG – PIB w Laboratorium Zaczynów Uszczelniających. Badania przeprowadzono dla temperatury 25°C i ciśnienia 10 MPa. W badanych zaczynach cementowych jako spoiwo wiążące zastosowano cement wiertniczy G. Zaczyny cementowe sporządzano na solance o pełnym nasyceniu o gęstości 1200 kg/m3 ze względu na bezpośrednią obecność soli w otworze. Do solanki dodawano kolejno środki: odpieniający, upłynniający i obniżający filtrację oraz nanomateriały. Pozostałe składniki: mikrocement, gips modelowy oraz cement mieszano ze sobą i wprowadzano następnie do wody zarobowej. W przypadku każdego zaczynu cementowego wykonywano badania parametrów technologicznych takich jak: właściwości reologiczne, gęstość, rozlewność, odstój wody oraz czas gęstnienia zaczynu. Przeprowadzano również badania wytrzymałości na ściskanie po 7 dniach oraz po 1 i 6 miesiącach, a także pomiar porowatości stwardniałych zaczynów cementowych po 6 miesiącach deponowania w pełni nasyconej solance. Opracowane zaczyny cementowe charakteryzowały się dobrymi parametrami reologicznymi oraz zerowym odstojem wody. Gęstości zaczynów cementowych wahały się w przedziale od 1910 kg/m3 do 1940 kg/m3. Wszystkie zbadane stwardniałe zaczyny cementowe charakteryzowały się zwartą mikrostrukturą o niskiej zawartości makroporów. Udział porów o średnicy powyżej 10 000 nm wyniósł od 1,3% do 3,2% ilości wszystkich porów. Natomiast udział porów o średnicy poniżej 100 nm w całej matrycy stwardniałego zaczynu cementowego wyniósł od 94,3% do 97,5%. Dodatek większej ilości mikrocementu oraz wprowadzenie nanokomponentów do receptur zaczynów cementowych spowodowały wzrost wytrzymałości na ściskanie oraz obniżenie porowatości kamieni cementowych.
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