B. Filar, T. Kwilosz, M. Miziołek, Agnieszka Moska
Zatwierdzona 2 lutego 2021 r. Polityka energetyczna Polski do 2040 r. (PEP2040) zakłada duży wzrost udziału energii pochodzącej z OZE we wszystkich sektorach gospodarki. Zgodnie z prognozą w 2030 r. udział OZE w końcowym zużyciu energii brutto powinien wynieść co najmniej 23%. Projekt PEP2040 zakłada rozwój energetyki wiatrowej i fotowoltaicznej, co wpłynie na wzrost zainstalowanej mocy elektrowni wiatrowych do około 8–11 GW oraz fotowoltaicznych do około 10–16 GW. Zgodnie z danymi publikowanymi przez Rynek Elektryczny sumaryczna moc zainstalowanych OZE w Polsce na koniec sierpnia 2022 r. osiągnęła 20,9 GW. Należy podkreślić, że sumaryczna moc zainstalowana w całej polskiej energetyce (OZE i konwencjonalna) w sierpniu 2022 r. wynosiła 59 GW. Spośród elektrowni OZE największy udział miała fotowoltaika (11 GW), co stanowiło 19,2% ogółu zainstalowanych mocy. Natomiast sumaryczna moc elektrowni wiatrowych wynosiła 7,7 GW (13,3%). W publikacji podkreślono również, że w 2022 r. moc zainstalowanej fotowoltaiki wzrosła w porównaniu z rokiem 2021 o 84%, a elektrowni wiatrowych – o 12,7%. Powodem szybkiego rozwoju OZE jest duży wzrost ceny konwencjonalnych nośników energii (paliwa kopalne), który wpłynął na wzrost ceny energii elektrycznej. W czerwcu 2022 r. cena kontraktów na dostawy energii elektrycznej wynosiła około 884,68 PLN/MWh. Dla porównania cena referencyjna energii elektrycznej produkowanej w elektrowniach wiatrowych, na podstawie wyników aukcji przeprowadzonej przez Prezesa Urzędu Regulacji Energetyki z grudnia 2021 r., wyniosła 250 PLN/MWh. Niestety produkcja prądu przez elektrownię wiatrową zależy od siły wiatru i cechuje się bardzo dużą zmiennością, często zmienia się z godziny na godzinę. Przykładowo w nocy elektrownie mogą pracować z mocą ponad 5 GW, a po południu wykorzystanie ich mocy będzie poniżej 1 GW. W związku z tym, że produkcja energii z OZE jest wysoce niestabilna, to jej nadwyżki powinny zostać zmagazynowane. Głównym celem publikacji jest określenie ilości wodoru, jaka może zostać wyprodukowana z nadwyżek energii pochodzących z elektrowni wiatrowej.
{"title":"Wykorzystanie energii pochodzącej z farm wiatrowych do produkcji zielonego wodoru","authors":"B. Filar, T. Kwilosz, M. Miziołek, Agnieszka Moska","doi":"10.18668/ng.2023.11.03","DOIUrl":"https://doi.org/10.18668/ng.2023.11.03","url":null,"abstract":"Zatwierdzona 2 lutego 2021 r. Polityka energetyczna Polski do 2040 r. (PEP2040) zakłada duży wzrost udziału energii pochodzącej z OZE we wszystkich sektorach gospodarki. Zgodnie z prognozą w 2030 r. udział OZE w końcowym zużyciu energii brutto powinien wynieść co najmniej 23%. Projekt PEP2040 zakłada rozwój energetyki wiatrowej i fotowoltaicznej, co wpłynie na wzrost zainstalowanej mocy elektrowni wiatrowych do około 8–11 GW oraz fotowoltaicznych do około 10–16 GW. Zgodnie z danymi publikowanymi przez Rynek Elektryczny sumaryczna moc zainstalowanych OZE w Polsce na koniec sierpnia 2022 r. osiągnęła 20,9 GW. Należy podkreślić, że sumaryczna moc zainstalowana w całej polskiej energetyce (OZE i konwencjonalna) w sierpniu 2022 r. wynosiła 59 GW. Spośród elektrowni OZE największy udział miała fotowoltaika (11 GW), co stanowiło 19,2% ogółu zainstalowanych mocy. Natomiast sumaryczna moc elektrowni wiatrowych wynosiła 7,7 GW (13,3%). W publikacji podkreślono również, że w 2022 r. moc zainstalowanej fotowoltaiki wzrosła w porównaniu z rokiem 2021 o 84%, a elektrowni wiatrowych – o 12,7%. Powodem szybkiego rozwoju OZE jest duży wzrost ceny konwencjonalnych nośników energii (paliwa kopalne), który wpłynął na wzrost ceny energii elektrycznej. W czerwcu 2022 r. cena kontraktów na dostawy energii elektrycznej wynosiła około 884,68 PLN/MWh. Dla porównania cena referencyjna energii elektrycznej produkowanej w elektrowniach wiatrowych, na podstawie wyników aukcji przeprowadzonej przez Prezesa Urzędu Regulacji Energetyki z grudnia 2021 r., wyniosła 250 PLN/MWh. Niestety produkcja prądu przez elektrownię wiatrową zależy od siły wiatru i cechuje się bardzo dużą zmiennością, często zmienia się z godziny na godzinę. Przykładowo w nocy elektrownie mogą pracować z mocą ponad 5 GW, a po południu wykorzystanie ich mocy będzie poniżej 1 GW. W związku z tym, że produkcja energii z OZE jest wysoce niestabilna, to jej nadwyżki powinny zostać zmagazynowane. Głównym celem publikacji jest określenie ilości wodoru, jaka może zostać wyprodukowana z nadwyżek energii pochodzących z elektrowni wiatrowej.","PeriodicalId":45266,"journal":{"name":"Nafta-Gaz","volume":"26 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139301964","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Gasim A. Mamedov, Rauf Kh. Melikov, Natig M. Abbasov, M. S. Rahimova
In the article, a multi-phase (non-homogeneous, heterogeneous) medium is considered as a macrosystem (continuum) composed of several (at least two) phases, such as a carrier phase (liquid, vapor or gas) and a carried phase (solid particles, bubbles or drops).The masses and mixtures of these phases undergo continuous changes over time due to the addition or separation of new masses to or from both phases. The model takes into account interphase transitions, discontinuities inside the mixture, and the possibility of phases being either continuous or discrete, depending on their location. A method for preliminary smoothing of discontinuities has been developed, leveraging the fact that the location in space, as well as the shape and size of the discrete phase are random. A function, denoted as φi (x, y, z, t), has been introduced, which indicates the probability of the presence of the i-th phase in the vicinity of a given point in space at time t, or that the given point of space x, y, z at time t belongs to the set of points of the i-th phase. On the other hand, this probability can be interpreted as the volumetric concentration of the i-th phase at a given point in space (i.e., the ratio of the measure of the set of points belonging to the i-th phase in the vicinity of the point under consideration at time t to the measure of the entire set of points in the surrounding area). This hypothetical medium, being equivalent to the original one, serves as a model for a multi-phase (inhomogeneous, heterogeneous, two-phase) medium. The uniqueness of the model arises from its construction. In addition, this paper considers several main areas of theoretical and experimental research concerning the hydrodynamics of a multi-phase (two-phase suspension-carrying) flow of a continuous medium. It also discusses the most important results achieved in existing works. A critical analysis of known theories for mathematically describing the motion of multi-phase (two-phase) systems and methods for averaging the hydrodynamic characteristics of a turbulent flow are given. The procedure for closing the equations systems of hydromechanics of multi-phase flows proposed in existing works is carried out within the framework of semi-empirical theories of turbulence. In nature, the vast majority of multi-phase (two-phase, inhomogeneous) mixtures exhibit turbulent behavior, making its study a crucial practical task. The mathematical description of the motion of a turbulent multi-phase flow relies on stylized laws of mechanics. The methods of operational analysis proposed at various times by different researchers for the mathematical description of the motion of a multi-phase (two-phase) flow have varying degrees of approximation and certain limited areas of application. One of the main challenges in formulating differential equations for the motion of a turbulent multi-phase (two-phase, suspension-carrying) flow is the fact that in a turbulent flow of a mixture, where the charac
在文章中，多相（非均相、异相）介质被视为一个宏观系统（连续体），由若干相（至少两相）组成，例如载体相（液体、蒸汽或气体）和承载相（固体颗粒、气泡或液滴）。由于新质量的加入或分离，这些相的质量和混合物会随时间发生连续变化。该模型考虑到了相间转换、混合物内部的不连续性，以及各相根据其位置成为连续或离散相的可能性。利用离散相在空间中的位置、形状和大小都是随机的这一事实，开发了一种初步平滑不连续性的方法。我们引入了一个函数φi (x, y, z, t)，表示第 i 个相位在时间 t 空间给定点附近出现的概率，或时间 t 空间 x、y、z 给定点属于第 i 个相位点集合的概率。另一方面，这种概率也可以解释为第 i 相在空间给定点上的体积浓度（即在时间 t 时，在所考虑的点附近属于第 i 相的点集的测量值与周围区域整个点集的测量值之比）。这种假设介质等同于原始介质，可作为多相（非均质、异相、两相）介质的模型。模型的唯一性源于其构造。此外，本文还探讨了有关连续介质的多相（两相悬浮液携带）流体力学的几个主要理论和实验研究领域。本文还讨论了现有研究中取得的最重要成果。对多相（两相）系统运动数学描述的已知理论和湍流流体力学特征的平均方法进行了批判性分析。在半经验湍流理论的框架内，对现有著作中提出的多相流流体力学方程组进行了闭合。在自然界中，绝大多数多相（两相、不均匀）混合物都表现出湍流行为，因此对其进行研究是一项重要的实际任务。湍流多相流运动的数学描述依赖于定型的力学定律。对于多相（两相）流运动的数学描述，不同研究人员在不同时期提出的运算分析方法具有不同程度的近似性和某些有限的应用领域。为湍流多相（两相、携带悬浮物）流的运动制定微分方程的主要挑战之一是，在混合物的湍流中，流动特性随时间随机发生混沌变化，在空间的每一点上，无论在大小还是方向上，都存在着具有弱不连续性和强不连续性的表面。因此，严格来说，多相流的实际速度和压力值不能被视为混合物所占整个区域的空间和时间坐标的连续函数。
{"title":"Derivation of phenomenological equations of hydromechanics of multi-phase flows","authors":"Gasim A. Mamedov, Rauf Kh. Melikov, Natig M. Abbasov, M. S. Rahimova","doi":"10.18668/ng.2023.11.06","DOIUrl":"https://doi.org/10.18668/ng.2023.11.06","url":null,"abstract":"In the article, a multi-phase (non-homogeneous, heterogeneous) medium is considered as a macrosystem (continuum) composed of several (at least two) phases, such as a carrier phase (liquid, vapor or gas) and a carried phase (solid particles, bubbles or drops).The masses and mixtures of these phases undergo continuous changes over time due to the addition or separation of new masses to or from both phases. The model takes into account interphase transitions, discontinuities inside the mixture, and the possibility of phases being either continuous or discrete, depending on their location. A method for preliminary smoothing of discontinuities has been developed, leveraging the fact that the location in space, as well as the shape and size of the discrete phase are random. A function, denoted as φi (x, y, z, t), has been introduced, which indicates the probability of the presence of the i-th phase in the vicinity of a given point in space at time t, or that the given point of space x, y, z at time t belongs to the set of points of the i-th phase. On the other hand, this probability can be interpreted as the volumetric concentration of the i-th phase at a given point in space (i.e., the ratio of the measure of the set of points belonging to the i-th phase in the vicinity of the point under consideration at time t to the measure of the entire set of points in the surrounding area). This hypothetical medium, being equivalent to the original one, serves as a model for a multi-phase (inhomogeneous, heterogeneous, two-phase) medium. The uniqueness of the model arises from its construction. In addition, this paper considers several main areas of theoretical and experimental research concerning the hydrodynamics of a multi-phase (two-phase suspension-carrying) flow of a continuous medium. It also discusses the most important results achieved in existing works. A critical analysis of known theories for mathematically describing the motion of multi-phase (two-phase) systems and methods for averaging the hydrodynamic characteristics of a turbulent flow are given. The procedure for closing the equations systems of hydromechanics of multi-phase flows proposed in existing works is carried out within the framework of semi-empirical theories of turbulence. In nature, the vast majority of multi-phase (two-phase, inhomogeneous) mixtures exhibit turbulent behavior, making its study a crucial practical task. The mathematical description of the motion of a turbulent multi-phase flow relies on stylized laws of mechanics. The methods of operational analysis proposed at various times by different researchers for the mathematical description of the motion of a multi-phase (two-phase) flow have varying degrees of approximation and certain limited areas of application. One of the main challenges in formulating differential equations for the motion of a turbulent multi-phase (two-phase, suspension-carrying) flow is the fact that in a turbulent flow of a mixture, where the charac","PeriodicalId":45266,"journal":{"name":"Nafta-Gaz","volume":"42 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139302519","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The paper discusses the mathematical model of hydromechanics of multiphase flows with varying mass. A multiphase flow is considered a continuum consisting of a set of a large number of different groups of particles. The derivation of motion equations and similarity criteria are given taking into account both the externally attached (or detached) mass and phase transitions within the medium. The equations of mass, momentum and energy transfer for individual phases and the medium as a whole are derived based on fundamental conservation laws. It was demonstrated that in the absence of sources (or flow-offs) of mass, momentum and energy, the known equations of single- and multi-phase flow hydromechanics follow as a special case from the obtained systems of motion equations and similarity criteria. The obtained motion equations are valid for the description of an ingredient of mixture and the medium as a whole, regardless of their physical and mechanical properties. Thermodynamic and rheological state equations, as well as expressions for heat flow, interfacial mass forces phase transitions, and heat exchange between phases can be used to close them. The implemented models make it possible to simulate both the stationary distribution of parameters along the wellbore during production and non-stationary processes that occur, for example, when the pump shaft speed changes during oil production. The developed approaches were implemented in the DataFlow software tool for analysis of the hydrodynamics of multiphase hydrocarbon flows, taking into account heat exchange with the rocks surrounding the well, and phase transitions in the fluid. Using the software package, test calculations were carried out to demonstrate the performance of the proposed and implemented models.
{"title":"Mathematical models of hydromechanics of multiphase flow with varying mass","authors":"Gasim A. Mamedov, Natiq M. Abbasov","doi":"10.18668/ng.2023.11.02","DOIUrl":"https://doi.org/10.18668/ng.2023.11.02","url":null,"abstract":"The paper discusses the mathematical model of hydromechanics of multiphase flows with varying mass. A multiphase flow is considered a continuum consisting of a set of a large number of different groups of particles. The derivation of motion equations and similarity criteria are given taking into account both the externally attached (or detached) mass and phase transitions within the medium. The equations of mass, momentum and energy transfer for individual phases and the medium as a whole are derived based on fundamental conservation laws. It was demonstrated that in the absence of sources (or flow-offs) of mass, momentum and energy, the known equations of single- and multi-phase flow hydromechanics follow as a special case from the obtained systems of motion equations and similarity criteria. The obtained motion equations are valid for the description of an ingredient of mixture and the medium as a whole, regardless of their physical and mechanical properties. Thermodynamic and rheological state equations, as well as expressions for heat flow, interfacial mass forces phase transitions, and heat exchange between phases can be used to close them. The implemented models make it possible to simulate both the stationary distribution of parameters along the wellbore during production and non-stationary processes that occur, for example, when the pump shaft speed changes during oil production. The developed approaches were implemented in the DataFlow software tool for analysis of the hydrodynamics of multiphase hydrocarbon flows, taking into account heat exchange with the rocks surrounding the well, and phase transitions in the fluid. Using the software package, test calculations were carried out to demonstrate the performance of the proposed and implemented models.","PeriodicalId":45266,"journal":{"name":"Nafta-Gaz","volume":"39 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139294633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The composition of oils is the main source of information that enables the evaluation and modeling of their physical, thermal and chemical properties (including their critical properties) across a wide range of state parameters. The more comprehensively the composition of oils is analyzed, the more precise information is provided for calculations and problem-solving in the field of oilfield mechanics and related areas, such as the extraction, preparation, transportation, and processing of oils and their fractions. The principal constituents of oils are hydrocarbons. Oils contain hydrocarbons of three homologous series: paraffins, naphthenes and aromas. In oils, there may be hydrocarbons of a mixed composition containing both naphthenic and aromatic rings. In addition to hydrocarbons, oils also contain oxygen, sulfur, nitrogen and other constituents. These compounds are the primary elements of asphaltene-resinous substances (ARS) found in oil. They are characterized by high relative densities (often exceeding 1 g/cm3), dark coloration, and relative chemical instability when exposed to elevated temperatures, oxygen, adsorbents, etc. The composition of asphaltene-resinous substances encompasses a wide range of substances. The validity of the proposed technique is justified by the observation that the data of molecular weight, Watson characteristic factor, and experimental density calculated from molar compositions should align on the same surface with a high degree of correlation. In addition, the experimental and calculated values, in terms of molecular composition, of molecular weights should lie on a straight line passing through the origin of coordinates with a slope coefficient equal to unity and exhibit high degree of correlation.
{"title":"Method for calculating the individual hydrocarbon composition from the accumulated fractional composition of oil and condensate samples","authors":"Arifa Q. Karimova","doi":"10.18668/ng.2023.11.05","DOIUrl":"https://doi.org/10.18668/ng.2023.11.05","url":null,"abstract":"The composition of oils is the main source of information that enables the evaluation and modeling of their physical, thermal and chemical properties (including their critical properties) across a wide range of state parameters. The more comprehensively the composition of oils is analyzed, the more precise information is provided for calculations and problem-solving in the field of oilfield mechanics and related areas, such as the extraction, preparation, transportation, and processing of oils and their fractions. The principal constituents of oils are hydrocarbons. Oils contain hydrocarbons of three homologous series: paraffins, naphthenes and aromas. In oils, there may be hydrocarbons of a mixed composition containing both naphthenic and aromatic rings. In addition to hydrocarbons, oils also contain oxygen, sulfur, nitrogen and other constituents. These compounds are the primary elements of asphaltene-resinous substances (ARS) found in oil. They are characterized by high relative densities (often exceeding 1 g/cm3), dark coloration, and relative chemical instability when exposed to elevated temperatures, oxygen, adsorbents, etc. The composition of asphaltene-resinous substances encompasses a wide range of substances. The validity of the proposed technique is justified by the observation that the data of molecular weight, Watson characteristic factor, and experimental density calculated from molar compositions should align on the same surface with a high degree of correlation. In addition, the experimental and calculated values, in terms of molecular composition, of molecular weights should lie on a straight line passing through the origin of coordinates with a slope coefficient equal to unity and exhibit high degree of correlation.","PeriodicalId":45266,"journal":{"name":"Nafta-Gaz","volume":"33 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139295086","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yelena Y. Shmoncheva, Gullu V. Jabbarova, Timur E. Abdulmutalibov
The review in this article focuses on various aspects of drilling extended reach (ERD) wells. Reaching extreme depths and setting world records for deviation illustrates the importance of well design and operating strategies. Studies of articles describing various locations, including Sakhalin Island in Russia and offshore Vietnam, provide insight into ERD operations. Furthermore, the challenges of drilling in specific geological conditions, such as layered sandstones and reactive clay, are considered. Particular attention is paid to issues related to wellbore instability and drilling fluid optimization. The results of technical studies highlight the key role of maintaining wellbore stability in achieving successful ERD results. The articles emphasize the importance of understanding geomechanical factors, employing optimal mud weight, lubrication, and specialized drilling fluids to counteract instability. It demonstrates that maintaining appropriate mud weights and employing specific drilling techniques are crucial for mitigating instability-related issues. The integration of mechanical and chemical approaches is advocated for effectively managing shale-related instability. The utilization of innovative materials and fluid systems is central to the successful resolution of stability-related problems. The incorporation of micronized sealing polymers in conjunction with conventional plugging materials is detailed as an effective approach to counter wellbore instability. The synergistic combination of materials, additives and mud salinity is showcased to achieve effective shale stabilization and optimize drilling time. The authors emphasize the importance of selecting the optimal composition for each well based on experience and laboratory testing and present laboratory-tested solutions that have been successfully applied in field operations. In summary, these articles collectively offer insights into a range of strategies to combat wellbore instability. They cover the use of advanced materials, innovative fluid systems, and chemical approaches to maintain wellbore stability, improve drilling efficiency, and reduce nonproductive time.
{"title":"Drilling fluids in complicated conditions: a review","authors":"Yelena Y. Shmoncheva, Gullu V. Jabbarova, Timur E. Abdulmutalibov","doi":"10.18668/ng.2023.10.03","DOIUrl":"https://doi.org/10.18668/ng.2023.10.03","url":null,"abstract":"The review in this article focuses on various aspects of drilling extended reach (ERD) wells. Reaching extreme depths and setting world records for deviation illustrates the importance of well design and operating strategies. Studies of articles describing various locations, including Sakhalin Island in Russia and offshore Vietnam, provide insight into ERD operations. Furthermore, the challenges of drilling in specific geological conditions, such as layered sandstones and reactive clay, are considered. Particular attention is paid to issues related to wellbore instability and drilling fluid optimization. The results of technical studies highlight the key role of maintaining wellbore stability in achieving successful ERD results. The articles emphasize the importance of understanding geomechanical factors, employing optimal mud weight, lubrication, and specialized drilling fluids to counteract instability. It demonstrates that maintaining appropriate mud weights and employing specific drilling techniques are crucial for mitigating instability-related issues. The integration of mechanical and chemical approaches is advocated for effectively managing shale-related instability. The utilization of innovative materials and fluid systems is central to the successful resolution of stability-related problems. The incorporation of micronized sealing polymers in conjunction with conventional plugging materials is detailed as an effective approach to counter wellbore instability. The synergistic combination of materials, additives and mud salinity is showcased to achieve effective shale stabilization and optimize drilling time. The authors emphasize the importance of selecting the optimal composition for each well based on experience and laboratory testing and present laboratory-tested solutions that have been successfully applied in field operations. In summary, these articles collectively offer insights into a range of strategies to combat wellbore instability. They cover the use of advanced materials, innovative fluid systems, and chemical approaches to maintain wellbore stability, improve drilling efficiency, and reduce nonproductive time.","PeriodicalId":45266,"journal":{"name":"Nafta-Gaz","volume":"51 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136093825","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
"Artykuł prezentuje próbę przeprowadzenia analizy chemostratygraficznej dla różnowiekowych skał budujących górotwór karpacki. W pierwszej kolejności zdecydowano się stworzyć syntetyczny profil geologiczny dla osadów występujących we wschodniej części polskich Karpat. Wykorzystane próbki, w większości piaskowce, pochodziły z głównych poziomów stratygraficznych w obrębie jednostek skolskiej i śląskiej, gdzie zidentyfikowano skały od dolnej kredy po paleocen. Ze względu na dostępność materiału badawczego do badań wytypowano próbki o udokumentowanej stratygrafii z dwóch otworów, D-1 i H-1, zwracając głównie uwagę na ich klasyfikację stratygraficzną. Następnie dla porównania wykonano profil chemostratygraficzny dla otworu Kuźmina-1. Stwierdzono obecność bardzo dużego zróżnicowania składu chemicznego pomiędzy głównymi poziomami stratygraficznymi wyróżnianymi na podstawie badań paleontologicznych w badanych otworach, co pozwoliło wyznaczać zdecydowane granice pomiędzy poszczególnymi poziomami stratygraficznymi. Możliwość stworzenia unikalnych modeli chemostratygraficznych dla czterech analizowanych poziomów stratygraficznych: kredy górnej – senonu (warstwy inoceramowe), kredy górnej / paleocenu (warstwy istebniańskie), eocenu (warstwy pstre) oraz oligocenu (warstwy krośnieńskie) potwierdziło również wykonanie diagramu klasyfikacyjnego Herrona. Największe zróżnicowanie cech chemostratygraficznych uzyskano w przypadku utworów kredowych. Wstępnie badania wykonano w laboratorium akredytowanym Actlabs, tak aby móc później przeprowadzić ewaluację wyników uzyskanych za pomocą przenośnych spektrometrów (pXRF Titan, o zakresie pomiarowym od Mg do U, oraz pXRF Tracer, który umożliwia również pomiar zawartości Na, oba aparaty firmy Bruker). Potwierdzono, że wyraźne zróżnicowanie zawartości poszczególnych pierwiastków widoczne jest zarówno dla pierwiastków głównych, jak i śladowych. Pierwiastki najbardziej diagnostyczne to Na, Mg, Fe, K, Ca, również Si, choć w tym przypadku zakres zmienności jest nieco mniejszy. W przypadku pierwiastków śladowych są to S, P, Mn, Ti, Sr, Zr, Ba, Rb i Zn, które można również analizować za pomocą przenośnych spektrometrów pXRF. Wykonane porównanie wyników składu chemicznego uzyskiwanych przenośnym spektrometrem pXRF oraz w laboratorium Actlabs wykazało, że możliwe jest wykorzystanie na większą skalę samych pomiarów spektrometrem pXRF. Dla większości pierwiastków diagnostycznych uzyskano wystarczająco precyzyjne wyniki przy wykorzystaniu przenośnych spektrometrów pXRF.
{"title":"Analiza chemostratygraficzna różnowiekowych osadów budujących górotwór karpacki","authors":"Sylwia Kowalska","doi":"10.18668/ng.2023.10.01","DOIUrl":"https://doi.org/10.18668/ng.2023.10.01","url":null,"abstract":"\"Artykuł prezentuje próbę przeprowadzenia analizy chemostratygraficznej dla różnowiekowych skał budujących górotwór karpacki. W pierwszej kolejności zdecydowano się stworzyć syntetyczny profil geologiczny dla osadów występujących we wschodniej części polskich Karpat. Wykorzystane próbki, w większości piaskowce, pochodziły z głównych poziomów stratygraficznych w obrębie jednostek skolskiej i śląskiej, gdzie zidentyfikowano skały od dolnej kredy po paleocen. Ze względu na dostępność materiału badawczego do badań wytypowano próbki o udokumentowanej stratygrafii z dwóch otworów, D-1 i H-1, zwracając głównie uwagę na ich klasyfikację stratygraficzną. Następnie dla porównania wykonano profil chemostratygraficzny dla otworu Kuźmina-1. Stwierdzono obecność bardzo dużego zróżnicowania składu chemicznego pomiędzy głównymi poziomami stratygraficznymi wyróżnianymi na podstawie badań paleontologicznych w badanych otworach, co pozwoliło wyznaczać zdecydowane granice pomiędzy poszczególnymi poziomami stratygraficznymi. Możliwość stworzenia unikalnych modeli chemostratygraficznych dla czterech analizowanych poziomów stratygraficznych: kredy górnej – senonu (warstwy inoceramowe), kredy górnej / paleocenu (warstwy istebniańskie), eocenu (warstwy pstre) oraz oligocenu (warstwy krośnieńskie) potwierdziło również wykonanie diagramu klasyfikacyjnego Herrona. Największe zróżnicowanie cech chemostratygraficznych uzyskano w przypadku utworów kredowych. Wstępnie badania wykonano w laboratorium akredytowanym Actlabs, tak aby móc później przeprowadzić ewaluację wyników uzyskanych za pomocą przenośnych spektrometrów (pXRF Titan, o zakresie pomiarowym od Mg do U, oraz pXRF Tracer, który umożliwia również pomiar zawartości Na, oba aparaty firmy Bruker). Potwierdzono, że wyraźne zróżnicowanie zawartości poszczególnych pierwiastków widoczne jest zarówno dla pierwiastków głównych, jak i śladowych. Pierwiastki najbardziej diagnostyczne to Na, Mg, Fe, K, Ca, również Si, choć w tym przypadku zakres zmienności jest nieco mniejszy. W przypadku pierwiastków śladowych są to S, P, Mn, Ti, Sr, Zr, Ba, Rb i Zn, które można również analizować za pomocą przenośnych spektrometrów pXRF. Wykonane porównanie wyników składu chemicznego uzyskiwanych przenośnym spektrometrem pXRF oraz w laboratorium Actlabs wykazało, że możliwe jest wykorzystanie na większą skalę samych pomiarów spektrometrem pXRF. Dla większości pierwiastków diagnostycznych uzyskano wystarczająco precyzyjne wyniki przy wykorzystaniu przenośnych spektrometrów pXRF.","PeriodicalId":45266,"journal":{"name":"Nafta-Gaz","volume":"3 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136160441","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The main goal of the reviewed article is to provide statistically determined relationships between the parameters of disintegration processes and the properties of rocks. The results of theoretical and experimental studies are discussed and analysed in the article. In relation to drilling, the formulas of drilling speed, depending on various parameters as an indicator that fully reflects the efficiency of the process, are given and compared. Thus, the drilling speed for percussion drilling is related to the characteristics of the rock and, at the same time, taking into account the constructional characteristics of the drilling tool. In percussion drilling, a new formula for drilling speed is presented, considering each impact and the frequency of the impact. The expression for the drilling speed was determined taking into account the degree of crushing of the rock matrix during drilling. Thus, the drilling speed is determined by considering the contact strength of the rock being drilled in the mechanical drilling method. The distribution of the stress state in the drilling zone was determined. Also, the shape and development characteristics of the cracks formed in the rock during the operation of the drilling tool (especially the dynamic percussions of the tool in the bottom zone of the well) were investigated. It should be noted that the energy intensity of the drilling process in the rock was determined by studying the next stages of the process of breaking the rock. The technical and economic indicators of the drilling works have been evaluated. Corresponding mathematical formulas are presented as a reliable calculation of drilling rates. The relevant mechanical and geophysical properties of the excavated rocks were considered. In the article, the drilling tools are selected depending on the drilling method, physical-mechanical properties of the rocks and geological conditions of the rock mass. The results of the obtained studies can be used in the design of the technological parameters of the drilling. The observations and results expressed in the article have a theoretical and practical aspect.
{"title":"Review of basic equations for evaluating drilling efficiency","authors":"Rafail K. Mehtiyev, Yusif A. Tanriverdiyev","doi":"10.18668/ng.2023.10.05","DOIUrl":"https://doi.org/10.18668/ng.2023.10.05","url":null,"abstract":"The main goal of the reviewed article is to provide statistically determined relationships between the parameters of disintegration processes and the properties of rocks. The results of theoretical and experimental studies are discussed and analysed in the article. In relation to drilling, the formulas of drilling speed, depending on various parameters as an indicator that fully reflects the efficiency of the process, are given and compared. Thus, the drilling speed for percussion drilling is related to the characteristics of the rock and, at the same time, taking into account the constructional characteristics of the drilling tool. In percussion drilling, a new formula for drilling speed is presented, considering each impact and the frequency of the impact. The expression for the drilling speed was determined taking into account the degree of crushing of the rock matrix during drilling. Thus, the drilling speed is determined by considering the contact strength of the rock being drilled in the mechanical drilling method. The distribution of the stress state in the drilling zone was determined. Also, the shape and development characteristics of the cracks formed in the rock during the operation of the drilling tool (especially the dynamic percussions of the tool in the bottom zone of the well) were investigated. It should be noted that the energy intensity of the drilling process in the rock was determined by studying the next stages of the process of breaking the rock. The technical and economic indicators of the drilling works have been evaluated. Corresponding mathematical formulas are presented as a reliable calculation of drilling rates. The relevant mechanical and geophysical properties of the excavated rocks were considered. In the article, the drilling tools are selected depending on the drilling method, physical-mechanical properties of the rocks and geological conditions of the rock mass. The results of the obtained studies can be used in the design of the technological parameters of the drilling. The observations and results expressed in the article have a theoretical and practical aspect.","PeriodicalId":45266,"journal":{"name":"Nafta-Gaz","volume":"125 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136092994","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ściśliwość porowa skał jest jednym z istotnych parametrów wykorzystywanych w trakcie badań złóż węglowodorów. Nieprawidłowe oszacowanie tego czynnika, a co za tym idzie – porowatości pierwotnej w warunkach in situ, prowadzi do błędów w szacowaniu zasobów złóż węglowodorów. Dotychczasowe próby opisania zależności pomiędzy porowatością mierzoną w ramach rutynowych badań petrofizycznych a ściśliwością porową doprowadziły do powstania szeregu modeli umożliwiających oszacowanie współczynnika ściśliwości porowej. Niestety, w trakcie prac zaczęto zauważać, że wyniki otrzymane na podstawie modeli nie mogą zastąpić badań laboratoryjnych, a jedynie służyć jako narzędzie pomocnicze. Dodatkowo wykazano, że uzyskane rezultaty różnią się w zależności od litologii, miejsca pochodzenia próbek i ciśnień, w jakich były badane. Doprowadziło to do powstawania coraz większej liczby modeli o różnym przeznaczeniu. W artykule użyto kilku najpopularniejszych modeli służących do oceny współczynnika ściśliwości piaskowców, które próbowano dopasować do uzyskanych wyników eksperymentalnych. Obiektem badań było 20 próbek piaskowców i heterolitów z rejonu zapadliska przedkarpackiego o porowatości od kilku do dwudziestu kilku procent. Przebadano je pod kątem właściwości petrofizycznych takich jak porowatość i przepuszczalność, a także dokonano analizy petrograficznej. Następnie przeprowadzono badanie ściśliwości porowej i wykonano analizę zależności pomiędzy ściśliwością a porowatością. Po uzyskaniu wyników eksperymentalnych porównano je z wynikami otrzymanymi na podstawie modeli literaturowych. W wyniku analizy statystycznej wytypowano najlepszy z modeli, który następnie został zmodyfikowany z wykorzystaniem języka R i środowiska Posit w celu jak najlepszego dopasowania do danych laboratoryjnych. Pozwoliło to na opracowanie modelu, który w porównaniu z dostępnymi modelami pozwala z dużo większą dokładnością przewidzieć współczynnik ściśliwości porowej piaskowców i heterolitów z zapadliska przedkarpackiego.
岩石的孔隙可压缩性是油气储层勘探中使用的重要参数之一。对这一因素以及原位条件下的原生孔隙度估计不准确，会导致油气储层资源量估计错误。以前曾尝试描述常规岩石物理研究测得的孔隙度与孔隙可压缩性之间的关系，并由此产生了许多估算孔隙可压缩性系数的模型。遗憾的是，在工作过程中，人们开始注意到，这些模型得出的结果无法取代实验室测试，只能作为一种辅助工具。此外，研究还表明，根据岩性、样本来源和测试压力的不同，获得的结果也不尽相同。因此，人们开发了越来越多不同用途的模型。本文使用了几种最常用的砂岩压缩系数评估模型，试图与实验结果相匹配。研究对象是来自前喀尔巴阡山塌陷地区的 20 个砂岩和杂岩样本，孔隙率从百分之几到百分之二十几不等。对这些样本进行了岩石物理特性（如孔隙度和渗透率）检查，并进行了岩相分析。然后进行了孔隙可压缩性研究，并对可压缩性和孔隙度之间的关系进行了分析。获得实验结果后，将其与文献模型得出的结果进行比较。经过统计分析，选出了最佳模型，然后使用 R 语言和 Posit 环境对其进行修改，使其最适合实验室数据。这样就可以建立一个模型，与现有模型相比，该模型可以更准确地预测前喀尔巴阡塌陷的砂岩和杂岩的孔隙压缩系数。
{"title":"Modele zmian ściśliwości przestrzeni porowej mioceńskich skał zbiornikowych z rejonu zapadliska przedkarpackiego","authors":"Krzysztof Nowak","doi":"10.18668/ng.2023.10.02","DOIUrl":"https://doi.org/10.18668/ng.2023.10.02","url":null,"abstract":"Ściśliwość porowa skał jest jednym z istotnych parametrów wykorzystywanych w trakcie badań złóż węglowodorów. Nieprawidłowe oszacowanie tego czynnika, a co za tym idzie – porowatości pierwotnej w warunkach in situ, prowadzi do błędów w szacowaniu zasobów złóż węglowodorów. Dotychczasowe próby opisania zależności pomiędzy porowatością mierzoną w ramach rutynowych badań petrofizycznych a ściśliwością porową doprowadziły do powstania szeregu modeli umożliwiających oszacowanie współczynnika ściśliwości porowej. Niestety, w trakcie prac zaczęto zauważać, że wyniki otrzymane na podstawie modeli nie mogą zastąpić badań laboratoryjnych, a jedynie służyć jako narzędzie pomocnicze. Dodatkowo wykazano, że uzyskane rezultaty różnią się w zależności od litologii, miejsca pochodzenia próbek i ciśnień, w jakich były badane. Doprowadziło to do powstawania coraz większej liczby modeli o różnym przeznaczeniu. W artykule użyto kilku najpopularniejszych modeli służących do oceny współczynnika ściśliwości piaskowców, które próbowano dopasować do uzyskanych wyników eksperymentalnych. Obiektem badań było 20 próbek piaskowców i heterolitów z rejonu zapadliska przedkarpackiego o porowatości od kilku do dwudziestu kilku procent. Przebadano je pod kątem właściwości petrofizycznych takich jak porowatość i przepuszczalność, a także dokonano analizy petrograficznej. Następnie przeprowadzono badanie ściśliwości porowej i wykonano analizę zależności pomiędzy ściśliwością a porowatością. Po uzyskaniu wyników eksperymentalnych porównano je z wynikami otrzymanymi na podstawie modeli literaturowych. W wyniku analizy statystycznej wytypowano najlepszy z modeli, który następnie został zmodyfikowany z wykorzystaniem języka R i środowiska Posit w celu jak najlepszego dopasowania do danych laboratoryjnych. Pozwoliło to na opracowanie modelu, który w porównaniu z dostępnymi modelami pozwala z dużo większą dokładnością przewidzieć współczynnik ściśliwości porowej piaskowców i heterolitów z zapadliska przedkarpackiego.","PeriodicalId":45266,"journal":{"name":"Nafta-Gaz","volume":"5 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136093819","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The maintenance of equipment and tools used in the workover of oil and gas wells depends on keeping them in good working condition, maintaining the reliability, strength, and temperature endurance of the tool. To restore wells after an accident and bring them back into operation, it is necessary to speed up the drilling and repair work by choosing the right repair equipment and following the existing rules and regulatory documents. The cutting elements of tools working under high pressure and loads are deformed, a tense situation is created in the cutting – a destruction zone and high temperatures (1000–1200°C) occur because of corrosion in the triboknots. The stress-deformation state in the cutting-destruction zone causes the formation of microcracks in the working area of the tool. Microcracks grow after a certain period. Cutting elements are quickly worn, in some cases break and fail quickly. Such cases affect the structural composition of the cutting elements, an increase in temperatures; as a result, riveting occurs. In order to keep the equipment and tools used in the repair in normal working condition, adjusting the mode parameters is one of the important requirements, in addition to taking special care of them. Optimum results obtained in repair and restoration depend on the efficiency of the cutting-destructive tool, longevity, material selection, construction manufacturing technologies, tools that meet modern requirements, dimensions, weight, and internal condition of the well being restored. It is necessary to keep the heat generated in the moving parts of the tool at the required level for the safe performance of restoration work. The thermal regime of cutting and rock-destroying tools depends on the physical-mechanical properties of the objects subjected to destruction, and the effect of thermomechanical stresses generated on the contact surfaces of the tool and the amount of heat released from the working surface. Studying the problems related to heat issues will ensure the temperature tolerance of not only the repair equipment, but also the equipment and tools used in other areas of the oil-field industry.
{"title":"Reductıon of thermal tensıons and temperatures formed ın the trıbonodes and surfaces of the equıpment and tools used ın well workover and restoratıon works","authors":"Amir G. Mustafayev, Chingiz R. Nasirov","doi":"10.18668/ng.2023.10.04","DOIUrl":"https://doi.org/10.18668/ng.2023.10.04","url":null,"abstract":"The maintenance of equipment and tools used in the workover of oil and gas wells depends on keeping them in good working condition, maintaining the reliability, strength, and temperature endurance of the tool. To restore wells after an accident and bring them back into operation, it is necessary to speed up the drilling and repair work by choosing the right repair equipment and following the existing rules and regulatory documents. The cutting elements of tools working under high pressure and loads are deformed, a tense situation is created in the cutting – a destruction zone and high temperatures (1000–1200°C) occur because of corrosion in the triboknots. The stress-deformation state in the cutting-destruction zone causes the formation of microcracks in the working area of the tool. Microcracks grow after a certain period. Cutting elements are quickly worn, in some cases break and fail quickly. Such cases affect the structural composition of the cutting elements, an increase in temperatures; as a result, riveting occurs. In order to keep the equipment and tools used in the repair in normal working condition, adjusting the mode parameters is one of the important requirements, in addition to taking special care of them. Optimum results obtained in repair and restoration depend on the efficiency of the cutting-destructive tool, longevity, material selection, construction manufacturing technologies, tools that meet modern requirements, dimensions, weight, and internal condition of the well being restored. It is necessary to keep the heat generated in the moving parts of the tool at the required level for the safe performance of restoration work. The thermal regime of cutting and rock-destroying tools depends on the physical-mechanical properties of the objects subjected to destruction, and the effect of thermomechanical stresses generated on the contact surfaces of the tool and the amount of heat released from the working surface. Studying the problems related to heat issues will ensure the temperature tolerance of not only the repair equipment, but also the equipment and tools used in other areas of the oil-field industry.","PeriodicalId":45266,"journal":{"name":"Nafta-Gaz","volume":"21 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136160602","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Considering the substantial prevalence of gas fields in the pool of developed fields, their development requires specialized approaches with the primary objective of optimizing the production process. The effectiveness of gas field development hinges on achieving the highest possible gas recovery factor. Achieving a high limit of the ultimate return of gas fields relies on decisions that vary depending on the precision of design estimates carried out at different stages of development and their timely execution. The accuracy of such estimates is, if possible, directly contingent on the thorough consideration of geological, technical, and technological factors when formulating methods for determining field development and operation indicators. Given the above considerations, this article proposes a methodology for determining the technological indicators of gas reservoir development, which enables to anticipate changes in reservoir pressure, temperature, and porosity of the gas reservoir, while accounting for the gas-dynamic interplay within the “reservoir-well” system in the depletion phase. The developed approach makes it possible to reliably ascertain reservoir development metrics by factoring in well conditions, temperature distribution within the reservoir, and reservoir deformation. In addition, it facilitates the necessary assessment for determining optimal well operations in light of reservoir conditions.
{"title":"The method for calculating technological indicators in the development of gas wells while considering the thermobaric and thermodynamic conditions within the “reservoir-well” system","authors":"Elmira V. Gadasheva, Sudaba H. Novruzova","doi":"10.18668/ng.2023.10.06","DOIUrl":"https://doi.org/10.18668/ng.2023.10.06","url":null,"abstract":"Considering the substantial prevalence of gas fields in the pool of developed fields, their development requires specialized approaches with the primary objective of optimizing the production process. The effectiveness of gas field development hinges on achieving the highest possible gas recovery factor. Achieving a high limit of the ultimate return of gas fields relies on decisions that vary depending on the precision of design estimates carried out at different stages of development and their timely execution. The accuracy of such estimates is, if possible, directly contingent on the thorough consideration of geological, technical, and technological factors when formulating methods for determining field development and operation indicators. Given the above considerations, this article proposes a methodology for determining the technological indicators of gas reservoir development, which enables to anticipate changes in reservoir pressure, temperature, and porosity of the gas reservoir, while accounting for the gas-dynamic interplay within the “reservoir-well” system in the depletion phase. The developed approach makes it possible to reliably ascertain reservoir development metrics by factoring in well conditions, temperature distribution within the reservoir, and reservoir deformation. In addition, it facilitates the necessary assessment for determining optimal well operations in light of reservoir conditions.","PeriodicalId":45266,"journal":{"name":"Nafta-Gaz","volume":"44 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136159932","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
京公网安备 11010802042870号
京ICP备2023020795号-1
扫码关注我们
求助内容：
应助结果提醒方式：