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Optimization design and microstructure analysis of ultra-high performance cement-based composites 超高性能水泥基复合材料的优化设计与微观结构分析
IF 4.4 3区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-06-06 DOI: 10.1080/21650373.2023.2219263
Zhidan Rong, Yali Wang, Maopeng Jiao
Good workability and mechanical properties are both important for ultra-high performance cement-based composites (UHPCC). To achieve this goal, UHPCC was produced through a cost-effective approach of substituting cement with mineral admixtures. Based on Modified Andreasen and Andersen grading (MAA) model and orthogonal experimental design, key factors were identified and analyzed. The effect of the sand-to-binder ratio on bulk packing density was examined, while the impact of water-to-binder ratio and sand-to-binder ratio on the workability and mechanical properties of UHPCC was systematically studied. Additionally, X-CT was utilized to quantitatively analyze the steel fiber distribution and mesoscopic pore structure of UHPCC. Results indicated that the sand-to-binder ratio had the significant effect on bulk density, with the optimal ratio being 1.25. The suitable fluidity of UHPCC was between 245–255mm, with an optimal water-to-binder ratio of 0.18. The compressive and flexural strength of the mortar prepared with the optimal parameters were 167.5 MPa and 41.2 MPa, respectively.
对于超高性能水泥基复合材料(UHPCC)来说,良好的可加工性和力学性能是非常重要的。为了实现这一目标,UHPCC是通过用矿物外加剂替代水泥的一种经济有效的方法生产出来的。基于修正Andreasen and Andersen分级(MAA)模型和正交试验设计,对关键因素进行了识别和分析。考察了砂胶比对堆积密度的影响,系统研究了水胶比和砂胶比对UHPCC和易性和力学性能的影响。此外,利用X-CT定量分析了UHPCC的钢纤维分布和介观孔隙结构。结果表明,砂胶比对堆积密度影响显著,最佳配比为1.25。UHPCC的适宜流动性为245 ~ 255mm,最佳水胶比为0.18。采用最优参数制备的砂浆抗压强度为167.5 MPa,抗折强度为41.2 MPa。
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引用次数: 1
A deep learning-based potential developed for calcium silicate hydrates with both high accuracy and efficiency 基于深度学习的硅酸钙水合物具有高精度和高效率的潜力
3区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-06-05 DOI: 10.1080/21650373.2023.2219251
Weihuan Li, Yang Zhou, Li Ding, Pengfei Lv, Yifan Su, Rui Wang, Changwen Miao
Machine learning potential is an emerging and powerful approach with which to address the challenges of achieving both accuracy and efficiency in molecular dynamics simulations. However, the development of machine learning potentials necessitates intricate construction of descriptors, particularly for complex material systems. Therefore, the Deep Potential method, which utilizes artificial neural networks to autonomously construct descriptors, are employed to develop a deep learning-based potential for calcium silicate hydrates (the basic building block of cement-based materials) in this study. The accuracy of this potential is validated through calculations of energetics, structural, and elastic properties, demonstrating alignment with first principle calculations and an efficiency 2–3 orders of magnitude higher. Additionally, the deep potential successfully reproduces precise predictions in C-S-H models with different calcium-to-silicon ratios, thereby confirming its remarkable transferability. This potential is expected to fulfill cross-scale computations and bottom-up design of cement-based materials with both high accuracy and efficiency.
机器学习潜力是一种新兴而强大的方法,可以解决在分子动力学模拟中实现准确性和效率的挑战。然而,机器学习潜力的发展需要复杂的描述符构建,特别是对于复杂的材料系统。因此,在本研究中,利用人工神经网络自主构建描述符的深度电位方法被用于开发基于深度学习的硅酸钙水合物(水泥基材料的基本组成部分)的电位。通过对能量学、结构和弹性特性的计算,验证了这一潜力的准确性,证明了与第一原理计算的一致性,效率提高了2-3个数量级。此外,深层电位在不同钙硅比的C-S-H模型中成功地再现了精确的预测,从而证实了其显著的可转移性。这种潜力有望以高精度和高效率实现水泥基材料的跨尺度计算和自下而上的设计。
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引用次数: 0
Boosting the performance of low-carbon alkali activated slag with APEG PCEs: a comparison with ordinary Portland cement APEG PCEs提高低碳碱矿渣性能与普通硅酸盐水泥的比较
IF 4.4 3区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-06-05 DOI: 10.1080/21650373.2023.2219253
Yue Zhang, L. Lei, J. Plank, Liugang Chen
This study focused on investigating the dispersing effectiveness of polycarboxylate (PCE) superplasticizers with different carboxylate groups in two binder systems: Alkali-activated Slag (AAS) and Ordinary Portland Cement (OPC). Two α-allyl-ω-hydroxy poly (ethylene glycol) ether (APEG) PCE copolymers were prepared from acrylic acid (AA) or maleic anhydride (MA) separately. Performance test results in AAS revealed that MA-7APEG polymer exhibited much stronger dispersing efficiency than AA-7APEG2, despite both PCE polymers having the same anionicity and comparable molecular weight. This difference in effectiveness can be attributed to the stronger calcium binding capacity of the MA-7APEG polymer, as determined through anionic charge measurements and potential titration analysis. The study highlights the importance of considering the properties of the carboxylate groups in the design of effective PCE superplasticizers for use in different binder systems.
研究了不同羧酸基团的聚羧酸系高效减水剂在碱矿渣(AAS)和普通硅酸盐水泥(OPC)两种粘结剂体系中的分散效果。以丙烯酸(AA)和马来酸酐(MA)为原料,分别制备了两种α-烯丙基-ω-羟基聚乙二醇醚(APEG)PCE共聚物。AAS中的性能测试结果显示,尽管两种PCE聚合物具有相同的阴离子性和相当的分子量,但MA-7APEG聚合物表现出比AA-7APEG2更强的分散效率。这种有效性的差异可归因于MA-7APEG聚合物更强的钙结合能力,这是通过阴离子电荷测量和电位滴定分析确定的。该研究强调了在设计用于不同粘合剂体系的有效PCE超塑化剂时考虑羧酸酯基团性质的重要性。
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引用次数: 2
Fractal characteristics of particle groups and mechanochemical effects of Yellow River sediment after mechanical grinding 黄河泥沙机械碾磨后颗粒群的分形特征及力学化学效应
IF 4.4 3区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-06-04 DOI: 10.1080/21650373.2023.2218841
M. Cao, Honglei Zhang
This paper investigated the fractal characteristics of particle groups and the mechanochemical effects of mechanically grinding Yellow River Sediment (MGYRS). The particle groups of MGYRS had good fractal characteristics, and the fractal dimension had a better correlation with the particle size, distribution and specific surface area of MGYRS, which could well reflect the changes in the physical properties of MGYRS. After mechanical milling, the analysis by XRD, FT-IR and XPS microscopic tests revealed that: the crystallinity and grain size of mineral crystals in MGYRS decreased with the increase in milling time. The electron binding energy of Si2p, Al2p and O1s shifted to the low-energy direction, and the chemical valence state of silicon atoms appeared Si3+ due to the breakage of the Si-O-Si/Al chemical bond. These changes in internal structure and chemical valence state were the microscopic manifestations of mechanochemical effects. The activation rate of MGYRS increased with the increase of grinding time, which was the macroscopic manifestation of mechanochemical effects.
研究了黄河泥沙机械碾磨过程中颗粒群的分形特征及力学化学效应。MGYRS颗粒群具有良好的分形特征,分形维数与MGYRS颗粒大小、分布和比表面积有较好的相关性,能很好地反映MGYRS物理性质的变化。机械磨矿后,通过XRD、FT-IR和XPS细观测试分析发现:随着磨矿时间的延长,MGYRS中矿物晶体的结晶度和晶粒尺寸减小。由于Si-O-Si/Al化学键断裂,Si2p、Al2p和O1s的电子结合能向低能方向转移,硅原子的化学价态出现Si3+。这些内部结构和化学价态的变化是机械化学作用的微观表现。MGYRS的活化率随磨矿时间的增加而增加,这是力学化学效应的宏观表现。
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引用次数: 0
Effect of recycled brick powder on the hydration process of cement paste 再生砖粉对水泥浆体水化过程的影响
IF 4.4 3区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-06-01 DOI: 10.1080/21650373.2023.2216702
Xu Luo, Shujun Li, Zhenhai Xu, Zhaoheng Guo, Cheng Liu, Xuemei Chen, Jianming Gao
Abstract Using recycled brick powder (RBP) in blended cement is beneficial to energy saving and emission reduction. The hydration process of blended cement containing RBP is significant for the mechanical property and durability of concrete. The hydration mechanism of blended cement containing recycled brick powder (RBP) has been investigated through hydration heat, hydration degree, and hydration products of the pastes to reveal the effect of RBP on hydration and the reaction mechanism of RBP. The results show that the addition of RBP reduces the heat release during the hydration process, but its nucleation and dilution effects promote cement hydration. The inclusion of RBP also decreases the amount of Ca(OH)2 in the system. The content of the amorphous phase in the system continuously increases with hydration time, and after 28 days of hydration, the amorphous phase is derived from both cement hydration and the pozzolanic reaction of RBP. Between 28 and 90 days of hydration, the reactivity of RBP significantly increases.
摘要在水泥中使用再生砖粉有利于节能减排。掺RBP水泥的水化过程对混凝土的力学性能和耐久性有重要影响。通过水化热、水化度、水化产物等指标研究了含再生砖粉水泥的水化机理,揭示了再生砖粉对水泥水化的影响以及再生砖粉的反应机理。结果表明:RBP的加入减少了水化过程中的放热,但其成核和稀释作用促进了水泥水化;RBP的加入也降低了系统中Ca(OH)2的含量。随着水化时间的延长,体系中非晶态相的含量不断增加,在水化28天后,非晶态相来源于水泥水化和RBP的火山灰反应。在水化28 ~ 90 d, RBP的反应性显著增强。
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引用次数: 1
Strength, shrinkage, heat evolution, and microstructure of high performance concrete containing high proportions of ground bottom ash blended with fly ash 含有高比例底灰与粉煤灰混合的高性能混凝土的强度、收缩、热演化和微观结构
IF 4.4 3区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-05-31 DOI: 10.1080/21650373.2023.2214138
Pakawat Pormmoon, Piyanat Charoenamnuaysuk, C. Jaturapitakkul, P. Chindaprasirt, Weerachart Tangchirapat
This study examines the use of ground bottom ash incorporating fly ash in high performance concrete. A self-compacting concrete was considered in this study as to maximize the properties of high performance concrete. Bottom ash was processed to a fine consistency by oven-drying, sieving, and grinding. Ordinary Portland cement (OPC), sieved and ground bottom ash (GBA), and fly ash (FA) were used for producing high performance concrete at a W/B ratio of 0.27. Replacement of 50% cement by GBA produced 101.0 MPa concrete at 28 days: 21.6% stronger than OPC concrete. The 50% GBA mixture needed a greater quantity of superplasticizer to satisfy slump flow requirements for self-compacting concrete, but that dosage was reduced with a partial replacement of GBA by FA. Elastic moduli of all blended concretes matched OPC concrete. However, the blended concretes experienced much less autogenous shrinkage. Pastes containing GBA and FA have less portlandite than OPC paste. In addition, replacing OPC by GBA–FA substantially reduced cumulative heat evolution.
本研究探讨了在高性能混凝土中掺入粉煤灰的底灰的使用。本研究考虑自密实混凝土,以最大限度地提高高性能混凝土的性能。底灰经烘箱干燥、筛分和研磨加工成细稠状。采用普通硅酸盐水泥(OPC)、过筛底灰(GBA)和粉煤灰(FA)配制高性能混凝土,W/B比为0.27。用GBA替代50%的水泥,28天产生101.0 MPa的混凝土,比OPC混凝土强21.6%。50%的GBA混合料需要大量的高效减水剂来满足自密实混凝土的坍落度流动要求,但用FA部分替代GBA可以降低该用量。所有混合混凝土的弹性模量与OPC混凝土相匹配。然而,混合混凝土的自收缩要小得多。含有GBA和FA的膏体比OPC膏体含有更少的硅酸盐。此外,用GBA-FA代替OPC大大减少了累积热演化。
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引用次数: 0
The self-healing properties and mechanism of the cracked fly ash-based engineered geopolymer composites (FA-EGC): effects of water and temperature 粉煤灰基工程地聚合物复合材料(FA-EGC)的自修复性能及机理:水和温度的影响
IF 4.4 3区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-05-31 DOI: 10.1080/21650373.2023.2213227
Xiaolu Guo, Shuting Yuan, Xinhao Liu
In this article, the self-healing properties and mechanism of cracked fly ash-based Engineered Geopolymer Composites (FA-EGC) in different environments are studied. Four kinds of environments (air, wet-dry cycles, 20 °C water, and 40 °C water) are chosen to simulate real service environments. The tensile property, ultrasonic pulse velocity, crack characteristic, and water absorption of FA-EGC are measured to evaluate the self-healing properties. The test results show that the existence of water and the increasing of temperature can benefit the self-healing performance of FA-EGC. In addition, the 28-day self-healing products are determined by X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), and scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) to explore the mechanism of the self-healing in different environments. The results demonstrate that N–A–S–H gels could be the main self-healing products in the air condition. While in the other environments with water, the (N/C)–A–S–H gels would be the primary products.
本文研究了粉煤灰基工程地质聚合物复合材料(FA-EGC)在不同环境中的自修复性能和机理。四种环境(空气、干湿循环、20 °C水和40 °C水)来模拟真实的服务环境。测量了FA-EGC的拉伸性能、超声脉冲速度、裂纹特性和吸水率,以评估其自修复性能。试验结果表明,水的存在和温度的升高有利于FA-EGC的自修复性能。此外,通过X射线衍射(XRD)、傅立叶变换红外光谱(FT-IR)和扫描电子显微镜能量色散光谱(SEM-EDS)测定了28天的自修复产物,以探索不同环境下的自修复机制。结果表明,N–A–S–H凝胶可能是空气条件下的主要自愈合产物。而在其他有水的环境中,(N/C)–A–S–H凝胶将是主要产品。
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引用次数: 2
Early-age autogenous shrinkage and tensile creep of concrete reinforced with polypropylene macro fiber 聚丙烯大纤维增强混凝土的早期自收缩和拉伸蠕变
IF 4.4 3区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-05-28 DOI: 10.1080/21650373.2023.2214135
Chuyuan Wen, D. Shen, Yueyao Luo, Wenting Wang, Ci Liu, Ming Li
Early-age autogenous shrinkage and thermal shrinkage developed in concrete may lead to cracking when the stress induced by restrained shrinkage is higher than the tensile strength of concrete. Early-age tensile creep (TC) of concrete can mitigate the tensile stress generated in concrete induced by restrained shrinkage. Characterizing the TC of concrete at early age is important for cracking resistance evaluation. The early-age autogenous shrinkage and TC of concrete with various proportions of polypropylene (PP) macro fiber (0%, 0.3%, 0.6%, and 0.9%) were investigated utilizing the Temperature Stress Test Machine. Fiber dispersion and the microstructure of concrete mixtures were also analyzed. Test results indicated that PP macro fiber reinforcement led to the improvement of mechanical properties and mitigation of autogenous shrinkage. TC behavior of concrete at early age including TC, TC coefficient, and specific TC decreased with the inclusion of PP macro fiber. A modified model for the prediction of the early-age specific TC of concrete reinforced with PP macro fiber was proposed.
当约束收缩引起的应力高于混凝土的抗拉强度时,混凝土中早期产生的自收缩和热收缩可能导致开裂。混凝土的早期拉伸蠕变(TC)可以减轻混凝土因约束收缩而产生的拉应力。表征混凝土早期的TC对于评估抗裂性非常重要。利用温度应力试验机研究了不同比例聚丙烯(PP)大纤维(0%、0.3%、0.6%和0.9%)混凝土的早期自收缩和TC。分析了纤维的分散性和混凝土混合料的微观结构。试验结果表明,聚丙烯大纤维增强材料能够改善力学性能,减缓自收缩。混凝土早期的TC行为,包括TC、TC系数和比TC,随着聚丙烯大纤维的加入而降低。提出了一种预测聚丙烯大纤维混凝土早期比TC的修正模型。
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引用次数: 2
Use of nano-silica in cement-based materials – a comprehensive review 纳米二氧化硅在水泥基材料中的应用综述
IF 4.4 3区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-05-26 DOI: 10.1080/21650373.2023.2214146
Hussein M. Hamada, Jinyan Shi, S. Yousif, Mohammed S. Al Jawahery, B. Tayeh, G. Jokhio
Recently, nano silica (NS) has gained the attraction of academic researchers and the construction industry because of enhancing the properties of cementitious composites. Although there have been some related reviews, the comprehensiveness and advancedness need to be further improved. This paper is a detailed review of previously conducted studies to explore the influence of NS in cementitious composites for evaluating mechanical properties and durability. The impact of NS on the fresh state, i.e. setting time and workability, and in the hardened state, i.e. compressive, flexural, and split tensile strengths is considered. Besides, the long-term durability is discussed that include permeability, resistance against acid and base attack, abrasion resistance, and carbonation resistance. Furthermore, volume stability and microstructure of concrete with NS are presented. A huge number of studies showed the positive effect of NS with optimized content for improving the concrete properties, while a negative effect was observed with the use of excess NS content. The inclusion of NS in cementitious composites substantially enhances the mechanical properties, durability and microstructure. Meanwhile, better dispersibility is the key to ensure the strengthening effect of NS, which can be improved by changing the morphology/size of NS, optimizing the stirring method, and adding surfactants. Further investigation of the application of NS in special concrete is its development direction, and the effect of NS on the microstructure of main hydration products needs to be further explored.
近年来,纳米二氧化硅(NS)因能提高胶凝复合材料的性能而受到学术界和建筑界的广泛关注。虽然已有一些相关综述,但其全面性和先进性有待进一步提高。本文详细回顾了之前进行的研究,以探讨NS对胶凝复合材料力学性能和耐久性的影响。考虑了NS对新鲜状态(即凝结时间和和易性)和硬化状态(即抗压、抗折和劈裂抗拉强度)的影响。此外,还讨论了其长期耐久性,包括透气性、抗酸碱侵蚀性、耐磨性和抗碳化性。此外,还介绍了掺NS混凝土的体积稳定性和微观结构。大量研究表明,优化掺量的NS对改善混凝土性能有积极作用,过量掺量的NS对改善混凝土性能有消极作用。在胶凝复合材料中加入NS可显著提高材料的力学性能、耐久性和微观结构。同时,良好的分散性是保证纳米粒子增强效果的关键,可以通过改变纳米粒子的形态/粒径、优化搅拌方式、添加表面活性剂等措施来提高纳米粒子的分散性。进一步研究NS在特种混凝土中的应用是其发展方向,NS对主要水化产物微观结构的影响有待进一步探讨。
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引用次数: 4
Strength and permeation characteristics of pervious concrete subjected to accelerated carbonation curing 加速碳化养护透水混凝土的强度和渗透特性
IF 4.4 3区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-05-24 DOI: 10.1080/21650373.2023.2213241
G. Sidhu, Himanshu Guleria, D. Sharma, S. Goyal
This study aims to investigate the influence of accelerated carbonation curing (ACC) on strength and permeation characteristics of pervious concrete. ACC envisaged well for CO2 sequestration in concrete. Pervious concrete is considered to be better recipient for CO2 curing due to presence of high interconnected pores. Carbonation of pervious concrete is deeper and homogeneous in comparison to normal concrete. Experimental results show that accelerated carbonation curing at 12-hour effectively improves strength of pervious concrete. Also, application-based interlocking pervious paver blocks subjected to 12-hour ACC provide the highest strength of 23.36 MPa. Permeation characteristics were found to be in optimum range despite of decrease in permeability due to the formation of CaCO3 in specimens subjected to ACC. Microstructural analysis also suggested intermingled matrix of CaCO3 and CSH gel. TGA revealed higher CO2 uptake for longer duration of ACC specimens, suggesting sequestration of CO2 in pervious concrete compare to conventional concrete.
本研究旨在探讨加速碳化养护(ACC)对透水混凝土强度和渗透特性的影响。ACC很好地设想了混凝土中的二氧化碳封存。透水混凝土被认为是CO2养护的更好的接受者,因为存在高度互联的孔隙。与普通混凝土相比,透水混凝土的碳化更深、更均匀。试验结果表明,12 h加速碳化养护能有效提高透水混凝土的强度。此外,基于应用的互锁透水摊铺机砌块经过12小时的ACC,其最高强度为23.36 MPa。尽管由于CaCO3的形成导致了渗透性的降低,但在经过ACC处理的样品中,渗透特性处于最佳范围内。微观结构分析表明CaCO3和CSH凝胶混合基质。TGA显示ACC试件的CO2吸收量较高,持续时间较长,表明透水混凝土与常规混凝土相比具有CO2固存作用。
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引用次数: 0
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Journal of Sustainable Cement-Based Materials
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