Reinforced concrete (RC) shear wall structures are widely utilized as blast-resistant chambers for storing hazardous chemical materials and high-pressure reaction equipment. They protect surrounding personnel and facilities by confining blast wave propagation and preventing chain reactions. This study investigates the failure mechanisms of full-scale RC shear wall protective structures under internal blast loading, with a specific focus on the influence of chamfer design on the failure modes of wall-slab joints, using both full-scale field tests and numerical simulations. Two RC shear wall structures were constructed with dimensions of 9.7 m × 8 m × 6.95 m and a wall thickness of 0.8 m. Internal detonations of 200 kg TNT were conducted to simulate the extreme loads potentially encountered in blast containment rooms. Based on the experimental and simulation results, the structural damage mechanisms and dynamic responses were analyzed. The results indicate that under internal blast loading, severe damage initiates at the wall-slab joints, primarily manifesting as shear damage. Structures with traditional right-angle joints suffered severe brittle shear failure, resulting in the separation of walls and slabs. In contrast, the chamfer design effectively alleviated stress concentration at the joints, shifting the failure mode from brittle shear to a ductile flexural behavior with superior energy dissipation capabilities. Furthermore, based on the experimental data, validated finite element models were employed to conduct an in-depth parametric analysis, quantifying the effects of reinforcement configuration and TNT charge weight on the structural dynamic response. This research provides new data support and theoretical references for the design and retrofitting of RC blast-resistant structures.
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