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A novel approach towards parametric assessment of reliability and resilience of high voltage mica-based insulation systems by statistical analysis of experimental failure data 通过对实验故障数据进行统计分析,对高压云母绝缘系统的可靠性和弹性进行参数评估的新方法
IF 4.4 2区 工程技术 Q1 Engineering Pub Date : 2024-03-25 DOI: 10.1049/hve2.12431
Shahram Negari, Davoud Esmaeil Moghadam

Insulation systems in high-voltage electric machines play a pivotal role in the reliable operation and longevity of the equipment. Mica-based insulation materials have proven to possess and maintain excellent dielectric properties in the long run and prevent premature insulation degradation. Numerous qualifications tests, such as voltage endurance, are outlined in IEC and IEEE standards. The authors, however, take a different parametric approach, opting for reliability assessment of insulation systems using derived three-parameter Weibull models. Therefore, instead of simple pass–fail criteria, empirical data is employed to determine failure rate probabilities quantitatively and objectively. Experimental data, including breakdown, dissipation factor, and partial discharge measurements, are used to construct the Weibull distribution model to predict fault and failure rates and calculate hazard functions. The rigorous examinations interpreted through the analytical model help assess insulation system resilience and particularly the impact of electrical field stress and mica content. Variation of electrical stress from 66.75 to 71.20 V/mil demonstrated how the mean time to failure of the system changed from 146.4 to 85.1 at 3 Un, hence identifying opportunities for design improvement and uncovering performance boundaries. Ultimately, the developed framework enhances comprehension of insulation system failure probabilities, guiding design decisions and ensuring a secure and reliable operation of electrical machines across applications.

高压电机的绝缘系统对设备的可靠运行和使用寿命起着至关重要的作用。云母基绝缘材料已被证明具有并能长期保持出色的介电特性,防止绝缘过早老化。国际电工委员会(IEC)和电气和电子工程师协会(IEEE)的标准中规定了许多资格测试,如耐压测试。然而,作者采用了一种不同的参数方法,利用衍生的三参数 Weibull 模型对绝缘系统进行可靠性评估。因此,作者没有采用简单的合格-不合格标准,而是利用经验数据来定量、客观地确定故障率概率。包括击穿、耗散因数和局部放电测量在内的实验数据被用来构建威布尔分布模型,以预测故障和失效率并计算危险函数。通过分析模型解释的严格检查有助于评估绝缘系统的弹性,特别是电场应力和云母含量的影响。电场应力从 66.75 V/mil 到 71.20 V/mil 的变化表明了系统在 3 Un 时的平均故障时间从 146.4 到 85.1 的变化,从而确定了改进设计的机会并揭示了性能边界。最终,开发的框架提高了对绝缘系统失效概率的理解,为设计决策提供了指导,并确保电机在各种应用中安全可靠地运行。
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引用次数: 0
A novel linear regression density peak clustering-based transmission line protection for line-commuted converter-voltage source converter hybrid high voltage direct current system 基于线性回归密度峰值聚类的新型输电线路保护,适用于线路换流器-电压源换流器混合高压直流系统
IF 4.4 2区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-03-25 DOI: 10.1049/hve2.12436
Shunguang Lei, Hongchun Shu, Zhimin Li, Yinan Hu, Xincui Tian, Taiwen Liu

Line-commuted converter (LCC)–voltage source converter (VSC) hybrid high voltage direct current (HVDC) transmission system is an innovative technology, the existing LCC and VSC protection require setting, and it is difficult to be directly applied in the LCC–VSC hybrid HVDC, which is a serious problem in practical engineering. A novel linear regression density peak clustering (LRDPC) approach is introduced for transmission line protection. LRDPC employs Least Squares linear regression to compute the fault current slope, followed by density peak clustering for fault type identification. The proposed protection structure is straightforward and setting-less, eliminating the need for fault pole selection elements and classification thresholds. Validation on the Kun-Liu-Long LCC–VSC HVDC RTDS system demonstrates the method's effectiveness in identifying diverse faults under varying conditions, including fault types, locations, resistances, and signal-to-noise ratios. Notably, it remains robust against fault impedance (600 Ω) and noise interference (20 dB).

线路换流器(LCC)-电压源换流器(VSC)混合高压直流(HVDC)输电系统是一项创新技术,现有的 LCC 和 VSC 保护需要设置,难以直接应用于 LCC-VSC 混合高压直流,这是实际工程中的一个严重问题。针对输电线路保护,引入了一种新颖的线性回归密度峰值聚类(LRDPC)方法。LRDPC 采用最小二乘法线性回归计算故障电流斜率,然后通过密度峰聚类进行故障类型识别。所提出的保护结构简单明了,无需设置,无需故障选极元件和分类阈值。在昆-柳-龙 LCC-VSC 高压直流 RTDS 系统上的验证表明,该方法能在不同条件下有效识别各种故障,包括故障类型、位置、电阻和信噪比。值得注意的是,该方法对故障阻抗(600 Ω)和噪声干扰(20 dB)仍具有很强的鲁棒性。
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引用次数: 0
Evaluation method for electromagnetic interference complexity of high voltage switch based on feature extraction and GCC-GRU network 基于特征提取和 GCC-GRU 网络的高压开关电磁干扰复杂性评估方法
IF 4.4 2区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-03-25 DOI: 10.1049/hve2.12402
Wenchao Lu, Jiandong Duan, Lin Cheng, Jiangping Lu, Jiaxin Tao, Jianning Yin

When some new-type sensors are subjected electromagnetic interference (EMI), the traditional standard can no longer serve as the guidance for their EMI protection. Therefore, it is necessary to evaluate the complexity of the new sensing equipment's suffering from electromagnetic interference. A hybrid method of feature extraction and complexity evaluation of Electromagnetic Interference signals based on generalised correntropy criterion (GCC) is proposed. First, a variational mode decomposition algorithm for adaptive extraction of decomposed signals is constructed using GCC, and Generalised S-transform is used for processing and reorganisation. Then, according to the time-frequency space model, a new quantitative evaluation criterion interference factor is proposed, which overcomes the shortcomings of the traditional qualitative classification and the inability to solve the cross classification of indicators. Then, the Gated Recurrent Unit is introduced, and the GCC-GRU evaluation model with GCC as the loss function is derived. The authors conduct EMI tests and measured signal evaluation with Medium Voltage and High Voltage switches, and the results show that the method proposed is correct and effective.

当一些新型传感器受到电磁干扰(EMI)时,传统的标准已不能作为其 EMI 防护的指导。因此,有必要对新型传感设备遭受电磁干扰的复杂性进行评估。本文提出了一种基于广义熵准则(GCC)的电磁干扰信号特征提取和复杂度评估混合方法。首先,利用 GCC 构建了自适应提取分解信号的变模分解算法,并使用广义 S 变换进行处理和重组。然后,根据时频空间模型,提出了一种新的定量评价准则干扰因子,克服了传统定性分类和无法解决指标交叉分类的缺点。然后,引入了门控循环单元,得出了以 GCC 为损失函数的 GCC-GRU 评估模型。作者对中压和高压开关进行了 EMI 测试和实测信号评估,结果表明所提出的方法是正确有效的。
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引用次数: 0
Theoretical assessment of discharge effects on the decomposition tendency of C6F12O over metallic surfaces 放电对金属表面 C6F12O 分解趋势影响的理论评估
IF 4.4 2区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-03-23 DOI: 10.1049/hve2.12426
Zhaolun Cui, Yanpeng Hao, Shuangshuang Tian, Xiaoxing Zhang, Yashuang Zheng

C6F12O is proposed to be one potential eco-friendly insulation gas to replace SF6. However, the assessment of its decomposition properties and the compatibility with metal electrodes in discharge faults is still challenging, which greatly hinders the development of its insulation and arc-extinction applications. Herein, a theoretical method is proposed to reasonably address the discharge effects on C6F12O decomposition over typical Cu and Al electrodes at atomic scale. The results show that both the external electric field and the excess electrons could affect the activation of C6F12O by changing the electron acceptance of C6F12O and the orbital hybridisation during the surface bonding. On metal surfaces, the C-F single bond in adsorbed C6F12O is the weakest position to decompose, and its cleavage could be promoted by the discharge effects. After the C-F breaking, the C-C cleavage remains unfavourable on Cu (111), but it is significantly promoted on Al (111), indicating a higher corrosion risk on the Al surface via continuous C6F12O decompositions. The proposed method as a valid supplement to the experiment reveals the discharge effects and the decomposition tendency of C6F12O on metal electrodes in discharge faults, which broadens the means for insulation gas evaluation.

C6F12O 被认为是一种潜在的环保绝缘气体,可替代 SF6。然而,对其分解特性以及在放电故障中与金属电极的兼容性的评估仍具有挑战性,这极大地阻碍了其绝缘和灭弧应用的发展。本文提出了一种理论方法,在原子尺度上合理解决典型的铜和铝电极对 C6F12O 分解的放电影响。结果表明,外电场和过剩电子都会通过改变 C6F12O 的电子接受度和表面键合过程中的轨道杂化来影响 C6F12O 的活化。在金属表面,吸附的 C6F12O 中的 C-F 单键是分解最弱的位置,放电效应可促进其裂解。在 C-F 断裂后,C-C 裂解在铜(111)上仍然是不利的,但在铝(111)上却明显得到促进,这表明通过持续的 C6F12O 分解,铝表面的腐蚀风险更高。所提出的方法作为实验的有效补充,揭示了放电故障中 C6F12O 在金属电极上的放电效应和分解趋势,拓宽了绝缘气体评估的途径。
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引用次数: 0
Study on thermal cycling ageing resistance of performances of polypropylene/elastomer/boron nitride nanocomposites for high voltage direct current cable insulation 用于高压直流电缆绝缘的聚丙烯/弹性体/氮化硼纳米复合材料耐热循环老化性能研究
IF 4.4 2区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-03-22 DOI: 10.1049/hve2.12429
Jing Li, Yu Gao, Zheng Song, Baixin Liu, Chenyi Guo, Yu Chen, Junguo Gao, Boxue Du

The influences of thermal cycling ageing on structures and insulation performances of polypropylene (PP)/elastomer/boron nitride (BN) nanocomposites are investigated. The Melt blending method was used to prepare the nanocomposites, in which propylene-based elastomer (PBE) or ethylene-octene copolymer elastomer (EOC) was contained for comparison. Then, the samples were treated using a thermal cycling process with a temperature range from −30 to 150°C, and the number of thermal cycles was set from 0 to 15. Scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry and X-ray diffraction measurements were taken to facilitate the comprehension of structural changes. Additionally, measurements were taken to assess the trap distribution and direct current (DC) breakdown strength of the samples. The obtained results revealed that following thermal cycling ageing, the morphology and crystallinity of PP/PBE/BN remained almost unchanged. In contrast, PP/EOC/BN exhibited substantial microstructural damage accompanied by a significant reduction in crystallinity. As the number of thermal cycles increased, the trap level and DC breakdown strength of PP/PBE/BN were maintained at high levels, while those of PP/EOC/BN initially remained stable but then experienced a sharp decline. It is suggested that the addition of BN nanoparticles enhances the thermal cycling ageing resistance of the PP/PBE blend, whereas it weakens this resistance of the PP/EOC blend.

研究了热循环老化对聚丙烯(PP)/弹性体/氮化硼(BN)纳米复合材料的结构和绝缘性能的影响。采用熔融混合法制备纳米复合材料,其中包含丙烯基弹性体(PBE)或乙烯-辛烯共聚物弹性体(EOC)以供比较。然后,采用热循环工艺处理样品,温度范围为 -30 至 150°C,热循环次数设定为 0 至 15 次。扫描电子显微镜(SEM)、傅立叶变换红外光谱(FTIR)、差示扫描量热法和 X 射线衍射测量有助于了解结构变化。此外,还测量了样品的阱分布和直流击穿强度。结果表明,经过热循环老化后,PP/PBE/BN 的形态和结晶度几乎保持不变。相反,PP/EOC/BN 出现了严重的微观结构损伤,同时结晶度显著降低。随着热循环次数的增加,PP/PBE/BN 的阱水平和直流击穿强度保持在较高水平,而 PP/EOC/BN 的阱水平和直流击穿强度最初保持稳定,但随后急剧下降。这表明 BN 纳米粒子的加入增强了 PP/PBE 共混物的耐热循环老化性,而削弱了 PP/EOC 共混物的耐热循环老化性。
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引用次数: 0
Gas production analysis for the buffer layer of high-voltage cross-linked polyethylene cables 高压交联聚乙烯电缆缓冲层产气分析
IF 4.4 2区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-03-21 DOI: 10.1049/hve2.12430
Wenqing Zhou, Licheng Li, Hao Cheng, Xun Wu, Gang Liu

The cross-linked polyethylene insulated cables with corrugated aluminium-sheathed are widely used in urban power systems. Recently, a new type of power cable fault has emerged, primarily due to defects in the buffer layer. However, there is a notable lack of effective evaluation methods for these defects in high-voltage (HV) cables. Initially, a theoretical analysis of the gas generation mechanism in the cable buffer layer was conducted, identifying distinct gas products at different stages. Subsequently, the diffusion kinetics of gas within the cable was studied, highlighting the importance of gas in determining the state of the buffer layer. The authors then collected and analysed 60 sets of buffer layer gases from two operational 110 kV HV cables using gas chromatography technology. Combining these results with the findings from on-site inspections, the characteristic gas components and concentration distribution under various defect conditions were summarised. The results found higher concentrations of CH4 in normal cables and defective cables, while there are higher concentrations of H2, CO and CO2 in defective cables, and the oxygen content decreases. The discoveries made in this research may offer a new approach for assessing the state of the cable buffer layer.

带波纹铝护套的交联聚乙烯绝缘电缆广泛应用于城市电力系统。最近,出现了一种新型电力电缆故障,主要是由于缓冲层的缺陷造成的。然而,对于高压(HV)电缆中的这些缺陷,目前明显缺乏有效的评估方法。最初,我们对电缆缓冲层中的气体生成机制进行了理论分析,确定了不同阶段的不同气体产物。随后,研究了气体在电缆内的扩散动力学,强调了气体在决定缓冲层状态方面的重要性。随后,作者利用气相色谱技术从两条运行中的 110 千伏高压电缆中收集并分析了 60 组缓冲层气体。将这些结果与现场检查结果相结合,总结出了各种缺陷条件下的特征气体成分和浓度分布。结果发现,正常电缆和缺陷电缆中 CH4 的浓度较高,而缺陷电缆中 H2、CO 和 CO2 的浓度较高,且氧含量降低。这项研究的发现为评估电缆缓冲层的状态提供了一种新方法。
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引用次数: 0
Accelerated thermal ageing on performance of polypropylene-based semiconducting screen for high voltage direct current cable applications—Effect of antioxidants 加速热老化对高压直流电缆用聚丙烯基半导体屏蔽性能的影响--抗氧化剂的效果
IF 4.4 2区 工程技术 Q1 Engineering Pub Date : 2024-03-20 DOI: 10.1049/hve2.12415
Haitian Wang, Yi Luo, Mingyu Zhou, Xintong Ren, George Chen

The potential of using eco-friendly thermoplastic polypropylene (PP)-based insulation for high voltage direct current (HVDC) cable has been widely investigated but much less work on the PP-based semiconducting screen (SC). Considering a long service life (>30 years) under high temperature and high electrical stress is required for typical HVDC cables, and investigations on the effect of antioxidant (AO) concentration and thermal oxidative stability, mechanical, and electrical properties of PP-based SCs have been conducted. It has been demonstrated that an appropriate combination and amounts of AOs are critical for achieving high thermal stability and maintaining the mechanical properties of SC after ageing in a harsh environment (150°C, with Cu, in air, 7 days). Although higher amounts of space charges have been observed in SC/PP/SC samples with higher AO concentrations, the impact on space charge behaviours is less after ageing, suggesting that ageing (or operating at high temperature) leads to microstructure evolution in SC and can potentially mitigate space accumulation in PP-based insulating materials.

在高压直流(HVDC)电缆中使用基于热塑性聚丙烯(PP)的环保型绝缘材料的潜力已得到广泛研究,但有关基于 PP 的半导体屏蔽(SC)的研究却少之又少。考虑到典型的 HVDC 电缆需要在高温和高电应力条件下具有较长的使用寿命(30 年),因此对抗氧化剂 (AO) 浓度和热氧化稳定性、PP 基 SC 的机械和电气性能的影响进行了研究。研究表明,适当的抗氧化剂组合和用量对于在恶劣环境(150°C,含铜,空气中,7 天)中老化后实现高热稳定性和保持 SC 的机械性能至关重要。虽然在 AO 浓度较高的 SC/PP/SC 样品中观察到了较高的空间电荷量,但老化后对空间电荷行为的影响较小,这表明老化(或在高温下工作)会导致 SC 中微结构的演变,并有可能减轻基于 PP 的绝缘材料中的空间累积。
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引用次数: 0
Parallel multi-rate simulation scheme for modular multilevel converter-based high-voltage direct current with accurate simulation of high-frequency characteristics and field programmable gate array-based implementation 基于模块化多电平转换器的高压直流电并行多速率模拟方案,精确模拟高频特性并基于现场可编程门阵列实现
IF 4.4 2区 工程技术 Q1 Engineering Pub Date : 2024-03-19 DOI: 10.1049/hve2.12418
Chongru Liu, Yanqi Hou, Haoyun Dong, Yipeng Lv, Xinyan Wang, Chenbo Su
The real-time simulation of the modular multilevel converter-based high-voltage direct current (MMC-HVDC) transmission system has become a popular research topic. However, in order to meet the real-time performance, the real-time simulation technology will cause additional simulation errors for MMC-HVDC, especially on its frequency characteristics. Therefore, a parallel multi-rate simulation scheme for MMC-HVDC is developed in this work to ensure accurate simulation of high-frequency characteristics. Firstly, a non-error method based on converter transformer decoupling is proposed to decouple the converter and alternating current system; direct current transmission line decoupling and arm decoupling methods are used to achieve decoupling among and within converters. A multi-rate data synchronous mechanism is established by considering the differences among high-frequency characteristics caused by delayed data interaction. Secondly, the computing architectures of the primary system solver and modular multilevel converter controller are designed based on a field programmable gate array (FPGA). The real-time simulation platform for a four-terminal true bipolar MMC-HVDC is constructed based on the FPGA array. Thirdly, the factors in multi-rate simulation affecting the simulation accuracy of high-frequency characteristics are analysed. The simulator is shown to be accurate in steady and dynamic states. The authors also verify its applicability for further research on high-frequency resonance based on control experiments.
基于模块化多电平换流器的高压直流(MMC-HVDC)输电系统的实时仿真已成为一个热门研究课题。然而,为了满足实时性,实时仿真技术会给 MMC-HVDC 带来额外的仿真误差,尤其是在频率特性方面。因此,本研究开发了一种并行多速率 MMC-HVDC 仿真方案,以确保高频特性的精确仿真。首先,提出了一种基于换流器变压器去耦的无误差方法,以实现换流器与交流系统的去耦;采用直流输电线去耦和臂去耦方法,实现换流器之间和换流器内部的去耦。考虑到延迟数据交互造成的高频特性差异,建立了多速率数据同步机制。其次,基于现场可编程门阵列(FPGA)设计了主系统求解器和模块化多电平转换器控制器的计算架构。基于 FPGA 阵列构建了四端真双极 MMC-HVDC 的实时仿真平台。第三,分析了多速率仿真中影响高频特性仿真精度的因素。结果表明,该模拟器在稳定和动态状态下都很精确。作者还在控制实验的基础上验证了该模拟器在进一步研究高频共振方面的适用性。
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引用次数: 0
Study on moisture absorption characteristics of glass fibre-reinforced epoxy resin material for composite insulators based on the 3D-Fick model 基于 3D-Fick 模型的复合绝缘子用玻璃纤维增强环氧树脂材料吸湿特性研究
IF 4.4 2区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-03-19 DOI: 10.1049/hve2.12433
Yuming Zhang, Yunpeng Liu, Sizu Hou, Jianghai Geng, Ping Wang

Long-term exposure to moisture leads to a gradual deterioration of performance and reduced service life of glass fibre-reinforced epoxy resin (GFRP) material in composite insulators. Therefore, it is necessary to analyse the moisture absorption characteristics of GFRP material and the evolution of damage to their internal interface properties. Moisture absorption tests on GFRP rod material used in composite insulators to obtain their three-dimensional diffusion coefficients are conducted. Atomic force microscopy was then employed to obtain the composite material system's fibre/matrix interfacial phase parameters. Furthermore, a finite element model incorporating representative volume elements with interfacial phases and a mesoscale transient moisture absorption finite element model for the composite material was established. Finally, the moisture absorption characteristics of GFRP material and the evolution of damage to the interfacial phase under thermal-humidity cycling conditions were investigated. The results showed that the diffusion coefficient along the fibre direction in GFRP material was higher than that in the perpendicular direction. The moisture diffusion finite element model, incorporating an anisotropic interfacial phase, fitted the anisotropic diffusion coefficients of GFRP material more accurately. As moisture invaded the GFRP material, the mismatch stresses continuously increased during the moisture absorption. Moreover, the non-uniform arrangement of fibres resulted in uneven distribution of moisture-induced stresses inside the material, leading to higher mismatch stresses in areas with dense fibre arrangements in the matrix. Prolonged high and low humidity cycles led to the development of micro-cracks, micro-porosity, and interface debonding along the fibre direction at the GFRP material interfaces, thereby affecting the anisotropic moisture absorption characteristics of the material. The findings of this study provide valuable insights into the mechanisms underlying the deterioration of GFRP material in composite insulator rods due to moisture degradation.

长期暴露在潮湿环境中会导致复合绝缘子中的玻璃纤维增强环氧树脂(GFRP)材料性能逐渐下降,使用寿命缩短。因此,有必要对玻璃纤维增强环氧树脂材料的吸湿特性及其内部界面特性的损坏演变进行分析。对复合绝缘子中使用的 GFRP 棒材料进行了吸湿测试,以获得其三维扩散系数。然后采用原子力显微镜获取复合材料系统的纤维/基体界面相参数。此外,还建立了一个包含界面相代表性体积元素的有限元模型,以及复合材料的中尺度瞬态吸湿有限元模型。最后,研究了热湿循环条件下 GFRP 材料的吸湿特性和界面相的损伤演变。结果表明,GFRP 材料沿纤维方向的扩散系数高于垂直方向的扩散系数。包含各向异性界面相的湿气扩散有限元模型更准确地拟合了 GFRP 材料的各向异性扩散系数。随着湿气侵入 GFRP 材料,错配应力在吸湿过程中不断增加。此外,由于纤维排列不均匀,材料内部的湿应力分布不均,导致基体中纤维排列密集区域的错配应力更高。长时间的高低湿度循环导致 GFRP 材料界面沿纤维方向出现微裂纹、微孔和界面脱粘,从而影响了材料的各向异性吸湿特性。这项研究的结果为了解复合绝缘子棒中的 GFRP 材料因湿度降解而退化的内在机制提供了宝贵的见解。
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引用次数: 0
Microstructure-ionisation potential relationship analysis for understanding the molecular ionisation difference of natural esters during the impulse discharge via DFT calculation 通过 DFT 计算了解天然酯在脉冲放电过程中的分子电离差的微观结构-电离势关系分析
IF 4.4 2区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-03-19 DOI: 10.1049/hve2.12428
Jingwen Zhang, Jian Hao, Wenyu Ye, Junyi Zhang, Ruijin Liao

Understanding the impulse discharge behaviour of natural ester (NE) is crucial for its safe application in high-voltage transformers. The ionisation potential (IP) of triglycerides plays a significant role in the process of molecular ionisation during impulse discharge for NE. The correlation coefficients between molecular size, frontier orbital, electrostatic potential, polarity, and IP were analysed. And the quantitative microstructure-IP model for triglycerides were built, which revealed that IP is strongly related to the highest occupied molecular orbital (HOMO) energy EHM, as well as the average value of positive electrostatic potential Vp(+), the average value of negative electrostatic potential Vp(−), and the surface area of negative electrostatic potential S(−). The HOMO and negative electrostatic potentials of saturated triglycerides are predominantly linked to the carbonyl O atoms. Conversely, in unsaturated triglycerides, the influence of C=C double bonds on HOMO and negative electrostatic potentials is more pronounced. Therefore, the IP of unsaturated NE with C=C bonds is lower than that of saturated NE, rendering it more susceptible to ionisation under a strong electric field which is unfavourable for impulse breakdown voltage. The structure-property correlation analysis is valuable for understanding ionisation mechanism during the impulse discharge breakdown of NE at the microscopic level.

了解天然酯(NE)的脉冲放电行为对其在高压变压器中的安全应用至关重要。甘油三酯的电离电位(IP)在 NE 的脉冲放电过程中的分子电离过程中起着重要作用。分析了分子大小、前沿轨道、静电电位、极性和 IP 之间的相关系数。建立了甘油三酯的定量微结构-IP 模型,发现 IP 与最高占据分子轨道(HOMO)能量 EHM 以及正静电位 Vp(+)平均值、负静电位 Vp(-)平均值和负静电位 S(-)表面积密切相关。饱和甘油三酯的 HOMO 和负静电位主要与羰基 O 原子相连。相反,在不饱和甘油三酯中,C=C 双键对 HOMO 和负静电势的影响更为明显。因此,带有 C=C 键的不饱和 NE 的 IP 值低于饱和 NE,使其在强电场下更容易电离,不利于脉冲击穿电压。结构-性质相关性分析对于从微观层面了解 NE 在脉冲放电击穿过程中的电离机制很有价值。
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引用次数: 0
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High Voltage
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