As an important part of cultural heritage, paper cultural relics have important historical, scientific and humanistic values. However, a large number of paper cultural relics are suffering from aging, mildew, yellowing, cracks, embrittlement and other threats, or are even completely damaged. To enhance the strength of paper cultural relics and prolong the life of paper cultural relics, a novel CMC-acrylate-OVPOSS graft copolymer was synthesized with carboxymethyl cellulose (CMC), methyl methacrylate (MMA), butyl acrylate (BA), hydroxyethyl methacrylate (HEMA), glycidyl methacrylate (GMA), octavinyl polyhedral oligomeric silsesquioxane (OVPOSS). The synthesized materials were analyzed by infrared spectroscopy, X-ray diffractometer, thermal analyzer and X-ray photoelectron spectroscopy. In addition, the reinforcement solution was coated on the surface of the paper, and the protective effect of the reinforcement solution on the paper was evaluated by testing the mechanical and optical properties of the paper. When the reinforcement solution with a mass concentration of 10 % was coated on the paper, the mechanical properties of the paper were greatly improved, and the gloss and whiteness were basically unchanged.
{"title":"Synthesis of Carboxymethyl Cellulose-Acrylate-OvPOSS Graft Copolymer and its Application in Paper Protection","authors":"Jinjie Zhang, Yingping Qi, Yongfeng Shen, Hua Li","doi":"10.5755/j02.ms.29181","DOIUrl":"https://doi.org/10.5755/j02.ms.29181","url":null,"abstract":"As an important part of cultural heritage, paper cultural relics have important historical, scientific and humanistic values. However, a large number of paper cultural relics are suffering from aging, mildew, yellowing, cracks, embrittlement and other threats, or are even completely damaged. To enhance the strength of paper cultural relics and prolong the life of paper cultural relics, a novel CMC-acrylate-OVPOSS graft copolymer was synthesized with carboxymethyl cellulose (CMC), methyl methacrylate (MMA), butyl acrylate (BA), hydroxyethyl methacrylate (HEMA), glycidyl methacrylate (GMA), octavinyl polyhedral oligomeric silsesquioxane (OVPOSS). The synthesized materials were analyzed by infrared spectroscopy, X-ray diffractometer, thermal analyzer and X-ray photoelectron spectroscopy. In addition, the reinforcement solution was coated on the surface of the paper, and the protective effect of the reinforcement solution on the paper was evaluated by testing the mechanical and optical properties of the paper. When the reinforcement solution with a mass concentration of 10 % was coated on the paper, the mechanical properties of the paper were greatly improved, and the gloss and whiteness were basically unchanged.","PeriodicalId":49875,"journal":{"name":"Materials Science-Poland","volume":" ","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42429516","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The current report focuses on the analysis of the investigation results of the Abrikosov vortex motion in the YBa2Cu3O7-d (YBCO) device, which is a c-axis textured 0.3 ´ 50 ´ 100 µm3 (thickness ´ width ´ length) stripe of YBCO superconductor deposited on a LaAlO3 substrate. A laser beam focused in a Gaussian-shape optical spot of 5 mm in diameter modifies the stripe, initiating the oxygen out-diffusion and its uneven distribution in illuminated areas and in this way causing the appearance of a higher level of deoxygenation in the spot center and a lower level at its edges (slopes of weak superconductivity region). At temperatures below the temperature of the superconducting transition Tc, the current-self-produced magnetic field penetrates the optically modified area of the stripe in a form of Abrikosov magnetic vortices, and due to the current-self-produced Lorentz force, the vortices move toward their annihilation line resulting in energy dissipation. The vortices pinned on the slopes experience strong pinning and exert a magnetic drag force on moving vortices, which is confirmed by the stepped current-voltage dependences of the YBCO devices measured at temperatures 0.933·Tc £ T £ 0.958·Tc. Our results demonstrate the advantages of partially deoxygenated YBCO material for the development of superconducting electronic devices with electronic properties controlled by the motion of Abrikosov vortices at temperatures below Tc of the superconductor.
{"title":"The Investigation of Vortex Motion in the YBCO Devices Manufactured Utilizing a Gaussian-shaped Optical Spot from a Continuous-wave Laser","authors":"A. Jukna","doi":"10.5755/j02.ms.31099","DOIUrl":"https://doi.org/10.5755/j02.ms.31099","url":null,"abstract":"The current report focuses on the analysis of the investigation results of the Abrikosov vortex motion in the YBa2Cu3O7-d (YBCO) device, which is a c-axis textured 0.3 ´ 50 ´ 100 µm3 (thickness ´ width ´ length) stripe of YBCO superconductor deposited on a LaAlO3 substrate. A laser beam focused in a Gaussian-shape optical spot of 5 mm in diameter modifies the stripe, initiating the oxygen out-diffusion and its uneven distribution in illuminated areas and in this way causing the appearance of a higher level of deoxygenation in the spot center and a lower level at its edges (slopes of weak superconductivity region). At temperatures below the temperature of the superconducting transition Tc, the current-self-produced magnetic field penetrates the optically modified area of the stripe in a form of Abrikosov magnetic vortices, and due to the current-self-produced Lorentz force, the vortices move toward their annihilation line resulting in energy dissipation. The vortices pinned on the slopes experience strong pinning and exert a magnetic drag force on moving vortices, which is confirmed by the stepped current-voltage dependences of the YBCO devices measured at temperatures 0.933·Tc £ T £ 0.958·Tc. Our results demonstrate the advantages of partially deoxygenated YBCO material for the development of superconducting electronic devices with electronic properties controlled by the motion of Abrikosov vortices at temperatures below Tc of the superconductor.","PeriodicalId":49875,"journal":{"name":"Materials Science-Poland","volume":" ","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42035191","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Di Ma, Shuying Li, Xinyu Lyu, Shu-bai Li, Yang Cao
A method of fabrication of AAO film in 0.3 mol/L H2C2O4 by adding 1,2-propanediol(PROH) and at sub-zero temperature has been proposed. The electrochemical characteristics of the barrier and porous layers of AAO films before and after pore-filling are examined using electrochemical impedance spectroscopy (EIS). It is shown that the high and medium frequency range corresponds to the barrier layer properties and the low frequency ranges reflect the sealed porous layer properties. The calculated thickness of the barrier layer is in the range of 1 ~ 18 nm. The resistance (Rb) and the thickness (δb) of the barrier layer increase and the capacitance of the barrier layer (CPEb) decrease with the volume percentage of PROH increasing from in electrolyte from 25 % to 75 %. The surface non-homogeneity of AAO film goes better by pore-filling, leading to a decrease in the capacitance of the porous layer (CPEp) and an increase in the porous layer thickness.
{"title":"Electrochemical Impedance Spectroscopy Study of Porous Anodic Alumina Films Fabricated at Low Temperature","authors":"Di Ma, Shuying Li, Xinyu Lyu, Shu-bai Li, Yang Cao","doi":"10.5755/j02.ms.30047","DOIUrl":"https://doi.org/10.5755/j02.ms.30047","url":null,"abstract":"A method of fabrication of AAO film in 0.3 mol/L H2C2O4 by adding 1,2-propanediol(PROH) and at sub-zero temperature has been proposed. The electrochemical characteristics of the barrier and porous layers of AAO films before and after pore-filling are examined using electrochemical impedance spectroscopy (EIS). It is shown that the high and medium frequency range corresponds to the barrier layer properties and the low frequency ranges reflect the sealed porous layer properties. The calculated thickness of the barrier layer is in the range of 1 ~ 18 nm. The resistance (Rb) and the thickness (δb) of the barrier layer increase and the capacitance of the barrier layer (CPEb) decrease with the volume percentage of PROH increasing from in electrolyte from 25 % to 75 %. The surface non-homogeneity of AAO film goes better by pore-filling, leading to a decrease in the capacitance of the porous layer (CPEp) and an increase in the porous layer thickness.","PeriodicalId":49875,"journal":{"name":"Materials Science-Poland","volume":" ","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48661383","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Vicen, O. Bokůvka, F. Nový, R. Nikolić, L. Trško, Z. Florková
The presented work deals with an analysis of causes of the very low service life of the new version of hand woodworking planing knife, which has replaced the original version of a planing knife. Based on the performed experimental works, chemical analysis, macroscopic and microscopic observation, SEM, diffractometric analysis, and Vickers hardness test it was concluded that the cause for the very low service life (practically the nonexistent one) of the new version of a planing knife are significant features of overheating. During the heating to the hardening temperature used steel was overheated, the cementite carbides dissolved, and the austenitic grains became coarse. The final microstructure of the used steel after hardening and tempering consists of brittle coarse martensitic needles, without any presence of the fine globular cementite carbides, accompanied by a very high amount of retained austenite. Thus, the chipping of the knife's cutting edge took place and the planer was unusable.
{"title":"Analysis of the Low Service Life of a Planing Knife – A Case Study","authors":"M. Vicen, O. Bokůvka, F. Nový, R. Nikolić, L. Trško, Z. Florková","doi":"10.5755/j02.ms.31109","DOIUrl":"https://doi.org/10.5755/j02.ms.31109","url":null,"abstract":"The presented work deals with an analysis of causes of the very low service life of the new version of hand woodworking planing knife, which has replaced the original version of a planing knife. Based on the performed experimental works, chemical analysis, macroscopic and microscopic observation, SEM, diffractometric analysis, and Vickers hardness test it was concluded that the cause for the very low service life (practically the nonexistent one) of the new version of a planing knife are significant features of overheating. During the heating to the hardening temperature used steel was overheated, the cementite carbides dissolved, and the austenitic grains became coarse. The final microstructure of the used steel after hardening and tempering consists of brittle coarse martensitic needles, without any presence of the fine globular cementite carbides, accompanied by a very high amount of retained austenite. Thus, the chipping of the knife's cutting edge took place and the planer was unusable.","PeriodicalId":49875,"journal":{"name":"Materials Science-Poland","volume":" ","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46358234","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nelson OSHOGWUE ETAFO, Joshua Omar Carranza, Carlos Eduardo RODRIGUEZ GARCIA, J. Oliva, E. VIESCA-VILLANUEVA, E. Hernández‐Hernández, Alejandro Santibañez, Oscar GOMEZ-ZAVALA
In this study, pure Sr2CeO4 (SCO) and codoped Sr2CeO4:Tm3+, Yb3+ (SCO:Tm, Yb) of powder phosphors were synthesized by a combustion technique. The concentration of Tm3+ was fixed at 0.5 mol %, while the Yb3+ doping concentration was varied from 0 to 7.0 mol %. The crystalline structure, morphology and luminescence properties were studied using X-ray diffraction (XRD), scanning electron microscope (SEM) and photoluminescence spectroscopy, respectively. The XRD analysis shows the crystalline orthorhombic phase for all synthesized samples of SCO and SCO: Tm, Yb. The SEM results show that the doped sample with 5.0 mol % Yb3+ has the lowest grain particle size of 1.92 mm. The SCO:Tm, Yb phosphors produce mainly blue and near infrared emission bands centered at 481 nm and 813 nm (under 980 nm, excitation) which corresponds respectively to 1G4→3H6 and 3H4→3H6 transitions of Tm3+. In addition, the international commission on illumination CIE coordinates were calculated for all samples taking the range of 400 – 700 nm obtaining for the 5.0 mol % Tm3+ doped sample the coordinates: (x,y) = (0.0833, 0.1671) which match with pure blue color. Due to the strong blue and near infrared emissions, the SCO:Tm, Yb phosphors could be good candidates for use in biomarkers or lighting applications.
{"title":"Blue/NIR-emitting Phosphor Based on Sr2CeO4: Tm3+, Yb3+ Obtained by Combustion Synthesis","authors":"Nelson OSHOGWUE ETAFO, Joshua Omar Carranza, Carlos Eduardo RODRIGUEZ GARCIA, J. Oliva, E. VIESCA-VILLANUEVA, E. Hernández‐Hernández, Alejandro Santibañez, Oscar GOMEZ-ZAVALA","doi":"10.5755/j02.ms.32518","DOIUrl":"https://doi.org/10.5755/j02.ms.32518","url":null,"abstract":"In this study, pure Sr2CeO4 (SCO) and codoped Sr2CeO4:Tm3+, Yb3+ (SCO:Tm, Yb) of powder phosphors were synthesized by a combustion technique. The concentration of Tm3+ was fixed at 0.5 mol %, while the Yb3+ doping concentration was varied from 0 to 7.0 mol %. The crystalline structure, morphology and luminescence properties were studied using X-ray diffraction (XRD), scanning electron microscope (SEM) and photoluminescence spectroscopy, respectively. The XRD analysis shows the crystalline orthorhombic phase for all synthesized samples of SCO and SCO: Tm, Yb. The SEM results show that the doped sample with 5.0 mol % Yb3+ has the lowest grain particle size of 1.92 mm. The SCO:Tm, Yb phosphors produce mainly blue and near infrared emission bands centered at 481 nm and 813 nm (under 980 nm, excitation) which corresponds respectively to 1G4→3H6 and 3H4→3H6 transitions of Tm3+. In addition, the international commission on illumination CIE coordinates were calculated for all samples taking the range of 400 – 700 nm obtaining for the 5.0 mol % Tm3+ doped sample the coordinates: (x,y) = (0.0833, 0.1671) which match with pure blue color. Due to the strong blue and near infrared emissions, the SCO:Tm, Yb phosphors could be good candidates for use in biomarkers or lighting applications.","PeriodicalId":49875,"journal":{"name":"Materials Science-Poland","volume":" ","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48309731","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-02-01DOI: 10.31044/1684-579x-2023-0-2-3-11
I. Karpov, A. Ushakov, L. Fedorov, E. Goncharova, M. Brungardt
В работе исследованы нанопорошки оксида никеля, синтезированные в плазме дугового разряда, при давлении газовой смеси в камере 70 Па с использованием аргона в качестве плазмообразующего газа. Наночастицы осаждали на подложку при температурах 300, 400, 500 и 600 K в течение 30 мин. Результаты рентгеноструктурного анализа подтверждают поликристаллический характер полученных наночастиц NiO при различных температурах осаждения. Размер наночастиц находится в диапазоне 3,2—32,7 нм. По результатам исследований намагниченности образцов с охлаждением в нулевом поле и с охлаждением в поле выявлена магнитная структура наночастиц NiO по типу ядро / оболочка. Высказаны предположения относительно магнитного состояния ядра и оболочки частиц.
{"title":"Ferromagnetic Interaction in Nickel Oxide Nanoparticles of Vacuum Arc Synthesis","authors":"I. Karpov, A. Ushakov, L. Fedorov, E. Goncharova, M. Brungardt","doi":"10.31044/1684-579x-2023-0-2-3-11","DOIUrl":"https://doi.org/10.31044/1684-579x-2023-0-2-3-11","url":null,"abstract":"В работе исследованы нанопорошки оксида никеля, синтезированные в плазме дугового разряда, при давлении газовой смеси в камере 70 Па с использованием аргона в качестве плазмообразующего газа. Наночастицы осаждали на подложку при температурах 300, 400, 500 и 600 K в течение 30 мин. Результаты рентгеноструктурного анализа подтверждают поликристаллический характер полученных наночастиц NiO при различных температурах осаждения. Размер наночастиц находится в диапазоне 3,2—32,7 нм. По результатам исследований намагниченности образцов с охлаждением в нулевом поле и с охлаждением в поле выявлена магнитная структура наночастиц NiO по типу ядро / оболочка. Высказаны предположения относительно магнитного состояния ядра и оболочки частиц.","PeriodicalId":49875,"journal":{"name":"Materials Science-Poland","volume":" ","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46749431","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Research studies investigating the possibility of using new core material (other than polystyrene) in concrete sandwich panels are being reported in the literature. In this paper, lightweight pervious concrete core is proposed as a new alternative. In this paper, the flexural behaviour of concrete sandwich panels with pervious concrete core is investigated under three-point and four-point bending conditions. The geometrical variables considered are core thickness and number of shear connector lines. Test results showed that, sandwich panels without shear connector trusses failed due to separation of wythes, and the panels with shear connector trusses achieved composite action. The variables considered were found to influence the initial stiffness, cracking moment, ultimate moment, load-deflection behaviour and load-strain behaviour of the panels. Analytical study indicated that the equation given in ACI 318 underestimated the strength of the tested panels. The equation have to be modified by explicitly including the shear connector details in the equation for predicting the flexural strength with reasonable accuracy. Further experimental and analytical studies on prototype concrete sandwich panels with pervious concrete core produced using lightweight aggregates are required in view of developing design guidelines for practical applications.
{"title":"Behaviour of Innovative Concrete Sandwich Panels with Pervious Concrete Core under Flexural Bending","authors":"J. ARUNRAJ CHRISTADOSS, Chinnaraj Pazhani","doi":"10.5755/j02.ms.32859","DOIUrl":"https://doi.org/10.5755/j02.ms.32859","url":null,"abstract":"Research studies investigating the possibility of using new core material (other than polystyrene) in concrete sandwich panels are being reported in the literature. In this paper, lightweight pervious concrete core is proposed as a new alternative. In this paper, the flexural behaviour of concrete sandwich panels with pervious concrete core is investigated under three-point and four-point bending conditions. The geometrical variables considered are core thickness and number of shear connector lines. Test results showed that, sandwich panels without shear connector trusses failed due to separation of wythes, and the panels with shear connector trusses achieved composite action. The variables considered were found to influence the initial stiffness, cracking moment, ultimate moment, load-deflection behaviour and load-strain behaviour of the panels. Analytical study indicated that the equation given in ACI 318 underestimated the strength of the tested panels. The equation have to be modified by explicitly including the shear connector details in the equation for predicting the flexural strength with reasonable accuracy. Further experimental and analytical studies on prototype concrete sandwich panels with pervious concrete core produced using lightweight aggregates are required in view of developing design guidelines for practical applications.","PeriodicalId":49875,"journal":{"name":"Materials Science-Poland","volume":" ","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-01-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46589364","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
J. Duplák, D. Dupláková, D. Mital, Zuzana Mitaľová
The usage of knowledge obtained by connecting various scientific areas provides new opportunities for developing multidisciplinary branches to improve processes, procedures, technologies, and products. The present paper is devoted to the description of new approaches to material engineering and its possibilities in the process of the selection of materials intended for the production of dental implants. To ensure the conciseness of the article, a selection of state-of-the-art of scientific contributions is created in the introductory part in the form of a summary table, based on which the following parts of the article are elaborated. The first view of new ways of materials engineering is provided through the elaboration of the categorization of the setting of biological materials used in the production of dental implants, while taking into account current trends, technologies and findings. The second view of new ways of materials engineering is an extended complex process of selection and implementation of biomaterials intended for the production of dental implants originally created and adopted by the American Dental Association. Future studies should investigate the comprehensive analysis of technologies for the production of dental implant materials and also analysis of ways of digitization in the production of dental implants.
{"title":"New Ways of Materials Engineering Implementation in the Selection Processes of Biomaterials Intended for the Production of Dental Implants – Narrative Literature Review","authors":"J. Duplák, D. Dupláková, D. Mital, Zuzana Mitaľová","doi":"10.5755/j02.ms.32685","DOIUrl":"https://doi.org/10.5755/j02.ms.32685","url":null,"abstract":"The usage of knowledge obtained by connecting various scientific areas provides new opportunities for developing multidisciplinary branches to improve processes, procedures, technologies, and products. The present paper is devoted to the description of new approaches to material engineering and its possibilities in the process of the selection of materials intended for the production of dental implants. To ensure the conciseness of the article, a selection of state-of-the-art of scientific contributions is created in the introductory part in the form of a summary table, based on which the following parts of the article are elaborated. The first view of new ways of materials engineering is provided through the elaboration of the categorization of the setting of biological materials used in the production of dental implants, while taking into account current trends, technologies and findings. The second view of new ways of materials engineering is an extended complex process of selection and implementation of biomaterials intended for the production of dental implants originally created and adopted by the American Dental Association. Future studies should investigate the comprehensive analysis of technologies for the production of dental implant materials and also analysis of ways of digitization in the production of dental implants.","PeriodicalId":49875,"journal":{"name":"Materials Science-Poland","volume":" ","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-01-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45276161","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xue Fang, Xian-Lu Cui, G. Su, Mingyue Chen, Meihui Song, Xiaochen Zhang, Yang Wang, B. Huang
To make the polyimide (PI) composite material having both heat resistance and magnetic permeability, Fe3O4/PI magnetic polyimide composite powder was synthesized by one-step solvothermal method. 4,4'-diaminodiphenyl ether (ODA) as monomers, ether anhydride polyamic acid (PAA) was designed and prepared by Fe3+ and polyimide precursor-polyamic acid triethylamine salt (PAAS) was reacted in a reactor, and the PI/Fe3O4 composite powders were synthesized under the condition of high temperature and high pressure. The obtained PI/Fe3O4 composite powders were analyzed by infrared spectroscopy, microscopic morphology and thermal properties. The morphology and structure of the samples were both characterized by scanning electron microscopy (SEM) and infrared spectroscopy (IR). The thermal properties of the composite microspheres were studied via thermogravimetric analysis (TGA) and the magnetic properties were determined by a vibrating sample magnetometer (VSM). The saturation magnetization decreases gradually, increasing the polyimide content, with a saturation magnetization of PI/Fe3O4 determined to be 20.29 emu/g.
{"title":"Preparation and Properties Magnetite/Polyimide Composites","authors":"Xue Fang, Xian-Lu Cui, G. Su, Mingyue Chen, Meihui Song, Xiaochen Zhang, Yang Wang, B. Huang","doi":"10.5755/j02.ms.32188","DOIUrl":"https://doi.org/10.5755/j02.ms.32188","url":null,"abstract":"To make the polyimide (PI) composite material having both heat resistance and magnetic permeability, Fe3O4/PI magnetic polyimide composite powder was synthesized by one-step solvothermal method. 4,4'-diaminodiphenyl ether (ODA) as monomers, ether anhydride polyamic acid (PAA) was designed and prepared by Fe3+ and polyimide precursor-polyamic acid triethylamine salt (PAAS) was reacted in a reactor, and the PI/Fe3O4 composite powders were synthesized under the condition of high temperature and high pressure. The obtained PI/Fe3O4 composite powders were analyzed by infrared spectroscopy, microscopic morphology and thermal properties. The morphology and structure of the samples were both characterized by scanning electron microscopy (SEM) and infrared spectroscopy (IR). The thermal properties of the composite microspheres were studied via thermogravimetric analysis (TGA) and the magnetic properties were determined by a vibrating sample magnetometer (VSM). The saturation magnetization decreases gradually, increasing the polyimide content, with a saturation magnetization of PI/Fe3O4 determined to be 20.29 emu/g.","PeriodicalId":49875,"journal":{"name":"Materials Science-Poland","volume":" ","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-01-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43694750","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The white fabric was printed with different printing temperatures and pressing times using the sublimation printing process in solid-tone black color with a 100 % total ink limiting level. Non-uniformity of the print was examined through print mottle determined by grey level co-occurrence matrix (GLCM) image processing method. Color strength of print was also determined by reflectance spectrophotometry. The print with the lower print mottle was obtained at a printing temperature of 190 °C at a longer pressing time of 120 s or at an increased printing temperature of up to 210 °C at the reduced pressing time of 60 s. The print with the lower print mottle had the lowest entropy, contrast, and correlation and the highest energy and homogeneity. The print with a higher color strength was accompanied by decreased print mottle. Choosing a suitable printing temperature and pressing time for sublimation printing is helpful in achieving print with low print mottle and high color strength and balancing cost, price, and price.
{"title":"Textile Sublimation Printing: GLCM Print Mottle Assessment of Black Printed Fabric","authors":"Emilija Toshikj, Bojan Prangoski","doi":"10.5755/j02.ms.32465","DOIUrl":"https://doi.org/10.5755/j02.ms.32465","url":null,"abstract":"The white fabric was printed with different printing temperatures and pressing times using the sublimation printing process in solid-tone black color with a 100 % total ink limiting level. Non-uniformity of the print was examined through print mottle determined by grey level co-occurrence matrix (GLCM) image processing method. Color strength of print was also determined by reflectance spectrophotometry. The print with the lower print mottle was obtained at a printing temperature of 190 °C at a longer pressing time of 120 s or at an increased printing temperature of up to 210 °C at the reduced pressing time of 60 s. The print with the lower print mottle had the lowest entropy, contrast, and correlation and the highest energy and homogeneity. The print with a higher color strength was accompanied by decreased print mottle. Choosing a suitable printing temperature and pressing time for sublimation printing is helpful in achieving print with low print mottle and high color strength and balancing cost, price, and price.","PeriodicalId":49875,"journal":{"name":"Materials Science-Poland","volume":"1 1","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"71237932","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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